[CP2K-user] [CP2K:17142] Re: "Fastest" AIMD simulation settings/parameters

Lenard Carroll lenardcarroll27 at gmail.com
Mon Jun 13 09:25:49 UTC 2022


I have attached my general input file, but also my output file which has
the timings.

On Mon, Jun 13, 2022 at 11:13 AM Jürg Hutter <hutter at chem.uzh.ch> wrote:

> Hi
>
> you have to provide enough information in order to give an educated answer.
> In your case, if you only changed the thermostat and that leads to a 10
> fold
> slow down of the calculation, you need to investigate the timing output at
> the
> end of the runs.
> Is the timing for the thermostat dominating your calculation? This would be
> very special and has to be investigated.
> Are there side effects, e.g. number of SCF iterations increasing? Also
> very unusual
> and should be investigated.
>
> You can see: no specific question backed with enough information - no
> good  answers.
>
> regards
>
> Juerg Hutter
>
> ________________________________________
> From: cp2k at googlegroups.com <cp2k at googlegroups.com> on behalf of ASSIDUO
> Network <lenardcarroll27 at gmail.com>
> Sent: Sunday, June 12, 2022 9:06 PM
> To: cp2k
> Subject: [CP2K:17134] Re: "Fastest" AIMD simulation settings/parameters
>
> Just replying to this to bump it higher since I haven't received a
> response yet.
>
> On Thursday, June 9, 2022 at 3:38:02 AM UTC+2 ASSIDUO Network wrote:
> Hi there, I have been running AIMD simulations for about a year now and it
> originally started off really slow, only getting 60 fs per day. In
> particular, I used the NVT ensemble and the Nose-Hoover thermostat. When
> swapping to the Langevin ensemble and adaptive-Langevin thermostat, the
> simulation time improved to 200-600 fs a day.
>
> I wanted to know what settings/parameters you would suggest to improve the
> speed even further? That is, what are the best settings to choose to get
> the fastest performance?
>
> Key things to keep in mind for my work:
> Using GTH-PBE potential and the DZVP-MOLOPT-SR-GTH basis set. Fermi dirac
> smearing must also be used
>
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>

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 DBCSR| CPU Multiplication driver                                           BLAS
 DBCSR| Multrec recursion limit                                              512
 DBCSR| Multiplication stack size                                           1000
 DBCSR| Maximum elements for images                                    UNLIMITED
 DBCSR| Multiplicative factor virtual images                                   1
 DBCSR| Use multiplication densification                                       T
 DBCSR| Multiplication size stacks                                             3
 DBCSR| Use memory pool for CPU allocation                                     F
 DBCSR| Number of 3D layers                                               SINGLE
 DBCSR| Use MPI memory allocation                                              F
 DBCSR| Use RMA algorithm                                                      F
 DBCSR| Use Communication thread                                               T
 DBCSR| Communication thread load                                             87
 DBCSR| MPI: My node id                                                        0
 DBCSR| MPI: Number of nodes                                                 108
 DBCSR| OMP: Current number of threads                                         1
 DBCSR| OMP: Max number of threads                                             1
 DBCSR| Split modifier for TAS multiplication algorithm                  1.0E+00


  **** **** ******  **  PROGRAM STARTED AT               2022-06-07 04:10:04.432
 ***** ** ***  *** **   PROGRAM STARTED ON                                acc104
 **    ****   ******    PROGRAM STARTED BY                             icre12895
 ***** **    ** ** **   PROGRAM PROCESS ID                                 89786
  **** **  *******  **  PROGRAM STARTED IN /ws/icre12/copy/AIMD/NONE-WITHOUT/CON
                                           T/Continue

 CP2K| version string:                                          CP2K version 8.1
 CP2K| source code revision number:                                  git:0b61f2f
 CP2K| cp2kflags: omp fftw3 elpa parallel mpi3 scalapack                        
 CP2K| is freely available from                            https://www.cp2k.org/
 CP2K| Program compiled at                          Wed Mar  9 08:35:11 CET 2022
 CP2K| Program compiled on                                                acc101
 CP2K| Program compiled for                           Linux-x86-64-gfortran-turg
 CP2K| Data directory path                             /home/icre12895/cp2k/data
 CP2K| Input file name                                 AU_AIMD-MD.REST-1.restart

 GLOBAL| Force Environment number                                              1
 GLOBAL| Basis set file name                                        BASIS_MOLOPT
 GLOBAL| Potential file name                                      GTH_POTENTIALS
 GLOBAL| MM Potential file name                                     MM_POTENTIAL
 GLOBAL| Coordinate file name                                      __STD_INPUT__
 GLOBAL| Method name                                                        CP2K
 GLOBAL| Project name                                                    AU_AIMD
 GLOBAL| Preferred FFT library                                             FFTW3
 GLOBAL| Preferred diagonalization lib.                                     ELPA
 GLOBAL| Run type                                                             MD
 GLOBAL| All-to-all communication in single precision                          F
 GLOBAL| FFTs using library dependent lengths                                  F
 GLOBAL| Global print level                                                  LOW
 GLOBAL| MPI I/O enabled                                                       T
 GLOBAL| Total number of message passing processes                           108
 GLOBAL| Number of threads for this process                                    1
 GLOBAL| This output is from process                                           0
 GLOBAL| CPU model name                 Intel(R) Xeon(R) Gold 6254 CPU @ 3.10GHz

 MEMORY| system memory details [Kb]
 MEMORY|                        rank 0           min           max       average
 MEMORY| MemTotal            196524180     196516100     196524180     196518793
 MEMORY| MemFree             186659764     186659764     186791652     186745541
 MEMORY| Buffers                585704        557160        585704        569072
 MEMORY| Cached                1246480       1151972       1246480       1185277
 MEMORY| Slab                   462616        462616        490804        474745
 MEMORY| SReclaimable           253452        253452        260916        257693
 MEMORY| MemLikelyFree       188745400     188745400     188772096     188757584


 GENERATE|  Preliminary Number of Bonds generated:                             0
 GENERATE|  Achieved consistency in connectivity generation.

 *******************************************************************************
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 **                                                                           **
 **                                                ... make the atoms dance   **
 **                                                                           **
 **            Copyright (C) by CP2K developers group (2000 - 2020)           **
 **                      J. Chem. Phys. 152, 194103 (2020)                    **
 **                                                                           **
 *******************************************************************************


 TOTAL NUMBERS AND MAXIMUM NUMBERS

  Total number of            - Atomic kinds:                                   2
                             - Atoms:                                        152
                             - Shell sets:                                   152
                             - Shells:                                      1048
                             - Primitive Cartesian functions:                760
                             - Cartesian basis functions:                   4432
                             - Spherical basis functions:                   3704

  Maximum angular momentum of- Orbital basis functions:                        3
                             - Local part of the GTH pseudopotential:          2
                             - Non-local part of the GTH pseudopotential:      4


 MODULE QUICKSTEP:  ATOMIC COORDINATES IN angstrom

  Atom  Kind  Element       X           Y           Z          Z(eff)       Mass

       1     1 Au  79    0.000000    0.000000    0.000000     11.0000     196.9666
       2     1 Au  79    0.000000    2.950430    0.000000     11.0000     196.9666
       3     1 Au  79    0.000000    5.900860    0.000000     11.0000     196.9666
       4     1 Au  79    8.851290    0.000000    0.000000     11.0000     196.9666
       5     1 Au  79    8.851290    2.950430    0.000000     11.0000     196.9666
       6     1 Au  79    8.851290    5.900860    0.000000     11.0000     196.9666
       7     1 Au  79    0.000000    8.851290    0.000000     11.0000     196.9666
       8     1 Au  79    0.000000   11.801720    0.000000     11.0000     196.9666
       9     1 Au  79    0.000000   14.752150    0.000000     11.0000     196.9666
      10     1 Au  79    8.851290    8.851290    0.000000     11.0000     196.9666
      11     1 Au  79    8.851290   11.801720    0.000000     11.0000     196.9666
      12     1 Au  79    8.851290   14.752150    0.000000     11.0000     196.9666
      13     1 Au  79    2.458690    1.475210    0.695420     11.0000     196.9666
      14     1 Au  79    2.458690    4.425650    0.695420     11.0000     196.9666
      15     1 Au  79    2.458690    7.376070    0.695420     11.0000     196.9666
      16     1 Au  79   11.309980    1.475210    0.695420     11.0000     196.9666
      17     1 Au  79   11.309980    4.425650    0.695420     11.0000     196.9666
      18     1 Au  79   11.309980    7.376070    0.695420     11.0000     196.9666
      19     1 Au  79    2.458690   10.326500    0.695420     11.0000     196.9666
      20     1 Au  79    2.458690   13.276940    0.695420     11.0000     196.9666
      21     1 Au  79    2.458690   16.227360    0.695420     11.0000     196.9666
      22     1 Au  79   11.309980   10.326500    0.695420     11.0000     196.9666
      23     1 Au  79   11.309980   13.276940    0.695420     11.0000     196.9666
      24     1 Au  79   11.309980   16.227360    0.695420     11.0000     196.9666
      25     1 Au  79    4.917380    0.000000    1.390850     11.0000     196.9666
      26     1 Au  79    4.917380    2.950430    1.390850     11.0000     196.9666
      27     1 Au  79    4.917380    5.900860    1.390850     11.0000     196.9666
      28     1 Au  79   13.768670    0.000000    1.390850     11.0000     196.9666
      29     1 Au  79   13.768670    2.950430    1.390850     11.0000     196.9666
      30     1 Au  79   13.768670    5.900860    1.390850     11.0000     196.9666
      31     1 Au  79    4.917380    8.851290    1.390850     11.0000     196.9666
      32     1 Au  79    4.917380   11.801720    1.390850     11.0000     196.9666
      33     1 Au  79    4.917380   14.752150    1.390850     11.0000     196.9666
      34     1 Au  79   13.768670    8.851290    1.390850     11.0000     196.9666
      35     1 Au  79   13.768670   11.801720    1.390850     11.0000     196.9666
      36     1 Au  79   13.768670   14.752150    1.390850     11.0000     196.9666
      37     1 Au  79    7.376070    1.475210    2.086270     11.0000     196.9666
      38     1 Au  79    7.376070    4.425650    2.086270     11.0000     196.9666
      39     1 Au  79    7.376070    7.376070    2.086270     11.0000     196.9666
      40     1 Au  79   16.227360    1.475210    2.086270     11.0000     196.9666
      41     1 Au  79   16.227360    4.425650    2.086270     11.0000     196.9666
      42     1 Au  79   16.227360    7.376070    2.086270     11.0000     196.9666
      43     1 Au  79    7.376070   10.326500    2.086270     11.0000     196.9666
      44     1 Au  79    7.376070   13.276940    2.086270     11.0000     196.9666
      45     1 Au  79    7.376070   16.227360    2.086270     11.0000     196.9666
      46     1 Au  79   16.227360   10.326500    2.086270     11.0000     196.9666
      47     1 Au  79   16.227360   13.276940    2.086270     11.0000     196.9666
      48     1 Au  79   16.227360   16.227360    2.086270     11.0000     196.9666
      49     1 Au  79    0.983480    0.000000    2.781690     11.0000     196.9666
      50     1 Au  79    0.983480    2.950430    2.781690     11.0000     196.9666
      51     1 Au  79    0.983480    5.900860    2.781690     11.0000     196.9666
      52     1 Au  79    9.834770    0.000000    2.781690     11.0000     196.9666
      53     1 Au  79    9.834770    2.950430    2.781690     11.0000     196.9666
      54     1 Au  79    9.834770    5.900860    2.781690     11.0000     196.9666
      55     1 Au  79    0.983480    8.851290    2.781690     11.0000     196.9666
      56     1 Au  79    0.983480   11.801720    2.781690     11.0000     196.9666
      57     1 Au  79    0.983480   14.752150    2.781690     11.0000     196.9666
      58     1 Au  79    9.834770    8.851290    2.781690     11.0000     196.9666
      59     1 Au  79    9.834770   11.801720    2.781690     11.0000     196.9666
      60     1 Au  79    9.834770   14.752150    2.781690     11.0000     196.9666
      61     1 Au  79    3.442170    1.475210    3.477110     11.0000     196.9666
      62     1 Au  79    3.442170    4.425650    3.477110     11.0000     196.9666
      63     1 Au  79    3.442170    7.376070    3.477110     11.0000     196.9666
      64     1 Au  79   12.293460    1.475210    3.477110     11.0000     196.9666
      65     1 Au  79   12.293460    4.425650    3.477110     11.0000     196.9666
      66     1 Au  79   12.293460    7.376070    3.477110     11.0000     196.9666
      67     1 Au  79    3.442170   10.326500    3.477110     11.0000     196.9666
      68     1 Au  79    3.442170   13.276940    3.477110     11.0000     196.9666
      69     1 Au  79    3.442170   16.227360    3.477110     11.0000     196.9666
      70     1 Au  79   12.293460   10.326500    3.477110     11.0000     196.9666
      71     1 Au  79   12.293460   13.276940    3.477110     11.0000     196.9666
      72     1 Au  79   12.293460   16.227360    3.477110     11.0000     196.9666
      73     1 Au  79    5.746535    0.094215    4.806718     11.0000     196.9666
      74     1 Au  79    7.951006    1.437802    4.978598     11.0000     196.9666
      75     1 Au  79    5.982540    5.769482    4.243450     11.0000     196.9666
      76     1 Au  79   16.378524   -1.276653    5.088502     11.0000     196.9666
      77     1 Au  79   15.299684    2.110143    5.000652     11.0000     196.9666
      78     1 Au  79   15.038871    6.333493    4.673865     11.0000     196.9666
      79     1 Au  79    5.786820    8.653810    4.723231     11.0000     196.9666
      80     1 Au  79    6.004422   11.624369    4.334651     11.0000     196.9666
      81     1 Au  79    5.753086   14.681343    4.146521     11.0000     196.9666
      82     1 Au  79   15.752843    9.422450    4.725330     11.0000     196.9666
      83     1 Au  79   13.711685   14.317742    5.920557     11.0000     196.9666
      84     1 Au  79   14.738749   16.152214    7.702161     11.0000     196.9666
      85     1 Au  79   10.756558    3.283065    5.845601     11.0000     196.9666
      86     1 Au  79    8.466845    4.389079    5.074695     11.0000     196.9666
      87     1 Au  79    8.301732    7.203947    4.750849     11.0000     196.9666
      88     1 Au  79   20.829999    2.031784    7.212468     11.0000     196.9666
      89     1 Au  79   18.583839    2.223521    5.554745     11.0000     196.9666
      90     1 Au  79   17.907442    7.207297    5.186126     11.0000     196.9666
      91     1 Au  79    8.319962   10.214722    4.740092     11.0000     196.9666
      92     1 Au  79    8.143699   13.355278    5.054053     11.0000     196.9666
      93     1 Au  79    9.251414   15.715793    7.100271     11.0000     196.9666
      94     1 Au  79   17.579338   11.315837    5.455097     11.0000     196.9666
      95     1 Au  79   14.782266   12.167617    4.481731     11.0000     196.9666
      96     1 Au  79   19.129666   16.575294    5.836086     11.0000     196.9666
      97     1 Au  79    6.685172   -1.659730    7.092851     11.0000     196.9666
      98     1 Au  79    5.448236    2.820962    4.924720     11.0000     196.9666
      99     1 Au  79    7.803138    3.921776    7.737128     11.0000     196.9666
     100     1 Au  79   11.052339    0.114611    5.574960     11.0000     196.9666
     101     1 Au  79   13.482268    2.681948    8.112022     11.0000     196.9666
     102     1 Au  79   11.025238    6.243460    5.740728     11.0000     196.9666
     103     1 Au  79    3.683202   11.830235    5.963696     11.0000     196.9666
     104     1 Au  79    6.169175   10.454064    9.565206     11.0000     196.9666
     105     1 Au  79    4.307268   14.445046    6.596343     11.0000     196.9666
     106     1 Au  79   11.260508    9.668178    6.415091     11.0000     196.9666
     107     1 Au  79    9.391210   11.611946    6.770771     11.0000     196.9666
     108     1 Au  79   10.917316   14.456799    5.480744     11.0000     196.9666
     109     1 Au  79    5.146979    4.266093    7.439761     11.0000     196.9666
     110     1 Au  79    2.221590    4.677965    7.421821     11.0000     196.9666
     111     1 Au  79    4.237031    6.962797    8.858800     11.0000     196.9666
     112     1 Au  79   16.668040    0.790299    6.920189     11.0000     196.9666
     113     1 Au  79    9.385572    7.805165    7.452563     11.0000     196.9666
     114     1 Au  79   13.567621    8.306153    5.992689     11.0000     196.9666
     115     1 Au  79    1.794417    7.460558    7.874167     11.0000     196.9666
     116     1 Au  79    3.360528   13.133681    8.798798     11.0000     196.9666
     117     1 Au  79    6.432394   12.811506    7.156056     11.0000     196.9666
     118     1 Au  79   14.466818    8.384715    8.771434     11.0000     196.9666
     119     1 Au  79   12.199896   11.995322    6.032043     11.0000     196.9666
     120     1 Au  79   11.877868   17.807106    9.171780     11.0000     196.9666
     121     1 Au  79    9.276894    1.198461    7.421091     11.0000     196.9666
     122     1 Au  79    6.593337    1.139750    7.630575     11.0000     196.9666
     123     1 Au  79    5.920174    3.721817    9.895317     11.0000     196.9666
     124     1 Au  79   18.191054   -2.091710    8.728937     11.0000     196.9666
     125     1 Au  79   16.206602    3.607903    7.405703     11.0000     196.9666
     126     1 Au  79   17.380387    4.500623    5.104648     11.0000     196.9666
     127     1 Au  79    6.450820    7.433399   10.131192     11.0000     196.9666
     128     1 Au  79    4.307208    9.086750    7.065395     11.0000     196.9666
     129     1 Au  79    7.233286    9.713557    7.163127     11.0000     196.9666
     130     1 Au  79   16.765435    9.540545    7.766253     11.0000     196.9666
     131     1 Au  79   14.470066   10.601703    6.879079     11.0000     196.9666
     132     1 Au  79   15.945236   13.702038    6.951417     11.0000     196.9666
     133     1 Au  79    1.436488    1.514795    8.936055     11.0000     196.9666
     134     1 Au  79    3.774621    6.438391    6.077164     11.0000     196.9666
     135     1 Au  79    2.398403   10.238835    8.602683     11.0000     196.9666
     136     1 Au  79   11.195155    4.785901    8.246236     11.0000     196.9666
     137     1 Au  79   13.990852    4.267319    5.959417     11.0000     196.9666
     138     1 Au  79   16.482080    6.343750    7.475409     11.0000     196.9666
     139     1 Au  79    1.418313   13.884509    5.626417     11.0000     196.9666
     140     1 Au  79    0.299814   12.132488    8.593231     11.0000     196.9666
     141     1 Au  79    4.245037   16.518397    8.364926     11.0000     196.9666
     142     1 Au  79   12.320508    7.326183    8.159407     11.0000     196.9666
     143     1 Au  79    6.567508    6.542102    6.909431     11.0000     196.9666
     144     1 Au  79    9.108261   19.142837    9.998640     11.0000     196.9666
     145     2 O    8   11.185490    2.623832    9.542775      6.0000      15.9994
     146     2 O    8    7.016272   18.995640    9.936335      6.0000      15.9994
     147     2 O    8    7.418919    8.982652   10.415336      6.0000      15.9994
     148     2 O    8    5.318584    5.571111   10.329695      6.0000      15.9994
     149     2 O    8   13.056991   15.962002    8.747037      6.0000      15.9994
     150     2 O    8    2.127612   -0.395282    9.109643      6.0000      15.9994
     151     2 O    8    1.074716    3.535687    8.933949      6.0000      15.9994
     152     2 O    8    5.319683   12.286073    9.214197      6.0000      15.9994




 SCF PARAMETERS         Density guess:                                    ATOMIC
                        --------------------------------------------------------
                        max_scf:                                             200
                        max_scf_history:                                       0
                        max_diis:                                              4
                        --------------------------------------------------------
                        eps_scf:                                        1.00E-06
                        eps_scf_history:                                0.00E+00
                        eps_diis:                                       1.00E-01
                        eps_eigval:                                     1.00E-05
                        --------------------------------------------------------
                        level_shift [a.u.]:                                 0.00
                        added MOs                                       200    0
                        --------------------------------------------------------
                        Mixing method:                            BROYDEN_MIXING
                                                charge density mixing in g-space
                        --------------------------------------------------------
                        Smear method:                                FERMI_DIRAC
                        Electronic temperature [K]:                       2300.0
                        Electronic temperature [a.u.]:                  7.28E-03
                        Accuracy threshold:                             1.00E-10
                        --------------------------------------------------------
                        No outer SCF

 LD| Gamma [1/fs]                                                      1.000E-02
 LD| Noisy Gamma [1/fs]                                                0.000E+00
 LD| Shadow Gamma [1/fs]                                               0.000E+00
 LD| Variance [a.u.]                                                   1.267E-04
 MD_PAR| Molecular dynamics protocol (MD input parameters)
 MD_PAR| Ensemble type                                                  LANGEVIN
 MD_PAR| Number of time steps                                                500
 MD_PAR| Time step [fs]                                                 2.000000
 MD_PAR| Temperature [K]                                             1000.000000
 MD_PAR| Temperature tolerance [K]                                      0.000000
 MD_PAR| Constraints activated
 MD_PAR| Tolerance for shake                                            0.000001
 MD_PAR| Print MD information every                                    1 step(s)
 MD_PAR| File type   Print frequency [steps]                          File names
 MD_PAR| Coordinates         10                        AU_AIMD-MD.TRAJ-pos-1.xyz
 MD_PAR| Velocities           1                                AU_AIMD-vel-1.xyz
 MD_PAR| Energies             1                                   AU_AIMD-1.ener
 MD_PAR| Dump                10                        AU_AIMD-MD.REST-1.restart

 ROT| Rotational analysis information
 ROT| Principal axes and moments of inertia [a.u.]
 ROT|                           1                   2                   3
 ROT| Eigenvalues      6.20956934969E+09   6.77537225536E+09   1.00513916080E+10
 ROT|      x              0.864931356977     -0.486274641819     -0.124220450980
 ROT|      y             -0.491816640896     -0.870539911269     -0.016632937947
 ROT|      z              0.100050684431     -0.075480034521      0.992115227649
 ROT| Number of rotovibrational vectors                                        6

 DOF| Calculation of degrees of freedom
 DOF| Number of atoms                                                        152
 DOF| Number of intramolecular constraints                                   216
 DOF| Number of intermolecular constraints                                     0
 DOF| Invariants (translations + rotations)                                    3
 DOF| Degrees of freedom                                                     237

 DOF| Restraints information
 DOF| Number of intramolecular restraints                                      0
 DOF| Number of intermolecular restraints                                      0

 *** WARNING in motion/thermostat/thermostat_methods.F:276 :: Thermostat ***
 *** for Particles has been defined but the ensemble provided does not   ***
 *** support thermostat for Particles! Ignoring thermostat input.        ***


 MD_VEL| Velocities initialization
 MD_VEL| Initial temperature [K]                                      940.289648
 MD_VEL| COM velocity            -0.0000056078     0.0000011335     0.0000195267

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                816
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: initial_guess


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 NoMix/Diag. 0.40E+00    6.6     0.65230795     -4913.1661660409 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.7     1.47729135     -5000.0433416897 -8.69E+01
     3 Broy./Diag. 0.40E+00    6.9     1.45242132     -4955.1225739023  4.49E+01
     4 Broy./Diag. 0.40E+00    9.3     0.33826126     -4915.7894255753  3.93E+01
     5 Broy./Diag. 0.40E+00    7.0     0.14744662     -4912.7434858952  3.05E+00
     6 Broy./Diag. 0.40E+00    7.6     0.19626900     -4912.4810169719  2.62E-01
     7 Broy./Diag. 0.40E+00   11.0     0.17301972     -4912.3396866294  1.41E-01
     8 Broy./Diag. 0.40E+00    7.3     0.24810835     -4912.2705249953  6.92E-02
     9 Broy./Diag. 0.40E+00    6.9     0.14142233     -4911.2677747074  1.00E+00
    10 Broy./Diag. 0.40E+00    7.1     0.04121884     -4911.4406954484 -1.73E-01
    11 Broy./Diag. 0.40E+00    7.5     0.02784593     -4911.7109398219 -2.70E-01
    12 Broy./Diag. 0.40E+00    7.2     0.01948756     -4911.6515425209  5.94E-02
    13 Broy./Diag. 0.40E+00    7.1     0.01695327     -4911.5749388931  7.66E-02
    14 Broy./Diag. 0.40E+00    7.2     0.02070283     -4911.6411761894 -6.62E-02
    15 Broy./Diag. 0.40E+00    7.4     0.02796539     -4911.6373244089  3.85E-03
    16 Broy./Diag. 0.40E+00    6.8     0.01809052     -4911.5003891241  1.37E-01
    17 Broy./Diag. 0.40E+00    7.3     0.01182993     -4911.5306984250 -3.03E-02
    18 Broy./Diag. 0.40E+00    6.9     0.01274657     -4911.5641757892 -3.35E-02
    19 Broy./Diag. 0.40E+00    7.1     0.00676378     -4911.5585097671  5.67E-03
    20 Broy./Diag. 0.40E+00    7.0     0.00475085     -4911.5151818439  4.33E-02
    21 Broy./Diag. 0.40E+00    6.9     0.00902174     -4911.5197318349 -4.55E-03
    22 Broy./Diag. 0.40E+00    6.6     0.00827016     -4911.5542748641 -3.45E-02
    23 Broy./Diag. 0.40E+00    7.3     0.00279379     -4911.5251870348  2.91E-02
    24 Broy./Diag. 0.40E+00    7.3     0.00287097     -4911.5148988012  1.03E-02
    25 Broy./Diag. 0.40E+00    7.2     0.00194561     -4911.5204412050 -5.54E-03
    26 Broy./Diag. 0.40E+00    6.8     0.00177376     -4911.5280612116 -7.62E-03
    27 Broy./Diag. 0.40E+00    6.8     0.00146338     -4911.5250495531  3.01E-03
    28 Broy./Diag. 0.40E+00    7.1     0.00250643     -4911.5174230369  7.63E-03
    29 Broy./Diag. 0.40E+00    6.8     0.00207158     -4911.5267982896 -9.38E-03
    30 Broy./Diag. 0.40E+00    7.2     0.00126762     -4911.5245340318  2.26E-03
    31 Broy./Diag. 0.40E+00    6.6     0.00084379     -4911.5198137241  4.72E-03
    32 Broy./Diag. 0.40E+00    7.4     0.00058549     -4911.5175016766  2.31E-03
    33 Broy./Diag. 0.40E+00    7.5     0.00060589     -4911.5186748088 -1.17E-03
    34 Broy./Diag. 0.40E+00    6.5     0.00051602     -4911.5210827645 -2.41E-03
    35 Broy./Diag. 0.40E+00    7.1     0.00062978     -4911.5177699644  3.31E-03
    36 Broy./Diag. 0.40E+00    7.3     0.00057528     -4911.5186208880 -8.51E-04
    37 Broy./Diag. 0.40E+00    7.1     0.00049787     -4911.5201238777 -1.50E-03
    38 Broy./Diag. 0.40E+00    6.8     0.00031073     -4911.5192394960  8.84E-04
    39 Broy./Diag. 0.40E+00    6.9     0.00047924     -4911.5179739399  1.27E-03
    40 Broy./Diag. 0.40E+00    6.9     0.00038566     -4911.5164839636  1.49E-03
    41 Broy./Diag. 0.40E+00    6.6     0.00034259     -4911.5183780013 -1.89E-03
    42 Broy./Diag. 0.40E+00    7.3     0.00025631     -4911.5178485831  5.29E-04
    43 Broy./Diag. 0.40E+00    7.2     0.00018673     -4911.5170454721  8.03E-04
    44 Broy./Diag. 0.40E+00    6.9     0.00010070     -4911.5173177112 -2.72E-04
    45 Broy./Diag. 0.40E+00    7.4     0.00019210     -4911.5174232023 -1.05E-04
    46 Broy./Diag. 0.40E+00    7.5     0.00019057     -4911.5179543406 -5.31E-04
    47 Broy./Diag. 0.40E+00    7.2     0.00019486     -4911.5168079332  1.15E-03
    48 Broy./Diag. 0.40E+00    6.8     0.00017746     -4911.5171090342 -3.01E-04
    49 Broy./Diag. 0.40E+00    7.3     0.00016107     -4911.5174821458 -3.73E-04
    50 Broy./Diag. 0.40E+00    7.3     0.00007685     -4911.5170844652  3.98E-04
    51 Broy./Diag. 0.40E+00    7.2     0.00006602     -4911.5169734768  1.11E-04
    52 Broy./Diag. 0.40E+00    7.1     0.00008631     -4911.5167968623  1.77E-04
    53 Broy./Diag. 0.40E+00    7.4     0.00006889     -4911.5172540673 -4.57E-04
    54 Broy./Diag. 0.40E+00    7.3     0.00006207     -4911.5169310779  3.23E-04
    55 Broy./Diag. 0.40E+00    7.5     0.00009203     -4911.5167824854  1.49E-04
    56 Broy./Diag. 0.40E+00    7.5     0.00006619     -4911.5170126095 -2.30E-04
    57 Broy./Diag. 0.40E+00    6.7     0.00004904     -4911.5169411565  7.15E-05
    58 Broy./Diag. 0.40E+00    7.3     0.00006606     -4911.5169194031  2.18E-05
    59 Broy./Diag. 0.40E+00    7.2     0.00005168     -4911.5166316708  2.88E-04
    60 Broy./Diag. 0.40E+00    7.8     0.00002837     -4911.5168028839 -1.71E-04
    61 Broy./Diag. 0.40E+00    7.0     0.00002994     -4911.5168327919 -2.99E-05
    62 Broy./Diag. 0.40E+00    7.3     0.00002356     -4911.5167213292  1.11E-04
    63 Broy./Diag. 0.40E+00    6.9     0.00001629     -4911.5167419045 -2.06E-05
    64 Broy./Diag. 0.40E+00    7.3     0.00003665     -4911.5167326622  9.24E-06
    65 Broy./Diag. 0.40E+00    6.8     0.00003990     -4911.5168581667 -1.26E-04
    66 Broy./Diag. 0.40E+00    7.2     0.00002248     -4911.5166793565  1.79E-04
    67 Broy./Diag. 0.40E+00    7.4     0.00002687     -4911.5166532808  2.61E-05
    68 Broy./Diag. 0.40E+00    6.7     0.00001911     -4911.5167328751 -7.96E-05
    69 Broy./Diag. 0.40E+00    7.1     0.00000980     -4911.5166960364  3.68E-05
    70 Broy./Diag. 0.40E+00    7.2     0.00000918     -4911.5166950663  9.70E-07
    71 Broy./Diag. 0.40E+00    7.0     0.00001458     -4911.5166557547  3.93E-05
    72 Broy./Diag. 0.40E+00    7.0     0.00001078     -4911.5167136338 -5.79E-05
    73 Broy./Diag. 0.40E+00    7.5     0.00001226     -4911.5166984901  1.51E-05
    74 Broy./Diag. 0.40E+00    7.2     0.00001279     -4911.5166465622  5.19E-05
    75 Broy./Diag. 0.40E+00    7.0     0.00000935     -4911.5166680842 -2.15E-05
    76 Broy./Diag. 0.40E+00    7.4     0.00000889     -4911.5166620633  6.02E-06
    77 Broy./Diag. 0.40E+00    6.8     0.00000989     -4911.5166787506 -1.67E-05
    78 Broy./Diag. 0.40E+00    7.1     0.00000604     -4911.5166411202  3.76E-05
    79 Broy./Diag. 0.40E+00    7.2     0.00000485     -4911.5166441834 -3.06E-06
    80 Broy./Diag. 0.40E+00    7.0     0.00000385     -4911.5166586445 -1.45E-05
    81 Broy./Diag. 0.40E+00    7.4     0.00000360     -4911.5166445695  1.41E-05
    82 Broy./Diag. 0.40E+00    7.1     0.00000395     -4911.5166469221 -2.35E-06
    83 Broy./Diag. 0.40E+00    6.6     0.00000670     -4911.5166367019  1.02E-05
    84 Broy./Diag. 0.40E+00    7.2     0.00000600     -4911.5166568527 -2.02E-05
    85 Broy./Diag. 0.40E+00    7.0     0.00000461     -4911.5166445097  1.23E-05
    86 Broy./Diag. 0.40E+00    7.3     0.00000352     -4911.5166303709  1.41E-05
    87 Broy./Diag. 0.40E+00    6.9     0.00000191     -4911.5166399077 -9.54E-06
    88 Broy./Diag. 0.40E+00    6.7     0.00000179     -4911.5166351423  4.77E-06
    89 Broy./Diag. 0.40E+00    6.8     0.00000175     -4911.5166387830 -3.64E-06
    90 Broy./Diag. 0.40E+00    7.1     0.00000207     -4911.5166321284  6.65E-06
    91 Broy./Diag. 0.40E+00    7.8     0.00000234     -4911.5166347789 -2.65E-06
    92 Broy./Diag. 0.40E+00    7.1     0.00000233     -4911.5166392513 -4.47E-06
    93 Broy./Diag. 0.40E+00    7.0     0.00000157     -4911.5166300422  9.21E-06
    94 Broy./Diag. 0.40E+00    7.1     0.00000174     -4911.5166331388 -3.10E-06
    95 Broy./Diag. 0.40E+00    6.5     0.00000164     -4911.5166293868  3.75E-06
    96 Broy./Diag. 0.40E+00    7.3     0.00000130     -4911.5166328949 -3.51E-06
    97 Broy./Diag. 0.40E+00    7.2     0.00000087     -4911.5166306201  2.27E-06

  *** SCF run converged in    97 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008365545306
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.97451087724130
  Hartree energy:                                            1781.42550698522632
  Exchange-correlation energy:                               -779.58813398672510
  Electronic entropic energy:                                  -0.23817563166122
  Fermi energy:                                                 0.08716583820109

  Total energy:                                             -4911.51663062014086

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.516625460269097

 MD_INI| MD initialization
 MD_INI| Potential energy [hartree]                          -0.491151662546E+04
 MD_INI| Kinetic energy [hartree]                             0.358260140059E+00
 MD_INI| Temperature [K]                                              954.679068
 MD_INI| Cell volume [bohr^3]                                 3.368836789525E+04
 MD_INI| Cell volume [ang^3]                                  4.992101011065E+03
 MD_INI| Cell lengths [bohr]      3.22968369E+01  3.22968369E+01  3.22968369E+01
 MD_INI| Cell lengths [ang]       1.70907500E+01  1.70907500E+01  1.70907500E+01
 MD_INI| Cell angles [deg]        9.00000000E+01  9.00000000E+01  9.00000000E+01

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.01191731     -4911.5139894172 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.9     0.02563484     -4911.4817137224  3.23E-02
     3 Broy./Diag. 0.40E+00    7.1     0.04166201     -4911.5893751237 -1.08E-01
     4 Broy./Diag. 0.40E+00    6.9     0.02888850     -4911.4543869114  1.35E-01
     5 Broy./Diag. 0.40E+00    6.8     0.00990781     -4911.5201957919 -6.58E-02
     6 Broy./Diag. 0.40E+00    7.3     0.00287433     -4911.5173473609  2.85E-03
     7 Broy./Diag. 0.40E+00    6.8     0.00244322     -4911.5202766197 -2.93E-03
     8 Broy./Diag. 0.40E+00    6.8     0.00172028     -4911.5133447095  6.93E-03
     9 Broy./Diag. 0.40E+00    7.0     0.00090745     -4911.5140350021 -6.90E-04
    10 Broy./Diag. 0.40E+00    6.8     0.00096635     -4911.5197389173 -5.70E-03
    11 Broy./Diag. 0.40E+00    7.0     0.00068262     -4911.5155096127  4.23E-03
    12 Broy./Diag. 0.40E+00    7.0     0.00024264     -4911.5157973590 -2.88E-04
    13 Broy./Diag. 0.40E+00    7.4     0.00018070     -4911.5155979802  1.99E-04
    14 Broy./Diag. 0.40E+00    7.2     0.00017850     -4911.5159924930 -3.95E-04
    15 Broy./Diag. 0.40E+00    7.0     0.00017611     -4911.5158012239  1.91E-04
    16 Broy./Diag. 0.40E+00    7.2     0.00015534     -4911.5152780088  5.23E-04
    17 Broy./Diag. 0.40E+00    7.2     0.00024445     -4911.5162208873 -9.43E-04
    18 Broy./Diag. 0.40E+00    6.8     0.00015542     -4911.5158665195  3.54E-04
    19 Broy./Diag. 0.40E+00    7.6     0.00006830     -4911.5156415255  2.25E-04
    20 Broy./Diag. 0.40E+00    7.0     0.00006966     -4911.5154553907  1.86E-04
    21 Broy./Diag. 0.40E+00    7.0     0.00008260     -4911.5155616707 -1.06E-04
    22 Broy./Diag. 0.40E+00    7.2     0.00004887     -4911.5157765760 -2.15E-04
    23 Broy./Diag. 0.40E+00    7.4     0.00005874     -4911.5154522348  3.24E-04
    24 Broy./Diag. 0.40E+00    7.0     0.00004905     -4911.5155514435 -9.92E-05
    25 Broy./Diag. 0.40E+00    6.9     0.00002726     -4911.5156057621 -5.43E-05
    26 Broy./Diag. 0.40E+00    7.0     0.00002876     -4911.5156574266 -5.17E-05
    27 Broy./Diag. 0.40E+00    7.2     0.00004798     -4911.5155325277  1.25E-04
    28 Broy./Diag. 0.40E+00    7.1     0.00003683     -4911.5154092850  1.23E-04
    29 Broy./Diag. 0.40E+00    7.5     0.00004594     -4911.5156386368 -2.29E-04
    30 Broy./Diag. 0.40E+00    7.2     0.00003151     -4911.5155340039  1.05E-04
    31 Broy./Diag. 0.40E+00    6.8     0.00001297     -4911.5155122815  2.17E-05
    32 Broy./Diag. 0.40E+00    7.4     0.00001210     -4911.5154764301  3.59E-05
    33 Broy./Diag. 0.40E+00    7.0     0.00001590     -4911.5155171269 -4.07E-05
    34 Broy./Diag. 0.40E+00    6.8     0.00001360     -4911.5155561515 -3.90E-05
    35 Broy./Diag. 0.40E+00    7.5     0.00001799     -4911.5154706899  8.55E-05
    36 Broy./Diag. 0.40E+00    7.3     0.00001937     -4911.5155101447 -3.95E-05
    37 Broy./Diag. 0.40E+00    7.5     0.00000979     -4911.5155133984 -3.25E-06
    38 Broy./Diag. 0.40E+00    7.1     0.00000979     -4911.5155248738 -1.15E-05
    39 Broy./Diag. 0.40E+00    7.4     0.00000969     -4911.5154908628  3.40E-05
    40 Broy./Diag. 0.40E+00    7.2     0.00000852     -4911.5154642694  2.66E-05
    41 Broy./Diag. 0.40E+00    6.8     0.00000836     -4911.5155140430 -4.98E-05
    42 Broy./Diag. 0.40E+00    7.7     0.00000641     -4911.5154939281  2.01E-05
    43 Broy./Diag. 0.40E+00    6.8     0.00000351     -4911.5154910021  2.93E-06
    44 Broy./Diag. 0.40E+00    7.3     0.00000504     -4911.5154837657  7.24E-06
    45 Broy./Diag. 0.40E+00    7.2     0.00000499     -4911.5154992165 -1.55E-05
    46 Broy./Diag. 0.40E+00    7.2     0.00000585     -4911.5155023527 -3.14E-06
    47 Broy./Diag. 0.40E+00    7.1     0.00000643     -4911.5154687226  3.36E-05
    48 Broy./Diag. 0.40E+00    7.1     0.00000546     -4911.5154853729 -1.67E-05
    49 Broy./Diag. 0.40E+00    7.0     0.00000235     -4911.5154850027  3.70E-07
    50 Broy./Diag. 0.40E+00    7.6     0.00000164     -4911.5154885448 -3.54E-06
    51 Broy./Diag. 0.40E+00    6.8     0.00000153     -4911.5154821454  6.40E-06
    52 Broy./Diag. 0.40E+00    6.8     0.00000231     -4911.5154806088  1.54E-06
    53 Broy./Diag. 0.40E+00    7.0     0.00000293     -4911.5154926775 -1.21E-05
    54 Broy./Diag. 0.40E+00    6.9     0.00000284     -4911.5154823158  1.04E-05
    55 Broy./Diag. 0.40E+00    6.9     0.00000163     -4911.5154819055  4.10E-07
    56 Broy./Diag. 0.40E+00    7.4     0.00000123     -4911.5154791124  2.79E-06
    57 Broy./Diag. 0.40E+00    7.0     0.00000124     -4911.5154835550 -4.44E-06
    58 Broy./Diag. 0.40E+00    6.9     0.00000125     -4911.5154845625 -1.01E-06
    59 Broy./Diag. 0.40E+00    6.7     0.00000120     -4911.5154777142  6.85E-06
    60 Broy./Diag. 0.40E+00    6.9     0.00000125     -4911.5154820142 -4.30E-06
    61 Broy./Diag. 0.40E+00    7.5     0.00000071     -4911.5154817525  2.62E-07

  *** SCF run converged in    61 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008365970154
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.96624815548421
  Hartree energy:                                            1781.43086386085065
  Exchange-correlation energy:                               -779.58390977262093
  Electronic entropic energy:                                  -0.23834515146056
  Fermi energy:                                                 0.08714925342378

  Total energy:                                             -4911.51548175249536

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.515479055408832

 MD| ***************************************************************************
 MD| Step number                                                            1101
 MD| Time [fs]                                                       2202.000000
 MD| Conserved quantity [hartree]                            -0.491116297385E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                   1143.300395           604.287848
 MD| Energy drift per atom [K]           0.325158135787E+03   0.269025278883E+03
 MD| Potential energy [hartree]         -0.491151547906E+04  -0.491156607915E+04
 MD| Kinetic energy [hartree]            0.352505200851E+00   0.376079979942E+00
 MD| Temperature [K]                             939.343508          1002.164753
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.01517236     -4911.5147499180 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.8     0.05306561     -4911.4408859320  7.39E-02
     3 Broy./Diag. 0.40E+00    7.4     0.06420034     -4911.7169687023 -2.76E-01
     4 Broy./Diag. 0.40E+00    7.2     0.02606210     -4911.4134772585  3.03E-01
     5 Broy./Diag. 0.40E+00    7.4     0.00579208     -4911.5035576070 -9.01E-02
     6 Broy./Diag. 0.40E+00    7.2     0.00399882     -4911.5408616838 -3.73E-02
     7 Broy./Diag. 0.40E+00    6.8     0.00332543     -4911.5166383718  2.42E-02
     8 Broy./Diag. 0.40E+00    7.0     0.00303904     -4911.5088903512  7.75E-03
     9 Broy./Diag. 0.40E+00    7.2     0.00098734     -4911.5172850444 -8.39E-03
    10 Broy./Diag. 0.40E+00    7.0     0.00041458     -4911.5159910100  1.29E-03
    11 Broy./Diag. 0.40E+00    6.7     0.00032353     -4911.5170308549 -1.04E-03
    12 Broy./Diag. 0.40E+00    7.4     0.00014143     -4911.5152608259  1.77E-03
    13 Broy./Diag. 0.40E+00    6.6     0.00012368     -4911.5166385533 -1.38E-03
    14 Broy./Diag. 0.40E+00    7.2     0.00017642     -4911.5160398503  5.99E-04
    15 Broy./Diag. 0.40E+00    6.9     0.00018527     -4911.5156199138  4.20E-04
    16 Broy./Diag. 0.40E+00    7.7     0.00010889     -4911.5161910608 -5.71E-04
    17 Broy./Diag. 0.40E+00    7.2     0.00009682     -4911.5160548385  1.36E-04
    18 Broy./Diag. 0.40E+00    7.3     0.00007715     -4911.5164437449 -3.89E-04
    19 Broy./Diag. 0.40E+00    7.0     0.00005727     -4911.5158079982  6.36E-04
    20 Broy./Diag. 0.40E+00    7.0     0.00006607     -4911.5161161287 -3.08E-04
    21 Broy./Diag. 0.40E+00    7.4     0.00008180     -4911.5161850406 -6.89E-05
    22 Broy./Diag. 0.40E+00    6.9     0.00005775     -4911.5159244621  2.61E-04
    23 Broy./Diag. 0.40E+00    7.2     0.00003062     -4911.5160191398 -9.47E-05
    24 Broy./Diag. 0.40E+00    7.8     0.00003322     -4911.5159334849  8.57E-05
    25 Broy./Diag. 0.40E+00    7.4     0.00002007     -4911.5161937126 -2.60E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00002886     -4911.5160039824  1.90E-04
    27 Broy./Diag. 0.40E+00    7.2     0.00003986     -4911.5159751127  2.89E-05
    28 Broy./Diag. 0.40E+00    7.2     0.00003259     -4911.5161029537 -1.28E-04
    29 Broy./Diag. 0.40E+00    7.6     0.00001898     -4911.5160333483  6.96E-05
    30 Broy./Diag. 0.40E+00    7.2     0.00001885     -4911.5160775391 -4.42E-05
    31 Broy./Diag. 0.40E+00    7.7     0.00001030     -4911.5159483161  1.29E-04
    32 Broy./Diag. 0.40E+00    7.1     0.00001411     -4911.5160473517 -9.90E-05
    33 Broy./Diag. 0.40E+00    7.0     0.00001934     -4911.5160541315 -6.78E-06
    34 Broy./Diag. 0.40E+00    7.0     0.00001667     -4911.5159876364  6.65E-05
    35 Broy./Diag. 0.40E+00    7.0     0.00001058     -4911.5160235603 -3.59E-05
    36 Broy./Diag. 0.40E+00    7.2     0.00001215     -4911.5160001719  2.34E-05
    37 Broy./Diag. 0.40E+00    7.0     0.00000682     -4911.5160701179 -6.99E-05
    38 Broy./Diag. 0.40E+00    7.1     0.00000952     -4911.5160004373  6.97E-05
    39 Broy./Diag. 0.40E+00    7.6     0.00001149     -4911.5159939899  6.45E-06
    40 Broy./Diag. 0.40E+00    6.9     0.00000940     -4911.5160312555 -3.73E-05
    41 Broy./Diag. 0.40E+00    8.3     0.00000624     -4911.5160099706  2.13E-05
    42 Broy./Diag. 0.40E+00    6.9     0.00000627     -4911.5160248737 -1.49E-05
    43 Broy./Diag. 0.40E+00    6.9     0.00000357     -4911.5159939493  3.09E-05
    44 Broy./Diag. 0.40E+00    7.3     0.00000431     -4911.5160269000 -3.30E-05
    45 Broy./Diag. 0.40E+00    7.0     0.00000622     -4911.5160240812  2.82E-06
    46 Broy./Diag. 0.40E+00    6.6     0.00000542     -4911.5160030533  2.10E-05
    47 Broy./Diag. 0.40E+00    7.3     0.00000356     -4911.5160156566 -1.26E-05
    48 Broy./Diag. 0.40E+00    7.5     0.00000390     -4911.5160070375  8.62E-06
    49 Broy./Diag. 0.40E+00    7.2     0.00000193     -4911.5160246989 -1.77E-05
    50 Broy./Diag. 0.40E+00    7.2     0.00000235     -4911.5160059386  1.88E-05
    51 Broy./Diag. 0.40E+00    6.9     0.00000334     -4911.5160073830 -1.44E-06
    52 Broy./Diag. 0.40E+00    6.9     0.00000304     -4911.5160177729 -1.04E-05
    53 Broy./Diag. 0.40E+00    6.9     0.00000203     -4911.5160103815  7.39E-06
    54 Broy./Diag. 0.40E+00    7.0     0.00000217     -4911.5160147725 -4.39E-06
    55 Broy./Diag. 0.40E+00    7.2     0.00000126     -4911.5160053378  9.43E-06
    56 Broy./Diag. 0.40E+00    7.2     0.00000118     -4911.5160160396 -1.07E-05
    57 Broy./Diag. 0.40E+00    6.9     0.00000214     -4911.5160132351  2.80E-06
    58 Broy./Diag. 0.40E+00    7.6     0.00000200     -4911.5160067549  6.48E-06
    59 Broy./Diag. 0.40E+00    7.2     0.00000115     -4911.5160118223 -5.07E-06
    60 Broy./Diag. 0.40E+00    7.4     0.00000126     -4911.5160092650  2.56E-06
    61 Broy./Diag. 0.40E+00    7.0     0.00000090     -4911.5160146963 -5.43E-06

  *** SCF run converged in    61 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008357780592
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.95423931952064
  Hartree energy:                                            1781.43735361569907
  Exchange-correlation energy:                               -779.57884440095336
  Electronic entropic energy:                                  -0.23842426584913
  Fermi energy:                                                 0.08712718144287

  Total energy:                                             -4911.51601469630623

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.516010425327295

 MD| ***************************************************************************
 MD| Step number                                                            1102
 MD| Time [fs]                                                       2204.000000
 MD| Conserved quantity [hartree]                            -0.491117241633E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    444.254899           604.142627
 MD| Energy drift per atom [K]           0.305541715488E+03   0.269058415395E+03
 MD| Potential energy [hartree]         -0.491151601043E+04  -0.491156603372E+04
 MD| Kinetic energy [hartree]            0.343594090491E+00   0.376050500914E+00
 MD| Temperature [K]                             915.597493          1002.086198
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02572518     -4911.5161029788 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.0     0.09917889     -4911.4236091711  9.25E-02
     3 Broy./Diag. 0.40E+00    7.3     0.10346494     -4911.7668903063 -3.43E-01
     4 Broy./Diag. 0.40E+00    7.4     0.03038744     -4911.4388692015  3.28E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01210776     -4911.4908432363 -5.20E-02
     6 Broy./Diag. 0.40E+00    7.4     0.01218003     -4911.5460741915 -5.52E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00676682     -4911.5160325418  3.00E-02
     8 Broy./Diag. 0.40E+00    7.4     0.00211729     -4911.5185190648 -2.49E-03
     9 Broy./Diag. 0.40E+00    7.1     0.00081223     -4911.5128089392  5.71E-03
    10 Broy./Diag. 0.40E+00    7.8     0.00051485     -4911.5202346345 -7.43E-03
    11 Broy./Diag. 0.40E+00    7.5     0.00043113     -4911.5182789336  1.96E-03
    12 Broy./Diag. 0.40E+00    9.4     0.00031220     -4911.5164382022  1.84E-03
    13 Broy./Diag. 0.40E+00    7.4     0.00039909     -4911.5180630017 -1.62E-03
    14 Broy./Diag. 0.40E+00    9.1     0.00024764     -4911.5173669872  6.96E-04
    15 Broy./Diag. 0.40E+00    9.5     0.00017677     -4911.5175863488 -2.19E-04
    16 Broy./Diag. 0.40E+00    6.6     0.00011523     -4911.5170574934  5.29E-04
    17 Broy./Diag. 0.40E+00    7.2     0.00012655     -4911.5177968956 -7.39E-04
    18 Broy./Diag. 0.40E+00    6.9     0.00011603     -4911.5180053241 -2.08E-04
    19 Broy./Diag. 0.40E+00    6.8     0.00017462     -4911.5170877011  9.18E-04
    20 Broy./Diag. 0.40E+00    7.5     0.00014199     -4911.5175679821 -4.80E-04
    21 Broy./Diag. 0.40E+00    7.5     0.00008182     -4911.5174666472  1.01E-04
    22 Broy./Diag. 0.40E+00    8.4     0.00004923     -4911.5177016749 -2.35E-04
    23 Broy./Diag. 0.40E+00    9.1     0.00004425     -4911.5174325354  2.69E-04
    24 Broy./Diag. 0.40E+00    7.5     0.00004397     -4911.5174208365  1.17E-05
    25 Broy./Diag. 0.40E+00   10.0     0.00008702     -4911.5177850840 -3.64E-04
    26 Broy./Diag. 0.40E+00    7.9     0.00007745     -4911.5175234380  2.62E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00005019     -4911.5175830424 -5.96E-05
    28 Broy./Diag. 0.40E+00    7.1     0.00003512     -4911.5174371504  1.46E-04
    29 Broy./Diag. 0.40E+00    8.1     0.00003481     -4911.5176093537 -1.72E-04
    30 Broy./Diag. 0.40E+00    7.1     0.00002273     -4911.5176419947 -3.26E-05
    31 Broy./Diag. 0.40E+00    8.5     0.00003921     -4911.5174654479  1.77E-04
    32 Broy./Diag. 0.40E+00    9.0     0.00003600     -4911.5175889333 -1.23E-04
    33 Broy./Diag. 0.40E+00    7.2     0.00001876     -4911.5175578395  3.11E-05
    34 Broy./Diag. 0.40E+00   11.5     0.00001907     -4911.5176191297 -6.13E-05
    35 Broy./Diag. 0.40E+00    7.4     0.00002300     -4911.5175399134  7.92E-05
    36 Broy./Diag. 0.40E+00    7.3     0.00001658     -4911.5175202411  1.97E-05
    37 Broy./Diag. 0.40E+00    7.3     0.00002996     -4911.5176323444 -1.12E-04
    38 Broy./Diag. 0.40E+00    6.8     0.00002703     -4911.5175432488  8.91E-05
    39 Broy./Diag. 0.40E+00    7.2     0.00001157     -4911.5175749332 -3.17E-05
    40 Broy./Diag. 0.40E+00    6.9     0.00001208     -4911.5175310974  4.38E-05
    41 Broy./Diag. 0.40E+00    7.5     0.00001238     -4911.5175755326 -4.44E-05
    42 Broy./Diag. 0.40E+00    7.3     0.00000825     -4911.5175930378 -1.75E-05
    43 Broy./Diag. 0.40E+00    7.7     0.00001369     -4911.5175457458  4.73E-05
    44 Broy./Diag. 0.40E+00    6.7     0.00001643     -4911.5175859383 -4.02E-05
    45 Broy./Diag. 0.40E+00    6.9     0.00000761     -4911.5175666485  1.93E-05
    46 Broy./Diag. 0.40E+00    7.2     0.00000833     -4911.5175936763 -2.70E-05
    47 Broy./Diag. 0.40E+00    7.6     0.00000824     -4911.5175652642  2.84E-05
    48 Broy./Diag. 0.40E+00    7.1     0.00000523     -4911.5175561903  9.07E-06
    49 Broy./Diag. 0.40E+00    7.5     0.00000704     -4911.5175877306 -3.15E-05
    50 Broy./Diag. 0.40E+00    7.3     0.00000799     -4911.5175677563  2.00E-05
    51 Broy./Diag. 0.40E+00    7.2     0.00000410     -4911.5175777644 -1.00E-05
    52 Broy./Diag. 0.40E+00    7.2     0.00000460     -4911.5175634010  1.44E-05
    53 Broy./Diag. 0.40E+00    7.1     0.00000479     -4911.5175798803 -1.65E-05
    54 Broy./Diag. 0.40E+00    7.4     0.00000370     -4911.5175847959 -4.92E-06
    55 Broy./Diag. 0.40E+00    6.6     0.00000420     -4911.5175646618  2.01E-05
    56 Broy./Diag. 0.40E+00    7.1     0.00000573     -4911.5175783552 -1.37E-05
    57 Broy./Diag. 0.40E+00    7.1     0.00000305     -4911.5175715077  6.85E-06
    58 Broy./Diag. 0.40E+00    7.1     0.00000274     -4911.5175814071 -9.90E-06
    59 Broy./Diag. 0.40E+00    7.8     0.00000249     -4911.5175716286  9.78E-06
    60 Broy./Diag. 0.40E+00    7.1     0.00000210     -4911.5175711556  4.73E-07
    61 Broy./Diag. 0.40E+00    7.3     0.00000222     -4911.5175822850 -1.11E-05
    62 Broy./Diag. 0.40E+00    7.3     0.00000307     -4911.5175747855  7.50E-06
    63 Broy./Diag. 0.40E+00    7.3     0.00000201     -4911.5175782064 -3.42E-06
    64 Broy./Diag. 0.40E+00    7.2     0.00000167     -4911.5175719844  6.22E-06
    65 Broy./Diag. 0.40E+00    7.0     0.00000161     -4911.5175790129 -7.03E-06
    66 Broy./Diag. 0.40E+00    7.2     0.00000133     -4911.5175794612 -4.48E-07
    67 Broy./Diag. 0.40E+00    6.6     0.00000116     -4911.5175732400  6.22E-06
    68 Broy./Diag. 0.40E+00    7.1     0.00000179     -4911.5175778325 -4.59E-06
    69 Broy./Diag. 0.40E+00    7.1     0.00000120     -4911.5175759681  1.86E-06
    70 Broy./Diag. 0.40E+00    7.3     0.00000090     -4911.5175792589 -3.29E-06

  *** SCF run converged in    70 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008349808668
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.93744060259860
  Hartree energy:                                            1781.44636633943037
  Exchange-correlation energy:                               -779.57260788722442
  Electronic entropic energy:                                  -0.23843927860372
  Fermi energy:                                                 0.08709565461870

  Total energy:                                             -4911.51757925888614

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.517578133070856

 MD| ***************************************************************************
 MD| Step number                                                            1103
 MD| Time [fs]                                                       2206.000000
 MD| Conserved quantity [hartree]                            -0.491118055830E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    532.559353           604.077729
 MD| Energy drift per atom [K]           0.288627079598E+03   0.269076156705E+03
 MD| Potential energy [hartree]         -0.491151757813E+04  -0.491156598979E+04
 MD| Kinetic energy [hartree]            0.337019837908E+00   0.376015115000E+00
 MD| Temperature [K]                             898.078655          1001.991903
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.03292020     -4911.5179003680 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.9     0.12365928     -4911.4150171811  1.03E-01
     3 Broy./Diag. 0.40E+00    7.0     0.12885167     -4911.7604948069 -3.45E-01
     4 Broy./Diag. 0.40E+00    7.5     0.03849058     -4911.4380719940  3.22E-01
     5 Broy./Diag. 0.40E+00    7.0     0.01827051     -4911.4876420267 -4.96E-02
     6 Broy./Diag. 0.40E+00    7.1     0.01522495     -4911.5432389973 -5.56E-02
     7 Broy./Diag. 0.40E+00    6.8     0.00721117     -4911.5128464938  3.04E-02
     8 Broy./Diag. 0.40E+00    7.0     0.00185199     -4911.5242938129 -1.14E-02
     9 Broy./Diag. 0.40E+00    7.0     0.00113813     -4911.5132162293  1.11E-02
    10 Broy./Diag. 0.40E+00    6.8     0.00075093     -4911.5232735934 -1.01E-02
    11 Broy./Diag. 0.40E+00    7.5     0.00058498     -4911.5204160053  2.86E-03
    12 Broy./Diag. 0.40E+00    7.3     0.00048442     -4911.5186745171  1.74E-03
    13 Broy./Diag. 0.40E+00    6.8     0.00052801     -4911.5203138069 -1.64E-03
    14 Broy./Diag. 0.40E+00    7.2     0.00026677     -4911.5194616843  8.52E-04
    15 Broy./Diag. 0.40E+00    6.6     0.00025054     -4911.5200150353 -5.53E-04
    16 Broy./Diag. 0.40E+00    7.4     0.00018447     -4911.5189666867  1.05E-03
    17 Broy./Diag. 0.40E+00    7.0     0.00018605     -4911.5200835481 -1.12E-03
    18 Broy./Diag. 0.40E+00    7.1     0.00019740     -4911.5201973079 -1.14E-04
    19 Broy./Diag. 0.40E+00    6.9     0.00027518     -4911.5191594346  1.04E-03
    20 Broy./Diag. 0.40E+00    7.2     0.00017545     -4911.5197619661 -6.03E-04
    21 Broy./Diag. 0.40E+00    7.2     0.00011650     -4911.5194921364  2.70E-04
    22 Broy./Diag. 0.40E+00    7.3     0.00006303     -4911.5199756530 -4.84E-04
    23 Broy./Diag. 0.40E+00    7.5     0.00004430     -4911.5196278581  3.48E-04
    24 Broy./Diag. 0.40E+00    7.2     0.00005577     -4911.5196184291  9.43E-06
    25 Broy./Diag. 0.40E+00    6.8     0.00011816     -4911.5199451594 -3.27E-04
    26 Broy./Diag. 0.40E+00    7.0     0.00009351     -4911.5196840603  2.61E-04
    27 Broy./Diag. 0.40E+00    6.8     0.00007146     -4911.5198058885 -1.22E-04
    28 Broy./Diag. 0.40E+00    7.1     0.00004984     -4911.5195091396  2.97E-04
    29 Broy./Diag. 0.40E+00    7.0     0.00003637     -4911.5197838346 -2.75E-04
    30 Broy./Diag. 0.40E+00    7.1     0.00002873     -4911.5198338518 -5.00E-05
    31 Broy./Diag. 0.40E+00    7.1     0.00005311     -4911.5196520099  1.82E-04
    32 Broy./Diag. 0.40E+00    7.1     0.00004075     -4911.5197678172 -1.16E-04
    33 Broy./Diag. 0.40E+00    7.1     0.00002194     -4911.5197117301  5.61E-05
    34 Broy./Diag. 0.40E+00    7.4     0.00002123     -4911.5198181065 -1.06E-04
    35 Broy./Diag. 0.40E+00    7.2     0.00002056     -4911.5197113459  1.07E-04
    36 Broy./Diag. 0.40E+00    7.9     0.00002179     -4911.5196800429  3.13E-05
    37 Broy./Diag. 0.40E+00    7.0     0.00004262     -4911.5198003813 -1.20E-04
    38 Broy./Diag. 0.40E+00    7.2     0.00003672     -4911.5197172039  8.32E-05
    39 Broy./Diag. 0.40E+00    7.2     0.00001537     -4911.5197722244 -5.50E-05
    40 Broy./Diag. 0.40E+00    6.8     0.00001451     -4911.5196869998  8.52E-05
    41 Broy./Diag. 0.40E+00    7.7     0.00001046     -4911.5197496856 -6.27E-05
    42 Broy./Diag. 0.40E+00    7.3     0.00000924     -4911.5197725566 -2.29E-05
    43 Broy./Diag. 0.40E+00    6.8     0.00001566     -4911.5197272438  4.53E-05
    44 Broy./Diag. 0.40E+00    7.0     0.00001926     -4911.5197560482 -2.88E-05
    45 Broy./Diag. 0.40E+00    7.1     0.00000827     -4911.5197279887  2.81E-05
    46 Broy./Diag. 0.40E+00    7.3     0.00001080     -4911.5197805232 -5.25E-05
    47 Broy./Diag. 0.40E+00    7.7     0.00000879     -4911.5197374568  4.31E-05
    48 Broy./Diag. 0.40E+00    7.1     0.00000721     -4911.5197225631  1.49E-05
    49 Broy./Diag. 0.40E+00    7.3     0.00000883     -4911.5197600933 -3.75E-05
    50 Broy./Diag. 0.40E+00    7.4     0.00000885     -4911.5197450526  1.50E-05
    51 Broy./Diag. 0.40E+00    7.1     0.00000386     -4911.5197578924 -1.28E-05
    52 Broy./Diag. 0.40E+00    6.9     0.00000494     -4911.5197339510  2.39E-05
    53 Broy./Diag. 0.40E+00    6.8     0.00000450     -4911.5197545546 -2.06E-05
    54 Broy./Diag. 0.40E+00    6.8     0.00000436     -4911.5197614637 -6.91E-06
    55 Broy./Diag. 0.40E+00    7.1     0.00000584     -4911.5197392048  2.23E-05
    56 Broy./Diag. 0.40E+00    7.7     0.00000712     -4911.5197506599 -1.15E-05
    57 Broy./Diag. 0.40E+00    7.0     0.00000347     -4911.5197408355  9.82E-06
    58 Broy./Diag. 0.40E+00    7.4     0.00000334     -4911.5197602209 -1.94E-05
    59 Broy./Diag. 0.40E+00    6.6     0.00000244     -4911.5197470399  1.32E-05
    60 Broy./Diag. 0.40E+00    7.3     0.00000190     -4911.5197451289  1.91E-06
    61 Broy./Diag. 0.40E+00    6.7     0.00000274     -4911.5197557853 -1.07E-05
    62 Broy./Diag. 0.40E+00    7.3     0.00000326     -4911.5197504068  5.38E-06
    63 Broy./Diag. 0.40E+00    7.5     0.00000203     -4911.5197540587 -3.65E-06
    64 Broy./Diag. 0.40E+00    7.4     0.00000217     -4911.5197430949  1.10E-05
    65 Broy./Diag. 0.40E+00    6.9     0.00000187     -4911.5197534985 -1.04E-05
    66 Broy./Diag. 0.40E+00    7.2     0.00000144     -4911.5197551476 -1.65E-06
    67 Broy./Diag. 0.40E+00    7.3     0.00000168     -4911.5197479504  7.20E-06
    68 Broy./Diag. 0.40E+00    7.6     0.00000197     -4911.5197518352 -3.88E-06
    69 Broy./Diag. 0.40E+00    7.0     0.00000106     -4911.5197496872  2.15E-06
    70 Broy./Diag. 0.40E+00    7.5     0.00000101     -4911.5197546808 -4.99E-06
    71 Broy./Diag. 0.40E+00    7.2     0.00000093     -4911.5197498403  4.84E-06

  *** SCF run converged in    71 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999974       -0.0000000026
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008348012139
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.91925383356829
  Hartree energy:                                            1781.45600369592489
  Exchange-correlation energy:                               -779.56620378603907
  Electronic entropic energy:                                  -0.23846455204985
  Fermi energy:                                                 0.08706002569458

  Total energy:                                             -4911.51974984028402

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.519752736273404

 MD| ***************************************************************************
 MD| Step number                                                            1104
 MD| Time [fs]                                                       2208.000000
 MD| Conserved quantity [hartree]                            -0.491118612569E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    514.293736           603.996403
 MD| Energy drift per atom [K]           0.277061022813E+03   0.269083389373E+03
 MD| Potential energy [hartree]         -0.491151975274E+04  -0.491156594791E+04
 MD| Kinetic energy [hartree]            0.333627051066E+00   0.375976720014E+00
 MD| Temperature [K]                             889.037676          1001.889590
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.6     0.02906996     -4911.5197163835 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.10223818     -4911.4459428333  7.38E-02
     3 Broy./Diag. 0.40E+00    7.3     0.11633203     -4911.6548000785 -2.09E-01
     4 Broy./Diag. 0.40E+00    7.4     0.04372798     -4911.4581614904  1.97E-01
     5 Broy./Diag. 0.40E+00    7.2     0.02525260     -4911.4832302192 -2.51E-02
     6 Broy./Diag. 0.40E+00    8.0     0.01536761     -4911.5505835493 -6.74E-02
     7 Broy./Diag. 0.40E+00    7.0     0.00540023     -4911.5122761209  3.83E-02
     8 Broy./Diag. 0.40E+00    7.4     0.00229120     -4911.5270704509 -1.48E-02
     9 Broy./Diag. 0.40E+00    7.0     0.00128992     -4911.5170085177  1.01E-02
    10 Broy./Diag. 0.40E+00    6.9     0.00056948     -4911.5256803661 -8.67E-03
    11 Broy./Diag. 0.40E+00    7.2     0.00054092     -4911.5221880061  3.49E-03
    12 Broy./Diag. 0.40E+00    7.3     0.00061703     -4911.5201783620  2.01E-03
    13 Broy./Diag. 0.40E+00    6.9     0.00038011     -4911.5223874217 -2.21E-03
    14 Broy./Diag. 0.40E+00    7.5     0.00021518     -4911.5220693290  3.18E-04
    15 Broy./Diag. 0.40E+00    6.5     0.00023029     -4911.5219611743  1.08E-04
    16 Broy./Diag. 0.40E+00    7.1     0.00020879     -4911.5212030111  7.58E-04
    17 Broy./Diag. 0.40E+00    7.5     0.00008919     -4911.5223264450 -1.12E-03
    18 Broy./Diag. 0.40E+00    7.1     0.00007563     -4911.5217311429  5.95E-04
    19 Broy./Diag. 0.40E+00    6.9     0.00013778     -4911.5217642467 -3.31E-05
    20 Broy./Diag. 0.40E+00    7.3     0.00011674     -4911.5222253864 -4.61E-04
    21 Broy./Diag. 0.40E+00    7.1     0.00005199     -4911.5219516161  2.74E-04
    22 Broy./Diag. 0.40E+00    6.8     0.00006318     -4911.5219425445  9.07E-06
    23 Broy./Diag. 0.40E+00    6.9     0.00004322     -4911.5217614081  1.81E-04
    24 Broy./Diag. 0.40E+00    7.3     0.00002340     -4911.5220593759 -2.98E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00004040     -4911.5219739422  8.54E-05
    26 Broy./Diag. 0.40E+00    7.1     0.00004197     -4911.5218350449  1.39E-04
    27 Broy./Diag. 0.40E+00    7.5     0.00001731     -4911.5219531009 -1.18E-04
    28 Broy./Diag. 0.40E+00    7.3     0.00002046     -4911.5219523695  7.31E-07
    29 Broy./Diag. 0.40E+00    7.3     0.00001559     -4911.5219869507 -3.46E-05
    30 Broy./Diag. 0.40E+00    7.1     0.00000931     -4911.5218885135  9.84E-05
    31 Broy./Diag. 0.40E+00    7.0     0.00001187     -4911.5219356316 -4.71E-05
    32 Broy./Diag. 0.40E+00    7.0     0.00001775     -4911.5219740694 -3.84E-05
    33 Broy./Diag. 0.40E+00    6.9     0.00001032     -4911.5219238771  5.02E-05
    34 Broy./Diag. 0.40E+00    7.0     0.00000936     -4911.5219307101 -6.83E-06
    35 Broy./Diag. 0.40E+00    6.9     0.00000733     -4911.5219205192  1.02E-05
    36 Broy./Diag. 0.40E+00    6.8     0.00000431     -4911.5219619571 -4.14E-05
    37 Broy./Diag. 0.40E+00    7.3     0.00000476     -4911.5219378443  2.41E-05
    38 Broy./Diag. 0.40E+00    7.2     0.00000672     -4911.5219239548  1.39E-05
    39 Broy./Diag. 0.40E+00    7.1     0.00000478     -4911.5219466236 -2.27E-05
    40 Broy./Diag. 0.40E+00    7.1     0.00000418     -4911.5219430595  3.56E-06
    41 Broy./Diag. 0.40E+00    7.1     0.00000401     -4911.5219460067 -2.95E-06
    42 Broy./Diag. 0.40E+00    7.0     0.00000255     -4911.5219267379  1.93E-05
    43 Broy./Diag. 0.40E+00    7.2     0.00000260     -4911.5219429869 -1.62E-05
    44 Broy./Diag. 0.40E+00    6.8     0.00000384     -4911.5219502878 -7.30E-06
    45 Broy./Diag. 0.40E+00    6.8     0.00000270     -4911.5219367785  1.35E-05
    46 Broy./Diag. 0.40E+00    7.4     0.00000214     -4911.5219399198 -3.14E-06
    47 Broy./Diag. 0.40E+00    7.0     0.00000215     -4911.5219389138  1.01E-06
    48 Broy./Diag. 0.40E+00    7.1     0.00000139     -4911.5219483066 -9.39E-06
    49 Broy./Diag. 0.40E+00    7.3     0.00000134     -4911.5219397792  8.53E-06
    50 Broy./Diag. 0.40E+00    7.1     0.00000204     -4911.5219365835  3.20E-06
    51 Broy./Diag. 0.40E+00    6.9     0.00000168     -4911.5219450246 -8.44E-06
    52 Broy./Diag. 0.40E+00    7.7     0.00000112     -4911.5219430945  1.93E-06
    53 Broy./Diag. 0.40E+00    6.7     0.00000127     -4911.5219435016 -4.07E-07
    54 Broy./Diag. 0.40E+00    6.9     0.00000091     -4911.5219383682  5.13E-06

  *** SCF run converged in    54 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008351033950
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.90872110556575
  Hartree energy:                                            1781.46087931821307
  Exchange-correlation energy:                               -779.56264008243556
  Electronic entropic energy:                                  -0.23855973725894
  Fermi energy:                                                 0.08703600152461

  Total energy:                                             -4911.52193836819333

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.521943818393083

 MD| ***************************************************************************
 MD| Step number                                                            1105
 MD| Time [fs]                                                       2210.000000
 MD| Conserved quantity [hartree]                            -0.491118950111E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    393.424081           603.805839
 MD| Energy drift per atom [K]           0.270048702530E+03   0.269084262960E+03
 MD| Potential energy [hartree]         -0.491152194382E+04  -0.491156590808E+04
 MD| Kinetic energy [hartree]            0.332442711218E+00   0.375937322721E+00
 MD| Temperature [K]                             885.881688          1001.784605
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.03164675     -4911.5208022778 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.9     0.08357724     -4911.5118883311  8.91E-03
     3 Broy./Diag. 0.40E+00    7.1     0.11702713     -4911.4383655978  7.35E-02
     4 Broy./Diag. 0.40E+00    8.2     0.07550155     -4911.6020599574 -1.64E-01
     5 Broy./Diag. 0.40E+00    7.3     0.02499073     -4911.4641206008  1.38E-01
     6 Broy./Diag. 0.40E+00    7.6     0.01077450     -4911.5388830333 -7.48E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00781224     -4911.5163778613  2.25E-02
     8 Broy./Diag. 0.40E+00    7.2     0.00291258     -4911.5302623492 -1.39E-02
     9 Broy./Diag. 0.40E+00    6.8     0.00184596     -4911.5194517523  1.08E-02
    10 Broy./Diag. 0.40E+00    7.6     0.00213499     -4911.5280775017 -8.63E-03
    11 Broy./Diag. 0.40E+00    7.1     0.00156392     -4911.5275918343  4.86E-04
    12 Broy./Diag. 0.40E+00    7.6     0.00054739     -4911.5217526533  5.84E-03
    13 Broy./Diag. 0.40E+00    7.1     0.00064608     -4911.5232076114 -1.45E-03
    14 Broy./Diag. 0.40E+00    7.3     0.00045809     -4911.5226383786  5.69E-04
    15 Broy./Diag. 0.40E+00    7.0     0.00022280     -4911.5240611022 -1.42E-03
    16 Broy./Diag. 0.40E+00    7.4     0.00048344     -4911.5225918718  1.47E-03
    17 Broy./Diag. 0.40E+00    7.5     0.00057756     -4911.5228104889 -2.19E-04
    18 Broy./Diag. 0.40E+00    8.0     0.00030479     -4911.5244249415 -1.61E-03
    19 Broy./Diag. 0.40E+00    6.8     0.00028983     -4911.5233000159  1.12E-03
    20 Broy./Diag. 0.40E+00    7.3     0.00025125     -4911.5233194672 -1.95E-05
    21 Broy./Diag. 0.40E+00    7.2     0.00013958     -4911.5224870303  8.32E-04
    22 Broy./Diag. 0.40E+00    7.1     0.00013700     -4911.5234778823 -9.91E-04
    23 Broy./Diag. 0.40E+00    6.9     0.00018442     -4911.5233898557  8.80E-05
    24 Broy./Diag. 0.40E+00    7.4     0.00009664     -4911.5228982260  4.92E-04
    25 Broy./Diag. 0.40E+00    6.9     0.00009622     -4911.5232372481 -3.39E-04
    26 Broy./Diag. 0.40E+00    6.8     0.00009141     -4911.5232418760 -4.63E-06
    27 Broy./Diag. 0.40E+00    7.0     0.00006938     -4911.5234174503 -1.76E-04
    28 Broy./Diag. 0.40E+00    7.3     0.00007783     -4911.5229265830  4.91E-04
    29 Broy./Diag. 0.40E+00    8.1     0.00012968     -4911.5230594502 -1.33E-04
    30 Broy./Diag. 0.40E+00    7.1     0.00008005     -4911.5234113043 -3.52E-04
    31 Broy./Diag. 0.40E+00    7.3     0.00006263     -4911.5231683699  2.43E-04
    32 Broy./Diag. 0.40E+00    6.8     0.00005233     -4911.5231754516 -7.08E-06
    33 Broy./Diag. 0.40E+00    7.4     0.00003113     -4911.5230968266  7.86E-05
    34 Broy./Diag. 0.40E+00    7.4     0.00001936     -4911.5233183325 -2.22E-04
    35 Broy./Diag. 0.40E+00    6.6     0.00004881     -4911.5232408949  7.74E-05
    36 Broy./Diag. 0.40E+00    7.0     0.00004093     -4911.5231032401  1.38E-04
    37 Broy./Diag. 0.40E+00    6.9     0.00003062     -4911.5232166926 -1.13E-04
    38 Broy./Diag. 0.40E+00    7.1     0.00003486     -4911.5232221303 -5.44E-06
    39 Broy./Diag. 0.40E+00    7.1     0.00002288     -4911.5232593236 -3.72E-05
    40 Broy./Diag. 0.40E+00    7.6     0.00001528     -4911.5231041056  1.55E-04
    41 Broy./Diag. 0.40E+00    7.1     0.00002403     -4911.5231803554 -7.62E-05
    42 Broy./Diag. 0.40E+00    6.7     0.00001987     -4911.5232511482 -7.08E-05
    43 Broy./Diag. 0.40E+00    7.0     0.00000926     -4911.5231997109  5.14E-05
    44 Broy./Diag. 0.40E+00    6.7     0.00001532     -4911.5231953138  4.40E-06
    45 Broy./Diag. 0.40E+00    6.8     0.00001074     -4911.5231779096  1.74E-05
    46 Broy./Diag. 0.40E+00    6.8     0.00000875     -4911.5232383265 -6.04E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00001703     -4911.5231927883  4.55E-05
    48 Broy./Diag. 0.40E+00    7.1     0.00001652     -4911.5231476776  4.51E-05
    49 Broy./Diag. 0.40E+00    7.0     0.00000651     -4911.5231982927 -5.06E-05
    50 Broy./Diag. 0.40E+00    7.3     0.00001045     -4911.5232039393 -5.65E-06
    51 Broy./Diag. 0.40E+00    7.0     0.00000633     -4911.5232166727 -1.27E-05
    52 Broy./Diag. 0.40E+00    7.1     0.00000378     -4911.5231841000  3.26E-05
    53 Broy./Diag. 0.40E+00    7.1     0.00000529     -4911.5232032064 -1.91E-05
    54 Broy./Diag. 0.40E+00    7.2     0.00000663     -4911.5232152189 -1.20E-05
    55 Broy./Diag. 0.40E+00    7.7     0.00000367     -4911.5231947560  2.05E-05
    56 Broy./Diag. 0.40E+00    7.1     0.00000617     -4911.5231939092  8.47E-07
    57 Broy./Diag. 0.40E+00    7.3     0.00000517     -4911.5231888948  5.01E-06
    58 Broy./Diag. 0.40E+00    6.8     0.00000296     -4911.5232133817 -2.45E-05
    59 Broy./Diag. 0.40E+00    7.3     0.00000388     -4911.5231982272  1.52E-05
    60 Broy./Diag. 0.40E+00    8.1     0.00000373     -4911.5231899956  8.23E-06
    61 Broy./Diag. 0.40E+00    7.5     0.00000185     -4911.5232024036 -1.24E-05
    62 Broy./Diag. 0.40E+00   10.0     0.00000209     -4911.5232025543 -1.51E-07
    63 Broy./Diag. 0.40E+00    7.3     0.00000232     -4911.5232029636 -4.09E-07
    64 Broy./Diag. 0.40E+00    9.9     0.00000142     -4911.5231924551  1.05E-05
    65 Broy./Diag. 0.40E+00    9.6     0.00000215     -4911.5232016506 -9.20E-06
    66 Broy./Diag. 0.40E+00    7.0     0.00000287     -4911.5232058784 -4.23E-06
    67 Broy./Diag. 0.40E+00    7.3     0.00000171     -4911.5231966470  9.23E-06
    68 Broy./Diag. 0.40E+00    7.2     0.00000155     -4911.5231978669 -1.22E-06
    69 Broy./Diag. 0.40E+00    7.1     0.00000144     -4911.5231979720 -1.05E-07
    70 Broy./Diag. 0.40E+00    7.9     0.00000065     -4911.5232043261 -6.35E-06

  *** SCF run converged in    70 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008356903972
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.90861548184876
  Hartree energy:                                            1781.45974158126637
  Exchange-correlation energy:                               -779.56250496123118
  Electronic entropic energy:                                  -0.23871746774115
  Fermi energy:                                                 0.08703009966233

  Total energy:                                             -4911.52320432607848

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.523200798465950

 MD| ***************************************************************************
 MD| Step number                                                            1106
 MD| Time [fs]                                                       2212.000000
 MD| Conserved quantity [hartree]                            -0.491117833803E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    520.816301           603.730804
 MD| Energy drift per atom [K]           0.293239612037E+03   0.269106103239E+03
 MD| Potential energy [hartree]         -0.491152320080E+04  -0.491156586947E+04
 MD| Kinetic energy [hartree]            0.344862773155E+00   0.375909226384E+00
 MD| Temperature [K]                             918.978234          1001.709735
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    8.9     0.03530925     -4911.5204379537 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.8     0.12457342     -4911.5668926878 -4.65E-02
     3 Broy./Diag. 0.40E+00    8.6     0.15290051     -4911.2576253547  3.09E-01
     4 Broy./Diag. 0.40E+00    9.6     0.08007088     -4911.6665292918 -4.09E-01
     5 Broy./Diag. 0.40E+00    6.9     0.02024164     -4911.4892905914  1.77E-01
     6 Broy./Diag. 0.40E+00    7.4     0.00443399     -4911.5184917878 -2.92E-02
     7 Broy./Diag. 0.40E+00    7.0     0.00574252     -4911.5303676815 -1.19E-02
     8 Broy./Diag. 0.40E+00    7.9     0.00457669     -4911.5223089981  8.06E-03
     9 Broy./Diag. 0.40E+00    7.2     0.00170760     -4911.5200834277  2.23E-03
    10 Broy./Diag. 0.40E+00    9.3     0.00098679     -4911.5300271626 -9.94E-03
    11 Broy./Diag. 0.40E+00    7.4     0.00095189     -4911.5246428692  5.38E-03
    12 Broy./Diag. 0.40E+00   10.2     0.00034907     -4911.5222511483  2.39E-03
    13 Broy./Diag. 0.40E+00    9.2     0.00037703     -4911.5228955762 -6.44E-04
    14 Broy./Diag. 0.40E+00    7.4     0.00054428     -4911.5241060024 -1.21E-03
    15 Broy./Diag. 0.40E+00    6.6     0.00046902     -4911.5238784736  2.28E-04
    16 Broy./Diag. 0.40E+00    7.3     0.00033820     -4911.5219547256  1.92E-03
    17 Broy./Diag. 0.40E+00    7.1     0.00053239     -4911.5236806873 -1.73E-03
    18 Broy./Diag. 0.40E+00    7.0     0.00024200     -4911.5242884650 -6.08E-04
    19 Broy./Diag. 0.40E+00    6.9     0.00016617     -4911.5234788775  8.10E-04
    20 Broy./Diag. 0.40E+00    6.6     0.00026459     -4911.5227555321  7.23E-04
    21 Broy./Diag. 0.40E+00    8.0     0.00019982     -4911.5228617626 -1.06E-04
    22 Broy./Diag. 0.40E+00    7.6     0.00011121     -4911.5235203450 -6.59E-04
    23 Broy./Diag. 0.40E+00    6.6     0.00019673     -4911.5229381585  5.82E-04
    24 Broy./Diag. 0.40E+00    7.3     0.00011290     -4911.5227433578  1.95E-04
    25 Broy./Diag. 0.40E+00    6.6     0.00007579     -4911.5230670132 -3.24E-04
    26 Broy./Diag. 0.40E+00    7.4     0.00010432     -4911.5233328492 -2.66E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00011949     -4911.5231338910  1.99E-04
    28 Broy./Diag. 0.40E+00    7.3     0.00007277     -4911.5227278450  4.06E-04
    29 Broy./Diag. 0.40E+00    7.1     0.00011806     -4911.5230907001 -3.63E-04
    30 Broy./Diag. 0.40E+00    7.3     0.00008203     -4911.5232013771 -1.11E-04
    31 Broy./Diag. 0.40E+00    7.1     0.00004771     -4911.5229907686  2.11E-04
    32 Broy./Diag. 0.40E+00    7.1     0.00005142     -4911.5228326578  1.58E-04
    33 Broy./Diag. 0.40E+00    6.9     0.00006232     -4911.5229602134 -1.28E-04
    34 Broy./Diag. 0.40E+00    6.8     0.00003618     -4911.5231811358 -2.21E-04
    35 Broy./Diag. 0.40E+00    6.9     0.00005887     -4911.5229717168  2.09E-04
    36 Broy./Diag. 0.40E+00    7.1     0.00005409     -4911.5229061460  6.56E-05
    37 Broy./Diag. 0.40E+00    7.0     0.00002579     -4911.5230148151 -1.09E-04
    38 Broy./Diag. 0.40E+00    7.7     0.00002703     -4911.5230828369 -6.80E-05
    39 Broy./Diag. 0.40E+00    6.9     0.00003868     -4911.5229877253  9.51E-05
    40 Broy./Diag. 0.40E+00    7.5     0.00002572     -4911.5228519419  1.36E-04
    41 Broy./Diag. 0.40E+00    6.9     0.00002437     -4911.5229981700 -1.46E-04
    42 Broy./Diag. 0.40E+00    7.0     0.00002674     -4911.5230223529 -2.42E-05
    43 Broy./Diag. 0.40E+00    6.9     0.00001151     -4911.5229707318  5.16E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00001310     -4911.5229371343  3.36E-05
    45 Broy./Diag. 0.40E+00    7.1     0.00001583     -4911.5229809638 -4.38E-05
    46 Broy./Diag. 0.40E+00    7.1     0.00001389     -4911.5230193430 -3.84E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00001442     -4911.5229390515  8.03E-05
    48 Broy./Diag. 0.40E+00    6.8     0.00001916     -4911.5229287613  1.03E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00000696     -4911.5229681446 -3.94E-05
    50 Broy./Diag. 0.40E+00    7.2     0.00000868     -4911.5229883708 -2.02E-05
    51 Broy./Diag. 0.40E+00    6.7     0.00000919     -4911.5229595570  2.88E-05
    52 Broy./Diag. 0.40E+00    6.9     0.00000708     -4911.5229392295  2.03E-05
    53 Broy./Diag. 0.40E+00    7.3     0.00000491     -4911.5229799426 -4.07E-05
    54 Broy./Diag. 0.40E+00    7.3     0.00000869     -4911.5229778232  2.12E-06
    55 Broy./Diag. 0.40E+00    7.1     0.00000355     -4911.5229588982  1.89E-05
    56 Broy./Diag. 0.40E+00    7.3     0.00000475     -4911.5229499874  8.91E-06
    57 Broy./Diag. 0.40E+00    7.9     0.00000564     -4911.5229671599 -1.72E-05
    58 Broy./Diag. 0.40E+00    7.5     0.00000470     -4911.5229756107 -8.45E-06
    59 Broy./Diag. 0.40E+00    7.3     0.00000301     -4911.5229490145  2.66E-05
    60 Broy./Diag. 0.40E+00    7.1     0.00000514     -4911.5229525691 -3.55E-06
    61 Broy./Diag. 0.40E+00    6.9     0.00000211     -4911.5229641438 -1.16E-05
    62 Broy./Diag. 0.40E+00    6.8     0.00000206     -4911.5229674551 -3.31E-06
    63 Broy./Diag. 0.40E+00    7.0     0.00000295     -4911.5229584296  9.03E-06
    64 Broy./Diag. 0.40E+00    6.9     0.00000230     -4911.5229540374  4.39E-06
    65 Broy./Diag. 0.40E+00    7.5     0.00000166     -4911.5229661362 -1.21E-05
    66 Broy./Diag. 0.40E+00    7.2     0.00000348     -4911.5229632599  2.88E-06
    67 Broy./Diag. 0.40E+00    7.1     0.00000192     -4911.5229554214  7.84E-06
    68 Broy./Diag. 0.40E+00    7.4     0.00000126     -4911.5229547306  6.91E-07
    69 Broy./Diag. 0.40E+00    7.2     0.00000189     -4911.5229610312 -6.30E-06
    70 Broy./Diag. 0.40E+00    7.1     0.00000140     -4911.5229636977 -2.67E-06
    71 Broy./Diag. 0.40E+00    6.9     0.00000088     -4911.5229564970  7.20E-06

  *** SCF run converged in    71 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008365777791
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.91813176261576
  Hartree energy:                                            1781.45295626043026
  Exchange-correlation energy:                               -779.56482146294911
  Electronic entropic energy:                                  -0.23888420738685
  Fermi energy:                                                 0.08704186751999

  Total energy:                                             -4911.52295649702046

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.522958861503867

 MD| ***************************************************************************
 MD| Step number                                                            1107
 MD| Time [fs]                                                       2214.000000
 MD| Conserved quantity [hartree]                            -0.491117783403E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    528.732842           603.663055
 MD| Energy drift per atom [K]           0.294286646781E+03   0.269128849891E+03
 MD| Potential energy [hartree]         -0.491152295886E+04  -0.491156583071E+04
 MD| Kinetic energy [hartree]            0.345124832578E+00   0.375881417536E+00
 MD| Temperature [K]                             919.676561          1001.635631
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.03666119     -4911.5186922840 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.7     0.14498587     -4911.5909696398 -7.23E-02
     3 Broy./Diag. 0.40E+00    7.5     0.16741474     -4911.1612207288  4.30E-01
     4 Broy./Diag. 0.40E+00    7.5     0.07823087     -4911.6818953280 -5.21E-01
     5 Broy./Diag. 0.40E+00    7.3     0.01801120     -4911.5012071173  1.81E-01
     6 Broy./Diag. 0.40E+00    6.8     0.00515854     -4911.5062248695 -5.02E-03
     7 Broy./Diag. 0.40E+00    7.3     0.00391973     -4911.5339539423 -2.77E-02
     8 Broy./Diag. 0.40E+00    7.1     0.00390307     -4911.5024884362  3.15E-02
     9 Broy./Diag. 0.40E+00    6.9     0.00152382     -4911.5230916120 -2.06E-02
    10 Broy./Diag. 0.40E+00    7.4     0.00079031     -4911.5240193793 -9.28E-04
    11 Broy./Diag. 0.40E+00    7.5     0.00084913     -4911.5225400806  1.48E-03
    12 Broy./Diag. 0.40E+00    7.3     0.00037397     -4911.5212418250  1.30E-03
    13 Broy./Diag. 0.40E+00    7.3     0.00031139     -4911.5211457099  9.61E-05
    14 Broy./Diag. 0.40E+00    7.5     0.00045985     -4911.5236181248 -2.47E-03
    15 Broy./Diag. 0.40E+00    7.4     0.00053918     -4911.5205471204  3.07E-03
    16 Broy./Diag. 0.40E+00    7.2     0.00035890     -4911.5211645590 -6.17E-04
    17 Broy./Diag. 0.40E+00    7.4     0.00053046     -4911.5216723594 -5.08E-04
    18 Broy./Diag. 0.40E+00    7.6     0.00020385     -4911.5222143284 -5.42E-04
    19 Broy./Diag. 0.40E+00    7.0     0.00016215     -4911.5219020999  3.12E-04
    20 Broy./Diag. 0.40E+00    7.0     0.00017830     -4911.5206440578  1.26E-03
    21 Broy./Diag. 0.40E+00    6.9     0.00019756     -4911.5219731880 -1.33E-03
    22 Broy./Diag. 0.40E+00    7.6     0.00013376     -4911.5216297056  3.43E-04
    23 Broy./Diag. 0.40E+00    7.3     0.00023225     -4911.5214296633  2.00E-04
    24 Broy./Diag. 0.40E+00    7.0     0.00014404     -4911.5211626698  2.67E-04
    25 Broy./Diag. 0.40E+00    7.6     0.00009818     -4911.5213562346 -1.94E-04
    26 Broy./Diag. 0.40E+00    6.8     0.00009569     -4911.5220000794 -6.44E-04
    27 Broy./Diag. 0.40E+00    7.9     0.00014137     -4911.5211035120  8.97E-04
    28 Broy./Diag. 0.40E+00    6.9     0.00009629     -4911.5213436360 -2.40E-04
    29 Broy./Diag. 0.40E+00    7.3     0.00011107     -4911.5214148307 -7.12E-05
    30 Broy./Diag. 0.40E+00    7.2     0.00007688     -4911.5215483326 -1.34E-04
    31 Broy./Diag. 0.40E+00    7.3     0.00004334     -4911.5214254650  1.23E-04
    32 Broy./Diag. 0.40E+00    7.5     0.00003840     -4911.5211398221  2.86E-04
    33 Broy./Diag. 0.40E+00    7.3     0.00006949     -4911.5215355083 -3.96E-04
    34 Broy./Diag. 0.40E+00    7.2     0.00005901     -4911.5214014648  1.34E-04
    35 Broy./Diag. 0.40E+00    7.2     0.00007173     -4911.5213448955  5.66E-05
    36 Broy./Diag. 0.40E+00    6.4     0.00006821     -4911.5212405286  1.04E-04
    37 Broy./Diag. 0.40E+00    7.1     0.00002608     -4911.5213284470 -8.79E-05
    38 Broy./Diag. 0.40E+00    7.2     0.00001939     -4911.5214885313 -1.60E-04
    39 Broy./Diag. 0.40E+00    6.9     0.00003200     -4911.5212616866  2.27E-04
    40 Broy./Diag. 0.40E+00    7.3     0.00003070     -4911.5213274959 -6.58E-05
    41 Broy./Diag. 0.40E+00    7.2     0.00002281     -4911.5213486029 -2.11E-05
    42 Broy./Diag. 0.40E+00    7.7     0.00003199     -4911.5213772004 -2.86E-05
    43 Broy./Diag. 0.40E+00    6.4     0.00001524     -4911.5213309513  4.62E-05
    44 Broy./Diag. 0.40E+00    6.9     0.00001306     -4911.5212384277  9.25E-05
    45 Broy./Diag. 0.40E+00    7.3     0.00001796     -4911.5213915846 -1.53E-04
    46 Broy./Diag. 0.40E+00    7.1     0.00002056     -4911.5213342347  5.73E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00001378     -4911.5213204832  1.38E-05
    48 Broy./Diag. 0.40E+00    6.9     0.00001863     -4911.5212973544  2.31E-05
    49 Broy./Diag. 0.40E+00    6.9     0.00000659     -4911.5213217221 -2.44E-05
    50 Broy./Diag. 0.40E+00    7.9     0.00000599     -4911.5213556882 -3.40E-05
    51 Broy./Diag. 0.40E+00    7.8     0.00000823     -4911.5212842078  7.15E-05
    52 Broy./Diag. 0.40E+00    7.0     0.00001212     -4911.5213153784 -3.12E-05
    53 Broy./Diag. 0.40E+00    7.3     0.00000668     -4911.5213221571 -6.78E-06
    54 Broy./Diag. 0.40E+00    7.1     0.00001207     -4911.5213312515 -9.09E-06
    55 Broy./Diag. 0.40E+00    7.1     0.00000492     -4911.5213135175  1.77E-05
    56 Broy./Diag. 0.40E+00    7.3     0.00000376     -4911.5212888330  2.47E-05
    57 Broy./Diag. 0.40E+00    6.9     0.00000413     -4911.5213343071 -4.55E-05
    58 Broy./Diag. 0.40E+00    7.1     0.00000529     -4911.5213144435  1.99E-05
    59 Broy./Diag. 0.40E+00    7.3     0.00000364     -4911.5213111909  3.25E-06
    60 Broy./Diag. 0.40E+00    7.2     0.00000607     -4911.5213056045  5.59E-06
    61 Broy./Diag. 0.40E+00    7.5     0.00000279     -4911.5213148015 -9.20E-06
    62 Broy./Diag. 0.40E+00    7.2     0.00000239     -4911.5213231488 -8.35E-06
    63 Broy./Diag. 0.40E+00    6.5     0.00000301     -4911.5212960425  2.71E-05
    64 Broy./Diag. 0.40E+00    7.1     0.00000368     -4911.5213118129 -1.58E-05
    65 Broy./Diag. 0.40E+00    6.9     0.00000243     -4911.5213124566 -6.44E-07
    66 Broy./Diag. 0.40E+00    7.5     0.00000359     -4911.5213151632 -2.71E-06
    67 Broy./Diag. 0.40E+00    7.3     0.00000180     -4911.5213091958  5.97E-06
    68 Broy./Diag. 0.40E+00    7.0     0.00000117     -4911.5213049530  4.24E-06
    69 Broy./Diag. 0.40E+00    7.3     0.00000140     -4911.5213162452 -1.13E-05
    70 Broy./Diag. 0.40E+00    7.1     0.00000191     -4911.5213082887  7.96E-06
    71 Broy./Diag. 0.40E+00    6.8     0.00000163     -4911.5213083190 -3.03E-08
    72 Broy./Diag. 0.40E+00    6.9     0.00000242     -4911.5213063394  1.98E-06
    73 Broy./Diag. 0.40E+00    7.1     0.00000138     -4911.5213107978 -4.46E-06
    74 Broy./Diag. 0.40E+00    7.4     0.00000084     -4911.5213124285 -1.63E-06

  *** SCF run converged in    74 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008375815648
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.93340850045024
  Hartree energy:                                            1781.44291002843238
  Exchange-correlation energy:                               -779.56821709790438
  Electronic entropic energy:                                  -0.23907506725360
  Fermi energy:                                                 0.08706079051628

  Total energy:                                             -4911.52131242853375

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.521308193488949

 MD| ***************************************************************************
 MD| Step number                                                            1108
 MD| Time [fs]                                                       2216.000000
 MD| Conserved quantity [hartree]                            -0.491117910390E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    540.692876           603.606222
 MD| Energy drift per atom [K]           0.291648528121E+03   0.269149174510E+03
 MD| Potential energy [hartree]         -0.491152130819E+04  -0.491156579052E+04
 MD| Kinetic energy [hartree]            0.342204290497E+00   0.375851023017E+00
 MD| Temperature [K]                             911.894003          1001.554637
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.04476277     -4911.5161158766 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.9     0.17168632     -4911.6222874249 -1.06E-01
     3 Broy./Diag. 0.40E+00    6.5     0.17830338     -4911.0657840475  5.57E-01
     4 Broy./Diag. 0.40E+00    7.1     0.06759553     -4911.6575160495 -5.92E-01
     5 Broy./Diag. 0.40E+00    6.9     0.01570725     -4911.5139933832  1.44E-01
     6 Broy./Diag. 0.40E+00    7.7     0.00539243     -4911.4957227904  1.83E-02
     7 Broy./Diag. 0.40E+00    6.9     0.00294871     -4911.5322666780 -3.65E-02
     8 Broy./Diag. 0.40E+00    7.5     0.00310150     -4911.5027581041  2.95E-02
     9 Broy./Diag. 0.40E+00    7.5     0.00121374     -4911.5211362326 -1.84E-02
    10 Broy./Diag. 0.40E+00    7.3     0.00071249     -4911.5207646099  3.72E-04
    11 Broy./Diag. 0.40E+00    6.9     0.00071571     -4911.5196721730  1.09E-03
    12 Broy./Diag. 0.40E+00    7.5     0.00026268     -4911.5190735033  5.99E-04
    13 Broy./Diag. 0.40E+00    7.2     0.00030868     -4911.5188667021  2.07E-04
    14 Broy./Diag. 0.40E+00    7.2     0.00032536     -4911.5208912719 -2.02E-03
    15 Broy./Diag. 0.40E+00    7.0     0.00052780     -4911.5179640912  2.93E-03
    16 Broy./Diag. 0.40E+00    7.1     0.00050518     -4911.5186551942 -6.91E-04
    17 Broy./Diag. 0.40E+00    7.5     0.00041988     -4911.5190031648 -3.48E-04
    18 Broy./Diag. 0.40E+00    7.7     0.00022554     -4911.5196532008 -6.50E-04
    19 Broy./Diag. 0.40E+00    7.3     0.00015466     -4911.5192278061  4.25E-04
    20 Broy./Diag. 0.40E+00    7.1     0.00014642     -4911.5181147160  1.11E-03
    21 Broy./Diag. 0.40E+00    7.5     0.00015228     -4911.5192222863 -1.11E-03
    22 Broy./Diag. 0.40E+00    7.3     0.00016776     -4911.5189750488  2.47E-04
    23 Broy./Diag. 0.40E+00    6.9     0.00019233     -4911.5188464354  1.29E-04
    24 Broy./Diag. 0.40E+00    6.7     0.00017661     -4911.5184196527  4.27E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00006712     -4911.5187056516 -2.86E-04
    26 Broy./Diag. 0.40E+00    7.5     0.00009579     -4911.5192484500 -5.43E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00008095     -4911.5185450190  7.03E-04
    28 Broy./Diag. 0.40E+00    7.3     0.00008709     -4911.5186891533 -1.44E-04
    29 Broy./Diag. 0.40E+00    6.6     0.00005085     -4911.5187248601 -3.57E-05
    30 Broy./Diag. 0.40E+00    7.1     0.00006660     -4911.5188801028 -1.55E-04
    31 Broy./Diag. 0.40E+00    6.9     0.00002739     -4911.5187447365  1.35E-04
    32 Broy./Diag. 0.40E+00    6.7     0.00004300     -4911.5185198051  2.25E-04
    33 Broy./Diag. 0.40E+00    7.8     0.00003677     -4911.5188443957 -3.25E-04
    34 Broy./Diag. 0.40E+00    7.3     0.00006299     -4911.5187450392  9.94E-05
    35 Broy./Diag. 0.40E+00    7.1     0.00004517     -4911.5187239854  2.11E-05
    36 Broy./Diag. 0.40E+00    6.8     0.00005274     -4911.5185906821  1.33E-04
    37 Broy./Diag. 0.40E+00    6.8     0.00001622     -4911.5186914953 -1.01E-04
    38 Broy./Diag. 0.40E+00    7.1     0.00002160     -4911.5188005962 -1.09E-04
    39 Broy./Diag. 0.40E+00    7.3     0.00001870     -4911.5186287593  1.72E-04
    40 Broy./Diag. 0.40E+00    7.0     0.00002739     -4911.5186724177 -4.37E-05
    41 Broy./Diag. 0.40E+00    8.1     0.00002237     -4911.5186839961 -1.16E-05
    42 Broy./Diag. 0.40E+00    7.4     0.00002868     -4911.5187226149 -3.86E-05
    43 Broy./Diag. 0.40E+00    7.1     0.00001168     -4911.5186692206  5.34E-05
    44 Broy./Diag. 0.40E+00    7.5     0.00001234     -4911.5185979532  7.13E-05
    45 Broy./Diag. 0.40E+00    7.3     0.00001268     -4911.5187108228 -1.13E-04
    46 Broy./Diag. 0.40E+00    7.3     0.00001475     -4911.5186775831  3.32E-05
    47 Broy./Diag. 0.40E+00    7.3     0.00001228     -4911.5186696556  7.93E-06
    48 Broy./Diag. 0.40E+00    7.3     0.00001064     -4911.5186485202  2.11E-05
    49 Broy./Diag. 0.40E+00    7.5     0.00000600     -4911.5186696200 -2.11E-05
    50 Broy./Diag. 0.40E+00    7.3     0.00000561     -4911.5186889384 -1.93E-05
    51 Broy./Diag. 0.40E+00    6.9     0.00000745     -4911.5186347047  5.42E-05
    52 Broy./Diag. 0.40E+00    7.1     0.00000810     -4911.5186583672 -2.37E-05
    53 Broy./Diag. 0.40E+00    6.6     0.00000916     -4911.5186622199 -3.85E-06
    54 Broy./Diag. 0.40E+00    6.8     0.00000770     -4911.5186768099 -1.46E-05
    55 Broy./Diag. 0.40E+00    7.3     0.00000497     -4911.5186576534  1.92E-05
    56 Broy./Diag. 0.40E+00    7.1     0.00000253     -4911.5186453122  1.23E-05
    57 Broy./Diag. 0.40E+00    7.3     0.00000359     -4911.5186718350 -2.65E-05
    58 Broy./Diag. 0.40E+00    7.9     0.00000318     -4911.5186590070  1.28E-05
    59 Broy./Diag. 0.40E+00    7.2     0.00000468     -4911.5186562736  2.73E-06
    60 Broy./Diag. 0.40E+00    7.3     0.00000364     -4911.5186496897  6.58E-06
    61 Broy./Diag. 0.40E+00    7.4     0.00000317     -4911.5186605205 -1.08E-05
    62 Broy./Diag. 0.40E+00    7.1     0.00000195     -4911.5186648573 -4.34E-06
    63 Broy./Diag. 0.40E+00    7.4     0.00000247     -4911.5186455315  1.93E-05
    64 Broy./Diag. 0.40E+00    6.8     0.00000179     -4911.5186563497 -1.08E-05
    65 Broy./Diag. 0.40E+00    6.9     0.00000229     -4911.5186568650 -5.15E-07
    66 Broy./Diag. 0.40E+00    7.1     0.00000173     -4911.5186592020 -2.34E-06
    67 Broy./Diag. 0.40E+00    6.8     0.00000157     -4911.5186535264  5.68E-06
    68 Broy./Diag. 0.40E+00    7.2     0.00000082     -4911.5186526891  8.37E-07

  *** SCF run converged in    68 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008388461788
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.95547264930883
  Hartree energy:                                            1781.42923754943331
  Exchange-correlation energy:                               -779.57379240120349
  Electronic entropic energy:                                  -0.23923190263328
  Fermi energy:                                                 0.08708921049237

  Total energy:                                             -4911.51865268905385

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.518653701549738

 MD| ***************************************************************************
 MD| Step number                                                            1109
 MD| Time [fs]                                                       2218.000000
 MD| Conserved quantity [hartree]                            -0.491116532916E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    497.577698           603.510615
 MD| Energy drift per atom [K]           0.320265071832E+03   0.269195266393E+03
 MD| Potential energy [hartree]         -0.491151865370E+04  -0.491156574802E+04
 MD| Kinetic energy [hartree]            0.353324541631E+00   0.375830710591E+00
 MD| Temperature [K]                             941.526858          1001.500509
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.05062098     -4911.5126817602 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.8     0.19072065     -4911.6627917473 -1.50E-01
     3 Broy./Diag. 0.40E+00    7.1     0.18044212     -4910.9738010377  6.89E-01
     4 Broy./Diag. 0.40E+00    6.9     0.05446816     -4911.6255730438 -6.52E-01
     5 Broy./Diag. 0.40E+00    6.9     0.01402292     -4911.5277768098  9.78E-02
     6 Broy./Diag. 0.40E+00    7.1     0.00535865     -4911.4875134249  4.03E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00530119     -4911.5306866438 -4.32E-02
     8 Broy./Diag. 0.40E+00    6.7     0.00496057     -4911.5045316815  2.62E-02
     9 Broy./Diag. 0.40E+00    7.1     0.00122309     -4911.5155956802 -1.11E-02
    10 Broy./Diag. 0.40E+00    7.3     0.00067722     -4911.5175244366 -1.93E-03
    11 Broy./Diag. 0.40E+00    6.9     0.00072242     -4911.5168264380  6.98E-04
    12 Broy./Diag. 0.40E+00    7.0     0.00032748     -4911.5164454449  3.81E-04
    13 Broy./Diag. 0.40E+00    7.5     0.00036610     -4911.5151178374  1.33E-03
    14 Broy./Diag. 0.40E+00    6.9     0.00051750     -4911.5174815596 -2.36E-03
    15 Broy./Diag. 0.40E+00    7.1     0.00060559     -4911.5151966582  2.28E-03
    16 Broy./Diag. 0.40E+00    6.7     0.00035065     -4911.5147286139  4.68E-04
    17 Broy./Diag. 0.40E+00    7.5     0.00038879     -4911.5154976341 -7.69E-04
    18 Broy./Diag. 0.40E+00    7.3     0.00021867     -4911.5160414368 -5.44E-04
    19 Broy./Diag. 0.40E+00    7.1     0.00018295     -4911.5160753477 -3.39E-05
    20 Broy./Diag. 0.40E+00    8.0     0.00019009     -4911.5147565787  1.32E-03
    21 Broy./Diag. 0.40E+00    7.2     0.00017467     -4911.5156176270 -8.61E-04
    22 Broy./Diag. 0.40E+00    9.3     0.00011751     -4911.5156183513 -7.24E-07
    23 Broy./Diag. 0.40E+00    6.8     0.00017055     -4911.5153109458  3.07E-04
    24 Broy./Diag. 0.40E+00    8.0     0.00015845     -4911.5150641512  2.47E-04
    25 Broy./Diag. 0.40E+00   10.5     0.00009485     -4911.5151037004 -3.95E-05
    26 Broy./Diag. 0.40E+00    7.7     0.00012058     -4911.5157926811 -6.89E-04
    27 Broy./Diag. 0.40E+00    7.5     0.00010816     -4911.5151418151  6.51E-04
    28 Broy./Diag. 0.40E+00    7.2     0.00006767     -4911.5151237051  1.81E-05
    29 Broy./Diag. 0.40E+00    7.1     0.00005887     -4911.5152572014 -1.33E-04
    30 Broy./Diag. 0.40E+00    7.9     0.00006442     -4911.5153161979 -5.90E-05
    31 Broy./Diag. 0.40E+00    7.2     0.00003897     -4911.5152505832  6.56E-05
    32 Broy./Diag. 0.40E+00   10.0     0.00005556     -4911.5149534774  2.97E-04
    33 Broy./Diag. 0.40E+00    7.7     0.00005481     -4911.5152620082 -3.09E-04
    34 Broy./Diag. 0.40E+00    7.3     0.00004877     -4911.5152216355  4.04E-05
    35 Broy./Diag. 0.40E+00   10.3     0.00004666     -4911.5151320588  8.96E-05
    36 Broy./Diag. 0.40E+00    7.0     0.00004871     -4911.5150658800  6.62E-05
    37 Broy./Diag. 0.40E+00    7.1     0.00002008     -4911.5151125192 -4.66E-05
    38 Broy./Diag. 0.40E+00    7.1     0.00002810     -4911.5152393242 -1.27E-04
    39 Broy./Diag. 0.40E+00    8.0     0.00002440     -4911.5150700539  1.69E-04
    40 Broy./Diag. 0.40E+00    6.9     0.00002073     -4911.5150861970 -1.61E-05
    41 Broy./Diag. 0.40E+00    9.2     0.00002014     -4911.5151219507 -3.58E-05
    42 Broy./Diag. 0.40E+00    7.4     0.00002693     -4911.5151264611 -4.51E-06
    43 Broy./Diag. 0.40E+00    8.7     0.00001278     -4911.5151029738  2.35E-05
    44 Broy./Diag. 0.40E+00   10.3     0.00001811     -4911.5150188918  8.41E-05
    45 Broy./Diag. 0.40E+00    6.9     0.00001593     -4911.5151297426 -1.11E-04
    46 Broy./Diag. 0.40E+00    6.9     0.00001236     -4911.5151050458  2.47E-05
    47 Broy./Diag. 0.40E+00    7.3     0.00001084     -4911.5150784420  2.66E-05
    48 Broy./Diag. 0.40E+00    6.9     0.00001067     -4911.5150732738  5.17E-06
    49 Broy./Diag. 0.40E+00    7.3     0.00000522     -4911.5150822621 -8.99E-06
    50 Broy./Diag. 0.40E+00    7.3     0.00000870     -4911.5151027590 -2.05E-05
    51 Broy./Diag. 0.40E+00    7.3     0.00000922     -4911.5150478388  5.49E-05
    52 Broy./Diag. 0.40E+00    6.9     0.00000727     -4911.5150665294 -1.87E-05
    53 Broy./Diag. 0.40E+00    8.1     0.00000782     -4911.5150782547 -1.17E-05
    54 Broy./Diag. 0.40E+00    7.3     0.00000751     -4911.5150802633 -2.01E-06
    55 Broy./Diag. 0.40E+00    6.8     0.00000446     -4911.5150682720  1.20E-05
    56 Broy./Diag. 0.40E+00    7.1     0.00000434     -4911.5150546092  1.37E-05
    57 Broy./Diag. 0.40E+00    6.9     0.00000431     -4911.5150804890 -2.59E-05
    58 Broy./Diag. 0.40E+00    6.9     0.00000332     -4911.5150680467  1.24E-05
    59 Broy./Diag. 0.40E+00    7.1     0.00000377     -4911.5150611226  6.92E-06
    60 Broy./Diag. 0.40E+00    7.1     0.00000345     -4911.5150611825 -5.99E-08
    61 Broy./Diag. 0.40E+00    7.3     0.00000288     -4911.5150661178 -4.94E-06
    62 Broy./Diag. 0.40E+00    7.3     0.00000313     -4911.5150715077 -5.39E-06
    63 Broy./Diag. 0.40E+00    7.1     0.00000298     -4911.5150518557  1.97E-05
    64 Broy./Diag. 0.40E+00    7.1     0.00000208     -4911.5150618720 -1.00E-05
    65 Broy./Diag. 0.40E+00    7.1     0.00000199     -4911.5150645836 -2.71E-06
    66 Broy./Diag. 0.40E+00    7.3     0.00000169     -4911.5150632079  1.38E-06
    67 Broy./Diag. 0.40E+00    7.3     0.00000149     -4911.5150597029  3.50E-06
    68 Broy./Diag. 0.40E+00    7.4     0.00000139     -4911.5150578459  1.86E-06
    69 Broy./Diag. 0.40E+00    7.3     0.00000155     -4911.5150651415 -7.30E-06
    70 Broy./Diag. 0.40E+00    7.4     0.00000138     -4911.5150587509  6.39E-06
    71 Broy./Diag. 0.40E+00    6.9     0.00000118     -4911.5150572451  1.51E-06
    72 Broy./Diag. 0.40E+00    7.0     0.00000116     -4911.5150582291 -9.84E-07
    73 Broy./Diag. 0.40E+00    7.1     0.00000111     -4911.5150604370 -2.21E-06
    74 Broy./Diag. 0.40E+00    6.9     0.00000089     -4911.5150606926 -2.56E-07

  *** SCF run converged in    74 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008406250224
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.98580444515483
  Hartree energy:                                            1781.41083371612558
  Exchange-correlation energy:                               -779.58198199742560
  Electronic entropic energy:                                  -0.23937837999755
  Fermi energy:                                                 0.08712970067873

  Total energy:                                             -4911.51506069258539

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.515056710505633

 MD| ***************************************************************************
 MD| Step number                                                            1110
 MD| Time [fs]                                                       2220.000000
 MD| Conserved quantity [hartree]                            -0.491116781094E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    560.239833           603.471632
 MD| Energy drift per atom [K]           0.315109255796E+03   0.269236630347E+03
 MD| Potential energy [hartree]         -0.491151505671E+04  -0.491156570235E+04
 MD| Kinetic energy [hartree]            0.347245767952E+00   0.375804958390E+00
 MD| Temperature [K]                             925.328355          1001.431885
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.04364027     -4911.5088730983 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.7     0.16848836     -4911.6599603999 -1.51E-01
     3 Broy./Diag. 0.40E+00    7.1     0.16752585     -4910.9847517470  6.75E-01
     4 Broy./Diag. 0.40E+00    7.3     0.05705814     -4911.6448262763 -6.60E-01
     5 Broy./Diag. 0.40E+00    7.2     0.01370083     -4911.5246472187  1.20E-01
     6 Broy./Diag. 0.40E+00    6.8     0.00685289     -4911.4839841414  4.07E-02
     7 Broy./Diag. 0.40E+00    7.0     0.00792004     -4911.5276656367 -4.37E-02
     8 Broy./Diag. 0.40E+00    7.3     0.00502495     -4911.5056340397  2.20E-02
     9 Broy./Diag. 0.40E+00    7.3     0.00088667     -4911.5110496007 -5.42E-03
    10 Broy./Diag. 0.40E+00    6.7     0.00091901     -4911.5142587716 -3.21E-03
    11 Broy./Diag. 0.40E+00    7.3     0.00091360     -4911.5135525120  7.06E-04
    12 Broy./Diag. 0.40E+00    7.1     0.00044205     -4911.5125464725  1.01E-03
    13 Broy./Diag. 0.40E+00    7.3     0.00053870     -4911.5107132873  1.83E-03
    14 Broy./Diag. 0.40E+00    7.3     0.00068250     -4911.5134283496 -2.72E-03
    15 Broy./Diag. 0.40E+00    6.6     0.00041366     -4911.5120907530  1.34E-03
    16 Broy./Diag. 0.40E+00    7.1     0.00048770     -4911.5108695975  1.22E-03
    17 Broy./Diag. 0.40E+00    7.5     0.00052735     -4911.5113778751 -5.08E-04
    18 Broy./Diag. 0.40E+00    6.9     0.00021476     -4911.5120611352 -6.83E-04
    19 Broy./Diag. 0.40E+00    7.5     0.00023521     -4911.5125946930 -5.34E-04
    20 Broy./Diag. 0.40E+00    7.2     0.00026407     -4911.5110842355  1.51E-03
    21 Broy./Diag. 0.40E+00    7.1     0.00016050     -4911.5116386194 -5.54E-04
    22 Broy./Diag. 0.40E+00    7.3     0.00018564     -4911.5118605415 -2.22E-04
    23 Broy./Diag. 0.40E+00    6.8     0.00026749     -4911.5115466079  3.14E-04
    24 Broy./Diag. 0.40E+00    7.2     0.00015165     -4911.5111847841  3.62E-04
    25 Broy./Diag. 0.40E+00    7.3     0.00015480     -4911.5109518937  2.33E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00017516     -4911.5119439557 -9.92E-04
    27 Broy./Diag. 0.40E+00    6.8     0.00011651     -4911.5113752161  5.69E-04
    28 Broy./Diag. 0.40E+00    7.4     0.00009641     -4911.5111762084  1.99E-04
    29 Broy./Diag. 0.40E+00    6.9     0.00010695     -4911.5112870638 -1.11E-04
    30 Broy./Diag. 0.40E+00    7.2     0.00007519     -4911.5114144131 -1.27E-04
    31 Broy./Diag. 0.40E+00    6.9     0.00007621     -4911.5113855505  2.89E-05
    32 Broy./Diag. 0.40E+00    7.3     0.00008712     -4911.5109068501  4.79E-04
    33 Broy./Diag. 0.40E+00    7.3     0.00006758     -4911.5112147129 -3.08E-04
    34 Broy./Diag. 0.40E+00    7.1     0.00006855     -4911.5113093952 -9.47E-05
    35 Broy./Diag. 0.40E+00    7.5     0.00007160     -4911.5111783206  1.31E-04
    36 Broy./Diag. 0.40E+00    7.1     0.00005800     -4911.5110743848  1.04E-04
    37 Broy./Diag. 0.40E+00    6.6     0.00003778     -4911.5110857130 -1.13E-05
    38 Broy./Diag. 0.40E+00    6.9     0.00004024     -4911.5112988425 -2.13E-04
    39 Broy./Diag. 0.40E+00    7.1     0.00002979     -4911.5111128783  1.86E-04
    40 Broy./Diag. 0.40E+00    7.5     0.00002951     -4911.5110709567  4.19E-05
    41 Broy./Diag. 0.40E+00    7.2     0.00003040     -4911.5111227086 -5.18E-05
    42 Broy./Diag. 0.40E+00    7.3     0.00003609     -4911.5111501461 -2.74E-05
    43 Broy./Diag. 0.40E+00    6.9     0.00002551     -4911.5111303520  1.98E-05
    44 Broy./Diag. 0.40E+00    6.9     0.00002951     -4911.5109805939  1.50E-04
    45 Broy./Diag. 0.40E+00    7.2     0.00001902     -4911.5111187938 -1.38E-04
    46 Broy./Diag. 0.40E+00    6.9     0.00001678     -4911.5111189366 -1.43E-07
    47 Broy./Diag. 0.40E+00    6.9     0.00001390     -4911.5110791066  3.98E-05
    48 Broy./Diag. 0.40E+00    7.1     0.00001719     -4911.5110585436  2.06E-05
    49 Broy./Diag. 0.40E+00    6.4     0.00001053     -4911.5110691302 -1.06E-05
    50 Broy./Diag. 0.40E+00    7.0     0.00001624     -4911.5111093588 -4.02E-05
    51 Broy./Diag. 0.40E+00    7.1     0.00001272     -4911.5110343732  7.50E-05
    52 Broy./Diag. 0.40E+00    7.3     0.00000998     -4911.5110384056 -4.03E-06
    53 Broy./Diag. 0.40E+00    7.6     0.00001031     -4911.5110619196 -2.35E-05
    54 Broy./Diag. 0.40E+00    7.4     0.00001211     -4911.5110694808 -7.56E-06
    55 Broy./Diag. 0.40E+00    7.4     0.00000614     -4911.5110572577  1.22E-05
    56 Broy./Diag. 0.40E+00    7.2     0.00000754     -4911.5110317614  2.55E-05
    57 Broy./Diag. 0.40E+00    7.2     0.00000588     -4911.5110658773 -3.41E-05
    58 Broy./Diag. 0.40E+00    6.9     0.00000424     -4911.5110551484  1.07E-05
    59 Broy./Diag. 0.40E+00    6.8     0.00000574     -4911.5110418394  1.33E-05
    60 Broy./Diag. 0.40E+00    6.7     0.00000693     -4911.5110378432  4.00E-06
    61 Broy./Diag. 0.40E+00    7.3     0.00000403     -4911.5110453868 -7.54E-06
    62 Broy./Diag. 0.40E+00    8.5     0.00000527     -4911.5110567532 -1.14E-05
    63 Broy./Diag. 0.40E+00    7.2     0.00000427     -4911.5110302308  2.65E-05
    64 Broy./Diag. 0.40E+00    7.1     0.00000211     -4911.5110388952 -8.66E-06
    65 Broy./Diag. 0.40E+00    7.1     0.00000305     -4911.5110439485 -5.05E-06
    66 Broy./Diag. 0.40E+00    7.3     0.00000356     -4911.5110438398  1.09E-07
    67 Broy./Diag. 0.40E+00    7.4     0.00000202     -4911.5110379604  5.88E-06
    68 Broy./Diag. 0.40E+00    6.8     0.00000245     -4911.5110331572  4.80E-06
    69 Broy./Diag. 0.40E+00    7.3     0.00000249     -4911.5110438003 -1.06E-05
    70 Broy./Diag. 0.40E+00    7.9     0.00000135     -4911.5110374774  6.32E-06
    71 Broy./Diag. 0.40E+00    7.3     0.00000213     -4911.5110333283  4.15E-06
    72 Broy./Diag. 0.40E+00    7.1     0.00000235     -4911.5110334931 -1.65E-07
    73 Broy./Diag. 0.40E+00    6.9     0.00000128     -4911.5110371023 -3.61E-06
    74 Broy./Diag. 0.40E+00    6.6     0.00000140     -4911.5110388482 -1.75E-06
    75 Broy./Diag. 0.40E+00    6.8     0.00000120     -4911.5110318200  7.03E-06
    76 Broy./Diag. 0.40E+00    7.3     0.00000063     -4911.5110351656 -3.35E-06

  *** SCF run converged in    76 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008425897437
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2750.01531949313494
  Hartree energy:                                            1781.39285396725199
  Exchange-correlation energy:                               -779.58937104095639
  Electronic entropic energy:                                  -0.23949933668915
  Fermi energy:                                                 0.08716857711029

  Total energy:                                             -4911.51103516564581

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.511031430558432

 MD| ***************************************************************************
 MD| Step number                                                            1111
 MD| Time [fs]                                                       2222.000000
 MD| Conserved quantity [hartree]                            -0.491117324719E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    551.264140           603.424641
 MD| Energy drift per atom [K]           0.303815635628E+03   0.269267754564E+03
 MD| Potential energy [hartree]         -0.491151103143E+04  -0.491156565314E+04
 MD| Kinetic energy [hartree]            0.337784236942E+00   0.375770736318E+00
 MD| Temperature [K]                             900.115599          1001.340692
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.8     0.02958713     -4911.5054014733 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.9     0.12175749     -4911.6250995906 -1.20E-01
     3 Broy./Diag. 0.40E+00    7.2     0.13896467     -4911.1227008153  5.02E-01
     4 Broy./Diag. 0.40E+00    7.3     0.06114651     -4911.6678219023 -5.45E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01378615     -4911.5105751273  1.57E-01
     6 Broy./Diag. 0.40E+00    7.4     0.00625319     -4911.4886911735  2.19E-02
     7 Broy./Diag. 0.40E+00    6.9     0.00705273     -4911.5229672329 -3.43E-02
     8 Broy./Diag. 0.40E+00    7.1     0.00412078     -4911.5001118001  2.29E-02
     9 Broy./Diag. 0.40E+00    7.1     0.00114305     -4911.5081840901 -8.07E-03
    10 Broy./Diag. 0.40E+00    6.9     0.00091427     -4911.5103500832 -2.17E-03
    11 Broy./Diag. 0.40E+00    7.1     0.00077105     -4911.5098400329  5.10E-04
    12 Broy./Diag. 0.40E+00    7.2     0.00041469     -4911.5074098720  2.43E-03
    13 Broy./Diag. 0.40E+00    7.5     0.00026503     -4911.5072962872  1.14E-04
    14 Broy./Diag. 0.40E+00    7.5     0.00045180     -4911.5092144605 -1.92E-03
    15 Broy./Diag. 0.40E+00    7.3     0.00038141     -4911.5074182336  1.80E-03
    16 Broy./Diag. 0.40E+00    7.5     0.00026712     -4911.5076954465 -2.77E-04
    17 Broy./Diag. 0.40E+00    6.8     0.00031188     -4911.5077496400 -5.42E-05
    18 Broy./Diag. 0.40E+00    7.0     0.00024439     -4911.5081861871 -4.37E-04
    19 Broy./Diag. 0.40E+00    7.3     0.00012948     -4911.5076397804  5.46E-04
    20 Broy./Diag. 0.40E+00    7.7     0.00014760     -4911.5067413958  8.98E-04
    21 Broy./Diag. 0.40E+00    6.9     0.00013472     -4911.5076293902 -8.88E-04
    22 Broy./Diag. 0.40E+00    7.3     0.00006193     -4911.5075484672  8.09E-05
    23 Broy./Diag. 0.40E+00    6.9     0.00008280     -4911.5074423367  1.06E-04
    24 Broy./Diag. 0.40E+00    7.1     0.00007728     -4911.5072841659  1.58E-04
    25 Broy./Diag. 0.40E+00    6.7     0.00003730     -4911.5074302944 -1.46E-04
    26 Broy./Diag. 0.40E+00    7.3     0.00004485     -4911.5076017991 -1.72E-04
    27 Broy./Diag. 0.40E+00    7.3     0.00005726     -4911.5072752043  3.27E-04
    28 Broy./Diag. 0.40E+00    7.0     0.00003599     -4911.5073355824 -6.04E-05
    29 Broy./Diag. 0.40E+00    7.5     0.00004223     -4911.5073643161 -2.87E-05
    30 Broy./Diag. 0.40E+00    7.2     0.00004945     -4911.5074504126 -8.61E-05
    31 Broy./Diag. 0.40E+00    7.2     0.00001931     -4911.5073411685  1.09E-04
    32 Broy./Diag. 0.40E+00    7.1     0.00002256     -4911.5072592515  8.19E-05
    33 Broy./Diag. 0.40E+00    7.1     0.00002309     -4911.5074126150 -1.53E-04
    34 Broy./Diag. 0.40E+00    7.1     0.00001654     -4911.5073498910  6.27E-05
    35 Broy./Diag. 0.40E+00    6.9     0.00001950     -4911.5073275299  2.24E-05
    36 Broy./Diag. 0.40E+00    7.2     0.00002672     -4911.5072817091  4.58E-05
    37 Broy./Diag. 0.40E+00    7.1     0.00001146     -4911.5073376038 -5.59E-05
    38 Broy./Diag. 0.40E+00    7.5     0.00001583     -4911.5073581202 -2.05E-05
    39 Broy./Diag. 0.40E+00    7.5     0.00001423     -4911.5072570034  1.01E-04
    40 Broy./Diag. 0.40E+00    7.5     0.00000992     -4911.5072994032 -4.24E-05
    41 Broy./Diag. 0.40E+00    6.9     0.00000904     -4911.5073088703 -9.47E-06
    42 Broy./Diag. 0.40E+00    7.3     0.00001368     -4911.5073182487 -9.38E-06
    43 Broy./Diag. 0.40E+00    7.1     0.00000695     -4911.5072863594  3.19E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00000742     -4911.5072789018  7.46E-06
    45 Broy./Diag. 0.40E+00    7.1     0.00000753     -4911.5073189207 -4.00E-05
    46 Broy./Diag. 0.40E+00    7.5     0.00000569     -4911.5072876416  3.13E-05
    47 Broy./Diag. 0.40E+00    6.7     0.00000535     -4911.5072847071  2.93E-06
    48 Broy./Diag. 0.40E+00    6.9     0.00000787     -4911.5072766792  8.03E-06
    49 Broy./Diag. 0.40E+00    7.3     0.00000481     -4911.5072952021 -1.85E-05
    50 Broy./Diag. 0.40E+00    6.9     0.00000411     -4911.5072948178  3.84E-07
    51 Broy./Diag. 0.40E+00    7.3     0.00000410     -4911.5072712293  2.36E-05
    52 Broy./Diag. 0.40E+00    7.4     0.00000295     -4911.5072879761 -1.67E-05
    53 Broy./Diag. 0.40E+00    6.9     0.00000283     -4911.5072853096  2.67E-06
    54 Broy./Diag. 0.40E+00    7.1     0.00000441     -4911.5072864058 -1.10E-06
    55 Broy./Diag. 0.40E+00    7.3     0.00000318     -4911.5072752904  1.11E-05
    56 Broy./Diag. 0.40E+00    7.6     0.00000231     -4911.5072769794 -1.69E-06
    57 Broy./Diag. 0.40E+00    7.0     0.00000273     -4911.5072863307 -9.35E-06
    58 Broy./Diag. 0.40E+00    7.3     0.00000190     -4911.5072751717  1.12E-05
    59 Broy./Diag. 0.40E+00    7.1     0.00000163     -4911.5072766733 -1.50E-06
    60 Broy./Diag. 0.40E+00    7.9     0.00000238     -4911.5072752914  1.38E-06
    61 Broy./Diag. 0.40E+00    7.3     0.00000190     -4911.5072804702 -5.18E-06
    62 Broy./Diag. 0.40E+00    6.9     0.00000126     -4911.5072780005  2.47E-06
    63 Broy./Diag. 0.40E+00    7.1     0.00000139     -4911.5072727617  5.24E-06
    64 Broy./Diag. 0.40E+00    7.7     0.00000107     -4911.5072784565 -5.69E-06
    65 Broy./Diag. 0.40E+00    6.9     0.00000090     -4911.5072759037  2.55E-06

  *** SCF run converged in    65 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008443408591
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2750.04132610962461
  Hartree energy:                                            1781.37707851454411
  Exchange-correlation energy:                               -779.59578053320206
  Electronic entropic energy:                                  -0.23956193018343
  Fermi energy:                                                 0.08720162409481

  Total energy:                                             -4911.50727590366114

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.507272335986272

 MD| ***************************************************************************
 MD| Step number                                                            1112
 MD| Time [fs]                                                       2224.000000
 MD| Conserved quantity [hartree]                            -0.491117378824E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    476.130574           603.310168
 MD| Energy drift per atom [K]           0.302691632105E+03   0.269297812008E+03
 MD| Potential energy [hartree]         -0.491150727234E+04  -0.491156560064E+04
 MD| Kinetic energy [hartree]            0.333484096606E+00   0.375732708765E+00
 MD| Temperature [K]                             888.656736          1001.239357
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.6     0.01983731     -4911.5023931848 -4.91E+03
     2 Broy./Diag. 0.40E+00    8.2     0.08250413     -4911.5972198946 -9.48E-02
     3 Broy./Diag. 0.40E+00    7.3     0.10859525     -4911.2432654220  3.54E-01
     4 Broy./Diag. 0.40E+00    7.3     0.06039669     -4911.6671877458 -4.24E-01
     5 Broy./Diag. 0.40E+00    6.8     0.01630474     -4911.4901496929  1.77E-01
     6 Broy./Diag. 0.40E+00    7.1     0.00493614     -4911.4967769438 -6.63E-03
     7 Broy./Diag. 0.40E+00    7.3     0.00490931     -4911.5189994647 -2.22E-02
     8 Broy./Diag. 0.40E+00    7.1     0.00272954     -4911.4967357055  2.23E-02
     9 Broy./Diag. 0.40E+00    7.3     0.00081490     -4911.5054195935 -8.68E-03
    10 Broy./Diag. 0.40E+00    7.3     0.00078521     -4911.5057035748 -2.84E-04
    11 Broy./Diag. 0.40E+00    7.3     0.00061894     -4911.5062240432 -5.20E-04
    12 Broy./Diag. 0.40E+00    7.3     0.00051405     -4911.5033155488  2.91E-03
    13 Broy./Diag. 0.40E+00    7.3     0.00017301     -4911.5049026546 -1.59E-03
    14 Broy./Diag. 0.40E+00    6.9     0.00015808     -4911.5055371726 -6.35E-04
    15 Broy./Diag. 0.40E+00    7.5     0.00018387     -4911.5043797246  1.16E-03
    16 Broy./Diag. 0.40E+00    7.1     0.00015462     -4911.5046281293 -2.48E-04
    17 Broy./Diag. 0.40E+00    6.9     0.00007544     -4911.5043651077  2.63E-04
    18 Broy./Diag. 0.40E+00    7.8     0.00007756     -4911.5039449641  4.20E-04
    19 Broy./Diag. 0.40E+00    7.3     0.00007599     -4911.5042707168 -3.26E-04
    20 Broy./Diag. 0.40E+00    7.3     0.00004990     -4911.5041657580  1.05E-04
    21 Broy./Diag. 0.40E+00    7.3     0.00002691     -4911.5041451792  2.06E-05
    22 Broy./Diag. 0.40E+00    7.3     0.00002367     -4911.5039877945  1.57E-04
    23 Broy./Diag. 0.40E+00    7.7     0.00002626     -4911.5041333460 -1.46E-04
    24 Broy./Diag. 0.40E+00    7.3     0.00002060     -4911.5040720136  6.13E-05
    25 Broy./Diag. 0.40E+00    7.3     0.00001633     -4911.5040415038  3.05E-05
    26 Broy./Diag. 0.40E+00    7.4     0.00002068     -4911.5041037715 -6.23E-05
    27 Broy./Diag. 0.40E+00    6.9     0.00001381     -4911.5040674259  3.63E-05
    28 Broy./Diag. 0.40E+00    6.9     0.00000947     -4911.5040707473 -3.32E-06
    29 Broy./Diag. 0.40E+00    7.1     0.00001024     -4911.5040031133  6.76E-05
    30 Broy./Diag. 0.40E+00    7.3     0.00001238     -4911.5040711311 -6.80E-05
    31 Broy./Diag. 0.40E+00    7.3     0.00000806     -4911.5040787912 -7.66E-06
    32 Broy./Diag. 0.40E+00    6.7     0.00001009     -4911.5040549783  2.38E-05
    33 Broy./Diag. 0.40E+00    7.1     0.00001065     -4911.5040727586 -1.78E-05
    34 Broy./Diag. 0.40E+00    7.1     0.00000446     -4911.5040644932  8.27E-06
    35 Broy./Diag. 0.40E+00    7.1     0.00000506     -4911.5040855821 -2.11E-05
    36 Broy./Diag. 0.40E+00    7.0     0.00000499     -4911.5040520241  3.36E-05
    37 Broy./Diag. 0.40E+00    7.7     0.00000374     -4911.5040642116 -1.22E-05
    38 Broy./Diag. 0.40E+00    6.6     0.00000330     -4911.5040756885 -1.15E-05
    39 Broy./Diag. 0.40E+00    7.1     0.00000433     -4911.5040706293  5.06E-06
    40 Broy./Diag. 0.40E+00    6.9     0.00000254     -4911.5040744826 -3.85E-06
    41 Broy./Diag. 0.40E+00    7.5     0.00000232     -4911.5040671249  7.36E-06
    42 Broy./Diag. 0.40E+00    7.2     0.00000224     -4911.5040823924 -1.53E-05
    43 Broy./Diag. 0.40E+00    6.9     0.00000179     -4911.5040758071  6.59E-06
    44 Broy./Diag. 0.40E+00    7.0     0.00000149     -4911.5040701041  5.70E-06
    45 Broy./Diag. 0.40E+00    7.1     0.00000169     -4911.5040751130 -5.01E-06
    46 Broy./Diag. 0.40E+00    6.9     0.00000118     -4911.5040739556  1.16E-06
    47 Broy./Diag. 0.40E+00    7.5     0.00000081     -4911.5040777146 -3.76E-06

  *** SCF run converged in    47 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008454923221
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2750.06241656524298
  Hartree energy:                                            1781.36490814464241
  Exchange-correlation energy:                               -779.60146689079647
  Electronic entropic energy:                                  -0.23959754111173
  Fermi energy:                                                 0.08722324213321

  Total energy:                                             -4911.50407771463870

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.504078175697941

 MD| ***************************************************************************
 MD| Step number                                                            1113
 MD| Time [fs]                                                       2226.000000
 MD| Conserved quantity [hartree]                            -0.491117432213E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    347.589602           603.080410
 MD| Energy drift per atom [K]           0.301582496354E+03   0.269326818912E+03
 MD| Potential energy [hartree]         -0.491150407818E+04  -0.491156554536E+04
 MD| Kinetic energy [hartree]            0.329756047245E+00   0.375691399994E+00
 MD| Temperature [K]                             878.722360          1001.129279
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.7     0.01924542     -4911.5002921210 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.0     0.03825163     -4911.5415928210 -4.13E-02
     3 Broy./Diag. 0.40E+00   10.0     0.04757208     -4911.4452821815  9.63E-02
     4 Broy./Diag. 0.40E+00    7.6     0.03180272     -4911.5883627510 -1.43E-01
     5 Broy./Diag. 0.40E+00    7.7     0.02065280     -4911.4571440888  1.31E-01
     6 Broy./Diag. 0.40E+00   11.2     0.00891127     -4911.5244354345 -6.73E-02
     7 Broy./Diag. 0.40E+00    7.2     0.00604994     -4911.5127061516  1.17E-02
     8 Broy./Diag. 0.40E+00    6.9     0.00268015     -4911.4967176985  1.60E-02
     9 Broy./Diag. 0.40E+00    7.1     0.00078604     -4911.5025364442 -5.82E-03
    10 Broy./Diag. 0.40E+00    7.0     0.00064860     -4911.5055277143 -2.99E-03
    11 Broy./Diag. 0.40E+00    8.4     0.00052291     -4911.5035148818  2.01E-03
    12 Broy./Diag. 0.40E+00    7.2     0.00060297     -4911.5005977166  2.92E-03
    13 Broy./Diag. 0.40E+00    8.6     0.00032009     -4911.5031968825 -2.60E-03
    14 Broy./Diag. 0.40E+00    8.9     0.00012044     -4911.5029035327  2.93E-04
    15 Broy./Diag. 0.40E+00    7.4     0.00015562     -4911.5023691097  5.34E-04
    16 Broy./Diag. 0.40E+00    9.1     0.00014971     -4911.5024129250 -4.38E-05
    17 Broy./Diag. 0.40E+00    8.8     0.00008721     -4911.5023595986  5.33E-05
    18 Broy./Diag. 0.40E+00    7.0     0.00007207     -4911.5020891126  2.70E-04
    19 Broy./Diag. 0.40E+00    7.2     0.00007626     -4911.5019241708  1.65E-04
    20 Broy./Diag. 0.40E+00    8.1     0.00007783     -4911.5022850845 -3.61E-04
    21 Broy./Diag. 0.40E+00    6.7     0.00004327     -4911.5020170217  2.68E-04
    22 Broy./Diag. 0.40E+00    8.9     0.00004066     -4911.5019357018  8.13E-05
    23 Broy./Diag. 0.40E+00    8.6     0.00003099     -4911.5019709559 -3.53E-05
    24 Broy./Diag. 0.40E+00    7.9     0.00002948     -4911.5020114775 -4.05E-05
    25 Broy./Diag. 0.40E+00   10.5     0.00002562     -4911.5020047183  6.76E-06
    26 Broy./Diag. 0.40E+00    7.2     0.00002721     -4911.5018978605  1.07E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00001977     -4911.5020047445 -1.07E-04
    28 Broy./Diag. 0.40E+00    7.1     0.00001128     -4911.5020012724  3.47E-06
    29 Broy./Diag. 0.40E+00    7.1     0.00001160     -4911.5019787030  2.26E-05
    30 Broy./Diag. 0.40E+00    7.7     0.00000837     -4911.5019561701  2.25E-05
    31 Broy./Diag. 0.40E+00    6.9     0.00000835     -4911.5019667916 -1.06E-05
    32 Broy./Diag. 0.40E+00    7.3     0.00001016     -4911.5019973025 -3.05E-05
    33 Broy./Diag. 0.40E+00    6.9     0.00000842     -4911.5019559243  4.14E-05
    34 Broy./Diag. 0.40E+00    7.8     0.00000409     -4911.5019643683 -8.44E-06
    35 Broy./Diag. 0.40E+00    7.1     0.00000495     -4911.5019705732 -6.20E-06
    36 Broy./Diag. 0.40E+00    6.8     0.00000323     -4911.5019786286 -8.06E-06
    37 Broy./Diag. 0.40E+00    6.7     0.00000312     -4911.5019711826  7.45E-06
    38 Broy./Diag. 0.40E+00    6.8     0.00000389     -4911.5019606012  1.06E-05
    39 Broy./Diag. 0.40E+00    7.1     0.00000337     -4911.5019758846 -1.53E-05
    40 Broy./Diag. 0.40E+00    7.0     0.00000178     -4911.5019698377  6.05E-06
    41 Broy./Diag. 0.40E+00    7.5     0.00000218     -4911.5019687919  1.05E-06
    42 Broy./Diag. 0.40E+00    7.5     0.00000182     -4911.5019652646  3.53E-06
    43 Broy./Diag. 0.40E+00    7.1     0.00000165     -4911.5019687694 -3.50E-06
    44 Broy./Diag. 0.40E+00    7.1     0.00000191     -4911.5019734912 -4.72E-06
    45 Broy./Diag. 0.40E+00    7.3     0.00000163     -4911.5019657918  7.70E-06
    46 Broy./Diag. 0.40E+00    6.8     0.00000100     -4911.5019689135 -3.12E-06

  *** SCF run converged in    46 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008453785511
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2750.07245820608750
  Hartree energy:                                            1781.35960411113456
  Exchange-correlation energy:                               -779.60411870359223
  Electronic entropic energy:                                  -0.23957454497879
  Fermi energy:                                                 0.08722594999504

  Total energy:                                             -4911.50196891353335

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.501967341269847

 MD| ***************************************************************************
 MD| Step number                                                            1114
 MD| Time [fs]                                                       2228.000000
 MD| Conserved quantity [hartree]                            -0.491116907846E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    360.790010           602.862914
 MD| Energy drift per atom [K]           0.312476031799E+03   0.269365552497E+03
 MD| Potential energy [hartree]         -0.491150196734E+04  -0.491156548829E+04
 MD| Kinetic energy [hartree]            0.332888880726E+00   0.375652977625E+00
 MD| Temperature [K]                             887.070625          1001.026892
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.01991042     -4911.4996056446 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.0     0.06007881     -4911.4829199446  1.67E-02
     3 Broy./Diag. 0.40E+00    7.7     0.08785094     -4911.6516094971 -1.69E-01
     4 Broy./Diag. 0.40E+00    7.7     0.05114360     -4911.3821574816  2.69E-01
     5 Broy./Diag. 0.40E+00    6.9     0.01306861     -4911.5184881957 -1.36E-01
     6 Broy./Diag. 0.40E+00    7.2     0.00519706     -4911.4978176311  2.07E-02
     7 Broy./Diag. 0.40E+00    7.2     0.00608494     -4911.5129034759 -1.51E-02
     8 Broy./Diag. 0.40E+00    7.1     0.00303365     -4911.4955432435  1.74E-02
     9 Broy./Diag. 0.40E+00    7.3     0.00075352     -4911.5008877016 -5.34E-03
    10 Broy./Diag. 0.40E+00    7.3     0.00068522     -4911.5063440161 -5.46E-03
    11 Broy./Diag. 0.40E+00    7.1     0.00055981     -4911.5014045688  4.94E-03
    12 Broy./Diag. 0.40E+00    7.3     0.00035142     -4911.5019973161 -5.93E-04
    13 Broy./Diag. 0.40E+00    7.1     0.00020747     -4911.5019165586  8.08E-05
    14 Broy./Diag. 0.40E+00    6.7     0.00015809     -4911.5020480594 -1.32E-04
    15 Broy./Diag. 0.40E+00    7.1     0.00010767     -4911.5016287182  4.19E-04
    16 Broy./Diag. 0.40E+00    6.9     0.00008914     -4911.5016983928 -6.97E-05
    17 Broy./Diag. 0.40E+00    7.1     0.00005097     -4911.5014947199  2.04E-04
    18 Broy./Diag. 0.40E+00    7.1     0.00007796     -4911.5014659363  2.88E-05
    19 Broy./Diag. 0.40E+00    7.1     0.00006145     -4911.5013459439  1.20E-04
    20 Broy./Diag. 0.40E+00    7.1     0.00003107     -4911.5014717725 -1.26E-04
    21 Broy./Diag. 0.40E+00    6.9     0.00002368     -4911.5012861930  1.86E-04
    22 Broy./Diag. 0.40E+00    7.5     0.00001922     -4911.5013531612 -6.70E-05
    23 Broy./Diag. 0.40E+00    7.3     0.00001328     -4911.5013243733  2.88E-05
    24 Broy./Diag. 0.40E+00    7.1     0.00000867     -4911.5013213491  3.02E-06
    25 Broy./Diag. 0.40E+00    6.8     0.00000943     -4911.5013080787  1.33E-05
    26 Broy./Diag. 0.40E+00    6.8     0.00001149     -4911.5013113289 -3.25E-06
    27 Broy./Diag. 0.40E+00    7.3     0.00001049     -4911.5013231177 -1.18E-05
    28 Broy./Diag. 0.40E+00    7.3     0.00000738     -4911.5012869014  3.62E-05
    29 Broy./Diag. 0.40E+00    7.0     0.00000744     -4911.5013168253 -2.99E-05
    30 Broy./Diag. 0.40E+00    7.0     0.00000595     -4911.5013080421  8.78E-06
    31 Broy./Diag. 0.40E+00    7.6     0.00000462     -4911.5013133473 -5.31E-06
    32 Broy./Diag. 0.40E+00    7.7     0.00000667     -4911.5013070406  6.31E-06
    33 Broy./Diag. 0.40E+00    6.9     0.00000814     -4911.5013028764  4.16E-06
    34 Broy./Diag. 0.40E+00    6.7     0.00000449     -4911.5013265792 -2.37E-05
    35 Broy./Diag. 0.40E+00    7.3     0.00000388     -4911.5013093555  1.72E-05
    36 Broy./Diag. 0.40E+00    7.1     0.00000432     -4911.5013180988 -8.74E-06
    37 Broy./Diag. 0.40E+00    6.6     0.00000202     -4911.5013121616  5.94E-06
    38 Broy./Diag. 0.40E+00    6.7     0.00000302     -4911.5013188857 -6.72E-06
    39 Broy./Diag. 0.40E+00    7.4     0.00000438     -4911.5013224179 -3.53E-06
    40 Broy./Diag. 0.40E+00    7.6     0.00000250     -4911.5013114320  1.10E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00000162     -4911.5013208836 -9.45E-06
    42 Broy./Diag. 0.40E+00    6.8     0.00000246     -4911.5013191973  1.69E-06
    43 Broy./Diag. 0.40E+00    6.9     0.00000157     -4911.5013230011 -3.80E-06
    44 Broy./Diag. 0.40E+00    7.0     0.00000120     -4911.5013197402  3.26E-06
    45 Broy./Diag. 0.40E+00    7.2     0.00000210     -4911.5013190116  7.29E-07
    46 Broy./Diag. 0.40E+00    6.8     0.00000130     -4911.5013247945 -5.78E-06
    47 Broy./Diag. 0.40E+00    7.3     0.00000079     -4911.5013212886  3.51E-06

  *** SCF run converged in    47 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008438696288
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2750.07294661104834
  Hartree energy:                                            1781.35963541518868
  Exchange-correlation energy:                               -779.60407439698179
  Electronic entropic energy:                                  -0.23949080778417
  Fermi energy:                                                 0.08721321837395

  Total energy:                                             -4911.50132128862424

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.501325185043243

 MD| ***************************************************************************
 MD| Step number                                                            1115
 MD| Time [fs]                                                       2230.000000
 MD| Conserved quantity [hartree]                            -0.491116577219E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    342.986280           602.629841
 MD| Energy drift per atom [K]           0.319344690453E+03   0.269410376835E+03
 MD| Potential energy [hartree]         -0.491150132519E+04  -0.491156543075E+04
 MD| Kinetic energy [hartree]            0.335552994088E+00   0.375617013514E+00
 MD| Temperature [K]                             894.169861          1000.931056
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.5     0.02290327     -4911.5000055057 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.9     0.09558256     -4911.4691302556  3.09E-02
     3 Broy./Diag. 0.40E+00    7.1     0.11700724     -4911.7375885720 -2.68E-01
     4 Broy./Diag. 0.40E+00    7.5     0.04705824     -4911.3815719261  3.56E-01
     5 Broy./Diag. 0.40E+00    7.3     0.01345963     -4911.5006511998 -1.19E-01
     6 Broy./Diag. 0.40E+00    7.3     0.00492904     -4911.5072569913 -6.61E-03
     7 Broy./Diag. 0.40E+00    7.1     0.00559479     -4911.5107071776 -3.45E-03
     8 Broy./Diag. 0.40E+00    7.6     0.00346797     -4911.4962222514  1.45E-02
     9 Broy./Diag. 0.40E+00    7.3     0.00053525     -4911.5015158804 -5.29E-03
    10 Broy./Diag. 0.40E+00    7.2     0.00044281     -4911.5055260418 -4.01E-03
    11 Broy./Diag. 0.40E+00    6.8     0.00033204     -4911.5022149635  3.31E-03
    12 Broy./Diag. 0.40E+00    7.1     0.00032375     -4911.5022334169 -1.85E-05
    13 Broy./Diag. 0.40E+00    7.3     0.00011538     -4911.5026027838 -3.69E-04
    14 Broy./Diag. 0.40E+00    7.5     0.00011869     -4911.5023119742  2.91E-04
    15 Broy./Diag. 0.40E+00    6.7     0.00009846     -4911.5019570263  3.55E-04
    16 Broy./Diag. 0.40E+00    6.5     0.00006828     -4911.5021507736 -1.94E-04
    17 Broy./Diag. 0.40E+00    7.4     0.00005589     -4911.5017519396  3.99E-04
    18 Broy./Diag. 0.40E+00    7.1     0.00007251     -4911.5018503139 -9.84E-05
    19 Broy./Diag. 0.40E+00    6.9     0.00005667     -4911.5019196086 -6.93E-05
    20 Broy./Diag. 0.40E+00    6.8     0.00002210     -4911.5017384533  1.81E-04
    21 Broy./Diag. 0.40E+00    7.1     0.00001344     -4911.5017593806 -2.09E-05
    22 Broy./Diag. 0.40E+00    7.2     0.00001450     -4911.5017088424  5.05E-05
    23 Broy./Diag. 0.40E+00    7.4     0.00001153     -4911.5017064781  2.36E-06
    24 Broy./Diag. 0.40E+00    7.0     0.00001042     -4911.5016797688  2.67E-05
    25 Broy./Diag. 0.40E+00    7.2     0.00001126     -4911.5017058713 -2.61E-05
    26 Broy./Diag. 0.40E+00    7.3     0.00000609     -4911.5016727900  3.31E-05
    27 Broy./Diag. 0.40E+00    7.1     0.00000339     -4911.5016846493 -1.19E-05
    28 Broy./Diag. 0.40E+00    7.1     0.00000329     -4911.5016752330  9.42E-06
    29 Broy./Diag. 0.40E+00    7.2     0.00000304     -4911.5016893586 -1.41E-05
    30 Broy./Diag. 0.40E+00    7.5     0.00000346     -4911.5016768654  1.25E-05
    31 Broy./Diag. 0.40E+00    7.3     0.00000371     -4911.5016910080 -1.41E-05
    32 Broy./Diag. 0.40E+00    6.9     0.00000239     -4911.5016846977  6.31E-06
    33 Broy./Diag. 0.40E+00    7.3     0.00000150     -4911.5016927832 -8.09E-06
    34 Broy./Diag. 0.40E+00    7.3     0.00000183     -4911.5016891459  3.64E-06
    35 Broy./Diag. 0.40E+00    7.1     0.00000158     -4911.5016997801 -1.06E-05
    36 Broy./Diag. 0.40E+00    6.9     0.00000108     -4911.5016955083  4.27E-06
    37 Broy./Diag. 0.40E+00    7.3     0.00000161     -4911.5017008141 -5.31E-06
    38 Broy./Diag. 0.40E+00    7.1     0.00000118     -4911.5016992613  1.55E-06
    39 Broy./Diag. 0.40E+00    8.0     0.00000064     -4911.5017040773 -4.82E-06

  *** SCF run converged in    39 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008417776430
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2750.06872643343740
  Hartree energy:                                            1781.36200040309768
  Exchange-correlation energy:                               -779.60272076117417
  Electronic entropic energy:                                  -0.23937179855181
  Fermi energy:                                                 0.08719718597245

  Total energy:                                             -4911.50170407728274

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.501702973253487

 MD| ***************************************************************************
 MD| Step number                                                            1116
 MD| Time [fs]                                                       2232.000000
 MD| Conserved quantity [hartree]                            -0.491116511731E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    288.373659           602.348249
 MD| Energy drift per atom [K]           0.320705175274E+03   0.269456339917E+03
 MD| Potential energy [hartree]         -0.491150170297E+04  -0.491156537364E+04
 MD| Kinetic energy [hartree]            0.336585659738E+00   0.375582039183E+00
 MD| Temperature [K]                             896.921673          1000.837858
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.02240679     -4911.5022747539 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.8     0.09644280     -4911.4512601941  5.10E-02
     3 Broy./Diag. 0.40E+00    6.9     0.11226180     -4911.7865938868 -3.35E-01
     4 Broy./Diag. 0.40E+00    6.9     0.04250406     -4911.3930037679  3.94E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01271334     -4911.4881629473 -9.52E-02
     6 Broy./Diag. 0.40E+00    7.5     0.00495431     -4911.5202557606 -3.21E-02
     7 Broy./Diag. 0.40E+00    7.2     0.00286658     -4911.5085511112  1.17E-02
     8 Broy./Diag. 0.40E+00    7.3     0.00242149     -4911.5010858286  7.47E-03
     9 Broy./Diag. 0.40E+00    6.9     0.00053436     -4911.5046330551 -3.55E-03
    10 Broy./Diag. 0.40E+00    6.9     0.00028457     -4911.5067624988 -2.13E-03
    11 Broy./Diag. 0.40E+00    6.9     0.00027610     -4911.5047972068  1.97E-03
    12 Broy./Diag. 0.40E+00    7.2     0.00024434     -4911.5040644913  7.33E-04
    13 Broy./Diag. 0.40E+00    7.1     0.00008066     -4911.5047921780 -7.28E-04
    14 Broy./Diag. 0.40E+00    7.3     0.00006811     -4911.5044680391  3.24E-04
    15 Broy./Diag. 0.40E+00    7.1     0.00006364     -4911.5041189411  3.49E-04
    16 Broy./Diag. 0.40E+00    7.0     0.00004127     -4911.5042914298 -1.72E-04
    17 Broy./Diag. 0.40E+00    7.0     0.00003774     -4911.5040076499  2.84E-04
    18 Broy./Diag. 0.40E+00    7.3     0.00004634     -4911.5039693771  3.83E-05
    19 Broy./Diag. 0.40E+00    6.6     0.00004699     -4911.5040769715 -1.08E-04
    20 Broy./Diag. 0.40E+00    7.3     0.00001896     -4911.5039207875  1.56E-04
    21 Broy./Diag. 0.40E+00    7.1     0.00001109     -4911.5038761045  4.47E-05
    22 Broy./Diag. 0.40E+00    7.0     0.00000823     -4911.5038776009 -1.50E-06
    23 Broy./Diag. 0.40E+00    7.3     0.00000625     -4911.5038809456 -3.34E-06
    24 Broy./Diag. 0.40E+00    6.9     0.00000683     -4911.5038281993  5.27E-05
    25 Broy./Diag. 0.40E+00    7.9     0.00000751     -4911.5038597671 -3.16E-05
    26 Broy./Diag. 0.40E+00    7.5     0.00000441     -4911.5038288601  3.09E-05
    27 Broy./Diag. 0.40E+00    6.8     0.00000274     -4911.5038283755  4.85E-07
    28 Broy./Diag. 0.40E+00    7.7     0.00000234     -4911.5038296447 -1.27E-06
    29 Broy./Diag. 0.40E+00    7.5     0.00000263     -4911.5038388357 -9.19E-06
    30 Broy./Diag. 0.40E+00    6.9     0.00000263     -4911.5038262922  1.25E-05
    31 Broy./Diag. 0.40E+00    6.9     0.00000320     -4911.5038418607 -1.56E-05
    32 Broy./Diag. 0.40E+00    7.2     0.00000168     -4911.5038355455  6.32E-06
    33 Broy./Diag. 0.40E+00    7.5     0.00000120     -4911.5038380575 -2.51E-06
    34 Broy./Diag. 0.40E+00    6.9     0.00000121     -4911.5038418949 -3.84E-06
    35 Broy./Diag. 0.40E+00    6.9     0.00000108     -4911.5038470916 -5.20E-06
    36 Broy./Diag. 0.40E+00    7.3     0.00000078     -4911.5038453984  1.69E-06

  *** SCF run converged in    36 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999974       -0.0000000026
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008393220556
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2750.05882146981912
  Hartree energy:                                            1781.36683135335443
  Exchange-correlation energy:                               -779.59994981902423
  Electronic entropic energy:                                  -0.23920983108621
  Fermi energy:                                                 0.08718117198747

  Total energy:                                             -4911.50384539835431

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.503852521760564

 MD| ***************************************************************************
 MD| Step number                                                            1117
 MD| Time [fs]                                                       2234.000000
 MD| Conserved quantity [hartree]                            -0.491116664528E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    265.250897           602.046461
 MD| Energy drift per atom [K]           0.317530868933E+03   0.269499378886E+03
 MD| Potential energy [hartree]         -0.491150385252E+04  -0.491156531857E+04
 MD| Kinetic energy [hartree]            0.337207237057E+00   0.375547683944E+00
 MD| Temperature [K]                             898.578030          1000.746309
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02632894     -4911.5059439911 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.7     0.11365219     -4911.4443649262  6.16E-02
     3 Broy./Diag. 0.40E+00    7.3     0.12038768     -4911.8240515780 -3.80E-01
     4 Broy./Diag. 0.40E+00    7.3     0.03722044     -4911.4126153534  4.11E-01
     5 Broy./Diag. 0.40E+00    6.7     0.01088504     -4911.4866988522 -7.41E-02
     6 Broy./Diag. 0.40E+00    7.1     0.00516351     -4911.5281731048 -4.15E-02
     7 Broy./Diag. 0.40E+00    7.0     0.00248606     -4911.5090012768  1.92E-02
     8 Broy./Diag. 0.40E+00    7.4     0.00193079     -4911.5115246479 -2.52E-03
     9 Broy./Diag. 0.40E+00    7.3     0.00063959     -4911.5072222154  4.30E-03
    10 Broy./Diag. 0.40E+00    7.2     0.00044319     -4911.5097267709 -2.50E-03
    11 Broy./Diag. 0.40E+00    7.3     0.00023893     -4911.5082660448  1.46E-03
    12 Broy./Diag. 0.40E+00    7.2     0.00019796     -4911.5075038106  7.62E-04
    13 Broy./Diag. 0.40E+00    6.9     0.00008781     -4911.5082716353 -7.68E-04
    14 Broy./Diag. 0.40E+00    7.1     0.00006628     -4911.5077022660  5.69E-04
    15 Broy./Diag. 0.40E+00    7.4     0.00003850     -4911.5079065890 -2.04E-04
    16 Broy./Diag. 0.40E+00    7.7     0.00004477     -4911.5077282381  1.78E-04
    17 Broy./Diag. 0.40E+00    7.5     0.00003276     -4911.5077431904 -1.50E-05
    18 Broy./Diag. 0.40E+00    7.6     0.00003633     -4911.5075699676  1.73E-04
    19 Broy./Diag. 0.40E+00    6.9     0.00001911     -4911.5076853154 -1.15E-04
    20 Broy./Diag. 0.40E+00    7.6     0.00001504     -4911.5075592538  1.26E-04
    21 Broy./Diag. 0.40E+00    7.7     0.00001175     -4911.5075638863 -4.63E-06
    22 Broy./Diag. 0.40E+00    7.3     0.00000806     -4911.5075345331  2.94E-05
    23 Broy./Diag. 0.40E+00    7.7     0.00000818     -4911.5075147079  1.98E-05
    24 Broy./Diag. 0.40E+00    7.3     0.00000872     -4911.5075001438  1.46E-05
    25 Broy./Diag. 0.40E+00    7.2     0.00000653     -4911.5075103905 -1.02E-05
    26 Broy./Diag. 0.40E+00    7.1     0.00000266     -4911.5074837316  2.67E-05
    27 Broy./Diag. 0.40E+00    7.3     0.00000356     -4911.5074874176 -3.69E-06
    28 Broy./Diag. 0.40E+00    7.3     0.00000279     -4911.5074863553  1.06E-06
    29 Broy./Diag. 0.40E+00    7.7     0.00000148     -4911.5074825454  3.81E-06
    30 Broy./Diag. 0.40E+00    7.3     0.00000182     -4911.5074836836 -1.14E-06
    31 Broy./Diag. 0.40E+00    7.0     0.00000122     -4911.5074884982 -4.81E-06
    32 Broy./Diag. 0.40E+00    6.9     0.00000109     -4911.5074846068  3.89E-06
    33 Broy./Diag. 0.40E+00    7.5     0.00000111     -4911.5074909515 -6.34E-06
    34 Broy./Diag. 0.40E+00    7.5     0.00000098     -4911.5074885323  2.42E-06

  *** SCF run converged in    34 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008369484672
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2750.04235444125788
  Hartree energy:                                            1781.37493683447065
  Exchange-correlation energy:                               -779.59540325906733
  Electronic entropic energy:                                  -0.23903773531837
  Fermi energy:                                                 0.08716042383860

  Total energy:                                             -4911.50748853225559

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.507497943979615

 MD| ***************************************************************************
 MD| Step number                                                            1118
 MD| Time [fs]                                                       2236.000000
 MD| Conserved quantity [hartree]                            -0.491116880110E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    255.251397           601.736269
 MD| Energy drift per atom [K]           0.313052246445E+03   0.269538334939E+03
 MD| Potential energy [hartree]         -0.491150749794E+04  -0.491156526685E+04
 MD| Kinetic energy [hartree]            0.338696847773E+00   0.375514722552E+00
 MD| Temperature [K]                             902.547492          1000.658475
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02578514     -4911.5096700838 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.5     0.10747989     -4911.4576580047  5.20E-02
     3 Broy./Diag. 0.40E+00    7.1     0.11979661     -4911.7774913051 -3.20E-01
     4 Broy./Diag. 0.40E+00    7.1     0.04033270     -4911.3953396006  3.82E-01
     5 Broy./Diag. 0.40E+00    7.1     0.00862507     -4911.4948000945 -9.95E-02
     6 Broy./Diag. 0.40E+00    6.6     0.00454209     -4911.5329686263 -3.82E-02
     7 Broy./Diag. 0.40E+00    7.2     0.00317721     -4911.5082269207  2.47E-02
     8 Broy./Diag. 0.40E+00    7.2     0.00213406     -4911.5232651122 -1.50E-02
     9 Broy./Diag. 0.40E+00    7.2     0.00047561     -4911.5112133406  1.21E-02
    10 Broy./Diag. 0.40E+00    8.2     0.00031947     -4911.5111431680  7.02E-05
    11 Broy./Diag. 0.40E+00    6.9     0.00024323     -4911.5119011090 -7.58E-04
    12 Broy./Diag. 0.40E+00    6.9     0.00023255     -4911.5107682221  1.13E-03
    13 Broy./Diag. 0.40E+00    7.2     0.00006428     -4911.5116854064 -9.17E-04
    14 Broy./Diag. 0.40E+00    6.9     0.00005255     -4911.5112159607  4.69E-04
    15 Broy./Diag. 0.40E+00    6.9     0.00004703     -4911.5114260971 -2.10E-04
    16 Broy./Diag. 0.40E+00    7.0     0.00006064     -4911.5113136126  1.12E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00003940     -4911.5113310025 -1.74E-05
    18 Broy./Diag. 0.40E+00    7.3     0.00003145     -4911.5113088588  2.21E-05
    19 Broy./Diag. 0.40E+00    7.5     0.00002916     -4911.5113496621 -4.08E-05
    20 Broy./Diag. 0.40E+00    7.2     0.00000936     -4911.5112668905  8.28E-05
    21 Broy./Diag. 0.40E+00    7.1     0.00001100     -4911.5113487020 -8.18E-05
    22 Broy./Diag. 0.40E+00    7.3     0.00001039     -4911.5112584715  9.02E-05
    23 Broy./Diag. 0.40E+00    7.5     0.00000770     -4911.5112870597 -2.86E-05
    24 Broy./Diag. 0.40E+00    7.1     0.00000625     -4911.5112867788  2.81E-07
    25 Broy./Diag. 0.40E+00    7.3     0.00000874     -4911.5112862189  5.60E-07
    26 Broy./Diag. 0.40E+00    7.7     0.00000429     -4911.5112635237  2.27E-05
    27 Broy./Diag. 0.40E+00    7.1     0.00000367     -4911.5112854938 -2.20E-05
    28 Broy./Diag. 0.40E+00    7.2     0.00000219     -4911.5112613523  2.41E-05
    29 Broy./Diag. 0.40E+00    6.9     0.00000192     -4911.5112725304 -1.12E-05
    30 Broy./Diag. 0.40E+00    7.3     0.00000084     -4911.5112720897  4.41E-07

  *** SCF run converged in    30 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008350791621
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2750.02256120259790
  Hartree energy:                                            1781.38499371648822
  Exchange-correlation energy:                               -779.58962684553103
  Electronic entropic energy:                                  -0.23886117655399
  Fermi energy:                                                 0.08713596035776

  Total energy:                                             -4911.51127208973776

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.511279543065029

 MD| ***************************************************************************
 MD| Step number                                                            1119
 MD| Time [fs]                                                       2238.000000
 MD| Conserved quantity [hartree]                            -0.491118120776E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    224.211699           601.398892
 MD| Energy drift per atom [K]           0.287277838134E+03   0.269554187936E+03
 MD| Potential energy [hartree]         -0.491151127954E+04  -0.491156521860E+04
 MD| Kinetic energy [hartree]            0.330071782519E+00   0.375474112239E+00
 MD| Temperature [K]                             879.563721          1000.550258
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02858685     -4911.5134603806 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.5     0.08116175     -4911.4617793068  5.17E-02
     3 Broy./Diag. 0.40E+00    7.2     0.10332983     -4911.7417846408 -2.80E-01
     4 Broy./Diag. 0.40E+00    6.9     0.04761379     -4911.3652275310  3.77E-01
     5 Broy./Diag. 0.40E+00    7.4     0.00775408     -4911.5025177235 -1.37E-01
     6 Broy./Diag. 0.40E+00    7.0     0.00537746     -4911.5349889561 -3.25E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00461135     -4911.5126880489  2.23E-02
     8 Broy./Diag. 0.40E+00    7.4     0.00319196     -4911.5231421460 -1.05E-02
     9 Broy./Diag. 0.40E+00    7.1     0.00044040     -4911.5159798769  7.16E-03
    10 Broy./Diag. 0.40E+00    8.0     0.00036055     -4911.5138686291  2.11E-03
    11 Broy./Diag. 0.40E+00    7.1     0.00021776     -4911.5155044088 -1.64E-03
    12 Broy./Diag. 0.40E+00   10.2     0.00025000     -4911.5148850215  6.19E-04
    13 Broy./Diag. 0.40E+00    8.0     0.00017193     -4911.5154104508 -5.25E-04
    14 Broy./Diag. 0.40E+00   10.8     0.00009125     -4911.5147191932  6.91E-04
    15 Broy./Diag. 0.40E+00    7.1     0.00005344     -4911.5154149994 -6.96E-04
    16 Broy./Diag. 0.40E+00    6.6     0.00004613     -4911.5150692082  3.46E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00002871     -4911.5151071226 -3.79E-05
    18 Broy./Diag. 0.40E+00    7.3     0.00004085     -4911.5151290434 -2.19E-05
    19 Broy./Diag. 0.40E+00    7.5     0.00004386     -4911.5152182877 -8.92E-05
    20 Broy./Diag. 0.40E+00    8.1     0.00002376     -4911.5151059445  1.12E-04
    21 Broy./Diag. 0.40E+00    7.6     0.00001722     -4911.5151745911 -6.86E-05
    22 Broy./Diag. 0.40E+00   10.0     0.00000927     -4911.5151391875  3.54E-05
    23 Broy./Diag. 0.40E+00    7.3     0.00000663     -4911.5151368394  2.35E-06
    24 Broy./Diag. 0.40E+00    9.7     0.00000534     -4911.5151558924 -1.91E-05
    25 Broy./Diag. 0.40E+00    8.5     0.00000791     -4911.5151642765 -8.38E-06
    26 Broy./Diag. 0.40E+00    7.7     0.00000645     -4911.5151381309  2.61E-05
    27 Broy./Diag. 0.40E+00    6.9     0.00000393     -4911.5151607126 -2.26E-05
    28 Broy./Diag. 0.40E+00    7.5     0.00000226     -4911.5151557095  5.00E-06
    29 Broy./Diag. 0.40E+00    8.2     0.00000177     -4911.5151536128  2.10E-06
    30 Broy./Diag. 0.40E+00    6.9     0.00000159     -4911.5151588870 -5.27E-06
    31 Broy./Diag. 0.40E+00   10.3     0.00000133     -4911.5151653074 -6.42E-06
    32 Broy./Diag. 0.40E+00    7.0     0.00000176     -4911.5151570284  8.28E-06
    33 Broy./Diag. 0.40E+00    8.6     0.00000167     -4911.5151669258 -9.90E-06
    34 Broy./Diag. 0.40E+00    9.2     0.00000103     -4911.5151648490  2.08E-06
    35 Broy./Diag. 0.40E+00    7.1     0.00000091     -4911.5151638661  9.83E-07

  *** SCF run converged in    35 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008335367593
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2750.00323839668908
  Hartree energy:                                            1781.39466412220418
  Exchange-correlation energy:                               -779.58405485089691
  Electronic entropic energy:                                  -0.23867237258654
  Fermi energy:                                                 0.08711689683448

  Total energy:                                             -4911.51516386606727

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.515163999276410

 MD| ***************************************************************************
 MD| Step number                                                            1120
 MD| Time [fs]                                                       2240.000000
 MD| Conserved quantity [hartree]                            -0.491118501550E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    283.243313           601.114825
 MD| Energy drift per atom [K]           0.279367398200E+03   0.269562949731E+03
 MD| Potential energy [hartree]         -0.491151516400E+04  -0.491156517391E+04
 MD| Kinetic energy [hartree]            0.330148501542E+00   0.375433642944E+00
 MD| Temperature [K]                             879.768159          1000.442417
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.03002420     -4911.5174973352 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.04095057     -4911.4877978378  2.97E-02
     3 Broy./Diag. 0.40E+00    6.7     0.06260604     -4911.6566530621 -1.69E-01
     4 Broy./Diag. 0.40E+00    7.1     0.04356844     -4911.3670348457  2.90E-01
     5 Broy./Diag. 0.40E+00    8.0     0.01567929     -4911.5339498533 -1.67E-01
     6 Broy./Diag. 0.40E+00    8.2     0.00612665     -4911.5249770430  8.97E-03
     7 Broy./Diag. 0.40E+00    7.1     0.00443918     -4911.5164557207  8.52E-03
     8 Broy./Diag. 0.40E+00    6.9     0.00316540     -4911.5273134369 -1.09E-02
     9 Broy./Diag. 0.40E+00    7.2     0.00077075     -4911.5211249160  6.19E-03
    10 Broy./Diag. 0.40E+00    7.5     0.00065724     -4911.5181307507  2.99E-03
    11 Broy./Diag. 0.40E+00    7.2     0.00052931     -4911.5175327277  5.98E-04
    12 Broy./Diag. 0.40E+00    7.2     0.00028245     -4911.5204418873 -2.91E-03
    13 Broy./Diag. 0.40E+00    6.9     0.00016532     -4911.5193569489  1.08E-03
    14 Broy./Diag. 0.40E+00    6.5     0.00012457     -4911.5189356562  4.21E-04
    15 Broy./Diag. 0.40E+00    7.4     0.00013973     -4911.5193787626 -4.43E-04
    16 Broy./Diag. 0.40E+00    7.1     0.00013454     -4911.5192378013  1.41E-04
    17 Broy./Diag. 0.40E+00    7.5     0.00005717     -4911.5191362560  1.02E-04
    18 Broy./Diag. 0.40E+00    7.5     0.00003314     -4911.5193350724 -1.99E-04
    19 Broy./Diag. 0.40E+00    7.2     0.00003521     -4911.5193788860 -4.38E-05
    20 Broy./Diag. 0.40E+00    7.3     0.00004053     -4911.5191160252  2.63E-04
    21 Broy./Diag. 0.40E+00    7.5     0.00003279     -4911.5193514404 -2.35E-04
    22 Broy./Diag. 0.40E+00    6.8     0.00001755     -4911.5193082489  4.32E-05
    23 Broy./Diag. 0.40E+00    8.3     0.00000921     -4911.5192841158  2.41E-05
    24 Broy./Diag. 0.40E+00    7.1     0.00000804     -4911.5192978252 -1.37E-05
    25 Broy./Diag. 0.40E+00    7.5     0.00000904     -4911.5193212309 -2.34E-05
    26 Broy./Diag. 0.40E+00    7.7     0.00000667     -4911.5192818222  3.94E-05
    27 Broy./Diag. 0.40E+00    7.1     0.00000289     -4911.5193018440 -2.00E-05
    28 Broy./Diag. 0.40E+00    7.1     0.00000343     -4911.5193159280 -1.41E-05
    29 Broy./Diag. 0.40E+00    7.1     0.00000536     -4911.5193069380  8.99E-06
    30 Broy./Diag. 0.40E+00    7.4     0.00000507     -4911.5193019125  5.03E-06
    31 Broy./Diag. 0.40E+00    7.3     0.00000214     -4911.5193239508 -2.20E-05
    32 Broy./Diag. 0.40E+00    7.1     0.00000166     -4911.5193102931  1.37E-05
    33 Broy./Diag. 0.40E+00    7.4     0.00000179     -4911.5193186350 -8.34E-06
    34 Broy./Diag. 0.40E+00    6.9     0.00000169     -4911.5193227660 -4.13E-06
    35 Broy./Diag. 0.40E+00    7.3     0.00000178     -4911.5193195567  3.21E-06
    36 Broy./Diag. 0.40E+00    7.1     0.00000164     -4911.5193156477  3.91E-06
    37 Broy./Diag. 0.40E+00    6.9     0.00000108     -4911.5193234180 -7.77E-06
    38 Broy./Diag. 0.40E+00    7.3     0.00000091     -4911.5193174287  5.99E-06

  *** SCF run converged in    38 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008323103895
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.98646074475528
  Hartree energy:                                            1781.40268714613921
  Exchange-correlation energy:                               -779.57966614033671
  Electronic entropic energy:                                  -0.23845991565261
  Fermi energy:                                                 0.08710870651437

  Total energy:                                             -4911.51931742870511

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.519316455250191

 MD| ***************************************************************************
 MD| Step number                                                            1121
 MD| Time [fs]                                                       2242.000000
 MD| Conserved quantity [hartree]                            -0.491117210985E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    284.622232           600.832494
 MD| Energy drift per atom [K]           0.306178427688E+03   0.269595612958E+03
 MD| Potential energy [hartree]         -0.491151931646E+04  -0.491156513300E+04
 MD| Kinetic energy [hartree]            0.347206605608E+00   0.375408462714E+00
 MD| Temperature [K]                             925.223997          1000.375318
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.02788425     -4911.5217920296 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.03202452     -4911.5149557957  6.84E-03
     3 Broy./Diag. 0.40E+00    7.1     0.04292031     -4911.5882788991 -7.33E-02
     4 Broy./Diag. 0.40E+00    7.1     0.02534349     -4911.4605238003  1.28E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01110899     -4911.5280413335 -6.75E-02
     6 Broy./Diag. 0.40E+00    7.5     0.00680873     -4911.5294692349 -1.43E-03
     7 Broy./Diag. 0.40E+00    6.9     0.00355754     -4911.5199989539  9.47E-03
     8 Broy./Diag. 0.40E+00    7.1     0.00319805     -4911.5370004308 -1.70E-02
     9 Broy./Diag. 0.40E+00    7.7     0.00108623     -4911.5243796260  1.26E-02
    10 Broy./Diag. 0.40E+00    7.4     0.00060371     -4911.5234865169  8.93E-04
    11 Broy./Diag. 0.40E+00    7.3     0.00048284     -4911.5230592626  4.27E-04
    12 Broy./Diag. 0.40E+00    7.1     0.00047014     -4911.5247683465 -1.71E-03
    13 Broy./Diag. 0.40E+00    7.1     0.00030227     -4911.5243672957  4.01E-04
    14 Broy./Diag. 0.40E+00    6.9     0.00047221     -4911.5224571162  1.91E-03
    15 Broy./Diag. 0.40E+00    6.8     0.00039210     -4911.5243887906 -1.93E-03
    16 Broy./Diag. 0.40E+00    7.1     0.00023074     -4911.5239624815  4.26E-04
    17 Broy./Diag. 0.40E+00    6.9     0.00025779     -4911.5241876401 -2.25E-04
    18 Broy./Diag. 0.40E+00    7.1     0.00020049     -4911.5232374524  9.50E-04
    19 Broy./Diag. 0.40E+00    6.9     0.00012193     -4911.5235900393 -3.53E-04
    20 Broy./Diag. 0.40E+00    7.5     0.00020691     -4911.5242963509 -7.06E-04
    21 Broy./Diag. 0.40E+00    7.5     0.00017635     -4911.5233970013  8.99E-04
    22 Broy./Diag. 0.40E+00    7.0     0.00007785     -4911.5236728864 -2.76E-04
    23 Broy./Diag. 0.40E+00    7.3     0.00011318     -4911.5235740190  9.89E-05
    24 Broy./Diag. 0.40E+00    7.5     0.00008656     -4911.5239987287 -4.25E-04
    25 Broy./Diag. 0.40E+00    7.2     0.00005275     -4911.5237795165  2.19E-04
    26 Broy./Diag. 0.40E+00    7.0     0.00007387     -4911.5234742807  3.05E-04
    27 Broy./Diag. 0.40E+00    6.9     0.00009283     -4911.5238710408 -3.97E-04
    28 Broy./Diag. 0.40E+00    7.3     0.00005116     -4911.5237288185  1.42E-04
    29 Broy./Diag. 0.40E+00    7.0     0.00005754     -4911.5237946543 -6.58E-05
    30 Broy./Diag. 0.40E+00    7.5     0.00005303     -4911.5235662592  2.28E-04
    31 Broy./Diag. 0.40E+00    7.1     0.00003150     -4911.5237047291 -1.38E-04
    32 Broy./Diag. 0.40E+00    7.3     0.00003483     -4911.5238679624 -1.63E-04
    33 Broy./Diag. 0.40E+00    7.6     0.00005002     -4911.5236464010  2.22E-04
    34 Broy./Diag. 0.40E+00    7.1     0.00003088     -4911.5237224425 -7.60E-05
    35 Broy./Diag. 0.40E+00    7.1     0.00002799     -4911.5236926262  2.98E-05
    36 Broy./Diag. 0.40E+00    7.3     0.00002848     -4911.5238070730 -1.14E-04
    37 Broy./Diag. 0.40E+00    7.3     0.00001658     -4911.5237242573  8.28E-05
    38 Broy./Diag. 0.40E+00    7.1     0.00001538     -4911.5236555536  6.87E-05
    39 Broy./Diag. 0.40E+00    7.1     0.00002759     -4911.5237678910 -1.12E-04
    40 Broy./Diag. 0.40E+00    7.1     0.00002188     -4911.5237230653  4.48E-05
    41 Broy./Diag. 0.40E+00    7.4     0.00001344     -4911.5237426396 -1.96E-05
    42 Broy./Diag. 0.40E+00    7.8     0.00001490     -4911.5236888628  5.38E-05
    43 Broy./Diag. 0.40E+00    6.9     0.00000943     -4911.5237334279 -4.46E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00000793     -4911.5237631843 -2.98E-05
    45 Broy./Diag. 0.40E+00    7.5     0.00001006     -4911.5237042279  5.90E-05
    46 Broy./Diag. 0.40E+00    7.2     0.00001064     -4911.5237293501 -2.51E-05
    47 Broy./Diag. 0.40E+00    7.2     0.00000807     -4911.5237198256  9.52E-06
    48 Broy./Diag. 0.40E+00    7.3     0.00000834     -4911.5237506351 -3.08E-05
    49 Broy./Diag. 0.40E+00    7.6     0.00000591     -4911.5237221398  2.85E-05
    50 Broy./Diag. 0.40E+00    8.0     0.00000528     -4911.5237085059  1.36E-05
    51 Broy./Diag. 0.40E+00    7.3     0.00000576     -4911.5237469875 -3.85E-05
    52 Broy./Diag. 0.40E+00    7.2     0.00000591     -4911.5237292107  1.78E-05
    53 Broy./Diag. 0.40E+00    7.1     0.00000388     -4911.5237348457 -5.63E-06
    54 Broy./Diag. 0.40E+00    7.0     0.00000392     -4911.5237212925  1.36E-05
    55 Broy./Diag. 0.40E+00    7.1     0.00000301     -4911.5237351327 -1.38E-05
    56 Broy./Diag. 0.40E+00    7.2     0.00000275     -4911.5237395950 -4.46E-06
    57 Broy./Diag. 0.40E+00    7.0     0.00000287     -4911.5237207813  1.88E-05
    58 Broy./Diag. 0.40E+00    7.4     0.00000341     -4911.5237322990 -1.15E-05
    59 Broy./Diag. 0.40E+00    7.2     0.00000267     -4911.5237291567  3.14E-06
    60 Broy./Diag. 0.40E+00    7.3     0.00000246     -4911.5237380402 -8.88E-06
    61 Broy./Diag. 0.40E+00    7.1     0.00000172     -4911.5237291904  8.85E-06
    62 Broy./Diag. 0.40E+00    7.1     0.00000142     -4911.5237277425  1.45E-06
    63 Broy./Diag. 0.40E+00    7.1     0.00000158     -4911.5237372344 -9.49E-06
    64 Broy./Diag. 0.40E+00    6.9     0.00000151     -4911.5237305408  6.69E-06
    65 Broy./Diag. 0.40E+00    6.9     0.00000115     -4911.5237325380 -2.00E-06
    66 Broy./Diag. 0.40E+00    7.9     0.00000150     -4911.5237293060  3.23E-06
    67 Broy./Diag. 0.40E+00    7.7     0.00000117     -4911.5237344610 -5.15E-06
    68 Broy./Diag. 0.40E+00    6.9     0.00000087     -4911.5237344930 -3.20E-08

  *** SCF run converged in    68 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008313118676
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.97098411428806
  Hartree energy:                                            1781.40988021370049
  Exchange-correlation energy:                               -779.57605253636393
  Electronic entropic energy:                                  -0.23820687335739
  Fermi energy:                                                 0.08710925502791

  Total energy:                                             -4911.52373449297102

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.523733513379739

 MD| ***************************************************************************
 MD| Step number                                                            1122
 MD| Time [fs]                                                       2244.000000
 MD| Conserved quantity [hartree]                            -0.491116756221E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    498.954171           600.741693
 MD| Energy drift per atom [K]           0.315625994206E+03   0.269636638254E+03
 MD| Potential energy [hartree]         -0.491152373351E+04  -0.491156509611E+04
 MD| Kinetic energy [hartree]            0.356171305926E+00   0.375391317298E+00
 MD| Temperature [K]                             949.112816          1000.329629
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.02301492     -4911.5256609948 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.8     0.05252246     -4911.5186733353  6.99E-03
     3 Broy./Diag. 0.40E+00    6.9     0.05827488     -4911.5834705570 -6.48E-02
     4 Broy./Diag. 0.40E+00    7.0     0.02545424     -4911.4804432655  1.03E-01
     5 Broy./Diag. 0.40E+00    7.3     0.01070132     -4911.5290840358 -4.86E-02
     6 Broy./Diag. 0.40E+00    7.5     0.00656204     -4911.5328152040 -3.73E-03
     7 Broy./Diag. 0.40E+00    6.9     0.00314309     -4911.5282608572  4.55E-03
     8 Broy./Diag. 0.40E+00    7.1     0.00297527     -4911.5244872727  3.77E-03
     9 Broy./Diag. 0.40E+00    7.1     0.00132823     -4911.5309872872 -6.50E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00079241     -4911.5259925786  4.99E-03
    11 Broy./Diag. 0.40E+00    7.1     0.00046141     -4911.5270438228 -1.05E-03
    12 Broy./Diag. 0.40E+00    7.1     0.00039185     -4911.5291020083 -2.06E-03
    13 Broy./Diag. 0.40E+00    7.0     0.00031680     -4911.5286156632  4.86E-04
    14 Broy./Diag. 0.40E+00    6.7     0.00049328     -4911.5277037095  9.12E-04
    15 Broy./Diag. 0.40E+00    7.0     0.00046237     -4911.5266974606  1.01E-03
    16 Broy./Diag. 0.40E+00    7.2     0.00030245     -4911.5283515952 -1.65E-03
    17 Broy./Diag. 0.40E+00    6.9     0.00030299     -4911.5281016843  2.50E-04
    18 Broy./Diag. 0.40E+00    7.2     0.00017850     -4911.5269989223  1.10E-03
    19 Broy./Diag. 0.40E+00    7.2     0.00013138     -4911.5275320958 -5.33E-04
    20 Broy./Diag. 0.40E+00    7.5     0.00017257     -4911.5279383827 -4.06E-04
    21 Broy./Diag. 0.40E+00    7.1     0.00017911     -4911.5281976795 -2.59E-04
    22 Broy./Diag. 0.40E+00    7.1     0.00007873     -4911.5274858517  7.12E-04
    23 Broy./Diag. 0.40E+00    7.0     0.00009506     -4911.5275850806 -9.92E-05
    24 Broy./Diag. 0.40E+00    7.1     0.00007062     -4911.5279322090 -3.47E-04
    25 Broy./Diag. 0.40E+00    7.4     0.00006312     -4911.5277008436  2.31E-04
    26 Broy./Diag. 0.40E+00    7.2     0.00007426     -4911.5275106818  1.90E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00012204     -4911.5275040957  6.59E-06
    28 Broy./Diag. 0.40E+00    7.3     0.00007666     -4911.5279890127 -4.85E-04
    29 Broy./Diag. 0.40E+00    7.3     0.00006379     -4911.5278318849  1.57E-04
    30 Broy./Diag. 0.40E+00    7.1     0.00003992     -4911.5275813310  2.51E-04
    31 Broy./Diag. 0.40E+00    7.1     0.00002587     -4911.5277008382 -1.20E-04
    32 Broy./Diag. 0.40E+00    6.9     0.00002513     -4911.5277683739 -6.75E-05
    33 Broy./Diag. 0.40E+00    6.9     0.00005205     -4911.5277460941  2.23E-05
    34 Broy./Diag. 0.40E+00    6.8     0.00003798     -4911.5275422967  2.04E-04
    35 Broy./Diag. 0.40E+00    7.4     0.00003105     -4911.5276617145 -1.19E-04
    36 Broy./Diag. 0.40E+00    7.1     0.00002669     -4911.5277775716 -1.16E-04
    37 Broy./Diag. 0.40E+00    7.2     0.00001750     -4911.5276912670  8.63E-05
    38 Broy./Diag. 0.40E+00    7.4     0.00001554     -4911.5276505543  4.07E-05
    39 Broy./Diag. 0.40E+00    7.0     0.00002444     -4911.5276633041 -1.27E-05
    40 Broy./Diag. 0.40E+00    7.3     0.00001994     -4911.5277569745 -9.37E-05
    41 Broy./Diag. 0.40E+00    6.9     0.00001196     -4911.5276940197  6.30E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00000981     -4911.5276571138  3.69E-05
    43 Broy./Diag. 0.40E+00    7.1     0.00000784     -4911.5276933569 -3.62E-05
    44 Broy./Diag. 0.40E+00    6.6     0.00000924     -4911.5277090422 -1.57E-05
    45 Broy./Diag. 0.40E+00    7.7     0.00001389     -4911.5276993016  9.74E-06
    46 Broy./Diag. 0.40E+00    7.3     0.00001374     -4911.5276510805  4.82E-05
    47 Broy./Diag. 0.40E+00    7.3     0.00000999     -4911.5276957709 -4.47E-05
    48 Broy./Diag. 0.40E+00    7.1     0.00000686     -4911.5277204596 -2.47E-05
    49 Broy./Diag. 0.40E+00    6.9     0.00000406     -4911.5276921623  2.83E-05
    50 Broy./Diag. 0.40E+00    7.0     0.00000387     -4911.5276858244  6.34E-06
    51 Broy./Diag. 0.40E+00    7.2     0.00000496     -4911.5276896274 -3.80E-06
    52 Broy./Diag. 0.40E+00    7.1     0.00000625     -4911.5277055013 -1.59E-05
    53 Broy./Diag. 0.40E+00    7.7     0.00000483     -4911.5276857775  1.97E-05
    54 Broy./Diag. 0.40E+00    6.9     0.00000389     -4911.5276806964  5.08E-06
    55 Broy./Diag. 0.40E+00    7.0     0.00000292     -4911.5276967783 -1.61E-05
    56 Broy./Diag. 0.40E+00    7.5     0.00000268     -4911.5276993450 -2.57E-06
    57 Broy./Diag. 0.40E+00    7.4     0.00000334     -4911.5276953657  3.98E-06
    58 Broy./Diag. 0.40E+00    7.5     0.00000301     -4911.5276849674  1.04E-05
    59 Broy./Diag. 0.40E+00    7.3     0.00000230     -4911.5276952533 -1.03E-05
    60 Broy./Diag. 0.40E+00    7.2     0.00000175     -4911.5276971027 -1.85E-06
    61 Broy./Diag. 0.40E+00    7.1     0.00000119     -4911.5276904433  6.66E-06
    62 Broy./Diag. 0.40E+00    7.3     0.00000120     -4911.5276909796 -5.36E-07
    63 Broy./Diag. 0.40E+00    7.3     0.00000214     -4911.5276932379 -2.26E-06
    64 Broy./Diag. 0.40E+00    7.9     0.00000222     -4911.5276991435 -5.91E-06
    65 Broy./Diag. 0.40E+00    7.5     0.00000156     -4911.5276913499  7.79E-06
    66 Broy./Diag. 0.40E+00    7.1     0.00000133     -4911.5276912822  6.77E-08
    67 Broy./Diag. 0.40E+00    7.1     0.00000088     -4911.5276959331 -4.65E-06

  *** SCF run converged in    67 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008305944733
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.95738629823472
  Hartree energy:                                            1781.41595367013042
  Exchange-correlation energy:                               -779.57277882667881
  Electronic entropic energy:                                  -0.23791762236324
  Fermi energy:                                                 0.08711691625250

  Total energy:                                             -4911.52769593309313

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.527694483643245

 MD| ***************************************************************************
 MD| Step number                                                            1123
 MD| Time [fs]                                                       2246.000000
 MD| Conserved quantity [hartree]                            -0.491116136155E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    487.562022           600.640910
 MD| Energy drift per atom [K]           0.328507631984E+03   0.269689061222E+03
 MD| Potential energy [hartree]         -0.491152769448E+04  -0.491156506280E+04
 MD| Kinetic energy [hartree]            0.366332928951E+00   0.375383251058E+00
 MD| Temperature [K]                             976.191153          1000.308134
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02002791     -4911.5279711159 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.06290993     -4911.5378973771 -9.93E-03
     3 Broy./Diag. 0.40E+00    7.1     0.06912169     -4911.5152640544  2.26E-02
     4 Broy./Diag. 0.40E+00    6.9     0.02755490     -4911.5283235073 -1.31E-02
     5 Broy./Diag. 0.40E+00    7.3     0.01236790     -4911.5212752076  7.05E-03
     6 Broy./Diag. 0.40E+00    7.1     0.01104085     -4911.5507388755 -2.95E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00635447     -4911.5227590082  2.80E-02
     8 Broy./Diag. 0.40E+00    6.8     0.00332021     -4911.5371192922 -1.44E-02
     9 Broy./Diag. 0.40E+00    7.1     0.00116175     -4911.5310164806  6.10E-03
    10 Broy./Diag. 0.40E+00    7.6     0.00094891     -4911.5296530821  1.36E-03
    11 Broy./Diag. 0.40E+00    7.3     0.00049935     -4911.5296380510  1.50E-05
    12 Broy./Diag. 0.40E+00    6.9     0.00064943     -4911.5298027162 -1.65E-04
    13 Broy./Diag. 0.40E+00    7.9     0.00055942     -4911.5313357465 -1.53E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00042296     -4911.5294925793  1.84E-03
    15 Broy./Diag. 0.40E+00    6.9     0.00027962     -4911.5299771623 -4.85E-04
    16 Broy./Diag. 0.40E+00    7.2     0.00030746     -4911.5299794490 -2.29E-06
    17 Broy./Diag. 0.40E+00    7.2     0.00024477     -4911.5303310291 -3.52E-04
    18 Broy./Diag. 0.40E+00    7.2     0.00030180     -4911.5299627935  3.68E-04
    19 Broy./Diag. 0.40E+00    7.1     0.00025095     -4911.5292940692  6.69E-04
    20 Broy./Diag. 0.40E+00    6.8     0.00015857     -4911.5302266537 -9.33E-04
    21 Broy./Diag. 0.40E+00    6.7     0.00011889     -4911.5300427854  1.84E-04
    22 Broy./Diag. 0.40E+00    6.9     0.00009130     -4911.5300026976  4.01E-05
    23 Broy./Diag. 0.40E+00    7.0     0.00006832     -4911.5298353914  1.67E-04
    24 Broy./Diag. 0.40E+00    7.2     0.00008026     -4911.5300107663 -1.75E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00011131     -4911.5301768203 -1.66E-04
    26 Broy./Diag. 0.40E+00    7.3     0.00007531     -4911.5297455497  4.31E-04
    27 Broy./Diag. 0.40E+00    7.0     0.00006732     -4911.5299189803 -1.73E-04
    28 Broy./Diag. 0.40E+00    6.8     0.00007930     -4911.5299618165 -4.28E-05
    29 Broy./Diag. 0.40E+00    7.3     0.00005268     -4911.5301253947 -1.64E-04
    30 Broy./Diag. 0.40E+00    7.7     0.00004268     -4911.5299609457  1.64E-04
    31 Broy./Diag. 0.40E+00    7.2     0.00004183     -4911.5298700162  9.09E-05
    32 Broy./Diag. 0.40E+00    6.7     0.00002521     -4911.5300429758 -1.73E-04
    33 Broy./Diag. 0.40E+00    7.1     0.00002197     -4911.5299917792  5.12E-05
    34 Broy./Diag. 0.40E+00    6.9     0.00002669     -4911.5299785632  1.32E-05
    35 Broy./Diag. 0.40E+00    7.3     0.00002361     -4911.5299424242  3.61E-05
    36 Broy./Diag. 0.40E+00    7.0     0.00002558     -4911.5300274420 -8.50E-05
    37 Broy./Diag. 0.40E+00    6.9     0.00003064     -4911.5300716167 -4.42E-05
    38 Broy./Diag. 0.40E+00    7.0     0.00002041     -4911.5299461942  1.25E-04
    39 Broy./Diag. 0.40E+00    7.4     0.00001119     -4911.5299875411 -4.13E-05
    40 Broy./Diag. 0.40E+00    7.0     0.00001517     -4911.5300002652 -1.27E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00000939     -4911.5300255725 -2.53E-05
    42 Broy./Diag. 0.40E+00    6.9     0.00000885     -4911.5299933411  3.22E-05
    43 Broy./Diag. 0.40E+00    7.3     0.00001026     -4911.5299814616  1.19E-05
    44 Broy./Diag. 0.40E+00    8.6     0.00001058     -4911.5300275371 -4.61E-05
    45 Broy./Diag. 0.40E+00    6.8     0.00000750     -4911.5300077243  1.98E-05
    46 Broy./Diag. 0.40E+00    8.8     0.00001034     -4911.5300045571  3.17E-06
    47 Broy./Diag. 0.40E+00    9.4     0.00000804     -4911.5299871746  1.74E-05
    48 Broy./Diag. 0.40E+00    7.3     0.00000601     -4911.5300157702 -2.86E-05
    49 Broy./Diag. 0.40E+00    8.1     0.00000571     -4911.5300236526 -7.88E-06
    50 Broy./Diag. 0.40E+00    9.7     0.00000361     -4911.5299996789  2.40E-05
    51 Broy./Diag. 0.40E+00    7.1     0.00000232     -4911.5300076685 -7.99E-06
    52 Broy./Diag. 0.40E+00    7.1     0.00000383     -4911.5300104932 -2.82E-06
    53 Broy./Diag. 0.40E+00    7.2     0.00000361     -4911.5300172008 -6.71E-06
    54 Broy./Diag. 0.40E+00    7.1     0.00000298     -4911.5300062404  1.10E-05
    55 Broy./Diag. 0.40E+00    7.8     0.00000410     -4911.5300040651  2.18E-06
    56 Broy./Diag. 0.40E+00    7.5     0.00000307     -4911.5300204621 -1.64E-05
    57 Broy./Diag. 0.40E+00   10.0     0.00000197     -4911.5300138585  6.60E-06
    58 Broy./Diag. 0.40E+00    7.4     0.00000195     -4911.5300121442  1.71E-06
    59 Broy./Diag. 0.40E+00    8.7     0.00000172     -4911.5300093934  2.75E-06
    60 Broy./Diag. 0.40E+00    9.3     0.00000096     -4911.5300148056 -5.41E-06

  *** SCF run converged in    60 steps ***


  Electronic density on regular grids:      -1631.9999999995        0.0000000005
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008304005323
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.94536934188363
  Hartree energy:                                            1781.42167478293163
  Exchange-correlation energy:                               -779.56908114128566
  Electronic entropic energy:                                  -0.23763833391212
  Fermi energy:                                                 0.08712277818653

  Total energy:                                             -4911.53001480563398

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.530015523730071

 MD| ***************************************************************************
 MD| Step number                                                            1124
 MD| Time [fs]                                                       2248.000000
 MD| Conserved quantity [hartree]                            -0.491114727055E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    451.552977           600.508270
 MD| Energy drift per atom [K]           0.357781189401E+03   0.269767435002E+03
 MD| Potential energy [hartree]         -0.491153001552E+04  -0.491156503162E+04
 MD| Kinetic energy [hartree]            0.382744969555E+00   0.375389800629E+00
 MD| Temperature [K]                            1019.925384          1000.325588
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                932
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.6     0.02786308     -4911.5288571286 -4.91E+03
     2 Broy./Diag. 0.40E+00    8.4     0.08665042     -4911.5463340327 -1.75E-02
     3 Broy./Diag. 0.40E+00    7.2     0.08417585     -4911.4775661960  6.88E-02
     4 Broy./Diag. 0.40E+00    8.5     0.02617960     -4911.5368333475 -5.93E-02
     5 Broy./Diag. 0.40E+00    7.2     0.01197019     -4911.5302285532  6.60E-03
     6 Broy./Diag. 0.40E+00    9.2     0.00750031     -4911.5328962561 -2.67E-03
     7 Broy./Diag. 0.40E+00    6.6     0.00741751     -4911.5240080844  8.89E-03
     8 Broy./Diag. 0.40E+00   10.4     0.00455879     -4911.5431886403 -1.92E-02
     9 Broy./Diag. 0.40E+00    8.9     0.00093290     -4911.5309291623  1.23E-02
    10 Broy./Diag. 0.40E+00    6.8     0.00090110     -4911.5302628687  6.66E-04
    11 Broy./Diag. 0.40E+00    7.1     0.00061653     -4911.5305986545 -3.36E-04
    12 Broy./Diag. 0.40E+00    6.8     0.00048469     -4911.5307073443 -1.09E-04
    13 Broy./Diag. 0.40E+00    6.6     0.00054325     -4911.5311479632 -4.41E-04
    14 Broy./Diag. 0.40E+00    6.5     0.00063321     -4911.5299062525  1.24E-03
    15 Broy./Diag. 0.40E+00    7.3     0.00035136     -4911.5312656975 -1.36E-03
    16 Broy./Diag. 0.40E+00    7.8     0.00029858     -4911.5306160258  6.50E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00030721     -4911.5309311705 -3.15E-04
    18 Broy./Diag. 0.40E+00    7.5     0.00023535     -4911.5307834040  1.48E-04
    19 Broy./Diag. 0.40E+00    6.9     0.00021231     -4911.5304101798  3.73E-04
    20 Broy./Diag. 0.40E+00    7.2     0.00022669     -4911.5309383224 -5.28E-04
    21 Broy./Diag. 0.40E+00    7.1     0.00015933     -4911.5305165976  4.22E-04
    22 Broy./Diag. 0.40E+00    7.7     0.00008436     -4911.5308431658 -3.27E-04
    23 Broy./Diag. 0.40E+00    6.9     0.00008251     -4911.5306482484  1.95E-04
    24 Broy./Diag. 0.40E+00    7.2     0.00006626     -4911.5307541805 -1.06E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00009703     -4911.5308857722 -1.32E-04
    26 Broy./Diag. 0.40E+00    7.3     0.00010470     -4911.5306228995  2.63E-04
    27 Broy./Diag. 0.40E+00    7.5     0.00009516     -4911.5308257507 -2.03E-04
    28 Broy./Diag. 0.40E+00    7.3     0.00006737     -4911.5306465394  1.79E-04
    29 Broy./Diag. 0.40E+00    7.5     0.00006305     -4911.5308909582 -2.44E-04
    30 Broy./Diag. 0.40E+00    6.9     0.00004207     -4911.5307845007  1.06E-04
    31 Broy./Diag. 0.40E+00    6.6     0.00003747     -4911.5306964701  8.80E-05
    32 Broy./Diag. 0.40E+00    7.3     0.00003311     -4911.5308151440 -1.19E-04
    33 Broy./Diag. 0.40E+00    7.9     0.00003644     -4911.5307765272  3.86E-05
    34 Broy./Diag. 0.40E+00    7.1     0.00002490     -4911.5308432960 -6.68E-05
    35 Broy./Diag. 0.40E+00    7.1     0.00002788     -4911.5307522185  9.11E-05
    36 Broy./Diag. 0.40E+00    6.9     0.00002660     -4911.5308187421 -6.65E-05
    37 Broy./Diag. 0.40E+00    7.1     0.00002739     -4911.5308730971 -5.44E-05
    38 Broy./Diag. 0.40E+00    6.7     0.00002471     -4911.5307879436  8.52E-05
    39 Broy./Diag. 0.40E+00    7.0     0.00001901     -4911.5308161635 -2.82E-05
    40 Broy./Diag. 0.40E+00    7.1     0.00001269     -4911.5307873192  2.88E-05
    41 Broy./Diag. 0.40E+00    7.3     0.00000978     -4911.5308430766 -5.58E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00000952     -4911.5308189800  2.41E-05
    43 Broy./Diag. 0.40E+00    7.3     0.00000879     -4911.5308008172  1.82E-05
    44 Broy./Diag. 0.40E+00    7.3     0.00001324     -4911.5308367810 -3.60E-05
    45 Broy./Diag. 0.40E+00    7.5     0.00001302     -4911.5308246600  1.21E-05
    46 Broy./Diag. 0.40E+00    7.1     0.00000962     -4911.5308458129 -2.12E-05
    47 Broy./Diag. 0.40E+00    6.9     0.00000792     -4911.5308013939  4.44E-05
    48 Broy./Diag. 0.40E+00    6.7     0.00000641     -4911.5308272365 -2.58E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00000486     -4911.5308418615 -1.46E-05
    50 Broy./Diag. 0.40E+00    6.8     0.00000461     -4911.5308244834  1.74E-05
    51 Broy./Diag. 0.40E+00    6.8     0.00000383     -4911.5308288173 -4.33E-06
    52 Broy./Diag. 0.40E+00    6.9     0.00000371     -4911.5308273472  1.47E-06
    53 Broy./Diag. 0.40E+00    7.1     0.00000368     -4911.5308447882 -1.74E-05
    54 Broy./Diag. 0.40E+00    7.3     0.00000338     -4911.5308325764  1.22E-05
    55 Broy./Diag. 0.40E+00    7.3     0.00000333     -4911.5308261895  6.39E-06
    56 Broy./Diag. 0.40E+00    6.9     0.00000371     -4911.5308386178 -1.24E-05
    57 Broy./Diag. 0.40E+00    7.5     0.00000325     -4911.5308367805  1.84E-06
    58 Broy./Diag. 0.40E+00    7.1     0.00000179     -4911.5308390542 -2.27E-06
    59 Broy./Diag. 0.40E+00    7.0     0.00000157     -4911.5308308466  8.21E-06
    60 Broy./Diag. 0.40E+00    7.3     0.00000117     -4911.5308370090 -6.16E-06
    61 Broy./Diag. 0.40E+00    6.9     0.00000138     -4911.5308395824 -2.57E-06
    62 Broy./Diag. 0.40E+00    7.5     0.00000140     -4911.5308348938  4.69E-06
    63 Broy./Diag. 0.40E+00    6.9     0.00000181     -4911.5308368501 -1.96E-06
    64 Broy./Diag. 0.40E+00    7.3     0.00000145     -4911.5308356434  1.21E-06
    65 Broy./Diag. 0.40E+00    7.5     0.00000131     -4911.5308425427 -6.90E-06
    66 Broy./Diag. 0.40E+00    7.0     0.00000094     -4911.5308372506  5.29E-06

  *** SCF run converged in    66 steps ***


  Electronic density on regular grids:      -1631.9999999995        0.0000000005
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008307843195
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.93798249876954
  Hartree energy:                                            1781.42519944741912
  Exchange-correlation energy:                               -779.56625272078668
  Electronic entropic energy:                                  -0.23742702725406
  Fermi energy:                                                 0.08713253974767

  Total energy:                                             -4911.53083725062152

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.530840249772154

 MD| ***************************************************************************
 MD| Step number                                                            1125
 MD| Time [fs]                                                       2250.000000
 MD| Conserved quantity [hartree]                            -0.491115359694E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    488.539045           600.408741
 MD| Energy drift per atom [K]           0.344638344400E+03   0.269833986921E+03
 MD| Potential energy [hartree]         -0.491153084025E+04  -0.491156500123E+04
 MD| Kinetic energy [hartree]            0.377243309190E+00   0.375391448192E+00
 MD| Temperature [K]                            1005.264752          1000.329978
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                932
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02998711     -4911.5291987813 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.09221094     -4911.5696480411 -4.04E-02
     3 Broy./Diag. 0.40E+00    6.8     0.08504838     -4911.3970877542  1.73E-01
     4 Broy./Diag. 0.40E+00    7.5     0.03286734     -4911.5875720996 -1.90E-01
     5 Broy./Diag. 0.40E+00    7.3     0.02132789     -4911.5047982932  8.28E-02
     6 Broy./Diag. 0.40E+00    7.5     0.00890096     -4911.5427787655 -3.80E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00562547     -4911.5249680498  1.78E-02
     8 Broy./Diag. 0.40E+00    7.1     0.00281685     -4911.5368894147 -1.19E-02
     9 Broy./Diag. 0.40E+00    7.5     0.00076905     -4911.5317878498  5.10E-03
    10 Broy./Diag. 0.40E+00    7.3     0.00064513     -4911.5300882055  1.70E-03
    11 Broy./Diag. 0.40E+00    7.3     0.00073232     -4911.5314582591 -1.37E-03
    12 Broy./Diag. 0.40E+00    7.3     0.00077745     -4911.5301955434  1.26E-03
    13 Broy./Diag. 0.40E+00    7.1     0.00029383     -4911.5316649328 -1.47E-03
    14 Broy./Diag. 0.40E+00    7.7     0.00012744     -4911.5309099046  7.55E-04
    15 Broy./Diag. 0.40E+00    6.7     0.00012177     -4911.5309936704 -8.38E-05
    16 Broy./Diag. 0.40E+00    7.1     0.00010801     -4911.5312435106 -2.50E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00008299     -4911.5309892411  2.54E-04
    18 Broy./Diag. 0.40E+00    7.3     0.00012642     -4911.5308170278  1.72E-04
    19 Broy./Diag. 0.40E+00    6.9     0.00008020     -4911.5312536781 -4.37E-04
    20 Broy./Diag. 0.40E+00    6.9     0.00002804     -4911.5310752904  1.78E-04
    21 Broy./Diag. 0.40E+00    7.5     0.00002262     -4911.5310353590  3.99E-05
    22 Broy./Diag. 0.40E+00    7.3     0.00001808     -4911.5311322782 -9.69E-05
    23 Broy./Diag. 0.40E+00    6.7     0.00001593     -4911.5310977656  3.45E-05
    24 Broy./Diag. 0.40E+00    7.6     0.00001313     -4911.5310747570  2.30E-05
    25 Broy./Diag. 0.40E+00    6.7     0.00000693     -4911.5311270520 -5.23E-05
    26 Broy./Diag. 0.40E+00    7.0     0.00000790     -4911.5311272287 -1.77E-07
    27 Broy./Diag. 0.40E+00    6.5     0.00000819     -4911.5311109901  1.62E-05
    28 Broy./Diag. 0.40E+00    6.7     0.00000885     -4911.5311241192 -1.31E-05
    29 Broy./Diag. 0.40E+00    7.3     0.00000685     -4911.5311491674 -2.50E-05
    30 Broy./Diag. 0.40E+00    7.1     0.00000471     -4911.5311154159  3.38E-05
    31 Broy./Diag. 0.40E+00    6.9     0.00000280     -4911.5311430997 -2.77E-05
    32 Broy./Diag. 0.40E+00    7.7     0.00000363     -4911.5311432563 -1.57E-07
    33 Broy./Diag. 0.40E+00    7.7     0.00000421     -4911.5311383625  4.89E-06
    34 Broy./Diag. 0.40E+00    7.1     0.00000283     -4911.5311371283  1.23E-06
    35 Broy./Diag. 0.40E+00    6.8     0.00000177     -4911.5311477372 -1.06E-05
    36 Broy./Diag. 0.40E+00    7.3     0.00000240     -4911.5311398387  7.90E-06
    37 Broy./Diag. 0.40E+00    6.6     0.00000273     -4911.5311353819  4.46E-06
    38 Broy./Diag. 0.40E+00    7.3     0.00000194     -4911.5311464036 -1.10E-05
    39 Broy./Diag. 0.40E+00    6.9     0.00000127     -4911.5311390148  7.39E-06
    40 Broy./Diag. 0.40E+00    7.5     0.00000146     -4911.5311379170  1.10E-06
    41 Broy./Diag. 0.40E+00    7.1     0.00000097     -4911.5311379083  8.71E-09

  *** SCF run converged in    41 steps ***


  Electronic density on regular grids:      -1631.9999999995        0.0000000005
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008315619941
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.93689201350253
  Hartree energy:                                            1781.42479811889052
  Exchange-correlation energy:                               -779.56523765571740
  Electronic entropic energy:                                  -0.23725104550148
  Fermi energy:                                                 0.08715878824093

  Total energy:                                             -4911.53113790831412

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.531134367204686

 MD| ***************************************************************************
 MD| Step number                                                            1126
 MD| Time [fs]                                                       2252.000000
 MD| Conserved quantity [hartree]                            -0.491115271577E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    301.936911           600.143669
 MD| Energy drift per atom [K]           0.346468947209E+03   0.269902046388E+03
 MD| Potential energy [hartree]         -0.491153113437E+04  -0.491156497115E+04
 MD| Kinetic energy [hartree]            0.378418598145E+00   0.375394136603E+00
 MD| Temperature [K]                            1008.396621          1000.337142
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                932
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02755252     -4911.5298055569 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.08518138     -4911.5865619538 -5.68E-02
     3 Broy./Diag. 0.40E+00    7.1     0.07572719     -4911.3274408090  2.59E-01
     4 Broy./Diag. 0.40E+00    7.1     0.04812016     -4911.6220483503 -2.95E-01
     5 Broy./Diag. 0.40E+00    7.1     0.02259999     -4911.5031062843  1.19E-01
     6 Broy./Diag. 0.40E+00    7.1     0.00509855     -4911.5344021274 -3.13E-02
     7 Broy./Diag. 0.40E+00    8.0     0.00604031     -4911.5273841953  7.02E-03
     8 Broy./Diag. 0.40E+00    7.0     0.00310750     -4911.5375327949 -1.01E-02
     9 Broy./Diag. 0.40E+00    6.7     0.00057775     -4911.5324098188  5.12E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00051746     -4911.5296847920  2.73E-03
    11 Broy./Diag. 0.40E+00    7.5     0.00016619     -4911.5320868525 -2.40E-03
    12 Broy./Diag. 0.40E+00    7.2     0.00042725     -4911.5322923669 -2.06E-04
    13 Broy./Diag. 0.40E+00    7.5     0.00037182     -4911.5304166042  1.88E-03
    14 Broy./Diag. 0.40E+00    7.5     0.00014946     -4911.5316826546 -1.27E-03
    15 Broy./Diag. 0.40E+00    7.5     0.00012035     -4911.5318857979 -2.03E-04
    16 Broy./Diag. 0.40E+00    7.1     0.00009167     -4911.5314767226  4.09E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00006624     -4911.5317018048 -2.25E-04
    18 Broy./Diag. 0.40E+00    7.3     0.00002874     -4911.5317537698 -5.20E-05
    19 Broy./Diag. 0.40E+00    7.5     0.00003252     -4911.5316242820  1.29E-04
    20 Broy./Diag. 0.40E+00    7.5     0.00002628     -4911.5317774339 -1.53E-04
    21 Broy./Diag. 0.40E+00    7.4     0.00002088     -4911.5317892142 -1.18E-05
    22 Broy./Diag. 0.40E+00    7.3     0.00001358     -4911.5317497077  3.95E-05
    23 Broy./Diag. 0.40E+00    6.9     0.00000648     -4911.5317492095  4.98E-07
    24 Broy./Diag. 0.40E+00    7.1     0.00001177     -4911.5317822147 -3.30E-05
    25 Broy./Diag. 0.40E+00    7.3     0.00001467     -4911.5317407601  4.15E-05
    26 Broy./Diag. 0.40E+00    7.3     0.00001016     -4911.5317871292 -4.64E-05
    27 Broy./Diag. 0.40E+00    7.0     0.00000390     -4911.5317835417  3.59E-06
    28 Broy./Diag. 0.40E+00    7.7     0.00000314     -4911.5317890185 -5.48E-06
    29 Broy./Diag. 0.40E+00    7.4     0.00000360     -4911.5317814527  7.57E-06
    30 Broy./Diag. 0.40E+00    7.3     0.00000279     -4911.5318037980 -2.23E-05
    31 Broy./Diag. 0.40E+00    7.3     0.00000466     -4911.5317953849  8.41E-06
    32 Broy./Diag. 0.40E+00    7.1     0.00000416     -4911.5318056248 -1.02E-05
    33 Broy./Diag. 0.40E+00    7.3     0.00000233     -4911.5318002432  5.38E-06
    34 Broy./Diag. 0.40E+00    7.1     0.00000157     -4911.5318051076 -4.86E-06
    35 Broy./Diag. 0.40E+00    7.3     0.00000107     -4911.5317981182  6.99E-06
    36 Broy./Diag. 0.40E+00    7.4     0.00000086     -4911.5318016492 -3.53E-06

  *** SCF run converged in    36 steps ***


  Electronic density on regular grids:      -1631.9999999995        0.0000000005
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008324421544
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.93324875428107
  Hartree energy:                                            1781.42552059758350
  Exchange-correlation energy:                               -779.56317875429613
  Electronic entropic energy:                                  -0.23705296787626
  Fermi energy:                                                 0.08718907235494

  Total energy:                                             -4911.53180164922924

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.531793703808944

 MD| ***************************************************************************
 MD| Step number                                                            1127
 MD| Time [fs]                                                       2254.000000
 MD| Conserved quantity [hartree]                            -0.491114521871E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    269.474675           599.850262
 MD| Energy drift per atom [K]           0.362043816426E+03   0.269983804836E+03
 MD| Potential energy [hartree]         -0.491153179370E+04  -0.491156494171E+04
 MD| Kinetic energy [hartree]            0.386574990440E+00   0.375404057502E+00
 MD| Temperature [K]                            1030.131489          1000.363579
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                932
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.02434535     -4911.5312289224 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.07571504     -4911.5524985639 -2.13E-02
     3 Broy./Diag. 0.40E+00    7.1     0.07545511     -4911.4090872348  1.43E-01
     4 Broy./Diag. 0.40E+00    7.0     0.03143805     -4911.5894836744 -1.80E-01
     5 Broy./Diag. 0.40E+00    7.5     0.02132394     -4911.5032081054  8.63E-02
     6 Broy./Diag. 0.40E+00    6.4     0.00927770     -4911.5464730686 -4.33E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00551857     -4911.5287459923  1.77E-02
     8 Broy./Diag. 0.40E+00    7.3     0.00315274     -4911.5378569630 -9.11E-03
     9 Broy./Diag. 0.40E+00    7.2     0.00074431     -4911.5338198368  4.04E-03
    10 Broy./Diag. 0.40E+00    7.0     0.00058203     -4911.5311697323  2.65E-03
    11 Broy./Diag. 0.40E+00    6.9     0.00032441     -4911.5333811927 -2.21E-03
    12 Broy./Diag. 0.40E+00    7.5     0.00042537     -4911.5324732665  9.08E-04
    13 Broy./Diag. 0.40E+00    7.3     0.00037029     -4911.5332685720 -7.95E-04
    14 Broy./Diag. 0.40E+00    7.0     0.00021141     -4911.5327138186  5.55E-04
    15 Broy./Diag. 0.40E+00    7.3     0.00009769     -4911.5331422734 -4.28E-04
    16 Broy./Diag. 0.40E+00    7.4     0.00011367     -4911.5328087470  3.34E-04
    17 Broy./Diag. 0.40E+00    6.9     0.00005247     -4911.5332828719 -4.74E-04
    18 Broy./Diag. 0.40E+00    7.3     0.00006590     -4911.5330873547  1.96E-04
    19 Broy./Diag. 0.40E+00    6.7     0.00006017     -4911.5332423467 -1.55E-04
    20 Broy./Diag. 0.40E+00    7.3     0.00004254     -4911.5331589782  8.34E-05
    21 Broy./Diag. 0.40E+00    6.7     0.00002689     -4911.5332385031 -7.95E-05
    22 Broy./Diag. 0.40E+00    6.9     0.00001843     -4911.5331709606  6.75E-05
    23 Broy./Diag. 0.40E+00    7.1     0.00000759     -4911.5332281038 -5.71E-05
    24 Broy./Diag. 0.40E+00    7.1     0.00001146     -4911.5332223289  5.77E-06
    25 Broy./Diag. 0.40E+00    6.9     0.00001353     -4911.5332265029 -4.17E-06
    26 Broy./Diag. 0.40E+00    7.3     0.00001116     -4911.5332226832  3.82E-06
    27 Broy./Diag. 0.40E+00    7.0     0.00000555     -4911.5332576215 -3.49E-05
    28 Broy./Diag. 0.40E+00    8.0     0.00000417     -4911.5332367192  2.09E-05
    29 Broy./Diag. 0.40E+00    7.6     0.00000352     -4911.5332572686 -2.05E-05
    30 Broy./Diag. 0.40E+00    7.5     0.00000363     -4911.5332526402  4.63E-06
    31 Broy./Diag. 0.40E+00    6.7     0.00000470     -4911.5332514366  1.20E-06
    32 Broy./Diag. 0.40E+00    6.9     0.00000400     -4911.5332530025 -1.57E-06
    33 Broy./Diag. 0.40E+00    7.0     0.00000299     -4911.5332618137 -8.81E-06
    34 Broy./Diag. 0.40E+00    7.9     0.00000181     -4911.5332485315  1.33E-05
    35 Broy./Diag. 0.40E+00    7.1     0.00000142     -4911.5332588927 -1.04E-05
    36 Broy./Diag. 0.40E+00    7.7     0.00000095     -4911.5332546536  4.24E-06

  *** SCF run converged in    36 steps ***


  Electronic density on regular grids:      -1631.9999999995        0.0000000005
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008329653709
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.92024079854127
  Hartree energy:                                            1781.43142665934806
  Exchange-correlation energy:                               -779.55772540794885
  Electronic entropic energy:                                  -0.23685747682184
  Fermi energy:                                                 0.08720752660000

  Total energy:                                             -4911.53325465362832

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.533247165950343

 MD| ***************************************************************************
 MD| Step number                                                            1128
 MD| Time [fs]                                                       2256.000000
 MD| Conserved quantity [hartree]                            -0.491116438620E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    266.866559           599.555064
 MD| Energy drift per atom [K]           0.322224034723E+03   0.270030117096E+03
 MD| Potential energy [hartree]         -0.491153324717E+04  -0.491156491361E+04
 MD| Kinetic energy [hartree]            0.368860964440E+00   0.375398256888E+00
 MD| Temperature [K]                             982.927774          1000.348121
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                932
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.01640292     -4911.5337087167 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.04652702     -4911.5230931482  1.06E-02
     3 Broy./Diag. 0.40E+00    7.3     0.05468213     -4911.4742415449  4.89E-02
     4 Broy./Diag. 0.40E+00    6.8     0.02389031     -4911.5621871584 -8.79E-02
     5 Broy./Diag. 0.40E+00    6.9     0.01774536     -4911.5137592388  4.84E-02
     6 Broy./Diag. 0.40E+00    6.9     0.01176851     -4911.5582036405 -4.44E-02
     7 Broy./Diag. 0.40E+00    7.5     0.00364401     -4911.5317853226  2.64E-02
     8 Broy./Diag. 0.40E+00    7.1     0.00238477     -4911.5360752207 -4.29E-03
     9 Broy./Diag. 0.40E+00    7.5     0.00068515     -4911.5359064445  1.69E-04
    10 Broy./Diag. 0.40E+00    7.3     0.00062553     -4911.5337193297  2.19E-03
    11 Broy./Diag. 0.40E+00    7.0     0.00055576     -4911.5353635789 -1.64E-03
    12 Broy./Diag. 0.40E+00    7.1     0.00072406     -4911.5342240326  1.14E-03
    13 Broy./Diag. 0.40E+00    7.1     0.00037159     -4911.5358215381 -1.60E-03
    14 Broy./Diag. 0.40E+00    7.0     0.00020986     -4911.5349705238  8.51E-04
    15 Broy./Diag. 0.40E+00    7.0     0.00021687     -4911.5352558836 -2.85E-04
    16 Broy./Diag. 0.40E+00    8.0     0.00014158     -4911.5354276649 -1.72E-04
    17 Broy./Diag. 0.40E+00    7.2     0.00012574     -4911.5350801795  3.47E-04
    18 Broy./Diag. 0.40E+00    7.5     0.00024526     -4911.5355401418 -4.60E-04
    19 Broy./Diag. 0.40E+00    7.1     0.00023360     -4911.5350603144  4.80E-04
    20 Broy./Diag. 0.40E+00    7.4     0.00010248     -4911.5356000818 -5.40E-04
    21 Broy./Diag. 0.40E+00    7.3     0.00008163     -4911.5354536330  1.46E-04
    22 Broy./Diag. 0.40E+00    6.9     0.00005069     -4911.5354204937  3.31E-05
    23 Broy./Diag. 0.40E+00    7.0     0.00003566     -4911.5355498636 -1.29E-04
    24 Broy./Diag. 0.40E+00    7.1     0.00004629     -4911.5354354085  1.14E-04
    25 Broy./Diag. 0.40E+00    7.4     0.00005673     -4911.5355540444 -1.19E-04
    26 Broy./Diag. 0.40E+00    7.7     0.00003023     -4911.5354289228  1.25E-04
    27 Broy./Diag. 0.40E+00    7.6     0.00002800     -4911.5355015950 -7.27E-05
    28 Broy./Diag. 0.40E+00    7.1     0.00002115     -4911.5355138788 -1.23E-05
    29 Broy./Diag. 0.40E+00    6.6     0.00001727     -4911.5354942542  1.96E-05
    30 Broy./Diag. 0.40E+00    7.1     0.00002596     -4911.5355540253 -5.98E-05
    31 Broy./Diag. 0.40E+00    6.8     0.00002874     -4911.5354945002  5.95E-05
    32 Broy./Diag. 0.40E+00    6.7     0.00001625     -4911.5355613412 -6.68E-05
    33 Broy./Diag. 0.40E+00    7.1     0.00001306     -4911.5355236837  3.77E-05
    34 Broy./Diag. 0.40E+00    7.1     0.00000987     -4911.5355352768 -1.16E-05
    35 Broy./Diag. 0.40E+00    7.3     0.00000772     -4911.5355462726 -1.10E-05
    36 Broy./Diag. 0.40E+00    6.9     0.00001083     -4911.5355274910  1.88E-05
    37 Broy./Diag. 0.40E+00    7.0     0.00001395     -4911.5355602208 -3.27E-05
    38 Broy./Diag. 0.40E+00    7.3     0.00000896     -4911.5355349072  2.53E-05
    39 Broy./Diag. 0.40E+00    7.3     0.00000764     -4911.5355580201 -2.31E-05
    40 Broy./Diag. 0.40E+00    6.8     0.00000619     -4911.5355547124  3.31E-06
    41 Broy./Diag. 0.40E+00    7.3     0.00000472     -4911.5355499797  4.73E-06
    42 Broy./Diag. 0.40E+00    6.9     0.00000608     -4911.5355659742 -1.60E-05
    43 Broy./Diag. 0.40E+00    7.1     0.00000703     -4911.5355467667  1.92E-05
    44 Broy./Diag. 0.40E+00    6.9     0.00000428     -4911.5355630215 -1.63E-05
    45 Broy./Diag. 0.40E+00    7.6     0.00000376     -4911.5355555062  7.52E-06
    46 Broy./Diag. 0.40E+00    7.1     0.00000340     -4911.5355613742 -5.87E-06
    47 Broy./Diag. 0.40E+00    8.0     0.00000262     -4911.5355641467 -2.77E-06
    48 Broy./Diag. 0.40E+00    7.1     0.00000305     -4911.5355594601  4.69E-06
    49 Broy./Diag. 0.40E+00    9.8     0.00000463     -4911.5355705984 -1.11E-05
    50 Broy./Diag. 0.40E+00    7.2     0.00000276     -4911.5355614020  9.20E-06
    51 Broy./Diag. 0.40E+00    9.6     0.00000206     -4911.5355681291 -6.73E-06
    52 Broy./Diag. 0.40E+00    8.5     0.00000178     -4911.5355649630  3.17E-06
    53 Broy./Diag. 0.40E+00    7.4     0.00000127     -4911.5355655981 -6.35E-07
    54 Broy./Diag. 0.40E+00    7.3     0.00000138     -4911.5355691911 -3.59E-06
    55 Broy./Diag. 0.40E+00    7.3     0.00000235     -4911.5355645002  4.69E-06
    56 Broy./Diag. 0.40E+00    7.3     0.00000158     -4911.5355697308 -5.23E-06
    57 Broy./Diag. 0.40E+00    8.7     0.00000121     -4911.5355673748  2.36E-06
    58 Broy./Diag. 0.40E+00    7.3     0.00000115     -4911.5355700719 -2.70E-06
    59 Broy./Diag. 0.40E+00    8.7     0.00000078     -4911.5355700842 -1.23E-08

  *** SCF run converged in    59 steps ***


  Electronic density on regular grids:      -1631.9999999995        0.0000000005
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008328741746
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.89702316567809
  Hartree energy:                                            1781.44303837307098
  Exchange-correlation energy:                               -779.54859529245402
  Electronic entropic energy:                                  -0.23669709219856
  Fermi energy:                                                 0.08720681306430

  Total energy:                                             -4911.53557008422376

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.535572533484810

 MD| ***************************************************************************
 MD| Step number                                                            1129
 MD| Time [fs]                                                       2258.000000
 MD| Conserved quantity [hartree]                            -0.491115212560E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    442.599205           599.416042
 MD| Energy drift per atom [K]           0.347695012236E+03   0.270098907969E+03
 MD| Potential energy [hartree]         -0.491153557253E+04  -0.491156488763E+04
 MD| Kinetic energy [hartree]            0.383446938099E+00   0.375405385923E+00
 MD| Temperature [K]                            1021.795965          1000.367119
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                932
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    7.5     0.01776310     -4911.5370885009 -4.91E+03
     2 Broy./Diag. 0.40E+00   10.3     0.03162191     -4911.5110822368  2.60E-02
     3 Broy./Diag. 0.40E+00    7.3     0.04139992     -4911.5251514464 -1.41E-02
     4 Broy./Diag. 0.40E+00    7.0     0.01981707     -4911.5079395696  1.72E-02
     5 Broy./Diag. 0.40E+00    7.3     0.01383598     -4911.5445623440 -3.66E-02
     6 Broy./Diag. 0.40E+00    7.5     0.01140238     -4911.5131796238  3.14E-02
     7 Broy./Diag. 0.40E+00    7.0     0.00366659     -4911.5411025920 -2.79E-02
     8 Broy./Diag. 0.40E+00    8.3     0.00226073     -4911.5374298447  3.67E-03
     9 Broy./Diag. 0.40E+00    8.9     0.00060007     -4911.5390608117 -1.63E-03
    10 Broy./Diag. 0.40E+00    7.9     0.00046852     -4911.5362817155  2.78E-03
    11 Broy./Diag. 0.40E+00   10.9     0.00022316     -4911.5382529368 -1.97E-03
    12 Broy./Diag. 0.40E+00    7.2     0.00029884     -4911.5390645787 -8.12E-04
    13 Broy./Diag. 0.40E+00    7.3     0.00033972     -4911.5378244376  1.24E-03
    14 Broy./Diag. 0.40E+00    7.0     0.00024522     -4911.5386075170 -7.83E-04
    15 Broy./Diag. 0.40E+00    7.3     0.00010803     -4911.5385143122  9.32E-05
    16 Broy./Diag. 0.40E+00    7.1     0.00010557     -4911.5387603745 -2.46E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00006871     -4911.5386085815  1.52E-04
    18 Broy./Diag. 0.40E+00    7.5     0.00004903     -4911.5389459979 -3.37E-04
    19 Broy./Diag. 0.40E+00    6.7     0.00003169     -4911.5389193291  2.67E-05
    20 Broy./Diag. 0.40E+00    7.8     0.00004651     -4911.5387871166  1.32E-04
    21 Broy./Diag. 0.40E+00    7.3     0.00004762     -4911.5389880608 -2.01E-04
    22 Broy./Diag. 0.40E+00    7.3     0.00002837     -4911.5389293984  5.87E-05
    23 Broy./Diag. 0.40E+00    7.1     0.00001717     -4911.5389749846 -4.56E-05
    24 Broy./Diag. 0.40E+00    7.0     0.00001287     -4911.5389321472  4.28E-05
    25 Broy./Diag. 0.40E+00    6.8     0.00000960     -4911.5389906599 -5.85E-05
    26 Broy./Diag. 0.40E+00    7.3     0.00000938     -4911.5389942921 -3.63E-06
    27 Broy./Diag. 0.40E+00    7.5     0.00001831     -4911.5389430064  5.13E-05
    28 Broy./Diag. 0.40E+00    7.1     0.00001525     -4911.5389904194 -4.74E-05
    29 Broy./Diag. 0.40E+00    7.7     0.00000790     -4911.5389807353  9.68E-06
    30 Broy./Diag. 0.40E+00    7.0     0.00000819     -4911.5390040869 -2.34E-05
    31 Broy./Diag. 0.40E+00    7.1     0.00000483     -4911.5389730984  3.10E-05
    32 Broy./Diag. 0.40E+00    7.2     0.00000425     -4911.5389771689 -4.07E-06
    33 Broy./Diag. 0.40E+00    7.3     0.00000780     -4911.5390015296 -2.44E-05
    34 Broy./Diag. 0.40E+00    7.3     0.00000793     -4911.5389781469  2.34E-05
    35 Broy./Diag. 0.40E+00    7.3     0.00000355     -4911.5389851587 -7.01E-06
    36 Broy./Diag. 0.40E+00    8.1     0.00000372     -4911.5389772635  7.90E-06
    37 Broy./Diag. 0.40E+00    7.1     0.00000284     -4911.5389914959 -1.42E-05
    38 Broy./Diag. 0.40E+00    6.9     0.00000233     -4911.5389886026  2.89E-06
    39 Broy./Diag. 0.40E+00    7.2     0.00000357     -4911.5389768654  1.17E-05
    40 Broy./Diag. 0.40E+00    7.7     0.00000449     -4911.5389880073 -1.11E-05
    41 Broy./Diag. 0.40E+00    7.7     0.00000243     -4911.5389832795  4.73E-06
    42 Broy./Diag. 0.40E+00    7.3     0.00000174     -4911.5389870610 -3.78E-06
    43 Broy./Diag. 0.40E+00    7.5     0.00000134     -4911.5389804246  6.64E-06
    44 Broy./Diag. 0.40E+00    7.3     0.00000105     -4911.5389818811 -1.46E-06
    45 Broy./Diag. 0.40E+00    7.1     0.00000144     -4911.5389861614 -4.28E-06
    46 Broy./Diag. 0.40E+00    7.1     0.00000196     -4911.5389813694  4.79E-06
    47 Broy./Diag. 0.40E+00    7.1     0.00000129     -4911.5389835911 -2.22E-06
    48 Broy./Diag. 0.40E+00    7.2     0.00000093     -4911.5389815413  2.05E-06

  *** SCF run converged in    48 steps ***


  Electronic density on regular grids:      -1631.9999999995        0.0000000005
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008322739536
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.86783164417193
  Hartree energy:                                            1781.45772606996843
  Exchange-correlation energy:                               -779.53765912513506
  Electronic entropic energy:                                  -0.23654086778264
  Fermi energy:                                                 0.08719603836875

  Total energy:                                             -4911.53898154132639

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.538981875023637

 MD| ***************************************************************************
 MD| Step number                                                            1130
 MD| Time [fs]                                                       2260.000000
 MD| Conserved quantity [hartree]                            -0.491116071187E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    367.435267           599.210749
 MD| Energy drift per atom [K]           0.329857320770E+03   0.270151791520E+03
 MD| Potential energy [hartree]         -0.491153898188E+04  -0.491156486470E+04
 MD| Kinetic energy [hartree]            0.378270001034E+00   0.375407920981E+00
 MD| Temperature [K]                            1008.000645          1000.373874
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                932
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.01959811     -4911.5404319833 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.03822503     -4911.5082331307  3.22E-02
     3 Broy./Diag. 0.40E+00    6.8     0.04500951     -4911.5588827975 -5.06E-02
     4 Broy./Diag. 0.40E+00    7.1     0.02245492     -4911.4720872549  8.68E-02
     5 Broy./Diag. 0.40E+00    6.8     0.01935734     -4911.5660254451 -9.39E-02
     6 Broy./Diag. 0.40E+00    7.0     0.01079373     -4911.5175721110  4.85E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00300273     -4911.5379037599 -2.03E-02
     8 Broy./Diag. 0.40E+00    6.7     0.00166217     -4911.5490429073 -1.11E-02
     9 Broy./Diag. 0.40E+00    7.6     0.00044711     -4911.5421574569  6.89E-03
    10 Broy./Diag. 0.40E+00    7.3     0.00042929     -4911.5397628068  2.39E-03
    11 Broy./Diag. 0.40E+00    7.3     0.00022399     -4911.5419896632 -2.23E-03
    12 Broy./Diag. 0.40E+00    7.8     0.00017154     -4911.5425150489 -5.25E-04
    13 Broy./Diag. 0.40E+00    7.1     0.00022744     -4911.5412200832  1.29E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00024656     -4911.5426682313 -1.45E-03
    15 Broy./Diag. 0.40E+00    7.3     0.00013740     -4911.5419698850  6.98E-04
    16 Broy./Diag. 0.40E+00    7.1     0.00008278     -4911.5419811812 -1.13E-05
    17 Broy./Diag. 0.40E+00    7.2     0.00004093     -4911.5424494844 -4.68E-04
    18 Broy./Diag. 0.40E+00    7.5     0.00004727     -4911.5424736533 -2.42E-05
    19 Broy./Diag. 0.40E+00    6.6     0.00003533     -4911.5422976943  1.76E-04
    20 Broy./Diag. 0.40E+00    7.1     0.00003914     -4911.5425841589 -2.86E-04
    21 Broy./Diag. 0.40E+00    7.1     0.00002918     -4911.5424530499  1.31E-04
    22 Broy./Diag. 0.40E+00    7.3     0.00001512     -4911.5424997119 -4.67E-05
    23 Broy./Diag. 0.40E+00    7.5     0.00000871     -4911.5425312818 -3.16E-05
    24 Broy./Diag. 0.40E+00    7.3     0.00000663     -4911.5425482116 -1.69E-05
    25 Broy./Diag. 0.40E+00    7.4     0.00000610     -4911.5425183296  2.99E-05
    26 Broy./Diag. 0.40E+00    7.1     0.00000961     -4911.5425820511 -6.37E-05
    27 Broy./Diag. 0.40E+00    7.1     0.00000842     -4911.5425402688  4.18E-05
    28 Broy./Diag. 0.40E+00    7.5     0.00000505     -4911.5425526337 -1.24E-05
    29 Broy./Diag. 0.40E+00    7.3     0.00000344     -4911.5425579007 -5.27E-06
    30 Broy./Diag. 0.40E+00    7.7     0.00000295     -4911.5425607054 -2.80E-06
    31 Broy./Diag. 0.40E+00    6.9     0.00000214     -4911.5425477381  1.30E-05
    32 Broy./Diag. 0.40E+00    7.3     0.00000253     -4911.5425618825 -1.41E-05
    33 Broy./Diag. 0.40E+00    7.1     0.00000356     -4911.5425515909  1.03E-05
    34 Broy./Diag. 0.40E+00    7.2     0.00000306     -4911.5425531144 -1.52E-06
    35 Broy./Diag. 0.40E+00    7.3     0.00000178     -4911.5425495080  3.61E-06
    36 Broy./Diag. 0.40E+00    7.1     0.00000111     -4911.5425536650 -4.16E-06
    37 Broy./Diag. 0.40E+00    7.3     0.00000089     -4911.5425447574  8.91E-06

  *** SCF run converged in    37 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008313930930
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.84014237870906
  Hartree energy:                                            1781.47129220053921
  Exchange-correlation energy:                               -779.52722795549903
  Electronic entropic energy:                                  -0.23641204697802
  Fermi energy:                                                 0.08718355649649

  Total energy:                                             -4911.54254475736070

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.542541713648461

 MD| ***************************************************************************
 MD| Step number                                                            1131
 MD| Time [fs]                                                       2262.000000
 MD| Conserved quantity [hartree]                            -0.491114662563E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    274.854672           598.923962
 MD| Energy drift per atom [K]           0.359120990018E+03   0.270230455710E+03
 MD| Potential energy [hartree]         -0.491154254171E+04  -0.491156484496E+04
 MD| Kinetic energy [hartree]            0.395916080449E+00   0.375426053748E+00
 MD| Temperature [K]                            1055.023299          1000.422194
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02141699     -4911.5432502060 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.7     0.03739967     -4911.5160541476  2.72E-02
     3 Broy./Diag. 0.40E+00    7.1     0.04210973     -4911.5587307995 -4.27E-02
     4 Broy./Diag. 0.40E+00    6.9     0.02354868     -4911.4716697829  8.71E-02
     5 Broy./Diag. 0.40E+00    6.9     0.01949599     -4911.5702738812 -9.86E-02
     6 Broy./Diag. 0.40E+00    7.1     0.01079255     -4911.5220803084  4.82E-02
     7 Broy./Diag. 0.40E+00    8.0     0.00369545     -4911.5398145410 -1.77E-02
     8 Broy./Diag. 0.40E+00    7.5     0.00224045     -4911.5504853031 -1.07E-02
     9 Broy./Diag. 0.40E+00    6.8     0.00075529     -4911.5455681510  4.92E-03
    10 Broy./Diag. 0.40E+00    6.9     0.00055019     -4911.5418290553  3.74E-03
    11 Broy./Diag. 0.40E+00    7.4     0.00041365     -4911.5435993218 -1.77E-03
    12 Broy./Diag. 0.40E+00    7.3     0.00056298     -4911.5459387109 -2.34E-03
    13 Broy./Diag. 0.40E+00    7.4     0.00036266     -4911.5441232128  1.82E-03
    14 Broy./Diag. 0.40E+00    7.3     0.00011974     -4911.5444133848 -2.90E-04
    15 Broy./Diag. 0.40E+00    7.9     0.00015748     -4911.5450991615 -6.86E-04
    16 Broy./Diag. 0.40E+00    6.8     0.00011747     -4911.5448709635  2.28E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00008946     -4911.5447644177  1.07E-04
    18 Broy./Diag. 0.40E+00    7.0     0.00011020     -4911.5450408815 -2.76E-04
    19 Broy./Diag. 0.40E+00    6.8     0.00013120     -4911.5456003236 -5.59E-04
    20 Broy./Diag. 0.40E+00    7.5     0.00008046     -4911.5451809603  4.19E-04
    21 Broy./Diag. 0.40E+00    7.5     0.00005150     -4911.5450816259  9.93E-05
    22 Broy./Diag. 0.40E+00    7.7     0.00004532     -4911.5453457013 -2.64E-04
    23 Broy./Diag. 0.40E+00    7.2     0.00003294     -4911.5453913702 -4.57E-05
    24 Broy./Diag. 0.40E+00    7.4     0.00002972     -4911.5453012683  9.01E-05
    25 Broy./Diag. 0.40E+00    7.1     0.00004034     -4911.5451767673  1.25E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00002652     -4911.5453693556 -1.93E-04
    27 Broy./Diag. 0.40E+00    7.3     0.00001406     -4911.5453779068 -8.55E-06
    28 Broy./Diag. 0.40E+00    7.3     0.00001364     -4911.5453116290  6.63E-05
    29 Broy./Diag. 0.40E+00    7.9     0.00001091     -4911.5453090874  2.54E-06
    30 Broy./Diag. 0.40E+00    7.3     0.00000748     -4911.5453483854 -3.93E-05
    31 Broy./Diag. 0.40E+00    7.1     0.00001557     -4911.5453796802 -3.13E-05
    32 Broy./Diag. 0.40E+00    8.1     0.00001313     -4911.5453043744  7.53E-05
    33 Broy./Diag. 0.40E+00    6.9     0.00000625     -4911.5453239168 -1.95E-05
    34 Broy./Diag. 0.40E+00    7.2     0.00000614     -4911.5453603910 -3.65E-05
    35 Broy./Diag. 0.40E+00    7.3     0.00000448     -4911.5453610955 -7.05E-07
    36 Broy./Diag. 0.40E+00    6.9     0.00000388     -4911.5453458697  1.52E-05
    37 Broy./Diag. 0.40E+00    7.3     0.00000567     -4911.5453381869  7.68E-06
    38 Broy./Diag. 0.40E+00    7.1     0.00000561     -4911.5453717271 -3.35E-05
    39 Broy./Diag. 0.40E+00    7.2     0.00000295     -4911.5453626397  9.09E-06
    40 Broy./Diag. 0.40E+00    7.1     0.00000340     -4911.5453480817  1.46E-05
    41 Broy./Diag. 0.40E+00    7.3     0.00000250     -4911.5453555112 -7.43E-06
    42 Broy./Diag. 0.40E+00    7.1     0.00000255     -4911.5453663842 -1.09E-05
    43 Broy./Diag. 0.40E+00    6.8     0.00000327     -4911.5453702088 -3.82E-06
    44 Broy./Diag. 0.40E+00    7.1     0.00000326     -4911.5453530104  1.72E-05
    45 Broy./Diag. 0.40E+00    7.7     0.00000160     -4911.5453619376 -8.93E-06
    46 Broy./Diag. 0.40E+00    6.9     0.00000173     -4911.5453704089 -8.47E-06
    47 Broy./Diag. 0.40E+00    7.9     0.00000123     -4911.5453675063  2.90E-06
    48 Broy./Diag. 0.40E+00    7.5     0.00000146     -4911.5453641028  3.40E-06
    49 Broy./Diag. 0.40E+00    6.8     0.00000152     -4911.5453635211  5.82E-07
    50 Broy./Diag. 0.40E+00    7.1     0.00000189     -4911.5453737930 -1.03E-05
    51 Broy./Diag. 0.40E+00    7.3     0.00000117     -4911.5453687411  5.05E-06
    52 Broy./Diag. 0.40E+00    7.3     0.00000117     -4911.5453655575  3.18E-06
    53 Broy./Diag. 0.40E+00    7.3     0.00000078     -4911.5453688019 -3.24E-06

  *** SCF run converged in    53 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008304574629
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.81340660209662
  Hartree energy:                                            1781.48476245240113
  Exchange-correlation energy:                               -779.51689366007963
  Electronic entropic energy:                                  -0.23630474124128
  Fermi energy:                                                 0.08716261716223

  Total energy:                                             -4911.54536880187607

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.545373658296739

 MD| ***************************************************************************
 MD| Step number                                                            1132
 MD| Time [fs]                                                       2264.000000
 MD| Conserved quantity [hartree]                            -0.491115676430E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    392.648024           598.741740
 MD| Energy drift per atom [K]           0.338058265395E+03   0.270290374269E+03
 MD| Potential energy [hartree]         -0.491154537366E+04  -0.491156482776E+04
 MD| Kinetic energy [hartree]            0.388609357652E+00   0.375437699776E+00
 MD| Temperature [K]                            1035.552600          1000.453227
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02162551     -4911.5455454801 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.03079332     -4911.5034306527  4.21E-02
     3 Broy./Diag. 0.40E+00    7.1     0.03725700     -4911.6074840087 -1.04E-01
     4 Broy./Diag. 0.40E+00    6.9     0.03280872     -4911.4259467187  1.82E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01983413     -4911.5705696346 -1.45E-01
     6 Broy./Diag. 0.40E+00    7.3     0.00958865     -4911.5355960981  3.50E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00395666     -4911.5402028158 -4.61E-03
     8 Broy./Diag. 0.40E+00    7.5     0.00157415     -4911.5492861577 -9.08E-03
     9 Broy./Diag. 0.40E+00    7.1     0.00108058     -4911.5488945412  3.92E-04
    10 Broy./Diag. 0.40E+00    7.1     0.00069897     -4911.5442366248  4.66E-03
    11 Broy./Diag. 0.40E+00    7.1     0.00073206     -4911.5434443604  7.92E-04
    12 Broy./Diag. 0.40E+00    7.1     0.00060519     -4911.5476805862 -4.24E-03
    13 Broy./Diag. 0.40E+00    7.7     0.00035552     -4911.5468785551  8.02E-04
    14 Broy./Diag. 0.40E+00    7.3     0.00014280     -4911.5464035486  4.75E-04
    15 Broy./Diag. 0.40E+00    7.2     0.00013360     -4911.5468986272 -4.95E-04
    16 Broy./Diag. 0.40E+00    7.1     0.00015401     -4911.5472861800 -3.88E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00017790     -4911.5470370740  2.49E-04
    18 Broy./Diag. 0.40E+00    7.3     0.00019592     -4911.5465438547  4.93E-04
    19 Broy./Diag. 0.40E+00    7.3     0.00015444     -4911.5476346098 -1.09E-03
    20 Broy./Diag. 0.40E+00    7.1     0.00007508     -4911.5477324671 -9.79E-05
    21 Broy./Diag. 0.40E+00    6.9     0.00005072     -4911.5473959611  3.37E-04
    22 Broy./Diag. 0.40E+00    7.1     0.00006557     -4911.5473452224  5.07E-05
    23 Broy./Diag. 0.40E+00    6.9     0.00003930     -4911.5475584353 -2.13E-04
    24 Broy./Diag. 0.40E+00    7.1     0.00005963     -4911.5476848050 -1.26E-04
    25 Broy./Diag. 0.40E+00    6.9     0.00004608     -4911.5473657818  3.19E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00002183     -4911.5474626574 -9.69E-05
    27 Broy./Diag. 0.40E+00    7.2     0.00001457     -4911.5475846959 -1.22E-04
    28 Broy./Diag. 0.40E+00    7.3     0.00001715     -4911.5475910198 -6.32E-06
    29 Broy./Diag. 0.40E+00    6.9     0.00001439     -4911.5475352740  5.57E-05
    30 Broy./Diag. 0.40E+00    7.3     0.00002476     -4911.5475043345  3.09E-05
    31 Broy./Diag. 0.40E+00    7.1     0.00002214     -4911.5476526491 -1.48E-04
    32 Broy./Diag. 0.40E+00    7.5     0.00001239     -4911.5476005341  5.21E-05
    33 Broy./Diag. 0.40E+00    7.1     0.00000888     -4911.5475445515  5.60E-05
    34 Broy./Diag. 0.40E+00    7.3     0.00000848     -4911.5475711924 -2.66E-05
    35 Broy./Diag. 0.40E+00    7.3     0.00000704     -4911.5476087301 -3.75E-05
    36 Broy./Diag. 0.40E+00    7.9     0.00001058     -4911.5476227771 -1.40E-05
    37 Broy./Diag. 0.40E+00    6.7     0.00001063     -4911.5475661864  5.66E-05
    38 Broy./Diag. 0.40E+00    6.7     0.00000617     -4911.5476006250 -3.44E-05
    39 Broy./Diag. 0.40E+00    7.3     0.00000497     -4911.5476287059 -2.81E-05
    40 Broy./Diag. 0.40E+00    7.9     0.00000440     -4911.5476178616  1.08E-05
    41 Broy./Diag. 0.40E+00    7.7     0.00000527     -4911.5476010310  1.68E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00000575     -4911.5476002394  7.92E-07
    43 Broy./Diag. 0.40E+00    7.1     0.00000668     -4911.5476393692 -3.91E-05
    44 Broy./Diag. 0.40E+00    7.9     0.00000412     -4911.5476187400  2.06E-05
    45 Broy./Diag. 0.40E+00    7.1     0.00000301     -4911.5476122810  6.46E-06
    46 Broy./Diag. 0.40E+00    7.3     0.00000231     -4911.5476208284 -8.55E-06
    47 Broy./Diag. 0.40E+00    7.3     0.00000235     -4911.5476304417 -9.61E-06
    48 Broy./Diag. 0.40E+00    7.2     0.00000282     -4911.5476308704 -4.29E-07
    49 Broy./Diag. 0.40E+00    7.3     0.00000356     -4911.5476143526  1.65E-05
    50 Broy./Diag. 0.40E+00    7.3     0.00000244     -4911.5476284392 -1.41E-05
    51 Broy./Diag. 0.40E+00    7.3     0.00000190     -4911.5476338368 -5.40E-06
    52 Broy./Diag. 0.40E+00    7.3     0.00000152     -4911.5476298817  3.96E-06
    53 Broy./Diag. 0.40E+00    7.1     0.00000153     -4911.5476265476  3.33E-06
    54 Broy./Diag. 0.40E+00    7.1     0.00000138     -4911.5476278311 -1.28E-06
    55 Broy./Diag. 0.40E+00    7.3     0.00000173     -4911.5476369195 -9.09E-06
    56 Broy./Diag. 0.40E+00    6.9     0.00000133     -4911.5476310059  5.91E-06
    57 Broy./Diag. 0.40E+00    7.5     0.00000098     -4911.5476300099  9.96E-07

  *** SCF run converged in    57 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008294880909
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.78326368339231
  Hartree energy:                                            1781.50104498931341
  Exchange-correlation energy:                               -779.50538500581274
  Electronic entropic energy:                                  -0.23621412264758
  Fermi energy:                                                 0.08712699440273

  Total energy:                                             -4911.54763000985076

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.547637407784350

 MD| ***************************************************************************
 MD| Step number                                                            1133
 MD| Time [fs]                                                       2266.000000
 MD| Conserved quantity [hartree]                            -0.491115128592E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    419.764053           598.583772
 MD| Energy drift per atom [K]           0.349439403726E+03   0.270360232195E+03
 MD| Potential energy [hartree]         -0.491154763741E+04  -0.491156481259E+04
 MD| Kinetic energy [hartree]            0.396351485590E+00   0.375456158546E+00
 MD| Temperature [K]                            1056.183551          1000.502416
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02353989     -4911.5472660549 -4.91E+03
     2 Broy./Diag. 0.40E+00    8.2     0.06949479     -4911.4846065718  6.27E-02
     3 Broy./Diag. 0.40E+00    7.3     0.07173655     -4911.6644425727 -1.80E-01
     4 Broy./Diag. 0.40E+00    7.3     0.03099542     -4911.4186359517  2.46E-01
     5 Broy./Diag. 0.40E+00    7.1     0.02128845     -4911.5731706545 -1.55E-01
     6 Broy./Diag. 0.40E+00    7.3     0.01036368     -4911.5343857213  3.88E-02
     7 Broy./Diag. 0.40E+00    7.2     0.00468472     -4911.5423383057 -7.95E-03
     8 Broy./Diag. 0.40E+00    7.3     0.00148614     -4911.5495621835 -7.22E-03
     9 Broy./Diag. 0.40E+00    7.3     0.00091132     -4911.5508662348 -1.30E-03
    10 Broy./Diag. 0.40E+00    7.3     0.00083949     -4911.5480001160  2.87E-03
    11 Broy./Diag. 0.40E+00    7.3     0.00076736     -4911.5441418774  3.86E-03
    12 Broy./Diag. 0.40E+00    6.9     0.00064963     -4911.5491484944 -5.01E-03
    13 Broy./Diag. 0.40E+00    7.3     0.00039964     -4911.5485560248  5.92E-04
    14 Broy./Diag. 0.40E+00    7.1     0.00014698     -4911.5482097714  3.46E-04
    15 Broy./Diag. 0.40E+00    7.1     0.00015034     -4911.5483088010 -9.90E-05
    16 Broy./Diag. 0.40E+00    7.7     0.00011296     -4911.5488971444 -5.88E-04
    17 Broy./Diag. 0.40E+00    7.5     0.00017105     -4911.5490741074 -1.77E-04
    18 Broy./Diag. 0.40E+00    7.3     0.00019430     -4911.5480937511  9.80E-04
    19 Broy./Diag. 0.40E+00    7.1     0.00017059     -4911.5491904868 -1.10E-03
    20 Broy./Diag. 0.40E+00    6.9     0.00010607     -4911.5493638528 -1.73E-04
    21 Broy./Diag. 0.40E+00    7.3     0.00005819     -4911.5491830178  1.81E-04
    22 Broy./Diag. 0.40E+00    6.7     0.00004598     -4911.5489986998  1.84E-04
    23 Broy./Diag. 0.40E+00    6.9     0.00004495     -4911.5490707103 -7.20E-05
    24 Broy./Diag. 0.40E+00    7.3     0.00006229     -4911.5494066932 -3.36E-04
    25 Broy./Diag. 0.40E+00    6.9     0.00005010     -4911.5490737946  3.33E-04
    26 Broy./Diag. 0.40E+00    7.0     0.00002853     -4911.5491282822 -5.45E-05
    27 Broy./Diag. 0.40E+00    7.5     0.00001560     -4911.5492147474 -8.65E-05
    28 Broy./Diag. 0.40E+00    6.7     0.00001586     -4911.5492771483 -6.24E-05
    29 Broy./Diag. 0.40E+00    7.4     0.00001996     -4911.5492459861  3.12E-05
    30 Broy./Diag. 0.40E+00    7.3     0.00002871     -4911.5491378211  1.08E-04
    31 Broy./Diag. 0.40E+00    7.3     0.00002802     -4911.5493186180 -1.81E-04
    32 Broy./Diag. 0.40E+00    7.1     0.00001643     -4911.5492925205  2.61E-05
    33 Broy./Diag. 0.40E+00    8.1     0.00001184     -4911.5492487010  4.38E-05
    34 Broy./Diag. 0.40E+00    7.1     0.00000903     -4911.5492397866  8.91E-06
    35 Broy./Diag. 0.40E+00    9.3     0.00000935     -4911.5492674189 -2.76E-05
    36 Broy./Diag. 0.40E+00    7.7     0.00001237     -4911.5493197361 -5.23E-05
    37 Broy./Diag. 0.40E+00    7.9     0.00001373     -4911.5492475125  7.22E-05
    38 Broy./Diag. 0.40E+00   10.4     0.00000812     -4911.5492747153 -2.72E-05
    39 Broy./Diag. 0.40E+00    7.3     0.00000774     -4911.5493016658 -2.70E-05
    40 Broy./Diag. 0.40E+00    6.9     0.00000551     -4911.5493101590 -8.49E-06
    41 Broy./Diag. 0.40E+00    6.8     0.00000649     -4911.5492959788  1.42E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00000627     -4911.5492669113  2.91E-05
    43 Broy./Diag. 0.40E+00    7.1     0.00000827     -4911.5493215173 -5.46E-05
    44 Broy./Diag. 0.40E+00    7.9     0.00000510     -4911.5493060674  1.54E-05
    45 Broy./Diag. 0.40E+00    7.4     0.00000426     -4911.5492996352  6.43E-06
    46 Broy./Diag. 0.40E+00    9.5     0.00000285     -4911.5492992956  3.40E-07
    47 Broy./Diag. 0.40E+00    7.1     0.00000267     -4911.5493099023 -1.06E-05
    48 Broy./Diag. 0.40E+00    8.6     0.00000316     -4911.5493222688 -1.24E-05
    49 Broy./Diag. 0.40E+00    9.9     0.00000456     -4911.5492979327  2.43E-05
    50 Broy./Diag. 0.40E+00    7.1     0.00000322     -4911.5493095455 -1.16E-05
    51 Broy./Diag. 0.40E+00    7.1     0.00000252     -4911.5493167819 -7.24E-06
    52 Broy./Diag. 0.40E+00    7.3     0.00000176     -4911.5493179368 -1.15E-06
    53 Broy./Diag. 0.40E+00    7.8     0.00000152     -4911.5493136627  4.27E-06
    54 Broy./Diag. 0.40E+00    7.4     0.00000161     -4911.5493085371  5.13E-06
    55 Broy./Diag. 0.40E+00    9.8     0.00000233     -4911.5493228335 -1.43E-05
    56 Broy./Diag. 0.40E+00    7.2     0.00000187     -4911.5493176034  5.23E-06
    57 Broy./Diag. 0.40E+00    9.4     0.00000127     -4911.5493160262  1.58E-06
    58 Broy./Diag. 0.40E+00    9.0     0.00000103     -4911.5493163757 -3.49E-07
    59 Broy./Diag. 0.40E+00    7.7     0.00000073     -4911.5493200531 -3.68E-06

  *** SCF run converged in    59 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008287527059
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.75383570430313
  Hartree energy:                                            1781.51730835060766
  Exchange-correlation energy:                               -779.49396700131069
  Electronic entropic energy:                                  -0.23615748953014
  Fermi energy:                                                 0.08708526492682

  Total energy:                                             -4911.54932005306546

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.549323894055306

 MD| ***************************************************************************
 MD| Step number                                                            1134
 MD| Time [fs]                                                       2268.000000
 MD| Conserved quantity [hartree]                            -0.491115555039E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    455.262372           598.457386
 MD| Energy drift per atom [K]           0.340580129274E+03   0.270422154503E+03
 MD| Potential energy [hartree]         -0.491154932389E+04  -0.491156479893E+04
 MD| Kinetic energy [hartree]            0.393773507549E+00   0.375472311411E+00
 MD| Temperature [K]                            1049.313846          1000.545459
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02178114     -4911.5480177264 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.06372744     -4911.5013305503  4.67E-02
     3 Broy./Diag. 0.40E+00    7.3     0.06794908     -4911.6340784623 -1.33E-01
     4 Broy./Diag. 0.40E+00    6.7     0.02452125     -4911.4354120917  1.99E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01949967     -4911.5735601465 -1.38E-01
     6 Broy./Diag. 0.40E+00    8.0     0.01156880     -4911.5300043857  4.36E-02
     7 Broy./Diag. 0.40E+00    7.0     0.00440957     -4911.5438098484 -1.38E-02
     8 Broy./Diag. 0.40E+00    6.9     0.00191596     -4911.5503061409 -6.50E-03
     9 Broy./Diag. 0.40E+00    7.3     0.00116361     -4911.5522376748 -1.93E-03
    10 Broy./Diag. 0.40E+00    6.8     0.00084409     -4911.5485933400  3.64E-03
    11 Broy./Diag. 0.40E+00    6.9     0.00074468     -4911.5452018750  3.39E-03
    12 Broy./Diag. 0.40E+00    6.9     0.00068575     -4911.5500819857 -4.88E-03
    13 Broy./Diag. 0.40E+00    6.9     0.00041291     -4911.5491480940  9.34E-04
    14 Broy./Diag. 0.40E+00    7.2     0.00015525     -4911.5490918898  5.62E-05
    15 Broy./Diag. 0.40E+00    6.9     0.00017378     -4911.5490451431  4.67E-05
    16 Broy./Diag. 0.40E+00    7.2     0.00016470     -4911.5496418241 -5.97E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00018760     -4911.5498293082 -1.87E-04
    18 Broy./Diag. 0.40E+00    7.1     0.00023228     -4911.5486229033  1.21E-03
    19 Broy./Diag. 0.40E+00    7.3     0.00018234     -4911.5497265882 -1.10E-03
    20 Broy./Diag. 0.40E+00    7.2     0.00008183     -4911.5498274709 -1.01E-04
    21 Broy./Diag. 0.40E+00    7.3     0.00006729     -4911.5499073179 -7.98E-05
    22 Broy./Diag. 0.40E+00    7.1     0.00008390     -4911.5496563259  2.51E-04
    23 Broy./Diag. 0.40E+00    7.2     0.00005408     -4911.5496062560  5.01E-05
    24 Broy./Diag. 0.40E+00    6.7     0.00007746     -4911.5500652453 -4.59E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00006971     -4911.5497396302  3.26E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00003402     -4911.5497367873  2.84E-06
    27 Broy./Diag. 0.40E+00    7.0     0.00002808     -4911.5498059206 -6.91E-05
    28 Broy./Diag. 0.40E+00    7.1     0.00004113     -4911.5499392723 -1.33E-04
    29 Broy./Diag. 0.40E+00    6.9     0.00003364     -4911.5499662568 -2.70E-05
    30 Broy./Diag. 0.40E+00    7.1     0.00004396     -4911.5497635034  2.03E-04
    31 Broy./Diag. 0.40E+00    6.7     0.00004024     -4911.5499582365 -1.95E-04
    32 Broy./Diag. 0.40E+00    6.9     0.00002121     -4911.5499770651 -1.88E-05
    33 Broy./Diag. 0.40E+00    6.9     0.00001414     -4911.5499586176  1.84E-05
    34 Broy./Diag. 0.40E+00    7.2     0.00002071     -4911.5499064060  5.22E-05
    35 Broy./Diag. 0.40E+00    7.1     0.00001795     -4911.5499153972 -8.99E-06
    36 Broy./Diag. 0.40E+00    7.1     0.00002357     -4911.5500225971 -1.07E-04
    37 Broy./Diag. 0.40E+00    7.1     0.00002303     -4911.5499250925  9.75E-05
    38 Broy./Diag. 0.40E+00    7.1     0.00001270     -4911.5499544539 -2.94E-05
    39 Broy./Diag. 0.40E+00    6.9     0.00000860     -4911.5499618057 -7.35E-06
    40 Broy./Diag. 0.40E+00    7.1     0.00001062     -4911.5500059381 -4.41E-05
    41 Broy./Diag. 0.40E+00    6.9     0.00001147     -4911.5500023727  3.57E-06
    42 Broy./Diag. 0.40E+00    7.2     0.00001049     -4911.5499442666  5.81E-05
    43 Broy./Diag. 0.40E+00    7.5     0.00001114     -4911.5500030995 -5.88E-05
    44 Broy./Diag. 0.40E+00    6.9     0.00000634     -4911.5499973871  5.71E-06
    45 Broy./Diag. 0.40E+00    7.3     0.00000421     -4911.5499994196 -2.03E-06
    46 Broy./Diag. 0.40E+00    7.1     0.00000521     -4911.5499852561  1.42E-05
    47 Broy./Diag. 0.40E+00    6.9     0.00000615     -4911.5499923340 -7.08E-06
    48 Broy./Diag. 0.40E+00    7.3     0.00000579     -4911.5500228743 -3.05E-05
    49 Broy./Diag. 0.40E+00    7.3     0.00000714     -4911.5499948871  2.80E-05
    50 Broy./Diag. 0.40E+00    7.0     0.00000424     -4911.5500014197 -6.53E-06
    51 Broy./Diag. 0.40E+00    7.3     0.00000258     -4911.5500030585 -1.64E-06
    52 Broy./Diag. 0.40E+00    7.1     0.00000262     -4911.5500158561 -1.28E-05
    53 Broy./Diag. 0.40E+00    7.2     0.00000354     -4911.5500131790  2.68E-06
    54 Broy./Diag. 0.40E+00    7.4     0.00000244     -4911.5499986332  1.45E-05
    55 Broy./Diag. 0.40E+00    6.7     0.00000394     -4911.5500166927 -1.81E-05
    56 Broy./Diag. 0.40E+00    7.1     0.00000276     -4911.5500138177  2.87E-06
    57 Broy./Diag. 0.40E+00    7.1     0.00000156     -4911.5500167549 -2.94E-06
    58 Broy./Diag. 0.40E+00    7.1     0.00000159     -4911.5500091197  7.64E-06
    59 Broy./Diag. 0.40E+00    7.3     0.00000192     -4911.5500129488 -3.83E-06
    60 Broy./Diag. 0.40E+00    7.2     0.00000142     -4911.5500218425 -8.89E-06
    61 Broy./Diag. 0.40E+00    7.3     0.00000213     -4911.5500128838  8.96E-06
    62 Broy./Diag. 0.40E+00    7.3     0.00000156     -4911.5500155997 -2.72E-06
    63 Broy./Diag. 0.40E+00    6.9     0.00000076     -4911.5500155874  1.24E-08

  *** SCF run converged in    63 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008284695746
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.73183869076274
  Hartree energy:                                            1781.52929018858640
  Exchange-correlation energy:                               -779.48464416884258
  Electronic entropic energy:                                  -0.23616065212449
  Fermi energy:                                                 0.08705148500342

  Total energy:                                             -4911.55001558735148

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.550022405976051

 MD| ***************************************************************************
 MD| Step number                                                            1135
 MD| Time [fs]                                                       2270.000000
 MD| Conserved quantity [hartree]                            -0.491115853915E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    455.727794           598.331633
 MD| Energy drift per atom [K]           0.334371070964E+03   0.270478497160E+03
 MD| Potential energy [hartree]         -0.491155002241E+04  -0.491156478591E+04
 MD| Kinetic energy [hartree]            0.391483252418E+00   0.375486417967E+00
 MD| Temperature [K]                            1043.210854          1000.583050
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.3     0.01725683     -4911.5473243415 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.04600795     -4911.5231442380  2.42E-02
     3 Broy./Diag. 0.40E+00    6.7     0.05307407     -4911.5802319050 -5.71E-02
     4 Broy./Diag. 0.40E+00    7.2     0.02279014     -4911.4717766602  1.08E-01
     5 Broy./Diag. 0.40E+00    7.4     0.01496940     -4911.5658050597 -9.40E-02
     6 Broy./Diag. 0.40E+00    7.5     0.01229483     -4911.5238476097  4.20E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00498141     -4911.5472664077 -2.34E-02
     8 Broy./Diag. 0.40E+00    7.1     0.00248738     -4911.5488231241 -1.56E-03
     9 Broy./Diag. 0.40E+00    6.7     0.00131381     -4911.5524016049 -3.58E-03
    10 Broy./Diag. 0.40E+00    7.5     0.00081475     -4911.5471629178  5.24E-03
    11 Broy./Diag. 0.40E+00    6.9     0.00059611     -4911.5457279067  1.44E-03
    12 Broy./Diag. 0.40E+00    7.2     0.00065518     -4911.5497605676 -4.03E-03
    13 Broy./Diag. 0.40E+00    6.8     0.00044197     -4911.5483795497  1.38E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00019489     -4911.5486711060 -2.92E-04
    15 Broy./Diag. 0.40E+00    6.9     0.00022005     -4911.5484921589  1.79E-04
    16 Broy./Diag. 0.40E+00    7.7     0.00015331     -4911.5492033661 -7.11E-04
    17 Broy./Diag. 0.40E+00    6.7     0.00015053     -4911.5491338865  6.95E-05
    18 Broy./Diag. 0.40E+00    7.7     0.00020257     -4911.5481872106  9.47E-04
    19 Broy./Diag. 0.40E+00    7.1     0.00017782     -4911.5491337378 -9.47E-04
    20 Broy./Diag. 0.40E+00    7.1     0.00009642     -4911.5490962651  3.75E-05
    21 Broy./Diag. 0.40E+00    7.3     0.00009859     -4911.5492509031 -1.55E-04
    22 Broy./Diag. 0.40E+00    7.5     0.00007888     -4911.5489935887  2.57E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00004717     -4911.5490273918 -3.38E-05
    24 Broy./Diag. 0.40E+00    6.8     0.00007604     -4911.5494108541 -3.83E-04
    25 Broy./Diag. 0.40E+00    7.0     0.00008068     -4911.5490956751  3.15E-04
    26 Broy./Diag. 0.40E+00    8.0     0.00004781     -4911.5491241614 -2.85E-05
    27 Broy./Diag. 0.40E+00    7.3     0.00004676     -4911.5491521472 -2.80E-05
    28 Broy./Diag. 0.40E+00    6.9     0.00004608     -4911.5493128966 -1.61E-04
    29 Broy./Diag. 0.40E+00    6.7     0.00003019     -4911.5493092015  3.70E-06
    30 Broy./Diag. 0.40E+00    6.8     0.00004058     -4911.5491379831  1.71E-04
    31 Broy./Diag. 0.40E+00    7.3     0.00004362     -4911.5493275334 -1.90E-04
    32 Broy./Diag. 0.40E+00    7.2     0.00002595     -4911.5493230785  4.45E-06
    33 Broy./Diag. 0.40E+00    7.5     0.00002133     -4911.5493359725 -1.29E-05
    34 Broy./Diag. 0.40E+00    6.6     0.00002592     -4911.5492594923  7.65E-05
    35 Broy./Diag. 0.40E+00    6.8     0.00001665     -4911.5492821443 -2.27E-05
    36 Broy./Diag. 0.40E+00    7.0     0.00002280     -4911.5493790475 -9.69E-05
    37 Broy./Diag. 0.40E+00    7.1     0.00002473     -4911.5492845940  9.45E-05
    38 Broy./Diag. 0.40E+00    7.0     0.00001571     -4911.5493204293 -3.58E-05
    39 Broy./Diag. 0.40E+00    7.3     0.00001111     -4911.5493155211  4.91E-06
    40 Broy./Diag. 0.40E+00    7.1     0.00001375     -4911.5493682045 -5.27E-05
    41 Broy./Diag. 0.40E+00    7.2     0.00001006     -4911.5493600011  8.20E-06
    42 Broy./Diag. 0.40E+00    7.3     0.00001017     -4911.5493113827  4.86E-05
    43 Broy./Diag. 0.40E+00    7.2     0.00001188     -4911.5493627080 -5.13E-05
    44 Broy./Diag. 0.40E+00    7.0     0.00000835     -4911.5493560381  6.67E-06
    45 Broy./Diag. 0.40E+00    7.5     0.00000515     -4911.5493646013 -8.56E-06
    46 Broy./Diag. 0.40E+00    6.8     0.00000783     -4911.5493441857  2.04E-05
    47 Broy./Diag. 0.40E+00    7.3     0.00000609     -4911.5493543285 -1.01E-05
    48 Broy./Diag. 0.40E+00    6.9     0.00000588     -4911.5493819978 -2.77E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00000724     -4911.5493583858  2.36E-05
    50 Broy./Diag. 0.40E+00    6.9     0.00000512     -4911.5493664023 -8.02E-06
    51 Broy./Diag. 0.40E+00    7.5     0.00000258     -4911.5493613231  5.08E-06
    52 Broy./Diag. 0.40E+00    7.3     0.00000400     -4911.5493778826 -1.66E-05
    53 Broy./Diag. 0.40E+00    7.1     0.00000362     -4911.5493741577  3.72E-06
    54 Broy./Diag. 0.40E+00    7.1     0.00000257     -4911.5493610344  1.31E-05
    55 Broy./Diag. 0.40E+00    6.6     0.00000417     -4911.5493766315 -1.56E-05
    56 Broy./Diag. 0.40E+00    7.3     0.00000327     -4911.5493737933  2.84E-06
    57 Broy./Diag. 0.40E+00    7.1     0.00000162     -4911.5493803837 -6.59E-06
    58 Broy./Diag. 0.40E+00    7.3     0.00000251     -4911.5493706505  9.73E-06
    59 Broy./Diag. 0.40E+00    6.9     0.00000204     -4911.5493742946 -3.64E-06
    60 Broy./Diag. 0.40E+00    7.3     0.00000142     -4911.5493822837 -7.99E-06
    61 Broy./Diag. 0.40E+00    7.3     0.00000222     -4911.5493756777  6.61E-06
    62 Broy./Diag. 0.40E+00    7.1     0.00000179     -4911.5493779549 -2.28E-06
    63 Broy./Diag. 0.40E+00    7.5     0.00000092     -4911.5493760111  1.94E-06

  *** SCF run converged in    63 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999974       -0.0000000026
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008286742395
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.72006090410969
  Hartree energy:                                            1781.53525468426551
  Exchange-correlation energy:                               -779.47811747014384
  Electronic entropic energy:                                  -0.23623451293315
  Fermi energy:                                                 0.08702817591834

  Total energy:                                             -4911.54937601106212

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.549384460871806

 MD| ***************************************************************************
 MD| Step number                                                            1136
 MD| Time [fs]                                                       2272.000000
 MD| Conserved quantity [hartree]                            -0.491118185313E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    457.934484           598.208044
 MD| Energy drift per atom [K]           0.285937107198E+03   0.270492105092E+03
 MD| Potential energy [hartree]         -0.491154938446E+04  -0.491156477235E+04
 MD| Kinetic energy [hartree]            0.367531331537E+00   0.375479415250E+00
 MD| Temperature [K]                             979.384614          1000.564389
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.01767656     -4911.5455899213 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.04791016     -4911.5363142049  9.28E-03
     3 Broy./Diag. 0.40E+00    6.9     0.05545188     -4911.5412613222 -4.95E-03
     4 Broy./Diag. 0.40E+00    6.8     0.02490566     -4911.5159387244  2.53E-02
     5 Broy./Diag. 0.40E+00    7.2     0.01558210     -4911.5440541390 -2.81E-02
     6 Broy./Diag. 0.40E+00    7.1     0.01283424     -4911.5612027367 -1.71E-02
     7 Broy./Diag. 0.40E+00    6.9     0.00464470     -4911.5308966463  3.03E-02
     8 Broy./Diag. 0.40E+00    6.8     0.00317037     -4911.5559301897 -2.50E-02
     9 Broy./Diag. 0.40E+00    7.1     0.00147557     -4911.5499769374  5.95E-03
    10 Broy./Diag. 0.40E+00    7.3     0.00089408     -4911.5457005198  4.28E-03
    11 Broy./Diag. 0.40E+00    6.9     0.00073682     -4911.5455819306  1.19E-04
    12 Broy./Diag. 0.40E+00    7.3     0.00066634     -4911.5468424840 -1.26E-03
    13 Broy./Diag. 0.40E+00    7.1     0.00043179     -4911.5481675960 -1.33E-03
    14 Broy./Diag. 0.40E+00    6.9     0.00025940     -4911.5464298054  1.74E-03
    15 Broy./Diag. 0.40E+00    7.3     0.00021316     -4911.5471706099 -7.41E-04
    16 Broy./Diag. 0.40E+00    6.9     0.00012529     -4911.5475133024 -3.43E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00015174     -4911.5473523992  1.61E-04
    18 Broy./Diag. 0.40E+00    7.4     0.00021366     -4911.5470760549  2.76E-04
    19 Broy./Diag. 0.40E+00    6.6     0.00016787     -4911.5468829149  1.93E-04
    20 Broy./Diag. 0.40E+00    7.2     0.00010481     -4911.5475700232 -6.87E-04
    21 Broy./Diag. 0.40E+00    7.3     0.00010755     -4911.5473012738  2.69E-04
    22 Broy./Diag. 0.40E+00    7.1     0.00005869     -4911.5472888927  1.24E-05
    23 Broy./Diag. 0.40E+00    7.3     0.00006330     -4911.5473785152 -8.96E-05
    24 Broy./Diag. 0.40E+00    7.1     0.00007396     -4911.5475220965 -1.44E-04
    25 Broy./Diag. 0.40E+00    7.0     0.00007998     -4911.5475719242 -4.98E-05
    26 Broy./Diag. 0.40E+00    7.3     0.00003906     -4911.5472313501  3.41E-04
    27 Broy./Diag. 0.40E+00    6.9     0.00005623     -4911.5474627230 -2.31E-04
    28 Broy./Diag. 0.40E+00    7.2     0.00003792     -4911.5475116995 -4.90E-05
    29 Broy./Diag. 0.40E+00    7.1     0.00002669     -4911.5475007026  1.10E-05
    30 Broy./Diag. 0.40E+00    7.0     0.00003844     -4911.5474491990  5.15E-05
    31 Broy./Diag. 0.40E+00    7.5     0.00003903     -4911.5474506238 -1.42E-06
    32 Broy./Diag. 0.40E+00    6.9     0.00001940     -4911.5476113358 -1.61E-04
    33 Broy./Diag. 0.40E+00    7.6     0.00002421     -4911.5475322083  7.91E-05
    34 Broy./Diag. 0.40E+00    7.6     0.00002044     -4911.5475102029  2.20E-05
    35 Broy./Diag. 0.40E+00    6.5     0.00001099     -4911.5475263016 -1.61E-05
    36 Broy./Diag. 0.40E+00    7.3     0.00001891     -4911.5475748027 -4.85E-05
    37 Broy./Diag. 0.40E+00    7.1     0.00002318     -4911.5475748168 -1.41E-08
    38 Broy./Diag. 0.40E+00    7.5     0.00001370     -4911.5474919473  8.29E-05
    39 Broy./Diag. 0.40E+00    6.9     0.00001352     -4911.5475613622 -6.94E-05
    40 Broy./Diag. 0.40E+00    7.2     0.00001204     -4911.5475801364 -1.88E-05
    41 Broy./Diag. 0.40E+00    6.9     0.00000563     -4911.5475786811  1.46E-06
    42 Broy./Diag. 0.40E+00    6.9     0.00000988     -4911.5475577156  2.10E-05
    43 Broy./Diag. 0.40E+00    7.5     0.00000981     -4911.5475565238  1.19E-06
    44 Broy./Diag. 0.40E+00    7.1     0.00000689     -4911.5475974195 -4.09E-05
    45 Broy./Diag. 0.40E+00    7.5     0.00000678     -4911.5475678070  2.96E-05
    46 Broy./Diag. 0.40E+00    8.0     0.00000753     -4911.5475671094  6.98E-07
    47 Broy./Diag. 0.40E+00    7.1     0.00000407     -4911.5475732286 -6.12E-06
    48 Broy./Diag. 0.40E+00    7.3     0.00000547     -4911.5475904964 -1.73E-05
    49 Broy./Diag. 0.40E+00    6.7     0.00000594     -4911.5475929169 -2.42E-06
    50 Broy./Diag. 0.40E+00    7.5     0.00000379     -4911.5475715918  2.13E-05
    51 Broy./Diag. 0.40E+00    7.5     0.00000289     -4911.5475867061 -1.51E-05
    52 Broy./Diag. 0.40E+00    7.3     0.00000325     -4911.5475907659 -4.06E-06
    53 Broy./Diag. 0.40E+00    7.7     0.00000215     -4911.5475897315  1.03E-06
    54 Broy./Diag. 0.40E+00    7.4     0.00000294     -4911.5475829391  6.79E-06
    55 Broy./Diag. 0.40E+00    7.3     0.00000338     -4911.5475842200 -1.28E-06
    56 Broy./Diag. 0.40E+00    7.3     0.00000255     -4911.5475978804 -1.37E-05
    57 Broy./Diag. 0.40E+00    7.2     0.00000196     -4911.5475901086  7.77E-06
    58 Broy./Diag. 0.40E+00    7.3     0.00000221     -4911.5475889901  1.12E-06
    59 Broy./Diag. 0.40E+00    7.1     0.00000130     -4911.5475904462 -1.46E-06
    60 Broy./Diag. 0.40E+00    6.9     0.00000127     -4911.5475950470 -4.60E-06
    61 Broy./Diag. 0.40E+00    7.5     0.00000177     -4911.5475953413 -2.94E-07
    62 Broy./Diag. 0.40E+00    7.9     0.00000127     -4911.5475881575  7.18E-06
    63 Broy./Diag. 0.40E+00    7.2     0.00000096     -4911.5475935057 -5.35E-06

  *** SCF run converged in    63 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008292322137
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.71465232988339
  Hartree energy:                                            1781.53736430330150
  Exchange-correlation energy:                               -779.47291931203154
  Electronic entropic energy:                                  -0.23635124285029
  Fermi energy:                                                 0.08701279153856

  Total energy:                                             -4911.54759350571658

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.547597620819033

 MD| ***************************************************************************
 MD| Step number                                                            1137
 MD| Time [fs]                                                       2274.000000
 MD| Conserved quantity [hartree]                            -0.491118866885E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    461.358921           598.087684
 MD| Energy drift per atom [K]           0.271777682846E+03   0.270493235767E+03
 MD| Potential energy [hartree]         -0.491154759762E+04  -0.491156475725E+04
 MD| Kinetic energy [hartree]            0.358928768577E+00   0.375464858832E+00
 MD| Temperature [K]                             956.460806          1000.525600
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.6     0.01932919     -4911.5435607623 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.5     0.04376074     -4911.5588221703 -1.53E-02
     3 Broy./Diag. 0.40E+00    7.3     0.05212763     -4911.4802579728  7.86E-02
     4 Broy./Diag. 0.40E+00    7.5     0.04248291     -4911.5782607878 -9.80E-02
     5 Broy./Diag. 0.40E+00    7.3     0.01917163     -4911.5176800488  6.06E-02
     6 Broy./Diag. 0.40E+00    7.5     0.00561150     -4911.5580343317 -4.04E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00479834     -4911.5307898850  2.72E-02
     8 Broy./Diag. 0.40E+00    7.5     0.00310433     -4911.5523466681 -2.16E-02
     9 Broy./Diag. 0.40E+00    6.9     0.00146326     -4911.5485009377  3.85E-03
    10 Broy./Diag. 0.40E+00    6.7     0.00172192     -4911.5424688660  6.03E-03
    11 Broy./Diag. 0.40E+00    6.9     0.00146679     -4911.5457770410 -3.31E-03
    12 Broy./Diag. 0.40E+00    7.3     0.00050739     -4911.5443908538  1.39E-03
    13 Broy./Diag. 0.40E+00    6.9     0.00027142     -4911.5460896436 -1.70E-03
    14 Broy./Diag. 0.40E+00    7.0     0.00025917     -4911.5446108236  1.48E-03
    15 Broy./Diag. 0.40E+00    7.1     0.00017606     -4911.5452747329 -6.64E-04
    16 Broy./Diag. 0.40E+00    6.9     0.00017623     -4911.5457117079 -4.37E-04
    17 Broy./Diag. 0.40E+00    6.9     0.00021108     -4911.5451602933  5.51E-04
    18 Broy./Diag. 0.40E+00    7.3     0.00014327     -4911.5453389393 -1.79E-04
    19 Broy./Diag. 0.40E+00    6.9     0.00009073     -4911.5450416753  2.97E-04
    20 Broy./Diag. 0.40E+00    6.9     0.00009502     -4911.5455262316 -4.85E-04
    21 Broy./Diag. 0.40E+00    7.1     0.00007869     -4911.5453009551  2.25E-04
    22 Broy./Diag. 0.40E+00    7.2     0.00005591     -4911.5452517914  4.92E-05
    23 Broy./Diag. 0.40E+00    7.1     0.00008431     -4911.5454646683 -2.13E-04
    24 Broy./Diag. 0.40E+00    7.0     0.00005965     -4911.5453865194  7.81E-05
    25 Broy./Diag. 0.40E+00    6.9     0.00003806     -4911.5454818020 -9.53E-05
    26 Broy./Diag. 0.40E+00    7.7     0.00004094     -4911.5452730060  2.09E-04
    27 Broy./Diag. 0.40E+00    7.0     0.00004216     -4911.5454344978 -1.61E-04
    28 Broy./Diag. 0.40E+00    7.1     0.00002968     -4911.5454697776 -3.53E-05
    29 Broy./Diag. 0.40E+00    8.0     0.00003990     -4911.5453664955  1.03E-04
    30 Broy./Diag. 0.40E+00    7.3     0.00003074     -4911.5454260697 -5.96E-05
    31 Broy./Diag. 0.40E+00   10.1     0.00001546     -4911.5453931725  3.29E-05
    32 Broy./Diag. 0.40E+00    7.2     0.00001666     -4911.5454926306 -9.95E-05
    33 Broy./Diag. 0.40E+00    9.8     0.00001919     -4911.5454303050  6.23E-05
    34 Broy./Diag. 0.40E+00    8.8     0.00001442     -4911.5454191632  1.11E-05
    35 Broy./Diag. 0.40E+00    7.1     0.00002132     -4911.5454776391 -5.85E-05
    36 Broy./Diag. 0.40E+00    7.3     0.00001747     -4911.5454505709  2.71E-05
    37 Broy./Diag. 0.40E+00    7.5     0.00000931     -4911.5454694434 -1.89E-05
    38 Broy./Diag. 0.40E+00    7.1     0.00000967     -4911.5454182611  5.12E-05
    39 Broy./Diag. 0.40E+00    7.2     0.00001021     -4911.5454676161 -4.94E-05
    40 Broy./Diag. 0.40E+00    8.0     0.00000688     -4911.5454749540 -7.34E-06
    41 Broy./Diag. 0.40E+00    6.8     0.00000948     -4911.5454514741  2.35E-05
    42 Broy./Diag. 0.40E+00    9.9     0.00000919     -4911.5454668561 -1.54E-05
    43 Broy./Diag. 0.40E+00    7.6     0.00000470     -4911.5454563041  1.06E-05
    44 Broy./Diag. 0.40E+00    9.8     0.00000519     -4911.5454807794 -2.45E-05
    45 Broy./Diag. 0.40E+00    8.6     0.00000572     -4911.5454579799  2.28E-05
    46 Broy./Diag. 0.40E+00    6.4     0.00000438     -4911.5454592671 -1.29E-06
    47 Broy./Diag. 0.40E+00    7.4     0.00000598     -4911.5454760980 -1.68E-05
    48 Broy./Diag. 0.40E+00    7.9     0.00000520     -4911.5454674527  8.65E-06
    49 Broy./Diag. 0.40E+00    7.9     0.00000268     -4911.5454746774 -7.22E-06
    50 Broy./Diag. 0.40E+00    8.6     0.00000265     -4911.5454634662  1.12E-05
    51 Broy./Diag. 0.40E+00    8.7     0.00000254     -4911.5454749828 -1.15E-05
    52 Broy./Diag. 0.40E+00    7.7     0.00000203     -4911.5454754749 -4.92E-07
    53 Broy./Diag. 0.40E+00   10.5     0.00000303     -4911.5454694927  5.98E-06
    54 Broy./Diag. 0.40E+00    7.2     0.00000322     -4911.5454743208 -4.83E-06
    55 Broy./Diag. 0.40E+00    7.1     0.00000180     -4911.5454707159  3.60E-06
    56 Broy./Diag. 0.40E+00    7.0     0.00000169     -4911.5454781245 -7.41E-06
    57 Broy./Diag. 0.40E+00    7.5     0.00000165     -4911.5454722935  5.83E-06
    58 Broy./Diag. 0.40E+00    7.1     0.00000123     -4911.5454729100 -6.17E-07
    59 Broy./Diag. 0.40E+00    7.1     0.00000156     -4911.5454766613 -3.75E-06
    60 Broy./Diag. 0.40E+00    7.3     0.00000145     -4911.5454747392  1.92E-06
    61 Broy./Diag. 0.40E+00    7.1     0.00000094     -4911.5454769166 -2.18E-06

  *** SCF run converged in    61 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008299174805
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.71546056030820
  Hartree energy:                                            1781.53561515873480
  Exchange-correlation energy:                               -779.46972024614877
  Electronic entropic energy:                                  -0.23649284905720
  Fermi energy:                                                 0.08700959150690

  Total energy:                                             -4911.54547691659172

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.545477725656383

 MD| ***************************************************************************
 MD| Step number                                                            1138
 MD| Time [fs]                                                       2276.000000
 MD| Conserved quantity [hartree]                            -0.491118026090E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    470.328047           597.975417
 MD| Energy drift per atom [K]           0.289244916526E+03   0.270509713518E+03
 MD| Potential energy [hartree]         -0.491154547773E+04  -0.491156474031E+04
 MD| Kinetic energy [hartree]            0.365216829964E+00   0.375455853534E+00
 MD| Temperature [K]                             973.217012          1000.501603
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.02284758     -4911.5405162803 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.5     0.05332296     -4911.5956126590 -5.51E-02
     3 Broy./Diag. 0.40E+00    7.3     0.07660045     -4911.3881319725  2.07E-01
     4 Broy./Diag. 0.40E+00    7.1     0.05273599     -4911.6318809807 -2.44E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01675804     -4911.5261855377  1.06E-01
     6 Broy./Diag. 0.40E+00    7.0     0.00662147     -4911.5427282280 -1.65E-02
     7 Broy./Diag. 0.40E+00    6.9     0.00390324     -4911.5304149975  1.23E-02
     8 Broy./Diag. 0.40E+00    7.1     0.00212656     -4911.5545268446 -2.41E-02
     9 Broy./Diag. 0.40E+00    6.9     0.00138917     -4911.5419990446  1.25E-02
    10 Broy./Diag. 0.40E+00    6.9     0.00163614     -4911.5403360288  1.66E-03
    11 Broy./Diag. 0.40E+00    7.4     0.00111334     -4911.5448997138 -4.56E-03
    12 Broy./Diag. 0.40E+00    7.1     0.00033835     -4911.5426557984  2.24E-03
    13 Broy./Diag. 0.40E+00    7.3     0.00028300     -4911.5426317553  2.40E-05
    14 Broy./Diag. 0.40E+00    7.1     0.00015772     -4911.5420145354  6.17E-04
    15 Broy./Diag. 0.40E+00    7.0     0.00016958     -4911.5431811558 -1.17E-03
    16 Broy./Diag. 0.40E+00    8.3     0.00018579     -4911.5428227040  3.58E-04
    17 Broy./Diag. 0.40E+00    7.5     0.00020591     -4911.5422180059  6.05E-04
    18 Broy./Diag. 0.40E+00    7.3     0.00009826     -4911.5426670151 -4.49E-04
    19 Broy./Diag. 0.40E+00    7.4     0.00008432     -4911.5426641325  2.88E-06
    20 Broy./Diag. 0.40E+00    7.3     0.00005421     -4911.5427379410 -7.38E-05
    21 Broy./Diag. 0.40E+00    7.2     0.00006391     -4911.5423304355  4.08E-04
    22 Broy./Diag. 0.40E+00    7.3     0.00006008     -4911.5425696679 -2.39E-04
    23 Broy./Diag. 0.40E+00    7.4     0.00007906     -4911.5427629656 -1.93E-04
    24 Broy./Diag. 0.40E+00    7.1     0.00004301     -4911.5425614211  2.02E-04
    25 Broy./Diag. 0.40E+00    7.3     0.00003390     -4911.5425508732  1.05E-05
    26 Broy./Diag. 0.40E+00    6.8     0.00003344     -4911.5425239467  2.69E-05
    27 Broy./Diag. 0.40E+00    7.3     0.00003546     -4911.5426982770 -1.74E-04
    28 Broy./Diag. 0.40E+00    7.1     0.00003084     -4911.5425497572  1.49E-04
    29 Broy./Diag. 0.40E+00    6.7     0.00004032     -4911.5424614641  8.83E-05
    30 Broy./Diag. 0.40E+00    6.9     0.00002429     -4911.5425819629 -1.20E-04
    31 Broy./Diag. 0.40E+00    7.3     0.00001697     -4911.5425831735 -1.21E-06
    32 Broy./Diag. 0.40E+00    7.0     0.00001520     -4911.5425917261 -8.55E-06
    33 Broy./Diag. 0.40E+00    6.9     0.00001686     -4911.5425191691  7.26E-05
    34 Broy./Diag. 0.40E+00    7.5     0.00001450     -4911.5425913456 -7.22E-05
    35 Broy./Diag. 0.40E+00    7.3     0.00002083     -4911.5426181546 -2.68E-05
    36 Broy./Diag. 0.40E+00    7.3     0.00001403     -4911.5425485088  6.96E-05
    37 Broy./Diag. 0.40E+00    6.9     0.00000944     -4911.5425531829 -4.67E-06
    38 Broy./Diag. 0.40E+00    7.1     0.00000889     -4911.5425492964  3.89E-06
    39 Broy./Diag. 0.40E+00    7.3     0.00000789     -4911.5425898278 -4.05E-05
    40 Broy./Diag. 0.40E+00    6.9     0.00000661     -4911.5425532164  3.66E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00000980     -4911.5425449899  8.23E-06
    42 Broy./Diag. 0.40E+00    7.3     0.00000779     -4911.5425773453 -3.24E-05
    43 Broy./Diag. 0.40E+00    7.5     0.00000476     -4911.5425702007  7.14E-06
    44 Broy./Diag. 0.40E+00    7.4     0.00000455     -4911.5425677962  2.40E-06
    45 Broy./Diag. 0.40E+00    6.9     0.00000449     -4911.5425459830  2.18E-05
    46 Broy./Diag. 0.40E+00    7.1     0.00000426     -4911.5425679083 -2.19E-05
    47 Broy./Diag. 0.40E+00    6.7     0.00000590     -4911.5425711732 -3.26E-06
    48 Broy./Diag. 0.40E+00    7.3     0.00000441     -4911.5425519917  1.92E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00000244     -4911.5425585873 -6.60E-06
    50 Broy./Diag. 0.40E+00    7.1     0.00000197     -4911.5425586674 -8.02E-08
    51 Broy./Diag. 0.40E+00    7.1     0.00000203     -4911.5425681795 -9.51E-06
    52 Broy./Diag. 0.40E+00    6.9     0.00000214     -4911.5425577890  1.04E-05
    53 Broy./Diag. 0.40E+00    7.3     0.00000333     -4911.5425566704  1.12E-06
    54 Broy./Diag. 0.40E+00    7.1     0.00000286     -4911.5425666881 -1.00E-05
    55 Broy./Diag. 0.40E+00    6.7     0.00000147     -4911.5425609483  5.74E-06
    56 Broy./Diag. 0.40E+00    7.5     0.00000121     -4911.5425609762 -2.79E-08
    57 Broy./Diag. 0.40E+00    7.3     0.00000125     -4911.5425563451  4.63E-06
    58 Broy./Diag. 0.40E+00    7.1     0.00000115     -4911.5425619049 -5.56E-06
    59 Broy./Diag. 0.40E+00    7.8     0.00000156     -4911.5425620190 -1.14E-07
    60 Broy./Diag. 0.40E+00    7.5     0.00000138     -4911.5425574839  4.54E-06
    61 Broy./Diag. 0.40E+00    7.3     0.00000086     -4911.5425604671 -2.98E-06

  *** SCF run converged in    61 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008307806177
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.72795060914950
  Hartree energy:                                            1781.52674692102437
  Exchange-correlation energy:                               -779.47023304077834
  Electronic entropic energy:                                  -0.23668551799942
  Fermi energy:                                                 0.08702301793454

  Total energy:                                             -4911.54256046714181

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.542559177299154

 MD| ***************************************************************************
 MD| Step number                                                            1139
 MD| Time [fs]                                                       2278.000000
 MD| Conserved quantity [hartree]                            -0.491117953998E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    446.777666           597.842671
 MD| Energy drift per atom [K]           0.290742584213E+03   0.270527477232E+03
 MD| Potential energy [hartree]         -0.491154255918E+04  -0.491156472083E+04
 MD| Kinetic energy [hartree]            0.363019192832E+00   0.375444934605E+00
 MD| Temperature [K]                             967.360825          1000.472507
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02356515     -4911.5363257531 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.7     0.07316198     -4911.6365235974 -1.00E-01
     3 Broy./Diag. 0.40E+00    6.9     0.09348987     -4911.2679388839  3.69E-01
     4 Broy./Diag. 0.40E+00    6.6     0.05576508     -4911.6495522118 -3.82E-01
     5 Broy./Diag. 0.40E+00    6.8     0.01615297     -4911.5398023340  1.10E-01
     6 Broy./Diag. 0.40E+00    6.7     0.00578808     -4911.5267763526  1.30E-02
     7 Broy./Diag. 0.40E+00    7.0     0.00418741     -4911.5278940519 -1.12E-03
     8 Broy./Diag. 0.40E+00    7.3     0.00248437     -4911.5523035934 -2.44E-02
     9 Broy./Diag. 0.40E+00    7.1     0.00151853     -4911.5364687255  1.58E-02
    10 Broy./Diag. 0.40E+00    6.9     0.00180251     -4911.5363097518  1.59E-04
    11 Broy./Diag. 0.40E+00    7.2     0.00114939     -4911.5414868958 -5.18E-03
    12 Broy./Diag. 0.40E+00    7.3     0.00045195     -4911.5392151018  2.27E-03
    13 Broy./Diag. 0.40E+00    7.6     0.00025282     -4911.5379629044  1.25E-03
    14 Broy./Diag. 0.40E+00    7.3     0.00018542     -4911.5378512960  1.12E-04
    15 Broy./Diag. 0.40E+00    7.3     0.00018297     -4911.5392823789 -1.43E-03
    16 Broy./Diag. 0.40E+00    7.3     0.00019480     -4911.5387096502  5.73E-04
    17 Broy./Diag. 0.40E+00    7.2     0.00021652     -4911.5380945450  6.15E-04
    18 Broy./Diag. 0.40E+00    7.1     0.00010376     -4911.5385819735 -4.87E-04
    19 Broy./Diag. 0.40E+00    7.1     0.00009141     -4911.5387992283 -2.17E-04
    20 Broy./Diag. 0.40E+00    7.1     0.00006777     -4911.5386310594  1.68E-04
    21 Broy./Diag. 0.40E+00    8.0     0.00006827     -4911.5381835308  4.48E-04
    22 Broy./Diag. 0.40E+00    6.8     0.00006196     -4911.5385214643 -3.38E-04
    23 Broy./Diag. 0.40E+00    7.2     0.00007380     -4911.5387112312 -1.90E-04
    24 Broy./Diag. 0.40E+00    6.8     0.00003513     -4911.5385001360  2.11E-04
    25 Broy./Diag. 0.40E+00    7.0     0.00004175     -4911.5384374007  6.27E-05
    26 Broy./Diag. 0.40E+00    7.4     0.00003726     -4911.5385150420 -7.76E-05
    27 Broy./Diag. 0.40E+00    7.0     0.00003705     -4911.5386664428 -1.51E-04
    28 Broy./Diag. 0.40E+00    7.2     0.00003201     -4911.5384625330  2.04E-04
    29 Broy./Diag. 0.40E+00    7.3     0.00004206     -4911.5383845161  7.80E-05
    30 Broy./Diag. 0.40E+00    7.3     0.00002118     -4911.5385177752 -1.33E-04
    31 Broy./Diag. 0.40E+00    7.1     0.00001870     -4911.5385356969 -1.79E-05
    32 Broy./Diag. 0.40E+00    7.3     0.00001445     -4911.5384994749  3.62E-05
    33 Broy./Diag. 0.40E+00    6.8     0.00001694     -4911.5384535782  4.59E-05
    34 Broy./Diag. 0.40E+00    7.1     0.00001415     -4911.5385424399 -8.89E-05
    35 Broy./Diag. 0.40E+00    7.3     0.00002192     -4911.5385515851 -9.15E-06
    36 Broy./Diag. 0.40E+00    7.1     0.00001346     -4911.5384750892  7.65E-05
    37 Broy./Diag. 0.40E+00    7.1     0.00001111     -4911.5384772328 -2.14E-06
    38 Broy./Diag. 0.40E+00    7.7     0.00000910     -4911.5384970380 -1.98E-05
    39 Broy./Diag. 0.40E+00    7.3     0.00000783     -4911.5385194961 -2.25E-05
    40 Broy./Diag. 0.40E+00    7.2     0.00000644     -4911.5384780519  4.14E-05
    41 Broy./Diag. 0.40E+00    7.7     0.00000990     -4911.5384799136 -1.86E-06
    42 Broy./Diag. 0.40E+00    6.7     0.00000713     -4911.5385127401 -3.28E-05
    43 Broy./Diag. 0.40E+00    6.7     0.00000459     -4911.5385033989  9.34E-06
    44 Broy./Diag. 0.40E+00    8.1     0.00000454     -4911.5384912695  1.21E-05
    45 Broy./Diag. 0.40E+00    7.3     0.00000492     -4911.5384816003  9.67E-06
    46 Broy./Diag. 0.40E+00    7.3     0.00000461     -4911.5385059206 -2.43E-05
    47 Broy./Diag. 0.40E+00    6.5     0.00000621     -4911.5385000811  5.84E-06
    48 Broy./Diag. 0.40E+00    6.9     0.00000446     -4911.5384798132  2.03E-05
    49 Broy./Diag. 0.40E+00    6.9     0.00000233     -4911.5384884917 -8.68E-06
    50 Broy./Diag. 0.40E+00    7.3     0.00000175     -4911.5384934837 -4.99E-06
    51 Broy./Diag. 0.40E+00    7.0     0.00000191     -4911.5384958617 -2.38E-06
    52 Broy./Diag. 0.40E+00    7.5     0.00000216     -4911.5384862148  9.65E-06
    53 Broy./Diag. 0.40E+00    7.0     0.00000348     -4911.5384896823 -3.47E-06
    54 Broy./Diag. 0.40E+00    6.9     0.00000301     -4911.5384996654 -9.98E-06
    55 Broy./Diag. 0.40E+00    6.9     0.00000157     -4911.5384915203  8.15E-06
    56 Broy./Diag. 0.40E+00    7.1     0.00000130     -4911.5384883815  3.14E-06
    57 Broy./Diag. 0.40E+00    7.1     0.00000130     -4911.5384877291  6.52E-07
    58 Broy./Diag. 0.40E+00    7.1     0.00000115     -4911.5384933936 -5.66E-06
    59 Broy./Diag. 0.40E+00    7.3     0.00000144     -4911.5384908681  2.53E-06
    60 Broy./Diag. 0.40E+00    7.1     0.00000133     -4911.5384868849  3.98E-06
    61 Broy./Diag. 0.40E+00    7.1     0.00000085     -4911.5384906745 -3.79E-06

  *** SCF run converged in    61 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008319285361
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.75204309488799
  Hartree energy:                                            1781.51107825332770
  Exchange-correlation energy:                               -779.47431363411783
  Electronic entropic energy:                                  -0.23695907549026
  Fermi energy:                                                 0.08705257881132

  Total energy:                                             -4911.53849067449119

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.538488852457704

 MD| ***************************************************************************
 MD| Step number                                                            1140
 MD| Time [fs]                                                       2280.000000
 MD| Conserved quantity [hartree]                            -0.491117914836E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    443.785868           597.707534
 MD| Energy drift per atom [K]           0.291556176248E+03   0.270545923460E+03
 MD| Potential energy [hartree]         -0.491153848885E+04  -0.491156469782E+04
 MD| Kinetic energy [hartree]            0.359340495343E+00   0.375430807904E+00
 MD| Temperature [K]                             957.557961          1000.434862
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.02705452     -4911.5315880921 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.9     0.10366347     -4911.6650861997 -1.33E-01
     3 Broy./Diag. 0.40E+00    7.0     0.11016034     -4911.1693939379  4.96E-01
     4 Broy./Diag. 0.40E+00    7.1     0.04801564     -4911.6207623653 -4.51E-01
     5 Broy./Diag. 0.40E+00    7.3     0.01312490     -4911.5522359307  6.85E-02
     6 Broy./Diag. 0.40E+00    7.1     0.00575232     -4911.5150668025  3.72E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00371501     -4911.5300344565 -1.50E-02
     8 Broy./Diag. 0.40E+00    7.3     0.00223859     -4911.5474029190 -1.74E-02
     9 Broy./Diag. 0.40E+00    6.9     0.00119553     -4911.5313047428  1.61E-02
    10 Broy./Diag. 0.40E+00    7.5     0.00092893     -4911.5351234488 -3.82E-03
    11 Broy./Diag. 0.40E+00    7.3     0.00067643     -4911.5354576297 -3.34E-04
    12 Broy./Diag. 0.40E+00    7.0     0.00031301     -4911.5338935691  1.56E-03
    13 Broy./Diag. 0.40E+00    7.1     0.00025664     -4911.5328557901  1.04E-03
    14 Broy./Diag. 0.40E+00    7.3     0.00018397     -4911.5337902896 -9.34E-04
    15 Broy./Diag. 0.40E+00    7.6     0.00013038     -4911.5348543209 -1.06E-03
    16 Broy./Diag. 0.40E+00    6.7     0.00012664     -4911.5336414339  1.21E-03
    17 Broy./Diag. 0.40E+00    7.3     0.00019624     -4911.5336336241  7.81E-06
    18 Broy./Diag. 0.40E+00    7.1     0.00009089     -4911.5340426366 -4.09E-04
    19 Broy./Diag. 0.40E+00    6.9     0.00009184     -4911.5340702971 -2.77E-05
    20 Broy./Diag. 0.40E+00    7.1     0.00005079     -4911.5336853117  3.85E-04
    21 Broy./Diag. 0.40E+00    7.5     0.00005694     -4911.5335387241  1.47E-04
    22 Broy./Diag. 0.40E+00    7.1     0.00005039     -4911.5339968080 -4.58E-04
    23 Broy./Diag. 0.40E+00    7.2     0.00006786     -4911.5338805140  1.16E-04
    24 Broy./Diag. 0.40E+00    7.2     0.00004251     -4911.5337004909  1.80E-04
    25 Broy./Diag. 0.40E+00    7.3     0.00004738     -4911.5337238005 -2.33E-05
    26 Broy./Diag. 0.40E+00    7.5     0.00002791     -4911.5338871748 -1.63E-04
    27 Broy./Diag. 0.40E+00    7.2     0.00003102     -4911.5338301629  5.70E-05
    28 Broy./Diag. 0.40E+00    7.7     0.00002564     -4911.5336353007  1.95E-04
    29 Broy./Diag. 0.40E+00    6.7     0.00003023     -4911.5337240513 -8.88E-05
    30 Broy./Diag. 0.40E+00    7.1     0.00002096     -4911.5337948864 -7.08E-05
    31 Broy./Diag. 0.40E+00    7.7     0.00001361     -4911.5337614198  3.35E-05
    32 Broy./Diag. 0.40E+00    6.9     0.00001084     -4911.5337156123  4.58E-05
    33 Broy./Diag. 0.40E+00    7.3     0.00001535     -4911.5337384239 -2.28E-05
    34 Broy./Diag. 0.40E+00    7.8     0.00001312     -4911.5338070546 -6.86E-05
    35 Broy./Diag. 0.40E+00    7.1     0.00001639     -4911.5337370137  7.00E-05
    36 Broy./Diag. 0.40E+00    7.5     0.00001480     -4911.5337032110  3.38E-05
    37 Broy./Diag. 0.40E+00    7.5     0.00000793     -4911.5337348868 -3.17E-05
    38 Broy./Diag. 0.40E+00    6.9     0.00000630     -4911.5337522958 -1.74E-05
    39 Broy./Diag. 0.40E+00    7.3     0.00000530     -4911.5337350201  1.73E-05
    40 Broy./Diag. 0.40E+00    7.1     0.00000545     -4911.5337176989  1.73E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00000714     -4911.5337430910 -2.54E-05
    42 Broy./Diag. 0.40E+00    8.1     0.00000750     -4911.5337503171 -7.23E-06
    43 Broy./Diag. 0.40E+00    7.4     0.00000415     -4911.5337285418  2.18E-05
    44 Broy./Diag. 0.40E+00    7.3     0.00000378     -4911.5337231823  5.36E-06
    45 Broy./Diag. 0.40E+00    7.1     0.00000356     -4911.5337367201 -1.35E-05
    46 Broy./Diag. 0.40E+00    7.3     0.00000325     -4911.5337398491 -3.13E-06
    47 Broy./Diag. 0.40E+00    7.0     0.00000325     -4911.5337237342  1.61E-05
    48 Broy./Diag. 0.40E+00    7.3     0.00000342     -4911.5337222698  1.46E-06
    49 Broy./Diag. 0.40E+00    7.1     0.00000193     -4911.5337319934 -9.72E-06
    50 Broy./Diag. 0.40E+00    6.9     0.00000117     -4911.5337324331 -4.40E-07
    51 Broy./Diag. 0.40E+00    7.1     0.00000114     -4911.5337250612  7.37E-06
    52 Broy./Diag. 0.40E+00    7.3     0.00000178     -4911.5337256532 -5.92E-07
    53 Broy./Diag. 0.40E+00    7.3     0.00000200     -4911.5337340056 -8.35E-06
    54 Broy./Diag. 0.40E+00    6.8     0.00000246     -4911.5337314196  2.59E-06
    55 Broy./Diag. 0.40E+00    6.9     0.00000151     -4911.5337236345  7.79E-06
    56 Broy./Diag. 0.40E+00    7.1     0.00000087     -4911.5337239228 -2.88E-07

  *** SCF run converged in    56 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008333631661
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.78234090688102
  Hartree energy:                                            1781.49207433516494
  Exchange-correlation energy:                               -779.48053247894018
  Electronic entropic energy:                                  -0.23726753806030
  Fermi energy:                                                 0.08709013730186

  Total energy:                                             -4911.53372392284291

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.533725154776221

 MD| ***************************************************************************
 MD| Step number                                                            1141
 MD| Time [fs]                                                       2282.000000
 MD| Conserved quantity [hartree]                            -0.491117938998E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    412.086899           597.544851
 MD| Energy drift per atom [K]           0.291054221470E+03   0.270563897428E+03
 MD| Potential energy [hartree]         -0.491153372515E+04  -0.491156467068E+04
 MD| Kinetic energy [hartree]            0.354335178752E+00   0.375412319184E+00
 MD| Temperature [K]                             944.219969          1000.385594
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02286841     -4911.5265717254 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.6     0.09086989     -4911.6441547513 -1.18E-01
     3 Broy./Diag. 0.40E+00    6.8     0.09660040     -4911.2320324153  4.12E-01
     4 Broy./Diag. 0.40E+00    7.7     0.04209363     -4911.6046828148 -3.73E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01227670     -4911.5431253931  6.16E-02
     6 Broy./Diag. 0.40E+00    7.3     0.00479338     -4911.5179186198  2.52E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00344922     -4911.5232317771 -5.31E-03
     8 Broy./Diag. 0.40E+00    7.0     0.00201834     -4911.5446886235 -2.15E-02
     9 Broy./Diag. 0.40E+00    7.1     0.00068889     -4911.5273714597  1.73E-02
    10 Broy./Diag. 0.40E+00    7.3     0.00068575     -4911.5306619068 -3.29E-03
    11 Broy./Diag. 0.40E+00    7.1     0.00062272     -4911.5307703646 -1.08E-04
    12 Broy./Diag. 0.40E+00    7.1     0.00026246     -4911.5290728622  1.70E-03
    13 Broy./Diag. 0.40E+00    7.0     0.00023301     -4911.5284133152  6.60E-04
    14 Broy./Diag. 0.40E+00    6.7     0.00016711     -4911.5291264469 -7.13E-04
    15 Broy./Diag. 0.40E+00    7.3     0.00013060     -4911.5301424922 -1.02E-03
    16 Broy./Diag. 0.40E+00    7.1     0.00007279     -4911.5287525568  1.39E-03
    17 Broy./Diag. 0.40E+00    7.2     0.00014751     -4911.5288260688 -7.35E-05
    18 Broy./Diag. 0.40E+00    7.1     0.00011983     -4911.5290674272 -2.41E-04
    19 Broy./Diag. 0.40E+00    6.9     0.00008279     -4911.5288811406  1.86E-04
    20 Broy./Diag. 0.40E+00    6.9     0.00004998     -4911.5285965606  2.85E-04
    21 Broy./Diag. 0.40E+00    7.1     0.00005378     -4911.5286154094 -1.88E-05
    22 Broy./Diag. 0.40E+00    7.3     0.00003899     -4911.5290471030 -4.32E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00003734     -4911.5286525905  3.95E-04
    24 Broy./Diag. 0.40E+00    7.1     0.00004230     -4911.5285724738  8.01E-05
    25 Broy./Diag. 0.40E+00    7.0     0.00002364     -4911.5286455040 -7.30E-05
    26 Broy./Diag. 0.40E+00    7.1     0.00002027     -4911.5286969311 -5.14E-05
    27 Broy./Diag. 0.40E+00    7.2     0.00001036     -4911.5286434832  5.34E-05
    28 Broy./Diag. 0.40E+00    6.7     0.00001113     -4911.5285892231  5.43E-05
    29 Broy./Diag. 0.40E+00    7.3     0.00001196     -4911.5286681670 -7.89E-05
    30 Broy./Diag. 0.40E+00    6.9     0.00001573     -4911.5286727526 -4.59E-06
    31 Broy./Diag. 0.40E+00    7.1     0.00000742     -4911.5286217398  5.10E-05
    32 Broy./Diag. 0.40E+00    7.5     0.00000845     -4911.5286136110  8.13E-06
    33 Broy./Diag. 0.40E+00    7.9     0.00000524     -4911.5286359187 -2.23E-05
    34 Broy./Diag. 0.40E+00    7.1     0.00000451     -4911.5286359924 -7.38E-08
    35 Broy./Diag. 0.40E+00   10.2     0.00000336     -4911.5286104733  2.55E-05
    36 Broy./Diag. 0.40E+00    7.4     0.00000582     -4911.5286101143  3.59E-07
    37 Broy./Diag. 0.40E+00    9.1     0.00000312     -4911.5286260881 -1.60E-05
    38 Broy./Diag. 0.40E+00    9.0     0.00000214     -4911.5286207879  5.30E-06
    39 Broy./Diag. 0.40E+00    7.1     0.00000183     -4911.5286118512  8.94E-06
    40 Broy./Diag. 0.40E+00    6.9     0.00000241     -4911.5286140007 -2.15E-06
    41 Broy./Diag. 0.40E+00    7.2     0.00000204     -4911.5286209862 -6.99E-06
    42 Broy./Diag. 0.40E+00    6.9     0.00000371     -4911.5286147438  6.24E-06
    43 Broy./Diag. 0.40E+00    7.5     0.00000275     -4911.5286047648  9.98E-06
    44 Broy./Diag. 0.40E+00    7.4     0.00000165     -4911.5286094514 -4.69E-06
    45 Broy./Diag. 0.40E+00    7.1     0.00000106     -4911.5286129171 -3.47E-06
    46 Broy./Diag. 0.40E+00    9.9     0.00000075     -4911.5286093866  3.53E-06

  *** SCF run converged in    46 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008349735838
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.81584652399306
  Hartree energy:                                            1781.47117276978815
  Exchange-correlation energy:                               -779.48771112316922
  Electronic entropic energy:                                  -0.23757853950081
  Fermi energy:                                                 0.08713282791182

  Total energy:                                             -4911.52860938659978

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.528604627473214

 MD| ***************************************************************************
 MD| Step number                                                            1142
 MD| Time [fs]                                                       2284.000000
 MD| Conserved quantity [hartree]                            -0.491118318511E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    347.538583           597.325932
 MD| Energy drift per atom [K]           0.283169971445E+03   0.270574936022E+03
 MD| Potential energy [hartree]         -0.491152860463E+04  -0.491156463910E+04
 MD| Kinetic energy [hartree]            0.345419520929E+00   0.375386055788E+00
 MD| Temperature [K]                             920.461836          1000.315608
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    8.0     0.01743290     -4911.5214507878 -4.91E+03
     2 Broy./Diag. 0.40E+00    8.9     0.07365394     -4911.6294622770 -1.08E-01
     3 Broy./Diag. 0.40E+00    7.3     0.08133400     -4911.2716303617  3.58E-01
     4 Broy./Diag. 0.40E+00    7.1     0.04032146     -4911.5957152732 -3.24E-01
     5 Broy./Diag. 0.40E+00    8.6     0.01483520     -4911.5322398285  6.35E-02
     6 Broy./Diag. 0.40E+00    7.4     0.00524220     -4911.5202588677  1.20E-02
     7 Broy./Diag. 0.40E+00    8.5     0.00403155     -4911.5135478669  6.71E-03
     8 Broy./Diag. 0.40E+00    9.1     0.00216148     -4911.5401866155 -2.66E-02
     9 Broy./Diag. 0.40E+00    7.6     0.00148246     -4911.5253889677  1.48E-02
    10 Broy./Diag. 0.40E+00   11.2     0.00151576     -4911.5208546892  4.53E-03
    11 Broy./Diag. 0.40E+00    7.6     0.00114237     -4911.5269217505 -6.07E-03
    12 Broy./Diag. 0.40E+00    7.1     0.00045153     -4911.5255246446  1.40E-03
    13 Broy./Diag. 0.40E+00    7.3     0.00027402     -4911.5243612678  1.16E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00020480     -4911.5235716310  7.90E-04
    15 Broy./Diag. 0.40E+00    7.1     0.00028149     -4911.5253227868 -1.75E-03
    16 Broy./Diag. 0.40E+00    6.5     0.00021242     -4911.5250406622  2.82E-04
    17 Broy./Diag. 0.40E+00    6.9     0.00028445     -4911.5234899027  1.55E-03
    18 Broy./Diag. 0.40E+00    6.8     0.00016178     -4911.5238794861 -3.90E-04
    19 Broy./Diag. 0.40E+00    7.6     0.00012879     -4911.5241987278 -3.19E-04
    20 Broy./Diag. 0.40E+00    7.1     0.00010572     -4911.5242105137 -1.18E-05
    21 Broy./Diag. 0.40E+00    6.9     0.00008956     -4911.5234494676  7.61E-04
    22 Broy./Diag. 0.40E+00    7.1     0.00009404     -4911.5236087425 -1.59E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00012629     -4911.5242537726 -6.45E-04
    24 Broy./Diag. 0.40E+00    7.3     0.00007006     -4911.5238271437  4.27E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00005729     -4911.5235721749  2.55E-04
    26 Broy./Diag. 0.40E+00    7.3     0.00007417     -4911.5235889594 -1.68E-05
    27 Broy./Diag. 0.40E+00    6.8     0.00005497     -4911.5239174245 -3.28E-04
    28 Broy./Diag. 0.40E+00    7.2     0.00004727     -4911.5236670440  2.50E-04
    29 Broy./Diag. 0.40E+00    7.5     0.00005734     -4911.5233953032  2.72E-04
    30 Broy./Diag. 0.40E+00    7.1     0.00003310     -4911.5235671153 -1.72E-04
    31 Broy./Diag. 0.40E+00    7.3     0.00001859     -4911.5236164985 -4.94E-05
    32 Broy./Diag. 0.40E+00    7.5     0.00002125     -4911.5235762890  4.02E-05
    33 Broy./Diag. 0.40E+00    7.0     0.00002389     -4911.5234755311  1.01E-04
    34 Broy./Diag. 0.40E+00    6.9     0.00003272     -4911.5235743572 -9.88E-05
    35 Broy./Diag. 0.40E+00    7.5     0.00003822     -4911.5236487057 -7.43E-05
    36 Broy./Diag. 0.40E+00    7.6     0.00002711     -4911.5234702587  1.78E-04
    37 Broy./Diag. 0.40E+00    7.4     0.00001504     -4911.5234437023  2.66E-05
    38 Broy./Diag. 0.40E+00    7.1     0.00001463     -4911.5234675947 -2.39E-05
    39 Broy./Diag. 0.40E+00    7.1     0.00000955     -4911.5235086089 -4.10E-05
    40 Broy./Diag. 0.40E+00    7.2     0.00000793     -4911.5234643559  4.43E-05
    41 Broy./Diag. 0.40E+00    7.5     0.00001265     -4911.5234460221  1.83E-05
    42 Broy./Diag. 0.40E+00    7.3     0.00001348     -4911.5234979823 -5.20E-05
    43 Broy./Diag. 0.40E+00    7.3     0.00000734     -4911.5234874932  1.05E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00000762     -4911.5234438779  4.36E-05
    45 Broy./Diag. 0.40E+00    7.5     0.00000734     -4911.5234295290  1.43E-05
    46 Broy./Diag. 0.40E+00    6.9     0.00000754     -4911.5234591030 -2.96E-05
    47 Broy./Diag. 0.40E+00    7.5     0.00000577     -4911.5234615717 -2.47E-06
    48 Broy./Diag. 0.40E+00    7.5     0.00000487     -4911.5234309895  3.06E-05
    49 Broy./Diag. 0.40E+00    7.3     0.00000222     -4911.5234338491 -2.86E-06
    50 Broy./Diag. 0.40E+00    7.1     0.00000217     -4911.5234436826 -9.83E-06
    51 Broy./Diag. 0.40E+00    6.9     0.00000212     -4911.5234434449  2.38E-07
    52 Broy./Diag. 0.40E+00    7.1     0.00000343     -4911.5234270516  1.64E-05
    53 Broy./Diag. 0.40E+00    7.1     0.00000449     -4911.5234288502 -1.80E-06
    54 Broy./Diag. 0.40E+00    7.3     0.00000500     -4911.5234482404 -1.94E-05
    55 Broy./Diag. 0.40E+00    7.1     0.00000197     -4911.5234352903  1.30E-05
    56 Broy./Diag. 0.40E+00    7.3     0.00000136     -4911.5234238931  1.14E-05
    57 Broy./Diag. 0.40E+00    7.1     0.00000108     -4911.5234243013 -4.08E-07
    58 Broy./Diag. 0.40E+00    7.1     0.00000124     -4911.5234298602 -5.56E-06
    59 Broy./Diag. 0.40E+00    7.5     0.00000085     -4911.5234288413  1.02E-06

  *** SCF run converged in    59 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008367646802
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.85312035609468
  Hartree energy:                                            1781.44795486363455
  Exchange-correlation energy:                               -779.49626918258878
  Electronic entropic energy:                                  -0.23789602386797
  Fermi energy:                                                 0.08718080537924

  Total energy:                                             -4911.52342884131849

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.523420906637512

 MD| ***************************************************************************
 MD| Step number                                                            1143
 MD| Time [fs]                                                       2286.000000
 MD| Conserved quantity [hartree]                            -0.491117970285E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    444.887745           597.192565
 MD| Energy drift per atom [K]           0.290404226647E+03   0.270592284483E+03
 MD| Potential energy [hartree]         -0.491152342091E+04  -0.491156460303E+04
 MD| Kinetic energy [hartree]            0.343718051749E+00   0.375358349748E+00
 MD| Temperature [K]                             915.927821          1000.241778
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.3     0.01897209     -4911.5163161139 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.5     0.07886822     -4911.6450167882 -1.29E-01
     3 Broy./Diag. 0.40E+00    7.1     0.08451057     -4911.2241527549  4.21E-01
     4 Broy./Diag. 0.40E+00    6.7     0.03769290     -4911.6007824251 -3.77E-01
     5 Broy./Diag. 0.40E+00    7.5     0.01297689     -4911.5393162732  6.15E-02
     6 Broy./Diag. 0.40E+00    7.3     0.00472225     -4911.5085323340  3.08E-02
     7 Broy./Diag. 0.40E+00    6.9     0.00412494     -4911.5120564093 -3.52E-03
     8 Broy./Diag. 0.40E+00    7.3     0.00268972     -4911.5324271335 -2.04E-02
     9 Broy./Diag. 0.40E+00    6.9     0.00142145     -4911.5208005064  1.16E-02
    10 Broy./Diag. 0.40E+00    7.5     0.00162263     -4911.5150537997  5.75E-03
    11 Broy./Diag. 0.40E+00    7.1     0.00116325     -4911.5218039606 -6.75E-03
    12 Broy./Diag. 0.40E+00    7.3     0.00045105     -4911.5209672753  8.37E-04
    13 Broy./Diag. 0.40E+00    7.0     0.00027272     -4911.5190142028  1.95E-03
    14 Broy./Diag. 0.40E+00    6.7     0.00026305     -4911.5183947472  6.19E-04
    15 Broy./Diag. 0.40E+00    7.2     0.00028634     -4911.5199902715 -1.60E-03
    16 Broy./Diag. 0.40E+00    7.3     0.00025381     -4911.5200949342 -1.05E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00029154     -4911.5182839104  1.81E-03
    18 Broy./Diag. 0.40E+00    7.5     0.00017611     -4911.5186050782 -3.21E-04
    19 Broy./Diag. 0.40E+00    7.3     0.00013758     -4911.5192451960 -6.40E-04
    20 Broy./Diag. 0.40E+00    7.5     0.00012145     -4911.5189833377  2.62E-04
    21 Broy./Diag. 0.40E+00    6.9     0.00010076     -4911.5182786830  7.05E-04
    22 Broy./Diag. 0.40E+00    7.2     0.00010837     -4911.5183246944 -4.60E-05
    23 Broy./Diag. 0.40E+00    7.1     0.00013635     -4911.5190806508 -7.56E-04
    24 Broy./Diag. 0.40E+00    6.9     0.00006644     -4911.5186694715  4.11E-04
    25 Broy./Diag. 0.40E+00    7.0     0.00005692     -4911.5182984734  3.71E-04
    26 Broy./Diag. 0.40E+00    7.2     0.00006953     -4911.5184138946 -1.15E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00006354     -4911.5186837518 -2.70E-04
    28 Broy./Diag. 0.40E+00    7.1     0.00004374     -4911.5184683524  2.15E-04
    29 Broy./Diag. 0.40E+00    6.7     0.00006165     -4911.5181479146  3.20E-04
    30 Broy./Diag. 0.40E+00    7.0     0.00003177     -4911.5183145217 -1.67E-04
    31 Broy./Diag. 0.40E+00    6.8     0.00001832     -4911.5183978983 -8.34E-05
    32 Broy./Diag. 0.40E+00    7.2     0.00002005     -4911.5183295121  6.84E-05
    33 Broy./Diag. 0.40E+00    7.0     0.00002525     -4911.5182434678  8.60E-05
    34 Broy./Diag. 0.40E+00    8.1     0.00002930     -4911.5183233859 -7.99E-05
    35 Broy./Diag. 0.40E+00    7.3     0.00004083     -4911.5184133495 -9.00E-05
    36 Broy./Diag. 0.40E+00    6.9     0.00002656     -4911.5182359569  1.77E-04
    37 Broy./Diag. 0.40E+00    7.1     0.00001533     -4911.5181875098  4.84E-05
    38 Broy./Diag. 0.40E+00    7.3     0.00001513     -4911.5182317419 -4.42E-05
    39 Broy./Diag. 0.40E+00    7.1     0.00001092     -4911.5182577286 -2.60E-05
    40 Broy./Diag. 0.40E+00    7.3     0.00000732     -4911.5182208109  3.69E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00001294     -4911.5181977409  2.31E-05
    42 Broy./Diag. 0.40E+00    8.0     0.00001306     -4911.5182457845 -4.80E-05
    43 Broy./Diag. 0.40E+00    7.1     0.00000742     -4911.5182447711  1.01E-06
    44 Broy./Diag. 0.40E+00    7.1     0.00000785     -4911.5181901108  5.47E-05
    45 Broy./Diag. 0.40E+00    7.1     0.00000831     -4911.5181846745  5.44E-06
    46 Broy./Diag. 0.40E+00    7.5     0.00000700     -4911.5182084536 -2.38E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00000623     -4911.5182132769 -4.82E-06
    48 Broy./Diag. 0.40E+00    7.5     0.00000494     -4911.5181820634  3.12E-05
    49 Broy./Diag. 0.40E+00    7.7     0.00000237     -4911.5181823323 -2.69E-07
    50 Broy./Diag. 0.40E+00    7.0     0.00000255     -4911.5181949003 -1.26E-05
    51 Broy./Diag. 0.40E+00    7.4     0.00000254     -4911.5181920381  2.86E-06
    52 Broy./Diag. 0.40E+00    7.5     0.00000306     -4911.5181769435  1.51E-05
    53 Broy./Diag. 0.40E+00    7.2     0.00000468     -4911.5181780903 -1.15E-06
    54 Broy./Diag. 0.40E+00    7.1     0.00000496     -4911.5181969903 -1.89E-05
    55 Broy./Diag. 0.40E+00    7.1     0.00000209     -4911.5181856726  1.13E-05
    56 Broy./Diag. 0.40E+00    7.3     0.00000188     -4911.5181715463  1.41E-05
    57 Broy./Diag. 0.40E+00    7.1     0.00000139     -4911.5181735927 -2.05E-06
    58 Broy./Diag. 0.40E+00    6.9     0.00000116     -4911.5181786605 -5.07E-06
    59 Broy./Diag. 0.40E+00    8.0     0.00000097     -4911.5181775905  1.07E-06

  *** SCF run converged in    59 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008388184923
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.89022386458782
  Hartree energy:                                            1781.42516007747417
  Exchange-correlation energy:                               -779.50501918678674
  Electronic entropic energy:                                  -0.23820369589134
  Fermi energy:                                                 0.08722794040373

  Total energy:                                             -4911.51817759053210

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.518168870958107

 MD| ***************************************************************************
 MD| Step number                                                            1144
 MD| Time [fs]                                                       2288.000000
 MD| Conserved quantity [hartree]                            -0.491117463899E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    433.236378           597.049247
 MD| Energy drift per atom [K]           0.300924237995E+03   0.270618798428E+03
 MD| Potential energy [hartree]         -0.491151816887E+04  -0.491156456244E+04
 MD| Kinetic energy [hartree]            0.343529885939E+00   0.375330527664E+00
 MD| Temperature [K]                             915.426403          1000.167639
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.01790193     -4911.5116791485 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.4     0.07304586     -4911.6209002197 -1.09E-01
     3 Broy./Diag. 0.40E+00    7.3     0.07872017     -4911.2709422416  3.50E-01
     4 Broy./Diag. 0.40E+00    7.3     0.03367891     -4911.5926915431 -3.22E-01
     5 Broy./Diag. 0.40E+00    7.3     0.01112234     -4911.5303764614  6.23E-02
     6 Broy./Diag. 0.40E+00    7.1     0.00490625     -4911.5035214801  2.69E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00399726     -4911.5089273178 -5.41E-03
     8 Broy./Diag. 0.40E+00    7.3     0.00244588     -4911.5281969576 -1.93E-02
     9 Broy./Diag. 0.40E+00    7.5     0.00094369     -4911.5162024754  1.20E-02
    10 Broy./Diag. 0.40E+00    7.1     0.00100744     -4911.5104802611  5.72E-03
    11 Broy./Diag. 0.40E+00    6.8     0.00078337     -4911.5161767064 -5.70E-03
    12 Broy./Diag. 0.40E+00    7.5     0.00028904     -4911.5154478130  7.29E-04
    13 Broy./Diag. 0.40E+00    7.1     0.00025336     -4911.5140874170  1.36E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00024780     -4911.5138716868  2.16E-04
    15 Broy./Diag. 0.40E+00    6.9     0.00026556     -4911.5152923453 -1.42E-03
    16 Broy./Diag. 0.40E+00    7.1     0.00020075     -4911.5148498610  4.42E-04
    17 Broy./Diag. 0.40E+00    6.7     0.00026035     -4911.5132674464  1.58E-03
    18 Broy./Diag. 0.40E+00    6.7     0.00016083     -4911.5137045645 -4.37E-04
    19 Broy./Diag. 0.40E+00    7.3     0.00013322     -4911.5141075279 -4.03E-04
    20 Broy./Diag. 0.40E+00    7.3     0.00009933     -4911.5139571636  1.50E-04
    21 Broy./Diag. 0.40E+00    6.9     0.00007755     -4911.5134072010  5.50E-04
    22 Broy./Diag. 0.40E+00    7.7     0.00008597     -4911.5135665590 -1.59E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00012271     -4911.5142116544 -6.45E-04
    24 Broy./Diag. 0.40E+00    7.5     0.00006495     -4911.5136983753  5.13E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00006180     -4911.5134743281  2.24E-04
    26 Broy./Diag. 0.40E+00    7.5     0.00006262     -4911.5135818674 -1.08E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00004328     -4911.5137115283 -1.30E-04
    28 Broy./Diag. 0.40E+00    7.8     0.00002946     -4911.5135723050  1.39E-04
    29 Broy./Diag. 0.40E+00    6.9     0.00004709     -4911.5133628643  2.09E-04
    30 Broy./Diag. 0.40E+00    7.3     0.00002915     -4911.5135382875 -1.75E-04
    31 Broy./Diag. 0.40E+00    7.3     0.00001852     -4911.5135608385 -2.26E-05
    32 Broy./Diag. 0.40E+00    7.3     0.00001944     -4911.5134847161  7.61E-05
    33 Broy./Diag. 0.40E+00    7.1     0.00002037     -4911.5134347639  5.00E-05
    34 Broy./Diag. 0.40E+00    7.1     0.00001967     -4911.5134986696 -6.39E-05
    35 Broy./Diag. 0.40E+00    7.1     0.00002969     -4911.5135397518 -4.11E-05
    36 Broy./Diag. 0.40E+00    7.5     0.00002323     -4911.5134004649  1.39E-04
    37 Broy./Diag. 0.40E+00    7.1     0.00001214     -4911.5133929042  7.56E-06
    38 Broy./Diag. 0.40E+00    6.9     0.00001188     -4911.5134268027 -3.39E-05
    39 Broy./Diag. 0.40E+00    6.9     0.00000837     -4911.5134407024 -1.39E-05
    40 Broy./Diag. 0.40E+00    6.9     0.00000560     -4911.5134044986  3.62E-05
    41 Broy./Diag. 0.40E+00    7.3     0.00001125     -4911.5133921191  1.24E-05
    42 Broy./Diag. 0.40E+00    6.8     0.00001312     -4911.5134383864 -4.63E-05
    43 Broy./Diag. 0.40E+00    7.3     0.00000625     -4911.5134295893  8.80E-06
    44 Broy./Diag. 0.40E+00    7.3     0.00000734     -4911.5133841473  4.54E-05
    45 Broy./Diag. 0.40E+00    7.3     0.00000630     -4911.5133818229  2.32E-06
    46 Broy./Diag. 0.40E+00    7.7     0.00000423     -4911.5134016418 -1.98E-05
    47 Broy./Diag. 0.40E+00    6.9     0.00000399     -4911.5134035603 -1.92E-06
    48 Broy./Diag. 0.40E+00    7.0     0.00000414     -4911.5133795026  2.41E-05
    49 Broy./Diag. 0.40E+00    7.2     0.00000214     -4911.5133825678 -3.07E-06
    50 Broy./Diag. 0.40E+00    7.3     0.00000293     -4911.5133944352 -1.19E-05
    51 Broy./Diag. 0.40E+00    6.8     0.00000257     -4911.5133896639  4.77E-06
    52 Broy./Diag. 0.40E+00    7.3     0.00000240     -4911.5133757079  1.40E-05
    53 Broy./Diag. 0.40E+00    7.3     0.00000336     -4911.5133770702 -1.36E-06
    54 Broy./Diag. 0.40E+00    7.3     0.00000382     -4911.5133927894 -1.57E-05
    55 Broy./Diag. 0.40E+00    7.3     0.00000155     -4911.5133828048  9.98E-06
    56 Broy./Diag. 0.40E+00    7.1     0.00000164     -4911.5133727561  1.00E-05
    57 Broy./Diag. 0.40E+00    7.7     0.00000117     -4911.5133746200 -1.86E-06
    58 Broy./Diag. 0.40E+00    7.7     0.00000092     -4911.5133787667 -4.15E-06

  *** SCF run converged in    58 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008406446865
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.92292194859101
  Hartree energy:                                            1781.40484144552943
  Exchange-correlation energy:                               -779.51231004102272
  Electronic entropic energy:                                  -0.23849367445753
  Fermi energy:                                                 0.08726734856840

  Total energy:                                             -4911.51337876669095

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.513369860868806

 MD| ***************************************************************************
 MD| Step number                                                            1145
 MD| Time [fs]                                                       2290.000000
 MD| Conserved quantity [hartree]                            -0.491117966932E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    426.787156           596.900546
 MD| Energy drift per atom [K]           0.290473887870E+03   0.270636139117E+03
 MD| Potential energy [hartree]         -0.491151336986E+04  -0.491156451774E+04
 MD| Kinetic energy [hartree]            0.333700537823E+00   0.375294169594E+00
 MD| Temperature [K]                             889.233501          1000.070753
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.01866580     -4911.5086256971 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.5     0.04784113     -4911.5817171549 -7.31E-02
     3 Broy./Diag. 0.40E+00    7.1     0.05299600     -4911.3693334892  2.12E-01
     4 Broy./Diag. 0.40E+00    7.1     0.03045424     -4911.5938440792 -2.25E-01
     5 Broy./Diag. 0.40E+00    6.9     0.01269322     -4911.5058695272  8.80E-02
     6 Broy./Diag. 0.40E+00    8.6     0.00482357     -4911.5120405872 -6.17E-03
     7 Broy./Diag. 0.40E+00    7.1     0.00362602     -4911.5110817696  9.59E-04
     8 Broy./Diag. 0.40E+00    7.1     0.00215346     -4911.5174480238 -6.37E-03
     9 Broy./Diag. 0.40E+00    7.3     0.00060710     -4911.5119049961  5.54E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00057785     -4911.5108719205  1.03E-03
    11 Broy./Diag. 0.40E+00    7.0     0.00062868     -4911.5133600490 -2.49E-03
    12 Broy./Diag. 0.40E+00    7.0     0.00039885     -4911.5112685045  2.09E-03
    13 Broy./Diag. 0.40E+00    6.9     0.00029519     -4911.5109985943  2.70E-04
    14 Broy./Diag. 0.40E+00    7.0     0.00024871     -4911.5110116815 -1.31E-05
    15 Broy./Diag. 0.40E+00    6.7     0.00019481     -4911.5117323424 -7.21E-04
    16 Broy./Diag. 0.40E+00    6.9     0.00014849     -4911.5109770826  7.55E-04
    17 Broy./Diag. 0.40E+00    7.5     0.00023772     -4911.5101643712  8.13E-04
    18 Broy./Diag. 0.40E+00    7.1     0.00021462     -4911.5109222476 -7.58E-04
    19 Broy./Diag. 0.40E+00    6.9     0.00013626     -4911.5107386898  1.84E-04
    20 Broy./Diag. 0.40E+00    7.5     0.00010759     -4911.5105232187  2.15E-04
    21 Broy./Diag. 0.40E+00    7.3     0.00006395     -4911.5101779863  3.45E-04
    22 Broy./Diag. 0.40E+00    6.9     0.00006162     -4911.5103908335 -2.13E-04
    23 Broy./Diag. 0.40E+00    8.0     0.00007774     -4911.5107268767 -3.36E-04
    24 Broy./Diag. 0.40E+00    7.2     0.00006439     -4911.5102803002  4.47E-04
    25 Broy./Diag. 0.40E+00    6.9     0.00005775     -4911.5102722114  8.09E-06
    26 Broy./Diag. 0.40E+00    7.0     0.00005928     -4911.5103761316 -1.04E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00003447     -4911.5104067950 -3.07E-05
    28 Broy./Diag. 0.40E+00    7.3     0.00002639     -4911.5102641526  1.43E-04
    29 Broy./Diag. 0.40E+00    7.1     0.00003759     -4911.5101080567  1.56E-04
    30 Broy./Diag. 0.40E+00    6.7     0.00003267     -4911.5103147026 -2.07E-04
    31 Broy./Diag. 0.40E+00    7.2     0.00001811     -4911.5102832845  3.14E-05
    32 Broy./Diag. 0.40E+00    7.1     0.00002116     -4911.5102132668  7.00E-05
    33 Broy./Diag. 0.40E+00    7.5     0.00001487     -4911.5101794681  3.38E-05
    34 Broy./Diag. 0.40E+00    7.3     0.00001305     -4911.5102374273 -5.80E-05
    35 Broy./Diag. 0.40E+00    6.9     0.00001974     -4911.5102699213 -3.25E-05
    36 Broy./Diag. 0.40E+00    7.5     0.00002090     -4911.5101339795  1.36E-04
    37 Broy./Diag. 0.40E+00    6.9     0.00001073     -4911.5101531206 -1.91E-05
    38 Broy./Diag. 0.40E+00    7.1     0.00001383     -4911.5101772411 -2.41E-05
    39 Broy./Diag. 0.40E+00    7.3     0.00000794     -4911.5101924061 -1.52E-05
    40 Broy./Diag. 0.40E+00    7.1     0.00000545     -4911.5101535173  3.89E-05
    41 Broy./Diag. 0.40E+00    6.7     0.00000931     -4911.5101395997  1.39E-05
    42 Broy./Diag. 0.40E+00    6.7     0.00001250     -4911.5101960309 -5.64E-05
    43 Broy./Diag. 0.40E+00    7.7     0.00000654     -4911.5101701808  2.59E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00000801     -4911.5101400688  3.01E-05
    45 Broy./Diag. 0.40E+00    7.3     0.00000570     -4911.5101330468  7.02E-06
    46 Broy./Diag. 0.40E+00    6.9     0.00000398     -4911.5101506978 -1.77E-05
    47 Broy./Diag. 0.40E+00    6.7     0.00000344     -4911.5101563159 -5.62E-06
    48 Broy./Diag. 0.40E+00    7.3     0.00000477     -4911.5101274616  2.89E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00000300     -4911.5101364595 -9.00E-06
    50 Broy./Diag. 0.40E+00    7.7     0.00000353     -4911.5101444982 -8.04E-06
    51 Broy./Diag. 0.40E+00    7.1     0.00000286     -4911.5101429868  1.51E-06
    52 Broy./Diag. 0.40E+00    7.1     0.00000219     -4911.5101296623  1.33E-05
    53 Broy./Diag. 0.40E+00    7.6     0.00000243     -4911.5101280345  1.63E-06
    54 Broy./Diag. 0.40E+00    8.0     0.00000348     -4911.5101441506 -1.61E-05
    55 Broy./Diag. 0.40E+00    8.2     0.00000211     -4911.5101326583  1.15E-05
    56 Broy./Diag. 0.40E+00    8.7     0.00000180     -4911.5101269004  5.76E-06
    57 Broy./Diag. 0.40E+00    7.0     0.00000149     -4911.5101264039  4.97E-07
    58 Broy./Diag. 0.40E+00   10.3     0.00000109     -4911.5101312354 -4.83E-06
    59 Broy./Diag. 0.40E+00    8.2     0.00000082     -4911.5101309565  2.79E-07

  *** SCF run converged in    59 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008415981232
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.94721650263455
  Hartree energy:                                            1781.38891951916503
  Exchange-correlation energy:                               -779.51722545352027
  Electronic entropic energy:                                  -0.23870314271151
  Fermi energy:                                                 0.08729604474328

  Total energy:                                             -4911.51013095652979

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.510121573432116

 MD| ***************************************************************************
 MD| Step number                                                            1146
 MD| Time [fs]                                                       2292.000000
 MD| Conserved quantity [hartree]                            -0.491119070513E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    438.482476           596.762310
 MD| Energy drift per atom [K]           0.267547379682E+03   0.270633443865E+03
 MD| Potential energy [hartree]         -0.491151012157E+04  -0.491156447027E+04
 MD| Kinetic energy [hartree]            0.319416439667E+00   0.375245410668E+00
 MD| Temperature [K]                             851.169736           999.940822
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02072134     -4911.5081688286 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.05168896     -4911.5425632209 -3.44E-02
     3 Broy./Diag. 0.40E+00    7.3     0.06050041     -4911.4646070441  7.80E-02
     4 Broy./Diag. 0.40E+00    8.0     0.02741707     -4911.5681129996 -1.04E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01134902     -4911.4839536353  8.42E-02
     6 Broy./Diag. 0.40E+00    9.1     0.00703425     -4911.5309858902 -4.70E-02
     7 Broy./Diag. 0.40E+00    7.4     0.00322260     -4911.5186239640  1.24E-02
     8 Broy./Diag. 0.40E+00    8.3     0.00180944     -4911.5061305212  1.25E-02
     9 Broy./Diag. 0.40E+00    9.7     0.00100870     -4911.5091703806 -3.04E-03
    10 Broy./Diag. 0.40E+00    6.9     0.00124821     -4911.5132749124 -4.10E-03
    11 Broy./Diag. 0.40E+00    6.7     0.00068568     -4911.5136023084 -3.27E-04
    12 Broy./Diag. 0.40E+00    7.2     0.00049067     -4911.5097125824  3.89E-03
    13 Broy./Diag. 0.40E+00    8.0     0.00041056     -4911.5115163249 -1.80E-03
    14 Broy./Diag. 0.40E+00    7.3     0.00027512     -4911.5115414611 -2.51E-05
    15 Broy./Diag. 0.40E+00    9.3     0.00020064     -4911.5102462361  1.30E-03
    16 Broy./Diag. 0.40E+00    7.2     0.00023386     -4911.5096179427  6.28E-04
    17 Broy./Diag. 0.40E+00    8.6     0.00024003     -4911.5102210546 -6.03E-04
    18 Broy./Diag. 0.40E+00   10.3     0.00026518     -4911.5113668170 -1.15E-03
    19 Broy./Diag. 0.40E+00    7.3     0.00015326     -4911.5096175653  1.75E-03
    20 Broy./Diag. 0.40E+00    7.5     0.00013875     -4911.5097328585 -1.15E-04
    21 Broy./Diag. 0.40E+00    7.3     0.00012211     -4911.5103911780 -6.58E-04
    22 Broy./Diag. 0.40E+00    7.5     0.00007834     -4911.5101198986  2.71E-04
    23 Broy./Diag. 0.40E+00    6.9     0.00006324     -4911.5097766169  3.43E-04
    24 Broy./Diag. 0.40E+00    7.1     0.00007358     -4911.5095637414  2.13E-04
    25 Broy./Diag. 0.40E+00    6.9     0.00005413     -4911.5099867457 -4.23E-04
    26 Broy./Diag. 0.40E+00    8.0     0.00003057     -4911.5098935231  9.32E-05
    27 Broy./Diag. 0.40E+00    7.3     0.00004537     -4911.5096484415  2.45E-04
    28 Broy./Diag. 0.40E+00    6.7     0.00005146     -4911.5097404825 -9.20E-05
    29 Broy./Diag. 0.40E+00    7.3     0.00004672     -4911.5098726112 -1.32E-04
    30 Broy./Diag. 0.40E+00    7.2     0.00004996     -4911.5098554719  1.71E-05
    31 Broy./Diag. 0.40E+00    7.3     0.00003872     -4911.5095353999  3.20E-04
    32 Broy./Diag. 0.40E+00    7.1     0.00001917     -4911.5096113895 -7.60E-05
    33 Broy./Diag. 0.40E+00    7.5     0.00001556     -4911.5096997681 -8.84E-05
    34 Broy./Diag. 0.40E+00    7.1     0.00001201     -4911.5096559181  4.38E-05
    35 Broy./Diag. 0.40E+00    7.5     0.00000984     -4911.5096173732  3.85E-05
    36 Broy./Diag. 0.40E+00    7.3     0.00001870     -4911.5096231281 -5.75E-06
    37 Broy./Diag. 0.40E+00    7.1     0.00002088     -4911.5097218864 -9.88E-05
    38 Broy./Diag. 0.40E+00    7.2     0.00001122     -4911.5096256061  9.63E-05
    39 Broy./Diag. 0.40E+00    7.3     0.00001220     -4911.5095804014  4.52E-05
    40 Broy./Diag. 0.40E+00    7.1     0.00001205     -4911.5096103082 -2.99E-05
    41 Broy./Diag. 0.40E+00    7.3     0.00000735     -4911.5096271246 -1.68E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00000585     -4911.5096145455  1.26E-05
    43 Broy./Diag. 0.40E+00    7.7     0.00000550     -4911.5095830841  3.15E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00000423     -4911.5096045726 -2.15E-05
    45 Broy./Diag. 0.40E+00    7.0     0.00000412     -4911.5096167666 -1.22E-05
    46 Broy./Diag. 0.40E+00    7.1     0.00000516     -4911.5095867203  3.00E-05
    47 Broy./Diag. 0.40E+00    6.9     0.00000515     -4911.5095832907  3.43E-06
    48 Broy./Diag. 0.40E+00    6.9     0.00000547     -4911.5095925582 -9.27E-06
    49 Broy./Diag. 0.40E+00    6.9     0.00000491     -4911.5096089031 -1.63E-05
    50 Broy./Diag. 0.40E+00    7.0     0.00000254     -4911.5095808029  2.81E-05
    51 Broy./Diag. 0.40E+00    7.1     0.00000190     -4911.5095768941  3.91E-06
    52 Broy./Diag. 0.40E+00    7.7     0.00000145     -4911.5095863814 -9.49E-06
    53 Broy./Diag. 0.40E+00    7.3     0.00000129     -4911.5095843709  2.01E-06
    54 Broy./Diag. 0.40E+00    7.5     0.00000121     -4911.5095804599  3.91E-06
    55 Broy./Diag. 0.40E+00    7.3     0.00000218     -4911.5095773303  3.13E-06
    56 Broy./Diag. 0.40E+00    7.3     0.00000197     -4911.5095888490 -1.15E-05
    57 Broy./Diag. 0.40E+00    6.7     0.00000160     -4911.5095841762  4.67E-06
    58 Broy./Diag. 0.40E+00    7.3     0.00000138     -4911.5095748471  9.33E-06
    59 Broy./Diag. 0.40E+00    6.9     0.00000107     -4911.5095763564 -1.51E-06
    60 Broy./Diag. 0.40E+00    7.0     0.00000072     -4911.5095785182 -2.16E-06

  *** SCF run converged in    60 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008412539540
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.95858659604755
  Hartree energy:                                            1781.37981991224228
  Exchange-correlation energy:                               -779.51884258991061
  Electronic entropic energy:                                  -0.23880405781232
  Fermi energy:                                                 0.08731135227741

  Total energy:                                             -4911.50957851817748

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.509574190085004

 MD| ***************************************************************************
 MD| Step number                                                            1147
 MD| Time [fs]                                                       2294.000000
 MD| Conserved quantity [hartree]                            -0.491117500216E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    453.786179           596.637658
 MD| Energy drift per atom [K]           0.300169758647E+03   0.270659194793E+03
 MD| Potential energy [hartree]         -0.491150957419E+04  -0.491156442241E+04
 MD| Kinetic energy [hartree]            0.334572031955E+00   0.375209950006E+00
 MD| Temperature [K]                             891.555828           999.846328
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02112546     -4911.5099360072 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.05079827     -4911.5021753547  7.76E-03
     3 Broy./Diag. 0.40E+00    6.9     0.05555585     -4911.5750527730 -7.29E-02
     4 Broy./Diag. 0.40E+00    6.7     0.02449953     -4911.5076731263  6.74E-02
     5 Broy./Diag. 0.40E+00    7.5     0.01091118     -4911.4983840185  9.29E-03
     6 Broy./Diag. 0.40E+00    7.3     0.00724054     -4911.5209194299 -2.25E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00414097     -4911.5335034981 -1.26E-02
     8 Broy./Diag. 0.40E+00    6.7     0.00226078     -4911.5007720707  3.27E-02
     9 Broy./Diag. 0.40E+00    7.0     0.00117295     -4911.5114504277 -1.07E-02
    10 Broy./Diag. 0.40E+00    7.3     0.00116400     -4911.5156948584 -4.24E-03
    11 Broy./Diag. 0.40E+00    7.2     0.00064089     -4911.5130530578  2.64E-03
    12 Broy./Diag. 0.40E+00    6.9     0.00045584     -4911.5120803937  9.73E-04
    13 Broy./Diag. 0.40E+00    7.4     0.00049580     -4911.5128096196 -7.29E-04
    14 Broy./Diag. 0.40E+00    7.1     0.00035715     -4911.5144878787 -1.68E-03
    15 Broy./Diag. 0.40E+00    7.3     0.00023636     -4911.5116356533  2.85E-03
    16 Broy./Diag. 0.40E+00    7.5     0.00023998     -4911.5113718278  2.64E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00022705     -4911.5124178636 -1.05E-03
    18 Broy./Diag. 0.40E+00    6.7     0.00022316     -4911.5125592491 -1.41E-04
    19 Broy./Diag. 0.40E+00    7.3     0.00016571     -4911.5116554253  9.04E-04
    20 Broy./Diag. 0.40E+00    7.3     0.00019037     -4911.5113145205  3.41E-04
    21 Broy./Diag. 0.40E+00    7.3     0.00016797     -4911.5127285347 -1.41E-03
    22 Broy./Diag. 0.40E+00    7.1     0.00008429     -4911.5120538425  6.75E-04
    23 Broy./Diag. 0.40E+00    7.3     0.00006861     -4911.5115355576  5.18E-04
    24 Broy./Diag. 0.40E+00    7.1     0.00007664     -4911.5115536627 -1.81E-05
    25 Broy./Diag. 0.40E+00    6.9     0.00005744     -4911.5117603258 -2.07E-04
    26 Broy./Diag. 0.40E+00    6.7     0.00003467     -4911.5118191492 -5.88E-05
    27 Broy./Diag. 0.40E+00    7.3     0.00005728     -4911.5114781417  3.41E-04
    28 Broy./Diag. 0.40E+00    6.9     0.00005329     -4911.5116717695 -1.94E-04
    29 Broy./Diag. 0.40E+00    6.8     0.00004294     -4911.5118141680 -1.42E-04
    30 Broy./Diag. 0.40E+00    6.7     0.00004994     -4911.5116197189  1.94E-04
    31 Broy./Diag. 0.40E+00    7.1     0.00004552     -4911.5114833556  1.36E-04
    32 Broy./Diag. 0.40E+00    7.3     0.00002586     -4911.5114396637  4.37E-05
    33 Broy./Diag. 0.40E+00    6.9     0.00002335     -4911.5116146465 -1.75E-04
    34 Broy./Diag. 0.40E+00    7.1     0.00001597     -4911.5115122086  1.02E-04
    35 Broy./Diag. 0.40E+00    7.1     0.00000936     -4911.5114725703  3.96E-05
    36 Broy./Diag. 0.40E+00    6.9     0.00001692     -4911.5115064169 -3.38E-05
    37 Broy./Diag. 0.40E+00    6.9     0.00002028     -4911.5115286611 -2.22E-05
    38 Broy./Diag. 0.40E+00    6.9     0.00001336     -4911.5115080269  2.06E-05
    39 Broy./Diag. 0.40E+00    7.3     0.00001621     -4911.5114274284  8.06E-05
    40 Broy./Diag. 0.40E+00    6.9     0.00001579     -4911.5114932391 -6.58E-05
    41 Broy./Diag. 0.40E+00    7.7     0.00000781     -4911.5115034925 -1.03E-05
    42 Broy./Diag. 0.40E+00    6.9     0.00000722     -4911.5114562363  4.73E-05
    43 Broy./Diag. 0.40E+00    7.3     0.00000644     -4911.5114500120  6.22E-06
    44 Broy./Diag. 0.40E+00    6.9     0.00000498     -4911.5114530275 -3.02E-06
    45 Broy./Diag. 0.40E+00    6.5     0.00000445     -4911.5114783583 -2.53E-05
    46 Broy./Diag. 0.40E+00    7.5     0.00000584     -4911.5114419098  3.64E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00000498     -4911.5114431432 -1.23E-06
    48 Broy./Diag. 0.40E+00    6.9     0.00000619     -4911.5114689908 -2.58E-05
    49 Broy./Diag. 0.40E+00    8.2     0.00000516     -4911.5114542971  1.47E-05
    50 Broy./Diag. 0.40E+00    7.0     0.00000345     -4911.5114425701  1.17E-05
    51 Broy./Diag. 0.40E+00    7.7     0.00000283     -4911.5114289415  1.36E-05
    52 Broy./Diag. 0.40E+00    7.5     0.00000193     -4911.5114467368 -1.78E-05
    53 Broy./Diag. 0.40E+00    6.9     0.00000119     -4911.5114425196  4.22E-06
    54 Broy./Diag. 0.40E+00    7.4     0.00000140     -4911.5114352479  7.27E-06
    55 Broy./Diag. 0.40E+00    6.9     0.00000189     -4911.5114383894 -3.14E-06
    56 Broy./Diag. 0.40E+00    7.3     0.00000202     -4911.5114413698 -2.98E-06
    57 Broy./Diag. 0.40E+00    6.9     0.00000194     -4911.5114436702 -2.30E-06
    58 Broy./Diag. 0.40E+00    7.3     0.00000175     -4911.5114296242  1.40E-05
    59 Broy./Diag. 0.40E+00    7.1     0.00000122     -4911.5114330609 -3.44E-06
    60 Broy./Diag. 0.40E+00    7.5     0.00000107     -4911.5114386515 -5.59E-06
    61 Broy./Diag. 0.40E+00    6.7     0.00000072     -4911.5114345013  4.15E-06

  *** SCF run converged in    61 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008397125865
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.95973845052731
  Hartree energy:                                            1781.37584697882767
  Exchange-correlation energy:                               -779.51783181407905
  Electronic entropic energy:                                  -0.23884957521422
  Fermi energy:                                                 0.08731698337421

  Total energy:                                             -4911.51143450131076

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.511430468126491

 MD| ***************************************************************************
 MD| Step number                                                            1148
 MD| Time [fs]                                                       2296.000000
 MD| Conserved quantity [hartree]                            -0.491117937997E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    442.839681           596.503688
 MD| Energy drift per atom [K]           0.291075002000E+03   0.270676978597E+03
 MD| Potential energy [hartree]         -0.491151143047E+04  -0.491156437625E+04
 MD| Kinetic energy [hartree]            0.332050494933E+00   0.375172354662E+00
 MD| Temperature [K]                             884.836524           999.746145
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.7     0.01951025     -4911.5134955427 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.9     0.06119820     -4911.4872076756  2.63E-02
     3 Broy./Diag. 0.40E+00    7.7     0.07273122     -4911.6464048009 -1.59E-01
     4 Broy./Diag. 0.40E+00    7.9     0.03869838     -4911.4736249093  1.73E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01488352     -4911.5233372269 -4.97E-02
     6 Broy./Diag. 0.40E+00    6.9     0.00699001     -4911.5113054693  1.20E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00548809     -4911.5412377040 -2.99E-02
     8 Broy./Diag. 0.40E+00    7.3     0.00231525     -4911.5087965086  3.24E-02
     9 Broy./Diag. 0.40E+00    6.9     0.00096176     -4911.5126050220 -3.81E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00128497     -4911.5198633846 -7.26E-03
    11 Broy./Diag. 0.40E+00    7.1     0.00096751     -4911.5153601664  4.50E-03
    12 Broy./Diag. 0.40E+00    7.3     0.00032099     -4911.5160204427 -6.60E-04
    13 Broy./Diag. 0.40E+00    7.1     0.00044722     -4911.5160571944 -3.68E-05
    14 Broy./Diag. 0.40E+00    6.9     0.00036655     -4911.5174426827 -1.39E-03
    15 Broy./Diag. 0.40E+00    7.5     0.00018183     -4911.5153018864  2.14E-03
    16 Broy./Diag. 0.40E+00    7.1     0.00025669     -4911.5148954055  4.06E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00032844     -4911.5163876231 -1.49E-03
    18 Broy./Diag. 0.40E+00    7.1     0.00020026     -4911.5158639074  5.24E-04
    19 Broy./Diag. 0.40E+00    7.1     0.00013995     -4911.5153711345  4.93E-04
    20 Broy./Diag. 0.40E+00    7.5     0.00018265     -4911.5150218196  3.49E-04
    21 Broy./Diag. 0.40E+00    7.5     0.00012493     -4911.5160160173 -9.94E-04
    22 Broy./Diag. 0.40E+00    7.1     0.00007602     -4911.5156693587  3.47E-04
    23 Broy./Diag. 0.40E+00    7.7     0.00010464     -4911.5150803032  5.89E-04
    24 Broy./Diag. 0.40E+00    7.1     0.00007731     -4911.5152770368 -1.97E-04
    25 Broy./Diag. 0.40E+00    7.0     0.00005510     -4911.5153755082 -9.85E-05
    26 Broy./Diag. 0.40E+00    7.1     0.00004561     -4911.5154467282 -7.12E-05
    27 Broy./Diag. 0.40E+00    7.5     0.00004978     -4911.5151323699  3.14E-04
    28 Broy./Diag. 0.40E+00    7.7     0.00004620     -4911.5152324797 -1.00E-04
    29 Broy./Diag. 0.40E+00    7.3     0.00005968     -4911.5154575136 -2.25E-04
    30 Broy./Diag. 0.40E+00    7.1     0.00004863     -4911.5151924162  2.65E-04
    31 Broy./Diag. 0.40E+00    7.2     0.00003620     -4911.5151381556  5.43E-05
    32 Broy./Diag. 0.40E+00    6.9     0.00002918     -4911.5151003363  3.78E-05
    33 Broy./Diag. 0.40E+00    7.1     0.00001889     -4911.5152223939 -1.22E-04
    34 Broy./Diag. 0.40E+00    6.9     0.00001255     -4911.5151630506  5.93E-05
    35 Broy./Diag. 0.40E+00    7.0     0.00001572     -4911.5150992115  6.38E-05
    36 Broy./Diag. 0.40E+00    7.1     0.00001657     -4911.5151557211 -5.65E-05
    37 Broy./Diag. 0.40E+00    7.3     0.00001512     -4911.5151463030  9.42E-06
    38 Broy./Diag. 0.40E+00    7.3     0.00001552     -4911.5151389171  7.39E-06
    39 Broy./Diag. 0.40E+00    7.1     0.00001313     -4911.5150784513  6.05E-05
    40 Broy./Diag. 0.40E+00    7.3     0.00001059     -4911.5151112973 -3.28E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00001190     -4911.5151463942 -3.51E-05
    42 Broy./Diag. 0.40E+00    6.9     0.00000858     -4911.5150856236  6.08E-05
    43 Broy./Diag. 0.40E+00    6.9     0.00000475     -4911.5150915984 -5.97E-06
    44 Broy./Diag. 0.40E+00    7.5     0.00000635     -4911.5150912455  3.53E-07
    45 Broy./Diag. 0.40E+00    7.3     0.00000449     -4911.5151102533 -1.90E-05
    46 Broy./Diag. 0.40E+00    7.1     0.00000397     -4911.5150812755  2.90E-05
    47 Broy./Diag. 0.40E+00    7.4     0.00000738     -4911.5150742330  7.04E-06
    48 Broy./Diag. 0.40E+00    6.9     0.00000686     -4911.5151073068 -3.31E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00000329     -4911.5150858408  2.15E-05
    50 Broy./Diag. 0.40E+00    6.9     0.00000377     -4911.5150774820  8.36E-06
    51 Broy./Diag. 0.40E+00    6.7     0.00000280     -4911.5150695103  7.97E-06
    52 Broy./Diag. 0.40E+00    7.3     0.00000144     -4911.5150815934 -1.21E-05
    53 Broy./Diag. 0.40E+00    7.3     0.00000172     -4911.5150798313  1.76E-06
    54 Broy./Diag. 0.40E+00    7.2     0.00000198     -4911.5150702418  9.59E-06
    55 Broy./Diag. 0.40E+00    7.5     0.00000137     -4911.5150759041 -5.66E-06
    56 Broy./Diag. 0.40E+00    7.4     0.00000196     -4911.5150769918 -1.09E-06
    57 Broy./Diag. 0.40E+00    7.1     0.00000196     -4911.5150767222  2.70E-07
    58 Broy./Diag. 0.40E+00    7.1     0.00000129     -4911.5150672163  9.51E-06
    59 Broy./Diag. 0.40E+00    6.9     0.00000159     -4911.5150683377 -1.12E-06
    60 Broy./Diag. 0.40E+00    7.3     0.00000143     -4911.5150757507 -7.41E-06
    61 Broy./Diag. 0.40E+00    7.3     0.00000067     -4911.5150698811  5.87E-06

  *** SCF run converged in    61 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008374509520
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.95373746693576
  Hartree energy:                                            1781.37579215446999
  Exchange-correlation energy:                               -779.51541073756073
  Electronic entropic energy:                                  -0.23884999719485
  Fermi energy:                                                 0.08731612012977

  Total energy:                                             -4911.51506988114670

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.515065656009938

 MD| ***************************************************************************
 MD| Step number                                                            1149
 MD| Time [fs]                                                       2298.000000
 MD| Conserved quantity [hartree]                            -0.491118746157E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    447.942021           596.374391
 MD| Energy drift per atom [K]           0.274285759683E+03   0.270680119399E+03
 MD| Potential energy [hartree]         -0.491151506566E+04  -0.491156433333E+04
 MD| Kinetic energy [hartree]            0.327604081431E+00   0.375130954947E+00
 MD| Temperature [K]                             872.987877           999.635825
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.01816599     -4911.5182276282 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.9     0.08090474     -4911.4783062274  3.99E-02
     3 Broy./Diag. 0.40E+00    7.1     0.09299835     -4911.6974243813 -2.19E-01
     4 Broy./Diag. 0.40E+00    7.0     0.04084091     -4911.4585233892  2.39E-01
     5 Broy./Diag. 0.40E+00    7.3     0.01054463     -4911.5217392288 -6.32E-02
     6 Broy./Diag. 0.40E+00    7.0     0.00494749     -4911.5187340808  3.01E-03
     7 Broy./Diag. 0.40E+00    6.9     0.00427881     -4911.5441218986 -2.54E-02
     8 Broy./Diag. 0.40E+00    7.9     0.00248246     -4911.5076381958  3.65E-02
     9 Broy./Diag. 0.40E+00    6.7     0.00104811     -4911.5208128941 -1.32E-02
    10 Broy./Diag. 0.40E+00    7.0     0.00074735     -4911.5227912041 -1.98E-03
    11 Broy./Diag. 0.40E+00    6.9     0.00054804     -4911.5196157337  3.18E-03
    12 Broy./Diag. 0.40E+00    7.3     0.00031635     -4911.5214157670 -1.80E-03
    13 Broy./Diag. 0.40E+00    7.3     0.00030796     -4911.5207650485  6.51E-04
    14 Broy./Diag. 0.40E+00    7.1     0.00023744     -4911.5212462086 -4.81E-04
    15 Broy./Diag. 0.40E+00    6.7     0.00017076     -4911.5196049562  1.64E-03
    16 Broy./Diag. 0.40E+00    7.3     0.00018640     -4911.5204824550 -8.77E-04
    17 Broy./Diag. 0.40E+00    6.9     0.00018833     -4911.5210325994 -5.50E-04
    18 Broy./Diag. 0.40E+00    7.0     0.00017194     -4911.5198435399  1.19E-03
    19 Broy./Diag. 0.40E+00    7.5     0.00011480     -4911.5201107123 -2.67E-04
    20 Broy./Diag. 0.40E+00    7.5     0.00010418     -4911.5199813122  1.29E-04
    21 Broy./Diag. 0.40E+00    7.5     0.00007268     -4911.5206137908 -6.32E-04
    22 Broy./Diag. 0.40E+00    7.3     0.00005128     -4911.5200322983  5.81E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00005772     -4911.5199039647  1.28E-04
    24 Broy./Diag. 0.40E+00    7.6     0.00005033     -4911.5201999401 -2.96E-04
    25 Broy./Diag. 0.40E+00    7.4     0.00003715     -4911.5200600460  1.40E-04
    26 Broy./Diag. 0.40E+00    7.5     0.00003175     -4911.5200743115 -1.43E-05
    27 Broy./Diag. 0.40E+00    7.5     0.00003173     -4911.5199092969  1.65E-04
    28 Broy./Diag. 0.40E+00    7.3     0.00002567     -4911.5201197069 -2.10E-04
    29 Broy./Diag. 0.40E+00    7.3     0.00003298     -4911.5200796937  4.00E-05
    30 Broy./Diag. 0.40E+00    7.0     0.00003216     -4911.5199142262  1.65E-04
    31 Broy./Diag. 0.40E+00    6.9     0.00002387     -4911.5199957447 -8.15E-05
    32 Broy./Diag. 0.40E+00    7.5     0.00001836     -4911.5199650120  3.07E-05
    33 Broy./Diag. 0.40E+00    7.1     0.00001344     -4911.5200136646 -4.87E-05
    34 Broy./Diag. 0.40E+00    7.2     0.00001078     -4911.5199297646  8.39E-05
    35 Broy./Diag. 0.40E+00    6.9     0.00001351     -4911.5199393422 -9.58E-06
    36 Broy./Diag. 0.40E+00    7.3     0.00001270     -4911.5199841763 -4.48E-05
    37 Broy./Diag. 0.40E+00    6.8     0.00001253     -4911.5199261377  5.80E-05
    38 Broy./Diag. 0.40E+00    7.1     0.00001153     -4911.5199491408 -2.30E-05
    39 Broy./Diag. 0.40E+00    7.0     0.00000850     -4911.5199235386  2.56E-05
    40 Broy./Diag. 0.40E+00    6.9     0.00000767     -4911.5199530203 -2.95E-05
    41 Broy./Diag. 0.40E+00    7.7     0.00000775     -4911.5199292580  2.38E-05
    42 Broy./Diag. 0.40E+00    7.2     0.00000689     -4911.5199071257  2.21E-05
    43 Broy./Diag. 0.40E+00    7.2     0.00000471     -4911.5199352736 -2.81E-05
    44 Broy./Diag. 0.40E+00    6.9     0.00000477     -4911.5199156100  1.97E-05
    45 Broy./Diag. 0.40E+00    7.1     0.00000369     -4911.5199219837 -6.37E-06
    46 Broy./Diag. 0.40E+00    7.5     0.00000371     -4911.5199107169  1.13E-05
    47 Broy./Diag. 0.40E+00    7.5     0.00000456     -4911.5199194283 -8.71E-06
    48 Broy./Diag. 0.40E+00    7.3     0.00000459     -4911.5199208467 -1.42E-06
    49 Broy./Diag. 0.40E+00    7.1     0.00000356     -4911.5198997973  2.10E-05
    50 Broy./Diag. 0.40E+00    7.2     0.00000344     -4911.5199119048 -1.21E-05
    51 Broy./Diag. 0.40E+00    7.1     0.00000235     -4911.5199082094  3.70E-06
    52 Broy./Diag. 0.40E+00    7.4     0.00000141     -4911.5199091718 -9.62E-07
    53 Broy./Diag. 0.40E+00    7.1     0.00000169     -4911.5199037148  5.46E-06
    54 Broy./Diag. 0.40E+00    7.3     0.00000206     -4911.5199025989  1.12E-06
    55 Broy./Diag. 0.40E+00    6.9     0.00000161     -4911.5199109550 -8.36E-06
    56 Broy./Diag. 0.40E+00    8.1     0.00000190     -4911.5199015950  9.36E-06
    57 Broy./Diag. 0.40E+00    7.5     0.00000179     -4911.5199024764 -8.81E-07
    58 Broy./Diag. 0.40E+00    9.5     0.00000103     -4911.5199010935  1.38E-06
    59 Broy./Diag. 0.40E+00    7.2     0.00000120     -4911.5199035964 -2.50E-06
    60 Broy./Diag. 0.40E+00    9.6     0.00000112     -4911.5199026730  9.23E-07
    61 Broy./Diag. 0.40E+00    8.7     0.00000084     -4911.5198976083  5.06E-06

  *** SCF run converged in    61 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008350268478
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.94436367050503
  Hartree energy:                                            1781.37769618358698
  Exchange-correlation energy:                               -779.51280788879535
  Electronic entropic energy:                                  -0.23881058695635
  Fermi energy:                                                 0.08731422738387

  Total energy:                                             -4911.51989760834567

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.519896154052731

 MD| ***************************************************************************
 MD| Step number                                                            1150
 MD| Time [fs]                                                       2300.000000
 MD| Conserved quantity [hartree]                            -0.491119656645E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    454.077954           596.250655
 MD| Energy drift per atom [K]           0.255370698072E+03   0.270666806859E+03
 MD| Potential energy [hartree]         -0.491151989615E+04  -0.491156429469E+04
 MD| Kinetic energy [hartree]            0.323329702360E+00   0.375085910379E+00
 MD| Temperature [K]                             861.597662           999.515791
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.6     0.02249780     -4911.5232835654 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.0     0.09114251     -4911.4947065350  2.86E-02
     3 Broy./Diag. 0.40E+00    7.4     0.10255769     -4911.6731948676 -1.78E-01
     4 Broy./Diag. 0.40E+00    8.1     0.04399805     -4911.4679995274  2.05E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01193369     -4911.5396250355 -7.16E-02
     6 Broy./Diag. 0.40E+00    9.6     0.00558579     -4911.5171497007  2.25E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00421569     -4911.5532656295 -3.61E-02
     8 Broy./Diag. 0.40E+00    8.6     0.00209617     -4911.5119269779  4.13E-02
     9 Broy./Diag. 0.40E+00   10.5     0.00089567     -4911.5260300439 -1.41E-02
    10 Broy./Diag. 0.40E+00    7.0     0.00103881     -4911.5284956703 -2.47E-03
    11 Broy./Diag. 0.40E+00    8.5     0.00065611     -4911.5251850960  3.31E-03
    12 Broy./Diag. 0.40E+00    7.3     0.00026937     -4911.5264789588 -1.29E-03
    13 Broy./Diag. 0.40E+00    7.7     0.00019533     -4911.5259785206  5.00E-04
    14 Broy./Diag. 0.40E+00    7.3     0.00014938     -4911.5263765299 -3.98E-04
    15 Broy./Diag. 0.40E+00    9.8     0.00012620     -4911.5250223307  1.35E-03
    16 Broy./Diag. 0.40E+00    7.2     0.00017682     -4911.5259926120 -9.70E-04
    17 Broy./Diag. 0.40E+00    9.4     0.00019348     -4911.5260090540 -1.64E-05
    18 Broy./Diag. 0.40E+00    9.6     0.00012754     -4911.5250484898  9.61E-04
    19 Broy./Diag. 0.40E+00    7.0     0.00006542     -4911.5252702042 -2.22E-04
    20 Broy./Diag. 0.40E+00    7.3     0.00005864     -4911.5252861886 -1.60E-05
    21 Broy./Diag. 0.40E+00    7.1     0.00004000     -4911.5256219878 -3.36E-04
    22 Broy./Diag. 0.40E+00    7.5     0.00003965     -4911.5251304184  4.92E-04
    23 Broy./Diag. 0.40E+00    7.3     0.00005896     -4911.5251936866 -6.33E-05
    24 Broy./Diag. 0.40E+00    6.9     0.00004233     -4911.5254353512 -2.42E-04
    25 Broy./Diag. 0.40E+00    6.9     0.00001821     -4911.5252753834  1.60E-04
    26 Broy./Diag. 0.40E+00    8.0     0.00002027     -4911.5252619002  1.35E-05
    27 Broy./Diag. 0.40E+00    7.3     0.00001466     -4911.5252048008  5.71E-05
    28 Broy./Diag. 0.40E+00    6.7     0.00001393     -4911.5253211517 -1.16E-04
    29 Broy./Diag. 0.40E+00    7.3     0.00002408     -4911.5252590144  6.21E-05
    30 Broy./Diag. 0.40E+00    7.1     0.00002221     -4911.5251758839  8.31E-05
    31 Broy./Diag. 0.40E+00    7.1     0.00001159     -4911.5252536881 -7.78E-05
    32 Broy./Diag. 0.40E+00    7.3     0.00001260     -4911.5252345666  1.91E-05
    33 Broy./Diag. 0.40E+00    7.5     0.00001127     -4911.5252432353 -8.67E-06
    34 Broy./Diag. 0.40E+00    7.9     0.00000652     -4911.5251977605  4.55E-05
    35 Broy./Diag. 0.40E+00    7.1     0.00001001     -4911.5252188459 -2.11E-05
    36 Broy./Diag. 0.40E+00    7.1     0.00000956     -4911.5252331347 -1.43E-05
    37 Broy./Diag. 0.40E+00    7.5     0.00000580     -4911.5251957613  3.74E-05
    38 Broy./Diag. 0.40E+00    6.9     0.00000573     -4911.5252121489 -1.64E-05
    39 Broy./Diag. 0.40E+00    7.3     0.00000746     -4911.5252036568  8.49E-06
    40 Broy./Diag. 0.40E+00    7.3     0.00000394     -4911.5252108186 -7.16E-06
    41 Broy./Diag. 0.40E+00    7.3     0.00000580     -4911.5251958017  1.50E-05
    42 Broy./Diag. 0.40E+00    7.5     0.00000580     -4911.5251919772  3.82E-06
    43 Broy./Diag. 0.40E+00    8.4     0.00000339     -4911.5252108091 -1.88E-05
    44 Broy./Diag. 0.40E+00    7.3     0.00000285     -4911.5251908098  2.00E-05
    45 Broy./Diag. 0.40E+00    7.3     0.00000378     -4911.5251950973 -4.29E-06
    46 Broy./Diag. 0.40E+00    7.1     0.00000189     -4911.5251944008  6.97E-07
    47 Broy./Diag. 0.40E+00    6.7     0.00000290     -4911.5251965416 -2.14E-06
    48 Broy./Diag. 0.40E+00    7.7     0.00000315     -4911.5251930927  3.45E-06
    49 Broy./Diag. 0.40E+00    7.3     0.00000217     -4911.5251830622  1.00E-05
    50 Broy./Diag. 0.40E+00    6.9     0.00000186     -4911.5251952867 -1.22E-05
    51 Broy./Diag. 0.40E+00    7.3     0.00000235     -4911.5251908182  4.47E-06
    52 Broy./Diag. 0.40E+00    7.1     0.00000105     -4911.5251877975  3.02E-06
    53 Broy./Diag. 0.40E+00    7.7     0.00000149     -4911.5251861576  1.64E-06
    54 Broy./Diag. 0.40E+00    7.4     0.00000165     -4911.5251879408 -1.78E-06
    55 Broy./Diag. 0.40E+00    7.7     0.00000109     -4911.5251915699 -3.63E-06
    56 Broy./Diag. 0.40E+00    6.7     0.00000102     -4911.5251840046  7.57E-06
    57 Broy./Diag. 0.40E+00    7.1     0.00000137     -4911.5251859908 -1.99E-06
    58 Broy./Diag. 0.40E+00    6.9     0.00000075     -4911.5251873007 -1.31E-06

  *** SCF run converged in    58 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008329060028
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.93187836830657
  Hartree energy:                                            1781.38153737985112
  Exchange-correlation energy:                               -779.50953914397826
  Electronic entropic energy:                                  -0.23872468209459
  Fermi energy:                                                 0.08731179247849

  Total energy:                                             -4911.52518730066822

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.525182464582940

 MD| ***************************************************************************
 MD| Step number                                                            1151
 MD| Time [fs]                                                       2302.000000
 MD| Conserved quantity [hartree]                            -0.491118175538E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    445.431886           596.119623
 MD| Energy drift per atom [K]           0.286140174139E+03   0.270680250271E+03
 MD| Potential energy [hartree]         -0.491152518246E+04  -0.491156426071E+04
 MD| Kinetic energy [hartree]            0.343427082725E+00   0.375058404882E+00
 MD| Temperature [K]                             915.152457           999.442496
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.02574408     -4911.5279230871 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.06894703     -4911.5033878628  2.45E-02
     3 Broy./Diag. 0.40E+00    6.8     0.08039074     -4911.6422219569 -1.39E-01
     4 Broy./Diag. 0.40E+00    7.2     0.04393118     -4911.4838071842  1.58E-01
     5 Broy./Diag. 0.40E+00    7.4     0.01786777     -4911.5499026392 -6.61E-02
     6 Broy./Diag. 0.40E+00    7.1     0.00655942     -4911.5196992400  3.02E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00439713     -4911.5584227484 -3.87E-02
     8 Broy./Diag. 0.40E+00    7.1     0.00168784     -4911.5216727441  3.68E-02
     9 Broy./Diag. 0.40E+00    6.9     0.00140763     -4911.5264205331 -4.75E-03
    10 Broy./Diag. 0.40E+00    7.7     0.00171612     -4911.5366395421 -1.02E-02
    11 Broy./Diag. 0.40E+00    7.3     0.00124498     -4911.5311485433  5.49E-03
    12 Broy./Diag. 0.40E+00    7.3     0.00040916     -4911.5306065531  5.42E-04
    13 Broy./Diag. 0.40E+00    7.3     0.00032168     -4911.5298330025  7.74E-04
    14 Broy./Diag. 0.40E+00    6.8     0.00025061     -4911.5316669145 -1.83E-03
    15 Broy./Diag. 0.40E+00    7.0     0.00014548     -4911.5299137762  1.75E-03
    16 Broy./Diag. 0.40E+00    7.3     0.00026020     -4911.5298006408  1.13E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00036788     -4911.5314092521 -1.61E-03
    18 Broy./Diag. 0.40E+00    7.1     0.00021563     -4911.5309592364  4.50E-04
    19 Broy./Diag. 0.40E+00    7.1     0.00011157     -4911.5302378061  7.21E-04
    20 Broy./Diag. 0.40E+00    7.5     0.00012293     -4911.5296228313  6.15E-04
    21 Broy./Diag. 0.40E+00    7.5     0.00006798     -4911.5305199019 -8.97E-04
    22 Broy./Diag. 0.40E+00    6.9     0.00005886     -4911.5304525816  6.73E-05
    23 Broy./Diag. 0.40E+00    7.3     0.00008025     -4911.5300099466  4.43E-04
    24 Broy./Diag. 0.40E+00    7.5     0.00006683     -4911.5301474172 -1.37E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00004518     -4911.5303241058 -1.77E-04
    26 Broy./Diag. 0.40E+00    7.3     0.00004909     -4911.5304315703 -1.07E-04
    27 Broy./Diag. 0.40E+00    6.9     0.00004184     -4911.5300060804  4.25E-04
    28 Broy./Diag. 0.40E+00    7.0     0.00004392     -4911.5300796948 -7.36E-05
    29 Broy./Diag. 0.40E+00    6.8     0.00005421     -4911.5303653135 -2.86E-04
    30 Broy./Diag. 0.40E+00    7.3     0.00003845     -4911.5301866738  1.79E-04
    31 Broy./Diag. 0.40E+00    7.1     0.00002513     -4911.5301039765  8.27E-05
    32 Broy./Diag. 0.40E+00    6.9     0.00001635     -4911.5300593493  4.46E-05
    33 Broy./Diag. 0.40E+00    7.0     0.00001511     -4911.5301894880 -1.30E-04
    34 Broy./Diag. 0.40E+00    6.7     0.00001386     -4911.5301455859  4.39E-05
    35 Broy./Diag. 0.40E+00    7.3     0.00002226     -4911.5300541619  9.14E-05
    36 Broy./Diag. 0.40E+00    7.3     0.00002292     -4911.5301324570 -7.83E-05
    37 Broy./Diag. 0.40E+00    7.3     0.00002006     -4911.5301573321 -2.49E-05
    38 Broy./Diag. 0.40E+00    6.9     0.00001086     -4911.5301457639  1.16E-05
    39 Broy./Diag. 0.40E+00    7.1     0.00001022     -4911.5300569791  8.88E-05
    40 Broy./Diag. 0.40E+00    7.3     0.00000739     -4911.5300934375 -3.65E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00000967     -4911.5301350504 -4.16E-05
    42 Broy./Diag. 0.40E+00    7.7     0.00000776     -4911.5300918557  4.32E-05
    43 Broy./Diag. 0.40E+00    7.3     0.00000785     -4911.5300875591  4.30E-06
    44 Broy./Diag. 0.40E+00    7.3     0.00000551     -4911.5300927935 -5.23E-06
    45 Broy./Diag. 0.40E+00    7.3     0.00000576     -4911.5301244413 -3.16E-05
    46 Broy./Diag. 0.40E+00    7.3     0.00000428     -4911.5300902782  3.42E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00000707     -4911.5300711329  1.91E-05
    48 Broy./Diag. 0.40E+00    7.2     0.00000583     -4911.5301035438 -3.24E-05
    49 Broy./Diag. 0.40E+00    6.7     0.00000453     -4911.5300980524  5.49E-06
    50 Broy./Diag. 0.40E+00    7.9     0.00000290     -4911.5300914539  6.60E-06
    51 Broy./Diag. 0.40E+00    7.3     0.00000217     -4911.5300796081  1.18E-05
    52 Broy./Diag. 0.40E+00    7.9     0.00000187     -4911.5300924978 -1.29E-05
    53 Broy./Diag. 0.40E+00    7.3     0.00000298     -4911.5300960705 -3.57E-06
    54 Broy./Diag. 0.40E+00    7.3     0.00000300     -4911.5300798361  1.62E-05
    55 Broy./Diag. 0.40E+00    7.5     0.00000297     -4911.5300840526 -4.22E-06
    56 Broy./Diag. 0.40E+00    6.6     0.00000247     -4911.5300882995 -4.25E-06
    57 Broy./Diag. 0.40E+00    7.5     0.00000149     -4911.5300925454 -4.25E-06
    58 Broy./Diag. 0.40E+00    6.8     0.00000115     -4911.5300823100  1.02E-05
    59 Broy./Diag. 0.40E+00    7.3     0.00000145     -4911.5300809376  1.37E-06
    60 Broy./Diag. 0.40E+00    7.1     0.00000143     -4911.5300887051 -7.77E-06
    61 Broy./Diag. 0.40E+00    7.3     0.00000112     -4911.5300855374  3.17E-06
    62 Broy./Diag. 0.40E+00    7.2     0.00000116     -4911.5300831702  2.37E-06
    63 Broy./Diag. 0.40E+00    7.2     0.00000075     -4911.5300818325  1.34E-06

  *** SCF run converged in    63 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008312157314
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.91702117446175
  Hartree energy:                                            1781.38728795299812
  Exchange-correlation energy:                               -779.50544475067932
  Electronic entropic energy:                                  -0.23860684579747
  Fermi energy:                                                 0.08730899670127

  Total energy:                                             -4911.53008183246038

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.530082292468251

 MD| ***************************************************************************
 MD| Step number                                                            1152
 MD| Time [fs]                                                       2304.000000
 MD| Conserved quantity [hartree]                            -0.491118095093E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    461.441318           596.002714
 MD| Energy drift per atom [K]           0.287811401551E+03   0.270695121062E+03
 MD| Potential energy [hartree]         -0.491153008229E+04  -0.491156423104E+04
 MD| Kinetic energy [hartree]            0.349131365839E+00   0.375035898771E+00
 MD| Temperature [K]                             930.353031           999.382522
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.02782706     -4911.5314518027 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.7     0.05999108     -4911.5219316203  9.52E-03
     3 Broy./Diag. 0.40E+00    7.8     0.06425110     -4911.5899186946 -6.80E-02
     4 Broy./Diag. 0.40E+00    7.3     0.02576414     -4911.5231065758  6.68E-02
     5 Broy./Diag. 0.40E+00    6.9     0.01720507     -4911.5351640793 -1.21E-02
     6 Broy./Diag. 0.40E+00    7.3     0.01075306     -4911.5256932928  9.47E-03
     7 Broy./Diag. 0.40E+00    7.3     0.00536249     -4911.5654174283 -3.97E-02
     8 Broy./Diag. 0.40E+00    7.0     0.00176179     -4911.5246687140  4.07E-02
     9 Broy./Diag. 0.40E+00    7.4     0.00190508     -4911.5297512666 -5.08E-03
    10 Broy./Diag. 0.40E+00    7.0     0.00122276     -4911.5417145812 -1.20E-02
    11 Broy./Diag. 0.40E+00    7.5     0.00100198     -4911.5368004652  4.91E-03
    12 Broy./Diag. 0.40E+00    6.9     0.00072564     -4911.5344717003  2.33E-03
    13 Broy./Diag. 0.40E+00    6.7     0.00051224     -4911.5330188038  1.45E-03
    14 Broy./Diag. 0.40E+00    6.9     0.00021395     -4911.5358723282 -2.85E-03
    15 Broy./Diag. 0.40E+00    7.6     0.00022892     -4911.5342453835  1.63E-03
    16 Broy./Diag. 0.40E+00    7.5     0.00022732     -4911.5334504694  7.95E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00030837     -4911.5350100658 -1.56E-03
    18 Broy./Diag. 0.40E+00    7.3     0.00028298     -4911.5352134331 -2.03E-04
    19 Broy./Diag. 0.40E+00    6.6     0.00021226     -4911.5344743142  7.39E-04
    20 Broy./Diag. 0.40E+00    7.1     0.00011849     -4911.5333044792  1.17E-03
    21 Broy./Diag. 0.40E+00    7.3     0.00011853     -4911.5342467192 -9.42E-04
    22 Broy./Diag. 0.40E+00    7.1     0.00007417     -4911.5344893243 -2.43E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00007560     -4911.5339542087  5.35E-04
    24 Broy./Diag. 0.40E+00    7.3     0.00008450     -4911.5339245894  2.96E-05
    25 Broy./Diag. 0.40E+00    7.3     0.00008088     -4911.5341149177 -1.90E-04
    26 Broy./Diag. 0.40E+00    7.5     0.00005722     -4911.5344724047 -3.57E-04
    27 Broy./Diag. 0.40E+00    6.8     0.00006955     -4911.5339042983  5.68E-04
    28 Broy./Diag. 0.40E+00    7.4     0.00006213     -4911.5338125343  9.18E-05
    29 Broy./Diag. 0.40E+00    6.8     0.00005251     -4911.5341769432 -3.64E-04
    30 Broy./Diag. 0.40E+00    7.2     0.00005239     -4911.5341063523  7.06E-05
    31 Broy./Diag. 0.40E+00    7.1     0.00003804     -4911.5339801828  1.26E-04
    32 Broy./Diag. 0.40E+00    7.2     0.00002185     -4911.5338138630  1.66E-04
    33 Broy./Diag. 0.40E+00    7.1     0.00002809     -4911.5340137960 -2.00E-04
    34 Broy./Diag. 0.40E+00    7.3     0.00002556     -4911.5340464562 -3.27E-05
    35 Broy./Diag. 0.40E+00    7.5     0.00002115     -4911.5338882605  1.58E-04
    36 Broy./Diag. 0.40E+00    7.3     0.00003073     -4911.5339197729 -3.15E-05
    37 Broy./Diag. 0.40E+00    7.1     0.00002532     -4911.5339765256 -5.68E-05
    38 Broy./Diag. 0.40E+00    7.1     0.00001514     -4911.5340325305 -5.60E-05
    39 Broy./Diag. 0.40E+00    6.7     0.00001243     -4911.5338914353  1.41E-04
    40 Broy./Diag. 0.40E+00    7.1     0.00001401     -4911.5338915089 -7.35E-08
    41 Broy./Diag. 0.40E+00    7.3     0.00000833     -4911.5339640061 -7.25E-05
    42 Broy./Diag. 0.40E+00    6.9     0.00001078     -4911.5339348427  2.92E-05
    43 Broy./Diag. 0.40E+00    7.1     0.00000972     -4911.5339162437  1.86E-05
    44 Broy./Diag. 0.40E+00    6.9     0.00000714     -4911.5338970742  1.92E-05
    45 Broy./Diag. 0.40E+00    7.2     0.00000588     -4911.5339570685 -6.00E-05
    46 Broy./Diag. 0.40E+00    6.8     0.00000964     -4911.5339357348  2.13E-05
    47 Broy./Diag. 0.40E+00    7.0     0.00000650     -4911.5338931705  4.26E-05
    48 Broy./Diag. 0.40E+00    7.5     0.00000740     -4911.5339154516 -2.23E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00000542     -4911.5339196047 -4.15E-06
    50 Broy./Diag. 0.40E+00    7.1     0.00000325     -4911.5339247889 -5.18E-06
    51 Broy./Diag. 0.40E+00    6.6     0.00000269     -4911.5338993088  2.55E-05
    52 Broy./Diag. 0.40E+00    6.9     0.00000421     -4911.5339094531 -1.01E-05
    53 Broy./Diag. 0.40E+00    7.1     0.00000366     -4911.5339240644 -1.46E-05
    54 Broy./Diag. 0.40E+00    7.1     0.00000401     -4911.5339074412  1.66E-05
    55 Broy./Diag. 0.40E+00    7.0     0.00000353     -4911.5339059339  1.51E-06
    56 Broy./Diag. 0.40E+00    7.5     0.00000221     -4911.5339029712  2.96E-06
    57 Broy./Diag. 0.40E+00    7.0     0.00000205     -4911.5339162172 -1.32E-05
    58 Broy./Diag. 0.40E+00    6.9     0.00000194     -4911.5339081061  8.11E-06
    59 Broy./Diag. 0.40E+00    6.9     0.00000165     -4911.5339021211  5.99E-06
    60 Broy./Diag. 0.40E+00    7.3     0.00000184     -4911.5339089175 -6.80E-06
    61 Broy./Diag. 0.40E+00    8.1     0.00000165     -4911.5339075330  1.38E-06
    62 Broy./Diag. 0.40E+00    7.3     0.00000123     -4911.5339078938 -3.61E-07
    63 Broy./Diag. 0.40E+00    7.0     0.00000119     -4911.5339020314  5.86E-06
    64 Broy./Diag. 0.40E+00    6.9     0.00000130     -4911.5339064214 -4.39E-06
    65 Broy./Diag. 0.40E+00    7.7     0.00000106     -4911.5339088279 -2.41E-06
    66 Broy./Diag. 0.40E+00    7.5     0.00000118     -4911.5339034690  5.36E-06
    67 Broy./Diag. 0.40E+00    7.1     0.00000101     -4911.5339046958 -1.23E-06
    68 Broy./Diag. 0.40E+00    6.9     0.00000071     -4911.5339039596  7.36E-07

  *** SCF run converged in    68 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008300395090
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.90889252676516
  Hartree energy:                                            1781.38944946003699
  Exchange-correlation energy:                               -779.50342843688918
  Electronic entropic energy:                                  -0.23847801365744
  Fermi energy:                                                 0.08732018828709

  Total energy:                                             -4911.53390395964198

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.533902953752659

 MD| ***************************************************************************
 MD| Step number                                                            1153
 MD| Time [fs]                                                       2306.000000
 MD| Conserved quantity [hartree]                            -0.491117409500E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    494.172095           595.914396
 MD| Energy drift per atom [K]           0.302054356218E+03   0.270722319011E+03
 MD| Potential energy [hartree]         -0.491153390295E+04  -0.491156420474E+04
 MD| Kinetic energy [hartree]            0.359807957844E+00   0.375022691537E+00
 MD| Temperature [K]                             958.803639           999.347328
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.6     0.03089701     -4911.5336142314 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.07986375     -4911.5684442303 -3.48E-02
     3 Broy./Diag. 0.40E+00    7.1     0.07969619     -4911.4451912597  1.23E-01
     4 Broy./Diag. 0.40E+00    7.1     0.02679754     -4911.6020603289 -1.57E-01
     5 Broy./Diag. 0.40E+00    6.7     0.01204418     -4911.5061008861  9.60E-02
     6 Broy./Diag. 0.40E+00    7.7     0.00989416     -4911.5574442831 -5.13E-02
     7 Broy./Diag. 0.40E+00    6.7     0.00590450     -4911.5510324204  6.41E-03
     8 Broy./Diag. 0.40E+00    6.8     0.00306467     -4911.5319761573  1.91E-02
     9 Broy./Diag. 0.40E+00    7.2     0.00250450     -4911.5290767131  2.90E-03
    10 Broy./Diag. 0.40E+00    7.3     0.00150016     -4911.5430090847 -1.39E-02
    11 Broy./Diag. 0.40E+00    7.1     0.00103205     -4911.5427939886  2.15E-04
    12 Broy./Diag. 0.40E+00    7.0     0.00063974     -4911.5355826631  7.21E-03
    13 Broy./Diag. 0.40E+00    7.7     0.00048219     -4911.5366972813 -1.11E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00034102     -4911.5377762933 -1.08E-03
    15 Broy./Diag. 0.40E+00    7.0     0.00026866     -4911.5373085241  4.68E-04
    16 Broy./Diag. 0.40E+00    7.3     0.00031443     -4911.5356441321  1.66E-03
    17 Broy./Diag. 0.40E+00    8.2     0.00028584     -4911.5362862363 -6.42E-04
    18 Broy./Diag. 0.40E+00    7.5     0.00028616     -4911.5379390451 -1.65E-03
    19 Broy./Diag. 0.40E+00    6.9     0.00019875     -4911.5367304822  1.21E-03
    20 Broy./Diag. 0.40E+00    6.9     0.00015336     -4911.5361143833  6.16E-04
    21 Broy./Diag. 0.40E+00    7.1     0.00013488     -4911.5363468901 -2.33E-04
    22 Broy./Diag. 0.40E+00    7.1     0.00010528     -4911.5369731578 -6.26E-04
    23 Broy./Diag. 0.40E+00    6.9     0.00009441     -4911.5365012999  4.72E-04
    24 Broy./Diag. 0.40E+00    6.9     0.00009814     -4911.5359789884  5.22E-04
    25 Broy./Diag. 0.40E+00    7.3     0.00008350     -4911.5364332445 -4.54E-04
    26 Broy./Diag. 0.40E+00    7.4     0.00006796     -4911.5366412055 -2.08E-04
    27 Broy./Diag. 0.40E+00    6.9     0.00007493     -4911.5363930354  2.48E-04
    28 Broy./Diag. 0.40E+00    7.3     0.00007402     -4911.5360696085  3.23E-04
    29 Broy./Diag. 0.40E+00    7.1     0.00005062     -4911.5363460449 -2.76E-04
    30 Broy./Diag. 0.40E+00    7.4     0.00005339     -4911.5365721572 -2.26E-04
    31 Broy./Diag. 0.40E+00    7.5     0.00004296     -4911.5362651117  3.07E-04
    32 Broy./Diag. 0.40E+00    7.3     0.00002527     -4911.5361869328  7.82E-05
    33 Broy./Diag. 0.40E+00    6.9     0.00003749     -4911.5362865731 -9.96E-05
    34 Broy./Diag. 0.40E+00    7.1     0.00003932     -4911.5364373119 -1.51E-04
    35 Broy./Diag. 0.40E+00    7.1     0.00002386     -4911.5362548566  1.82E-04
    36 Broy./Diag. 0.40E+00    6.9     0.00003007     -4911.5361598614  9.50E-05
    37 Broy./Diag. 0.40E+00    7.1     0.00002933     -4911.5363359434 -1.76E-04
    38 Broy./Diag. 0.40E+00    7.6     0.00001681     -4911.5363554645 -1.95E-05
    39 Broy./Diag. 0.40E+00    7.1     0.00001874     -4911.5362709045  8.46E-05
    40 Broy./Diag. 0.40E+00    6.9     0.00001842     -4911.5362130321  5.79E-05
    41 Broy./Diag. 0.40E+00    7.5     0.00001166     -4911.5362905078 -7.75E-05
    42 Broy./Diag. 0.40E+00    7.2     0.00001255     -4911.5362964423 -5.93E-06
    43 Broy./Diag. 0.40E+00    7.3     0.00001454     -4911.5362257455  7.07E-05
    44 Broy./Diag. 0.40E+00    7.3     0.00000958     -4911.5362352753 -9.53E-06
    45 Broy./Diag. 0.40E+00    7.3     0.00001165     -4911.5362725422 -3.73E-05
    46 Broy./Diag. 0.40E+00    7.1     0.00001209     -4911.5362881597 -1.56E-05
    47 Broy./Diag. 0.40E+00    6.8     0.00000955     -4911.5362342073  5.40E-05
    48 Broy./Diag. 0.40E+00    7.7     0.00000619     -4911.5362331360  1.07E-06
    49 Broy./Diag. 0.40E+00    7.3     0.00000722     -4911.5362670858 -3.39E-05
    50 Broy./Diag. 0.40E+00    9.9     0.00000476     -4911.5362538258  1.33E-05
    51 Broy./Diag. 0.40E+00    7.4     0.00000395     -4911.5362390667  1.48E-05
    52 Broy./Diag. 0.40E+00    8.9     0.00000542     -4911.5362388669  2.00E-07
    53 Broy./Diag. 0.40E+00    9.4     0.00000641     -4911.5362607128 -2.18E-05
    54 Broy./Diag. 0.40E+00    7.3     0.00000379     -4911.5362536644  7.05E-06
    55 Broy./Diag. 0.40E+00    6.7     0.00000498     -4911.5362308263  2.28E-05
    56 Broy./Diag. 0.40E+00    7.1     0.00000314     -4911.5362435122 -1.27E-05
    57 Broy./Diag. 0.40E+00    7.3     0.00000227     -4911.5362508031 -7.29E-06
    58 Broy./Diag. 0.40E+00    7.2     0.00000199     -4911.5362483117  2.49E-06
    59 Broy./Diag. 0.40E+00    7.8     0.00000283     -4911.5362386826  9.63E-06
    60 Broy./Diag. 0.40E+00    8.3     0.00000127     -4911.5362423616 -3.68E-06
    61 Broy./Diag. 0.40E+00    9.3     0.00000251     -4911.5362491262 -6.76E-06
    62 Broy./Diag. 0.40E+00    7.3     0.00000202     -4911.5362415686  7.56E-06
    63 Broy./Diag. 0.40E+00   11.1     0.00000167     -4911.5362378913  3.68E-06
    64 Broy./Diag. 0.40E+00    7.5     0.00000133     -4911.5362405909 -2.70E-06
    65 Broy./Diag. 0.40E+00    7.4     0.00000196     -4911.5362462302 -5.64E-06
    66 Broy./Diag. 0.40E+00    6.9     0.00000074     -4911.5362424516  3.78E-06

  *** SCF run converged in    66 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008293271218
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.90739763751299
  Hartree energy:                                            1781.38832687199124
  Exchange-correlation energy:                               -779.50323623865802
  Electronic entropic energy:                                  -0.23839112381028
  Fermi energy:                                                 0.08733973158411

  Total energy:                                             -4911.53624245158790

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.536239566345103

 MD| ***************************************************************************
 MD| Step number                                                            1154
 MD| Time [fs]                                                       2308.000000
 MD| Conserved quantity [hartree]                            -0.491117062537E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    498.008003           595.829555
 MD| Energy drift per atom [K]           0.309262377858E+03   0.270755715942E+03
 MD| Potential energy [hartree]         -0.491153623957E+04  -0.491156418050E+04
 MD| Kinetic energy [hartree]            0.365614194412E+00   0.375014538593E+00
 MD| Temperature [K]                             974.275895           999.325602
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.03089979     -4911.5343881006 -4.91E+03
     2 Broy./Diag. 0.40E+00   10.0     0.09362600     -4911.6025778073 -6.82E-02
     3 Broy./Diag. 0.40E+00    8.1     0.08614260     -4911.3314133385  2.71E-01
     4 Broy./Diag. 0.40E+00    8.3     0.02819850     -4911.6332912494 -3.02E-01
     5 Broy./Diag. 0.40E+00   10.4     0.01842692     -4911.5019986151  1.31E-01
     6 Broy./Diag. 0.40E+00    6.7     0.01046189     -4911.5500657902 -4.81E-02
     7 Broy./Diag. 0.40E+00    6.9     0.00449774     -4911.5530329117 -2.97E-03
     8 Broy./Diag. 0.40E+00    7.5     0.00230693     -4911.5330947099  1.99E-02
     9 Broy./Diag. 0.40E+00    7.1     0.00269159     -4911.5290755807  4.02E-03
    10 Broy./Diag. 0.40E+00    7.3     0.00151350     -4911.5418752350 -1.28E-02
    11 Broy./Diag. 0.40E+00    6.9     0.00145175     -4911.5444165014 -2.54E-03
    12 Broy./Diag. 0.40E+00    7.8     0.00081828     -4911.5363198462  8.10E-03
    13 Broy./Diag. 0.40E+00    8.3     0.00036072     -4911.5367965754 -4.77E-04
    14 Broy./Diag. 0.40E+00    7.3     0.00027623     -4911.5382456339 -1.45E-03
    15 Broy./Diag. 0.40E+00    7.3     0.00030404     -4911.5379383092  3.07E-04
    16 Broy./Diag. 0.40E+00    7.1     0.00029197     -4911.5363787399  1.56E-03
    17 Broy./Diag. 0.40E+00    7.3     0.00034322     -4911.5364979613 -1.19E-04
    18 Broy./Diag. 0.40E+00    7.3     0.00033014     -4911.5384374412 -1.94E-03
    19 Broy./Diag. 0.40E+00    6.9     0.00020047     -4911.5376649886  7.72E-04
    20 Broy./Diag. 0.40E+00    6.9     0.00014725     -4911.5368056147  8.59E-04
    21 Broy./Diag. 0.40E+00    7.1     0.00015847     -4911.5369630847 -1.57E-04
    22 Broy./Diag. 0.40E+00    7.5     0.00010969     -4911.5375914494 -6.28E-04
    23 Broy./Diag. 0.40E+00    6.9     0.00011591     -4911.5372561292  3.35E-04
    24 Broy./Diag. 0.40E+00    7.3     0.00013348     -4911.5366094137  6.47E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00008170     -4911.5370304867 -4.21E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00007558     -4911.5373064053 -2.76E-04
    27 Broy./Diag. 0.40E+00    7.4     0.00008115     -4911.5371374793  1.69E-04
    28 Broy./Diag. 0.40E+00    7.4     0.00007654     -4911.5368052366  3.32E-04
    29 Broy./Diag. 0.40E+00    7.3     0.00005201     -4911.5370101775 -2.05E-04
    30 Broy./Diag. 0.40E+00    7.8     0.00006658     -4911.5372910420 -2.81E-04
    31 Broy./Diag. 0.40E+00    7.1     0.00004062     -4911.5370226921  2.68E-04
    32 Broy./Diag. 0.40E+00    6.7     0.00002616     -4911.5369118193  1.11E-04
    33 Broy./Diag. 0.40E+00    7.2     0.00003688     -4911.5370159016 -1.04E-04
    34 Broy./Diag. 0.40E+00    6.9     0.00004661     -4911.5371616893 -1.46E-04
    35 Broy./Diag. 0.40E+00    7.7     0.00002555     -4911.5370019221  1.60E-04
    36 Broy./Diag. 0.40E+00    7.1     0.00004260     -4911.5368732466  1.29E-04
    37 Broy./Diag. 0.40E+00    7.7     0.00002854     -4911.5370576962 -1.84E-04
    38 Broy./Diag. 0.40E+00    7.0     0.00001526     -4911.5371016763 -4.40E-05
    39 Broy./Diag. 0.40E+00    7.1     0.00001851     -4911.5370159033  8.58E-05
    40 Broy./Diag. 0.40E+00    7.3     0.00002276     -4911.5369611152  5.48E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00001274     -4911.5370327826 -7.17E-05
    42 Broy./Diag. 0.40E+00    7.7     0.00001897     -4911.5370524047 -1.96E-05
    43 Broy./Diag. 0.40E+00    7.3     0.00001679     -4911.5369704579  8.19E-05
    44 Broy./Diag. 0.40E+00    7.5     0.00001088     -4911.5369657545  4.70E-06
    45 Broy./Diag. 0.40E+00    7.4     0.00001165     -4911.5370184350 -5.27E-05
    46 Broy./Diag. 0.40E+00    6.9     0.00001544     -4911.5370386909 -2.03E-05
    47 Broy./Diag. 0.40E+00    7.3     0.00000974     -4911.5369874108  5.13E-05
    48 Broy./Diag. 0.40E+00    7.6     0.00000927     -4911.5369774525  9.96E-06
    49 Broy./Diag. 0.40E+00    7.0     0.00000785     -4911.5370185185 -4.11E-05
    50 Broy./Diag. 0.40E+00    6.9     0.00000566     -4911.5370105141  8.00E-06
    51 Broy./Diag. 0.40E+00    7.1     0.00000501     -4911.5369877281  2.28E-05
    52 Broy./Diag. 0.40E+00    7.0     0.00000799     -4911.5369870007  7.27E-07
    53 Broy./Diag. 0.40E+00    6.9     0.00000704     -4911.5370120316 -2.50E-05
    54 Broy./Diag. 0.40E+00    7.1     0.00000628     -4911.5370112257  8.06E-07
    55 Broy./Diag. 0.40E+00    7.2     0.00000602     -4911.5369822711  2.90E-05
    56 Broy./Diag. 0.40E+00    7.0     0.00000363     -4911.5369917308 -9.46E-06
    57 Broy./Diag. 0.40E+00    7.3     0.00000272     -4911.5370044594 -1.27E-05
    58 Broy./Diag. 0.40E+00    7.1     0.00000297     -4911.5370027705  1.69E-06
    59 Broy./Diag. 0.40E+00    7.2     0.00000319     -4911.5369924113  1.04E-05
    60 Broy./Diag. 0.40E+00    7.2     0.00000240     -4911.5369934539 -1.04E-06
    61 Broy./Diag. 0.40E+00    6.7     0.00000311     -4911.5370044386 -1.10E-05
    62 Broy./Diag. 0.40E+00    6.9     0.00000241     -4911.5369977884  6.65E-06
    63 Broy./Diag. 0.40E+00    7.5     0.00000194     -4911.5369904552  7.33E-06
    64 Broy./Diag. 0.40E+00    7.1     0.00000203     -4911.5369934968 -3.04E-06
    65 Broy./Diag. 0.40E+00    7.1     0.00000210     -4911.5370000627 -6.57E-06
    66 Broy./Diag. 0.40E+00    6.9     0.00000127     -4911.5369981658  1.90E-06
    67 Broy./Diag. 0.40E+00    7.1     0.00000155     -4911.5369921078  6.06E-06
    68 Broy./Diag. 0.40E+00    6.9     0.00000087     -4911.5369958822 -3.77E-06

  *** SCF run converged in    68 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008292634089
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.91254216717334
  Hartree energy:                                            1781.38406217653232
  Exchange-correlation energy:                               -779.50490868435213
  Electronic entropic energy:                                  -0.23835196955794
  Fermi energy:                                                 0.08736356169422

  Total energy:                                             -4911.53699588217842

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.536994997492002

 MD| ***************************************************************************
 MD| Step number                                                            1155
 MD| Time [fs]                                                       2310.000000
 MD| Conserved quantity [hartree]                            -0.491118514900E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    506.532433           595.752242
 MD| Energy drift per atom [K]           0.279090051245E+03   0.270762931817E+03
 MD| Potential energy [hartree]         -0.491153699500E+04  -0.491156415697E+04
 MD| Kinetic energy [hartree]            0.351845997156E+00   0.374994479250E+00
 MD| Temperature [K]                             937.586885           999.272149
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.02680125     -4911.5335728830 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.08556928     -4911.6214393628 -8.79E-02
     3 Broy./Diag. 0.40E+00    6.9     0.08030477     -4911.2501348021  3.71E-01
     4 Broy./Diag. 0.40E+00    6.9     0.03385703     -4911.6738345421 -4.24E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01966854     -4911.4958861789  1.78E-01
     6 Broy./Diag. 0.40E+00    7.2     0.00944850     -4911.5451870581 -4.93E-02
     7 Broy./Diag. 0.40E+00    6.9     0.00359281     -4911.5540355835 -8.85E-03
     8 Broy./Diag. 0.40E+00    7.3     0.00215183     -4911.5277829797  2.63E-02
     9 Broy./Diag. 0.40E+00    7.1     0.00183772     -4911.5313031361 -3.52E-03
    10 Broy./Diag. 0.40E+00    6.7     0.00124568     -4911.5389106038 -7.61E-03
    11 Broy./Diag. 0.40E+00    7.1     0.00125648     -4911.5425395208 -3.63E-03
    12 Broy./Diag. 0.40E+00    6.9     0.00074292     -4911.5350064463  7.53E-03
    13 Broy./Diag. 0.40E+00    7.0     0.00034850     -4911.5353585430 -3.52E-04
    14 Broy./Diag. 0.40E+00    7.4     0.00023631     -4911.5372033483 -1.84E-03
    15 Broy./Diag. 0.40E+00    7.1     0.00018404     -4911.5364081120  7.95E-04
    16 Broy./Diag. 0.40E+00    7.3     0.00021777     -4911.5356547602  7.53E-04
    17 Broy./Diag. 0.40E+00    7.5     0.00032596     -4911.5354668264  1.88E-04
    18 Broy./Diag. 0.40E+00    7.2     0.00029221     -4911.5373952842 -1.93E-03
    19 Broy./Diag. 0.40E+00    7.1     0.00018516     -4911.5365429655  8.52E-04
    20 Broy./Diag. 0.40E+00    7.3     0.00011289     -4911.5357151544  8.28E-04
    21 Broy./Diag. 0.40E+00    7.3     0.00010008     -4911.5361655353 -4.50E-04
    22 Broy./Diag. 0.40E+00    7.5     0.00008125     -4911.5364325195 -2.67E-04
    23 Broy./Diag. 0.40E+00    7.3     0.00010120     -4911.5363255330  1.07E-04
    24 Broy./Diag. 0.40E+00    7.1     0.00010662     -4911.5357457006  5.80E-04
    25 Broy./Diag. 0.40E+00    7.0     0.00007376     -4911.5361474815 -4.02E-04
    26 Broy./Diag. 0.40E+00    7.2     0.00005020     -4911.5363955332 -2.48E-04
    27 Broy./Diag. 0.40E+00    7.3     0.00006839     -4911.5361105846  2.85E-04
    28 Broy./Diag. 0.40E+00    7.8     0.00006602     -4911.5359899200  1.21E-04
    29 Broy./Diag. 0.40E+00    7.1     0.00005564     -4911.5360835896 -9.37E-05
    30 Broy./Diag. 0.40E+00    7.1     0.00006287     -4911.5363858831 -3.02E-04
    31 Broy./Diag. 0.40E+00    7.3     0.00003779     -4911.5361194712  2.66E-04
    32 Broy./Diag. 0.40E+00    7.3     0.00001963     -4911.5360211792  9.83E-05
    33 Broy./Diag. 0.40E+00    7.3     0.00003234     -4911.5361592489 -1.38E-04
    34 Broy./Diag. 0.40E+00    7.7     0.00003176     -4911.5361957095 -3.65E-05
    35 Broy./Diag. 0.40E+00    6.9     0.00002488     -4911.5361275088  6.82E-05
    36 Broy./Diag. 0.40E+00    6.8     0.00003997     -4911.5360074710  1.20E-04
    37 Broy./Diag. 0.40E+00    7.2     0.00002647     -4911.5361835778 -1.76E-04
    38 Broy./Diag. 0.40E+00    7.1     0.00001574     -4911.5362028816 -1.93E-05
    39 Broy./Diag. 0.40E+00    7.3     0.00001606     -4911.5361112394  9.16E-05
    40 Broy./Diag. 0.40E+00    6.9     0.00001549     -4911.5361141893 -2.95E-06
    41 Broy./Diag. 0.40E+00    7.3     0.00001212     -4911.5361405693 -2.64E-05
    42 Broy./Diag. 0.40E+00    6.9     0.00001647     -4911.5361653502 -2.48E-05
    43 Broy./Diag. 0.40E+00    7.5     0.00001458     -4911.5360951392  7.02E-05
    44 Broy./Diag. 0.40E+00    7.9     0.00001054     -4911.5361042948 -9.16E-06
    45 Broy./Diag. 0.40E+00    7.0     0.00000923     -4911.5361544437 -5.01E-05
    46 Broy./Diag. 0.40E+00    7.1     0.00001003     -4911.5361382393  1.62E-05
    47 Broy./Diag. 0.40E+00    6.9     0.00000978     -4911.5361229608  1.53E-05
    48 Broy./Diag. 0.40E+00    7.3     0.00000913     -4911.5361103758  1.26E-05
    49 Broy./Diag. 0.40E+00    7.0     0.00000764     -4911.5361498160 -3.94E-05
    50 Broy./Diag. 0.40E+00    7.2     0.00000562     -4911.5361354472  1.44E-05
    51 Broy./Diag. 0.40E+00    7.2     0.00000377     -4911.5361132485  2.22E-05
    52 Broy./Diag. 0.40E+00    7.0     0.00000512     -4911.5361286714 -1.54E-05
    53 Broy./Diag. 0.40E+00    7.5     0.00000661     -4911.5361336113 -4.94E-06
    54 Broy./Diag. 0.40E+00    7.3     0.00000553     -4911.5361361495 -2.54E-06
    55 Broy./Diag. 0.40E+00    7.5     0.00000557     -4911.5361129467  2.32E-05
    56 Broy./Diag. 0.40E+00    7.5     0.00000369     -4911.5361263822 -1.34E-05
    57 Broy./Diag. 0.40E+00    7.0     0.00000215     -4911.5361383371 -1.20E-05
    58 Broy./Diag. 0.40E+00    7.1     0.00000180     -4911.5361276217  1.07E-05
    59 Broy./Diag. 0.40E+00    7.1     0.00000313     -4911.5361266920  9.30E-07
    60 Broy./Diag. 0.40E+00    7.3     0.00000235     -4911.5361261503  5.42E-07
    61 Broy./Diag. 0.40E+00    7.1     0.00000285     -4911.5361356202 -9.47E-06
    62 Broy./Diag. 0.40E+00    6.8     0.00000231     -4911.5361272319  8.39E-06
    63 Broy./Diag. 0.40E+00    6.9     0.00000152     -4911.5361215745  5.66E-06
    64 Broy./Diag. 0.40E+00    7.1     0.00000134     -4911.5361305908 -9.02E-06
    65 Broy./Diag. 0.40E+00    7.0     0.00000208     -4911.5361302250  3.66E-07
    66 Broy./Diag. 0.40E+00    7.1     0.00000130     -4911.5361298411  3.84E-07
    67 Broy./Diag. 0.40E+00    6.9     0.00000154     -4911.5361248227  5.02E-06
    68 Broy./Diag. 0.40E+00    7.3     0.00000095     -4911.5361296535 -4.83E-06

  *** SCF run converged in    68 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008303421105
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.92210357140675
  Hartree energy:                                            1781.37809703388189
  Exchange-correlation energy:                               -779.50767371759412
  Electronic entropic energy:                                  -0.23831707564151
  Fermi energy:                                                 0.08739244895998

  Total energy:                                             -4911.53612965352477

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.536128371190898

 MD| ***************************************************************************
 MD| Step number                                                            1156
 MD| Time [fs]                                                       2312.000000
 MD| Conserved quantity [hartree]                            -0.491118104805E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    496.149981           595.666081
 MD| Energy drift per atom [K]           0.287609634879E+03   0.270777505089E+03
 MD| Potential energy [hartree]         -0.491153612837E+04  -0.491156413272E+04
 MD| Kinetic energy [hartree]            0.355080322977E+00   0.374977252471E+00
 MD| Temperature [K]                             946.205603           999.226244
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.02448127     -4911.5317050043 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.9     0.07462661     -4911.6429382272 -1.11E-01
     3 Broy./Diag. 0.40E+00    6.9     0.07147780     -4911.1533897446  4.90E-01
     4 Broy./Diag. 0.40E+00    7.1     0.03899699     -4911.6872092137 -5.34E-01
     5 Broy./Diag. 0.40E+00    6.9     0.01913944     -4911.5021439947  1.85E-01
     6 Broy./Diag. 0.40E+00    7.1     0.00708709     -4911.5284382280 -2.63E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00369344     -4911.5541504969 -2.57E-02
     8 Broy./Diag. 0.40E+00    7.4     0.00219558     -4911.5214463282  3.27E-02
     9 Broy./Diag. 0.40E+00    6.9     0.00128193     -4911.5314300457 -9.98E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00149466     -4911.5327209229 -1.29E-03
    11 Broy./Diag. 0.40E+00    6.5     0.00114812     -4911.5392457607 -6.52E-03
    12 Broy./Diag. 0.40E+00    7.0     0.00058256     -4911.5332428085  6.00E-03
    13 Broy./Diag. 0.40E+00    7.0     0.00032620     -4911.5324170875  8.26E-04
    14 Broy./Diag. 0.40E+00    7.3     0.00021551     -4911.5347571988 -2.34E-03
    15 Broy./Diag. 0.40E+00    7.6     0.00019223     -4911.5335510709  1.21E-03
    16 Broy./Diag. 0.40E+00    7.1     0.00026237     -4911.5336677139 -1.17E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00032765     -4911.5328723935  7.95E-04
    18 Broy./Diag. 0.40E+00    7.5     0.00022872     -4911.5346916799 -1.82E-03
    19 Broy./Diag. 0.40E+00    7.3     0.00017489     -4911.5343643943  3.27E-04
    20 Broy./Diag. 0.40E+00    7.1     0.00010670     -4911.5333440553  1.02E-03
    21 Broy./Diag. 0.40E+00    7.0     0.00010061     -4911.5340276113 -6.84E-04
    22 Broy./Diag. 0.40E+00    7.5     0.00007012     -4911.5339738975  5.37E-05
    23 Broy./Diag. 0.40E+00    7.3     0.00010494     -4911.5341677491 -1.94E-04
    24 Broy./Diag. 0.40E+00    7.3     0.00008430     -4911.5336203351  5.47E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00007215     -4911.5338550918 -2.35E-04
    26 Broy./Diag. 0.40E+00    7.0     0.00005318     -4911.5341976394 -3.43E-04
    27 Broy./Diag. 0.40E+00    7.5     0.00006380     -4911.5338792324  3.18E-04
    28 Broy./Diag. 0.40E+00    7.6     0.00004772     -4911.5339486292 -6.94E-05
    29 Broy./Diag. 0.40E+00    6.9     0.00006573     -4911.5338542547  9.44E-05
    30 Broy./Diag. 0.40E+00    7.6     0.00005402     -4911.5341938184 -3.40E-04
    31 Broy./Diag. 0.40E+00    6.8     0.00004000     -4911.5340325726  1.61E-04
    32 Broy./Diag. 0.40E+00    7.1     0.00002176     -4911.5338799716  1.53E-04
    33 Broy./Diag. 0.40E+00    7.3     0.00002799     -4911.5340384280 -1.58E-04
    34 Broy./Diag. 0.40E+00    7.9     0.00002067     -4911.5339989643  3.95E-05
    35 Broy./Diag. 0.40E+00    7.1     0.00003040     -4911.5340467153 -4.78E-05
    36 Broy./Diag. 0.40E+00    6.9     0.00003399     -4911.5339079213  1.39E-04
    37 Broy./Diag. 0.40E+00    7.3     0.00002416     -4911.5340163224 -1.08E-04
    38 Broy./Diag. 0.40E+00    7.3     0.00001377     -4911.5340775023 -6.12E-05
    39 Broy./Diag. 0.40E+00    7.0     0.00001353     -4911.5339936555  8.38E-05
    40 Broy./Diag. 0.40E+00    7.1     0.00001123     -4911.5340311274 -3.75E-05
    41 Broy./Diag. 0.40E+00    7.2     0.00001136     -4911.5340029291  2.82E-05
    42 Broy./Diag. 0.40E+00    7.6     0.00001320     -4911.5340535769 -5.06E-05
    43 Broy./Diag. 0.40E+00    7.3     0.00001073     -4911.5340153651  3.82E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00000760     -4911.5340032577  1.21E-05
    45 Broy./Diag. 0.40E+00    7.5     0.00000721     -4911.5340430193 -3.98E-05
    46 Broy./Diag. 0.40E+00    7.1     0.00000747     -4911.5340202933  2.27E-05
    47 Broy./Diag. 0.40E+00    7.3     0.00000811     -4911.5340445745 -2.43E-05
    48 Broy./Diag. 0.40E+00    7.3     0.00000844     -4911.5340143208  3.03E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00000589     -4911.5340393475 -2.50E-05
    50 Broy./Diag. 0.40E+00    7.1     0.00000404     -4911.5340400975 -7.50E-07
    51 Broy./Diag. 0.40E+00    7.1     0.00000338     -4911.5340254025  1.47E-05
    52 Broy./Diag. 0.40E+00    7.1     0.00000373     -4911.5340405100 -1.51E-05
    53 Broy./Diag. 0.40E+00    7.5     0.00000433     -4911.5340256459  1.49E-05
    54 Broy./Diag. 0.40E+00    7.3     0.00000438     -4911.5340421061 -1.65E-05
    55 Broy./Diag. 0.40E+00    7.1     0.00000386     -4911.5340319531  1.02E-05
    56 Broy./Diag. 0.40E+00    6.9     0.00000273     -4911.5340343554 -2.40E-06
    57 Broy./Diag. 0.40E+00    6.9     0.00000231     -4911.5340414191 -7.06E-06
    58 Broy./Diag. 0.40E+00    6.8     0.00000183     -4911.5340328384  8.58E-06
    59 Broy./Diag. 0.40E+00    7.6     0.00000227     -4911.5340425495 -9.71E-06
    60 Broy./Diag. 0.40E+00    7.3     0.00000209     -4911.5340343010  8.25E-06
    61 Broy./Diag. 0.40E+00    7.1     0.00000179     -4911.5340393507 -5.05E-06
    62 Broy./Diag. 0.40E+00    7.1     0.00000140     -4911.5340382260  1.12E-06
    63 Broy./Diag. 0.40E+00    7.7     0.00000135     -4911.5340370924  1.13E-06
    64 Broy./Diag. 0.40E+00    6.9     0.00000119     -4911.5340420491 -4.96E-06
    65 Broy./Diag. 0.40E+00    7.1     0.00000147     -4911.5340356920  6.36E-06
    66 Broy./Diag. 0.40E+00    6.8     0.00000131     -4911.5340417295 -6.04E-06
    67 Broy./Diag. 0.40E+00    6.9     0.00000112     -4911.5340392990  2.43E-06
    68 Broy./Diag. 0.40E+00    6.7     0.00000075     -4911.5340402492 -9.50E-07

  *** SCF run converged in    68 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008326392725
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.92942439371109
  Hartree energy:                                            1781.37444760490826
  Exchange-correlation energy:                               -779.50926850805843
  Electronic entropic energy:                                  -0.23830449280794
  Fermi energy:                                                 0.08741575599025

  Total energy:                                             -4911.53404024916927

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.534041396513203

 MD| ***************************************************************************
 MD| Step number                                                            1157
 MD| Time [fs]                                                       2314.000000
 MD| Conserved quantity [hartree]                            -0.491119439447E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    496.056902           595.579988
 MD| Energy drift per atom [K]           0.259882915763E+03   0.270768088850E+03
 MD| Potential energy [hartree]         -0.491153404140E+04  -0.491156410671E+04
 MD| Kinetic energy [hartree]            0.339646927573E+00   0.374946716322E+00
 MD| Temperature [K]                             905.079232           999.144872
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.01866083     -4911.5300998339 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.9     0.05461855     -4911.6246078670 -9.45E-02
     3 Broy./Diag. 0.40E+00    6.9     0.06597680     -4911.1976860393  4.27E-01
     4 Broy./Diag. 0.40E+00    6.9     0.03584355     -4911.6716862114 -4.74E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01648765     -4911.5080674501  1.64E-01
     6 Broy./Diag. 0.40E+00    7.3     0.00570056     -4911.5223722975 -1.43E-02
     7 Broy./Diag. 0.40E+00    6.8     0.00327484     -4911.5515784798 -2.92E-02
     8 Broy./Diag. 0.40E+00    7.0     0.00199548     -4911.5178819232  3.37E-02
     9 Broy./Diag. 0.40E+00    6.9     0.00115995     -4911.5306057067 -1.27E-02
    10 Broy./Diag. 0.40E+00    7.0     0.00150253     -4911.5289585577  1.65E-03
    11 Broy./Diag. 0.40E+00    7.1     0.00106045     -4911.5363900200 -7.43E-03
    12 Broy./Diag. 0.40E+00    7.1     0.00049964     -4911.5313136709  5.08E-03
    13 Broy./Diag. 0.40E+00    7.1     0.00027034     -4911.5300444784  1.27E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00021683     -4911.5325299260 -2.49E-03
    15 Broy./Diag. 0.40E+00    7.4     0.00020040     -4911.5310223760  1.51E-03
    16 Broy./Diag. 0.40E+00    7.3     0.00029061     -4911.5317317882 -7.09E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00032234     -4911.5306499593  1.08E-03
    18 Broy./Diag. 0.40E+00    7.1     0.00021054     -4911.5324074084 -1.76E-03
    19 Broy./Diag. 0.40E+00    7.1     0.00015292     -4911.5324290493 -2.16E-05
    20 Broy./Diag. 0.40E+00    7.3     0.00010535     -4911.5312139859  1.22E-03
    21 Broy./Diag. 0.40E+00    8.0     0.00010336     -4911.5320577434 -8.44E-04
    22 Broy./Diag. 0.40E+00    6.9     0.00009160     -4911.5318180098  2.40E-04
    23 Broy./Diag. 0.40E+00   10.3     0.00011036     -4911.5322104965 -3.92E-04
    24 Broy./Diag. 0.40E+00    6.9     0.00007816     -4911.5316459565  5.65E-04
    25 Broy./Diag. 0.40E+00   10.3     0.00006451     -4911.5317932953 -1.47E-04
    26 Broy./Diag. 0.40E+00    7.9     0.00005766     -4911.5322622438 -4.69E-04
    27 Broy./Diag. 0.40E+00    6.8     0.00006795     -4911.5318772579  3.85E-04
    28 Broy./Diag. 0.40E+00    6.9     0.00006211     -4911.5320594984 -1.82E-04
    29 Broy./Diag. 0.40E+00    6.9     0.00007199     -4911.5318356688  2.24E-04
    30 Broy./Diag. 0.40E+00    7.1     0.00004979     -4911.5322291809 -3.94E-04
    31 Broy./Diag. 0.40E+00    7.1     0.00003482     -4911.5321367824  9.24E-05
    32 Broy./Diag. 0.40E+00    8.0     0.00002380     -4911.5319108775  2.26E-04
    33 Broy./Diag. 0.40E+00    7.3     0.00003056     -4911.5321096793 -1.99E-04
    34 Broy./Diag. 0.40E+00    9.8     0.00002858     -4911.5320369514  7.27E-05
    35 Broy./Diag. 0.40E+00    7.0     0.00003563     -4911.5321619177 -1.25E-04
    36 Broy./Diag. 0.40E+00    8.4     0.00003187     -4911.5319769070  1.85E-04
    37 Broy./Diag. 0.40E+00    9.1     0.00002137     -4911.5320505764 -7.37E-05
    38 Broy./Diag. 0.40E+00    7.5     0.00001513     -4911.5321837787 -1.33E-04
    39 Broy./Diag. 0.40E+00    7.1     0.00001538     -4911.5320722315  1.12E-04
    40 Broy./Diag. 0.40E+00    7.4     0.00001438     -4911.5321198685 -4.76E-05
    41 Broy./Diag. 0.40E+00    8.0     0.00001447     -4911.5320670634  5.28E-05
    42 Broy./Diag. 0.40E+00    8.5     0.00001313     -4911.5321525656 -8.55E-05
    43 Broy./Diag. 0.40E+00    8.9     0.00000990     -4911.5321213755  3.12E-05
    44 Broy./Diag. 0.40E+00    8.0     0.00000739     -4911.5320745542  4.68E-05
    45 Broy./Diag. 0.40E+00   10.6     0.00000834     -4911.5321372331 -6.27E-05
    46 Broy./Diag. 0.40E+00    8.1     0.00000934     -4911.5321170183  2.02E-05
    47 Broy./Diag. 0.40E+00    7.3     0.00001013     -4911.5321529987 -3.60E-05
    48 Broy./Diag. 0.40E+00    7.1     0.00000860     -4911.5320981808  5.48E-05
    49 Broy./Diag. 0.40E+00    7.3     0.00000519     -4911.5321245462 -2.64E-05
    50 Broy./Diag. 0.40E+00    6.9     0.00000398     -4911.5321502422 -2.57E-05
    51 Broy./Diag. 0.40E+00    7.5     0.00000321     -4911.5321206404  2.96E-05
    52 Broy./Diag. 0.40E+00    7.2     0.00000445     -4911.5321352074 -1.46E-05
    53 Broy./Diag. 0.40E+00    7.1     0.00000540     -4911.5321201612  1.50E-05
    54 Broy./Diag. 0.40E+00    7.8     0.00000462     -4911.5321514643 -3.13E-05
    55 Broy./Diag. 0.40E+00    6.9     0.00000331     -4911.5321363564  1.51E-05
    56 Broy./Diag. 0.40E+00    7.7     0.00000268     -4911.5321229337  1.34E-05
    57 Broy./Diag. 0.40E+00    7.3     0.00000199     -4911.5321439753 -2.10E-05
    58 Broy./Diag. 0.40E+00    7.3     0.00000218     -4911.5321366612  7.31E-06
    59 Broy./Diag. 0.40E+00    7.3     0.00000279     -4911.5321449412 -8.28E-06
    60 Broy./Diag. 0.40E+00    7.3     0.00000227     -4911.5321302099  1.47E-05
    61 Broy./Diag. 0.40E+00    7.7     0.00000146     -4911.5321402034 -9.99E-06
    62 Broy./Diag. 0.40E+00    7.1     0.00000140     -4911.5321456837 -5.48E-06
    63 Broy./Diag. 0.40E+00    6.9     0.00000112     -4911.5321365336  9.15E-06
    64 Broy./Diag. 0.40E+00    7.3     0.00000128     -4911.5321420159 -5.48E-06
    65 Broy./Diag. 0.40E+00    7.1     0.00000173     -4911.5321383270  3.69E-06
    66 Broy./Diag. 0.40E+00    6.7     0.00000146     -4911.5321477861 -9.46E-06
    67 Broy./Diag. 0.40E+00    6.9     0.00000096     -4911.5321414751  6.31E-06

  *** SCF run converged in    67 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008353411993
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.92557207235041
  Hartree energy:                                            1781.37798518638738
  Exchange-correlation energy:                               -779.50707541743998
  Electronic entropic energy:                                  -0.23828431798933
  Fermi energy:                                                 0.08741997142945

  Total energy:                                             -4911.53214147506878

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.532144929240530

 MD| ***************************************************************************
 MD| Step number                                                            1158
 MD| Time [fs]                                                       2316.000000
 MD| Conserved quantity [hartree]                            -0.491119437372E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    510.414423           595.506443
 MD| Energy drift per atom [K]           0.259926018076E+03   0.270758726094E+03
 MD| Potential energy [hartree]         -0.491153214493E+04  -0.491156407911E+04
 MD| Kinetic energy [hartree]            0.337771207855E+00   0.374914613119E+00
 MD| Temperature [K]                             900.080880           999.059324
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.01584724     -4911.5298114857 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.8     0.02471667     -4911.5433262625 -1.35E-02
     3 Broy./Diag. 0.40E+00    7.3     0.04044979     -4911.4360115453  1.07E-01
     4 Broy./Diag. 0.40E+00    7.0     0.03093206     -4911.6479496723 -2.12E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01424555     -4911.4878228966  1.60E-01
     6 Broy./Diag. 0.40E+00    6.9     0.00652824     -4911.5418525007 -5.40E-02
     7 Broy./Diag. 0.40E+00    7.0     0.00349167     -4911.5499356025 -8.08E-03
     8 Broy./Diag. 0.40E+00    7.3     0.00139272     -4911.5140719133  3.59E-02
     9 Broy./Diag. 0.40E+00    7.3     0.00079491     -4911.5316250522 -1.76E-02
    10 Broy./Diag. 0.40E+00    7.1     0.00102860     -4911.5290317766  2.59E-03
    11 Broy./Diag. 0.40E+00    7.3     0.00075538     -4911.5333911849 -4.36E-03
    12 Broy./Diag. 0.40E+00    6.7     0.00047927     -4911.5296096958  3.78E-03
    13 Broy./Diag. 0.40E+00    7.1     0.00025910     -4911.5305188735 -9.09E-04
    14 Broy./Diag. 0.40E+00    7.5     0.00020615     -4911.5315812482 -1.06E-03
    15 Broy./Diag. 0.40E+00    6.8     0.00013518     -4911.5297233376  1.86E-03
    16 Broy./Diag. 0.40E+00    7.3     0.00020994     -4911.5314842992 -1.76E-03
    17 Broy./Diag. 0.40E+00    7.8     0.00025436     -4911.5308796525  6.05E-04
    18 Broy./Diag. 0.40E+00    6.9     0.00018546     -4911.5320972402 -1.22E-03
    19 Broy./Diag. 0.40E+00    7.2     0.00013672     -4911.5314634487  6.34E-04
    20 Broy./Diag. 0.40E+00    7.5     0.00007691     -4911.5310309342  4.33E-04
    21 Broy./Diag. 0.40E+00    6.9     0.00005884     -4911.5318705472 -8.40E-04
    22 Broy./Diag. 0.40E+00    7.1     0.00007364     -4911.5312262599  6.44E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00008712     -4911.5316777863 -4.52E-04
    24 Broy./Diag. 0.40E+00    7.1     0.00006441     -4911.5313623263  3.15E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00005634     -4911.5316608825 -2.99E-04
    26 Broy./Diag. 0.40E+00    6.8     0.00003676     -4911.5317865620 -1.26E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00002320     -4911.5315363241  2.50E-04
    28 Broy./Diag. 0.40E+00    6.9     0.00003143     -4911.5317969144 -2.61E-04
    29 Broy./Diag. 0.40E+00    6.9     0.00004118     -4911.5316192932  1.78E-04
    30 Broy./Diag. 0.40E+00    6.8     0.00003145     -4911.5317927396 -1.73E-04
    31 Broy./Diag. 0.40E+00    7.2     0.00002840     -4911.5316758153  1.17E-04
    32 Broy./Diag. 0.40E+00    6.9     0.00002299     -4911.5316591557  1.67E-05
    33 Broy./Diag. 0.40E+00    6.9     0.00001324     -4911.5317942336 -1.35E-04
    34 Broy./Diag. 0.40E+00    7.1     0.00001660     -4911.5316717261  1.23E-04
    35 Broy./Diag. 0.40E+00    7.3     0.00002389     -4911.5317992599 -1.28E-04
    36 Broy./Diag. 0.40E+00    7.3     0.00001983     -4911.5317054950  9.38E-05
    37 Broy./Diag. 0.40E+00    7.1     0.00001464     -4911.5317820244 -7.65E-05
    38 Broy./Diag. 0.40E+00    7.1     0.00001496     -4911.5317909555 -8.93E-06
    39 Broy./Diag. 0.40E+00    6.9     0.00000705     -4911.5317158400  7.51E-05
    40 Broy./Diag. 0.40E+00    6.9     0.00000883     -4911.5317981151 -8.23E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00001372     -4911.5317327507  6.54E-05
    42 Broy./Diag. 0.40E+00    7.0     0.00001161     -4911.5317977651 -6.50E-05
    43 Broy./Diag. 0.40E+00    7.5     0.00000790     -4911.5317626810  3.51E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00000869     -4911.5317739547 -1.13E-05
    45 Broy./Diag. 0.40E+00    7.0     0.00000371     -4911.5318066555 -3.27E-05
    46 Broy./Diag. 0.40E+00    6.9     0.00000348     -4911.5317685880  3.81E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00000592     -4911.5318036555 -3.51E-05
    48 Broy./Diag. 0.40E+00    6.9     0.00000567     -4911.5317789994  2.47E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00000392     -4911.5317981837 -1.92E-05
    50 Broy./Diag. 0.40E+00    6.9     0.00000535     -4911.5317935871  4.60E-06
    51 Broy./Diag. 0.40E+00    7.1     0.00000253     -4911.5317827671  1.08E-05
    52 Broy./Diag. 0.40E+00    6.9     0.00000228     -4911.5318072809 -2.45E-05
    53 Broy./Diag. 0.40E+00    7.7     0.00000382     -4911.5317849319  2.23E-05
    54 Broy./Diag. 0.40E+00    7.5     0.00000331     -4911.5318042060 -1.93E-05
    55 Broy./Diag. 0.40E+00    7.1     0.00000215     -4911.5317953755  8.83E-06
    56 Broy./Diag. 0.40E+00    6.7     0.00000282     -4911.5317993611 -3.99E-06
    57 Broy./Diag. 0.40E+00    7.1     0.00000156     -4911.5318044296 -5.07E-06
    58 Broy./Diag. 0.40E+00    7.3     0.00000124     -4911.5317921071  1.23E-05
    59 Broy./Diag. 0.40E+00    7.3     0.00000207     -4911.5318065511 -1.44E-05
    60 Broy./Diag. 0.40E+00    7.4     0.00000208     -4911.5317970201  9.53E-06
    61 Broy./Diag. 0.40E+00    8.1     0.00000150     -4911.5318037774 -6.76E-06
    62 Broy./Diag. 0.40E+00    7.3     0.00000193     -4911.5318015045  2.27E-06
    63 Broy./Diag. 0.40E+00    6.9     0.00000103     -4911.5318004758  1.03E-06
    64 Broy./Diag. 0.40E+00    6.9     0.00000073     -4911.5318069096 -6.43E-06

  *** SCF run converged in    64 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008374560528
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.90506346786742
  Hartree energy:                                            1781.39161102371236
  Exchange-correlation energy:                               -779.49990996142037
  Electronic entropic energy:                                  -0.23823263629371
  Fermi energy:                                                 0.08739802843833

  Total energy:                                             -4911.53180690956015

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.531806607673388

 MD| ***************************************************************************
 MD| Step number                                                            1159
 MD| Time [fs]                                                       2318.000000
 MD| Conserved quantity [hartree]                            -0.491118209925E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    465.019153           595.393857
 MD| Energy drift per atom [K]           0.285425793352E+03   0.270771381027E+03
 MD| Potential energy [hartree]         -0.491153180661E+04  -0.491156405127E+04
 MD| Kinetic energy [hartree]            0.349707354386E+00   0.374892863975E+00
 MD| Temperature [K]                             931.887905           999.001368
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.01359896     -4911.5327067265 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.7     0.01938825     -4911.4896567207  4.31E-02
     3 Broy./Diag. 0.40E+00    7.2     0.02383647     -4911.5710021086 -8.13E-02
     4 Broy./Diag. 0.40E+00    6.9     0.01709944     -4911.5164225155  5.46E-02
     5 Broy./Diag. 0.40E+00    7.6     0.00881282     -4911.5045099886  1.19E-02
     6 Broy./Diag. 0.40E+00    6.7     0.00716452     -4911.5830714793 -7.86E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00433255     -4911.5263876413  5.67E-02
     8 Broy./Diag. 0.40E+00    6.9     0.00229500     -4911.5293199039 -2.93E-03
     9 Broy./Diag. 0.40E+00    7.1     0.00072462     -4911.5349005482 -5.58E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00067395     -4911.5325074000  2.39E-03
    11 Broy./Diag. 0.40E+00    7.3     0.00054189     -4911.5330438464 -5.36E-04
    12 Broy./Diag. 0.40E+00    6.8     0.00044972     -4911.5316590181  1.38E-03
    13 Broy./Diag. 0.40E+00    6.6     0.00032977     -4911.5352555063 -3.60E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00032901     -4911.5334400705  1.82E-03
    15 Broy./Diag. 0.40E+00    7.1     0.00020230     -4911.5327046285  7.35E-04
    16 Broy./Diag. 0.40E+00    7.1     0.00018388     -4911.5341788770 -1.47E-03
    17 Broy./Diag. 0.40E+00    7.2     0.00023569     -4911.5340789281  9.99E-05
    18 Broy./Diag. 0.40E+00    7.1     0.00022697     -4911.5345424152 -4.63E-04
    19 Broy./Diag. 0.40E+00    6.9     0.00018350     -4911.5330951765  1.45E-03
    20 Broy./Diag. 0.40E+00    7.2     0.00011241     -4911.5344439493 -1.35E-03
    21 Broy./Diag. 0.40E+00    8.1     0.00007937     -4911.5345970790 -1.53E-04
    22 Broy./Diag. 0.40E+00    7.6     0.00007843     -4911.5341373378  4.60E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00008985     -4911.5343352028 -1.98E-04
    24 Broy./Diag. 0.40E+00    7.1     0.00006459     -4911.5342699796  6.52E-05
    25 Broy./Diag. 0.40E+00    7.1     0.00009265     -4911.5347261498 -4.56E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00007734     -4911.5340779969  6.48E-04
    27 Broy./Diag. 0.40E+00    7.0     0.00004655     -4911.5343479844 -2.70E-04
    28 Broy./Diag. 0.40E+00    6.9     0.00005029     -4911.5346130771 -2.65E-04
    29 Broy./Diag. 0.40E+00    7.3     0.00005726     -4911.5345218784  9.12E-05
    30 Broy./Diag. 0.40E+00    7.1     0.00003136     -4911.5346174702 -9.56E-05
    31 Broy./Diag. 0.40E+00    7.1     0.00002962     -4911.5344511690  1.66E-04
    32 Broy./Diag. 0.40E+00    7.1     0.00002312     -4911.5346528292 -2.02E-04
    33 Broy./Diag. 0.40E+00    6.9     0.00001755     -4911.5345942337  5.86E-05
    34 Broy./Diag. 0.40E+00    7.7     0.00001976     -4911.5345241686  7.01E-05
    35 Broy./Diag. 0.40E+00    6.9     0.00002987     -4911.5346141118 -8.99E-05
    36 Broy./Diag. 0.40E+00    6.5     0.00002409     -4911.5345729204  4.12E-05
    37 Broy./Diag. 0.40E+00    7.7     0.00002158     -4911.5346862019 -1.13E-04
    38 Broy./Diag. 0.40E+00    7.1     0.00001962     -4911.5345790603  1.07E-04
    39 Broy./Diag. 0.40E+00    7.7     0.00000954     -4911.5346291012 -5.00E-05
    40 Broy./Diag. 0.40E+00    7.1     0.00000867     -4911.5346612036 -3.21E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00001125     -4911.5346362019  2.50E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00000987     -4911.5346672909 -3.11E-05
    43 Broy./Diag. 0.40E+00    7.6     0.00000755     -4911.5346269062  4.04E-05
    44 Broy./Diag. 0.40E+00    7.3     0.00000987     -4911.5346707811 -4.39E-05
    45 Broy./Diag. 0.40E+00    7.8     0.00000730     -4911.5346522169  1.86E-05
    46 Broy./Diag. 0.40E+00    7.1     0.00000581     -4911.5346560509 -3.83E-06
    47 Broy./Diag. 0.40E+00    7.5     0.00000775     -4911.5346733441 -1.73E-05
    48 Broy./Diag. 0.40E+00    7.3     0.00000663     -4911.5346512056  2.21E-05
    49 Broy./Diag. 0.40E+00    7.3     0.00000383     -4911.5346803251 -2.91E-05
    50 Broy./Diag. 0.40E+00    6.9     0.00000371     -4911.5346682571  1.21E-05
    51 Broy./Diag. 0.40E+00    7.1     0.00000273     -4911.5346747479 -6.49E-06
    52 Broy./Diag. 0.40E+00    6.8     0.00000236     -4911.5346728489  1.90E-06
    53 Broy./Diag. 0.40E+00    7.3     0.00000315     -4911.5346714418  1.41E-06
    54 Broy./Diag. 0.40E+00    7.5     0.00000364     -4911.5346862550 -1.48E-05
    55 Broy./Diag. 0.40E+00    6.9     0.00000284     -4911.5346713117  1.49E-05
    56 Broy./Diag. 0.40E+00    7.1     0.00000270     -4911.5346790323 -7.72E-06
    57 Broy./Diag. 0.40E+00    7.3     0.00000217     -4911.5346786203  4.12E-07
    58 Broy./Diag. 0.40E+00    7.1     0.00000135     -4911.5346830826 -4.46E-06
    59 Broy./Diag. 0.40E+00    7.1     0.00000150     -4911.5346842359 -1.15E-06
    60 Broy./Diag. 0.40E+00    7.2     0.00000144     -4911.5346774038  6.83E-06
    61 Broy./Diag. 0.40E+00    6.9     0.00000114     -4911.5346850839 -7.68E-06
    62 Broy./Diag. 0.40E+00    7.1     0.00000116     -4911.5346832391  1.84E-06
    63 Broy./Diag. 0.40E+00    7.5     0.00000121     -4911.5346845937 -1.35E-06
    64 Broy./Diag. 0.40E+00    7.5     0.00000096     -4911.5346817488  2.84E-06

  *** SCF run converged in    64 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008369414428
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.86760150339433
  Hartree energy:                                            1781.41441374974943
  Exchange-correlation energy:                               -779.48813998726405
  Electronic entropic energy:                                  -0.23821819434845
  Fermi energy:                                                 0.08734915204970

  Total energy:                                             -4911.53468174883892

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.534688258831920

 MD| ***************************************************************************
 MD| Step number                                                            1160
 MD| Time [fs]                                                       2320.000000
 MD| Conserved quantity [hartree]                            -0.491119294623E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    467.213170           595.283356
 MD| Energy drift per atom [K]           0.262891589542E+03   0.270764588104E+03
 MD| Potential energy [hartree]         -0.491153468826E+04  -0.491156402595E+04
 MD| Kinetic energy [hartree]            0.341742032863E+00   0.374864285672E+00
 MD| Temperature [K]                             910.662195           998.925214
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.8     0.01639748     -4911.5388756314 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.9     0.05221668     -4911.4445038101  9.44E-02
     3 Broy./Diag. 0.40E+00    7.0     0.05896098     -4911.7324581212 -2.88E-01
     4 Broy./Diag. 0.40E+00    7.1     0.02702920     -4911.4178036344  3.15E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01493389     -4911.5235100267 -1.06E-01
     6 Broy./Diag. 0.40E+00    6.8     0.00785744     -4911.5523615172 -2.89E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00340487     -4911.5488631411  3.50E-03
     8 Broy./Diag. 0.40E+00    7.1     0.00274576     -4911.5236339372  2.52E-02
     9 Broy./Diag. 0.40E+00    7.1     0.00137036     -4911.5394278507 -1.58E-02
    10 Broy./Diag. 0.40E+00    7.1     0.00085185     -4911.5410367689 -1.61E-03
    11 Broy./Diag. 0.40E+00    7.0     0.00097214     -4911.5361428747  4.89E-03
    12 Broy./Diag. 0.40E+00    6.9     0.00062959     -4911.5387123633 -2.57E-03
    13 Broy./Diag. 0.40E+00    7.3     0.00026120     -4911.5395937530 -8.81E-04
    14 Broy./Diag. 0.40E+00    7.1     0.00034881     -4911.5397803800 -1.87E-04
    15 Broy./Diag. 0.40E+00    8.1     0.00044109     -4911.5378218992  1.96E-03
    16 Broy./Diag. 0.40E+00    7.1     0.00031584     -4911.5395097589 -1.69E-03
    17 Broy./Diag. 0.40E+00    6.9     0.00031007     -4911.5409800368 -1.47E-03
    18 Broy./Diag. 0.40E+00    6.9     0.00030678     -4911.5399448658  1.04E-03
    19 Broy./Diag. 0.40E+00    7.5     0.00018699     -4911.5399916684 -4.68E-05
    20 Broy./Diag. 0.40E+00    6.9     0.00007988     -4911.5400439209 -5.23E-05
    21 Broy./Diag. 0.40E+00    7.1     0.00013969     -4911.5406961424 -6.52E-04
    22 Broy./Diag. 0.40E+00    6.7     0.00013971     -4911.5402822074  4.14E-04
    23 Broy./Diag. 0.40E+00    7.9     0.00012288     -4911.5400603743  2.22E-04
    24 Broy./Diag. 0.40E+00    7.3     0.00010152     -4911.5405717408 -5.11E-04
    25 Broy./Diag. 0.40E+00    7.3     0.00008825     -4911.5406097248 -3.80E-05
    26 Broy./Diag. 0.40E+00    7.3     0.00005414     -4911.5405393403  7.04E-05
    27 Broy./Diag. 0.40E+00    6.9     0.00006973     -4911.5404745315  6.48E-05
    28 Broy./Diag. 0.40E+00    6.9     0.00008040     -4911.5407062728 -2.32E-04
    29 Broy./Diag. 0.40E+00    7.3     0.00005689     -4911.5407906379 -8.44E-05
    30 Broy./Diag. 0.40E+00    6.9     0.00004255     -4911.5405989522  1.92E-04
    31 Broy./Diag. 0.40E+00    7.3     0.00002766     -4911.5407001979 -1.01E-04
    32 Broy./Diag. 0.40E+00    6.9     0.00002110     -4911.5407301092 -2.99E-05
    33 Broy./Diag. 0.40E+00    6.9     0.00002748     -4911.5407523010 -2.22E-05
    34 Broy./Diag. 0.40E+00    7.1     0.00004358     -4911.5407075290  4.48E-05
    35 Broy./Diag. 0.40E+00    7.1     0.00003431     -4911.5407543636 -4.68E-05
    36 Broy./Diag. 0.40E+00    6.9     0.00003454     -4911.5408733983 -1.19E-04
    37 Broy./Diag. 0.40E+00    7.1     0.00001997     -4911.5407744135  9.90E-05
    38 Broy./Diag. 0.40E+00    6.9     0.00001607     -4911.5408027594 -2.83E-05
    39 Broy./Diag. 0.40E+00    7.1     0.00001123     -4911.5408052362 -2.48E-06
    40 Broy./Diag. 0.40E+00    7.5     0.00001755     -4911.5408440763 -3.88E-05
    41 Broy./Diag. 0.40E+00    6.9     0.00001266     -4911.5408303026  1.38E-05
    42 Broy./Diag. 0.40E+00    7.3     0.00001719     -4911.5408091294  2.12E-05
    43 Broy./Diag. 0.40E+00    7.3     0.00001069     -4911.5408648478 -5.57E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00000956     -4911.5408686200 -3.77E-06
    45 Broy./Diag. 0.40E+00    7.1     0.00000870     -4911.5408564094  1.22E-05
    46 Broy./Diag. 0.40E+00    7.3     0.00001183     -4911.5408466753  9.73E-06
    47 Broy./Diag. 0.40E+00    6.9     0.00000733     -4911.5408702413 -2.36E-05
    48 Broy./Diag. 0.40E+00    7.3     0.00000788     -4911.5408874639 -1.72E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00000489     -4911.5408608368  2.66E-05
    50 Broy./Diag. 0.40E+00    7.3     0.00000387     -4911.5408706348 -9.80E-06
    51 Broy./Diag. 0.40E+00    7.7     0.00000319     -4911.5408811164 -1.05E-05
    52 Broy./Diag. 0.40E+00    7.2     0.00000605     -4911.5408866009 -5.48E-06
    53 Broy./Diag. 0.40E+00    7.1     0.00000534     -4911.5408764261  1.02E-05
    54 Broy./Diag. 0.40E+00    7.2     0.00000535     -4911.5408734823  2.94E-06
    55 Broy./Diag. 0.40E+00    6.6     0.00000395     -4911.5408975646 -2.41E-05
    56 Broy./Diag. 0.40E+00    7.6     0.00000276     -4911.5408898596  7.71E-06
    57 Broy./Diag. 0.40E+00    7.7     0.00000196     -4911.5408868119  3.05E-06
    58 Broy./Diag. 0.40E+00    7.3     0.00000267     -4911.5408862150  5.97E-07
    59 Broy./Diag. 0.40E+00    6.8     0.00000231     -4911.5408937507 -7.54E-06
    60 Broy./Diag. 0.40E+00    6.9     0.00000216     -4911.5408958766 -2.13E-06
    61 Broy./Diag. 0.40E+00    7.1     0.00000215     -4911.5408887139  7.16E-06
    62 Broy./Diag. 0.40E+00    7.0     0.00000181     -4911.5408931605 -4.45E-06
    63 Broy./Diag. 0.40E+00    6.9     0.00000117     -4911.5408982482 -5.09E-06
    64 Broy./Diag. 0.40E+00    7.1     0.00000199     -4911.5408982558 -7.56E-09
    65 Broy./Diag. 0.40E+00    6.7     0.00000182     -4911.5408942601  4.00E-06
    66 Broy./Diag. 0.40E+00    7.3     0.00000121     -4911.5408942930 -3.30E-08
    67 Broy./Diag. 0.40E+00    7.1     0.00000093     -4911.5408999047 -5.61E-06

  *** SCF run converged in    67 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008333887684
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.81513035516355
  Hartree energy:                                            1781.44489560640000
  Exchange-correlation energy:                               -779.47235637226538
  Electronic entropic energy:                                  -0.23823030879735
  Fermi energy:                                                 0.08727867148845

  Total energy:                                             -4911.54089990474131

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.540902429145717

 MD| ***************************************************************************
 MD| Step number                                                            1161
 MD| Time [fs]                                                       2322.000000
 MD| Conserved quantity [hartree]                            -0.491120761599E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    487.066152           595.190146
 MD| Energy drift per atom [K]           0.232415678468E+03   0.270731557174E+03
 MD| Potential energy [hartree]         -0.491154090243E+04  -0.491156400604E+04
 MD| Kinetic energy [hartree]            0.333286442593E+00   0.374828473576E+00
 MD| Temperature [K]                             888.130034           998.829783
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.02808465     -4911.5456885142 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.7     0.09336604     -4911.3935096573  1.52E-01
     3 Broy./Diag. 0.40E+00    8.0     0.08829995     -4911.9438022991 -5.50E-01
     4 Broy./Diag. 0.40E+00    7.3     0.03573760     -4911.4113061651  5.32E-01
     5 Broy./Diag. 0.40E+00    9.5     0.01923871     -4911.5238501609 -1.13E-01
     6 Broy./Diag. 0.40E+00    7.0     0.00744204     -4911.5521955968 -2.83E-02
     7 Broy./Diag. 0.40E+00   10.0     0.00382435     -4911.5573034883 -5.11E-03
     8 Broy./Diag. 0.40E+00    8.6     0.00330387     -4911.5280642938  2.92E-02
     9 Broy./Diag. 0.40E+00    7.3     0.00156144     -4911.5442625561 -1.62E-02
    10 Broy./Diag. 0.40E+00    6.9     0.00076857     -4911.5484005144 -4.14E-03
    11 Broy./Diag. 0.40E+00    6.8     0.00080066     -4911.5446378087  3.76E-03
    12 Broy./Diag. 0.40E+00    6.9     0.00067760     -4911.5462461962 -1.61E-03
    13 Broy./Diag. 0.40E+00    8.3     0.00032334     -4911.5460779071  1.68E-04
    14 Broy./Diag. 0.40E+00    7.3     0.00013833     -4911.5461722629 -9.44E-05
    15 Broy./Diag. 0.40E+00    8.2     0.00022826     -4911.5465948276 -4.23E-04
    16 Broy./Diag. 0.40E+00    8.4     0.00029988     -4911.5469251549 -3.30E-04
    17 Broy./Diag. 0.40E+00    7.7     0.00017256     -4911.5475967025 -6.72E-04
    18 Broy./Diag. 0.40E+00   10.9     0.00019078     -4911.5472159963  3.81E-04
    19 Broy./Diag. 0.40E+00    7.2     0.00015125     -4911.5478257766 -6.10E-04
    20 Broy./Diag. 0.40E+00    6.9     0.00009420     -4911.5477321310  9.36E-05
    21 Broy./Diag. 0.40E+00    7.3     0.00005849     -4911.5476806864  5.14E-05
    22 Broy./Diag. 0.40E+00    8.1     0.00008849     -4911.5477866390 -1.06E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00006196     -4911.5478012599 -1.46E-05
    24 Broy./Diag. 0.40E+00    8.4     0.00005392     -4911.5478976518 -9.64E-05
    25 Broy./Diag. 0.40E+00    8.7     0.00003983     -4911.5477712520  1.26E-04
    26 Broy./Diag. 0.40E+00    7.5     0.00003192     -4911.5478731750 -1.02E-04
    27 Broy./Diag. 0.40E+00    9.9     0.00001600     -4911.5479084241 -3.52E-05
    28 Broy./Diag. 0.40E+00    7.6     0.00003125     -4911.5478879359  2.05E-05
    29 Broy./Diag. 0.40E+00    7.3     0.00003264     -4911.5478796474  8.29E-06
    30 Broy./Diag. 0.40E+00    6.7     0.00002660     -4911.5478860590 -6.41E-06
    31 Broy./Diag. 0.40E+00    7.2     0.00002051     -4911.5479614176 -7.54E-05
    32 Broy./Diag. 0.40E+00    7.1     0.00001574     -4911.5479137904  4.76E-05
    33 Broy./Diag. 0.40E+00    7.3     0.00000925     -4911.5479036746  1.01E-05
    34 Broy./Diag. 0.40E+00    7.0     0.00001088     -4911.5479381431 -3.45E-05
    35 Broy./Diag. 0.40E+00    7.3     0.00001393     -4911.5479513059 -1.32E-05
    36 Broy./Diag. 0.40E+00    7.9     0.00001346     -4911.5479498135  1.49E-06
    37 Broy./Diag. 0.40E+00    7.1     0.00001234     -4911.5479168573  3.30E-05
    38 Broy./Diag. 0.40E+00    7.3     0.00000859     -4911.5479602904 -4.34E-05
    39 Broy./Diag. 0.40E+00    7.3     0.00000644     -4911.5479729607 -1.27E-05
    40 Broy./Diag. 0.40E+00    6.6     0.00000727     -4911.5479500826  2.29E-05
    41 Broy./Diag. 0.40E+00    7.2     0.00000876     -4911.5479510195 -9.37E-07
    42 Broy./Diag. 0.40E+00    7.1     0.00000680     -4911.5479644529 -1.34E-05
    43 Broy./Diag. 0.40E+00    7.3     0.00000663     -4911.5479824394 -1.80E-05
    44 Broy./Diag. 0.40E+00    7.5     0.00000385     -4911.5479626883  1.98E-05
    45 Broy./Diag. 0.40E+00    7.3     0.00000345     -4911.5479666565 -3.97E-06
    46 Broy./Diag. 0.40E+00    7.5     0.00000290     -4911.5479793869 -1.27E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00000496     -4911.5479806408 -1.25E-06
    48 Broy./Diag. 0.40E+00    7.3     0.00000413     -4911.5479758372  4.80E-06
    49 Broy./Diag. 0.40E+00    7.1     0.00000455     -4911.5479696491  6.19E-06
    50 Broy./Diag. 0.40E+00    7.1     0.00000240     -4911.5479851292 -1.55E-05
    51 Broy./Diag. 0.40E+00    7.1     0.00000195     -4911.5479841111  1.02E-06
    52 Broy./Diag. 0.40E+00    7.5     0.00000156     -4911.5479799720  4.14E-06
    53 Broy./Diag. 0.40E+00    7.3     0.00000240     -4911.5479814570 -1.49E-06
    54 Broy./Diag. 0.40E+00    7.1     0.00000168     -4911.5479850425 -3.59E-06
    55 Broy./Diag. 0.40E+00    7.3     0.00000232     -4911.5479884995 -3.46E-06
    56 Broy./Diag. 0.40E+00    6.9     0.00000150     -4911.5479816643  6.84E-06
    57 Broy./Diag. 0.40E+00    7.0     0.00000138     -4911.5479846676 -3.00E-06
    58 Broy./Diag. 0.40E+00    6.9     0.00000097     -4911.5479887693 -4.10E-06

  *** SCF run converged in    58 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008290071498
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.75546474474868
  Hartree energy:                                            1781.47971703472990
  Exchange-correlation energy:                               -779.45457734806541
  Electronic entropic energy:                                  -0.23825358586487
  Fermi energy:                                                 0.08719376637858

  Total energy:                                             -4911.54798876931818

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.547993066852541

 MD| ***************************************************************************
 MD| Step number                                                            1162
 MD| Time [fs]                                                       2324.000000
 MD| Conserved quantity [hartree]                            -0.491120657250E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    445.868836           595.061642
 MD| Energy drift per atom [K]           0.234583476999E+03   0.270700448671E+03
 MD| Potential energy [hartree]         -0.491154799307E+04  -0.491156399226E+04
 MD| Kinetic energy [hartree]            0.341420562982E+00   0.374799723223E+00
 MD| Temperature [K]                             909.805553           998.753170
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.03550285     -4911.5516570168 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.12321633     -4911.3768570371  1.75E-01
     3 Broy./Diag. 0.40E+00    7.0     0.11302803     -4912.0168839943 -6.40E-01
     4 Broy./Diag. 0.40E+00    6.9     0.04348134     -4911.4207455099  5.96E-01
     5 Broy./Diag. 0.40E+00    6.9     0.02167268     -4911.5286561155 -1.08E-01
     6 Broy./Diag. 0.40E+00    7.3     0.00735035     -4911.5526899776 -2.40E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00460107     -4911.5669946172 -1.43E-02
     8 Broy./Diag. 0.40E+00    6.8     0.00344197     -4911.5308754146  3.61E-02
     9 Broy./Diag. 0.40E+00    6.8     0.00190892     -4911.5501171987 -1.92E-02
    10 Broy./Diag. 0.40E+00    7.3     0.00094130     -4911.5540414219 -3.92E-03
    11 Broy./Diag. 0.40E+00    7.1     0.00083114     -4911.5511485207  2.89E-03
    12 Broy./Diag. 0.40E+00    7.1     0.00071411     -4911.5522558459 -1.11E-03
    13 Broy./Diag. 0.40E+00    7.1     0.00036900     -4911.5515098670  7.46E-04
    14 Broy./Diag. 0.40E+00    7.1     0.00019426     -4911.5523147511 -8.05E-04
    15 Broy./Diag. 0.40E+00    7.1     0.00016806     -4911.5531570054 -8.42E-04
    16 Broy./Diag. 0.40E+00    6.7     0.00018074     -4911.5525468194  6.10E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00020795     -4911.5537871114 -1.24E-03
    18 Broy./Diag. 0.40E+00    7.3     0.00011429     -4911.5538822998 -9.52E-05
    19 Broy./Diag. 0.40E+00    7.2     0.00008184     -4911.5540475550 -1.65E-04
    20 Broy./Diag. 0.40E+00    7.3     0.00007725     -4911.5539468172  1.01E-04
    21 Broy./Diag. 0.40E+00    6.9     0.00004177     -4911.5542247705 -2.78E-04
    22 Broy./Diag. 0.40E+00    7.1     0.00003537     -4911.5542290890 -4.32E-06
    23 Broy./Diag. 0.40E+00    6.9     0.00001671     -4911.5541339656  9.51E-05
    24 Broy./Diag. 0.40E+00    7.1     0.00002940     -4911.5542753556 -1.41E-04
    25 Broy./Diag. 0.40E+00    7.0     0.00002663     -4911.5542660570  9.30E-06
    26 Broy./Diag. 0.40E+00    7.1     0.00001006     -4911.5542372802  2.88E-05
    27 Broy./Diag. 0.40E+00    6.9     0.00001363     -4911.5542359428  1.34E-06
    28 Broy./Diag. 0.40E+00    7.1     0.00000981     -4911.5542758577 -3.99E-05
    29 Broy./Diag. 0.40E+00    7.1     0.00000837     -4911.5542478663  2.80E-05
    30 Broy./Diag. 0.40E+00    7.5     0.00000464     -4911.5542153652  3.25E-05
    31 Broy./Diag. 0.40E+00    7.5     0.00000535     -4911.5542449225 -2.96E-05
    32 Broy./Diag. 0.40E+00    7.4     0.00000555     -4911.5542347863  1.01E-05
    33 Broy./Diag. 0.40E+00    6.8     0.00000476     -4911.5542284175  6.37E-06
    34 Broy./Diag. 0.40E+00    7.0     0.00000345     -4911.5542194999  8.92E-06
    35 Broy./Diag. 0.40E+00    7.1     0.00000340     -4911.5542310922 -1.16E-05
    36 Broy./Diag. 0.40E+00    7.3     0.00000257     -4911.5542245342  6.56E-06
    37 Broy./Diag. 0.40E+00    7.1     0.00000176     -4911.5542097051  1.48E-05
    38 Broy./Diag. 0.40E+00    7.1     0.00000227     -4911.5542189633 -9.26E-06
    39 Broy./Diag. 0.40E+00    7.1     0.00000296     -4911.5542165868  2.38E-06
    40 Broy./Diag. 0.40E+00    6.6     0.00000268     -4911.5542177184 -1.13E-06
    41 Broy./Diag. 0.40E+00    7.3     0.00000143     -4911.5542075008  1.02E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00000138     -4911.5542114181 -3.92E-06
    43 Broy./Diag. 0.40E+00    7.1     0.00000091     -4911.5542160644 -4.65E-06

  *** SCF run converged in    43 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008252682679
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.69291791096930
  Hartree energy:                                            1781.51704580250907
  Exchange-correlation energy:                               -779.43548867023719
  Electronic entropic energy:                                  -0.23835110142885
  Fermi energy:                                                 0.08709932881286

  Total energy:                                             -4911.55421606435448

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.554209074447499

 MD| ***************************************************************************
 MD| Step number                                                            1163
 MD| Time [fs]                                                       2326.000000
 MD| Conserved quantity [hartree]                            -0.491121298073E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    313.175131           594.819263
 MD| Energy drift per atom [K]           0.221270618894E+03   0.270657946668E+03
 MD| Potential energy [hartree]         -0.491155420907E+04  -0.491156398384E+04
 MD| Kinetic energy [hartree]            0.341228347354E+00   0.374770857036E+00
 MD| Temperature [K]                             909.293344           998.676248
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.03805402     -4911.5565035316 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.2     0.13680091     -4911.3873953117  1.69E-01
     3 Broy./Diag. 0.40E+00    7.1     0.12315668     -4912.0008026325 -6.13E-01
     4 Broy./Diag. 0.40E+00    7.2     0.04793867     -4911.4340490539  5.67E-01
     5 Broy./Diag. 0.40E+00    7.3     0.02150733     -4911.5387139360 -1.05E-01
     6 Broy./Diag. 0.40E+00    7.1     0.00702027     -4911.5519930046 -1.33E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00505310     -4911.5724632707 -2.05E-02
     8 Broy./Diag. 0.40E+00    8.2     0.00327472     -4911.5336045026  3.89E-02
     9 Broy./Diag. 0.40E+00    7.4     0.00195920     -4911.5555249833 -2.19E-02
    10 Broy./Diag. 0.40E+00    7.1     0.00095744     -4911.5575242303 -2.00E-03
    11 Broy./Diag. 0.40E+00    7.3     0.00076441     -4911.5558231893  1.70E-03
    12 Broy./Diag. 0.40E+00    7.2     0.00065531     -4911.5573793199 -1.56E-03
    13 Broy./Diag. 0.40E+00    7.2     0.00034241     -4911.5560667852  1.31E-03
    14 Broy./Diag. 0.40E+00    7.7     0.00028148     -4911.5571268032 -1.06E-03
    15 Broy./Diag. 0.40E+00    7.2     0.00017243     -4911.5582213055 -1.09E-03
    16 Broy./Diag. 0.40E+00    7.9     0.00015999     -4911.5570000058  1.22E-03
    17 Broy./Diag. 0.40E+00    7.3     0.00019850     -4911.5588994283 -1.90E-03
    18 Broy./Diag. 0.40E+00    7.2     0.00012552     -4911.5590722268 -1.73E-04
    19 Broy./Diag. 0.40E+00    7.1     0.00008729     -4911.5589016130  1.71E-04
    20 Broy./Diag. 0.40E+00    7.3     0.00007613     -4911.5588297686  7.18E-05
    21 Broy./Diag. 0.40E+00    7.1     0.00004273     -4911.5591405501 -3.11E-04
    22 Broy./Diag. 0.40E+00    7.5     0.00003614     -4911.5592080978 -6.75E-05
    23 Broy./Diag. 0.40E+00    7.3     0.00002113     -4911.5589634887  2.45E-04
    24 Broy./Diag. 0.40E+00    7.1     0.00003597     -4911.5592149486 -2.51E-04
    25 Broy./Diag. 0.40E+00    6.7     0.00002684     -4911.5592392867 -2.43E-05
    26 Broy./Diag. 0.40E+00    7.1     0.00001972     -4911.5591433542  9.59E-05
    27 Broy./Diag. 0.40E+00    7.7     0.00001612     -4911.5590962552  4.71E-05
    28 Broy./Diag. 0.40E+00    7.3     0.00001509     -4911.5591574845 -6.12E-05
    29 Broy./Diag. 0.40E+00    7.1     0.00001199     -4911.5592150785 -5.76E-05
    30 Broy./Diag. 0.40E+00    7.0     0.00001056     -4911.5590864027  1.29E-04
    31 Broy./Diag. 0.40E+00    7.1     0.00001201     -4911.5591297740 -4.34E-05
    32 Broy./Diag. 0.40E+00    6.9     0.00001073     -4911.5591787359 -4.90E-05
    33 Broy./Diag. 0.40E+00    8.1     0.00000673     -4911.5591696142  9.12E-06
    34 Broy./Diag. 0.40E+00    6.9     0.00000600     -4911.5591330824  3.65E-05
    35 Broy./Diag. 0.40E+00    6.9     0.00000429     -4911.5591122481  2.08E-05
    36 Broy./Diag. 0.40E+00    7.1     0.00000455     -4911.5591607871 -4.85E-05
    37 Broy./Diag. 0.40E+00    7.1     0.00000378     -4911.5591388662  2.19E-05
    38 Broy./Diag. 0.40E+00    7.3     0.00000340     -4911.5591239535  1.49E-05
    39 Broy./Diag. 0.40E+00    7.3     0.00000272     -4911.5591283559 -4.40E-06
    40 Broy./Diag. 0.40E+00    7.1     0.00000254     -4911.5591411345 -1.28E-05
    41 Broy./Diag. 0.40E+00    7.5     0.00000218     -4911.5591442081 -3.07E-06
    42 Broy./Diag. 0.40E+00    7.0     0.00000279     -4911.5591179153  2.63E-05
    43 Broy./Diag. 0.40E+00    7.2     0.00000239     -4911.5591326955 -1.48E-05
    44 Broy./Diag. 0.40E+00    7.7     0.00000215     -4911.5591373734 -4.68E-06
    45 Broy./Diag. 0.40E+00    7.1     0.00000148     -4911.5591331450  4.23E-06
    46 Broy./Diag. 0.40E+00    7.3     0.00000119     -4911.5591266125  6.53E-06
    47 Broy./Diag. 0.40E+00    7.3     0.00000108     -4911.5591259623  6.50E-07
    48 Broy./Diag. 0.40E+00    6.9     0.00000145     -4911.5591341766 -8.21E-06
    49 Broy./Diag. 0.40E+00    7.1     0.00000126     -4911.5591267806  7.40E-06
    50 Broy./Diag. 0.40E+00    7.1     0.00000118     -4911.5591258275  9.53E-07
    51 Broy./Diag. 0.40E+00    7.1     0.00000108     -4911.5591275980 -1.77E-06
    52 Broy./Diag. 0.40E+00    6.9     0.00000096     -4911.5591303749 -2.78E-06

  *** SCF run converged in    52 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008227266536
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.63268654898957
  Hartree energy:                                            1781.55385965597725
  Exchange-correlation energy:                               -779.41683101714659
  Electronic entropic energy:                                  -0.23850531947488
  Fermi energy:                                                 0.08700217536462

  Total energy:                                             -4911.55913037490336

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.559125429469532

 MD| ***************************************************************************
 MD| Step number                                                            1164
 MD| Time [fs]                                                       2328.000000
 MD| Conserved quantity [hartree]                            -0.491122163136E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    384.411728           594.638501
 MD| Energy drift per atom [K]           0.203299232206E+03   0.270600078356E+03
 MD| Potential energy [hartree]         -0.491155912543E+04  -0.491156397967E+04
 MD| Kinetic energy [hartree]            0.337494068784E+00   0.374738832303E+00
 MD| Temperature [K]                             899.342369           998.590910
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.03520140     -4911.5593940049 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.12784199     -4911.4156984625  1.44E-01
     3 Broy./Diag. 0.40E+00    6.9     0.11725759     -4911.9280018057 -5.12E-01
     4 Broy./Diag. 0.40E+00    7.3     0.04788000     -4911.4382704849  4.90E-01
     5 Broy./Diag. 0.40E+00    7.3     0.02090043     -4911.5510375798 -1.13E-01
     6 Broy./Diag. 0.40E+00    6.9     0.00738055     -4911.5534992560 -2.46E-03
     7 Broy./Diag. 0.40E+00    7.2     0.00462251     -4911.5704841290 -1.70E-02
     8 Broy./Diag. 0.40E+00    7.2     0.00345461     -4911.5419364624  2.85E-02
     9 Broy./Diag. 0.40E+00    6.9     0.00193340     -4911.5616813617 -1.97E-02
    10 Broy./Diag. 0.40E+00    6.9     0.00101928     -4911.5583111327  3.37E-03
    11 Broy./Diag. 0.40E+00    7.3     0.00090104     -4911.5567512529  1.56E-03
    12 Broy./Diag. 0.40E+00    7.1     0.00066643     -4911.5616993044 -4.95E-03
    13 Broy./Diag. 0.40E+00    7.3     0.00030729     -4911.5601040506  1.60E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00018307     -4911.5591532177  9.51E-04
    15 Broy./Diag. 0.40E+00    7.3     0.00019002     -4911.5607597080 -1.61E-03
    16 Broy./Diag. 0.40E+00    6.9     0.00017037     -4911.5610574844 -2.98E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00014400     -4911.5612523747 -1.95E-04
    18 Broy./Diag. 0.40E+00    7.0     0.00013910     -4911.5614477574 -1.95E-04
    19 Broy./Diag. 0.40E+00    6.9     0.00006534     -4911.5618420205 -3.94E-04
    20 Broy./Diag. 0.40E+00    7.1     0.00006472     -4911.5616642568  1.78E-04
    21 Broy./Diag. 0.40E+00    6.9     0.00004235     -4911.5619453756 -2.81E-04
    22 Broy./Diag. 0.40E+00    7.2     0.00002200     -4911.5619505601 -5.18E-06
    23 Broy./Diag. 0.40E+00    7.6     0.00001384     -4911.5619541653 -3.61E-06
    24 Broy./Diag. 0.40E+00    6.9     0.00001240     -4911.5619518636  2.30E-06
    25 Broy./Diag. 0.40E+00    7.0     0.00001452     -4911.5619696409 -1.78E-05
    26 Broy./Diag. 0.40E+00    6.9     0.00001492     -4911.5619767926 -7.15E-06
    27 Broy./Diag. 0.40E+00    7.1     0.00000983     -4911.5619546628  2.21E-05
    28 Broy./Diag. 0.40E+00    7.1     0.00001001     -4911.5619726605 -1.80E-05
    29 Broy./Diag. 0.40E+00    7.3     0.00000822     -4911.5619545097  1.82E-05
    30 Broy./Diag. 0.40E+00    7.2     0.00000661     -4911.5619673869 -1.29E-05
    31 Broy./Diag. 0.40E+00    7.5     0.00000321     -4911.5619416961  2.57E-05
    32 Broy./Diag. 0.40E+00    7.1     0.00000244     -4911.5619402246  1.47E-06
    33 Broy./Diag. 0.40E+00    6.9     0.00000246     -4911.5619393095  9.15E-07
    34 Broy./Diag. 0.40E+00    7.3     0.00000195     -4911.5619219683  1.73E-05
    35 Broy./Diag. 0.40E+00    7.3     0.00000327     -4911.5619259052 -3.94E-06
    36 Broy./Diag. 0.40E+00    7.7     0.00000328     -4911.5619285643 -2.66E-06
    37 Broy./Diag. 0.40E+00    7.7     0.00000138     -4911.5619130609  1.55E-05
    38 Broy./Diag. 0.40E+00    8.0     0.00000169     -4911.5619151234 -2.06E-06
    39 Broy./Diag. 0.40E+00    7.3     0.00000111     -4911.5619143646  7.59E-07
    40 Broy./Diag. 0.40E+00    7.0     0.00000078     -4911.5619107207  3.64E-06

  *** SCF run converged in    40 steps ***


  Electronic density on regular grids:      -1631.9999999995        0.0000000005
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000022
  Total charge density g-space grids:          -0.0000000022

  Overlap energy of the core charge distribution:               0.00008213420393
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.57912883995641
  Hartree energy:                                            1781.58737299329414
  Exchange-correlation energy:                               -779.39937087770272
  Electronic entropic energy:                                  -0.23870129445595
  Fermi energy:                                                 0.08691008482888

  Total energy:                                             -4911.56191072074216

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.561912158568703

 MD| ***************************************************************************
 MD| Step number                                                            1165
 MD| Time [fs]                                                       2330.000000
 MD| Conserved quantity [hartree]                            -0.491123777719E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    295.479424           594.381712
 MD| Energy drift per atom [K]           0.169756849324E+03   0.270513517645E+03
 MD| Potential energy [hartree]         -0.491156191216E+04  -0.491156397790E+04
 MD| Kinetic energy [hartree]            0.324134972904E+00   0.374695395514E+00
 MD| Temperature [K]                             863.743518           998.475161
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                932
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.03146028     -4911.5606854121 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.11519215     -4911.4379377143  1.23E-01
     3 Broy./Diag. 0.40E+00    6.9     0.10694240     -4911.8671075249 -4.29E-01
     4 Broy./Diag. 0.40E+00    6.6     0.04453426     -4911.4608280434  4.06E-01
     5 Broy./Diag. 0.40E+00    8.1     0.01806815     -4911.5539592626 -9.31E-02
     6 Broy./Diag. 0.40E+00    7.0     0.00672308     -4911.5516629318  2.30E-03
     7 Broy./Diag. 0.40E+00    6.7     0.00449796     -4911.5751617892 -2.35E-02
     8 Broy./Diag. 0.40E+00    7.3     0.00320041     -4911.5398079343  3.54E-02
     9 Broy./Diag. 0.40E+00    7.1     0.00175303     -4911.5606127684 -2.08E-02
    10 Broy./Diag. 0.40E+00    7.0     0.00097240     -4911.5607923167 -1.80E-04
    11 Broy./Diag. 0.40E+00    7.1     0.00074901     -4911.5594882195  1.30E-03
    12 Broy./Diag. 0.40E+00    7.3     0.00059934     -4911.5622400648 -2.75E-03
    13 Broy./Diag. 0.40E+00    6.7     0.00028891     -4911.5605016810  1.74E-03
    14 Broy./Diag. 0.40E+00    7.2     0.00025127     -4911.5607420099 -2.40E-04
    15 Broy./Diag. 0.40E+00    7.5     0.00014931     -4911.5621441475 -1.40E-03
    16 Broy./Diag. 0.40E+00    7.1     0.00014664     -4911.5614075667  7.37E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00014815     -4911.5626729900 -1.27E-03
    18 Broy./Diag. 0.40E+00    7.4     0.00013478     -4911.5629135422 -2.41E-04
    19 Broy./Diag. 0.40E+00    7.1     0.00004205     -4911.5627903146  1.23E-04
    20 Broy./Diag. 0.40E+00    7.3     0.00005260     -4911.5628334193 -4.31E-05
    21 Broy./Diag. 0.40E+00    7.1     0.00004243     -4911.5631699883 -3.37E-04
    22 Broy./Diag. 0.40E+00    8.1     0.00002136     -4911.5630023388  1.68E-04
    23 Broy./Diag. 0.40E+00    7.3     0.00001563     -4911.5630124535 -1.01E-05
    24 Broy./Diag. 0.40E+00    7.5     0.00000988     -4911.5630945005 -8.20E-05
    25 Broy./Diag. 0.40E+00    6.8     0.00001066     -4911.5630510745  4.34E-05
    26 Broy./Diag. 0.40E+00    6.8     0.00001139     -4911.5630462556  4.82E-06
    27 Broy./Diag. 0.40E+00    7.2     0.00000860     -4911.5631135595 -6.73E-05
    28 Broy./Diag. 0.40E+00    6.9     0.00000701     -4911.5630558239  5.77E-05
    29 Broy./Diag. 0.40E+00    7.1     0.00000578     -4911.5630526653  3.16E-06
    30 Broy./Diag. 0.40E+00    7.4     0.00000624     -4911.5630672543 -1.46E-05
    31 Broy./Diag. 0.40E+00    6.9     0.00000303     -4911.5630450907  2.22E-05
    32 Broy./Diag. 0.40E+00    6.9     0.00000357     -4911.5630373138  7.78E-06
    33 Broy./Diag. 0.40E+00    6.9     0.00000338     -4911.5630603652 -2.31E-05
    34 Broy./Diag. 0.40E+00    7.1     0.00000305     -4911.5630310851  2.93E-05
    35 Broy./Diag. 0.40E+00    7.5     0.00000255     -4911.5630292133  1.87E-06
    36 Broy./Diag. 0.40E+00    7.1     0.00000105     -4911.5630323367 -3.12E-06
    37 Broy./Diag. 0.40E+00    7.0     0.00000102     -4911.5630283062  4.03E-06
    38 Broy./Diag. 0.40E+00    6.9     0.00000122     -4911.5630211978  7.11E-06
    39 Broy./Diag. 0.40E+00    7.7     0.00000116     -4911.5630301412 -8.94E-06
    40 Broy./Diag. 0.40E+00    7.5     0.00000113     -4911.5630201368  1.00E-05
    41 Broy./Diag. 0.40E+00    7.3     0.00000083     -4911.5630205316 -3.95E-07

  *** SCF run converged in    41 steps ***


  Electronic density on regular grids:      -1631.9999999995        0.0000000005
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000022
  Total charge density g-space grids:          -0.0000000022

  Overlap energy of the core charge distribution:               0.00008206919456
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.53370481173806
  Hartree energy:                                            1781.61633652513319
  Exchange-correlation energy:                               -779.38379092847413
  Electronic entropic energy:                                  -0.23893050945935
  Fermi energy:                                                 0.08682768184084

  Total energy:                                             -4911.56302053159652

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.563023553841958

 MD| ***************************************************************************
 MD| Step number                                                            1166
 MD| Time [fs]                                                       2332.000000
 MD| Conserved quantity [hartree]                            -0.491124200712E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    302.030701           594.130982
 MD| Energy drift per atom [K]           0.160969311795E+03   0.270419568926E+03
 MD| Potential energy [hartree]         -0.491156302355E+04  -0.491156397708E+04
 MD| Kinetic energy [hartree]            0.321016434858E+00   0.374649358670E+00
 MD| Temperature [K]                             855.433348           998.352484
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                932
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.02820798     -4911.5608839865 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.7     0.10330277     -4911.4604014371  1.00E-01
     3 Broy./Diag. 0.40E+00    7.0     0.10369257     -4911.8048440990 -3.44E-01
     4 Broy./Diag. 0.40E+00    7.2     0.04188063     -4911.4726087183  3.32E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01638400     -4911.5615606595 -8.90E-02
     6 Broy./Diag. 0.40E+00    7.3     0.00659274     -4911.5490303489  1.25E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00436334     -4911.5734754983 -2.44E-02
     8 Broy./Diag. 0.40E+00    7.1     0.00300672     -4911.5427176172  3.08E-02
     9 Broy./Diag. 0.40E+00    7.1     0.00167053     -4911.5612432639 -1.85E-02
    10 Broy./Diag. 0.40E+00    7.4     0.00100540     -4911.5605537396  6.90E-04
    11 Broy./Diag. 0.40E+00    8.1     0.00076979     -4911.5595858758  9.68E-04
    12 Broy./Diag. 0.40E+00    7.1     0.00059313     -4911.5626751196 -3.09E-03
    13 Broy./Diag. 0.40E+00   10.5     0.00037864     -4911.5608585700  1.82E-03
    14 Broy./Diag. 0.40E+00    6.9     0.00029742     -4911.5610753275 -2.17E-04
    15 Broy./Diag. 0.40E+00   10.3     0.00015415     -4911.5622474526 -1.17E-03
    16 Broy./Diag. 0.40E+00    8.1     0.00013672     -4911.5620550094  1.92E-04
    17 Broy./Diag. 0.40E+00    6.9     0.00011620     -4911.5627462360 -6.91E-04
    18 Broy./Diag. 0.40E+00    7.3     0.00013352     -4911.5630205803 -2.74E-04
    19 Broy./Diag. 0.40E+00    7.3     0.00005121     -4911.5629434075  7.72E-05
    20 Broy./Diag. 0.40E+00    7.1     0.00004650     -4911.5630988426 -1.55E-04
    21 Broy./Diag. 0.40E+00    7.9     0.00004462     -4911.5632394126 -1.41E-04
    22 Broy./Diag. 0.40E+00    7.7     0.00001880     -4911.5631311848  1.08E-04
    23 Broy./Diag. 0.40E+00    8.1     0.00002280     -4911.5632301148 -9.89E-05
    24 Broy./Diag. 0.40E+00    8.7     0.00001812     -4911.5632015137  2.86E-05
    25 Broy./Diag. 0.40E+00    7.2     0.00001313     -4911.5632321157 -3.06E-05
    26 Broy./Diag. 0.40E+00    9.9     0.00001474     -4911.5631959982  3.61E-05
    27 Broy./Diag. 0.40E+00    8.9     0.00001292     -4911.5632375356 -4.15E-05
    28 Broy./Diag. 0.40E+00    7.1     0.00000620     -4911.5631910216  4.65E-05
    29 Broy./Diag. 0.40E+00    6.9     0.00000679     -4911.5631847886  6.23E-06
    30 Broy./Diag. 0.40E+00    8.0     0.00000373     -4911.5632036097 -1.88E-05
    31 Broy./Diag. 0.40E+00    7.1     0.00000288     -4911.5631872621  1.63E-05
    32 Broy./Diag. 0.40E+00    8.1     0.00000441     -4911.5631851810  2.08E-06
    33 Broy./Diag. 0.40E+00    9.0     0.00000444     -4911.5631787128  6.47E-06
    34 Broy./Diag. 0.40E+00    8.0     0.00000191     -4911.5631818731 -3.16E-06
    35 Broy./Diag. 0.40E+00   11.2     0.00000226     -4911.5631649828  1.69E-05
    36 Broy./Diag. 0.40E+00    7.1     0.00000103     -4911.5631765333 -1.16E-05
    37 Broy./Diag. 0.40E+00    6.9     0.00000163     -4911.5631689607  7.57E-06
    38 Broy./Diag. 0.40E+00    7.1     0.00000159     -4911.5631661565  2.80E-06
    39 Broy./Diag. 0.40E+00    7.0     0.00000145     -4911.5631650488  1.11E-06
    40 Broy./Diag. 0.40E+00    7.5     0.00000084     -4911.5631666712 -1.62E-06

  *** SCF run converged in    40 steps ***


  Electronic density on regular grids:      -1631.9999999995        0.0000000005
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000022
  Total charge density g-space grids:          -0.0000000022

  Overlap energy of the core charge distribution:               0.00008203743911
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.49407715917187
  Hartree energy:                                            1781.64222413387211
  Exchange-correlation energy:                               -779.36996707364312
  Electronic entropic energy:                                  -0.23916038653475
  Fermi energy:                                                 0.08675387266295

  Total energy:                                             -4911.56316667117517

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.563165766746351

 MD| ***************************************************************************
 MD| Step number                                                            1167
 MD| Time [fs]                                                       2334.000000
 MD| Conserved quantity [hartree]                            -0.491122951163E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    317.753405           593.894155
 MD| Energy drift per atom [K]           0.186928254687E+03   0.270348025383E+03
 MD| Potential energy [hartree]         -0.491156316577E+04  -0.491156397638E+04
 MD| Kinetic energy [hartree]            0.333654138917E+00   0.374614229947E+00
 MD| Temperature [K]                             889.109859           998.258874
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                932
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.6     0.02445040     -4911.5602568394 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.09171480     -4911.4743667587  8.59E-02
     3 Broy./Diag. 0.40E+00    7.6     0.09855281     -4911.7775017207 -3.03E-01
     4 Broy./Diag. 0.40E+00    6.9     0.04062705     -4911.4760251162  3.01E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01575911     -4911.5645450473 -8.85E-02
     6 Broy./Diag. 0.40E+00    7.1     0.00665990     -4911.5513609153  1.32E-02
     7 Broy./Diag. 0.40E+00    7.2     0.00516109     -4911.5692290435 -1.79E-02
     8 Broy./Diag. 0.40E+00    7.7     0.00308565     -4911.5493280081  1.99E-02
     9 Broy./Diag. 0.40E+00    6.9     0.00175065     -4911.5638961122 -1.46E-02
    10 Broy./Diag. 0.40E+00    7.0     0.00134092     -4911.5589019387  4.99E-03
    11 Broy./Diag. 0.40E+00    7.1     0.00101618     -4911.5566171590  2.28E-03
    12 Broy./Diag. 0.40E+00    7.2     0.00057520     -4911.5622554975 -5.64E-03
    13 Broy./Diag. 0.40E+00    7.1     0.00037765     -4911.5612451965  1.01E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00024560     -4911.5606329863  6.12E-04
    15 Broy./Diag. 0.40E+00    7.3     0.00022247     -4911.5605891596  4.38E-05
    16 Broy./Diag. 0.40E+00    6.9     0.00020242     -4911.5624426284 -1.85E-03
    17 Broy./Diag. 0.40E+00    7.1     0.00016081     -4911.5619589115  4.84E-04
    18 Broy./Diag. 0.40E+00    7.3     0.00016653     -4911.5617253556  2.34E-04
    19 Broy./Diag. 0.40E+00    7.7     0.00010448     -4911.5626006832 -8.75E-04
    20 Broy./Diag. 0.40E+00    7.0     0.00007407     -4911.5622498165  3.51E-04
    21 Broy./Diag. 0.40E+00    6.7     0.00006288     -4911.5622937751 -4.40E-05
    22 Broy./Diag. 0.40E+00    6.9     0.00003959     -4911.5623719091 -7.81E-05
    23 Broy./Diag. 0.40E+00    7.9     0.00004093     -4911.5626057797 -2.34E-04
    24 Broy./Diag. 0.40E+00    7.8     0.00005018     -4911.5624475029  1.58E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00004618     -4911.5622644117  1.83E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00002652     -4911.5624900195 -2.26E-04
    27 Broy./Diag. 0.40E+00    6.9     0.00002129     -4911.5624527710  3.72E-05
    28 Broy./Diag. 0.40E+00    7.5     0.00001447     -4911.5624445389  8.23E-06
    29 Broy./Diag. 0.40E+00    7.3     0.00001511     -4911.5623867976  5.77E-05
    30 Broy./Diag. 0.40E+00    7.1     0.00001343     -4911.5624600481 -7.33E-05
    31 Broy./Diag. 0.40E+00    7.1     0.00001613     -4911.5624759516 -1.59E-05
    32 Broy./Diag. 0.40E+00    7.3     0.00001025     -4911.5624081778  6.78E-05
    33 Broy./Diag. 0.40E+00    7.2     0.00000824     -4911.5624348761 -2.67E-05
    34 Broy./Diag. 0.40E+00    7.1     0.00000793     -4911.5624340736  8.03E-07
    35 Broy./Diag. 0.40E+00    7.3     0.00000733     -4911.5624471497 -1.31E-05
    36 Broy./Diag. 0.40E+00    7.3     0.00000643     -4911.5624177744  2.94E-05
    37 Broy./Diag. 0.40E+00    6.9     0.00000750     -4911.5624198804 -2.11E-06
    38 Broy./Diag. 0.40E+00    7.5     0.00000458     -4911.5624477519 -2.79E-05
    39 Broy./Diag. 0.40E+00    7.1     0.00000336     -4911.5624306127  1.71E-05
    40 Broy./Diag. 0.40E+00    6.9     0.00000345     -4911.5624334652 -2.85E-06
    41 Broy./Diag. 0.40E+00    6.7     0.00000281     -4911.5624293773  4.09E-06
    42 Broy./Diag. 0.40E+00    7.5     0.00000313     -4911.5624386689 -9.29E-06
    43 Broy./Diag. 0.40E+00    6.7     0.00000398     -4911.5624353013  3.37E-06
    44 Broy./Diag. 0.40E+00    6.6     0.00000298     -4911.5624227603  1.25E-05
    45 Broy./Diag. 0.40E+00    7.1     0.00000210     -4911.5624352577 -1.25E-05
    46 Broy./Diag. 0.40E+00    7.1     0.00000186     -4911.5624318573  3.40E-06
    47 Broy./Diag. 0.40E+00    7.3     0.00000138     -4911.5624331603 -1.30E-06
    48 Broy./Diag. 0.40E+00    7.3     0.00000153     -4911.5624305742  2.59E-06
    49 Broy./Diag. 0.40E+00    7.3     0.00000178     -4911.5624318560 -1.28E-06
    50 Broy./Diag. 0.40E+00    7.1     0.00000152     -4911.5624357674 -3.91E-06
    51 Broy./Diag. 0.40E+00    7.0     0.00000122     -4911.5624295987  6.17E-06
    52 Broy./Diag. 0.40E+00    7.1     0.00000112     -4911.5624325836 -2.98E-06
    53 Broy./Diag. 0.40E+00    6.7     0.00000111     -4911.5624319461  6.37E-07
    54 Broy./Diag. 0.40E+00    7.2     0.00000087     -4911.5624326382 -6.92E-07

  *** SCF run converged in    54 steps ***


  Electronic density on regular grids:      -1631.9999999995        0.0000000005
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000022
  Total charge density g-space grids:          -0.0000000022

  Overlap energy of the core charge distribution:               0.00008202276690
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.46160195598804
  Hartree energy:                                            1781.66382600441148
  Exchange-correlation energy:                               -779.35812273101692
  Electronic entropic energy:                                  -0.23939737571344
  Fermi energy:                                                 0.08669243699114

  Total energy:                                             -4911.56243263818305

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.562432746300146

 MD| ***************************************************************************
 MD| Step number                                                            1168
 MD| Time [fs]                                                       2336.000000
 MD| Conserved quantity [hartree]                            -0.491122730977E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    394.617508           593.723541
 MD| Energy drift per atom [K]           0.191502531528E+03   0.270280520680E+03
 MD| Potential energy [hartree]         -0.491156243275E+04  -0.491156397506E+04
 MD| Kinetic energy [hartree]            0.335122973764E+00   0.374580418940E+00
 MD| Temperature [K]                             893.023958           998.168776
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                932
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.01923116     -4911.5592292001 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.06394494     -4911.4918866604  6.73E-02
     3 Broy./Diag. 0.40E+00    7.5     0.07487258     -4911.7141678589 -2.22E-01
     4 Broy./Diag. 0.40E+00    7.1     0.03647582     -4911.4841167073  2.30E-01
     5 Broy./Diag. 0.40E+00    7.0     0.01405081     -4911.5580780346 -7.40E-02
     6 Broy./Diag. 0.40E+00    7.0     0.00662061     -4911.5552621086  2.82E-03
     7 Broy./Diag. 0.40E+00    6.5     0.00470894     -4911.5654694327 -1.02E-02
     8 Broy./Diag. 0.40E+00    7.0     0.00292964     -4911.5502483074  1.52E-02
     9 Broy./Diag. 0.40E+00    7.1     0.00176173     -4911.5623737769 -1.21E-02
    10 Broy./Diag. 0.40E+00    7.1     0.00146415     -4911.5581814871  4.19E-03
    11 Broy./Diag. 0.40E+00    7.5     0.00112741     -4911.5555346416  2.65E-03
    12 Broy./Diag. 0.40E+00    6.9     0.00058147     -4911.5604932386 -4.96E-03
    13 Broy./Diag. 0.40E+00    7.1     0.00042014     -4911.5601808918  3.12E-04
    14 Broy./Diag. 0.40E+00    7.1     0.00041556     -4911.5599418007  2.39E-04
    15 Broy./Diag. 0.40E+00    6.6     0.00041560     -4911.5584415244  1.50E-03
    16 Broy./Diag. 0.40E+00    6.7     0.00035841     -4911.5608435633 -2.40E-03
    17 Broy./Diag. 0.40E+00    6.9     0.00043696     -4911.5613036161 -4.60E-04
    18 Broy./Diag. 0.40E+00    7.3     0.00025267     -4911.5599755803  1.33E-03
    19 Broy./Diag. 0.40E+00    7.3     0.00015383     -4911.5609507389 -9.75E-04
    20 Broy./Diag. 0.40E+00    6.8     0.00015463     -4911.5610554378 -1.05E-04
    21 Broy./Diag. 0.40E+00    7.1     0.00013194     -4911.5612207037 -1.65E-04
    22 Broy./Diag. 0.40E+00    7.3     0.00010542     -4911.5605566495  6.64E-04
    23 Broy./Diag. 0.40E+00    8.0     0.00010044     -4911.5609607045 -4.04E-04
    24 Broy./Diag. 0.40E+00    7.2     0.00008895     -4911.5612241602 -2.63E-04
    25 Broy./Diag. 0.40E+00    6.8     0.00004847     -4911.5609450234  2.79E-04
    26 Broy./Diag. 0.40E+00    6.8     0.00004943     -4911.5609967919 -5.18E-05
    27 Broy./Diag. 0.40E+00    6.9     0.00004369     -4911.5610311199 -3.43E-05
    28 Broy./Diag. 0.40E+00    7.3     0.00005155     -4911.5612298951 -1.99E-04
    29 Broy./Diag. 0.40E+00    6.9     0.00003810     -4911.5610795481  1.50E-04
    30 Broy./Diag. 0.40E+00    6.7     0.00003688     -4911.5610213637  5.82E-05
    31 Broy./Diag. 0.40E+00    7.1     0.00002173     -4911.5611561755 -1.35E-04
    32 Broy./Diag. 0.40E+00    7.9     0.00002482     -4911.5611310757  2.51E-05
    33 Broy./Diag. 0.40E+00    7.5     0.00002143     -4911.5611282155  2.86E-06
    34 Broy./Diag. 0.40E+00    7.3     0.00003195     -4911.5610713723  5.68E-05
    35 Broy./Diag. 0.40E+00    7.7     0.00002539     -4911.5611687985 -9.74E-05
    36 Broy./Diag. 0.40E+00    7.1     0.00002729     -4911.5612100026 -4.12E-05
    37 Broy./Diag. 0.40E+00    7.2     0.00001374     -4911.5611194922  9.05E-05
    38 Broy./Diag. 0.40E+00    7.3     0.00001358     -4911.5611680067 -4.85E-05
    39 Broy./Diag. 0.40E+00    7.0     0.00001384     -4911.5611642923  3.71E-06
    40 Broy./Diag. 0.40E+00    7.1     0.00001921     -4911.5611896065 -2.53E-05
    41 Broy./Diag. 0.40E+00    6.7     0.00001424     -4911.5611429407  4.67E-05
    42 Broy./Diag. 0.40E+00    7.3     0.00001564     -4911.5611628810 -1.99E-05
    43 Broy./Diag. 0.40E+00    7.1     0.00000999     -4911.5612114740 -4.86E-05
    44 Broy./Diag. 0.40E+00    7.3     0.00000840     -4911.5611756842  3.58E-05
    45 Broy./Diag. 0.40E+00    7.1     0.00000942     -4911.5611846283 -8.94E-06
    46 Broy./Diag. 0.40E+00    6.9     0.00000707     -4911.5611829864  1.64E-06
    47 Broy./Diag. 0.40E+00    7.5     0.00000646     -4911.5612012939 -1.83E-05
    48 Broy./Diag. 0.40E+00    7.7     0.00000697     -4911.5611970378  4.26E-06
    49 Broy./Diag. 0.40E+00    7.5     0.00000470     -4911.5611795652  1.75E-05
    50 Broy./Diag. 0.40E+00    7.5     0.00000461     -4911.5612036864 -2.41E-05
    51 Broy./Diag. 0.40E+00    6.9     0.00000690     -4911.5612002907  3.40E-06
    52 Broy./Diag. 0.40E+00    7.0     0.00000530     -4911.5612006941 -4.03E-07
    53 Broy./Diag. 0.40E+00    6.9     0.00000535     -4911.5611921775  8.52E-06
    54 Broy./Diag. 0.40E+00    7.3     0.00000476     -4911.5612005025 -8.33E-06
    55 Broy./Diag. 0.40E+00    7.1     0.00000322     -4911.5612139375 -1.34E-05
    56 Broy./Diag. 0.40E+00    7.7     0.00000233     -4911.5611982611  1.57E-05
    57 Broy./Diag. 0.40E+00    7.1     0.00000356     -4911.5612042005 -5.94E-06
    58 Broy./Diag. 0.40E+00    7.1     0.00000241     -4911.5612050457 -8.45E-07
    59 Broy./Diag. 0.40E+00    6.9     0.00000338     -4911.5612105530 -5.51E-06
    60 Broy./Diag. 0.40E+00    7.3     0.00000364     -4911.5612057349  4.82E-06
    61 Broy./Diag. 0.40E+00    7.1     0.00000245     -4911.5611993835  6.35E-06
    62 Broy./Diag. 0.40E+00    7.1     0.00000178     -4911.5612129460 -1.36E-05
    63 Broy./Diag. 0.40E+00    6.7     0.00000225     -4911.5612096417  3.30E-06
    64 Broy./Diag. 0.40E+00    6.9     0.00000154     -4911.5612088331  8.09E-07
    65 Broy./Diag. 0.40E+00    7.3     0.00000124     -4911.5612076116  1.22E-06
    66 Broy./Diag. 0.40E+00    7.1     0.00000142     -4911.5612105487 -2.94E-06
    67 Broy./Diag. 0.40E+00    6.9     0.00000127     -4911.5612132254 -2.68E-06
    68 Broy./Diag. 0.40E+00    7.3     0.00000097     -4911.5612067686  6.46E-06

  *** SCF run converged in    68 steps ***


  Electronic density on regular grids:      -1631.9999999995        0.0000000005
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000022
  Total charge density g-space grids:          -0.0000000022

  Overlap energy of the core charge distribution:               0.00008201297574
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.43806971524464
  Hartree energy:                                            1781.67952148978657
  Exchange-correlation energy:                               -779.34876561660985
  Electronic entropic energy:                                  -0.23969188043423
  Fermi energy:                                                 0.08664535939618

  Total energy:                                             -4911.56120676856426

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.561213866806611

 MD| ***************************************************************************
 MD| Step number                                                            1169
 MD| Time [fs]                                                       2338.000000
 MD| Conserved quantity [hartree]                            -0.491122051049E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    494.004113           593.638238
 MD| Energy drift per atom [K]           0.205627801371E+03   0.270225214675E+03
 MD| Potential energy [hartree]         -0.491156121387E+04  -0.491156397270E+04
 MD| Kinetic energy [hartree]            0.340703376702E+00   0.374551439434E+00
 MD| Temperature [K]                             907.894420           998.091552
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                932
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.01821078     -4911.5587553165 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.05601903     -4911.5104528845  4.83E-02
     3 Broy./Diag. 0.40E+00    7.5     0.06183387     -4911.6505190703 -1.40E-01
     4 Broy./Diag. 0.40E+00    7.1     0.03303425     -4911.4926218782  1.58E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01363495     -4911.5643703046 -7.17E-02
     6 Broy./Diag. 0.40E+00    7.3     0.00685837     -4911.5543944788  9.98E-03
     7 Broy./Diag. 0.40E+00    7.1     0.00442715     -4911.5598082656 -5.41E-03
     8 Broy./Diag. 0.40E+00    7.1     0.00256532     -4911.5539399423  5.87E-03
     9 Broy./Diag. 0.40E+00    7.3     0.00174634     -4911.5631263678 -9.19E-03
    10 Broy./Diag. 0.40E+00    7.3     0.00140904     -4911.5568362400  6.29E-03
    11 Broy./Diag. 0.40E+00    6.9     0.00127681     -4911.5546893737  2.15E-03
    12 Broy./Diag. 0.40E+00    7.1     0.00061326     -4911.5600487086 -5.36E-03
    13 Broy./Diag. 0.40E+00    6.9     0.00048524     -4911.5598247310  2.24E-04
    14 Broy./Diag. 0.40E+00    7.3     0.00040652     -4911.5596612861  1.63E-04
    15 Broy./Diag. 0.40E+00    7.6     0.00041047     -4911.5581782683  1.48E-03
    16 Broy./Diag. 0.40E+00    7.1     0.00039918     -4911.5603536107 -2.18E-03
    17 Broy./Diag. 0.40E+00    7.3     0.00056587     -4911.5606590431 -3.05E-04
    18 Broy./Diag. 0.40E+00    6.8     0.00037795     -4911.5586881898  1.97E-03
    19 Broy./Diag. 0.40E+00    7.1     0.00024501     -4911.5597808395 -1.09E-03
    20 Broy./Diag. 0.40E+00    6.9     0.00018799     -4911.5601774585 -3.97E-04
    21 Broy./Diag. 0.40E+00    7.3     0.00017817     -4911.5606277385 -4.50E-04
    22 Broy./Diag. 0.40E+00    7.5     0.00009412     -4911.5598820437  7.46E-04
    23 Broy./Diag. 0.40E+00    7.3     0.00013122     -4911.5601118347 -2.30E-04
    24 Broy./Diag. 0.40E+00    6.7     0.00012427     -4911.5605269387 -4.15E-04
    25 Broy./Diag. 0.40E+00    7.3     0.00009698     -4911.5602101366  3.17E-04
    26 Broy./Diag. 0.40E+00    7.3     0.00013134     -4911.5601193754  9.08E-05
    27 Broy./Diag. 0.40E+00    7.3     0.00012187     -4911.5601939682 -7.46E-05
    28 Broy./Diag. 0.40E+00    7.3     0.00010875     -4911.5606395895 -4.46E-04
    29 Broy./Diag. 0.40E+00    7.1     0.00008683     -4911.5604657505  1.74E-04
    30 Broy./Diag. 0.40E+00    7.1     0.00005992     -4911.5602432121  2.23E-04
    31 Broy./Diag. 0.40E+00    7.3     0.00003339     -4911.5604601775 -2.17E-04
    32 Broy./Diag. 0.40E+00    6.9     0.00004014     -4911.5604670596 -6.88E-06
    33 Broy./Diag. 0.40E+00    6.8     0.00005529     -4911.5604608761  6.18E-06
    34 Broy./Diag. 0.40E+00    7.1     0.00006385     -4911.5602865988  1.74E-04
    35 Broy./Diag. 0.40E+00    6.6     0.00005236     -4911.5604950101 -2.08E-04
    36 Broy./Diag. 0.40E+00    7.7     0.00005562     -4911.5606147077 -1.20E-04
    37 Broy./Diag. 0.40E+00    7.1     0.00003025     -4911.5604180694  1.97E-04
    38 Broy./Diag. 0.40E+00    8.1     0.00002848     -4911.5604733050 -5.52E-05
    39 Broy./Diag. 0.40E+00    7.1     0.00001577     -4911.5604885009 -1.52E-05
    40 Broy./Diag. 0.40E+00    7.4     0.00002314     -4911.5605367362 -4.82E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00001449     -4911.5604796415  5.71E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00002182     -4911.5604871630 -7.52E-06
    43 Broy./Diag. 0.40E+00    6.9     0.00001677     -4911.5605631494 -7.60E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00002123     -4911.5605287430  3.44E-05
    45 Broy./Diag. 0.40E+00    7.1     0.00001896     -4911.5605216320  7.11E-06
    46 Broy./Diag. 0.40E+00    8.0     0.00001825     -4911.5605081400  1.35E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00000963     -4911.5605548196 -4.67E-05
    48 Broy./Diag. 0.40E+00    7.3     0.00001032     -4911.5605567851 -1.97E-06
    49 Broy./Diag. 0.40E+00    7.3     0.00000603     -4911.5605230497  3.37E-05
    50 Broy./Diag. 0.40E+00    7.1     0.00000672     -4911.5605486363 -2.56E-05
    51 Broy./Diag. 0.40E+00    7.1     0.00000894     -4911.5605509254 -2.29E-06
    52 Broy./Diag. 0.40E+00    7.3     0.00001223     -4911.5605553906 -4.47E-06
    53 Broy./Diag. 0.40E+00    6.6     0.00001000     -4911.5605287098  2.67E-05
    54 Broy./Diag. 0.40E+00    7.5     0.00000853     -4911.5605447463 -1.60E-05
    55 Broy./Diag. 0.40E+00    6.8     0.00000581     -4911.5605745043 -2.98E-05
    56 Broy./Diag. 0.40E+00    7.3     0.00000337     -4911.5605512281  2.33E-05
    57 Broy./Diag. 0.40E+00    7.6     0.00000437     -4911.5605528125 -1.58E-06
    58 Broy./Diag. 0.40E+00    7.1     0.00000275     -4911.5605542005 -1.39E-06
    59 Broy./Diag. 0.40E+00    6.8     0.00000390     -4911.5605630306 -8.83E-06
    60 Broy./Diag. 0.40E+00    6.6     0.00000448     -4911.5605572516  5.78E-06
    61 Broy./Diag. 0.40E+00    7.1     0.00000375     -4911.5605463352  1.09E-05
    62 Broy./Diag. 0.40E+00    7.1     0.00000269     -4911.5605645943 -1.83E-05
    63 Broy./Diag. 0.40E+00    8.1     0.00000434     -4911.5605652006 -6.06E-07
    64 Broy./Diag. 0.40E+00    7.2     0.00000249     -4911.5605631523  2.05E-06
    65 Broy./Diag. 0.40E+00    7.3     0.00000214     -4911.5605574744  5.68E-06
    66 Broy./Diag. 0.40E+00    7.4     0.00000167     -4911.5605620718 -4.60E-06
    67 Broy./Diag. 0.40E+00    7.1     0.00000147     -4911.5605669217 -4.85E-06
    68 Broy./Diag. 0.40E+00    7.7     0.00000111     -4911.5605601905  6.73E-06
    69 Broy./Diag. 0.40E+00    7.1     0.00000219     -4911.5605620376 -1.85E-06
    70 Broy./Diag. 0.40E+00    7.7     0.00000141     -4911.5605639218 -1.88E-06
    71 Broy./Diag. 0.40E+00    7.1     0.00000190     -4911.5605678112 -3.89E-06
    72 Broy./Diag. 0.40E+00    7.1     0.00000170     -4911.5605643046  3.51E-06
    73 Broy./Diag. 0.40E+00    7.1     0.00000113     -4911.5605606294  3.68E-06
    74 Broy./Diag. 0.40E+00    6.7     0.00000069     -4911.5605664997 -5.87E-06

  *** SCF run converged in    74 steps ***


  Electronic density on regular grids:      -1631.9999999995        0.0000000005
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000022
  Total charge density g-space grids:          -0.0000000022

  Overlap energy of the core charge distribution:               0.00008200134294
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.41927554908807
  Hartree energy:                                            1781.69178089172692
  Exchange-correlation energy:                               -779.34125974992344
  Electronic entropic energy:                                  -0.24002267434061
  Fermi energy:                                                 0.08660632717317

  Total energy:                                             -4911.56056649970287

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.560567410641852

 MD| ***************************************************************************
 MD| Step number                                                            1170
 MD| Time [fs]                                                       2340.000000
 MD| Conserved quantity [hartree]                            -0.491122352201E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    540.941939           593.593198
 MD| Energy drift per atom [K]           0.199371479629E+03   0.270164655927E+03
 MD| Potential energy [hartree]         -0.491156056741E+04  -0.491156396979E+04
 MD| Kinetic energy [hartree]            0.337045402954E+00   0.374519382993E+00
 MD| Temperature [K]                             898.146780           998.006129
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                932
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.6     0.01641444     -4911.5584323643 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.04030469     -4911.5260274798  3.24E-02
     3 Broy./Diag. 0.40E+00    6.9     0.05829561     -4911.6076228067 -8.16E-02
     4 Broy./Diag. 0.40E+00    7.3     0.03618101     -4911.5101968840  9.74E-02
     5 Broy./Diag. 0.40E+00    7.5     0.01451119     -4911.5715497343 -6.14E-02
     6 Broy./Diag. 0.40E+00    7.5     0.00653444     -4911.5506791598  2.09E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00473239     -4911.5603789973 -9.70E-03
     8 Broy./Diag. 0.40E+00    7.1     0.00310456     -4911.5532153151  7.16E-03
     9 Broy./Diag. 0.40E+00    7.1     0.00182934     -4911.5637030750 -1.05E-02
    10 Broy./Diag. 0.40E+00    7.3     0.00176051     -4911.5563765010  7.33E-03
    11 Broy./Diag. 0.40E+00    7.5     0.00147474     -4911.5548082024  1.57E-03
    12 Broy./Diag. 0.40E+00    7.1     0.00063163     -4911.5598168758 -5.01E-03
    13 Broy./Diag. 0.40E+00    7.3     0.00039412     -4911.5591995297  6.17E-04
    14 Broy./Diag. 0.40E+00    6.7     0.00054225     -4911.5596241278 -4.25E-04
    15 Broy./Diag. 0.40E+00    7.1     0.00041175     -4911.5580084694  1.62E-03
    16 Broy./Diag. 0.40E+00    7.1     0.00047608     -4911.5600644687 -2.06E-03
    17 Broy./Diag. 0.40E+00    6.8     0.00063148     -4911.5602640166 -2.00E-04
    18 Broy./Diag. 0.40E+00    8.2     0.00036555     -4911.5585293923  1.73E-03
    19 Broy./Diag. 0.40E+00    7.0     0.00026720     -4911.5595258989 -9.97E-04
    20 Broy./Diag. 0.40E+00   10.7     0.00026874     -4911.5596552958 -1.29E-04
    21 Broy./Diag. 0.40E+00    7.8     0.00023309     -4911.5603530657 -6.98E-04
    22 Broy./Diag. 0.40E+00   10.0     0.00010919     -4911.5594899724  8.63E-04
    23 Broy./Diag. 0.40E+00    8.5     0.00019342     -4911.5598355740 -3.46E-04
    24 Broy./Diag. 0.40E+00    7.5     0.00015977     -4911.5602663366 -4.31E-04
    25 Broy./Diag. 0.40E+00    7.6     0.00012597     -4911.5598666250  4.00E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00013987     -4911.5599761837 -1.10E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00017435     -4911.5597543156  2.22E-04
    28 Broy./Diag. 0.40E+00    8.5     0.00010151     -4911.5603470659 -5.93E-04
    29 Broy./Diag. 0.40E+00    7.0     0.00011089     -4911.5601167707  2.30E-04
    30 Broy./Diag. 0.40E+00    8.8     0.00007437     -4911.5599212805  1.95E-04
    31 Broy./Diag. 0.40E+00    8.5     0.00004762     -4911.5601860125 -2.65E-04
    32 Broy./Diag. 0.40E+00    7.7     0.00003354     -4911.5601107142  7.53E-05
    33 Broy./Diag. 0.40E+00   10.0     0.00008223     -4911.5601840859 -7.34E-05
    34 Broy./Diag. 0.40E+00    7.8     0.00007300     -4911.5599365176  2.48E-04
    35 Broy./Diag. 0.40E+00    6.9     0.00007207     -4911.5602078684 -2.71E-04
    36 Broy./Diag. 0.40E+00    7.4     0.00007062     -4911.5603070733 -9.92E-05
    37 Broy./Diag. 0.40E+00    8.0     0.00003448     -4911.5600696945  2.37E-04
    38 Broy./Diag. 0.40E+00    7.1     0.00002220     -4911.5601907735 -1.21E-04
    39 Broy./Diag. 0.40E+00    9.8     0.00002511     -4911.5601659299  2.48E-05
    40 Broy./Diag. 0.40E+00    7.7     0.00002763     -4911.5602395179 -7.36E-05
    41 Broy./Diag. 0.40E+00    7.9     0.00001873     -4911.5601565666  8.30E-05
    42 Broy./Diag. 0.40E+00   10.9     0.00002802     -4911.5601855118 -2.89E-05
    43 Broy./Diag. 0.40E+00    7.3     0.00002156     -4911.5602706545 -8.51E-05
    44 Broy./Diag. 0.40E+00    7.2     0.00002070     -4911.5601908497  7.98E-05
    45 Broy./Diag. 0.40E+00    7.2     0.00002077     -4911.5602275377 -3.67E-05
    46 Broy./Diag. 0.40E+00    6.9     0.00002210     -4911.5601884486  3.91E-05
    47 Broy./Diag. 0.40E+00    6.9     0.00001203     -4911.5602557426 -6.73E-05
    48 Broy./Diag. 0.40E+00    7.3     0.00001214     -4911.5602442868  1.15E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00000719     -4911.5602096462  3.46E-05
    50 Broy./Diag. 0.40E+00    7.3     0.00000811     -4911.5602485007 -3.89E-05
    51 Broy./Diag. 0.40E+00    8.0     0.00000840     -4911.5602309142  1.76E-05
    52 Broy./Diag. 0.40E+00    6.6     0.00001491     -4911.5602469581 -1.60E-05
    53 Broy./Diag. 0.40E+00    6.7     0.00001141     -4911.5602094691  3.75E-05
    54 Broy./Diag. 0.40E+00    7.1     0.00001058     -4911.5602381913 -2.87E-05
    55 Broy./Diag. 0.40E+00    7.8     0.00000717     -4911.5602686397 -3.04E-05
    56 Broy./Diag. 0.40E+00    7.3     0.00000416     -4911.5602341338  3.45E-05
    57 Broy./Diag. 0.40E+00    7.3     0.00000315     -4911.5602461771 -1.20E-05
    58 Broy./Diag. 0.40E+00    7.1     0.00000327     -4911.5602430175  3.16E-06
    59 Broy./Diag. 0.40E+00    7.0     0.00000468     -4911.5602531134 -1.01E-05
    60 Broy./Diag. 0.40E+00    7.1     0.00000587     -4911.5602416217  1.15E-05
    61 Broy./Diag. 0.40E+00    6.7     0.00000441     -4911.5602343488  7.27E-06
    62 Broy./Diag. 0.40E+00    7.3     0.00000357     -4911.5602592359 -2.49E-05
    63 Broy./Diag. 0.40E+00    7.2     0.00000345     -4911.5602498457  9.39E-06
    64 Broy./Diag. 0.40E+00    7.1     0.00000278     -4911.5602530750 -3.23E-06
    65 Broy./Diag. 0.40E+00    7.9     0.00000195     -4911.5602465916  6.48E-06
    66 Broy./Diag. 0.40E+00    7.1     0.00000182     -4911.5602526270 -6.04E-06
    67 Broy./Diag. 0.40E+00    8.2     0.00000154     -4911.5602550009 -2.37E-06
    68 Broy./Diag. 0.40E+00    7.2     0.00000116     -4911.5602465952  8.41E-06
    69 Broy./Diag. 0.40E+00    7.1     0.00000182     -4911.5602525106 -5.92E-06
    70 Broy./Diag. 0.40E+00    7.3     0.00000212     -4911.5602513679  1.14E-06
    71 Broy./Diag. 0.40E+00    8.3     0.00000196     -4911.5602563060 -4.94E-06
    72 Broy./Diag. 0.40E+00    7.1     0.00000201     -4911.5602508862  5.42E-06
    73 Broy./Diag. 0.40E+00    7.5     0.00000115     -4911.5602495813  1.30E-06
    74 Broy./Diag. 0.40E+00    7.1     0.00000071     -4911.5602562246 -6.64E-06

  *** SCF run converged in    74 steps ***


  Electronic density on regular grids:      -1631.9999999995        0.0000000005
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000022
  Total charge density g-space grids:          -0.0000000022

  Overlap energy of the core charge distribution:               0.00008200592201
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.40787923889729
  Hartree energy:                                            1781.69930286353338
  Exchange-correlation energy:                               -779.33671086524600
  Electronic entropic energy:                                  -0.24038693790649
  Fermi energy:                                                 0.08657940010886

  Total energy:                                             -4911.56025622457400

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.560255056033384

 MD| ***************************************************************************
 MD| Step number                                                            1171
 MD| Time [fs]                                                       2342.000000
 MD| Conserved quantity [hartree]                            -0.491121064459E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    568.060786           593.571394
 MD| Energy drift per atom [K]           0.226123866617E+03   0.270127046372E+03
 MD| Potential energy [hartree]         -0.491156025506E+04  -0.491156396662E+04
 MD| Kinetic energy [hartree]            0.349610468522E+00   0.374498111503E+00
 MD| Temperature [K]                             931.629727           997.949446
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                932
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.01830470     -4911.5581472826 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.05535357     -4911.5663694463 -8.22E-03
     3 Broy./Diag. 0.40E+00    7.7     0.05269477     -4911.4889908813  7.74E-02
     4 Broy./Diag. 0.40E+00    7.3     0.03584197     -4911.5705794238 -8.16E-02
     5 Broy./Diag. 0.40E+00    7.6     0.01669606     -4911.5839596042 -1.34E-02
     6 Broy./Diag. 0.40E+00    6.7     0.00732664     -4911.5423228043  4.16E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00583748     -4911.5685919044 -2.63E-02
     8 Broy./Diag. 0.40E+00    7.1     0.00313814     -4911.5501952768  1.84E-02
     9 Broy./Diag. 0.40E+00    6.9     0.00195050     -4911.5637184915 -1.35E-02
    10 Broy./Diag. 0.40E+00    6.7     0.00179271     -4911.5545465082  9.17E-03
    11 Broy./Diag. 0.40E+00    7.3     0.00159314     -4911.5566813161 -2.13E-03
    12 Broy./Diag. 0.40E+00    7.1     0.00079039     -4911.5605039775 -3.82E-03
    13 Broy./Diag. 0.40E+00    7.2     0.00047268     -4911.5583731319  2.13E-03
    14 Broy./Diag. 0.40E+00    6.7     0.00057637     -4911.5603396164 -1.97E-03
    15 Broy./Diag. 0.40E+00    7.1     0.00033662     -4911.5581771171  2.16E-03
    16 Broy./Diag. 0.40E+00    7.3     0.00049286     -4911.5599455631 -1.77E-03
    17 Broy./Diag. 0.40E+00    7.6     0.00062229     -4911.5595485733  3.97E-04
    18 Broy./Diag. 0.40E+00    7.1     0.00039220     -4911.5587974085  7.51E-04
    19 Broy./Diag. 0.40E+00    7.3     0.00028656     -4911.5598634615 -1.07E-03
    20 Broy./Diag. 0.40E+00    7.3     0.00035881     -4911.5590166350  8.47E-04
    21 Broy./Diag. 0.40E+00    7.5     0.00021597     -4911.5603446556 -1.33E-03
    22 Broy./Diag. 0.40E+00    6.9     0.00011340     -4911.5594764835  8.68E-04
    23 Broy./Diag. 0.40E+00    6.9     0.00021867     -4911.5597590367 -2.83E-04
    24 Broy./Diag. 0.40E+00    7.2     0.00019796     -4911.5600603197 -3.01E-04
    25 Broy./Diag. 0.40E+00    7.5     0.00012189     -4911.5597528003  3.08E-04
    26 Broy./Diag. 0.40E+00    6.9     0.00020097     -4911.5600252548 -2.72E-04
    27 Broy./Diag. 0.40E+00    7.4     0.00019256     -4911.5593436920  6.82E-04
    28 Broy./Diag. 0.40E+00    7.5     0.00009039     -4911.5601274340 -7.84E-04
    29 Broy./Diag. 0.40E+00    7.3     0.00010748     -4911.5599773016  1.50E-04
    30 Broy./Diag. 0.40E+00    7.3     0.00008877     -4911.5598170344  1.60E-04
    31 Broy./Diag. 0.40E+00    6.7     0.00004639     -4911.5599880843 -1.71E-04
    32 Broy./Diag. 0.40E+00    7.1     0.00004249     -4911.5599125723  7.55E-05
    33 Broy./Diag. 0.40E+00    7.3     0.00007740     -4911.5600678454 -1.55E-04
    34 Broy./Diag. 0.40E+00    6.8     0.00005932     -4911.5597705015  2.97E-04
    35 Broy./Diag. 0.40E+00    7.2     0.00007365     -4911.5599607490 -1.90E-04
    36 Broy./Diag. 0.40E+00    6.9     0.00008263     -4911.5600919366 -1.31E-04
    37 Broy./Diag. 0.40E+00    7.1     0.00004320     -4911.5599433735  1.49E-04
    38 Broy./Diag. 0.40E+00    6.9     0.00002752     -4911.5600135066 -7.01E-05
    39 Broy./Diag. 0.40E+00    6.9     0.00002957     -4911.5599361681  7.73E-05
    40 Broy./Diag. 0.40E+00    7.3     0.00002223     -4911.5600596762 -1.24E-04
    41 Broy./Diag. 0.40E+00    6.6     0.00001707     -4911.5599952880  6.44E-05
    42 Broy./Diag. 0.40E+00    7.0     0.00003303     -4911.5599880116  7.28E-06
    43 Broy./Diag. 0.40E+00    7.1     0.00002988     -4911.5600553090 -6.73E-05
    44 Broy./Diag. 0.40E+00    7.3     0.00001988     -4911.5600216997  3.36E-05
    45 Broy./Diag. 0.40E+00    7.1     0.00002578     -4911.5600617407 -4.00E-05
    46 Broy./Diag. 0.40E+00    7.0     0.00002208     -4911.5599665768  9.52E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00001324     -4911.5600383618 -7.18E-05
    48 Broy./Diag. 0.40E+00    6.7     0.00001112     -4911.5600503102 -1.19E-05
    49 Broy./Diag. 0.40E+00    7.6     0.00000870     -4911.5600244090  2.59E-05
    50 Broy./Diag. 0.40E+00    7.9     0.00000721     -4911.5600377410 -1.33E-05
    51 Broy./Diag. 0.40E+00    8.0     0.00000934     -4911.5600279372  9.80E-06
    52 Broy./Diag. 0.40E+00    7.3     0.00001298     -4911.5600614997 -3.36E-05
    53 Broy./Diag. 0.40E+00    7.3     0.00001169     -4911.5600183889  4.31E-05
    54 Broy./Diag. 0.40E+00    7.1     0.00001116     -4911.5600199135 -1.52E-06
    55 Broy./Diag. 0.40E+00    7.3     0.00000828     -4911.5600522723 -3.24E-05
    56 Broy./Diag. 0.40E+00    7.1     0.00000391     -4911.5600410576  1.12E-05
    57 Broy./Diag. 0.40E+00    7.2     0.00000400     -4911.5600448016 -3.74E-06
    58 Broy./Diag. 0.40E+00    7.1     0.00000347     -4911.5600332869  1.15E-05
    59 Broy./Diag. 0.40E+00    7.8     0.00000413     -4911.5600489045 -1.56E-05
    60 Broy./Diag. 0.40E+00    7.1     0.00000450     -4911.5600469028  2.00E-06
    61 Broy./Diag. 0.40E+00    7.4     0.00000481     -4911.5600349218  1.20E-05
    62 Broy./Diag. 0.40E+00    6.9     0.00000350     -4911.5600439814 -9.06E-06
    63 Broy./Diag. 0.40E+00    6.9     0.00000410     -4911.5600437731  2.08E-07
    64 Broy./Diag. 0.40E+00    7.5     0.00000308     -4911.5600538277 -1.01E-05
    65 Broy./Diag. 0.40E+00    6.7     0.00000204     -4911.5600408612  1.30E-05
    66 Broy./Diag. 0.40E+00    6.9     0.00000178     -4911.5600433753 -2.51E-06
    67 Broy./Diag. 0.40E+00    7.3     0.00000154     -4911.5600489418 -5.57E-06
    68 Broy./Diag. 0.40E+00    7.3     0.00000125     -4911.5600456748  3.27E-06
    69 Broy./Diag. 0.40E+00    7.1     0.00000219     -4911.5600456157  5.91E-08
    70 Broy./Diag. 0.40E+00    6.9     0.00000242     -4911.5600408148  4.80E-06
    71 Broy./Diag. 0.40E+00    7.1     0.00000154     -4911.5600512949 -1.05E-05
    72 Broy./Diag. 0.40E+00    7.8     0.00000177     -4911.5600483103  2.98E-06
    73 Broy./Diag. 0.40E+00    6.5     0.00000140     -4911.5600429723  5.34E-06
    74 Broy./Diag. 0.40E+00    6.9     0.00000085     -4911.5600466678 -3.70E-06

  *** SCF run converged in    74 steps ***


  Electronic density on regular grids:      -1631.9999999995        0.0000000005
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000022
  Total charge density g-space grids:          -0.0000000022

  Overlap energy of the core charge distribution:               0.00008203120912
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.40445587972090
  Hartree energy:                                            1781.70178436165861
  Exchange-correlation energy:                               -779.33519476269498
  Electronic entropic energy:                                  -0.24075166442914
  Fermi energy:                                                 0.08656978148467

  Total energy:                                             -4911.56004666782974

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.560047698400012

 MD| ***************************************************************************
 MD| Step number                                                            1172
 MD| Time [fs]                                                       2344.000000
 MD| Conserved quantity [hartree]                            -0.491119418334E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    538.103662           593.524067
 MD| Energy drift per atom [K]           0.260321533778E+03   0.270118679894E+03
 MD| Potential energy [hartree]         -0.491156004770E+04  -0.491156396327E+04
 MD| Kinetic energy [hartree]            0.365864360843E+00   0.374490744821E+00
 MD| Temperature [K]                             974.942529           997.929815
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                932
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02217240     -4911.5583787848 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.7     0.05961110     -4911.5866716297 -2.83E-02
     3 Broy./Diag. 0.40E+00    7.3     0.06197624     -4911.4533456424  1.33E-01
     4 Broy./Diag. 0.40E+00    6.9     0.03551918     -4911.5839228488 -1.31E-01
     5 Broy./Diag. 0.40E+00    7.5     0.01627101     -4911.5840274581 -1.05E-04
     6 Broy./Diag. 0.40E+00    6.7     0.00877861     -4911.5463592666  3.77E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00589292     -4911.5683656659 -2.20E-02
     8 Broy./Diag. 0.40E+00    6.9     0.00257815     -4911.5537782767  1.46E-02
     9 Broy./Diag. 0.40E+00    6.9     0.00216707     -4911.5669540522 -1.32E-02
    10 Broy./Diag. 0.40E+00    6.9     0.00217177     -4911.5543559305  1.26E-02
    11 Broy./Diag. 0.40E+00    7.4     0.00169031     -4911.5575296262 -3.17E-03
    12 Broy./Diag. 0.40E+00    7.5     0.00092499     -4911.5614534890 -3.92E-03
    13 Broy./Diag. 0.40E+00    7.1     0.00071497     -4911.5592999624  2.15E-03
    14 Broy./Diag. 0.40E+00    7.2     0.00055118     -4911.5609930470 -1.69E-03
    15 Broy./Diag. 0.40E+00    7.3     0.00028126     -4911.5590503540  1.94E-03
    16 Broy./Diag. 0.40E+00    6.9     0.00052845     -4911.5608237174 -1.77E-03
    17 Broy./Diag. 0.40E+00    7.2     0.00049894     -4911.5599056332  9.18E-04
    18 Broy./Diag. 0.40E+00    6.6     0.00037004     -4911.5593709590  5.35E-04
    19 Broy./Diag. 0.40E+00    7.5     0.00033223     -4911.5603396014 -9.69E-04
    20 Broy./Diag. 0.40E+00    6.8     0.00031294     -4911.5597564682  5.83E-04
    21 Broy./Diag. 0.40E+00    7.5     0.00020213     -4911.5608363973 -1.08E-03
    22 Broy./Diag. 0.40E+00    7.8     0.00014186     -4911.5597612287  1.08E-03
    23 Broy./Diag. 0.40E+00    6.9     0.00019698     -4911.5603372920 -5.76E-04
    24 Broy./Diag. 0.40E+00    7.3     0.00019429     -4911.5605037028 -1.66E-04
    25 Broy./Diag. 0.40E+00    7.3     0.00014392     -4911.5599955215  5.08E-04
    26 Broy./Diag. 0.40E+00    7.0     0.00016511     -4911.5603780234 -3.83E-04
    27 Broy./Diag. 0.40E+00    6.9     0.00014911     -4911.5598319044  5.46E-04
    28 Broy./Diag. 0.40E+00    6.9     0.00009694     -4911.5605530249 -7.21E-04
    29 Broy./Diag. 0.40E+00    7.2     0.00009554     -4911.5601823982  3.71E-04
    30 Broy./Diag. 0.40E+00    7.5     0.00007685     -4911.5601529586  2.94E-05
    31 Broy./Diag. 0.40E+00    7.5     0.00005534     -4911.5603709986 -2.18E-04
    32 Broy./Diag. 0.40E+00    7.1     0.00005454     -4911.5602038910  1.67E-04
    33 Broy./Diag. 0.40E+00    7.2     0.00006750     -4911.5603801436 -1.76E-04
    34 Broy./Diag. 0.40E+00    6.9     0.00005437     -4911.5600922038  2.88E-04
    35 Broy./Diag. 0.40E+00    7.1     0.00006742     -4911.5603451030 -2.53E-04
    36 Broy./Diag. 0.40E+00    6.8     0.00006962     -4911.5603465847 -1.48E-06
    37 Broy./Diag. 0.40E+00    7.3     0.00004398     -4911.5601697309  1.77E-04
    38 Broy./Diag. 0.40E+00    7.0     0.00003089     -4911.5603337362 -1.64E-04
    39 Broy./Diag. 0.40E+00    7.5     0.00002946     -4911.5602370802  9.67E-05
    40 Broy./Diag. 0.40E+00    7.3     0.00002716     -4911.5603533653 -1.16E-04
    41 Broy./Diag. 0.40E+00    7.7     0.00002135     -4911.5602404764  1.13E-04
    42 Broy./Diag. 0.40E+00    6.9     0.00002952     -4911.5602794582 -3.90E-05
    43 Broy./Diag. 0.40E+00    6.9     0.00002900     -4911.5603433207 -6.39E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00002324     -4911.5602278185  1.16E-04
    45 Broy./Diag. 0.40E+00    7.2     0.00002144     -4911.5603155953 -8.78E-05
    46 Broy./Diag. 0.40E+00    7.5     0.00001945     -4911.5602405725  7.50E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00001350     -4911.5603203739 -7.98E-05
    48 Broy./Diag. 0.40E+00    7.3     0.00001275     -4911.5602957680  2.46E-05
    49 Broy./Diag. 0.40E+00    7.0     0.00000918     -4911.5602699768  2.58E-05
    50 Broy./Diag. 0.40E+00    6.9     0.00000885     -4911.5603087710 -3.88E-05
    51 Broy./Diag. 0.40E+00    7.0     0.00000964     -4911.5602728697  3.59E-05
    52 Broy./Diag. 0.40E+00    7.5     0.00001230     -4911.5603019548 -2.91E-05
    53 Broy./Diag. 0.40E+00    7.5     0.00001092     -4911.5602580134  4.39E-05
    54 Broy./Diag. 0.40E+00    7.2     0.00001087     -4911.5602880796 -3.01E-05
    55 Broy./Diag. 0.40E+00    7.2     0.00000815     -4911.5603084809 -2.04E-05
    56 Broy./Diag. 0.40E+00    7.1     0.00000543     -4911.5602717638  3.67E-05
    57 Broy./Diag. 0.40E+00    7.1     0.00000435     -4911.5602971177 -2.54E-05
    58 Broy./Diag. 0.40E+00    7.2     0.00000365     -4911.5602842780  1.28E-05
    59 Broy./Diag. 0.40E+00    8.2     0.00000498     -4911.5602956470 -1.14E-05
    60 Broy./Diag. 0.40E+00    7.5     0.00000543     -4911.5602834217  1.22E-05
    61 Broy./Diag. 0.40E+00    7.3     0.00000452     -4911.5602795075  3.91E-06
    62 Broy./Diag. 0.40E+00    7.3     0.00000424     -4911.5602983004 -1.88E-05
    63 Broy./Diag. 0.40E+00    6.9     0.00000450     -4911.5602779173  2.04E-05
    64 Broy./Diag. 0.40E+00    6.9     0.00000285     -4911.5602915222 -1.36E-05
    65 Broy./Diag. 0.40E+00    7.3     0.00000238     -4911.5602830268  8.50E-06
    66 Broy./Diag. 0.40E+00    7.7     0.00000228     -4911.5602892042 -6.18E-06
    67 Broy./Diag. 0.40E+00    7.6     0.00000175     -4911.5602905884 -1.38E-06
    68 Broy./Diag. 0.40E+00    7.1     0.00000140     -4911.5602836023  6.99E-06
    69 Broy./Diag. 0.40E+00    7.1     0.00000201     -4911.5602904371 -6.83E-06
    70 Broy./Diag. 0.40E+00    7.3     0.00000184     -4911.5602844714  5.97E-06
    71 Broy./Diag. 0.40E+00    7.4     0.00000199     -4911.5602892699 -4.80E-06
    72 Broy./Diag. 0.40E+00    7.0     0.00000206     -4911.5602844095  4.86E-06
    73 Broy./Diag. 0.40E+00    7.3     0.00000146     -4911.5602845273 -1.18E-07
    74 Broy./Diag. 0.40E+00    7.1     0.00000092     -4911.5602901152 -5.59E-06

  *** SCF run converged in    74 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008205960093
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.40471361561595
  Hartree energy:                                            1781.70166720971201
  Exchange-correlation energy:                               -779.33528249050335
  Electronic entropic energy:                                  -0.24104796742586
  Fermi energy:                                                 0.08657451396166

  Total energy:                                             -4911.56029011524151

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.560286106804597

 MD| ***************************************************************************
 MD| Step number                                                            1173
 MD| Time [fs]                                                       2346.000000
 MD| Conserved quantity [hartree]                            -0.491119271040E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    542.157376           593.480276
 MD| Energy drift per atom [K]           0.263381506507E+03   0.270112936353E+03
 MD| Potential energy [hartree]         -0.491156028611E+04  -0.491156396014E+04
 MD| Kinetic energy [hartree]            0.367575705273E+00   0.374484849647E+00
 MD| Temperature [K]                             979.502860           997.914106
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02640745     -4911.5588711985 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.9     0.06309813     -4911.5768985324 -1.80E-02
     3 Broy./Diag. 0.40E+00    7.1     0.05619659     -4911.5208754090  5.60E-02
     4 Broy./Diag. 0.40E+00    7.1     0.03407295     -4911.5519232059 -3.10E-02
     5 Broy./Diag. 0.40E+00    7.3     0.01816190     -4911.5936379589 -4.17E-02
     6 Broy./Diag. 0.40E+00    7.3     0.00819506     -4911.5511383691  4.25E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00531819     -4911.5633265678 -1.22E-02
     8 Broy./Diag. 0.40E+00    8.1     0.00285534     -4911.5580032319  5.32E-03
     9 Broy./Diag. 0.40E+00    7.0     0.00226615     -4911.5696098343 -1.16E-02
    10 Broy./Diag. 0.40E+00    7.5     0.00190295     -4911.5573837216  1.22E-02
    11 Broy./Diag. 0.40E+00    7.3     0.00195036     -4911.5577091571 -3.25E-04
    12 Broy./Diag. 0.40E+00    7.1     0.00091574     -4911.5626709794 -4.96E-03
    13 Broy./Diag. 0.40E+00    7.6     0.00062611     -4911.5607711279  1.90E-03
    14 Broy./Diag. 0.40E+00    7.3     0.00051937     -4911.5613784725 -6.07E-04
    15 Broy./Diag. 0.40E+00    7.1     0.00031873     -4911.5601329199  1.25E-03
    16 Broy./Diag. 0.40E+00    7.1     0.00042946     -4911.5618289350 -1.70E-03
    17 Broy./Diag. 0.40E+00    7.1     0.00048383     -4911.5611706107  6.58E-04
    18 Broy./Diag. 0.40E+00    6.9     0.00032114     -4911.5602895628  8.81E-04
    19 Broy./Diag. 0.40E+00    6.7     0.00024728     -4911.5611806226 -8.91E-04
    20 Broy./Diag. 0.40E+00    7.3     0.00025795     -4911.5609120447  2.69E-04
    21 Broy./Diag. 0.40E+00    7.3     0.00023470     -4911.5615035208 -5.91E-04
    22 Broy./Diag. 0.40E+00    7.5     0.00016834     -4911.5604129659  1.09E-03
    23 Broy./Diag. 0.40E+00    7.3     0.00021045     -4911.5610906713 -6.78E-04
    24 Broy./Diag. 0.40E+00    7.1     0.00019040     -4911.5613701905 -2.80E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00012024     -4911.5607110905  6.59E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00012833     -4911.5610166948 -3.06E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00013587     -4911.5607424047  2.74E-04
    28 Broy./Diag. 0.40E+00    7.3     0.00010135     -4911.5612775431 -5.35E-04
    29 Broy./Diag. 0.40E+00    7.1     0.00009689     -4911.5608606953  4.17E-04
    30 Broy./Diag. 0.40E+00    7.3     0.00008187     -4911.5608034592  5.72E-05
    31 Broy./Diag. 0.40E+00    7.5     0.00005420     -4911.5610898159 -2.86E-04
    32 Broy./Diag. 0.40E+00    7.3     0.00005545     -4911.5609053393  1.84E-04
    33 Broy./Diag. 0.40E+00    7.1     0.00007384     -4911.5610029902 -9.77E-05
    34 Broy./Diag. 0.40E+00    6.7     0.00006366     -4911.5607442695  2.59E-04
    35 Broy./Diag. 0.40E+00    7.1     0.00006536     -4911.5610316215 -2.87E-04
    36 Broy./Diag. 0.40E+00    6.9     0.00006468     -4911.5610357349 -4.11E-06
    37 Broy./Diag. 0.40E+00    7.1     0.00003749     -4911.5608062103  2.30E-04
    38 Broy./Diag. 0.40E+00    7.3     0.00002698     -4911.5609636692 -1.57E-04
    39 Broy./Diag. 0.40E+00    8.1     0.00003246     -4911.5609050453  5.86E-05
    40 Broy./Diag. 0.40E+00    7.5     0.00003776     -4911.5609983014 -9.33E-05
    41 Broy./Diag. 0.40E+00    9.4     0.00002766     -4911.5608373761  1.61E-04
    42 Broy./Diag. 0.40E+00    7.5     0.00003408     -4911.5608860568 -4.87E-05
    43 Broy./Diag. 0.40E+00    8.2     0.00002710     -4911.5609968399 -1.11E-04
    44 Broy./Diag. 0.40E+00   10.7     0.00002012     -4911.5608690799  1.28E-04
    45 Broy./Diag. 0.40E+00    7.3     0.00002123     -4911.5609174504 -4.84E-05
    46 Broy./Diag. 0.40E+00    7.5     0.00002127     -4911.5608597912  5.77E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00001472     -4911.5609471520 -8.74E-05
    48 Broy./Diag. 0.40E+00    7.5     0.00001585     -4911.5609138333  3.33E-05
    49 Broy./Diag. 0.40E+00    7.2     0.00001255     -4911.5608647871  4.90E-05
    50 Broy./Diag. 0.40E+00    7.3     0.00001022     -4911.5609225766 -5.78E-05
    51 Broy./Diag. 0.40E+00    8.2     0.00001179     -4911.5608940142  2.86E-05
    52 Broy./Diag. 0.40E+00    8.8     0.00001565     -4911.5609171801 -2.32E-05
    53 Broy./Diag. 0.40E+00    7.2     0.00001211     -4911.5608549031  6.23E-05
    54 Broy./Diag. 0.40E+00   10.0     0.00001156     -4911.5608917261 -3.68E-05
    55 Broy./Diag. 0.40E+00    8.1     0.00000972     -4911.5609247490 -3.30E-05
    56 Broy./Diag. 0.40E+00    6.8     0.00000573     -4911.5608788945  4.59E-05
    57 Broy./Diag. 0.40E+00    6.9     0.00000570     -4911.5608966304 -1.77E-05
    58 Broy./Diag. 0.40E+00    7.8     0.00000615     -4911.5608849524  1.17E-05
    59 Broy./Diag. 0.40E+00    8.1     0.00000698     -4911.5609058439 -2.09E-05
    60 Broy./Diag. 0.40E+00    8.0     0.00000755     -4911.5608851669  2.07E-05
    61 Broy./Diag. 0.40E+00    9.1     0.00000656     -4911.5608695409  1.56E-05
    62 Broy./Diag. 0.40E+00    7.4     0.00000423     -4911.5609006698 -3.11E-05
    63 Broy./Diag. 0.40E+00   11.0     0.00000448     -4911.5608855554  1.51E-05
    64 Broy./Diag. 0.40E+00    7.8     0.00000397     -4911.5608928917 -7.34E-06
    65 Broy./Diag. 0.40E+00    6.9     0.00000331     -4911.5608782514  1.46E-05
    66 Broy./Diag. 0.40E+00    6.9     0.00000336     -4911.5608892826 -1.10E-05
    67 Broy./Diag. 0.40E+00    7.1     0.00000307     -4911.5608940111 -4.73E-06
    68 Broy./Diag. 0.40E+00    7.3     0.00000201     -4911.5608784455  1.56E-05
    69 Broy./Diag. 0.40E+00    7.4     0.00000261     -4911.5608862459 -7.80E-06
    70 Broy./Diag. 0.40E+00    7.1     0.00000269     -4911.5608820815  4.16E-06
    71 Broy./Diag. 0.40E+00    7.3     0.00000275     -4911.5608906180 -8.54E-06
    72 Broy./Diag. 0.40E+00    7.3     0.00000265     -4911.5608810011  9.62E-06
    73 Broy./Diag. 0.40E+00    7.1     0.00000198     -4911.5608786694  2.33E-06
    74 Broy./Diag. 0.40E+00    7.3     0.00000127     -4911.5608888191 -1.01E-05
    75 Broy./Diag. 0.40E+00    7.1     0.00000124     -4911.5608831172  5.70E-06
    76 Broy./Diag. 0.40E+00    7.3     0.00000139     -4911.5608845091 -1.39E-06
    77 Broy./Diag. 0.40E+00    7.7     0.00000125     -4911.5608800018  4.51E-06
    78 Broy./Diag. 0.40E+00    7.3     0.00000159     -4911.5608847061 -4.70E-06
    79 Broy./Diag. 0.40E+00    6.9     0.00000137     -4911.5608857609 -1.05E-06
    80 Broy./Diag. 0.40E+00    6.9     0.00000117     -4911.5608780031  7.76E-06
    81 Broy./Diag. 0.40E+00    7.3     0.00000087     -4911.5608826361 -4.63E-06

  *** SCF run converged in    81 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008208200030
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.40445865409856
  Hartree energy:                                            1781.70163319273797
  Exchange-correlation energy:                               -779.33535059104588
  Electronic entropic energy:                                  -0.24128344732743
  Fermi energy:                                                 0.08658135578343

  Total energy:                                             -4911.56088263611036

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.560880168238327

 MD| ***************************************************************************
 MD| Step number                                                            1174
 MD| Time [fs]                                                       2348.000000
 MD| Conserved quantity [hartree]                            -0.491117447566E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    614.660909           593.498317
 MD| Energy drift per atom [K]           0.301263537559E+03   0.270139470085E+03
 MD| Potential energy [hartree]         -0.491156088017E+04  -0.491156395751E+04
 MD| Kinetic energy [hartree]            0.386404507077E+00   0.374495002677E+00
 MD| Temperature [K]                            1029.677191           997.941161
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.02838083     -4911.5588489367 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.06149962     -4911.5724079644 -1.36E-02
     3 Broy./Diag. 0.40E+00    7.2     0.07411161     -4911.5356564893  3.68E-02
     4 Broy./Diag. 0.40E+00    6.7     0.03957077     -4911.5472667010 -1.16E-02
     5 Broy./Diag. 0.40E+00    7.1     0.01494271     -4911.5939085825 -4.66E-02
     6 Broy./Diag. 0.40E+00    6.9     0.00924847     -4911.5490317804  4.49E-02
     7 Broy./Diag. 0.40E+00    7.6     0.00629335     -4911.5559802429 -6.95E-03
     8 Broy./Diag. 0.40E+00    7.3     0.00349371     -4911.5646851817 -8.70E-03
     9 Broy./Diag. 0.40E+00    7.4     0.00189548     -4911.5676526958 -2.97E-03
    10 Broy./Diag. 0.40E+00    7.3     0.00199762     -4911.5578000181  9.85E-03
    11 Broy./Diag. 0.40E+00    6.8     0.00150594     -4911.5591704134 -1.37E-03
    12 Broy./Diag. 0.40E+00    7.0     0.00082791     -4911.5633316604 -4.16E-03
    13 Broy./Diag. 0.40E+00    7.6     0.00072418     -4911.5609625150  2.37E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00063612     -4911.5604124894  5.50E-04
    15 Broy./Diag. 0.40E+00    6.9     0.00024317     -4911.5608758155 -4.63E-04
    16 Broy./Diag. 0.40E+00    7.1     0.00035731     -4911.5621562198 -1.28E-03
    17 Broy./Diag. 0.40E+00    6.9     0.00032079     -4911.5609807146  1.18E-03
    18 Broy./Diag. 0.40E+00    7.4     0.00032939     -4911.5605504401  4.30E-04
    19 Broy./Diag. 0.40E+00    7.1     0.00024483     -4911.5615704385 -1.02E-03
    20 Broy./Diag. 0.40E+00    7.3     0.00029967     -4911.5613218588  2.49E-04
    21 Broy./Diag. 0.40E+00    7.0     0.00021068     -4911.5612065754  1.15E-04
    22 Broy./Diag. 0.40E+00    6.9     0.00018668     -4911.5604871393  7.19E-04
    23 Broy./Diag. 0.40E+00    7.5     0.00018159     -4911.5613945856 -9.07E-04
    24 Broy./Diag. 0.40E+00    6.5     0.00018320     -4911.5614518263 -5.72E-05
    25 Broy./Diag. 0.40E+00    7.1     0.00012376     -4911.5607886696  6.63E-04
    26 Broy./Diag. 0.40E+00    7.3     0.00010586     -4911.5610904620 -3.02E-04
    27 Broy./Diag. 0.40E+00    6.9     0.00008736     -4911.5611335853 -4.31E-05
    28 Broy./Diag. 0.40E+00    7.3     0.00008683     -4911.5613190996 -1.86E-04
    29 Broy./Diag. 0.40E+00    6.9     0.00008927     -4911.5609078006  4.11E-04
    30 Broy./Diag. 0.40E+00    6.9     0.00007861     -4911.5610129562 -1.05E-04
    31 Broy./Diag. 0.40E+00    7.3     0.00007437     -4911.5612722356 -2.59E-04
    32 Broy./Diag. 0.40E+00    7.1     0.00006984     -4911.5610514326  2.21E-04
    33 Broy./Diag. 0.40E+00    7.5     0.00006822     -4911.5610202228  3.12E-05
    34 Broy./Diag. 0.40E+00    7.1     0.00005812     -4911.5609231802  9.70E-05
    35 Broy./Diag. 0.40E+00    7.1     0.00005778     -4911.5612030428 -2.80E-04
    36 Broy./Diag. 0.40E+00    7.7     0.00004081     -4911.5610956700  1.07E-04
    37 Broy./Diag. 0.40E+00    7.3     0.00004056     -4911.5609606142  1.35E-04
    38 Broy./Diag. 0.40E+00    7.1     0.00002987     -4911.5610976829 -1.37E-04
    39 Broy./Diag. 0.40E+00    7.1     0.00003435     -4911.5610763658  2.13E-05
    40 Broy./Diag. 0.40E+00    7.1     0.00004199     -4911.5611067637 -3.04E-05
    41 Broy./Diag. 0.40E+00    6.9     0.00004096     -4911.5609124248  1.94E-04
    42 Broy./Diag. 0.40E+00    7.1     0.00002616     -4911.5610359033 -1.23E-04
    43 Broy./Diag. 0.40E+00    7.1     0.00002768     -4911.5611108714 -7.50E-05
    44 Broy./Diag. 0.40E+00    6.8     0.00001905     -4911.5610018816  1.09E-04
    45 Broy./Diag. 0.40E+00    7.3     0.00001514     -4911.5610250385 -2.32E-05
    46 Broy./Diag. 0.40E+00    6.9     0.00001401     -4911.5610134528  1.16E-05
    47 Broy./Diag. 0.40E+00    7.5     0.00001819     -4911.5610705708 -5.71E-05
    48 Broy./Diag. 0.40E+00    7.1     0.00001257     -4911.5610125598  5.80E-05
    49 Broy./Diag. 0.40E+00    7.3     0.00001492     -4911.5609881422  2.44E-05
    50 Broy./Diag. 0.40E+00    7.1     0.00001318     -4911.5610498578 -6.17E-05
    51 Broy./Diag. 0.40E+00    7.3     0.00001128     -4911.5610259290  2.39E-05
    52 Broy./Diag. 0.40E+00    6.8     0.00001006     -4911.5610282046 -2.28E-06
    53 Broy./Diag. 0.40E+00    7.3     0.00001148     -4911.5609876376  4.06E-05
    54 Broy./Diag. 0.40E+00    7.3     0.00000669     -4911.5610279268 -4.03E-05
    55 Broy./Diag. 0.40E+00    7.0     0.00000692     -4911.5610359629 -8.04E-06
    56 Broy./Diag. 0.40E+00    6.9     0.00000681     -4911.5610020082  3.40E-05
    57 Broy./Diag. 0.40E+00    7.3     0.00000558     -4911.5610180231 -1.60E-05
    58 Broy./Diag. 0.40E+00    7.1     0.00000595     -4911.5610158925  2.13E-06
    59 Broy./Diag. 0.40E+00    7.1     0.00000876     -4911.5610315028 -1.56E-05
    60 Broy./Diag. 0.40E+00    7.4     0.00000573     -4911.5610006891  3.08E-05
    61 Broy./Diag. 0.40E+00    7.3     0.00000468     -4911.5610009404 -2.51E-07
    62 Broy./Diag. 0.40E+00    6.9     0.00000415     -4911.5610235850 -2.26E-05
    63 Broy./Diag. 0.40E+00    7.1     0.00000319     -4911.5610114989  1.21E-05
    64 Broy./Diag. 0.40E+00    7.1     0.00000318     -4911.5610114265  7.24E-08
    65 Broy./Diag. 0.40E+00    7.9     0.00000360     -4911.5610042642  7.16E-06
    66 Broy./Diag. 0.40E+00    7.3     0.00000305     -4911.5610174806 -1.32E-05
    67 Broy./Diag. 0.40E+00    7.1     0.00000296     -4911.5610153514  2.13E-06
    68 Broy./Diag. 0.40E+00    7.5     0.00000267     -4911.5610008409  1.45E-05
    69 Broy./Diag. 0.40E+00    7.3     0.00000230     -4911.5610097319 -8.89E-06
    70 Broy./Diag. 0.40E+00    7.3     0.00000237     -4911.5610094135  3.18E-07
    71 Broy./Diag. 0.40E+00    7.3     0.00000241     -4911.5610132258 -3.81E-06
    72 Broy./Diag. 0.40E+00    6.6     0.00000185     -4911.5610036402  9.59E-06
    73 Broy./Diag. 0.40E+00    7.8     0.00000158     -4911.5610061138 -2.47E-06
    74 Broy./Diag. 0.40E+00    6.9     0.00000138     -4911.5610133926 -7.28E-06
    75 Broy./Diag. 0.40E+00    7.7     0.00000133     -4911.5610071111  6.28E-06
    76 Broy./Diag. 0.40E+00    6.9     0.00000158     -4911.5610071273 -1.63E-08
    77 Broy./Diag. 0.40E+00    6.7     0.00000141     -4911.5610048216  2.31E-06
    78 Broy./Diag. 0.40E+00    7.3     0.00000134     -4911.5610103454 -5.52E-06
    79 Broy./Diag. 0.40E+00    7.1     0.00000113     -4911.5610082933  2.05E-06
    80 Broy./Diag. 0.40E+00    6.9     0.00000091     -4911.5610032465  5.05E-06

  *** SCF run converged in    80 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008212260921
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.40821442283050
  Hartree energy:                                            1781.69930478800075
  Exchange-correlation energy:                               -779.33665836670423
  Electronic entropic energy:                                  -0.24152372899395
  Fermi energy:                                                 0.08659128529901

  Total energy:                                             -4911.56100324651015

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.561004720552774

 MD| ***************************************************************************
 MD| Step number                                                            1175
 MD| Time [fs]                                                       2350.000000
 MD| Conserved quantity [hartree]                            -0.491116829153E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    581.004439           593.487684
 MD| Energy drift per atom [K]           0.314110855635E+03   0.270176892541E+03
 MD| Potential energy [hartree]         -0.491156100472E+04  -0.491156395500E+04
 MD| Kinetic energy [hartree]            0.392713192160E+00   0.374510507519E+00
 MD| Temperature [K]                            1046.488354           997.982478
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02537538     -4911.5579166256 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.06707917     -4911.6090780529 -5.12E-02
     3 Broy./Diag. 0.40E+00    7.3     0.06604223     -4911.4247402063  1.84E-01
     4 Broy./Diag. 0.40E+00    7.3     0.03290766     -4911.6130231790 -1.88E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01900706     -4911.5651240781  4.79E-02
     6 Broy./Diag. 0.40E+00    7.1     0.00939798     -4911.5593140741  5.81E-03
     7 Broy./Diag. 0.40E+00    7.1     0.00403264     -4911.5475448875  1.18E-02
     8 Broy./Diag. 0.40E+00    7.3     0.00266712     -4911.5747968051 -2.73E-02
     9 Broy./Diag. 0.40E+00    8.1     0.00237955     -4911.5615948254  1.32E-02
    10 Broy./Diag. 0.40E+00    7.3     0.00131830     -4911.5565209877  5.07E-03
    11 Broy./Diag. 0.40E+00    6.8     0.00155037     -4911.5630487244 -6.53E-03
    12 Broy./Diag. 0.40E+00    6.9     0.00083124     -4911.5609484231  2.10E-03
    13 Broy./Diag. 0.40E+00    7.3     0.00044701     -4911.5604565218  4.92E-04
    14 Broy./Diag. 0.40E+00    6.8     0.00028884     -4911.5587172061  1.74E-03
    15 Broy./Diag. 0.40E+00    7.0     0.00044033     -4911.5608756074 -2.16E-03
    16 Broy./Diag. 0.40E+00    7.3     0.00038406     -4911.5613838576 -5.08E-04
    17 Broy./Diag. 0.40E+00    6.9     0.00037898     -4911.5593586073  2.03E-03
    18 Broy./Diag. 0.40E+00    7.3     0.00033668     -4911.5603968674 -1.04E-03
    19 Broy./Diag. 0.40E+00    7.3     0.00022840     -4911.5605238739 -1.27E-04
    20 Broy./Diag. 0.40E+00    7.5     0.00017296     -4911.5606307097 -1.07E-04
    21 Broy./Diag. 0.40E+00    7.1     0.00022184     -4911.5596762297  9.54E-04
    22 Broy./Diag. 0.40E+00    7.1     0.00017810     -4911.5598931442 -2.17E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00021043     -4911.5607188117 -8.26E-04
    24 Broy./Diag. 0.40E+00    7.3     0.00019482     -4911.5600491065  6.70E-04
    25 Broy./Diag. 0.40E+00    7.5     0.00011147     -4911.5600293953  1.97E-05
    26 Broy./Diag. 0.40E+00    7.0     0.00006868     -4911.5601113637 -8.20E-05
    27 Broy./Diag. 0.40E+00    7.3     0.00010286     -4911.5604116983 -3.00E-04
    28 Broy./Diag. 0.40E+00    6.9     0.00008078     -4911.5603114902  1.00E-04
    29 Broy./Diag. 0.40E+00    7.1     0.00007216     -4911.5599542936  3.57E-04
    30 Broy./Diag. 0.40E+00    7.3     0.00007801     -4911.5602791589 -3.25E-04
    31 Broy./Diag. 0.40E+00    6.6     0.00006664     -4911.5602322512  4.69E-05
    32 Broy./Diag. 0.40E+00    7.5     0.00004831     -4911.5601637164  6.85E-05
    33 Broy./Diag. 0.40E+00    6.7     0.00007356     -4911.5600243348  1.39E-04
    34 Broy./Diag. 0.40E+00    6.7     0.00006341     -4911.5601111914 -8.69E-05
    35 Broy./Diag. 0.40E+00    6.7     0.00005083     -4911.5603481865 -2.37E-04
    36 Broy./Diag. 0.40E+00    7.0     0.00004737     -4911.5600833913  2.65E-04
    37 Broy./Diag. 0.40E+00    7.1     0.00003468     -4911.5601373445 -5.40E-05
    38 Broy./Diag. 0.40E+00    7.1     0.00002348     -4911.5601730767 -3.57E-05
    39 Broy./Diag. 0.40E+00    7.3     0.00003887     -4911.5601764158 -3.34E-06
    40 Broy./Diag. 0.40E+00    7.5     0.00004305     -4911.5601525453  2.39E-05
    41 Broy./Diag. 0.40E+00    7.2     0.00002644     -4911.5600365401  1.16E-04
    42 Broy./Diag. 0.40E+00    6.9     0.00003267     -4911.5601969644 -1.60E-04
    43 Broy./Diag. 0.40E+00    7.3     0.00002631     -4911.5601402970  5.67E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00002209     -4911.5601076161  3.27E-05
    45 Broy./Diag. 0.40E+00    7.1     0.00001507     -4911.5601211950 -1.36E-05
    46 Broy./Diag. 0.40E+00    7.3     0.00001705     -4911.5601252750 -4.08E-06
    47 Broy./Diag. 0.40E+00    7.3     0.00001072     -4911.5601608156 -3.55E-05
    48 Broy./Diag. 0.40E+00    7.5     0.00001455     -4911.5600929055  6.79E-05
    49 Broy./Diag. 0.40E+00    6.7     0.00001083     -4911.5601299408 -3.70E-05
    50 Broy./Diag. 0.40E+00    7.7     0.00001601     -4911.5601392581 -9.32E-06
    51 Broy./Diag. 0.40E+00    6.9     0.00001143     -4911.5601235897  1.57E-05
    52 Broy./Diag. 0.40E+00    6.9     0.00001363     -4911.5601193211  4.27E-06
    53 Broy./Diag. 0.40E+00    6.8     0.00000673     -4911.5600970944  2.22E-05
    54 Broy./Diag. 0.40E+00    7.0     0.00000868     -4911.5601427611 -4.57E-05
    55 Broy./Diag. 0.40E+00    7.1     0.00000516     -4911.5601164718  2.63E-05
    56 Broy./Diag. 0.40E+00    7.2     0.00000825     -4911.5601121276  4.34E-06
    57 Broy./Diag. 0.40E+00    7.4     0.00000464     -4911.5601226157 -1.05E-05
    58 Broy./Diag. 0.40E+00    7.5     0.00000740     -4911.5601207098  1.91E-06
    59 Broy./Diag. 0.40E+00    7.1     0.00000531     -4911.5601294158 -8.71E-06
    60 Broy./Diag. 0.40E+00    7.3     0.00000643     -4911.5600959897  3.34E-05
    61 Broy./Diag. 0.40E+00    7.3     0.00000385     -4911.5601195267 -2.35E-05
    62 Broy./Diag. 0.40E+00    6.9     0.00000552     -4911.5601206295 -1.10E-06
    63 Broy./Diag. 0.40E+00    7.1     0.00000261     -4911.5601124227  8.21E-06
    64 Broy./Diag. 0.40E+00    7.2     0.00000326     -4911.5601138075 -1.38E-06
    65 Broy./Diag. 0.40E+00    6.9     0.00000240     -4911.5601104350  3.37E-06
    66 Broy./Diag. 0.40E+00    7.1     0.00000318     -4911.5601221731 -1.17E-05
    67 Broy./Diag. 0.40E+00    7.3     0.00000247     -4911.5601095383  1.26E-05
    68 Broy./Diag. 0.40E+00    8.1     0.00000333     -4911.5601098923 -3.54E-07
    69 Broy./Diag. 0.40E+00    7.1     0.00000201     -4911.5601151075 -5.22E-06
    70 Broy./Diag. 0.40E+00    6.9     0.00000246     -4911.5601133564  1.75E-06
    71 Broy./Diag. 0.40E+00    7.3     0.00000180     -4911.5601152392 -1.88E-06
    72 Broy./Diag. 0.40E+00    7.2     0.00000172     -4911.5601069245  8.31E-06
    73 Broy./Diag. 0.40E+00    7.1     0.00000135     -4911.5601143876 -7.46E-06
    74 Broy./Diag. 0.40E+00    7.3     0.00000156     -4911.5601135234  8.64E-07
    75 Broy./Diag. 0.40E+00    7.2     0.00000123     -4911.5601103500  3.17E-06
    76 Broy./Diag. 0.40E+00    7.8     0.00000142     -4911.5601115821 -1.23E-06
    77 Broy./Diag. 0.40E+00    7.1     0.00000117     -4911.5601105176  1.06E-06
    78 Broy./Diag. 0.40E+00    7.2     0.00000129     -4911.5601147373 -4.22E-06
    79 Broy./Diag. 0.40E+00    7.3     0.00000109     -4911.5601089212  5.82E-06
    80 Broy./Diag. 0.40E+00    7.3     0.00000093     -4911.5601100748 -1.15E-06

  *** SCF run converged in    80 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008218930127
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.41895245329169
  Hartree energy:                                            1781.69310415937593
  Exchange-correlation energy:                               -779.34006099835597
  Electronic entropic energy:                                  -0.24176537709154
  Fermi energy:                                                 0.08660960416885

  Total energy:                                             -4911.56011007475263

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.560109566714345

 MD| ***************************************************************************
 MD| Step number                                                            1176
 MD| Time [fs]                                                       2352.000000
 MD| Conserved quantity [hartree]                            -0.491116601944E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    582.220501           593.478103
 MD| Energy drift per atom [K]           0.318831039098E+03   0.270218265114E+03
 MD| Potential energy [hartree]         -0.491156010957E+04  -0.491156395173E+04
 MD| Kinetic energy [hartree]            0.394090126632E+00   0.374527156855E+00
 MD| Temperature [K]                            1050.157561           998.026845
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.02536235     -4911.5563065526 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.7     0.05089269     -4911.6268609380 -7.06E-02
     3 Broy./Diag. 0.40E+00    7.5     0.05292611     -4911.3955613274  2.31E-01
     4 Broy./Diag. 0.40E+00    6.7     0.02763314     -4911.6553486676 -2.60E-01
     5 Broy./Diag. 0.40E+00    6.7     0.01666198     -4911.5449099697  1.10E-01
     6 Broy./Diag. 0.40E+00    7.5     0.00744013     -4911.5681535479 -2.32E-02
     7 Broy./Diag. 0.40E+00    7.4     0.00552757     -4911.5425177591  2.56E-02
     8 Broy./Diag. 0.40E+00    7.1     0.00409508     -4911.5754423139 -3.29E-02
     9 Broy./Diag. 0.40E+00    6.6     0.00197340     -4911.5594838351  1.60E-02
    10 Broy./Diag. 0.40E+00    7.5     0.00158333     -4911.5549570274  4.53E-03
    11 Broy./Diag. 0.40E+00    7.3     0.00152872     -4911.5639101905 -8.95E-03
    12 Broy./Diag. 0.40E+00    7.6     0.00076443     -4911.5589370855  4.97E-03
    13 Broy./Diag. 0.40E+00    7.2     0.00053849     -4911.5597078983 -7.71E-04
    14 Broy./Diag. 0.40E+00    7.3     0.00051283     -4911.5570067899  2.70E-03
    15 Broy./Diag. 0.40E+00    7.3     0.00030464     -4911.5595557721 -2.55E-03
    16 Broy./Diag. 0.40E+00    6.8     0.00037003     -4911.5597721411 -2.16E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00032857     -4911.5578272035  1.94E-03
    18 Broy./Diag. 0.40E+00    7.1     0.00026567     -4911.5591870265 -1.36E-03
    19 Broy./Diag. 0.40E+00    7.1     0.00024192     -4911.5589176344  2.69E-04
    20 Broy./Diag. 0.40E+00    7.2     0.00025158     -4911.5595467990 -6.29E-04
    21 Broy./Diag. 0.40E+00    7.2     0.00017347     -4911.5583209463  1.23E-03
    22 Broy./Diag. 0.40E+00    7.3     0.00016561     -4911.5583558143 -3.49E-05
    23 Broy./Diag. 0.40E+00    7.1     0.00016528     -4911.5591475785 -7.92E-04
    24 Broy./Diag. 0.40E+00    7.3     0.00015096     -4911.5584860084  6.62E-04
    25 Broy./Diag. 0.40E+00    6.8     0.00012125     -4911.5586270262 -1.41E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00013610     -4911.5584400856  1.87E-04
    27 Broy./Diag. 0.40E+00    6.9     0.00010806     -4911.5590937670 -6.54E-04
    28 Broy./Diag. 0.40E+00    7.3     0.00010369     -4911.5588677095  2.26E-04
    29 Broy./Diag. 0.40E+00    7.3     0.00009208     -4911.5583720758  4.96E-04
    30 Broy./Diag. 0.40E+00    7.3     0.00006789     -4911.5587509206 -3.79E-04
    31 Broy./Diag. 0.40E+00    6.9     0.00005804     -4911.5586573525  9.36E-05
    32 Broy./Diag. 0.40E+00    7.3     0.00006419     -4911.5587317878 -7.44E-05
    33 Broy./Diag. 0.40E+00    7.1     0.00005975     -4911.5584174057  3.14E-04
    34 Broy./Diag. 0.40E+00    6.7     0.00006127     -4911.5585688787 -1.51E-04
    35 Broy./Diag. 0.40E+00    6.9     0.00006294     -4911.5588182339 -2.49E-04
    36 Broy./Diag. 0.40E+00    7.2     0.00004670     -4911.5585357790  2.82E-04
    37 Broy./Diag. 0.40E+00    7.4     0.00003902     -4911.5586007299 -6.50E-05
    38 Broy./Diag. 0.40E+00    7.1     0.00003339     -4911.5585541221  4.66E-05
    39 Broy./Diag. 0.40E+00    7.3     0.00003220     -4911.5586875982 -1.33E-04
    40 Broy./Diag. 0.40E+00    7.1     0.00003589     -4911.5585909424  9.67E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00003290     -4911.5584578620  1.33E-04
    42 Broy./Diag. 0.40E+00    6.8     0.00002530     -4911.5586131592 -1.55E-04
    43 Broy./Diag. 0.40E+00    8.1     0.00002797     -4911.5585645074  4.87E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00002279     -4911.5585903708 -2.59E-05
    45 Broy./Diag. 0.40E+00   10.5     0.00002090     -4911.5585021616  8.82E-05
    46 Broy./Diag. 0.40E+00    6.9     0.00002088     -4911.5585642679 -6.21E-05
    47 Broy./Diag. 0.40E+00    7.8     0.00001900     -4911.5586176126 -5.33E-05
    48 Broy./Diag. 0.40E+00   11.0     0.00001269     -4911.5585220108  9.56E-05
    49 Broy./Diag. 0.40E+00    7.2     0.00001297     -4911.5585544834 -3.25E-05
    50 Broy./Diag. 0.40E+00    7.1     0.00001201     -4911.5585436400  1.08E-05
    51 Broy./Diag. 0.40E+00    7.1     0.00001185     -4911.5585790494 -3.54E-05
    52 Broy./Diag. 0.40E+00    7.0     0.00001347     -4911.5585356969  4.34E-05
    53 Broy./Diag. 0.40E+00    8.2     0.00001302     -4911.5585081086  2.76E-05
    54 Broy./Diag. 0.40E+00    7.1     0.00000853     -4911.5585722192 -6.41E-05
    55 Broy./Diag. 0.40E+00    8.7     0.00000876     -4911.5585425827  2.96E-05
    56 Broy./Diag. 0.40E+00    9.7     0.00000707     -4911.5585454427 -2.86E-06
    57 Broy./Diag. 0.40E+00    8.9     0.00000602     -4911.5585272042  1.82E-05
    58 Broy./Diag. 0.40E+00    9.3     0.00000643     -4911.5585480446 -2.08E-05
    59 Broy./Diag. 0.40E+00    7.4     0.00000785     -4911.5585525074 -4.46E-06
    60 Broy./Diag. 0.40E+00    7.4     0.00000532     -4911.5585138978  3.86E-05
    61 Broy./Diag. 0.40E+00    7.3     0.00000546     -4911.5585365109 -2.26E-05
    62 Broy./Diag. 0.40E+00    8.2     0.00000515     -4911.5585339799  2.53E-06
    63 Broy./Diag. 0.40E+00    7.7     0.00000429     -4911.5585448548 -1.09E-05
    64 Broy./Diag. 0.40E+00   10.1     0.00000395     -4911.5585272956  1.76E-05
    65 Broy./Diag. 0.40E+00    7.0     0.00000423     -4911.5585252478  2.05E-06
    66 Broy./Diag. 0.40E+00    8.6     0.00000295     -4911.5585448589 -1.96E-05
    67 Broy./Diag. 0.40E+00    9.7     0.00000303     -4911.5585300556  1.48E-05
    68 Broy./Diag. 0.40E+00    7.3     0.00000274     -4911.5585308832 -8.28E-07
    69 Broy./Diag. 0.40E+00    6.9     0.00000256     -4911.5585261452  4.74E-06
    70 Broy./Diag. 0.40E+00    7.1     0.00000252     -4911.5585358993 -9.75E-06
    71 Broy./Diag. 0.40E+00    6.7     0.00000301     -4911.5585348512  1.05E-06
    72 Broy./Diag. 0.40E+00    7.1     0.00000215     -4911.5585204528  1.44E-05
    73 Broy./Diag. 0.40E+00    6.9     0.00000190     -4911.5585312781 -1.08E-05
    74 Broy./Diag. 0.40E+00    7.3     0.00000166     -4911.5585301039  1.17E-06
    75 Broy./Diag. 0.40E+00    8.3     0.00000142     -4911.5585317358 -1.63E-06
    76 Broy./Diag. 0.40E+00    6.9     0.00000147     -4911.5585257460  5.99E-06
    77 Broy./Diag. 0.40E+00    7.1     0.00000159     -4911.5585265705 -8.25E-07
    78 Broy./Diag. 0.40E+00    7.4     0.00000136     -4911.5585331042 -6.53E-06
    79 Broy./Diag. 0.40E+00    7.1     0.00000134     -4911.5585257903  7.31E-06
    80 Broy./Diag. 0.40E+00    6.9     0.00000110     -4911.5585267498 -9.60E-07
    81 Broy./Diag. 0.40E+00    6.9     0.00000095     -4911.5585258845  8.65E-07

  *** SCF run converged in    81 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008226716042
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.43563245099085
  Hartree energy:                                            1781.68390525433233
  Exchange-correlation energy:                               -779.34572345856793
  Electronic entropic energy:                                  -0.24199990609046
  Fermi energy:                                                 0.08663525148731

  Total energy:                                             -4911.55852588453581

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.558525308868411

 MD| ***************************************************************************
 MD| Step number                                                            1177
 MD| Time [fs]                                                       2354.000000
 MD| Conserved quantity [hartree]                            -0.491117415420E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    612.332310           593.494122
 MD| Energy drift per atom [K]           0.301931372027E+03   0.270245209130E+03
 MD| Potential energy [hartree]         -0.491155852531E+04  -0.491156394712E+04
 MD| Kinetic energy [hartree]            0.384371113789E+00   0.374535520455E+00
 MD| Temperature [K]                            1024.258676           998.049132
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.6     0.02706747     -4911.5541229174 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.5     0.05425835     -4911.6150972000 -6.10E-02
     3 Broy./Diag. 0.40E+00    7.5     0.06685317     -4911.4712042646  1.44E-01
     4 Broy./Diag. 0.40E+00    7.1     0.04013046     -4911.5896257591 -1.18E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01801159     -4911.5808053687  8.82E-03
     6 Broy./Diag. 0.40E+00    6.7     0.00820411     -4911.5419033200  3.89E-02
     7 Broy./Diag. 0.40E+00    6.9     0.00716960     -4911.5438561873 -1.95E-03
     8 Broy./Diag. 0.40E+00    6.8     0.00478446     -4911.5798912014 -3.60E-02
     9 Broy./Diag. 0.40E+00    7.5     0.00224772     -4911.5568826287  2.30E-02
    10 Broy./Diag. 0.40E+00    7.7     0.00194716     -4911.5549905938  1.89E-03
    11 Broy./Diag. 0.40E+00    8.1     0.00141907     -4911.5587434606 -3.75E-03
    12 Broy./Diag. 0.40E+00    7.7     0.00069772     -4911.5584233681  3.20E-04
    13 Broy./Diag. 0.40E+00    6.9     0.00062300     -4911.5568218101  1.60E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00055202     -4911.5549737517  1.85E-03
    15 Broy./Diag. 0.40E+00    6.9     0.00038445     -4911.5579885384 -3.01E-03
    16 Broy./Diag. 0.40E+00    6.9     0.00034356     -4911.5577594719  2.29E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00033204     -4911.5562358110  1.52E-03
    18 Broy./Diag. 0.40E+00    7.3     0.00029699     -4911.5566937865 -4.58E-04
    19 Broy./Diag. 0.40E+00    7.5     0.00026893     -4911.5572370411 -5.43E-04
    20 Broy./Diag. 0.40E+00    6.8     0.00030071     -4911.5574289929 -1.92E-04
    21 Broy./Diag. 0.40E+00    6.7     0.00021956     -4911.5558832560  1.55E-03
    22 Broy./Diag. 0.40E+00    7.1     0.00012034     -4911.5562825366 -3.99E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00013215     -4911.5569393998 -6.57E-04
    24 Broy./Diag. 0.40E+00    7.1     0.00013735     -4911.5565890061  3.50E-04
    25 Broy./Diag. 0.40E+00    7.0     0.00012108     -4911.5562827076  3.06E-04
    26 Broy./Diag. 0.40E+00    6.9     0.00015577     -4911.5563238565 -4.11E-05
    27 Broy./Diag. 0.40E+00    7.1     0.00013585     -4911.5570534079 -7.30E-04
    28 Broy./Diag. 0.40E+00    7.3     0.00007322     -4911.5566187485  4.35E-04
    29 Broy./Diag. 0.40E+00    7.1     0.00008359     -4911.5562166249  4.02E-04
    30 Broy./Diag. 0.40E+00    7.3     0.00005476     -4911.5564779708 -2.61E-04
    31 Broy./Diag. 0.40E+00    7.1     0.00006414     -4911.5565416575 -6.37E-05
    32 Broy./Diag. 0.40E+00    6.9     0.00007599     -4911.5564965860  4.51E-05
    33 Broy./Diag. 0.40E+00    7.3     0.00006888     -4911.5561738543  3.23E-04
    34 Broy./Diag. 0.40E+00    7.4     0.00004557     -4911.5564196684 -2.46E-04
    35 Broy./Diag. 0.40E+00    7.5     0.00005990     -4911.5566093829 -1.90E-04
    36 Broy./Diag. 0.40E+00    6.9     0.00003656     -4911.5563586190  2.51E-04
    37 Broy./Diag. 0.40E+00    7.1     0.00003778     -4911.5563428445  1.58E-05
    38 Broy./Diag. 0.40E+00    6.9     0.00003872     -4911.5563723028 -2.95E-05
    39 Broy./Diag. 0.40E+00    7.1     0.00003591     -4911.5564735208 -1.01E-04
    40 Broy./Diag. 0.40E+00    6.4     0.00003150     -4911.5563399211  1.34E-04
    41 Broy./Diag. 0.40E+00    6.8     0.00002939     -4911.5562696074  7.03E-05
    42 Broy./Diag. 0.40E+00    7.0     0.00002205     -4911.5563920376 -1.22E-04
    43 Broy./Diag. 0.40E+00    7.1     0.00002625     -4911.5563698501  2.22E-05
    44 Broy./Diag. 0.40E+00    7.5     0.00002502     -4911.5563369176  3.29E-05
    45 Broy./Diag. 0.40E+00    6.9     0.00002010     -4911.5562900410  4.69E-05
    46 Broy./Diag. 0.40E+00    7.1     0.00002229     -4911.5563651410 -7.51E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00001603     -4911.5563719915 -6.85E-06
    48 Broy./Diag. 0.40E+00    7.5     0.00001278     -4911.5563001878  7.18E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00001224     -4911.5563279774 -2.78E-05
    50 Broy./Diag. 0.40E+00    6.9     0.00001367     -4911.5563309157 -2.94E-06
    51 Broy./Diag. 0.40E+00    6.8     0.00001227     -4911.5563435594 -1.26E-05
    52 Broy./Diag. 0.40E+00    7.1     0.00001621     -4911.5562954126  4.81E-05
    53 Broy./Diag. 0.40E+00    7.1     0.00001042     -4911.5563033951 -7.98E-06
    54 Broy./Diag. 0.40E+00    7.1     0.00000942     -4911.5563439455 -4.06E-05
    55 Broy./Diag. 0.40E+00    7.5     0.00000786     -4911.5563116476  3.23E-05
    56 Broy./Diag. 0.40E+00    7.1     0.00000771     -4911.5563095751  2.07E-06
    57 Broy./Diag. 0.40E+00    7.1     0.00000625     -4911.5563068980  2.68E-06
    58 Broy./Diag. 0.40E+00    6.8     0.00000882     -4911.5563233593 -1.65E-05
    59 Broy./Diag. 0.40E+00    7.1     0.00000598     -4911.5563112016  1.22E-05
    60 Broy./Diag. 0.40E+00    7.1     0.00000612     -4911.5562893969  2.18E-05
    61 Broy./Diag. 0.40E+00    7.1     0.00000498     -4911.5563120001 -2.26E-05
    62 Broy./Diag. 0.40E+00    7.2     0.00000554     -4911.5563077323  4.27E-06
    63 Broy./Diag. 0.40E+00    7.1     0.00000451     -4911.5563066737  1.06E-06
    64 Broy./Diag. 0.40E+00    6.9     0.00000543     -4911.5562948567  1.18E-05
    65 Broy./Diag. 0.40E+00    7.9     0.00000319     -4911.5563033744 -8.52E-06
    66 Broy./Diag. 0.40E+00    7.5     0.00000339     -4911.5563111675 -7.79E-06
    67 Broy./Diag. 0.40E+00    7.1     0.00000275     -4911.5562962587  1.49E-05
    68 Broy./Diag. 0.40E+00    7.8     0.00000294     -4911.5562993803 -3.12E-06
    69 Broy./Diag. 0.40E+00    7.4     0.00000271     -4911.5563001454 -7.65E-07
    70 Broy./Diag. 0.40E+00    7.5     0.00000362     -4911.5563045787 -4.43E-06
    71 Broy./Diag. 0.40E+00    7.4     0.00000260     -4911.5562970747  7.50E-06
    72 Broy./Diag. 0.40E+00    7.3     0.00000230     -4911.5562925530  4.52E-06
    73 Broy./Diag. 0.40E+00    7.2     0.00000171     -4911.5563023013 -9.75E-06
    74 Broy./Diag. 0.40E+00    6.8     0.00000171     -4911.5562984974  3.80E-06
    75 Broy./Diag. 0.40E+00    7.1     0.00000156     -4911.5562970191  1.48E-06
    76 Broy./Diag. 0.40E+00    7.3     0.00000190     -4911.5562947755  2.24E-06
    77 Broy./Diag. 0.40E+00    7.7     0.00000165     -4911.5562985765 -3.80E-06
    78 Broy./Diag. 0.40E+00    6.9     0.00000148     -4911.5562989939 -4.17E-07
    79 Broy./Diag. 0.40E+00    7.5     0.00000120     -4911.5562925090  6.48E-06
    80 Broy./Diag. 0.40E+00    7.1     0.00000110     -4911.5562955563 -3.05E-06
    81 Broy./Diag. 0.40E+00    7.5     0.00000102     -4911.5562959781 -4.22E-07
    82 Broy./Diag. 0.40E+00    6.6     0.00000115     -4911.5562968105 -8.32E-07
    83 Broy./Diag. 0.40E+00    7.5     0.00000107     -4911.5562939679  2.84E-06
    84 Broy./Diag. 0.40E+00    6.7     0.00000079     -4911.5562938444  1.24E-07

  *** SCF run converged in    84 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008234225949
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.45471387687894
  Hartree energy:                                            1781.67362206074404
  Exchange-correlation energy:                               -779.35206677070039
  Electronic entropic energy:                                  -0.24222286920141
  Fermi energy:                                                 0.08666102438765

  Total energy:                                             -4911.55629384438726

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.556292825659511

 MD| ***************************************************************************
 MD| Step number                                                            1178
 MD| Time [fs]                                                       2356.000000
 MD| Conserved quantity [hartree]                            -0.491117557836E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    610.494297           593.508554
 MD| Energy drift per atom [K]           0.298972717306E+03   0.270269595809E+03
 MD| Potential energy [hartree]         -0.491155629283E+04  -0.491156394062E+04
 MD| Kinetic energy [hartree]            0.380714464580E+00   0.374540765739E+00
 MD| Temperature [K]                            1014.514565           998.063109
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.02365997     -4911.5522090799 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.9     0.06427566     -4911.6031980336 -5.10E-02
     3 Broy./Diag. 0.40E+00    6.9     0.06425840     -4911.5481896866  5.50E-02
     4 Broy./Diag. 0.40E+00    7.1     0.03503255     -4911.4865000631  6.17E-02
     5 Broy./Diag. 0.40E+00    7.0     0.02049466     -4911.6537782030 -1.67E-01
     6 Broy./Diag. 0.40E+00    7.3     0.00982679     -4911.5258954614  1.28E-01
     7 Broy./Diag. 0.40E+00    6.9     0.00613586     -4911.5383557191 -1.25E-02
     8 Broy./Diag. 0.40E+00    7.1     0.00436512     -4911.5684148289 -3.01E-02
     9 Broy./Diag. 0.40E+00    7.9     0.00275492     -4911.5611455001  7.27E-03
    10 Broy./Diag. 0.40E+00    6.9     0.00200509     -4911.5544896680  6.66E-03
    11 Broy./Diag. 0.40E+00    6.9     0.00215426     -4911.5478013250  6.69E-03
    12 Broy./Diag. 0.40E+00    7.1     0.00101091     -4911.5595072645 -1.17E-02
    13 Broy./Diag. 0.40E+00    6.7     0.00061183     -4911.5549385444  4.57E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00060194     -4911.5526542972  2.28E-03
    15 Broy./Diag. 0.40E+00    7.2     0.00042101     -4911.5551272188 -2.47E-03
    16 Broy./Diag. 0.40E+00    7.6     0.00035992     -4911.5556771921 -5.50E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00042860     -4911.5556286406  4.86E-05
    18 Broy./Diag. 0.40E+00    7.0     0.00037003     -4911.5533780903  2.25E-03
    19 Broy./Diag. 0.40E+00    6.6     0.00025428     -4911.5551358366 -1.76E-03
    20 Broy./Diag. 0.40E+00    7.0     0.00030987     -4911.5554183666 -2.83E-04
    21 Broy./Diag. 0.40E+00    6.6     0.00024809     -4911.5542235703  1.19E-03
    22 Broy./Diag. 0.40E+00    7.1     0.00016943     -4911.5541399112  8.37E-05
    23 Broy./Diag. 0.40E+00    6.9     0.00020108     -4911.5542585058 -1.19E-04
    24 Broy./Diag. 0.40E+00    7.4     0.00018372     -4911.5552780913 -1.02E-03
    25 Broy./Diag. 0.40E+00    7.4     0.00010846     -4911.5542854668  9.93E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00015251     -4911.5542138516  7.16E-05
    27 Broy./Diag. 0.40E+00    6.9     0.00014542     -4911.5548040377 -5.90E-04
    28 Broy./Diag. 0.40E+00    7.1     0.00009676     -4911.5546228765  1.81E-04
    29 Broy./Diag. 0.40E+00    7.1     0.00011311     -4911.5545072934  1.16E-04
    30 Broy./Diag. 0.40E+00    7.3     0.00010457     -4911.5539561066  5.51E-04
    31 Broy./Diag. 0.40E+00    7.3     0.00006103     -4911.5545219035 -5.66E-04
    32 Broy./Diag. 0.40E+00    7.3     0.00007739     -4911.5545069532  1.50E-05
    33 Broy./Diag. 0.40E+00    7.1     0.00007526     -4911.5541872542  3.20E-04
    34 Broy./Diag. 0.40E+00    7.5     0.00005355     -4911.5542900425 -1.03E-04
    35 Broy./Diag. 0.40E+00    7.1     0.00006191     -4911.5543329236 -4.29E-05
    36 Broy./Diag. 0.40E+00    7.1     0.00006480     -4911.5545462334 -2.13E-04
    37 Broy./Diag. 0.40E+00    7.1     0.00004161     -4911.5541719574  3.74E-04
    38 Broy./Diag. 0.40E+00    7.5     0.00004221     -4911.5542095998 -3.76E-05
    39 Broy./Diag. 0.40E+00    7.1     0.00004683     -4911.5543617100 -1.52E-04
    40 Broy./Diag. 0.40E+00    6.9     0.00003276     -4911.5542807937  8.09E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00003230     -4911.5542568317  2.40E-05
    42 Broy./Diag. 0.40E+00    7.3     0.00003530     -4911.5541517107  1.05E-04
    43 Broy./Diag. 0.40E+00    6.9     0.00002912     -4911.5543464065 -1.95E-04
    44 Broy./Diag. 0.40E+00    6.7     0.00002437     -4911.5542971066  4.93E-05
    45 Broy./Diag. 0.40E+00    7.5     0.00002822     -4911.5541929910  1.04E-04
    46 Broy./Diag. 0.40E+00    7.9     0.00002137     -4911.5542480074 -5.50E-05
    47 Broy./Diag. 0.40E+00    7.3     0.00001953     -4911.5542449481  3.06E-06
    48 Broy./Diag. 0.40E+00    7.1     0.00002041     -4911.5542897143 -4.48E-05
    49 Broy./Diag. 0.40E+00    7.5     0.00001788     -4911.5541773518  1.12E-04
    50 Broy./Diag. 0.40E+00    7.4     0.00001274     -4911.5542162477 -3.89E-05
    51 Broy./Diag. 0.40E+00    7.3     0.00001697     -4911.5542576702 -4.14E-05
    52 Broy./Diag. 0.40E+00    7.5     0.00001333     -4911.5542168372  4.08E-05
    53 Broy./Diag. 0.40E+00    7.1     0.00001206     -4911.5542166804  1.57E-07
    54 Broy./Diag. 0.40E+00    6.9     0.00001348     -4911.5541890959  2.76E-05
    55 Broy./Diag. 0.40E+00    7.1     0.00001251     -4911.5542531981 -6.41E-05
    56 Broy./Diag. 0.40E+00    6.6     0.00000781     -4911.5542161233  3.71E-05
    57 Broy./Diag. 0.40E+00    7.7     0.00000937     -4911.5541925171  2.36E-05
    58 Broy./Diag. 0.40E+00    6.9     0.00000773     -4911.5542160565 -2.35E-05
    59 Broy./Diag. 0.40E+00    7.1     0.00000697     -4911.5542089620  7.09E-06
    60 Broy./Diag. 0.40E+00    7.1     0.00000812     -4911.5542221505 -1.32E-05
    61 Broy./Diag. 0.40E+00    7.3     0.00000753     -4911.5541842114  3.79E-05
    62 Broy./Diag. 0.40E+00    7.3     0.00000505     -4911.5542082682 -2.41E-05
    63 Broy./Diag. 0.40E+00    7.1     0.00000659     -4911.5542193900 -1.11E-05
    64 Broy./Diag. 0.40E+00    7.0     0.00000503     -4911.5541978000  2.16E-05
    65 Broy./Diag. 0.40E+00    7.1     0.00000410     -4911.5542025027 -4.70E-06
    66 Broy./Diag. 0.40E+00    7.1     0.00000498     -4911.5541943968  8.11E-06
    67 Broy./Diag. 0.40E+00    7.8     0.00000440     -4911.5542136414 -1.92E-05
    68 Broy./Diag. 0.40E+00    7.1     0.00000262     -4911.5541967711  1.69E-05
    69 Broy./Diag. 0.40E+00    7.3     0.00000367     -4911.5541924190  4.35E-06
    70 Broy./Diag. 0.40E+00    7.7     0.00000327     -4911.5542037236 -1.13E-05
    71 Broy./Diag. 0.40E+00    7.1     0.00000245     -4911.5541987522  4.97E-06
    72 Broy./Diag. 0.40E+00    7.3     0.00000325     -4911.5542017731 -3.02E-06
    73 Broy./Diag. 0.40E+00    6.9     0.00000276     -4911.5541892903  1.25E-05
    74 Broy./Diag. 0.40E+00    7.3     0.00000174     -4911.5542003825 -1.11E-05
    75 Broy./Diag. 0.40E+00    8.1     0.00000229     -4911.5542008766 -4.94E-07
    76 Broy./Diag. 0.40E+00    6.9     0.00000190     -4911.5541928026  8.07E-06
    77 Broy./Diag. 0.40E+00    7.2     0.00000130     -4911.5541958223 -3.02E-06
    78 Broy./Diag. 0.40E+00    7.3     0.00000199     -4911.5541937435  2.08E-06
    79 Broy./Diag. 0.40E+00    6.7     0.00000172     -4911.5542004014 -6.66E-06
    80 Broy./Diag. 0.40E+00    6.8     0.00000134     -4911.5541922900  8.11E-06
    81 Broy./Diag. 0.40E+00    7.1     0.00000146     -4911.5541925286 -2.39E-07
    82 Broy./Diag. 0.40E+00    7.1     0.00000136     -4911.5541974224 -4.89E-06
    83 Broy./Diag. 0.40E+00    7.5     0.00000079     -4911.5541944781  2.94E-06

  *** SCF run converged in    83 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008240596738
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.47357686514169
  Hartree energy:                                            1781.66316829661082
  Exchange-correlation energy:                               -779.35820370383715
  Electronic entropic energy:                                  -0.24239584709746
  Fermi energy:                                                 0.08668581007227

  Total energy:                                             -4911.55419447810800

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.554191893641473

 MD| ***************************************************************************
 MD| Step number                                                            1179
 MD| Time [fs]                                                       2358.000000
 MD| Conserved quantity [hartree]                            -0.491118630537E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    603.281689           593.516843
 MD| Energy drift per atom [K]           0.276687738204E+03   0.270275039527E+03
 MD| Potential energy [hartree]         -0.491155419189E+04  -0.491156393235E+04
 MD| Kinetic energy [hartree]            0.367886525673E+00   0.374535121769E+00
 MD| Temperature [K]                             980.331123           998.048069
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.01985077     -4911.5500366850 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.05380951     -4911.6061987367 -5.62E-02
     3 Broy./Diag. 0.40E+00    7.7     0.06138989     -4911.5221786527  8.40E-02
     4 Broy./Diag. 0.40E+00    7.4     0.03568242     -4911.4929631195  2.92E-02
     5 Broy./Diag. 0.40E+00    6.9     0.01989204     -4911.6499352629 -1.57E-01
     6 Broy./Diag. 0.40E+00    7.0     0.00973195     -4911.5232965221  1.27E-01
     7 Broy./Diag. 0.40E+00    7.1     0.00713517     -4911.5371035503 -1.38E-02
     8 Broy./Diag. 0.40E+00    7.6     0.00426055     -4911.5635802430 -2.65E-02
     9 Broy./Diag. 0.40E+00    6.9     0.00245346     -4911.5601334923  3.45E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00216188     -4911.5515004676  8.63E-03
    11 Broy./Diag. 0.40E+00    7.1     0.00223701     -4911.5455137785  5.99E-03
    12 Broy./Diag. 0.40E+00    7.3     0.00100540     -4911.5572291321 -1.17E-02
    13 Broy./Diag. 0.40E+00    7.1     0.00072074     -4911.5523103338  4.92E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00064537     -4911.5504831342  1.83E-03
    15 Broy./Diag. 0.40E+00    7.2     0.00036233     -4911.5526445543 -2.16E-03
    16 Broy./Diag. 0.40E+00    7.1     0.00031860     -4911.5534846863 -8.40E-04
    17 Broy./Diag. 0.40E+00    7.2     0.00044215     -4911.5530760020  4.09E-04
    18 Broy./Diag. 0.40E+00    6.9     0.00036769     -4911.5510514882  2.02E-03
    19 Broy./Diag. 0.40E+00    7.1     0.00026133     -4911.5530199269 -1.97E-03
    20 Broy./Diag. 0.40E+00    6.9     0.00033985     -4911.5530809083 -6.10E-05
    21 Broy./Diag. 0.40E+00    7.3     0.00022201     -4911.5519769763  1.10E-03
    22 Broy./Diag. 0.40E+00    7.5     0.00014534     -4911.5517753151  2.02E-04
    23 Broy./Diag. 0.40E+00    7.5     0.00020472     -4911.5521038434 -3.29E-04
    24 Broy./Diag. 0.40E+00    6.7     0.00017696     -4911.5529507729 -8.47E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00010458     -4911.5519038175  1.05E-03
    26 Broy./Diag. 0.40E+00    7.3     0.00016435     -4911.5520139382 -1.10E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00013757     -4911.5525442007 -5.30E-04
    28 Broy./Diag. 0.40E+00    7.3     0.00008463     -4911.5523919595  1.52E-04
    29 Broy./Diag. 0.40E+00    7.1     0.00012315     -4911.5521484092  2.44E-04
    30 Broy./Diag. 0.40E+00    7.7     0.00010996     -4911.5517017203  4.47E-04
    31 Broy./Diag. 0.40E+00    6.8     0.00005942     -4911.5523348700 -6.33E-04
    32 Broy./Diag. 0.40E+00    7.1     0.00008132     -4911.5521967210  1.38E-04
    33 Broy./Diag. 0.40E+00    7.4     0.00006950     -4911.5519312530  2.65E-04
    34 Broy./Diag. 0.40E+00    7.3     0.00004528     -4911.5520450788 -1.14E-04
    35 Broy./Diag. 0.40E+00    7.7     0.00006190     -4911.5521381221 -9.30E-05
    36 Broy./Diag. 0.40E+00    7.4     0.00006619     -4911.5522562394 -1.18E-04
    37 Broy./Diag. 0.40E+00    7.2     0.00004469     -4911.5518787412  3.77E-04
    38 Broy./Diag. 0.40E+00    7.6     0.00004669     -4911.5520136705 -1.35E-04
    39 Broy./Diag. 0.40E+00    8.2     0.00004654     -4911.5521335188 -1.20E-04
    40 Broy./Diag. 0.40E+00    8.7     0.00002875     -4911.5520369133  9.66E-05
    41 Broy./Diag. 0.40E+00    8.6     0.00003127     -4911.5519960108  4.09E-05
    42 Broy./Diag. 0.40E+00    7.5     0.00003467     -4911.5519409058  5.51E-05
    43 Broy./Diag. 0.40E+00   11.1     0.00002681     -4911.5521188257 -1.78E-04
    44 Broy./Diag. 0.40E+00    7.3     0.00002446     -4911.5520202600  9.86E-05
    45 Broy./Diag. 0.40E+00    7.1     0.00002792     -4911.5519598858  6.04E-05
    46 Broy./Diag. 0.40E+00    7.3     0.00002082     -4911.5520239921 -6.41E-05
    47 Broy./Diag. 0.40E+00    7.3     0.00001933     -4911.5520227862  1.21E-06
    48 Broy./Diag. 0.40E+00    6.9     0.00002145     -4911.5520453964 -2.26E-05
    49 Broy./Diag. 0.40E+00    8.4     0.00001409     -4911.5519430046  1.02E-04
    50 Broy./Diag. 0.40E+00    7.0     0.00001252     -4911.5520038259 -6.08E-05
    51 Broy./Diag. 0.40E+00   10.4     0.00001576     -4911.5520193502 -1.55E-05
    52 Broy./Diag. 0.40E+00    7.3     0.00001247     -4911.5519797359  3.96E-05
    53 Broy./Diag. 0.40E+00    8.8     0.00001128     -4911.5519891262 -9.39E-06
    54 Broy./Diag. 0.40E+00    9.5     0.00001423     -4911.5519678564  2.13E-05
    55 Broy./Diag. 0.40E+00    7.8     0.00000969     -4911.5520207281 -5.29E-05
    56 Broy./Diag. 0.40E+00    7.0     0.00000984     -4911.5519775394  4.32E-05
    57 Broy./Diag. 0.40E+00    7.3     0.00000907     -4911.5519731318  4.41E-06
    58 Broy./Diag. 0.40E+00    7.6     0.00000762     -4911.5519932802 -2.01E-05
    59 Broy./Diag. 0.40E+00    7.9     0.00000580     -4911.5519792412  1.40E-05
    60 Broy./Diag. 0.40E+00   10.3     0.00000808     -4911.5519928609 -1.36E-05
    61 Broy./Diag. 0.40E+00    7.8     0.00000574     -4911.5519647589  2.81E-05
    62 Broy./Diag. 0.40E+00   10.6     0.00000655     -4911.5519862325 -2.15E-05
    63 Broy./Diag. 0.40E+00    8.1     0.00000607     -4911.5519856588  5.74E-07
    64 Broy./Diag. 0.40E+00    6.9     0.00000508     -4911.5519712231  1.44E-05
    65 Broy./Diag. 0.40E+00    7.1     0.00000355     -4911.5519824535 -1.12E-05
    66 Broy./Diag. 0.40E+00    6.9     0.00000517     -4911.5519700192  1.24E-05
    67 Broy./Diag. 0.40E+00    7.3     0.00000351     -4911.5519851930 -1.52E-05
    68 Broy./Diag. 0.40E+00    6.9     0.00000371     -4911.5519726658  1.25E-05
    69 Broy./Diag. 0.40E+00    7.8     0.00000324     -4911.5519743703 -1.70E-06
    70 Broy./Diag. 0.40E+00    7.5     0.00000313     -4911.5519793673 -5.00E-06
    71 Broy./Diag. 0.40E+00    7.5     0.00000226     -4911.5519711249  8.24E-06
    72 Broy./Diag. 0.40E+00    6.9     0.00000337     -4911.5519790284 -7.90E-06
    73 Broy./Diag. 0.40E+00    7.3     0.00000253     -4911.5519688370  1.02E-05
    74 Broy./Diag. 0.40E+00    7.1     0.00000228     -4911.5519761194 -7.28E-06
    75 Broy./Diag. 0.40E+00    7.3     0.00000206     -4911.5519740494  2.07E-06
    76 Broy./Diag. 0.40E+00    7.1     0.00000181     -4911.5519710980  2.95E-06
    77 Broy./Diag. 0.40E+00    7.1     0.00000135     -4911.5519758299 -4.73E-06
    78 Broy./Diag. 0.40E+00    7.3     0.00000191     -4911.5519700787  5.75E-06
    79 Broy./Diag. 0.40E+00    7.3     0.00000164     -4911.5519756766 -5.60E-06
    80 Broy./Diag. 0.40E+00    7.3     0.00000125     -4911.5519712164  4.46E-06
    81 Broy./Diag. 0.40E+00    7.3     0.00000130     -4911.5519723911 -1.17E-06
    82 Broy./Diag. 0.40E+00    7.7     0.00000127     -4911.5519735464 -1.16E-06
    83 Broy./Diag. 0.40E+00    7.1     0.00000093     -4911.5519699606  3.59E-06

  *** SCF run converged in    83 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008247970523
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.50039245571088
  Hartree energy:                                            1781.64810853248900
  Exchange-correlation energy:                               -779.36752968581982
  Electronic entropic energy:                                  -0.24260126141585
  Fermi energy:                                                 0.08672046068930

  Total energy:                                             -4911.55196996059385

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.551970353257275

 MD| ***************************************************************************
 MD| Step number                                                            1180
 MD| Time [fs]                                                       2360.000000
 MD| Conserved quantity [hartree]                            -0.491119938158E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    632.977286           593.550284
 MD| Energy drift per atom [K]           0.249522357841E+03   0.270257452508E+03
 MD| Potential energy [hartree]         -0.491155197035E+04  -0.491156392222E+04
 MD| Kinetic energy [hartree]            0.352588768301E+00   0.374516523165E+00
 MD| Temperature [K]                             939.566195           997.998508
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.02023150     -4911.5471840756 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.06832534     -4911.6544846071 -1.07E-01
     3 Broy./Diag. 0.40E+00    8.0     0.07045405     -4911.3563073581  2.98E-01
     4 Broy./Diag. 0.40E+00    6.9     0.03488100     -4911.5995453655 -2.43E-01
     5 Broy./Diag. 0.40E+00    7.3     0.01962599     -4911.6065604560 -7.02E-03
     6 Broy./Diag. 0.40E+00    6.7     0.00869433     -4911.5154563505  9.11E-02
     7 Broy./Diag. 0.40E+00    7.5     0.00520025     -4911.5398219811 -2.44E-02
     8 Broy./Diag. 0.40E+00    7.0     0.00552679     -4911.5650060140 -2.52E-02
     9 Broy./Diag. 0.40E+00    7.0     0.00315705     -4911.5475260356  1.75E-02
    10 Broy./Diag. 0.40E+00    7.6     0.00211342     -4911.5479507478 -4.25E-04
    11 Broy./Diag. 0.40E+00    6.8     0.00196840     -4911.5499525910 -2.00E-03
    12 Broy./Diag. 0.40E+00    7.3     0.00093224     -4911.5536064424 -3.65E-03
    13 Broy./Diag. 0.40E+00    7.3     0.00041068     -4911.5489878886  4.62E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00061555     -4911.5478561660  1.13E-03
    15 Broy./Diag. 0.40E+00    7.5     0.00054326     -4911.5505915787 -2.74E-03
    16 Broy./Diag. 0.40E+00    7.0     0.00043365     -4911.5498806689  7.11E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00049779     -4911.5496243040  2.56E-04
    18 Broy./Diag. 0.40E+00    7.0     0.00036950     -4911.5488975908  7.27E-04
    19 Broy./Diag. 0.40E+00    7.3     0.00022499     -4911.5504438097 -1.55E-03
    20 Broy./Diag. 0.40E+00    6.8     0.00033689     -4911.5500601320  3.84E-04
    21 Broy./Diag. 0.40E+00    7.5     0.00030585     -4911.5487026551  1.36E-03
    22 Broy./Diag. 0.40E+00    7.2     0.00016138     -4911.5494144601 -7.12E-04
    23 Broy./Diag. 0.40E+00    7.3     0.00024933     -4911.5493746329  3.98E-05
    24 Broy./Diag. 0.40E+00    7.1     0.00020759     -4911.5497987761 -4.24E-04
    25 Broy./Diag. 0.40E+00    7.2     0.00011520     -4911.5490084131  7.90E-04
    26 Broy./Diag. 0.40E+00    7.3     0.00016852     -4911.5492332528 -2.25E-04
    27 Broy./Diag. 0.40E+00    7.5     0.00018594     -4911.5499267358 -6.93E-04
    28 Broy./Diag. 0.40E+00    7.3     0.00007971     -4911.5493537683  5.73E-04
    29 Broy./Diag. 0.40E+00    7.7     0.00011630     -4911.5493884637 -3.47E-05
    30 Broy./Diag. 0.40E+00    7.3     0.00009540     -4911.5491693383  2.19E-04
    31 Broy./Diag. 0.40E+00    7.1     0.00006967     -4911.5494914011 -3.22E-04
    32 Broy./Diag. 0.40E+00    7.3     0.00008061     -4911.5493738318  1.18E-04
    33 Broy./Diag. 0.40E+00    7.3     0.00010868     -4911.5490053071  3.69E-04
    34 Broy./Diag. 0.40E+00    7.1     0.00004903     -4911.5493801011 -3.75E-04
    35 Broy./Diag. 0.40E+00    7.2     0.00007536     -4911.5493274002  5.27E-05
    36 Broy./Diag. 0.40E+00    7.1     0.00006454     -4911.5494416765 -1.14E-04
    37 Broy./Diag. 0.40E+00    6.8     0.00004886     -4911.5491963527  2.45E-04
    38 Broy./Diag. 0.40E+00    7.1     0.00003226     -4911.5492621140 -6.58E-05
    39 Broy./Diag. 0.40E+00    6.9     0.00005718     -4911.5494011542 -1.39E-04
    40 Broy./Diag. 0.40E+00    7.2     0.00003298     -4911.5491921630  2.09E-04
    41 Broy./Diag. 0.40E+00    7.1     0.00003878     -4911.5492338352 -4.17E-05
    42 Broy./Diag. 0.40E+00    6.9     0.00004007     -4911.5491883211  4.55E-05
    43 Broy./Diag. 0.40E+00    6.9     0.00003395     -4911.5493412729 -1.53E-04
    44 Broy./Diag. 0.40E+00    7.1     0.00002943     -4911.5492797071  6.16E-05
    45 Broy./Diag. 0.40E+00    7.1     0.00003249     -4911.5491755315  1.04E-04
    46 Broy./Diag. 0.40E+00    7.3     0.00002089     -4911.5493068863 -1.31E-04
    47 Broy./Diag. 0.40E+00    6.8     0.00001869     -4911.5492700238  3.69E-05
    48 Broy./Diag. 0.40E+00    6.6     0.00002034     -4911.5492774188 -7.39E-06
    49 Broy./Diag. 0.40E+00    6.9     0.00001580     -4911.5492008724  7.65E-05
    50 Broy./Diag. 0.40E+00    7.3     0.00001976     -4911.5492418747 -4.10E-05
    51 Broy./Diag. 0.40E+00    6.9     0.00002085     -4911.5492918766 -5.00E-05
    52 Broy./Diag. 0.40E+00    7.1     0.00001684     -4911.5492010163  9.09E-05
    53 Broy./Diag. 0.40E+00    7.1     0.00001265     -4911.5492334715 -3.25E-05
    54 Broy./Diag. 0.40E+00    7.3     0.00001344     -4911.5492275890  5.88E-06
    55 Broy./Diag. 0.40E+00    7.1     0.00000824     -4911.5492725194 -4.49E-05
    56 Broy./Diag. 0.40E+00    7.5     0.00001197     -4911.5492392355  3.33E-05
    57 Broy./Diag. 0.40E+00    7.3     0.00000939     -4911.5492120956  2.71E-05
    58 Broy./Diag. 0.40E+00    7.3     0.00000962     -4911.5492574886 -4.54E-05
    59 Broy./Diag. 0.40E+00    7.3     0.00000759     -4911.5492361660  2.13E-05
    60 Broy./Diag. 0.40E+00    7.3     0.00000884     -4911.5492392008 -3.03E-06
    61 Broy./Diag. 0.40E+00    7.1     0.00000596     -4911.5492126872  2.65E-05
    62 Broy./Diag. 0.40E+00    7.9     0.00000849     -4911.5492360299 -2.33E-05
    63 Broy./Diag. 0.40E+00    7.5     0.00000556     -4911.5492514260 -1.54E-05
    64 Broy./Diag. 0.40E+00    6.9     0.00000572     -4911.5492205238  3.09E-05
    65 Broy./Diag. 0.40E+00    6.8     0.00000413     -4911.5492345034 -1.40E-05
    66 Broy./Diag. 0.40E+00    7.3     0.00000502     -4911.5492310085  3.49E-06
    67 Broy./Diag. 0.40E+00    7.1     0.00000362     -4911.5492429693 -1.20E-05
    68 Broy./Diag. 0.40E+00    6.9     0.00000534     -4911.5492286174  1.44E-05
    69 Broy./Diag. 0.40E+00    7.1     0.00000347     -4911.5492212281  7.39E-06
    70 Broy./Diag. 0.40E+00    8.0     0.00000407     -4911.5492404828 -1.93E-05
    71 Broy./Diag. 0.40E+00    7.1     0.00000252     -4911.5492295650  1.09E-05
    72 Broy./Diag. 0.40E+00    7.3     0.00000308     -4911.5492322225 -2.66E-06
    73 Broy./Diag. 0.40E+00    7.1     0.00000228     -4911.5492252483  6.97E-06
    74 Broy./Diag. 0.40E+00    7.2     0.00000290     -4911.5492333309 -8.08E-06
    75 Broy./Diag. 0.40E+00    7.5     0.00000226     -4911.5492350959 -1.77E-06
    76 Broy./Diag. 0.40E+00    6.9     0.00000247     -4911.5492240769  1.10E-05
    77 Broy./Diag. 0.40E+00    6.9     0.00000156     -4911.5492316288 -7.55E-06
    78 Broy./Diag. 0.40E+00    7.2     0.00000210     -4911.5492291158  2.51E-06
    79 Broy./Diag. 0.40E+00    6.8     0.00000160     -4911.5492332265 -4.11E-06
    80 Broy./Diag. 0.40E+00    7.1     0.00000177     -4911.5492278452  5.38E-06
    81 Broy./Diag. 0.40E+00    6.9     0.00000150     -4911.5492273633  4.82E-07
    82 Broy./Diag. 0.40E+00    6.9     0.00000157     -4911.5492335241 -6.16E-06
    83 Broy./Diag. 0.40E+00    7.1     0.00000084     -4911.5492282746  5.25E-06

  *** SCF run converged in    83 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008257280919
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.53427058744592
  Hartree energy:                                            1781.62933627010648
  Exchange-correlation energy:                               -779.37963199600495
  Electronic entropic energy:                                  -0.24286321586127
  Fermi energy:                                                 0.08676307902728

  Total energy:                                             -4911.54922827456994

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.549228758948630

 MD| ***************************************************************************
 MD| Step number                                                            1181
 MD| Time [fs]                                                       2362.000000
 MD| Conserved quantity [hartree]                            -0.491120136995E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    603.563034           593.558762
 MD| Energy drift per atom [K]           0.245391607479E+03   0.270236397601E+03
 MD| Potential energy [hartree]         -0.491154922876E+04  -0.491156390978E+04
 MD| Kinetic energy [hartree]            0.347858812801E+00   0.374493951014E+00
 MD| Temperature [K]                             926.961976           997.938359
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.01873833     -4911.5444219260 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.9     0.06964921     -4911.6682535316 -1.24E-01
     3 Broy./Diag. 0.40E+00    7.3     0.06924827     -4911.2980787602  3.70E-01
     4 Broy./Diag. 0.40E+00    6.9     0.02793003     -4911.6432004576 -3.45E-01
     5 Broy./Diag. 0.40E+00    6.9     0.01954372     -4911.5669528222  7.62E-02
     6 Broy./Diag. 0.40E+00    8.2     0.01193410     -4911.5435043561  2.34E-02
     7 Broy./Diag. 0.40E+00    7.2     0.00714053     -4911.5192167025  2.43E-02
     8 Broy./Diag. 0.40E+00    7.5     0.00352820     -4911.5619613390 -4.27E-02
     9 Broy./Diag. 0.40E+00    7.3     0.00296566     -4911.5491549039  1.28E-02
    10 Broy./Diag. 0.40E+00    6.9     0.00197646     -4911.5433787427  5.78E-03
    11 Broy./Diag. 0.40E+00    7.2     0.00204374     -4911.5497084429 -6.33E-03
    12 Broy./Diag. 0.40E+00    7.1     0.00122897     -4911.5485124374  1.20E-03
    13 Broy./Diag. 0.40E+00    7.5     0.00080789     -4911.5478015123  7.11E-04
    14 Broy./Diag. 0.40E+00    7.1     0.00057039     -4911.5438575935  3.94E-03
    15 Broy./Diag. 0.40E+00    7.7     0.00041622     -4911.5474771189 -3.62E-03
    16 Broy./Diag. 0.40E+00    7.1     0.00046853     -4911.5474269834  5.01E-05
    17 Broy./Diag. 0.40E+00    6.7     0.00036912     -4911.5464773947  9.50E-04
    18 Broy./Diag. 0.40E+00    6.9     0.00038851     -4911.5467981857 -3.21E-04
    19 Broy./Diag. 0.40E+00    6.8     0.00031030     -4911.5467894999  8.69E-06
    20 Broy./Diag. 0.40E+00    7.7     0.00026885     -4911.5475010950 -7.12E-04
    21 Broy./Diag. 0.40E+00    7.5     0.00026791     -4911.5459514410  1.55E-03
    22 Broy./Diag. 0.40E+00    6.9     0.00021482     -4911.5464545989 -5.03E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00018827     -4911.5466570207 -2.02E-04
    24 Broy./Diag. 0.40E+00    6.9     0.00019618     -4911.5466235226  3.35E-05
    25 Broy./Diag. 0.40E+00    7.1     0.00013642     -4911.5466987870 -7.53E-05
    26 Broy./Diag. 0.40E+00    7.3     0.00012609     -4911.5462823718  4.16E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00013056     -4911.5469931497 -7.11E-04
    28 Broy./Diag. 0.40E+00    7.0     0.00010643     -4911.5466098026  3.83E-04
    29 Broy./Diag. 0.40E+00    6.8     0.00009284     -4911.5465485536  6.12E-05
    30 Broy./Diag. 0.40E+00    7.5     0.00009763     -4911.5465203559  2.82E-05
    31 Broy./Diag. 0.40E+00    7.1     0.00007426     -4911.5464794766  4.09E-05
    32 Broy./Diag. 0.40E+00    7.1     0.00006953     -4911.5467299690 -2.50E-04
    33 Broy./Diag. 0.40E+00    7.5     0.00007569     -4911.5463174934  4.12E-04
    34 Broy./Diag. 0.40E+00    7.2     0.00006534     -4911.5465624234 -2.45E-04
    35 Broy./Diag. 0.40E+00    7.3     0.00005914     -4911.5465651898 -2.77E-06
    36 Broy./Diag. 0.40E+00    6.6     0.00005676     -4911.5465912258 -2.60E-05
    37 Broy./Diag. 0.40E+00    7.1     0.00004707     -4911.5465642588  2.70E-05
    38 Broy./Diag. 0.40E+00    7.1     0.00003737     -4911.5463845951  1.80E-04
    39 Broy./Diag. 0.40E+00    6.9     0.00004287     -4911.5466055091 -2.21E-04
    40 Broy./Diag. 0.40E+00    7.5     0.00004373     -4911.5464661859  1.39E-04
    41 Broy./Diag. 0.40E+00    7.3     0.00003386     -4911.5464753492 -9.16E-06
    42 Broy./Diag. 0.40E+00    7.3     0.00003422     -4911.5464499243  2.54E-05
    43 Broy./Diag. 0.40E+00    7.1     0.00003334     -4911.5464754922 -2.56E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00002181     -4911.5465855197 -1.10E-04
    45 Broy./Diag. 0.40E+00    7.3     0.00002282     -4911.5464288151  1.57E-04
    46 Broy./Diag. 0.40E+00    7.1     0.00002427     -4911.5465079199 -7.91E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00001894     -4911.5464986304  9.29E-06
    48 Broy./Diag. 0.40E+00    7.1     0.00001876     -4911.5465083721 -9.74E-06
    49 Broy./Diag. 0.40E+00    6.9     0.00002034     -4911.5464858792  2.25E-05
    50 Broy./Diag. 0.40E+00    7.3     0.00001357     -4911.5464244053  6.15E-05
    51 Broy./Diag. 0.40E+00    6.9     0.00001399     -4911.5465281244 -1.04E-04
    52 Broy./Diag. 0.40E+00    7.1     0.00001527     -4911.5464738050  5.43E-05
    53 Broy./Diag. 0.40E+00    7.5     0.00001190     -4911.5464779894 -4.18E-06
    54 Broy./Diag. 0.40E+00    7.5     0.00001209     -4911.5464708323  7.16E-06
    55 Broy./Diag. 0.40E+00    7.1     0.00001197     -4911.5464849596 -1.41E-05
    56 Broy./Diag. 0.40E+00    7.1     0.00000824     -4911.5465094663 -2.45E-05
    57 Broy./Diag. 0.40E+00    6.8     0.00000814     -4911.5464429803  6.65E-05
    58 Broy./Diag. 0.40E+00    7.1     0.00000915     -4911.5464799530 -3.70E-05
    59 Broy./Diag. 0.40E+00    7.1     0.00000817     -4911.5464776049  2.35E-06
    60 Broy./Diag. 0.40E+00    7.5     0.00000751     -4911.5464825489 -4.94E-06
    61 Broy./Diag. 0.40E+00    7.7     0.00000738     -4911.5464715383  1.10E-05
    62 Broy./Diag. 0.40E+00    7.7     0.00000506     -4911.5464568990  1.46E-05
    63 Broy./Diag. 0.40E+00    7.1     0.00000496     -4911.5464979363 -4.10E-05
    64 Broy./Diag. 0.40E+00    7.1     0.00000504     -4911.5464718112  2.61E-05
    65 Broy./Diag. 0.40E+00    7.1     0.00000480     -4911.5464733690 -1.56E-06
    66 Broy./Diag. 0.40E+00    7.3     0.00000484     -4911.5464705760  2.79E-06
    67 Broy./Diag. 0.40E+00    7.3     0.00000438     -4911.5464771863 -6.61E-06
    68 Broy./Diag. 0.40E+00    7.5     0.00000310     -4911.5464840184 -6.83E-06
    69 Broy./Diag. 0.40E+00    7.8     0.00000316     -4911.5464590176  2.50E-05
    70 Broy./Diag. 0.40E+00    7.5     0.00000324     -4911.5464772881 -1.83E-05
    71 Broy./Diag. 0.40E+00    6.9     0.00000301     -4911.5464752675  2.02E-06
    72 Broy./Diag. 0.40E+00    6.9     0.00000274     -4911.5464766203 -1.35E-06
    73 Broy./Diag. 0.40E+00    7.3     0.00000274     -4911.5464721369  4.48E-06
    74 Broy./Diag. 0.40E+00    7.3     0.00000238     -4911.5464675046  4.63E-06
    75 Broy./Diag. 0.40E+00    7.2     0.00000205     -4911.5464816156 -1.41E-05
    76 Broy./Diag. 0.40E+00    6.9     0.00000208     -4911.5464694828  1.21E-05
    77 Broy./Diag. 0.40E+00    6.7     0.00000188     -4911.5464718949 -2.41E-06
    78 Broy./Diag. 0.40E+00    7.2     0.00000187     -4911.5464710881  8.07E-07
    79 Broy./Diag. 0.40E+00    7.1     0.00000159     -4911.5464738674 -2.78E-06
    80 Broy./Diag. 0.40E+00    6.7     0.00000155     -4911.5464761598 -2.29E-06
    81 Broy./Diag. 0.40E+00    6.9     0.00000119     -4911.5464682371  7.92E-06
    82 Broy./Diag. 0.40E+00    6.9     0.00000137     -4911.5464755859 -7.35E-06
    83 Broy./Diag. 0.40E+00    7.3     0.00000118     -4911.5464734525  2.13E-06
    84 Broy./Diag. 0.40E+00    6.9     0.00000111     -4911.5464737302 -2.78E-07
    85 Broy./Diag. 0.40E+00    7.4     0.00000109     -4911.5464720785  1.65E-06
    86 Broy./Diag. 0.40E+00    7.9     0.00000118     -4911.5464705529  1.53E-06
    87 Broy./Diag. 0.40E+00    7.3     0.00000073     -4911.5464756551 -5.10E-06

  *** SCF run converged in    87 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008266815468
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.56819991476732
  Hartree energy:                                            1781.61078388609099
  Exchange-correlation energy:                               -779.39201892426445
  Electronic entropic energy:                                  -0.24310065918612
  Fermi energy:                                                 0.08680526294442

  Total energy:                                             -4911.54647565514097

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.546472678188366

 MD| ***************************************************************************
 MD| Step number                                                            1182
 MD| Time [fs]                                                       2364.000000
 MD| Conserved quantity [hartree]                            -0.491120586138E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    633.634820           593.592668
 MD| Energy drift per atom [K]           0.236060805309E+03   0.270207484241E+03
 MD| Potential energy [hartree]         -0.491154647268E+04  -0.491156389502E+04
 MD| Kinetic energy [hartree]            0.340611295064E+00   0.374465285484E+00
 MD| Temperature [K]                             907.649044           997.861972
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.01865204     -4911.5424598610 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.05252025     -4911.6366055136 -9.41E-02
     3 Broy./Diag. 0.40E+00    7.5     0.05482779     -4911.3786836755  2.58E-01
     4 Broy./Diag. 0.40E+00    7.5     0.02497083     -4911.5859981310 -2.07E-01
     5 Broy./Diag. 0.40E+00    7.3     0.01988024     -4911.6067767821 -2.08E-02
     6 Broy./Diag. 0.40E+00    7.1     0.01156214     -4911.5064011609  1.00E-01
     7 Broy./Diag. 0.40E+00    7.1     0.00695948     -4911.5437304038 -3.73E-02
     8 Broy./Diag. 0.40E+00    7.5     0.00372073     -4911.5488924891 -5.16E-03
     9 Broy./Diag. 0.40E+00    7.7     0.00279526     -4911.5477026595  1.19E-03
    10 Broy./Diag. 0.40E+00    7.3     0.00180929     -4911.5427315850  4.97E-03
    11 Broy./Diag. 0.40E+00    7.5     0.00190965     -4911.5423327377  3.99E-04
    12 Broy./Diag. 0.40E+00    6.6     0.00117027     -4911.5478126143 -5.48E-03
    13 Broy./Diag. 0.40E+00    7.1     0.00070704     -4911.5432193162  4.59E-03
    14 Broy./Diag. 0.40E+00    7.4     0.00053085     -4911.5440455461 -8.26E-04
    15 Broy./Diag. 0.40E+00    7.0     0.00044331     -4911.5447647263 -7.19E-04
    16 Broy./Diag. 0.40E+00    7.1     0.00037787     -4911.5447434210  2.13E-05
    17 Broy./Diag. 0.40E+00    7.7     0.00040279     -4911.5449702770 -2.27E-04
    18 Broy./Diag. 0.40E+00    7.5     0.00042750     -4911.5436024961  1.37E-03
    19 Broy./Diag. 0.40E+00    6.9     0.00029222     -4911.5449631514 -1.36E-03
    20 Broy./Diag. 0.40E+00    7.2     0.00030085     -4911.5445550950  4.08E-04
    21 Broy./Diag. 0.40E+00    7.2     0.00025674     -4911.5443173891  2.38E-04
    22 Broy./Diag. 0.40E+00    7.2     0.00021215     -4911.5445070149 -1.90E-04
    23 Broy./Diag. 0.40E+00    7.3     0.00016104     -4911.5441893088  3.18E-04
    24 Broy./Diag. 0.40E+00    7.1     0.00020480     -4911.5448753877 -6.86E-04
    25 Broy./Diag. 0.40E+00    7.4     0.00013537     -4911.5442512255  6.24E-04
    26 Broy./Diag. 0.40E+00    7.3     0.00015881     -4911.5444281185 -1.77E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00014284     -4911.5445079205 -7.98E-05
    28 Broy./Diag. 0.40E+00    7.1     0.00013663     -4911.5443857617  1.22E-04
    29 Broy./Diag. 0.40E+00    8.1     0.00010489     -4911.5446331082 -2.47E-04
    30 Broy./Diag. 0.40E+00    7.3     0.00013375     -4911.5441113922  5.22E-04
    31 Broy./Diag. 0.40E+00    9.8     0.00008488     -4911.5445151771 -4.04E-04
    32 Broy./Diag. 0.40E+00    7.0     0.00008310     -4911.5444361362  7.90E-05
    33 Broy./Diag. 0.40E+00   10.0     0.00006657     -4911.5444158344  2.03E-05
    34 Broy./Diag. 0.40E+00    8.3     0.00007225     -4911.5444370567 -2.12E-05
    35 Broy./Diag. 0.40E+00    7.2     0.00004899     -4911.5442914075  1.46E-04
    36 Broy./Diag. 0.40E+00    7.3     0.00008289     -4911.5445616471 -2.70E-04
    37 Broy./Diag. 0.40E+00    7.2     0.00006703     -4911.5443056700  2.56E-04
    38 Broy./Diag. 0.40E+00    6.9     0.00005210     -4911.5443645426 -5.89E-05
    39 Broy./Diag. 0.40E+00    8.4     0.00004596     -4911.5443842504 -1.97E-05
    40 Broy./Diag. 0.40E+00    6.9     0.00004600     -4911.5443844852 -2.35E-07
    41 Broy./Diag. 0.40E+00    8.1     0.00002977     -4911.5444763093 -9.18E-05
    42 Broy./Diag. 0.40E+00    8.5     0.00003923     -4911.5443073120  1.69E-04
    43 Broy./Diag. 0.40E+00    7.3     0.00003691     -4911.5444426246 -1.35E-04
    44 Broy./Diag. 0.40E+00    9.7     0.00002464     -4911.5444146850  2.79E-05
    45 Broy./Diag. 0.40E+00    8.6     0.00002907     -4911.5443995882  1.51E-05
    46 Broy./Diag. 0.40E+00    7.0     0.00003196     -4911.5443913744  8.21E-06
    47 Broy./Diag. 0.40E+00    6.5     0.00002214     -4911.5443345217  5.69E-05
    48 Broy./Diag. 0.40E+00    8.0     0.00002701     -4911.5444578674 -1.23E-04
    49 Broy./Diag. 0.40E+00    6.9     0.00002464     -4911.5443616134  9.63E-05
    50 Broy./Diag. 0.40E+00    8.3     0.00001276     -4911.5443822913 -2.07E-05
    51 Broy./Diag. 0.40E+00    8.4     0.00001651     -4911.5443936113 -1.13E-05
    52 Broy./Diag. 0.40E+00    7.2     0.00001624     -4911.5444001477 -6.54E-06
    53 Broy./Diag. 0.40E+00    8.9     0.00001337     -4911.5444198950 -1.97E-05
    54 Broy./Diag. 0.40E+00    9.8     0.00001551     -4911.5443448551  7.50E-05
    55 Broy./Diag. 0.40E+00    7.3     0.00001674     -4911.5444107134 -6.59E-05
    56 Broy./Diag. 0.40E+00    6.9     0.00000826     -4911.5443975228  1.32E-05
    57 Broy./Diag. 0.40E+00    7.1     0.00001135     -4911.5443902659  7.26E-06
    58 Broy./Diag. 0.40E+00    7.7     0.00001015     -4911.5443857725  4.49E-06
    59 Broy./Diag. 0.40E+00    7.1     0.00000792     -4911.5443754631  1.03E-05
    60 Broy./Diag. 0.40E+00    7.3     0.00000863     -4911.5444184930 -4.30E-05
    61 Broy./Diag. 0.40E+00    7.1     0.00000916     -4911.5443794943  3.90E-05
    62 Broy./Diag. 0.40E+00    7.9     0.00000511     -4911.5443891056 -9.61E-06
    63 Broy./Diag. 0.40E+00    7.4     0.00000778     -4911.5443937059 -4.60E-06
    64 Broy./Diag. 0.40E+00    7.3     0.00000659     -4911.5443968660 -3.16E-06
    65 Broy./Diag. 0.40E+00    7.4     0.00000574     -4911.5444016657 -4.80E-06
    66 Broy./Diag. 0.40E+00    7.3     0.00000553     -4911.5443713027  3.04E-05
    67 Broy./Diag. 0.40E+00    7.5     0.00000587     -4911.5444002201 -2.89E-05
    68 Broy./Diag. 0.40E+00    7.1     0.00000333     -4911.5443940403  6.18E-06
    69 Broy./Diag. 0.40E+00    6.7     0.00000431     -4911.5443922312  1.81E-06
    70 Broy./Diag. 0.40E+00    7.1     0.00000389     -4911.5443905279  1.70E-06
    71 Broy./Diag. 0.40E+00    7.3     0.00000349     -4911.5443877506  2.78E-06
    72 Broy./Diag. 0.40E+00    6.9     0.00000356     -4911.5444042399 -1.65E-05
    73 Broy./Diag. 0.40E+00    6.9     0.00000405     -4911.5443852237  1.90E-05
    74 Broy./Diag. 0.40E+00    7.3     0.00000243     -4911.5443911741 -5.95E-06
    75 Broy./Diag. 0.40E+00    7.0     0.00000308     -4911.5443924087 -1.23E-06
    76 Broy./Diag. 0.40E+00    7.1     0.00000231     -4911.5443938281 -1.42E-06
    77 Broy./Diag. 0.40E+00    7.5     0.00000209     -4911.5443954426 -1.61E-06
    78 Broy./Diag. 0.40E+00    8.1     0.00000189     -4911.5443861160  9.33E-06
    79 Broy./Diag. 0.40E+00    6.7     0.00000251     -4911.5443972846 -1.12E-05
    80 Broy./Diag. 0.40E+00    7.0     0.00000161     -4911.5443934847  3.80E-06
    81 Broy./Diag. 0.40E+00    7.1     0.00000192     -4911.5443932336  2.51E-07
    82 Broy./Diag. 0.40E+00    7.3     0.00000167     -4911.5443923404  8.93E-07
    83 Broy./Diag. 0.40E+00    7.2     0.00000147     -4911.5443911897  1.15E-06
    84 Broy./Diag. 0.40E+00    7.0     0.00000120     -4911.5443973340 -6.14E-06
    85 Broy./Diag. 0.40E+00    7.3     0.00000159     -4911.5443901335  7.20E-06
    86 Broy./Diag. 0.40E+00    7.1     0.00000104     -4911.5443932027 -3.07E-06
    87 Broy./Diag. 0.40E+00    7.4     0.00000112     -4911.5443933320 -1.29E-07
    88 Broy./Diag. 0.40E+00    7.1     0.00000090     -4911.5443938775 -5.46E-07

  *** SCF run converged in    88 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008273897016
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.59322948196314
  Hartree energy:                                            1781.59747386777963
  Exchange-correlation energy:                               -779.40147996040389
  Electronic entropic energy:                                  -0.24327750828697
  Fermi energy:                                                 0.08683552672610

  Total energy:                                             -4911.54439387754246

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.544394038278369

 MD| ***************************************************************************
 MD| Step number                                                            1183
 MD| Time [fs]                                                       2366.000000
 MD| Conserved quantity [hartree]                            -0.491120762821E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    664.958421           593.652994
 MD| Energy drift per atom [K]           0.232390281298E+03   0.270175517036E+03
 MD| Potential energy [hartree]         -0.491154439404E+04  -0.491156387854E+04
 MD| Kinetic energy [hartree]            0.336765826647E+00   0.374433417810E+00
 MD| Temperature [K]                             897.401775           997.777052
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.01649590     -4911.5415368764 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.04156696     -4911.6051498395 -6.36E-02
     3 Broy./Diag. 0.40E+00    7.1     0.06368451     -4911.4489677245  1.56E-01
     4 Broy./Diag. 0.40E+00    6.9     0.04832529     -4911.5330812041 -8.41E-02
     5 Broy./Diag. 0.40E+00    6.9     0.02027409     -4911.6216463306 -8.86E-02
     6 Broy./Diag. 0.40E+00    6.9     0.01050248     -4911.5150400445  1.07E-01
     7 Broy./Diag. 0.40E+00    7.1     0.00757006     -4911.5375251964 -2.25E-02
     8 Broy./Diag. 0.40E+00    6.9     0.00252905     -4911.5498314158 -1.23E-02
     9 Broy./Diag. 0.40E+00    7.1     0.00188600     -4911.5436884965  6.14E-03
    10 Broy./Diag. 0.40E+00    7.7     0.00262858     -4911.5439953396 -3.07E-04
    11 Broy./Diag. 0.40E+00    7.5     0.00207378     -4911.5401680267  3.83E-03
    12 Broy./Diag. 0.40E+00    7.1     0.00054185     -4911.5443581303 -4.19E-03
    13 Broy./Diag. 0.40E+00    7.5     0.00063765     -4911.5426320411  1.73E-03
    14 Broy./Diag. 0.40E+00    7.5     0.00045660     -4911.5430453133 -4.13E-04
    15 Broy./Diag. 0.40E+00    7.1     0.00029174     -4911.5435142814 -4.69E-04
    16 Broy./Diag. 0.40E+00    7.3     0.00029317     -4911.5430434939  4.71E-04
    17 Broy./Diag. 0.40E+00    7.0     0.00045932     -4911.5438486280 -8.05E-04
    18 Broy./Diag. 0.40E+00    7.0     0.00032598     -4911.5426825533  1.17E-03
    19 Broy./Diag. 0.40E+00    7.1     0.00020005     -4911.5432417086 -5.59E-04
    20 Broy./Diag. 0.40E+00    7.3     0.00028923     -4911.5434126148 -1.71E-04
    21 Broy./Diag. 0.40E+00    6.9     0.00015151     -4911.5432285334  1.84E-04
    22 Broy./Diag. 0.40E+00    6.8     0.00013669     -4911.5435052977 -2.77E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00016910     -4911.5429996918  5.06E-04
    24 Broy./Diag. 0.40E+00    7.1     0.00011903     -4911.5435423250 -5.43E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00008892     -4911.5433633818  1.79E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00010858     -4911.5432639768  9.94E-05
    27 Broy./Diag. 0.40E+00    6.9     0.00009400     -4911.5433351715 -7.12E-05
    28 Broy./Diag. 0.40E+00    7.4     0.00008727     -4911.5432862687  4.89E-05
    29 Broy./Diag. 0.40E+00    7.5     0.00012188     -4911.5436066851 -3.20E-04
    30 Broy./Diag. 0.40E+00    7.1     0.00009986     -4911.5431730841  4.34E-04
    31 Broy./Diag. 0.40E+00    7.1     0.00006704     -4911.5433390192 -1.66E-04
    32 Broy./Diag. 0.40E+00    7.3     0.00005781     -4911.5434402167 -1.01E-04
    33 Broy./Diag. 0.40E+00    7.1     0.00005573     -4911.5434012921  3.89E-05
    34 Broy./Diag. 0.40E+00    7.1     0.00004308     -4911.5434024217 -1.13E-06
    35 Broy./Diag. 0.40E+00    7.0     0.00005039     -4911.5432547296  1.48E-04
    36 Broy./Diag. 0.40E+00    7.1     0.00005692     -4911.5434874260 -2.33E-04
    37 Broy./Diag. 0.40E+00    6.9     0.00005245     -4911.5433889029  9.85E-05
    38 Broy./Diag. 0.40E+00    7.5     0.00003683     -4911.5433228154  6.61E-05
    39 Broy./Diag. 0.40E+00    7.2     0.00004532     -4911.5433831349 -6.03E-05
    40 Broy./Diag. 0.40E+00    7.2     0.00002620     -4911.5433898838 -6.75E-06
    41 Broy./Diag. 0.40E+00    7.5     0.00002776     -4911.5434750999 -8.52E-05
    42 Broy./Diag. 0.40E+00    7.0     0.00002766     -4911.5433424213  1.33E-04
    43 Broy./Diag. 0.40E+00    7.1     0.00002383     -4911.5433997017 -5.73E-05
    44 Broy./Diag. 0.40E+00    7.4     0.00001684     -4911.5434331262 -3.34E-05
    45 Broy./Diag. 0.40E+00    7.1     0.00002605     -4911.5434022822  3.08E-05
    46 Broy./Diag. 0.40E+00    6.9     0.00001742     -4911.5433976163  4.67E-06
    47 Broy./Diag. 0.40E+00    7.2     0.00002032     -4911.5433539539  4.37E-05
    48 Broy./Diag. 0.40E+00    7.8     0.00002064     -4911.5434595449 -1.06E-04
    49 Broy./Diag. 0.40E+00    6.9     0.00001785     -4911.5434144566  4.51E-05
    50 Broy./Diag. 0.40E+00    6.7     0.00000926     -4911.5433944046  2.01E-05
    51 Broy./Diag. 0.40E+00    6.9     0.00001370     -4911.5434176875 -2.33E-05
    52 Broy./Diag. 0.40E+00    7.5     0.00000775     -4911.5434224118 -4.72E-06
    53 Broy./Diag. 0.40E+00    7.1     0.00001190     -4911.5434360944 -1.37E-05
    54 Broy./Diag. 0.40E+00    7.2     0.00001292     -4911.5433753399  6.08E-05
    55 Broy./Diag. 0.40E+00    7.1     0.00001212     -4911.5434176012 -4.23E-05
    56 Broy./Diag. 0.40E+00    7.9     0.00000685     -4911.5434323809 -1.48E-05
    57 Broy./Diag. 0.40E+00    7.1     0.00000998     -4911.5434154024  1.70E-05
    58 Broy./Diag. 0.40E+00    7.1     0.00000519     -4911.5434145669  8.36E-07
    59 Broy./Diag. 0.40E+00    7.0     0.00000635     -4911.5434071519  7.42E-06
    60 Broy./Diag. 0.40E+00    7.1     0.00000640     -4911.5434409374 -3.38E-05
    61 Broy./Diag. 0.40E+00    6.7     0.00000620     -4911.5434190441  2.19E-05
    62 Broy./Diag. 0.40E+00    7.3     0.00000434     -4911.5434132988  5.75E-06
    63 Broy./Diag. 0.40E+00    6.9     0.00000634     -4911.5434248444 -1.15E-05
    64 Broy./Diag. 0.40E+00    7.1     0.00000350     -4911.5434266838 -1.84E-06
    65 Broy./Diag. 0.40E+00    7.3     0.00000477     -4911.5434306886 -4.00E-06
    66 Broy./Diag. 0.40E+00    7.3     0.00000484     -4911.5434062239  2.45E-05
    67 Broy./Diag. 0.40E+00    7.1     0.00000396     -4911.5434261480 -1.99E-05
    68 Broy./Diag. 0.40E+00    7.3     0.00000284     -4911.5434300222 -3.87E-06
    69 Broy./Diag. 0.40E+00    6.9     0.00000327     -4911.5434242033  5.82E-06
    70 Broy./Diag. 0.40E+00    7.1     0.00000212     -4911.5434238201  3.83E-07
    71 Broy./Diag. 0.40E+00    7.3     0.00000254     -4911.5434218450  1.98E-06
    72 Broy./Diag. 0.40E+00    7.1     0.00000311     -4911.5434351488 -1.33E-05
    73 Broy./Diag. 0.40E+00    7.6     0.00000279     -4911.5434224635  1.27E-05
    74 Broy./Diag. 0.40E+00    6.7     0.00000233     -4911.5434215678  8.96E-07
    75 Broy./Diag. 0.40E+00    7.1     0.00000233     -4911.5434269323 -5.36E-06
    76 Broy./Diag. 0.40E+00    7.1     0.00000136     -4911.5434275991 -6.67E-07
    77 Broy./Diag. 0.40E+00    7.1     0.00000145     -4911.5434288843 -1.29E-06
    78 Broy./Diag. 0.40E+00    7.6     0.00000172     -4911.5434217875  7.10E-06
    79 Broy./Diag. 0.40E+00    7.1     0.00000146     -4911.5434294002 -7.61E-06
    80 Broy./Diag. 0.40E+00    7.9     0.00000146     -4911.5434296939 -2.94E-07
    81 Broy./Diag. 0.40E+00    7.1     0.00000142     -4911.5434269845  2.71E-06
    82 Broy./Diag. 0.40E+00    7.1     0.00000110     -4911.5434269841  4.53E-10
    83 Broy./Diag. 0.40E+00    7.0     0.00000100     -4911.5434262845  7.00E-07
    84 Broy./Diag. 0.40E+00    6.9     0.00000114     -4911.5434313111 -5.03E-06
    85 Broy./Diag. 0.40E+00    7.3     0.00000093     -4911.5434264055  4.91E-06

  *** SCF run converged in    85 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008276809067
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.60532747109755
  Hartree energy:                                            1781.59140659245418
  Exchange-correlation energy:                               -779.40642201175069
  Electronic entropic energy:                                  -0.24339871158112
  Fermi energy:                                                 0.08685235303095

  Total energy:                                             -4911.54342640546565

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.543429738063423

 MD| ***************************************************************************
 MD| Step number                                                            1184
 MD| Time [fs]                                                       2368.000000
 MD| Conserved quantity [hartree]                            -0.491121937094E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    617.198008           593.672880
 MD| Energy drift per atom [K]           0.207995173031E+03   0.270122999854E+03
 MD| Potential energy [hartree]         -0.491154342974E+04  -0.491156386127E+04
 MD| Kinetic energy [hartree]            0.324058796352E+00   0.374390871677E+00
 MD| Temperature [K]                             863.540526           997.663677
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.01758885     -4911.5418073239 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.7     0.02206990     -4911.5905021010 -4.87E-02
     3 Broy./Diag. 0.40E+00    7.3     0.03700104     -4911.4483926392  1.42E-01
     4 Broy./Diag. 0.40E+00    7.7     0.03359557     -4911.6189509971 -1.71E-01
     5 Broy./Diag. 0.40E+00    6.9     0.01820824     -4911.5732087935  4.57E-02
     6 Broy./Diag. 0.40E+00    7.5     0.01077572     -4911.4951083514  7.81E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00603413     -4911.5522322150 -5.71E-02
     8 Broy./Diag. 0.40E+00    7.1     0.00306251     -4911.5411277824  1.11E-02
     9 Broy./Diag. 0.40E+00    6.9     0.00219962     -4911.5452596137 -4.13E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00145048     -4911.5395651059  5.69E-03
    11 Broy./Diag. 0.40E+00    7.5     0.00146057     -4911.5446680381 -5.10E-03
    12 Broy./Diag. 0.40E+00    7.1     0.00070297     -4911.5450487411 -3.81E-04
    13 Broy./Diag. 0.40E+00    7.1     0.00066662     -4911.5411996128  3.85E-03
    14 Broy./Diag. 0.40E+00    7.3     0.00034659     -4911.5440095213 -2.81E-03
    15 Broy./Diag. 0.40E+00    6.8     0.00034298     -4911.5435715485  4.38E-04
    16 Broy./Diag. 0.40E+00    6.9     0.00032285     -4911.5440319712 -4.60E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00041466     -4911.5432188278  8.13E-04
    18 Broy./Diag. 0.40E+00    7.3     0.00037134     -4911.5431448963  7.39E-05
    19 Broy./Diag. 0.40E+00    6.9     0.00026514     -4911.5443681569 -1.22E-03
    20 Broy./Diag. 0.40E+00    6.8     0.00022947     -4911.5431209327  1.25E-03
    21 Broy./Diag. 0.40E+00    7.2     0.00019026     -4911.5435195076 -3.99E-04
    22 Broy./Diag. 0.40E+00    7.1     0.00014872     -4911.5434590482  6.05E-05
    23 Broy./Diag. 0.40E+00    7.3     0.00011959     -4911.5437585728 -3.00E-04
    24 Broy./Diag. 0.40E+00    7.1     0.00012082     -4911.5436929320  6.56E-05
    25 Broy./Diag. 0.40E+00    7.5     0.00009928     -4911.5433901956  3.03E-04
    26 Broy./Diag. 0.40E+00    6.9     0.00010663     -4911.5439152603 -5.25E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00009926     -4911.5436698481  2.45E-04
    28 Broy./Diag. 0.40E+00    7.4     0.00011163     -4911.5436813479 -1.15E-05
    29 Broy./Diag. 0.40E+00    7.2     0.00009824     -4911.5435105577  1.71E-04
    30 Broy./Diag. 0.40E+00    6.9     0.00010580     -4911.5436341276 -1.24E-04
    31 Broy./Diag. 0.40E+00    7.3     0.00005988     -4911.5438656314 -2.32E-04
    32 Broy./Diag. 0.40E+00    6.9     0.00005952     -4911.5435112154  3.54E-04
    33 Broy./Diag. 0.40E+00    7.1     0.00004418     -4911.5436893551 -1.78E-04
    34 Broy./Diag. 0.40E+00    7.3     0.00005096     -4911.5436965603 -7.21E-06
    35 Broy./Diag. 0.40E+00    7.3     0.00003347     -4911.5437600275 -6.35E-05
    36 Broy./Diag. 0.40E+00    7.1     0.00006403     -4911.5436740225  8.60E-05
    37 Broy./Diag. 0.40E+00    7.3     0.00004132     -4911.5435372664  1.37E-04
    38 Broy./Diag. 0.40E+00    7.3     0.00004911     -4911.5438394869 -3.02E-04
    39 Broy./Diag. 0.40E+00    7.3     0.00003082     -4911.5436818901  1.58E-04
    40 Broy./Diag. 0.40E+00    7.9     0.00003315     -4911.5436805786  1.31E-06
    41 Broy./Diag. 0.40E+00    7.4     0.00001582     -4911.5436585475  2.20E-05
    42 Broy./Diag. 0.40E+00    7.3     0.00002420     -4911.5437134202 -5.49E-05
    43 Broy./Diag. 0.40E+00    7.1     0.00001716     -4911.5437561787 -4.28E-05
    44 Broy./Diag. 0.40E+00    6.9     0.00002317     -4911.5436497110  1.06E-04
    45 Broy./Diag. 0.40E+00    7.6     0.00001597     -4911.5437322415 -8.25E-05
    46 Broy./Diag. 0.40E+00    7.4     0.00002329     -4911.5437337413 -1.50E-06
    47 Broy./Diag. 0.40E+00    7.4     0.00001295     -4911.5437450632 -1.13E-05
    48 Broy./Diag. 0.40E+00    7.3     0.00002004     -4911.5436996120  4.55E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00001412     -4911.5436700885  2.95E-05
    50 Broy./Diag. 0.40E+00    7.3     0.00001255     -4911.5437539060 -8.38E-05
    51 Broy./Diag. 0.40E+00    6.9     0.00000754     -4911.5437084223  4.55E-05
    52 Broy./Diag. 0.40E+00    7.4     0.00001049     -4911.5437155348 -7.11E-06
    53 Broy./Diag. 0.40E+00    8.1     0.00000806     -4911.5437140165  1.52E-06
    54 Broy./Diag. 0.40E+00    7.5     0.00001042     -4911.5437390166 -2.50E-05
    55 Broy./Diag. 0.40E+00    7.3     0.00000967     -4911.5437455760 -6.56E-06
    56 Broy./Diag. 0.40E+00    6.9     0.00000970     -4911.5436912215  5.44E-05
    57 Broy./Diag. 0.40E+00    7.1     0.00000708     -4911.5437336550 -4.24E-05
    58 Broy./Diag. 0.40E+00    7.1     0.00000655     -4911.5437281885  5.47E-06
    59 Broy./Diag. 0.40E+00    7.1     0.00000473     -4911.5437312084 -3.02E-06
    60 Broy./Diag. 0.40E+00    6.7     0.00000515     -4911.5437202787  1.09E-05
    61 Broy./Diag. 0.40E+00    6.9     0.00000477     -4911.5437192488  1.03E-06
    62 Broy./Diag. 0.40E+00    7.9     0.00000428     -4911.5437431328 -2.39E-05
    63 Broy./Diag. 0.40E+00    7.1     0.00000458     -4911.5437230102  2.01E-05
    64 Broy./Diag. 0.40E+00    7.2     0.00000460     -4911.5437286095 -5.60E-06
    65 Broy./Diag. 0.40E+00    6.6     0.00000401     -4911.5437273437  1.27E-06
    66 Broy./Diag. 0.40E+00    7.3     0.00000375     -4911.5437358563 -8.51E-06
    67 Broy./Diag. 0.40E+00    6.7     0.00000343     -4911.5437362351 -3.79E-07
    68 Broy./Diag. 0.40E+00    6.9     0.00000227     -4911.5437205821  1.57E-05
    69 Broy./Diag. 0.40E+00    6.8     0.00000257     -4911.5437346696 -1.41E-05
    70 Broy./Diag. 0.40E+00    8.5     0.00000224     -4911.5437314447  3.22E-06
    71 Broy./Diag. 0.40E+00    6.8     0.00000223     -4911.5437331158 -1.67E-06
    72 Broy./Diag. 0.40E+00    6.9     0.00000252     -4911.5437297479  3.37E-06
    73 Broy./Diag. 0.40E+00    7.1     0.00000251     -4911.5437292814  4.67E-07
    74 Broy./Diag. 0.40E+00    7.3     0.00000150     -4911.5437389413 -9.66E-06
    75 Broy./Diag. 0.40E+00    7.0     0.00000197     -4911.5437294690  9.47E-06
    76 Broy./Diag. 0.40E+00    6.9     0.00000146     -4911.5437330813 -3.61E-06
    77 Broy./Diag. 0.40E+00    7.3     0.00000136     -4911.5437322055  8.76E-07
    78 Broy./Diag. 0.40E+00    7.3     0.00000120     -4911.5437343890 -2.18E-06
    79 Broy./Diag. 0.40E+00    7.0     0.00000138     -4911.5437347064 -3.17E-07
    80 Broy./Diag. 0.40E+00    7.1     0.00000075     -4911.5437302207  4.49E-06

  *** SCF run converged in    80 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008276172499
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.61340497270749
  Hartree energy:                                            1781.58673707490038
  Exchange-correlation energy:                               -779.41003374153627
  Electronic entropic energy:                                  -0.24349881113130
  Fermi energy:                                                 0.08686884639937

  Total energy:                                             -4911.54373022071741

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.543735709536122

 MD| ***************************************************************************
 MD| Step number                                                            1185
 MD| Time [fs]                                                       2370.000000
 MD| Conserved quantity [hartree]                            -0.491120431637E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    584.389432           593.665046
 MD| Energy drift per atom [K]           0.239270525604E+03   0.270096964010E+03
 MD| Potential energy [hartree]         -0.491154373571E+04  -0.491156384428E+04
 MD| Kinetic energy [hartree]            0.339419344316E+00   0.374361359839E+00
 MD| Temperature [K]                             904.472776           997.585035
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.01918640     -4911.5430170053 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.0     0.04231450     -4911.6231859473 -8.02E-02
     3 Broy./Diag. 0.40E+00    7.5     0.05927778     -4911.3360365923  2.87E-01
     4 Broy./Diag. 0.40E+00    7.1     0.03409768     -4911.7217848005 -3.86E-01
     5 Broy./Diag. 0.40E+00    7.3     0.01921159     -4911.5247913692  1.97E-01
     6 Broy./Diag. 0.40E+00    7.3     0.01403828     -4911.5444338968 -1.96E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00505061     -4911.5368574998  7.58E-03
     8 Broy./Diag. 0.40E+00    7.1     0.00324029     -4911.5512980181 -1.44E-02
     9 Broy./Diag. 0.40E+00    7.3     0.00259702     -4911.5472310292  4.07E-03
    10 Broy./Diag. 0.40E+00    7.3     0.00181266     -4911.5367742692  1.05E-02
    11 Broy./Diag. 0.40E+00    7.1     0.00152500     -4911.5512331847 -1.45E-02
    12 Broy./Diag. 0.40E+00    6.6     0.00110702     -4911.5449860554  6.25E-03
    13 Broy./Diag. 0.40E+00    7.0     0.00055601     -4911.5448906155  9.54E-05
    14 Broy./Diag. 0.40E+00    6.7     0.00032970     -4911.5440708218  8.20E-04
    15 Broy./Diag. 0.40E+00    7.1     0.00033391     -4911.5451733006 -1.10E-03
    16 Broy./Diag. 0.40E+00    6.7     0.00032918     -4911.5459240794 -7.51E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00026244     -4911.5436385995  2.29E-03
    18 Broy./Diag. 0.40E+00    7.1     0.00035580     -4911.5452690724 -1.63E-03
    19 Broy./Diag. 0.40E+00    6.7     0.00025823     -4911.5451796657  8.94E-05
    20 Broy./Diag. 0.40E+00    7.9     0.00014466     -4911.5451224014  5.73E-05
    21 Broy./Diag. 0.40E+00    7.4     0.00018882     -4911.5447618717  3.61E-04
    22 Broy./Diag. 0.40E+00    9.9     0.00016382     -4911.5446449637  1.17E-04
    23 Broy./Diag. 0.40E+00    7.3     0.00011536     -4911.5454474297 -8.02E-04
    24 Broy./Diag. 0.40E+00    7.9     0.00011618     -4911.5447166308  7.31E-04
    25 Broy./Diag. 0.40E+00   11.7     0.00010101     -4911.5449630464 -2.46E-04
    26 Broy./Diag. 0.40E+00    7.4     0.00007627     -4911.5449383498  2.47E-05
    27 Broy./Diag. 0.40E+00    7.1     0.00007654     -4911.5450035483 -6.52E-05
    28 Broy./Diag. 0.40E+00    7.3     0.00008846     -4911.5450874331 -8.39E-05
    29 Broy./Diag. 0.40E+00    7.5     0.00006588     -4911.5447643981  3.23E-04
    30 Broy./Diag. 0.40E+00    8.3     0.00007292     -4911.5451856788 -4.21E-04
    31 Broy./Diag. 0.40E+00    7.5     0.00006283     -4911.5449838054  2.02E-04
    32 Broy./Diag. 0.40E+00    9.2     0.00004229     -4911.5450022895 -1.85E-05
    33 Broy./Diag. 0.40E+00    7.3     0.00004026     -4911.5450058240 -3.53E-06
    34 Broy./Diag. 0.40E+00    8.3     0.00004984     -4911.5449596750  4.61E-05
    35 Broy./Diag. 0.40E+00    9.8     0.00003332     -4911.5451145987 -1.55E-04
    36 Broy./Diag. 0.40E+00    7.2     0.00003958     -4911.5449096054  2.05E-04
    37 Broy./Diag. 0.40E+00    7.3     0.00004355     -4911.5450503363 -1.41E-04
    38 Broy./Diag. 0.40E+00    7.3     0.00003131     -4911.5450398206  1.05E-05
    39 Broy./Diag. 0.40E+00    8.1     0.00002483     -4911.5450256524  1.42E-05
    40 Broy./Diag. 0.40E+00    7.1     0.00003421     -4911.5450599730 -3.43E-05
    41 Broy./Diag. 0.40E+00    9.8     0.00001781     -4911.5449677347  9.22E-05
    42 Broy./Diag. 0.40E+00    7.7     0.00002239     -4911.5450874882 -1.20E-04
    43 Broy./Diag. 0.40E+00    8.3     0.00001783     -4911.5450059172  8.16E-05
    44 Broy./Diag. 0.40E+00   10.7     0.00001483     -4911.5450225181 -1.66E-05
    45 Broy./Diag. 0.40E+00    7.1     0.00001204     -4911.5450357168 -1.32E-05
    46 Broy./Diag. 0.40E+00    7.3     0.00002120     -4911.5450251346  1.06E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00001379     -4911.5450782160 -5.31E-05
    48 Broy./Diag. 0.40E+00    7.3     0.00001547     -4911.5449978714  8.03E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00001305     -4911.5450609269 -6.31E-05
    50 Broy./Diag. 0.40E+00    7.1     0.00000987     -4911.5450495197  1.14E-05
    51 Broy./Diag. 0.40E+00    7.7     0.00000607     -4911.5450408056  8.71E-06
    52 Broy./Diag. 0.40E+00    8.0     0.00000976     -4911.5450480837 -7.28E-06
    53 Broy./Diag. 0.40E+00    7.1     0.00000804     -4911.5450276291  2.05E-05
    54 Broy./Diag. 0.40E+00    7.3     0.00000975     -4911.5450698885 -4.23E-05
    55 Broy./Diag. 0.40E+00    6.9     0.00000820     -4911.5450298658  4.00E-05
    56 Broy./Diag. 0.40E+00    7.1     0.00000750     -4911.5450454867 -1.56E-05
    57 Broy./Diag. 0.40E+00    6.9     0.00000584     -4911.5450525325 -7.05E-06
    58 Broy./Diag. 0.40E+00    7.1     0.00000630     -4911.5450479950  4.54E-06
    59 Broy./Diag. 0.40E+00    7.1     0.00000508     -4911.5450615923 -1.36E-05
    60 Broy./Diag. 0.40E+00    6.7     0.00000407     -4911.5450372210  2.44E-05
    61 Broy./Diag. 0.40E+00    7.1     0.00000404     -4911.5450584988 -2.13E-05
    62 Broy./Diag. 0.40E+00    7.1     0.00000375     -4911.5450512023  7.30E-06
    63 Broy./Diag. 0.40E+00    6.9     0.00000343     -4911.5450491816  2.02E-06
    64 Broy./Diag. 0.40E+00    7.5     0.00000401     -4911.5450528549 -3.67E-06
    65 Broy./Diag. 0.40E+00    7.1     0.00000390     -4911.5450459227  6.93E-06
    66 Broy./Diag. 0.40E+00    7.3     0.00000300     -4911.5450636583 -1.77E-05
    67 Broy./Diag. 0.40E+00    7.1     0.00000273     -4911.5450475081  1.62E-05
    68 Broy./Diag. 0.40E+00    6.9     0.00000229     -4911.5450538521 -6.34E-06
    69 Broy./Diag. 0.40E+00    7.9     0.00000199     -4911.5450557793 -1.93E-06
    70 Broy./Diag. 0.40E+00    7.3     0.00000196     -4911.5450540717  1.71E-06
    71 Broy./Diag. 0.40E+00    7.3     0.00000218     -4911.5450576417 -3.57E-06
    72 Broy./Diag. 0.40E+00    7.5     0.00000161     -4911.5450490197  8.62E-06
    73 Broy./Diag. 0.40E+00    7.1     0.00000196     -4911.5450595277 -1.05E-05
    74 Broy./Diag. 0.40E+00    7.3     0.00000174     -4911.5450551009  4.43E-06
    75 Broy./Diag. 0.40E+00    7.0     0.00000145     -4911.5450547033  3.98E-07
    76 Broy./Diag. 0.40E+00    7.1     0.00000135     -4911.5450562838 -1.58E-06
    77 Broy./Diag. 0.40E+00    7.3     0.00000132     -4911.5450542230  2.06E-06
    78 Broy./Diag. 0.40E+00    7.3     0.00000087     -4911.5450593325 -5.11E-06

  *** SCF run converged in    78 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008273546900
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.62304691236977
  Hartree energy:                                            1781.58018631864388
  Exchange-correlation energy:                               -779.41439896650604
  Electronic entropic energy:                                  -0.24355379078499
  Fermi energy:                                                 0.08689476878200

  Total energy:                                             -4911.54505933245855

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.545058416545544

 MD| ***************************************************************************
 MD| Step number                                                            1186
 MD| Time [fs]                                                       2372.000000
 MD| Conserved quantity [hartree]                            -0.491120853536E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    592.882549           593.664386
 MD| Energy drift per atom [K]           0.230505705464E+03   0.270063581836E+03
 MD| Potential energy [hartree]         -0.491154505842E+04  -0.491156382844E+04
 MD| Kinetic energy [hartree]            0.336523053157E+00   0.374329455702E+00
 MD| Temperature [K]                             896.754841           997.500018
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.01909523     -4911.5448376690 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.06625747     -4911.6405413303 -9.57E-02
     3 Broy./Diag. 0.40E+00    6.7     0.07572063     -4911.2582714806  3.82E-01
     4 Broy./Diag. 0.40E+00    7.7     0.04703725     -4911.6873280452 -4.29E-01
     5 Broy./Diag. 0.40E+00    7.3     0.02433083     -4911.5433874287  1.44E-01
     6 Broy./Diag. 0.40E+00    7.1     0.00749536     -4911.5382565343  5.13E-03
     7 Broy./Diag. 0.40E+00    7.2     0.00588691     -4911.5407251557 -2.47E-03
     8 Broy./Diag. 0.40E+00    7.1     0.00313044     -4911.5510703039 -1.03E-02
     9 Broy./Diag. 0.40E+00    7.3     0.00275807     -4911.5489751355  2.10E-03
    10 Broy./Diag. 0.40E+00    7.3     0.00242189     -4911.5387889870  1.02E-02
    11 Broy./Diag. 0.40E+00    6.9     0.00225146     -4911.5506463405 -1.19E-02
    12 Broy./Diag. 0.40E+00    7.0     0.00091712     -4911.5480254888  2.62E-03
    13 Broy./Diag. 0.40E+00    7.1     0.00053663     -4911.5465270683  1.50E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00042299     -4911.5461627772  3.64E-04
    15 Broy./Diag. 0.40E+00    7.2     0.00027222     -4911.5468727253 -7.10E-04
    16 Broy./Diag. 0.40E+00    7.1     0.00037826     -4911.5473953565 -5.23E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00042979     -4911.5456017649  1.79E-03
    18 Broy./Diag. 0.40E+00    7.1     0.00027302     -4911.5468145494 -1.21E-03
    19 Broy./Diag. 0.40E+00    7.5     0.00016662     -4911.5471122544 -2.98E-04
    20 Broy./Diag. 0.40E+00    6.9     0.00019230     -4911.5469453855  1.67E-04
    21 Broy./Diag. 0.40E+00    7.3     0.00018451     -4911.5467554339  1.90E-04
    22 Broy./Diag. 0.40E+00    7.1     0.00013640     -4911.5466581254  9.73E-05
    23 Broy./Diag. 0.40E+00    6.9     0.00017521     -4911.5472437020 -5.86E-04
    24 Broy./Diag. 0.40E+00    6.9     0.00011688     -4911.5467661555  4.78E-04
    25 Broy./Diag. 0.40E+00    7.3     0.00006935     -4911.5468258759 -5.97E-05
    26 Broy./Diag. 0.40E+00    7.3     0.00007668     -4911.5468938656 -6.80E-05
    27 Broy./Diag. 0.40E+00    7.1     0.00007801     -4911.5469407822 -4.69E-05
    28 Broy./Diag. 0.40E+00    7.5     0.00007096     -4911.5469840600 -4.33E-05
    29 Broy./Diag. 0.40E+00    7.3     0.00009574     -4911.5467443278  2.40E-04
    30 Broy./Diag. 0.40E+00    7.4     0.00007209     -4911.5470318899 -2.88E-04
    31 Broy./Diag. 0.40E+00    7.2     0.00003790     -4911.5469728264  5.91E-05
    32 Broy./Diag. 0.40E+00    7.5     0.00003891     -4911.5469439611  2.89E-05
    33 Broy./Diag. 0.40E+00    7.3     0.00004290     -4911.5469562926 -1.23E-05
    34 Broy./Diag. 0.40E+00    6.9     0.00003505     -4911.5469299506  2.63E-05
    35 Broy./Diag. 0.40E+00    7.1     0.00004431     -4911.5470263037 -9.64E-05
    36 Broy./Diag. 0.40E+00    6.9     0.00003913     -4911.5469027180  1.24E-04
    37 Broy./Diag. 0.40E+00    7.3     0.00002198     -4911.5469735673 -7.08E-05
    38 Broy./Diag. 0.40E+00    7.3     0.00002335     -4911.5469855280 -1.20E-05
    39 Broy./Diag. 0.40E+00    7.0     0.00002431     -4911.5469773988  8.13E-06
    40 Broy./Diag. 0.40E+00    7.3     0.00002373     -4911.5469971281 -1.97E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00002135     -4911.5469509772  4.62E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00002038     -4911.5470192505 -6.83E-05
    43 Broy./Diag. 0.40E+00    7.1     0.00000998     -4911.5469783493  4.09E-05
    44 Broy./Diag. 0.40E+00    6.7     0.00001074     -4911.5469849067 -6.56E-06
    45 Broy./Diag. 0.40E+00    6.8     0.00001207     -4911.5469951643 -1.03E-05
    46 Broy./Diag. 0.40E+00    6.9     0.00001254     -4911.5469911220  4.04E-06
    47 Broy./Diag. 0.40E+00    7.3     0.00001253     -4911.5470087937 -1.77E-05
    48 Broy./Diag. 0.40E+00    7.1     0.00001400     -4911.5469738024  3.50E-05
    49 Broy./Diag. 0.40E+00    7.7     0.00000736     -4911.5470088516 -3.50E-05
    50 Broy./Diag. 0.40E+00    7.0     0.00000650     -4911.5470060282  2.82E-06
    51 Broy./Diag. 0.40E+00    7.1     0.00000563     -4911.5469983804  7.65E-06
    52 Broy./Diag. 0.40E+00    7.5     0.00000591     -4911.5470017765 -3.40E-06
    53 Broy./Diag. 0.40E+00    7.0     0.00000535     -4911.5470004948  1.28E-06
    54 Broy./Diag. 0.40E+00    7.5     0.00000729     -4911.5470158683 -1.54E-05
    55 Broy./Diag. 0.40E+00    6.7     0.00000447     -4911.5469965718  1.93E-05
    56 Broy./Diag. 0.40E+00    7.5     0.00000392     -4911.5470035615 -6.99E-06
    57 Broy./Diag. 0.40E+00    7.9     0.00000378     -4911.5470111225 -7.56E-06
    58 Broy./Diag. 0.40E+00    7.1     0.00000338     -4911.5470109737  1.49E-07
    59 Broy./Diag. 0.40E+00    7.1     0.00000316     -4911.5470077552  3.22E-06
    60 Broy./Diag. 0.40E+00    7.3     0.00000372     -4911.5470012583  6.50E-06
    61 Broy./Diag. 0.40E+00    7.3     0.00000234     -4911.5470147336 -1.35E-05
    62 Broy./Diag. 0.40E+00    7.0     0.00000177     -4911.5470106905  4.04E-06
    63 Broy./Diag. 0.40E+00    6.8     0.00000174     -4911.5470068375  3.85E-06
    64 Broy./Diag. 0.40E+00    7.5     0.00000171     -4911.5470090060 -2.17E-06
    65 Broy./Diag. 0.40E+00    7.1     0.00000186     -4911.5470140041 -5.00E-06
    66 Broy./Diag. 0.40E+00    7.5     0.00000257     -4911.5470157946 -1.79E-06
    67 Broy./Diag. 0.40E+00    6.9     0.00000174     -4911.5470065547  9.24E-06
    68 Broy./Diag. 0.40E+00    6.9     0.00000110     -4911.5470109854 -4.43E-06
    69 Broy./Diag. 0.40E+00    7.1     0.00000108     -4911.5470147611 -3.78E-06
    70 Broy./Diag. 0.40E+00    7.3     0.00000099     -4911.5470134674  1.29E-06

  *** SCF run converged in    70 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008269933429
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.62869707864957
  Hartree energy:                                            1781.57570832799888
  Exchange-correlation energy:                               -779.41751712719326
  Electronic entropic energy:                                  -0.24356191010272
  Fermi energy:                                                 0.08691786200981

  Total energy:                                             -4911.54701346738602

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.547015325171742

 MD| ***************************************************************************
 MD| Step number                                                            1187
 MD| Time [fs]                                                       2374.000000
 MD| Conserved quantity [hartree]                            -0.491120118314E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    510.077404           593.593967
 MD| Energy drift per atom [K]           0.245779683693E+03   0.270043123624E+03
 MD| Potential energy [hartree]         -0.491154701533E+04  -0.491156381428E+04
 MD| Kinetic energy [hartree]            0.345832181812E+00   0.374305447889E+00
 MD| Temperature [K]                             921.561481           997.436042
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.01727637     -4911.5469091482 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.8     0.06601665     -4911.6120461580 -6.51E-02
     3 Broy./Diag. 0.40E+00    6.9     0.07619260     -4911.3239581017  2.88E-01
     4 Broy./Diag. 0.40E+00    6.9     0.04561669     -4911.6727729854 -3.49E-01
     5 Broy./Diag. 0.40E+00    7.1     0.02559697     -4911.5215723099  1.51E-01
     6 Broy./Diag. 0.40E+00    7.4     0.00761892     -4911.5464857802 -2.49E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00536064     -4911.5496463065 -3.16E-03
     8 Broy./Diag. 0.40E+00    7.3     0.00268933     -4911.5466805422  2.97E-03
     9 Broy./Diag. 0.40E+00    7.3     0.00248815     -4911.5535727008 -6.89E-03
    10 Broy./Diag. 0.40E+00    7.5     0.00234927     -4911.5411522027  1.24E-02
    11 Broy./Diag. 0.40E+00    7.1     0.00231486     -4911.5520329583 -1.09E-02
    12 Broy./Diag. 0.40E+00    7.0     0.00099581     -4911.5483007670  3.73E-03
    13 Broy./Diag. 0.40E+00    7.1     0.00051852     -4911.5485985705 -2.98E-04
    14 Broy./Diag. 0.40E+00    7.3     0.00038325     -4911.5491656153 -5.67E-04
    15 Broy./Diag. 0.40E+00    7.1     0.00026450     -4911.5484985576  6.67E-04
    16 Broy./Diag. 0.40E+00    8.1     0.00039336     -4911.5495652728 -1.07E-03
    17 Broy./Diag. 0.40E+00    6.9     0.00045585     -4911.5478043828  1.76E-03
    18 Broy./Diag. 0.40E+00    7.1     0.00032063     -4911.5490342727 -1.23E-03
    19 Broy./Diag. 0.40E+00    7.3     0.00018028     -4911.5488766547  1.58E-04
    20 Broy./Diag. 0.40E+00    7.1     0.00019558     -4911.5488218757  5.48E-05
    21 Broy./Diag. 0.40E+00    7.2     0.00017279     -4911.5493052741 -4.83E-04
    22 Broy./Diag. 0.40E+00    7.3     0.00014236     -4911.5487916917  5.14E-04
    23 Broy./Diag. 0.40E+00    7.3     0.00020178     -4911.5493896223 -5.98E-04
    24 Broy./Diag. 0.40E+00    7.5     0.00013931     -4911.5488203053  5.69E-04
    25 Broy./Diag. 0.40E+00    6.8     0.00006725     -4911.5490511777 -2.31E-04
    26 Broy./Diag. 0.40E+00    7.3     0.00008133     -4911.5491286902 -7.75E-05
    27 Broy./Diag. 0.40E+00    6.9     0.00007981     -4911.5489060193  2.23E-04
    28 Broy./Diag. 0.40E+00    6.9     0.00006627     -4911.5491660283 -2.60E-04
    29 Broy./Diag. 0.40E+00    7.2     0.00010122     -4911.5489665652  1.99E-04
    30 Broy./Diag. 0.40E+00    7.1     0.00008237     -4911.5492797238 -3.13E-04
    31 Broy./Diag. 0.40E+00    7.0     0.00003893     -4911.5491182028  1.62E-04
    32 Broy./Diag. 0.40E+00    7.5     0.00004196     -4911.5490545222  6.37E-05
    33 Broy./Diag. 0.40E+00    7.3     0.00004714     -4911.5492394450 -1.85E-04
    34 Broy./Diag. 0.40E+00    7.3     0.00003828     -4911.5490889445  1.51E-04
    35 Broy./Diag. 0.40E+00    7.1     0.00005309     -4911.5491852872 -9.63E-05
    36 Broy./Diag. 0.40E+00    6.9     0.00004467     -4911.5490355605  1.50E-04
    37 Broy./Diag. 0.40E+00    7.3     0.00002727     -4911.5491864556 -1.51E-04
    38 Broy./Diag. 0.40E+00    6.9     0.00002443     -4911.5492373805 -5.09E-05
    39 Broy./Diag. 0.40E+00    7.3     0.00002847     -4911.5491137143  1.24E-04
    40 Broy./Diag. 0.40E+00    7.1     0.00002523     -4911.5492117937 -9.81E-05
    41 Broy./Diag. 0.40E+00    6.9     0.00002608     -4911.5491747373  3.71E-05
    42 Broy./Diag. 0.40E+00    6.9     0.00002499     -4911.5492519867 -7.72E-05
    43 Broy./Diag. 0.40E+00    7.3     0.00001581     -4911.5491630562  8.89E-05
    44 Broy./Diag. 0.40E+00    7.3     0.00000957     -4911.5491523960  1.07E-05
    45 Broy./Diag. 0.40E+00    6.8     0.00001423     -4911.5492322288 -7.98E-05
    46 Broy./Diag. 0.40E+00    7.1     0.00001596     -4911.5491854335  4.68E-05
    47 Broy./Diag. 0.40E+00    7.6     0.00001551     -4911.5492047479 -1.93E-05
    48 Broy./Diag. 0.40E+00    6.9     0.00001623     -4911.5491655729  3.92E-05
    49 Broy./Diag. 0.40E+00    7.5     0.00001071     -4911.5492298023 -6.42E-05
    50 Broy./Diag. 0.40E+00    6.9     0.00000829     -4911.5492371823 -7.38E-06
    51 Broy./Diag. 0.40E+00    7.3     0.00000705     -4911.5491816162  5.56E-05
    52 Broy./Diag. 0.40E+00    7.3     0.00000844     -4911.5492142421 -3.26E-05
    53 Broy./Diag. 0.40E+00    7.3     0.00000756     -4911.5492094975  4.74E-06
    54 Broy./Diag. 0.40E+00    6.8     0.00000996     -4911.5492304801 -2.10E-05
    55 Broy./Diag. 0.40E+00    7.0     0.00000570     -4911.5491937882  3.67E-05
    56 Broy./Diag. 0.40E+00    6.9     0.00000610     -4911.5492028313 -9.04E-06
    57 Broy./Diag. 0.40E+00    7.3     0.00000458     -4911.5492372059 -3.44E-05
    58 Broy./Diag. 0.40E+00    7.1     0.00000560     -4911.5492153332  2.19E-05
    59 Broy./Diag. 0.40E+00    7.3     0.00000423     -4911.5492198103 -4.48E-06
    60 Broy./Diag. 0.40E+00    7.5     0.00000504     -4911.5492083975  1.14E-05
    61 Broy./Diag. 0.40E+00    8.4     0.00000284     -4911.5492281166 -1.97E-05
    62 Broy./Diag. 0.40E+00    7.3     0.00000364     -4911.5492248191  3.30E-06
    63 Broy./Diag. 0.40E+00    7.0     0.00000213     -4911.5492097300  1.51E-05
    64 Broy./Diag. 0.40E+00    7.3     0.00000328     -4911.5492233765 -1.36E-05
    65 Broy./Diag. 0.40E+00    7.3     0.00000270     -4911.5492219756  1.40E-06
    66 Broy./Diag. 0.40E+00    7.5     0.00000364     -4911.5492297938 -7.82E-06
    67 Broy./Diag. 0.40E+00    7.1     0.00000210     -4911.5492168119  1.30E-05
    68 Broy./Diag. 0.40E+00    7.5     0.00000220     -4911.5492204929 -3.68E-06
    69 Broy./Diag. 0.40E+00    8.5     0.00000115     -4911.5492291161 -8.62E-06
    70 Broy./Diag. 0.40E+00    7.3     0.00000173     -4911.5492223651  6.75E-06
    71 Broy./Diag. 0.40E+00    7.7     0.00000161     -4911.5492238665 -1.50E-06
    72 Broy./Diag. 0.40E+00    7.1     0.00000195     -4911.5492203246  3.54E-06
    73 Broy./Diag. 0.40E+00    7.5     0.00000142     -4911.5492281469 -7.82E-06
    74 Broy./Diag. 0.40E+00    7.1     0.00000155     -4911.5492263826  1.76E-06
    75 Broy./Diag. 0.40E+00    7.6     0.00000083     -4911.5492219861  4.40E-06

  *** SCF run converged in    75 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008265365462
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.62724082452678
  Hartree energy:                                            1781.57544692582292
  Exchange-correlation energy:                               -779.41800565419817
  Electronic entropic energy:                                  -0.24356424732571
  Fermi energy:                                                 0.08692974986980

  Total energy:                                             -4911.54922198608710

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.549228049419980

 MD| ***************************************************************************
 MD| Step number                                                            1188
 MD| Time [fs]                                                       2376.000000
 MD| Conserved quantity [hartree]                            -0.491120420179E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    551.479720           593.558517
 MD| Energy drift per atom [K]           0.239508551733E+03   0.270017421122E+03
 MD| Potential energy [hartree]         -0.491154922805E+04  -0.491156380200E+04
 MD| Kinetic energy [hartree]            0.345026259490E+00   0.374280802108E+00
 MD| Temperature [K]                             919.413887           997.370367
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.01947383     -4911.5483840037 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.9     0.07290398     -4911.6027358114 -5.44E-02
     3 Broy./Diag. 0.40E+00    7.4     0.07790014     -4911.3252676625  2.77E-01
     4 Broy./Diag. 0.40E+00    7.6     0.05301648     -4911.6569793649 -3.32E-01
     5 Broy./Diag. 0.40E+00    7.3     0.02808745     -4911.5043765398  1.53E-01
     6 Broy./Diag. 0.40E+00    7.1     0.00693472     -4911.5503638578 -4.60E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00483209     -4911.5573270729 -6.96E-03
     8 Broy./Diag. 0.40E+00    7.5     0.00272067     -4911.5433742241  1.40E-02
     9 Broy./Diag. 0.40E+00    7.6     0.00233797     -4911.5616567771 -1.83E-02
    10 Broy./Diag. 0.40E+00    7.4     0.00302953     -4911.5425209907  1.91E-02
    11 Broy./Diag. 0.40E+00    6.9     0.00274121     -4911.5527811103 -1.03E-02
    12 Broy./Diag. 0.40E+00    7.3     0.00106610     -4911.5482012936  4.58E-03
    13 Broy./Diag. 0.40E+00    7.3     0.00057108     -4911.5500850609 -1.88E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00036966     -4911.5516873014 -1.60E-03
    15 Broy./Diag. 0.40E+00    7.3     0.00030301     -4911.5494998447  2.19E-03
    16 Broy./Diag. 0.40E+00    7.1     0.00049996     -4911.5513887317 -1.89E-03
    17 Broy./Diag. 0.40E+00    6.9     0.00054195     -4911.5495345007  1.85E-03
    18 Broy./Diag. 0.40E+00    7.1     0.00030591     -4911.5507216659 -1.19E-03
    19 Broy./Diag. 0.40E+00    7.3     0.00019868     -4911.5501405899  5.81E-04
    20 Broy./Diag. 0.40E+00    7.1     0.00020967     -4911.5501581736 -1.76E-05
    21 Broy./Diag. 0.40E+00    7.1     0.00018363     -4911.5513618778 -1.20E-03
    22 Broy./Diag. 0.40E+00    7.1     0.00018754     -4911.5502626990  1.10E-03
    23 Broy./Diag. 0.40E+00    7.5     0.00025408     -4911.5509818705 -7.19E-04
    24 Broy./Diag. 0.40E+00    7.1     0.00015183     -4911.5503803826  6.01E-04
    25 Broy./Diag. 0.40E+00    7.3     0.00007583     -4911.5507751909 -3.95E-04
    26 Broy./Diag. 0.40E+00    7.3     0.00010399     -4911.5508192691 -4.41E-05
    27 Broy./Diag. 0.40E+00    7.3     0.00006912     -4911.5503068442  5.12E-04
    28 Broy./Diag. 0.40E+00    7.3     0.00007950     -4911.5508413699 -5.35E-04
    29 Broy./Diag. 0.40E+00    7.3     0.00012325     -4911.5505743315  2.67E-04
    30 Broy./Diag. 0.40E+00    6.7     0.00008701     -4911.5509015189 -3.27E-04
    31 Broy./Diag. 0.40E+00    6.7     0.00005672     -4911.5506862607  2.15E-04
    32 Broy./Diag. 0.40E+00    7.1     0.00006148     -4911.5506511743  3.51E-05
    33 Broy./Diag. 0.40E+00    7.3     0.00004874     -4911.5509710802 -3.20E-04
    34 Broy./Diag. 0.40E+00    6.9     0.00004668     -4911.5506634952  3.08E-04
    35 Broy./Diag. 0.40E+00    7.1     0.00007048     -4911.5508317176 -1.68E-04
    36 Broy./Diag. 0.40E+00    7.1     0.00004762     -4911.5506473359  1.84E-04
    37 Broy./Diag. 0.40E+00    7.0     0.00003732     -4911.5508088133 -1.61E-04
    38 Broy./Diag. 0.40E+00    7.3     0.00003435     -4911.5508672233 -5.84E-05
    39 Broy./Diag. 0.40E+00    6.7     0.00003430     -4911.5507091301  1.58E-04
    40 Broy./Diag. 0.40E+00    8.5     0.00003025     -4911.5508810982 -1.72E-04
    41 Broy./Diag. 0.40E+00    7.3     0.00004076     -4911.5507767489  1.04E-04
    42 Broy./Diag. 0.40E+00   10.3     0.00002892     -4911.5508985705 -1.22E-04
    43 Broy./Diag. 0.40E+00    7.6     0.00002294     -4911.5508057339  9.28E-05
    44 Broy./Diag. 0.40E+00    9.3     0.00001471     -4911.5507769565  2.88E-05
    45 Broy./Diag. 0.40E+00    9.0     0.00001867     -4911.5508757891 -9.88E-05
    46 Broy./Diag. 0.40E+00    7.5     0.00001563     -4911.5508024661  7.33E-05
    47 Broy./Diag. 0.40E+00    6.7     0.00002444     -4911.5508618931 -5.94E-05
    48 Broy./Diag. 0.40E+00    7.1     0.00001854     -4911.5507927122  6.92E-05
    49 Broy./Diag. 0.40E+00    7.3     0.00001599     -4911.5508576876 -6.50E-05
    50 Broy./Diag. 0.40E+00    8.1     0.00000893     -4911.5508813785 -2.37E-05
    51 Broy./Diag. 0.40E+00    7.5     0.00001219     -4911.5508141399  6.72E-05
    52 Broy./Diag. 0.40E+00   10.0     0.00000772     -4911.5508617991 -4.77E-05
    53 Broy./Diag. 0.40E+00    7.8     0.00001259     -4911.5508354596  2.63E-05
    54 Broy./Diag. 0.40E+00    8.7     0.00001120     -4911.5508757710 -4.03E-05
    55 Broy./Diag. 0.40E+00   10.0     0.00000979     -4911.5508395606  3.62E-05
    56 Broy./Diag. 0.40E+00    7.1     0.00000573     -4911.5508375094  2.05E-06
    57 Broy./Diag. 0.40E+00    7.3     0.00000849     -4911.5508813934 -4.39E-05
    58 Broy./Diag. 0.40E+00    6.7     0.00000487     -4911.5508518842  2.95E-05
    59 Broy./Diag. 0.40E+00    8.0     0.00000831     -4911.5508703853 -1.85E-05
    60 Broy./Diag. 0.40E+00    7.1     0.00000678     -4911.5508440322  2.64E-05
    61 Broy./Diag. 0.40E+00    9.8     0.00000545     -4911.5508681055 -2.41E-05
    62 Broy./Diag. 0.40E+00    7.5     0.00000326     -4911.5508706365 -2.53E-06
    63 Broy./Diag. 0.40E+00    8.7     0.00000502     -4911.5508491346  2.15E-05
    64 Broy./Diag. 0.40E+00    9.9     0.00000322     -4911.5508687370 -1.96E-05
    65 Broy./Diag. 0.40E+00    6.9     0.00000486     -4911.5508602599  8.48E-06
    66 Broy./Diag. 0.40E+00    7.0     0.00000478     -4911.5508766127 -1.64E-05
    67 Broy./Diag. 0.40E+00    7.1     0.00000380     -4911.5508610461  1.56E-05
    68 Broy./Diag. 0.40E+00    7.1     0.00000213     -4911.5508616078 -5.62E-07
    69 Broy./Diag. 0.40E+00    6.7     0.00000289     -4911.5508749363 -1.33E-05
    70 Broy./Diag. 0.40E+00    7.3     0.00000201     -4911.5508643692  1.06E-05
    71 Broy./Diag. 0.40E+00    7.4     0.00000279     -4911.5508703424 -5.97E-06
    72 Broy./Diag. 0.40E+00    7.5     0.00000277     -4911.5508615244  8.82E-06
    73 Broy./Diag. 0.40E+00    7.3     0.00000234     -4911.5508719493 -1.04E-05
    74 Broy./Diag. 0.40E+00    7.1     0.00000159     -4911.5508719084  4.10E-08
    75 Broy./Diag. 0.40E+00    7.6     0.00000194     -4911.5508648626  7.05E-06
    76 Broy./Diag. 0.40E+00    6.5     0.00000144     -4911.5508724838 -7.62E-06
    77 Broy./Diag. 0.40E+00    7.1     0.00000152     -4911.5508689824  3.50E-06
    78 Broy./Diag. 0.40E+00    7.5     0.00000168     -4911.5508743464 -5.36E-06
    79 Broy./Diag. 0.40E+00    7.1     0.00000129     -4911.5508685678  5.78E-06
    80 Broy./Diag. 0.40E+00    7.1     0.00000096     -4911.5508694048 -8.37E-07

  *** SCF run converged in    80 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008261806673
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.62408417685447
  Hartree energy:                                            1781.57619056790054
  Exchange-correlation energy:                               -779.41724698212442
  Electronic entropic energy:                                  -0.24355730065587
  Fermi energy:                                                 0.08693983704500

  Total energy:                                             -4911.55086940478577

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.550873746084108

 MD| ***************************************************************************
 MD| Step number                                                            1189
 MD| Time [fs]                                                       2378.000000
 MD| Conserved quantity [hartree]                            -0.491121344818E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    607.080747           593.569890
 MD| Energy drift per atom [K]           0.220299495333E+03   0.269975606214E+03
 MD| Potential energy [hartree]         -0.491155087375E+04  -0.491156379113E+04
 MD| Kinetic energy [hartree]            0.337425562904E+00   0.374249805271E+00
 MD| Temperature [K]                             899.159817           997.287768
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.1     0.02278335     -4911.5487660977 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.7     0.09024172     -4911.6064906557 -5.77E-02
     3 Broy./Diag. 0.40E+00    7.3     0.08683590     -4911.2890446199  3.17E-01
     4 Broy./Diag. 0.40E+00    7.7     0.05973652     -4911.6363633843 -3.47E-01
     5 Broy./Diag. 0.40E+00    7.1     0.02907508     -4911.5068282999  1.30E-01
     6 Broy./Diag. 0.40E+00    7.3     0.00761689     -4911.5522866910 -4.55E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00512200     -4911.5483628747  3.92E-03
     8 Broy./Diag. 0.40E+00    7.7     0.00320350     -4911.5483709583 -8.08E-06
     9 Broy./Diag. 0.40E+00    7.5     0.00332535     -4911.5582233575 -9.85E-03
    10 Broy./Diag. 0.40E+00    6.9     0.00334793     -4911.5453457521  1.29E-02
    11 Broy./Diag. 0.40E+00    7.3     0.00288066     -4911.5536658904 -8.32E-03
    12 Broy./Diag. 0.40E+00    6.9     0.00098633     -4911.5484738438  5.19E-03
    13 Broy./Diag. 0.40E+00    6.9     0.00060296     -4911.5508459954 -2.37E-03
    14 Broy./Diag. 0.40E+00    6.9     0.00047565     -4911.5514486794 -6.03E-04
    15 Broy./Diag. 0.40E+00    7.1     0.00035695     -4911.5503160045  1.13E-03
    16 Broy./Diag. 0.40E+00    7.1     0.00053506     -4911.5513226839 -1.01E-03
    17 Broy./Diag. 0.40E+00    7.1     0.00060616     -4911.5501684868  1.15E-03
    18 Broy./Diag. 0.40E+00    7.3     0.00030732     -4911.5515430428 -1.37E-03
    19 Broy./Diag. 0.40E+00    6.9     0.00021892     -4911.5504954250  1.05E-03
    20 Broy./Diag. 0.40E+00    7.0     0.00024115     -4911.5506242280 -1.29E-04
    21 Broy./Diag. 0.40E+00    6.7     0.00023563     -4911.5515812847 -9.57E-04
    22 Broy./Diag. 0.40E+00    6.8     0.00019933     -4911.5510474175  5.34E-04
    23 Broy./Diag. 0.40E+00    6.9     0.00027773     -4911.5512630626 -2.16E-04
    24 Broy./Diag. 0.40E+00    6.9     0.00016230     -4911.5506395003  6.24E-04
    25 Broy./Diag. 0.40E+00    7.2     0.00008901     -4911.5514148722 -7.75E-04
    26 Broy./Diag. 0.40E+00    7.3     0.00011224     -4911.5512909958  1.24E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00010362     -4911.5507692912  5.22E-04
    28 Broy./Diag. 0.40E+00    7.1     0.00009093     -4911.5511388172 -3.70E-04
    29 Broy./Diag. 0.40E+00    7.3     0.00015590     -4911.5511557907 -1.70E-05
    30 Broy./Diag. 0.40E+00    6.9     0.00010841     -4911.5515039335 -3.48E-04
    31 Broy./Diag. 0.40E+00    8.1     0.00004778     -4911.5509770042  5.27E-04
    32 Broy./Diag. 0.40E+00    7.0     0.00006459     -4911.5511224377 -1.45E-04
    33 Broy./Diag. 0.40E+00    7.0     0.00006577     -4911.5514786029 -3.56E-04
    34 Broy./Diag. 0.40E+00    7.1     0.00004493     -4911.5512356854  2.43E-04
    35 Broy./Diag. 0.40E+00    6.7     0.00007676     -4911.5512122087  2.35E-05
    36 Broy./Diag. 0.40E+00    7.5     0.00005723     -4911.5510679179  1.44E-04
    37 Broy./Diag. 0.40E+00    6.9     0.00002860     -4911.5513806589 -3.13E-04
    38 Broy./Diag. 0.40E+00    6.5     0.00003618     -4911.5512984063  8.23E-05
    39 Broy./Diag. 0.40E+00    7.0     0.00004263     -4911.5511285853  1.70E-04
    40 Broy./Diag. 0.40E+00    7.3     0.00003360     -4911.5513051105 -1.77E-04
    41 Broy./Diag. 0.40E+00    7.5     0.00004773     -4911.5513294973 -2.44E-05
    42 Broy./Diag. 0.40E+00    6.7     0.00003569     -4911.5514016494 -7.22E-05
    43 Broy./Diag. 0.40E+00    6.9     0.00001630     -4911.5512195448  1.82E-04
    44 Broy./Diag. 0.40E+00    7.5     0.00001497     -4911.5512795059 -6.00E-05
    45 Broy./Diag. 0.40E+00    7.1     0.00002177     -4911.5513655187 -8.60E-05
    46 Broy./Diag. 0.40E+00    7.2     0.00001905     -4911.5512821116  8.34E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00002694     -4911.5512860147 -3.90E-06
    48 Broy./Diag. 0.40E+00    7.3     0.00002454     -4911.5512586560  2.74E-05
    49 Broy./Diag. 0.40E+00    7.3     0.00001339     -4911.5513788814 -1.20E-04
    50 Broy./Diag. 0.40E+00    7.2     0.00001124     -4911.5513317386  4.71E-05
    51 Broy./Diag. 0.40E+00    7.0     0.00001321     -4911.5512810981  5.06E-05
    52 Broy./Diag. 0.40E+00    6.9     0.00001139     -4911.5513380013 -5.69E-05
    53 Broy./Diag. 0.40E+00    7.1     0.00001239     -4911.5513364402  1.56E-06
    54 Broy./Diag. 0.40E+00    7.6     0.00001323     -4911.5513461144 -9.67E-06
    55 Broy./Diag. 0.40E+00    6.7     0.00000881     -4911.5512871284  5.90E-05
    56 Broy./Diag. 0.40E+00    6.8     0.00000720     -4911.5513283826 -4.13E-05
    57 Broy./Diag. 0.40E+00    7.6     0.00000882     -4911.5513570396 -2.87E-05
    58 Broy./Diag. 0.40E+00    7.1     0.00000811     -4911.5513204517  3.66E-05
    59 Broy./Diag. 0.40E+00    7.2     0.00000826     -4911.5513272740 -6.82E-06
    60 Broy./Diag. 0.40E+00    6.9     0.00000842     -4911.5513229504  4.32E-06
    61 Broy./Diag. 0.40E+00    7.5     0.00000516     -4911.5513582947 -3.53E-05
    62 Broy./Diag. 0.40E+00    6.9     0.00000389     -4911.5513349682  2.33E-05
    63 Broy./Diag. 0.40E+00    6.9     0.00000480     -4911.5513231699  1.18E-05
    64 Broy./Diag. 0.40E+00    7.3     0.00000499     -4911.5513467369 -2.36E-05
    65 Broy./Diag. 0.40E+00    7.3     0.00000450     -4911.5513428335  3.90E-06
    66 Broy./Diag. 0.40E+00    6.6     0.00000556     -4911.5513446147 -1.78E-06
    67 Broy./Diag. 0.40E+00    7.8     0.00000380     -4911.5513239935  2.06E-05
    68 Broy./Diag. 0.40E+00    7.3     0.00000236     -4911.5513434013 -1.94E-05
    69 Broy./Diag. 0.40E+00    7.4     0.00000268     -4911.5513495611 -6.16E-06
    70 Broy./Diag. 0.40E+00    7.7     0.00000285     -4911.5513369512  1.26E-05
    71 Broy./Diag. 0.40E+00    7.3     0.00000258     -4911.5513409606 -4.01E-06
    72 Broy./Diag. 0.40E+00    7.9     0.00000314     -4911.5513406568  3.04E-07
    73 Broy./Diag. 0.40E+00    6.9     0.00000224     -4911.5513513909 -1.07E-05
    74 Broy./Diag. 0.40E+00    7.1     0.00000152     -4911.5513400199  1.14E-05
    75 Broy./Diag. 0.40E+00    8.1     0.00000177     -4911.5513386532  1.37E-06
    76 Broy./Diag. 0.40E+00    7.3     0.00000193     -4911.5513479388 -9.29E-06
    77 Broy./Diag. 0.40E+00    7.1     0.00000137     -4911.5513453567  2.58E-06
    78 Broy./Diag. 0.40E+00    7.3     0.00000186     -4911.5513457104 -3.54E-07
    79 Broy./Diag. 0.40E+00    7.3     0.00000130     -4911.5513403229  5.39E-06
    80 Broy./Diag. 0.40E+00    7.0     0.00000082     -4911.5513475819 -7.26E-06

  *** SCF run converged in    80 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008261121257
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.62166904823198
  Hartree energy:                                            1781.57654543565786
  Exchange-correlation energy:                               -779.41567262209480
  Electronic entropic energy:                                  -0.24354953953364
  Fermi energy:                                                 0.08694857706510

  Total energy:                                             -4911.55134758192889

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.551348199176573

 MD| ***************************************************************************
 MD| Step number                                                            1190
 MD| Time [fs]                                                       2380.000000
 MD| Conserved quantity [hartree]                            -0.491120282317E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    581.361569           593.559631
 MD| Energy drift per atom [K]           0.242372589917E+03   0.269952410402E+03
 MD| Potential energy [hartree]         -0.491155134820E+04  -0.491156378067E+04
 MD| Kinetic energy [hartree]            0.348525031016E+00   0.374228187813E+00
 MD| Temperature [K]                             928.737291           997.230162
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.01999785     -4911.5483107648 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.7     0.07114837     -4911.5998695596 -5.16E-02
     3 Broy./Diag. 0.40E+00    7.1     0.07498641     -4911.3264570130  2.73E-01
     4 Broy./Diag. 0.40E+00    7.5     0.05050818     -4911.6369512044 -3.10E-01
     5 Broy./Diag. 0.40E+00    7.1     0.03019288     -4911.4946113873  1.42E-01
     6 Broy./Diag. 0.40E+00    7.5     0.00802491     -4911.5538072839 -5.92E-02
     7 Broy./Diag. 0.40E+00    6.9     0.00512998     -4911.5484048626  5.40E-03
     8 Broy./Diag. 0.40E+00    6.9     0.00321253     -4911.5471850381  1.22E-03
     9 Broy./Diag. 0.40E+00    7.1     0.00311502     -4911.5581084355 -1.09E-02
    10 Broy./Diag. 0.40E+00    7.1     0.00283792     -4911.5458286397  1.23E-02
    11 Broy./Diag. 0.40E+00    8.1     0.00307628     -4911.5544657760 -8.64E-03
    12 Broy./Diag. 0.40E+00    6.9     0.00121767     -4911.5477872901  6.68E-03
    13 Broy./Diag. 0.40E+00    7.1     0.00057480     -4911.5505504536 -2.76E-03
    14 Broy./Diag. 0.40E+00    7.3     0.00049424     -4911.5510262513 -4.76E-04
    15 Broy./Diag. 0.40E+00    6.7     0.00038016     -4911.5498266253  1.20E-03
    16 Broy./Diag. 0.40E+00    6.9     0.00044589     -4911.5509588233 -1.13E-03
    17 Broy./Diag. 0.40E+00    7.1     0.00060818     -4911.5497194194  1.24E-03
    18 Broy./Diag. 0.40E+00    7.3     0.00040800     -4911.5511735458 -1.45E-03
    19 Broy./Diag. 0.40E+00    6.7     0.00019545     -4911.5500618756  1.11E-03
    20 Broy./Diag. 0.40E+00    7.5     0.00025038     -4911.5503281749 -2.66E-04
    21 Broy./Diag. 0.40E+00    6.7     0.00026554     -4911.5511935660 -8.65E-04
    22 Broy./Diag. 0.40E+00    6.9     0.00021857     -4911.5505363725  6.57E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00028986     -4911.5508866560 -3.50E-04
    24 Broy./Diag. 0.40E+00    7.1     0.00021229     -4911.5502116738  6.75E-04
    25 Broy./Diag. 0.40E+00    7.5     0.00008654     -4911.5510127702 -8.01E-04
    26 Broy./Diag. 0.40E+00    7.5     0.00010186     -4911.5508125933  2.00E-04
    27 Broy./Diag. 0.40E+00    7.3     0.00009969     -4911.5504086804  4.04E-04
    28 Broy./Diag. 0.40E+00    7.2     0.00009891     -4911.5507721787 -3.63E-04
    29 Broy./Diag. 0.40E+00    6.9     0.00014631     -4911.5507315275  4.07E-05
    30 Broy./Diag. 0.40E+00    7.3     0.00013312     -4911.5510461603 -3.15E-04
    31 Broy./Diag. 0.40E+00    6.9     0.00006117     -4911.5505199539  5.26E-04
    32 Broy./Diag. 0.40E+00    7.1     0.00006354     -4911.5507511669 -2.31E-04
    33 Broy./Diag. 0.40E+00    7.3     0.00006516     -4911.5510435870 -2.92E-04
    34 Broy./Diag. 0.40E+00    7.3     0.00005349     -4911.5507836196  2.60E-04
    35 Broy./Diag. 0.40E+00    6.9     0.00006670     -4911.5507892892 -5.67E-06
    36 Broy./Diag. 0.40E+00    7.1     0.00006170     -4911.5506904498  9.88E-05
    37 Broy./Diag. 0.40E+00    7.1     0.00003462     -4911.5509732717 -2.83E-04
    38 Broy./Diag. 0.40E+00    7.3     0.00003027     -4911.5508293422  1.44E-04
    39 Broy./Diag. 0.40E+00    7.0     0.00004110     -4911.5507200379  1.09E-04
    40 Broy./Diag. 0.40E+00    7.3     0.00004042     -4911.5509096898 -1.90E-04
    41 Broy./Diag. 0.40E+00    7.1     0.00004229     -4911.5509127409 -3.05E-06
    42 Broy./Diag. 0.40E+00    7.1     0.00003968     -4911.5509536387 -4.09E-05
    43 Broy./Diag. 0.40E+00    7.7     0.00001964     -4911.5507790617  1.75E-04
    44 Broy./Diag. 0.40E+00    6.9     0.00001361     -4911.5508809552 -1.02E-04
    45 Broy./Diag. 0.40E+00    6.7     0.00001912     -4911.5509288936 -4.79E-05
    46 Broy./Diag. 0.40E+00    7.1     0.00001970     -4911.5508468460  8.20E-05
    47 Broy./Diag. 0.40E+00    7.5     0.00002167     -4911.5508644119 -1.76E-05
    48 Broy./Diag. 0.40E+00    7.1     0.00002475     -4911.5508567749  7.64E-06
    49 Broy./Diag. 0.40E+00    7.1     0.00001413     -4911.5509573253 -1.01E-04
    50 Broy./Diag. 0.40E+00    6.9     0.00001123     -4911.5508818559  7.55E-05
    51 Broy./Diag. 0.40E+00    7.5     0.00001231     -4911.5508623310  1.95E-05
    52 Broy./Diag. 0.40E+00    6.7     0.00001153     -4911.5509195587 -5.72E-05
    53 Broy./Diag. 0.40E+00    7.1     0.00001005     -4911.5509070452  1.25E-05
    54 Broy./Diag. 0.40E+00    7.3     0.00001304     -4911.5509099824 -2.94E-06
    55 Broy./Diag. 0.40E+00    7.2     0.00000770     -4911.5508643119  4.57E-05
    56 Broy./Diag. 0.40E+00    7.1     0.00000633     -4911.5509157506 -5.14E-05
    57 Broy./Diag. 0.40E+00    7.5     0.00000818     -4911.5509195504 -3.80E-06
    58 Broy./Diag. 0.40E+00    7.1     0.00000812     -4911.5508865219  3.30E-05
    59 Broy./Diag. 0.40E+00    7.7     0.00000679     -4911.5509032629 -1.67E-05
    60 Broy./Diag. 0.40E+00    6.7     0.00000838     -4911.5509028588  4.04E-07
    61 Broy./Diag. 0.40E+00    6.8     0.00000470     -4911.5509283788 -2.55E-05
    62 Broy./Diag. 0.40E+00    7.0     0.00000368     -4911.5508994837  2.89E-05
    63 Broy./Diag. 0.40E+00    7.0     0.00000425     -4911.5509023716 -2.89E-06
    64 Broy./Diag. 0.40E+00    6.9     0.00000434     -4911.5509206124 -1.82E-05
    65 Broy./Diag. 0.40E+00    7.0     0.00000341     -4911.5509108896  9.72E-06
    66 Broy./Diag. 0.40E+00    7.1     0.00000544     -4911.5509117864 -8.97E-07
    67 Broy./Diag. 0.40E+00    7.1     0.00000353     -4911.5508983278  1.35E-05
    68 Broy./Diag. 0.40E+00    7.1     0.00000267     -4911.5509209148 -2.26E-05
    69 Broy./Diag. 0.40E+00    7.3     0.00000270     -4911.5509168535  4.06E-06
    70 Broy./Diag. 0.40E+00    8.3     0.00000257     -4911.5509070935  9.76E-06
    71 Broy./Diag. 0.40E+00    7.1     0.00000201     -4911.5509147902 -7.70E-06
    72 Broy./Diag. 0.40E+00    6.9     0.00000270     -4911.5509147106  7.96E-08
    73 Broy./Diag. 0.40E+00    7.7     0.00000208     -4911.5509202049 -5.49E-06
    74 Broy./Diag. 0.40E+00    7.1     0.00000187     -4911.5509079696  1.22E-05
    75 Broy./Diag. 0.40E+00    7.1     0.00000175     -4911.5509134598 -5.49E-06
    76 Broy./Diag. 0.40E+00    7.1     0.00000171     -4911.5509197502 -6.29E-06
    77 Broy./Diag. 0.40E+00    7.1     0.00000139     -4911.5509145749  5.18E-06
    78 Broy./Diag. 0.40E+00    8.0     0.00000171     -4911.5509154589 -8.84E-07
    79 Broy./Diag. 0.40E+00    7.1     0.00000128     -4911.5509126688  2.79E-06
    80 Broy./Diag. 0.40E+00    7.1     0.00000103     -4911.5509200196 -7.35E-06
    81 Broy./Diag. 0.40E+00    7.1     0.00000094     -4911.5509166761  3.34E-06

  *** SCF run converged in    81 steps ***


  Electronic density on regular grids:      -1631.9999999995        0.0000000005
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008261888628
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.61739333804462
  Hartree energy:                                            1781.57802023062231
  Exchange-correlation energy:                               -779.41243990735802
  Electronic entropic energy:                                  -0.24355043635274
  Fermi energy:                                                 0.08695299991255

  Total energy:                                             -4911.55091667611669

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.550918711716804

 MD| ***************************************************************************
 MD| Step number                                                            1191
 MD| Time [fs]                                                       2382.000000
 MD| Conserved quantity [hartree]                            -0.491119999043E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    588.217223           593.555145
 MD| Energy drift per atom [K]           0.248257505011E+03   0.269934194696E+03
 MD| Potential energy [hartree]         -0.491155091871E+04  -0.491156376987E+04
 MD| Kinetic energy [hartree]            0.350928282347E+00   0.374208624501E+00
 MD| Temperature [K]                             935.141391           997.178031
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.02067734     -4911.5472909141 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.04219045     -4911.5651710612 -1.79E-02
     3 Broy./Diag. 0.40E+00    6.9     0.04952195     -4911.4269402525  1.38E-01
     4 Broy./Diag. 0.40E+00    6.9     0.04216081     -4911.6063841937 -1.79E-01
     5 Broy./Diag. 0.40E+00    7.1     0.02795526     -4911.4892199968  1.17E-01
     6 Broy./Diag. 0.40E+00    7.3     0.00905079     -4911.5610122603 -7.18E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00439064     -4911.5414171571  1.96E-02
     8 Broy./Diag. 0.40E+00    7.5     0.00313742     -4911.5468953172 -5.48E-03
     9 Broy./Diag. 0.40E+00    7.1     0.00258737     -4911.5564518371 -9.56E-03
    10 Broy./Diag. 0.40E+00    6.7     0.00229503     -4911.5466868793  9.76E-03
    11 Broy./Diag. 0.40E+00    6.9     0.00276256     -4911.5520997638 -5.41E-03
    12 Broy./Diag. 0.40E+00    6.6     0.00116669     -4911.5458604042  6.24E-03
    13 Broy./Diag. 0.40E+00    7.7     0.00048061     -4911.5501196995 -4.26E-03
    14 Broy./Diag. 0.40E+00    6.9     0.00047353     -4911.5495263295  5.93E-04
    15 Broy./Diag. 0.40E+00    7.3     0.00036353     -4911.5486275524  8.99E-04
    16 Broy./Diag. 0.40E+00    7.1     0.00038338     -4911.5496650216 -1.04E-03
    17 Broy./Diag. 0.40E+00    7.3     0.00059198     -4911.5490772591  5.88E-04
    18 Broy./Diag. 0.40E+00    7.1     0.00046605     -4911.5501939727 -1.12E-03
    19 Broy./Diag. 0.40E+00    7.5     0.00021480     -4911.5484473623  1.75E-03
    20 Broy./Diag. 0.40E+00    7.1     0.00025702     -4911.5494143046 -9.67E-04
    21 Broy./Diag. 0.40E+00    7.1     0.00027195     -4911.5500497894 -6.35E-04
    22 Broy./Diag. 0.40E+00    7.3     0.00019901     -4911.5494471415  6.03E-04
    23 Broy./Diag. 0.40E+00    6.9     0.00028149     -4911.5495770509 -1.30E-04
    24 Broy./Diag. 0.40E+00    7.3     0.00023536     -4911.5491063401  4.71E-04
    25 Broy./Diag. 0.40E+00    7.3     0.00009822     -4911.5501163893 -1.01E-03
    26 Broy./Diag. 0.40E+00    7.5     0.00009557     -4911.5496067543  5.10E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00010387     -4911.5493734014  2.33E-04
    28 Broy./Diag. 0.40E+00    6.9     0.00008996     -4911.5497011974 -3.28E-04
    29 Broy./Diag. 0.40E+00    7.5     0.00014035     -4911.5497512810 -5.01E-05
    30 Broy./Diag. 0.40E+00    7.9     0.00014769     -4911.5499287224 -1.77E-04
    31 Broy./Diag. 0.40E+00    7.1     0.00006998     -4911.5493356200  5.93E-04
    32 Broy./Diag. 0.40E+00    7.1     0.00005391     -4911.5497793937 -4.44E-04
    33 Broy./Diag. 0.40E+00    6.9     0.00007143     -4911.5499283771 -1.49E-04
    34 Broy./Diag. 0.40E+00    7.1     0.00005094     -4911.5497171137  2.11E-04
    35 Broy./Diag. 0.40E+00    7.3     0.00005946     -4911.5496903158  2.68E-05
    36 Broy./Diag. 0.40E+00    7.1     0.00006560     -4911.5496753529  1.50E-05
    37 Broy./Diag. 0.40E+00    7.1     0.00003987     -4911.5499377306 -2.62E-04
    38 Broy./Diag. 0.40E+00    7.3     0.00002924     -4911.5496846183  2.53E-04
    39 Broy./Diag. 0.40E+00    7.1     0.00004484     -4911.5496907144 -6.10E-06
    40 Broy./Diag. 0.40E+00    6.8     0.00003863     -4911.5498360190 -1.45E-04
    41 Broy./Diag. 0.40E+00    7.4     0.00003727     -4911.5498577686 -2.17E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00004106     -4911.5498534981  4.27E-06
    43 Broy./Diag. 0.40E+00    8.4     0.00002142     -4911.5497041435  1.49E-04
    44 Broy./Diag. 0.40E+00    7.3     0.00001502     -4911.5498537949 -1.50E-04
    45 Broy./Diag. 0.40E+00    9.5     0.00002014     -4911.5498405911  1.32E-05
    46 Broy./Diag. 0.40E+00    7.6     0.00001914     -4911.5497866621  5.39E-05
    47 Broy./Diag. 0.40E+00    7.8     0.00001901     -4911.5497980236 -1.14E-05
    48 Broy./Diag. 0.40E+00   10.6     0.00002556     -4911.5498143226 -1.63E-05
    49 Broy./Diag. 0.40E+00    6.7     0.00001589     -4911.5498942401 -7.99E-05
    50 Broy./Diag. 0.40E+00    7.1     0.00001191     -4911.5497900840  1.04E-04
    51 Broy./Diag. 0.40E+00    7.1     0.00001210     -4911.5498196791 -2.96E-05
    52 Broy./Diag. 0.40E+00    6.7     0.00001032     -4911.5498538500 -3.42E-05
    53 Broy./Diag. 0.40E+00    7.5     0.00000894     -4911.5498464326  7.42E-06
    54 Broy./Diag. 0.40E+00    7.9     0.00001354     -4911.5498398270  6.61E-06
    55 Broy./Diag. 0.40E+00    7.5     0.00000853     -4911.5498058075  3.40E-05
    56 Broy./Diag. 0.40E+00    9.9     0.00000678     -4911.5498658675 -6.01E-05
    57 Broy./Diag. 0.40E+00    7.4     0.00000807     -4911.5498425759  2.33E-05
    58 Broy./Diag. 0.40E+00    9.7     0.00000734     -4911.5498269671  1.56E-05
    59 Broy./Diag. 0.40E+00    8.7     0.00000574     -4911.5498408206 -1.39E-05
    60 Broy./Diag. 0.40E+00    7.3     0.00000836     -4911.5498469291 -6.11E-06
    61 Broy./Diag. 0.40E+00    7.1     0.00000509     -4911.5498646436 -1.77E-05
    62 Broy./Diag. 0.40E+00    7.4     0.00000371     -4911.5498330851  3.16E-05
    63 Broy./Diag. 0.40E+00    7.8     0.00000359     -4911.5498501235 -1.70E-05
    64 Broy./Diag. 0.40E+00    7.1     0.00000370     -4911.5498570395 -6.92E-06
    65 Broy./Diag. 0.40E+00    9.8     0.00000342     -4911.5498500560  6.98E-06
    66 Broy./Diag. 0.40E+00    7.2     0.00000560     -4911.5498481732  1.88E-06
    67 Broy./Diag. 0.40E+00    9.7     0.00000386     -4911.5498398744  8.30E-06
    68 Broy./Diag. 0.40E+00    8.8     0.00000260     -4911.5498633516 -2.35E-05
    69 Broy./Diag. 0.40E+00    6.7     0.00000222     -4911.5498508944  1.25E-05
    70 Broy./Diag. 0.40E+00    6.9     0.00000210     -4911.5498488801  2.01E-06
    71 Broy./Diag. 0.40E+00    7.1     0.00000188     -4911.5498544941 -5.61E-06
    72 Broy./Diag. 0.40E+00    7.3     0.00000264     -4911.5498557585 -1.26E-06
    73 Broy./Diag. 0.40E+00    7.5     0.00000227     -4911.5498586685 -2.91E-06
    74 Broy./Diag. 0.40E+00    7.4     0.00000167     -4911.5498463800  1.23E-05
    75 Broy./Diag. 0.40E+00    7.1     0.00000149     -4911.5498569484 -1.06E-05
    76 Broy./Diag. 0.40E+00    7.9     0.00000142     -4911.5498576395 -6.91E-07
    77 Broy./Diag. 0.40E+00    6.9     0.00000139     -4911.5498541353  3.50E-06
    78 Broy./Diag. 0.40E+00    6.9     0.00000166     -4911.5498545543 -4.19E-07
    79 Broy./Diag. 0.40E+00    7.3     0.00000134     -4911.5498533669  1.19E-06
    80 Broy./Diag. 0.40E+00    7.3     0.00000084     -4911.5498600681 -6.70E-06

  *** SCF run converged in    80 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008262286355
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.60912615298093
  Hartree energy:                                            1781.58225135686871
  Exchange-correlation energy:                               -779.40733964030539
  Electronic entropic energy:                                  -0.24355801948269
  Fermi energy:                                                 0.08694950588926

  Total energy:                                             -4911.54986006813033

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.549858701851008

 MD| ***************************************************************************
 MD| Step number                                                            1192
 MD| Time [fs]                                                       2384.000000
 MD| Conserved quantity [hartree]                            -0.491120145630E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    605.777916           593.565399
 MD| Energy drift per atom [K]           0.245212209157E+03   0.269913454776E+03
 MD| Potential energy [hartree]         -0.491154985870E+04  -0.491156375820E+04
 MD| Kinetic energy [hartree]            0.348402401257E+00   0.374186974984E+00
 MD| Temperature [K]                             928.410511           997.120340
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.6     0.02038739     -4911.5458585219 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.9     0.04354166     -4911.5241330467  2.17E-02
     3 Broy./Diag. 0.40E+00    7.1     0.04787120     -4911.5208438791  3.29E-03
     4 Broy./Diag. 0.40E+00    7.3     0.03801420     -4911.5546299751 -3.38E-02
     5 Broy./Diag. 0.40E+00    6.9     0.02603692     -4911.4922785530  6.24E-02
     6 Broy./Diag. 0.40E+00    6.9     0.00833218     -4911.5677714410 -7.55E-02
     7 Broy./Diag. 0.40E+00    6.9     0.00378706     -4911.5344396545  3.33E-02
     8 Broy./Diag. 0.40E+00    7.2     0.00277625     -4911.5490987526 -1.47E-02
     9 Broy./Diag. 0.40E+00    7.5     0.00221009     -4911.5479974906  1.10E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00162481     -4911.5476482207  3.49E-04
    11 Broy./Diag. 0.40E+00    7.5     0.00214099     -4911.5486600084 -1.01E-03
    12 Broy./Diag. 0.40E+00    8.1     0.00108504     -4911.5442820917  4.38E-03
    13 Broy./Diag. 0.40E+00    7.8     0.00034068     -4911.5486205181 -4.34E-03
    14 Broy./Diag. 0.40E+00    7.3     0.00040501     -4911.5472236182  1.40E-03
    15 Broy./Diag. 0.40E+00    7.1     0.00040132     -4911.5474460246 -2.22E-04
    16 Broy./Diag. 0.40E+00    7.3     0.00024296     -4911.5473675385  7.85E-05
    17 Broy./Diag. 0.40E+00    7.5     0.00052651     -4911.5477029757 -3.35E-04
    18 Broy./Diag. 0.40E+00    7.7     0.00051413     -4911.5485209943 -8.18E-04
    19 Broy./Diag. 0.40E+00    7.1     0.00022269     -4911.5465764149  1.94E-03
    20 Broy./Diag. 0.40E+00    7.3     0.00020020     -4911.5478088554 -1.23E-03
    21 Broy./Diag. 0.40E+00    7.1     0.00028895     -4911.5478584282 -4.96E-05
    22 Broy./Diag. 0.40E+00    7.1     0.00015102     -4911.5480278386 -1.69E-04
    23 Broy./Diag. 0.40E+00    7.6     0.00022463     -4911.5477633042  2.65E-04
    24 Broy./Diag. 0.40E+00    7.2     0.00021238     -4911.5474378731  3.25E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00009568     -4911.5482955980 -8.58E-04
    26 Broy./Diag. 0.40E+00    7.5     0.00008243     -4911.5478233049  4.72E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00012803     -4911.5477977948  2.55E-05
    28 Broy./Diag. 0.40E+00    7.5     0.00010324     -4911.5478542609 -5.65E-05
    29 Broy./Diag. 0.40E+00    7.1     0.00013604     -4911.5481008187 -2.47E-04
    30 Broy./Diag. 0.40E+00    7.1     0.00015262     -4911.5482745548 -1.74E-04
    31 Broy./Diag. 0.40E+00    7.3     0.00006806     -4911.5477152197  5.59E-04
    32 Broy./Diag. 0.40E+00    6.9     0.00004422     -4911.5480558194 -3.41E-04
    33 Broy./Diag. 0.40E+00    6.9     0.00005934     -4911.5481161437 -6.03E-05
    34 Broy./Diag. 0.40E+00    7.5     0.00006071     -4911.5480851142  3.10E-05
    35 Broy./Diag. 0.40E+00    7.2     0.00005687     -4911.5479758085  1.09E-04
    36 Broy./Diag. 0.40E+00    7.1     0.00007506     -4911.5479645379  1.13E-05
    37 Broy./Diag. 0.40E+00    7.3     0.00004617     -4911.5482438742 -2.79E-04
    38 Broy./Diag. 0.40E+00    7.1     0.00003237     -4911.5480399983  2.04E-04
    39 Broy./Diag. 0.40E+00    7.3     0.00003412     -4911.5480412385 -1.24E-06
    40 Broy./Diag. 0.40E+00    7.3     0.00004288     -4911.5480908637 -4.96E-05
    41 Broy./Diag. 0.40E+00    7.0     0.00002877     -4911.5481673131 -7.64E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00003905     -4911.5481726134 -5.30E-06
    43 Broy./Diag. 0.40E+00    7.1     0.00002249     -4911.5480341129  1.39E-04
    44 Broy./Diag. 0.40E+00    7.1     0.00001493     -4911.5481426468 -1.09E-04
    45 Broy./Diag. 0.40E+00    7.1     0.00001955     -4911.5481532220 -1.06E-05
    46 Broy./Diag. 0.40E+00    6.9     0.00002777     -4911.5481282795  2.49E-05
    47 Broy./Diag. 0.40E+00    7.6     0.00001732     -4911.5480995697  2.87E-05
    48 Broy./Diag. 0.40E+00    7.3     0.00002675     -4911.5481177702 -1.82E-05
    49 Broy./Diag. 0.40E+00    6.9     0.00001777     -4911.5482110898 -9.33E-05
    50 Broy./Diag. 0.40E+00    7.3     0.00000997     -4911.5481373293  7.38E-05
    51 Broy./Diag. 0.40E+00    7.3     0.00000989     -4911.5481366989  6.30E-07
    52 Broy./Diag. 0.40E+00    6.9     0.00001246     -4911.5481602523 -2.36E-05
    53 Broy./Diag. 0.40E+00    6.9     0.00000879     -4911.5481730324 -1.28E-05
    54 Broy./Diag. 0.40E+00    7.3     0.00001535     -4911.5481643652  8.67E-06
    55 Broy./Diag. 0.40E+00    7.3     0.00001151     -4911.5481177455  4.66E-05
    56 Broy./Diag. 0.40E+00    6.9     0.00000673     -4911.5481748283 -5.71E-05
    57 Broy./Diag. 0.40E+00    7.3     0.00000829     -4911.5481773994 -2.57E-06
    58 Broy./Diag. 0.40E+00    7.3     0.00000841     -4911.5481599008  1.75E-05
    59 Broy./Diag. 0.40E+00    7.3     0.00000509     -4911.5481584811  1.42E-06
    60 Broy./Diag. 0.40E+00    7.7     0.00000727     -4911.5481667965 -8.32E-06
    61 Broy./Diag. 0.40E+00    6.9     0.00000595     -4911.5481888747 -2.21E-05
    62 Broy./Diag. 0.40E+00    7.4     0.00000302     -4911.5481621344  2.67E-05
    63 Broy./Diag. 0.40E+00    7.3     0.00000434     -4911.5481653423 -3.21E-06
    64 Broy./Diag. 0.40E+00    7.3     0.00000493     -4911.5481787868 -1.34E-05
    65 Broy./Diag. 0.40E+00    7.3     0.00000354     -4911.5481793294 -5.43E-07
    66 Broy./Diag. 0.40E+00    7.3     0.00000526     -4911.5481740582  5.27E-06
    67 Broy./Diag. 0.40E+00    7.1     0.00000432     -4911.5481613402  1.27E-05
    68 Broy./Diag. 0.40E+00    6.9     0.00000182     -4911.5481824360 -2.11E-05
    69 Broy./Diag. 0.40E+00    7.1     0.00000258     -4911.5481811808  1.26E-06
    70 Broy./Diag. 0.40E+00    7.9     0.00000235     -4911.5481737682  7.41E-06
    71 Broy./Diag. 0.40E+00    7.1     0.00000180     -4911.5481759472 -2.18E-06
    72 Broy./Diag. 0.40E+00    7.6     0.00000263     -4911.5481800965 -4.15E-06
    73 Broy./Diag. 0.40E+00    6.9     0.00000283     -4911.5481858856 -5.79E-06
    74 Broy./Diag. 0.40E+00    7.1     0.00000143     -4911.5481728783  1.30E-05
    75 Broy./Diag. 0.40E+00    6.7     0.00000175     -4911.5481771431 -4.26E-06
    76 Broy./Diag. 0.40E+00    7.2     0.00000157     -4911.5481832909 -6.15E-06
    77 Broy./Diag. 0.40E+00    7.3     0.00000129     -4911.5481816934  1.60E-06
    78 Broy./Diag. 0.40E+00    7.8     0.00000141     -4911.5481797427  1.95E-06
    79 Broy./Diag. 0.40E+00    7.1     0.00000138     -4911.5481774816  2.26E-06
    80 Broy./Diag. 0.40E+00    7.1     0.00000078     -4911.5481842747 -6.79E-06

  *** SCF run converged in    80 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008262411096
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.59652677155009
  Hartree energy:                                            1781.58970968959989
  Exchange-correlation energy:                               -779.40047624063686
  Electronic entropic energy:                                  -0.24360460474239
  Fermi energy:                                                 0.08693582098121

  Total energy:                                             -4911.54818427472674

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.548184193687121

 MD| ***************************************************************************
 MD| Step number                                                            1193
 MD| Time [fs]                                                       2386.000000
 MD| Conserved quantity [hartree]                            -0.491121233503E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    586.686632           593.559633
 MD| Energy drift per atom [K]           0.222612021555E+03   0.269873805628E+03
 MD| Potential energy [hartree]         -0.491154818419E+04  -0.491156374515E+04
 MD| Kinetic energy [hartree]            0.335849158723E+00   0.374154839346E+00
 MD| Temperature [K]                             894.959070           997.034706
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.01928350     -4911.5446940832 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.03488509     -4911.5213577080  2.33E-02
     3 Broy./Diag. 0.40E+00    7.1     0.04157313     -4911.5215305261 -1.73E-04
     4 Broy./Diag. 0.40E+00    6.8     0.03472590     -4911.5411396816 -1.96E-02
     5 Broy./Diag. 0.40E+00    7.5     0.02419789     -4911.5074124919  3.37E-02
     6 Broy./Diag. 0.40E+00    7.3     0.00877273     -4911.5689917589 -6.16E-02
     7 Broy./Diag. 0.40E+00    7.2     0.00371676     -4911.5257982194  4.32E-02
     8 Broy./Diag. 0.40E+00    6.7     0.00238766     -4911.5499951677 -2.42E-02
     9 Broy./Diag. 0.40E+00    7.3     0.00170238     -4911.5460788133  3.92E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00160257     -4911.5463896660 -3.11E-04
    11 Broy./Diag. 0.40E+00    7.5     0.00182883     -4911.5463742794  1.54E-05
    12 Broy./Diag. 0.40E+00    7.5     0.00105132     -4911.5433257101  3.05E-03
    13 Broy./Diag. 0.40E+00    7.8     0.00033070     -4911.5474593274 -4.13E-03
    14 Broy./Diag. 0.40E+00    7.2     0.00039858     -4911.5452901365  2.17E-03
    15 Broy./Diag. 0.40E+00    7.2     0.00031903     -4911.5461920354 -9.02E-04
    16 Broy./Diag. 0.40E+00    6.7     0.00029285     -4911.5459895064  2.03E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00049590     -4911.5464828810 -4.93E-04
    18 Broy./Diag. 0.40E+00    7.3     0.00051921     -4911.5470356637 -5.53E-04
    19 Broy./Diag. 0.40E+00    7.1     0.00023892     -4911.5450690151  1.97E-03
    20 Broy./Diag. 0.40E+00    6.8     0.00021971     -4911.5466625154 -1.59E-03
    21 Broy./Diag. 0.40E+00    7.1     0.00023897     -4911.5463180962  3.44E-04
    22 Broy./Diag. 0.40E+00    7.5     0.00015284     -4911.5466463629 -3.28E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00019682     -4911.5463534691  2.93E-04
    24 Broy./Diag. 0.40E+00    6.7     0.00018777     -4911.5462002746  1.53E-04
    25 Broy./Diag. 0.40E+00    6.9     0.00009431     -4911.5469883805 -7.88E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00008527     -4911.5463990012  5.89E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00011336     -4911.5465599646 -1.61E-04
    28 Broy./Diag. 0.40E+00    7.5     0.00009910     -4911.5465384159  2.15E-05
    29 Broy./Diag. 0.40E+00    7.3     0.00013369     -4911.5468075710 -2.69E-04
    30 Broy./Diag. 0.40E+00    7.5     0.00013941     -4911.5468912245 -8.37E-05
    31 Broy./Diag. 0.40E+00    7.4     0.00006759     -4911.5463536391  5.38E-04
    32 Broy./Diag. 0.40E+00    7.7     0.00004122     -4911.5467917742 -4.38E-04
    33 Broy./Diag. 0.40E+00    7.2     0.00005622     -4911.5467622181  2.96E-05
    34 Broy./Diag. 0.40E+00    7.1     0.00004698     -4911.5467771589 -1.49E-05
    35 Broy./Diag. 0.40E+00    6.9     0.00005539     -4911.5466607891  1.16E-04
    36 Broy./Diag. 0.40E+00    6.7     0.00006674     -4911.5467014154 -4.06E-05
    37 Broy./Diag. 0.40E+00    6.9     0.00004530     -4911.5469583087 -2.57E-04
    38 Broy./Diag. 0.40E+00    7.1     0.00003255     -4911.5466851960  2.73E-04
    39 Broy./Diag. 0.40E+00    6.9     0.00003582     -4911.5467621935 -7.70E-05
    40 Broy./Diag. 0.40E+00    7.3     0.00002962     -4911.5467778968 -1.57E-05
    41 Broy./Diag. 0.40E+00    7.7     0.00003114     -4911.5468660914 -8.82E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00003273     -4911.5468495267  1.66E-05
    43 Broy./Diag. 0.40E+00    7.8     0.00001944     -4911.5467292768  1.20E-04
    44 Broy./Diag. 0.40E+00    7.1     0.00001440     -4911.5468550997 -1.26E-04
    45 Broy./Diag. 0.40E+00    7.0     0.00001938     -4911.5468336685  2.14E-05
    46 Broy./Diag. 0.40E+00    7.2     0.00001686     -4911.5468314751  2.19E-06
    47 Broy./Diag. 0.40E+00    6.9     0.00002114     -4911.5467958828  3.56E-05
    48 Broy./Diag. 0.40E+00    7.3     0.00002389     -4911.5468254755 -2.96E-05
    49 Broy./Diag. 0.40E+00    6.9     0.00001557     -4911.5469123156 -8.68E-05
    50 Broy./Diag. 0.40E+00    7.3     0.00000924     -4911.5468230681  8.92E-05
    51 Broy./Diag. 0.40E+00    7.1     0.00000845     -4911.5468440760 -2.10E-05
    52 Broy./Diag. 0.40E+00    7.1     0.00000783     -4911.5468552564 -1.12E-05
    53 Broy./Diag. 0.40E+00    6.9     0.00001092     -4911.5468717350 -1.65E-05
    54 Broy./Diag. 0.40E+00    6.9     0.00001343     -4911.5468590771  1.27E-05
    55 Broy./Diag. 0.40E+00    7.1     0.00000963     -4911.5468196795  3.94E-05
    56 Broy./Diag. 0.40E+00    7.1     0.00000646     -4911.5468807442 -6.11E-05
    57 Broy./Diag. 0.40E+00    7.1     0.00000709     -4911.5468683180  1.24E-05
    58 Broy./Diag. 0.40E+00    7.3     0.00000581     -4911.5468624723  5.85E-06
    59 Broy./Diag. 0.40E+00    6.9     0.00000618     -4911.5468578839  4.59E-06
    60 Broy./Diag. 0.40E+00    7.1     0.00000641     -4911.5468675906 -9.71E-06
    61 Broy./Diag. 0.40E+00    7.3     0.00000477     -4911.5468864993 -1.89E-05
    62 Broy./Diag. 0.40E+00    6.9     0.00000339     -4911.5468591373  2.74E-05
    63 Broy./Diag. 0.40E+00    7.7     0.00000343     -4911.5468689514 -9.81E-06
    64 Broy./Diag. 0.40E+00    7.3     0.00000374     -4911.5468760782 -7.13E-06
    65 Broy./Diag. 0.40E+00    7.1     0.00000450     -4911.5468788786 -2.80E-06
    66 Broy./Diag. 0.40E+00    7.2     0.00000481     -4911.5468730180  5.86E-06
    67 Broy./Diag. 0.40E+00    7.1     0.00000348     -4911.5468623565  1.07E-05
    68 Broy./Diag. 0.40E+00    7.1     0.00000227     -4911.5468833351 -2.10E-05
    69 Broy./Diag. 0.40E+00    7.1     0.00000194     -4911.5468782319  5.10E-06
    70 Broy./Diag. 0.40E+00    7.1     0.00000189     -4911.5468747695  3.46E-06
    71 Broy./Diag. 0.40E+00    6.7     0.00000198     -4911.5468757765 -1.01E-06
    72 Broy./Diag. 0.40E+00    7.5     0.00000250     -4911.5468798990 -4.12E-06
    73 Broy./Diag. 0.40E+00    7.3     0.00000231     -4911.5468849167 -5.02E-06
    74 Broy./Diag. 0.40E+00    7.1     0.00000155     -4911.5468720010  1.29E-05
    75 Broy./Diag. 0.40E+00    6.9     0.00000132     -4911.5468784323 -6.43E-06
    76 Broy./Diag. 0.40E+00    7.7     0.00000139     -4911.5468819053 -3.47E-06
    77 Broy./Diag. 0.40E+00    7.3     0.00000121     -4911.5468812526  6.53E-07
    78 Broy./Diag. 0.40E+00    6.9     0.00000130     -4911.5468794410  1.81E-06
    79 Broy./Diag. 0.40E+00    7.7     0.00000110     -4911.5468777129  1.73E-06
    80 Broy./Diag. 0.40E+00    8.5     0.00000076     -4911.5468840543 -6.34E-06

  *** SCF run converged in    80 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008260187120
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.57718891942113
  Hartree energy:                                            1781.60118337200083
  Exchange-correlation energy:                               -779.39124172191464
  Electronic entropic energy:                                  -0.24367470976771
  Fermi energy:                                                 0.08690939378294

  Total energy:                                             -4911.54688405425804

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.546883813368368

 MD| ***************************************************************************
 MD| Step number                                                            1194
 MD| Time [fs]                                                       2388.000000
 MD| Conserved quantity [hartree]                            -0.491120668953E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    582.940735           593.550740
 MD| Energy drift per atom [K]           0.234340363810E+03   0.269844045626E+03
 MD| Potential energy [hartree]         -0.491154688381E+04  -0.491156373103E+04
 MD| Kinetic energy [hartree]            0.340194285523E+00   0.374126396671E+00
 MD| Temperature [K]                             906.537812           996.958913
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.02022361     -4911.5437554823 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.03793546     -4911.4992107851  4.45E-02
     3 Broy./Diag. 0.40E+00    7.1     0.04762779     -4911.5831476226 -8.39E-02
     4 Broy./Diag. 0.40E+00    7.2     0.02259862     -4911.4730494305  1.10E-01
     5 Broy./Diag. 0.40E+00    7.3     0.01746821     -4911.5497310639 -7.67E-02
     6 Broy./Diag. 0.40E+00    7.5     0.01472740     -4911.5626917854 -1.30E-02
     7 Broy./Diag. 0.40E+00    7.5     0.00545791     -4911.5152137438  4.75E-02
     8 Broy./Diag. 0.40E+00    7.5     0.00226227     -4911.5537930418 -3.86E-02
     9 Broy./Diag. 0.40E+00    7.5     0.00145194     -4911.5455106722  8.28E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00128589     -4911.5461062875 -5.96E-04
    11 Broy./Diag. 0.40E+00    7.1     0.00111479     -4911.5414944204  4.61E-03
    12 Broy./Diag. 0.40E+00    7.1     0.00105230     -4911.5445264693 -3.03E-03
    13 Broy./Diag. 0.40E+00    7.1     0.00073535     -4911.5473641821 -2.84E-03
    14 Broy./Diag. 0.40E+00    7.3     0.00037601     -4911.5438480538  3.52E-03
    15 Broy./Diag. 0.40E+00    6.7     0.00027868     -4911.5454739249 -1.63E-03
    16 Broy./Diag. 0.40E+00    7.8     0.00020999     -4911.5452038874  2.70E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00034842     -4911.5460874197 -8.84E-04
    18 Broy./Diag. 0.40E+00    7.1     0.00053147     -4911.5449934260  1.09E-03
    19 Broy./Diag. 0.40E+00    7.1     0.00039865     -4911.5440243188  9.69E-04
    20 Broy./Diag. 0.40E+00    7.3     0.00019829     -4911.5460355862 -2.01E-03
    21 Broy./Diag. 0.40E+00    7.7     0.00019442     -4911.5453239321  7.12E-04
    22 Broy./Diag. 0.40E+00    7.1     0.00013041     -4911.5456694155 -3.45E-04
    23 Broy./Diag. 0.40E+00    6.9     0.00011900     -4911.5452582906  4.11E-04
    24 Broy./Diag. 0.40E+00    6.7     0.00016981     -4911.5457525767 -4.94E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00015360     -4911.5460563641 -3.04E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00008355     -4911.5452863672  7.70E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00008942     -4911.5456472705 -3.61E-04
    28 Broy./Diag. 0.40E+00    7.3     0.00009250     -4911.5456269599  2.03E-05
    29 Broy./Diag. 0.40E+00    6.9     0.00008452     -4911.5459623293 -3.35E-04
    30 Broy./Diag. 0.40E+00    7.1     0.00012640     -4911.5455975194  3.65E-04
    31 Broy./Diag. 0.40E+00    7.1     0.00010476     -4911.5454454546  1.52E-04
    32 Broy./Diag. 0.40E+00    7.3     0.00004302     -4911.5459832933 -5.38E-04
    33 Broy./Diag. 0.40E+00    6.7     0.00004466     -4911.5458240482  1.59E-04
    34 Broy./Diag. 0.40E+00    7.1     0.00004581     -4911.5458285273 -4.48E-06
    35 Broy./Diag. 0.40E+00    7.1     0.00004226     -4911.5456756316  1.53E-04
    36 Broy./Diag. 0.40E+00    6.9     0.00006307     -4911.5458946477 -2.19E-04
    37 Broy./Diag. 0.40E+00    7.3     0.00007228     -4911.5459677503 -7.31E-05
    38 Broy./Diag. 0.40E+00    6.7     0.00003491     -4911.5456257632  3.42E-04
    39 Broy./Diag. 0.40E+00    7.5     0.00003276     -4911.5458186526 -1.93E-04
    40 Broy./Diag. 0.40E+00    6.7     0.00002945     -4911.5458405873 -2.19E-05
    41 Broy./Diag. 0.40E+00    7.2     0.00002761     -4911.5459486377 -1.08E-04
    42 Broy./Diag. 0.40E+00    7.3     0.00002610     -4911.5458311909  1.17E-04
    43 Broy./Diag. 0.40E+00    7.3     0.00002501     -4911.5458067656  2.44E-05
    44 Broy./Diag. 0.40E+00    7.2     0.00001479     -4911.5459299725 -1.23E-04
    45 Broy./Diag. 0.40E+00    6.9     0.00001808     -4911.5458593250  7.06E-05
    46 Broy./Diag. 0.40E+00    7.5     0.00001511     -4911.5458594142 -8.92E-08
    47 Broy./Diag. 0.40E+00    8.4     0.00002086     -4911.5458204369  3.90E-05
    48 Broy./Diag. 0.40E+00    7.1     0.00002063     -4911.5459159237 -9.55E-05
    49 Broy./Diag. 0.40E+00    9.4     0.00002030     -4911.5459349338 -1.90E-05
    50 Broy./Diag. 0.40E+00    7.6     0.00001002     -4911.5458434151  9.15E-05
    51 Broy./Diag. 0.40E+00   10.3     0.00000792     -4911.5458935784 -5.02E-05
    52 Broy./Diag. 0.40E+00    8.8     0.00000588     -4911.5458976979 -4.12E-06
    53 Broy./Diag. 0.40E+00    6.8     0.00001049     -4911.5459115781 -1.39E-05
    54 Broy./Diag. 0.40E+00    7.5     0.00001079     -4911.5458681446  4.34E-05
    55 Broy./Diag. 0.40E+00    7.1     0.00001210     -4911.5458752161 -7.07E-06
    56 Broy./Diag. 0.40E+00    7.3     0.00000763     -4911.5459315076 -5.63E-05
    57 Broy./Diag. 0.40E+00    8.0     0.00000717     -4911.5458954539  3.61E-05
    58 Broy./Diag. 0.40E+00    7.5     0.00000414     -4911.5458966719 -1.22E-06
    59 Broy./Diag. 0.40E+00    9.9     0.00000506     -4911.5458920885  4.58E-06
    60 Broy./Diag. 0.40E+00    7.4     0.00000461     -4911.5459148063 -2.27E-05
    61 Broy./Diag. 0.40E+00    8.7     0.00000548     -4911.5459118236  2.98E-06
    62 Broy./Diag. 0.40E+00    9.4     0.00000356     -4911.5458879421  2.39E-05
    63 Broy./Diag. 0.40E+00    7.1     0.00000347     -4911.5459083900 -2.04E-05
    64 Broy./Diag. 0.40E+00    7.3     0.00000276     -4911.5459100623 -1.67E-06
    65 Broy./Diag. 0.40E+00    7.7     0.00000393     -4911.5459129716 -2.91E-06
    66 Broy./Diag. 0.40E+00    8.0     0.00000359     -4911.5458975153  1.55E-05
    67 Broy./Diag. 0.40E+00    7.3     0.00000376     -4911.5459031577 -5.64E-06
    68 Broy./Diag. 0.40E+00   10.2     0.00000211     -4911.5459200697 -1.69E-05
    69 Broy./Diag. 0.40E+00    7.2     0.00000173     -4911.5459085602  1.15E-05
    70 Broy./Diag. 0.40E+00   10.0     0.00000144     -4911.5459084455  1.15E-07
    71 Broy./Diag. 0.40E+00    9.0     0.00000163     -4911.5459087137 -2.68E-07
    72 Broy./Diag. 0.40E+00    7.1     0.00000205     -4911.5459160245 -7.31E-06
    73 Broy./Diag. 0.40E+00    6.9     0.00000268     -4911.5459127596  3.26E-06
    74 Broy./Diag. 0.40E+00    6.8     0.00000166     -4911.5459023114  1.04E-05
    75 Broy./Diag. 0.40E+00    6.7     0.00000127     -4911.5459131213 -1.08E-05
    76 Broy./Diag. 0.40E+00    7.3     0.00000107     -4911.5459136738 -5.52E-07
    77 Broy./Diag. 0.40E+00    7.3     0.00000093     -4911.5459136418  3.20E-08

  *** SCF run converged in    77 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008256237804
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.55883873072025
  Hartree energy:                                            1781.61177511957135
  Exchange-correlation energy:                               -779.38245124765513
  Electronic entropic energy:                                  -0.24373627315626
  Fermi energy:                                                 0.08687879252932

  Total energy:                                             -4911.54591364180669

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.545915043046989

 MD| ***************************************************************************
 MD| Step number                                                            1195
 MD| Time [fs]                                                       2390.000000
 MD| Conserved quantity [hartree]                            -0.491121023280E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    585.077405           593.543649
 MD| Energy drift per atom [K]           0.226979335854E+03   0.269808175576E+03
 MD| Potential energy [hartree]         -0.491154591504E+04  -0.491156371612E+04
 MD| Kinetic energy [hartree]            0.335682240727E+00   0.374094225830E+00
 MD| Temperature [K]                             894.514273           996.873185
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    7.4     0.01818490     -4911.5429121901 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.02486917     -4911.5155918146  2.73E-02
     3 Broy./Diag. 0.40E+00    7.3     0.03928474     -4911.5257089037 -1.01E-02
     4 Broy./Diag. 0.40E+00    6.9     0.03577081     -4911.5493500367 -2.36E-02
     5 Broy./Diag. 0.40E+00    7.2     0.01879854     -4911.5126272338  3.67E-02
     6 Broy./Diag. 0.40E+00    7.3     0.00770676     -4911.5732462582 -6.06E-02
     7 Broy./Diag. 0.40E+00    7.4     0.00410665     -4911.5297745231  4.35E-02
     8 Broy./Diag. 0.40E+00    6.5     0.00192178     -4911.5566977649 -2.69E-02
     9 Broy./Diag. 0.40E+00    7.1     0.00126152     -4911.5441788907  1.25E-02
    10 Broy./Diag. 0.40E+00    7.1     0.00100481     -4911.5437018689  4.77E-04
    11 Broy./Diag. 0.40E+00    7.2     0.00103140     -4911.5445431840 -8.41E-04
    12 Broy./Diag. 0.40E+00    7.1     0.00060713     -4911.5432791219  1.26E-03
    13 Broy./Diag. 0.40E+00    7.1     0.00032911     -4911.5457672996 -2.49E-03
    14 Broy./Diag. 0.40E+00    7.3     0.00028718     -4911.5433204742  2.45E-03
    15 Broy./Diag. 0.40E+00    7.1     0.00023078     -4911.5450077693 -1.69E-03
    16 Broy./Diag. 0.40E+00    7.1     0.00024204     -4911.5445910784  4.17E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00044067     -4911.5443799001  2.11E-04
    18 Broy./Diag. 0.40E+00    7.5     0.00037965     -4911.5449127482 -5.33E-04
    19 Broy./Diag. 0.40E+00    7.5     0.00018173     -4911.5438258826  1.09E-03
    20 Broy./Diag. 0.40E+00    7.3     0.00013845     -4911.5450727671 -1.25E-03
    21 Broy./Diag. 0.40E+00    7.1     0.00011388     -4911.5443032588  7.70E-04
    22 Broy./Diag. 0.40E+00    7.2     0.00008348     -4911.5446404461 -3.37E-04
    23 Broy./Diag. 0.40E+00    6.5     0.00010386     -4911.5447148920 -7.44E-05
    24 Broy./Diag. 0.40E+00    7.1     0.00010648     -4911.5446371801  7.77E-05
    25 Broy./Diag. 0.40E+00    6.9     0.00007615     -4911.5449166089 -2.79E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00004640     -4911.5443986286  5.18E-04
    27 Broy./Diag. 0.40E+00    7.3     0.00006051     -4911.5448104749 -4.12E-04
    28 Broy./Diag. 0.40E+00    7.3     0.00008402     -4911.5446860064  1.24E-04
    29 Broy./Diag. 0.40E+00    6.9     0.00009136     -4911.5447017300 -1.57E-05
    30 Broy./Diag. 0.40E+00    6.7     0.00007807     -4911.5447793169 -7.76E-05
    31 Broy./Diag. 0.40E+00    7.2     0.00003537     -4911.5445929358  1.86E-04
    32 Broy./Diag. 0.40E+00    7.1     0.00002481     -4911.5448855933 -2.93E-04
    33 Broy./Diag. 0.40E+00    7.5     0.00002334     -4911.5447406335  1.45E-04
    34 Broy./Diag. 0.40E+00    7.3     0.00002622     -4911.5447593540 -1.87E-05
    35 Broy./Diag. 0.40E+00    7.4     0.00003199     -4911.5447762060 -1.69E-05
    36 Broy./Diag. 0.40E+00    6.7     0.00004250     -4911.5447814999 -5.29E-06
    37 Broy./Diag. 0.40E+00    7.5     0.00002765     -4911.5448813687 -9.99E-05
    38 Broy./Diag. 0.40E+00    7.3     0.00002505     -4911.5446819174  1.99E-04
    39 Broy./Diag. 0.40E+00    7.3     0.00001654     -4911.5448129142 -1.31E-04
    40 Broy./Diag. 0.40E+00    6.9     0.00001692     -4911.5448210657 -8.15E-06
    41 Broy./Diag. 0.40E+00    6.9     0.00001450     -4911.5448081819  1.29E-05
    42 Broy./Diag. 0.40E+00    7.5     0.00001530     -4911.5448058282  2.35E-06
    43 Broy./Diag. 0.40E+00    6.9     0.00000956     -4911.5447782763  2.76E-05
    44 Broy./Diag. 0.40E+00    7.5     0.00001319     -4911.5448452382 -6.70E-05
    45 Broy./Diag. 0.40E+00    7.3     0.00000974     -4911.5447842065  6.10E-05
    46 Broy./Diag. 0.40E+00    7.3     0.00001128     -4911.5447921264 -7.92E-06
    47 Broy./Diag. 0.40E+00    7.1     0.00001193     -4911.5448136876 -2.16E-05
    48 Broy./Diag. 0.40E+00    7.1     0.00001392     -4911.5448218927 -8.21E-06
    49 Broy./Diag. 0.40E+00    7.1     0.00000748     -4911.5448471502 -2.53E-05
    50 Broy./Diag. 0.40E+00    7.3     0.00000557     -4911.5447979834  4.92E-05
    51 Broy./Diag. 0.40E+00    7.7     0.00000283     -4911.5448257415 -2.78E-05
    52 Broy./Diag. 0.40E+00    7.3     0.00000408     -4911.5448259462 -2.05E-07
    53 Broy./Diag. 0.40E+00    6.6     0.00000549     -4911.5448164342  9.51E-06
    54 Broy./Diag. 0.40E+00    7.3     0.00000734     -4911.5448160878  3.46E-07
    55 Broy./Diag. 0.40E+00    6.7     0.00000518     -4911.5448114806  4.61E-06
    56 Broy./Diag. 0.40E+00    7.3     0.00000498     -4911.5448444655 -3.30E-05
    57 Broy./Diag. 0.40E+00    7.3     0.00000312     -4911.5448196829  2.48E-05
    58 Broy./Diag. 0.40E+00    7.4     0.00000228     -4911.5448207524 -1.07E-06
    59 Broy./Diag. 0.40E+00    7.1     0.00000245     -4911.5448280465 -7.29E-06
    60 Broy./Diag. 0.40E+00    7.1     0.00000295     -4911.5448284966 -4.50E-07
    61 Broy./Diag. 0.40E+00    7.1     0.00000240     -4911.5448301631 -1.67E-06
    62 Broy./Diag. 0.40E+00    6.9     0.00000185     -4911.5448170579  1.31E-05
    63 Broy./Diag. 0.40E+00    7.1     0.00000189     -4911.5448309696 -1.39E-05
    64 Broy./Diag. 0.40E+00    7.0     0.00000202     -4911.5448305839  3.86E-07
    65 Broy./Diag. 0.40E+00    7.1     0.00000231     -4911.5448249005  5.68E-06
    66 Broy./Diag. 0.40E+00    7.9     0.00000227     -4911.5448260712 -1.17E-06
    67 Broy./Diag. 0.40E+00    7.1     0.00000161     -4911.5448258084  2.63E-07
    68 Broy./Diag. 0.40E+00    6.7     0.00000090     -4911.5448343486 -8.54E-06

  *** SCF run converged in    68 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008254412478
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.54830123830834
  Hartree energy:                                            1781.61762398928454
  Exchange-correlation energy:                               -779.37664580615092
  Electronic entropic energy:                                  -0.24377377163707
  Fermi energy:                                                 0.08685477741222

  Total energy:                                             -4911.54483434857048

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.544830865273980

 MD| ***************************************************************************
 MD| Step number                                                            1196
 MD| Time [fs]                                                       2392.000000
 MD| Conserved quantity [hartree]                            -0.491120770445E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    495.840284           593.461957
 MD| Energy drift per atom [K]           0.232231890828E+03   0.269776757278E+03
 MD| Potential energy [hartree]         -0.491154483087E+04  -0.491156370033E+04
 MD| Kinetic energy [hartree]            0.337126411450E+00   0.374063316286E+00
 MD| Temperature [K]                             898.362649           996.790819
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.01508017     -4911.5423237777 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.05024667     -4911.5473523641 -5.03E-03
     3 Broy./Diag. 0.40E+00    6.9     0.07678167     -4911.3980103597  1.49E-01
     4 Broy./Diag. 0.40E+00    7.3     0.04714075     -4911.6506646773 -2.53E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01301634     -4911.5254116428  1.25E-01
     6 Broy./Diag. 0.40E+00    7.2     0.00521525     -4911.5464801431 -2.11E-02
     7 Broy./Diag. 0.40E+00    7.8     0.00302581     -4911.5360807055  1.04E-02
     8 Broy./Diag. 0.40E+00    6.9     0.00195486     -4911.5521708603 -1.61E-02
     9 Broy./Diag. 0.40E+00    7.5     0.00132750     -4911.5450544554  7.12E-03
    10 Broy./Diag. 0.40E+00    7.7     0.00142933     -4911.5373955498  7.66E-03
    11 Broy./Diag. 0.40E+00    6.9     0.00104793     -4911.5449106424 -7.52E-03
    12 Broy./Diag. 0.40E+00    6.5     0.00048958     -4911.5437765731  1.13E-03
    13 Broy./Diag. 0.40E+00    6.7     0.00022738     -4911.5438631424 -8.66E-05
    14 Broy./Diag. 0.40E+00    7.1     0.00021209     -4911.5429482409  9.15E-04
    15 Broy./Diag. 0.40E+00    7.5     0.00018348     -4911.5440837603 -1.14E-03
    16 Broy./Diag. 0.40E+00    7.8     0.00028283     -4911.5442572231 -1.73E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00039953     -4911.5426192274  1.64E-03
    18 Broy./Diag. 0.40E+00    7.5     0.00021058     -4911.5434398288 -8.21E-04
    19 Broy./Diag. 0.40E+00    7.0     0.00014693     -4911.5438240832 -3.84E-04
    20 Broy./Diag. 0.40E+00    6.8     0.00010127     -4911.5440970836 -2.73E-04
    21 Broy./Diag. 0.40E+00    7.5     0.00011419     -4911.5434673828  6.30E-04
    22 Broy./Diag. 0.40E+00    6.9     0.00007715     -4911.5436458869 -1.79E-04
    23 Broy./Diag. 0.40E+00    7.3     0.00010405     -4911.5441674922 -5.22E-04
    24 Broy./Diag. 0.40E+00    6.9     0.00006424     -4911.5438900447  2.77E-04
    25 Broy./Diag. 0.40E+00    7.3     0.00006197     -4911.5437857442  1.04E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00003770     -4911.5437132290  7.25E-05
    27 Broy./Diag. 0.40E+00    7.3     0.00006246     -4911.5440404871 -3.27E-04
    28 Broy./Diag. 0.40E+00    7.1     0.00006550     -4911.5438992672  1.41E-04
    29 Broy./Diag. 0.40E+00    7.3     0.00008895     -4911.5435517146  3.48E-04
    30 Broy./Diag. 0.40E+00    7.5     0.00005331     -4911.5438862915 -3.35E-04
    31 Broy./Diag. 0.40E+00    7.1     0.00003480     -4911.5439710311 -8.47E-05
    32 Broy./Diag. 0.40E+00    7.4     0.00001989     -4911.5439959655 -2.49E-05
    33 Broy./Diag. 0.40E+00    7.5     0.00001735     -4911.5438724163  1.24E-04
    34 Broy./Diag. 0.40E+00    6.9     0.00001731     -4911.5439209109 -4.85E-05
    35 Broy./Diag. 0.40E+00    7.3     0.00002938     -4911.5440028874 -8.20E-05
    36 Broy./Diag. 0.40E+00    6.9     0.00002931     -4911.5438845037  1.18E-04
    37 Broy./Diag. 0.40E+00    6.9     0.00002269     -4911.5438718181  1.27E-05
    38 Broy./Diag. 0.40E+00    7.1     0.00001652     -4911.5438913299 -1.95E-05
    39 Broy./Diag. 0.40E+00    7.1     0.00001107     -4911.5439825860 -9.13E-05
    40 Broy./Diag. 0.40E+00    7.5     0.00001216     -4911.5439482794  3.43E-05
    41 Broy./Diag. 0.40E+00    6.7     0.00001380     -4911.5438978249  5.05E-05
    42 Broy./Diag. 0.40E+00    6.9     0.00001117     -4911.5439587742 -6.09E-05
    43 Broy./Diag. 0.40E+00    6.8     0.00000689     -4911.5439558413  2.93E-06
    44 Broy./Diag. 0.40E+00    7.1     0.00000794     -4911.5439482241  7.62E-06
    45 Broy./Diag. 0.40E+00    7.1     0.00000783     -4911.5439118627  3.64E-05
    46 Broy./Diag. 0.40E+00    7.3     0.00000765     -4911.5439494452 -3.76E-05
    47 Broy./Diag. 0.40E+00    6.9     0.00001125     -4911.5439777780 -2.83E-05
    48 Broy./Diag. 0.40E+00    6.7     0.00001063     -4911.5439269356  5.08E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00000487     -4911.5439402239 -1.33E-05
    50 Broy./Diag. 0.40E+00    7.3     0.00000295     -4911.5439493424 -9.12E-06
    51 Broy./Diag. 0.40E+00    6.8     0.00000297     -4911.5439614279 -1.21E-05
    52 Broy./Diag. 0.40E+00    7.1     0.00000255     -4911.5439499306  1.15E-05
    53 Broy./Diag. 0.40E+00    7.3     0.00000430     -4911.5439435195  6.41E-06
    54 Broy./Diag. 0.40E+00    7.2     0.00000519     -4911.5439660284 -2.25E-05
    55 Broy./Diag. 0.40E+00    7.5     0.00000308     -4911.5439569047  9.12E-06
    56 Broy./Diag. 0.40E+00    7.3     0.00000250     -4911.5439514566  5.45E-06
    57 Broy./Diag. 0.40E+00    7.1     0.00000275     -4911.5439466970  4.76E-06
    58 Broy./Diag. 0.40E+00    6.5     0.00000139     -4911.5439582692 -1.16E-05
    59 Broy./Diag. 0.40E+00    7.1     0.00000199     -4911.5439611771 -2.91E-06
    60 Broy./Diag. 0.40E+00    7.1     0.00000227     -4911.5439510163  1.02E-05
    61 Broy./Diag. 0.40E+00    7.1     0.00000125     -4911.5439566152 -5.60E-06
    62 Broy./Diag. 0.40E+00    6.8     0.00000122     -4911.5439591924 -2.58E-06
    63 Broy./Diag. 0.40E+00    7.1     0.00000163     -4911.5439599396 -7.47E-07
    64 Broy./Diag. 0.40E+00    7.1     0.00000108     -4911.5439533875  6.55E-06
    65 Broy./Diag. 0.40E+00    7.4     0.00000151     -4911.5439545844 -1.20E-06
    66 Broy./Diag. 0.40E+00    7.1     0.00000179     -4911.5439630196 -8.44E-06
    67 Broy./Diag. 0.40E+00    7.0     0.00000094     -4911.5439582705  4.75E-06

  *** SCF run converged in    67 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008252932004
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.53662714972916
  Hartree energy:                                            1781.62428040659324
  Exchange-correlation energy:                               -779.37075163533370
  Electronic entropic energy:                                  -0.24377420865614
  Fermi energy:                                                 0.08682890686761

  Total energy:                                             -4911.54395827054032

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.543960083933598

 MD| ***************************************************************************
 MD| Step number                                                            1197
 MD| Time [fs]                                                       2394.000000
 MD| Conserved quantity [hartree]                            -0.491120954992E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    486.249914           593.372390
 MD| Energy drift per atom [K]           0.228398005170E+03   0.269742188563E+03
 MD| Potential energy [hartree]         -0.491154396008E+04  -0.491156368384E+04
 MD| Kinetic energy [hartree]            0.334410166506E+00   0.374030189177E+00
 MD| Temperature [K]                             891.124494           996.702543
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.01438341     -4911.5420373443 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.7     0.06354431     -4911.5181624356  2.39E-02
     3 Broy./Diag. 0.40E+00    6.9     0.08636939     -4911.4488719302  6.93E-02
     4 Broy./Diag. 0.40E+00    7.1     0.04620662     -4911.6265850162 -1.78E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01527680     -4911.4908155168  1.36E-01
     6 Broy./Diag. 0.40E+00    7.5     0.00696485     -4911.5621560861 -7.13E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00268148     -4911.5439218606  1.82E-02
     8 Broy./Diag. 0.40E+00    7.0     0.00213825     -4911.5373006303  6.62E-03
     9 Broy./Diag. 0.40E+00    7.3     0.00144334     -4911.5439474935 -6.65E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00108667     -4911.5400636307  3.88E-03
    11 Broy./Diag. 0.40E+00    7.3     0.00086578     -4911.5443343996 -4.27E-03
    12 Broy./Diag. 0.40E+00    7.1     0.00048610     -4911.5418646143  2.47E-03
    13 Broy./Diag. 0.40E+00    7.2     0.00034967     -4911.5433957215 -1.53E-03
    14 Broy./Diag. 0.40E+00    7.3     0.00018566     -4911.5428984109  4.97E-04
    15 Broy./Diag. 0.40E+00    7.3     0.00025530     -4911.5428815641  1.68E-05
    16 Broy./Diag. 0.40E+00    7.6     0.00022046     -4911.5434641522 -5.83E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00030284     -4911.5423712691  1.09E-03
    18 Broy./Diag. 0.40E+00    7.1     0.00015933     -4911.5433944529 -1.02E-03
    19 Broy./Diag. 0.40E+00    7.2     0.00016745     -4911.5431171648  2.77E-04
    20 Broy./Diag. 0.40E+00    7.3     0.00008052     -4911.5433682185 -2.51E-04
    21 Broy./Diag. 0.40E+00    7.1     0.00009035     -4911.5432697455  9.85E-05
    22 Broy./Diag. 0.40E+00    7.6     0.00008858     -4911.5432275934  4.22E-05
    23 Broy./Diag. 0.40E+00    7.9     0.00011526     -4911.5436842635 -4.57E-04
    24 Broy./Diag. 0.40E+00    7.3     0.00006945     -4911.5432933850  3.91E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00006771     -4911.5434065110 -1.13E-04
    26 Broy./Diag. 0.40E+00    7.7     0.00005443     -4911.5433026165  1.04E-04
    27 Broy./Diag. 0.40E+00    7.3     0.00004599     -4911.5434853827 -1.83E-04
    28 Broy./Diag. 0.40E+00    7.1     0.00005370     -4911.5434904839 -5.10E-06
    29 Broy./Diag. 0.40E+00    7.1     0.00006388     -4911.5432725846  2.18E-04
    30 Broy./Diag. 0.40E+00    7.1     0.00004504     -4911.5435269656 -2.54E-04
    31 Broy./Diag. 0.40E+00    8.4     0.00003519     -4911.5434924833  3.45E-05
    32 Broy./Diag. 0.40E+00    7.5     0.00003514     -4911.5435740822 -8.16E-05
    33 Broy./Diag. 0.40E+00    7.6     0.00002129     -4911.5434646001  1.09E-04
    34 Broy./Diag. 0.40E+00    7.3     0.00002620     -4911.5434767426 -1.21E-05
    35 Broy./Diag. 0.40E+00    7.0     0.00003585     -4911.5436052534 -1.29E-04
    36 Broy./Diag. 0.40E+00    7.3     0.00003284     -4911.5434618352  1.43E-04
    37 Broy./Diag. 0.40E+00    7.1     0.00001687     -4911.5435062269 -4.44E-05
    38 Broy./Diag. 0.40E+00    7.1     0.00002354     -4911.5434919182  1.43E-05
    39 Broy./Diag. 0.40E+00    6.7     0.00001165     -4911.5435755824 -8.37E-05
    40 Broy./Diag. 0.40E+00    7.1     0.00001523     -4911.5435770371 -1.45E-06
    41 Broy./Diag. 0.40E+00    7.3     0.00001649     -4911.5435047244  7.23E-05
    42 Broy./Diag. 0.40E+00    6.8     0.00001713     -4911.5435823423 -7.76E-05
    43 Broy./Diag. 0.40E+00    7.1     0.00000876     -4911.5435628842  1.95E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00001270     -4911.5435813365 -1.85E-05
    45 Broy./Diag. 0.40E+00    7.3     0.00000620     -4911.5435365448  4.48E-05
    46 Broy./Diag. 0.40E+00    6.6     0.00000862     -4911.5435509207 -1.44E-05
    47 Broy./Diag. 0.40E+00    7.0     0.00000987     -4911.5436016020 -5.07E-05
    48 Broy./Diag. 0.40E+00    8.2     0.00001133     -4911.5435564859  4.51E-05
    49 Broy./Diag. 0.40E+00    7.3     0.00000566     -4911.5435739142 -1.74E-05
    50 Broy./Diag. 0.40E+00    7.1     0.00000671     -4911.5435667327  7.18E-06
    51 Broy./Diag. 0.40E+00    7.5     0.00000396     -4911.5435934734 -2.67E-05
    52 Broy./Diag. 0.40E+00    7.5     0.00000465     -4911.5435869572  6.52E-06
    53 Broy./Diag. 0.40E+00    6.9     0.00000474     -4911.5435583592  2.86E-05
    54 Broy./Diag. 0.40E+00    6.9     0.00000643     -4911.5435906648 -3.23E-05
    55 Broy./Diag. 0.40E+00    7.1     0.00000372     -4911.5435829521  7.71E-06
    56 Broy./Diag. 0.40E+00    7.1     0.00000423     -4911.5435905624 -7.61E-06
    57 Broy./Diag. 0.40E+00    7.7     0.00000287     -4911.5435768275  1.37E-05
    58 Broy./Diag. 0.40E+00    7.1     0.00000227     -4911.5435831412 -6.31E-06
    59 Broy./Diag. 0.40E+00    7.1     0.00000255     -4911.5435998765 -1.67E-05
    60 Broy./Diag. 0.40E+00    6.9     0.00000338     -4911.5435829212  1.70E-05
    61 Broy./Diag. 0.40E+00    7.1     0.00000198     -4911.5435893321 -6.41E-06
    62 Broy./Diag. 0.40E+00    7.2     0.00000226     -4911.5435861622  3.17E-06
    63 Broy./Diag. 0.40E+00    6.9     0.00000185     -4911.5435957235 -9.56E-06
    64 Broy./Diag. 0.40E+00    7.3     0.00000158     -4911.5435920661  3.66E-06
    65 Broy./Diag. 0.40E+00    6.9     0.00000159     -4911.5435827433  9.32E-06
    66 Broy./Diag. 0.40E+00    7.1     0.00000212     -4911.5435961599 -1.34E-05
    67 Broy./Diag. 0.40E+00    7.3     0.00000129     -4911.5435926639  3.50E-06
    68 Broy./Diag. 0.40E+00    7.5     0.00000125     -4911.5435951537 -2.49E-06
    69 Broy./Diag. 0.40E+00    7.3     0.00000111     -4911.5435907505  4.40E-06
    70 Broy./Diag. 0.40E+00    7.2     0.00000089     -4911.5435933833 -2.63E-06

  *** SCF run converged in    70 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008250539822
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.51801907927802
  Hartree energy:                                            1781.63557620027268
  Exchange-correlation energy:                               -779.36311736703465
  Electronic entropic energy:                                  -0.24373130751141
  Fermi energy:                                                 0.08678974682129

  Total energy:                                             -4911.54359338330778

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.543597638864412

 MD| ***************************************************************************
 MD| Step number                                                            1198
 MD| Time [fs]                                                       2396.000000
 MD| Conserved quantity [hartree]                            -0.491120071030E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    514.888544           593.306878
 MD| Energy drift per atom [K]           0.246761990312E+03   0.269723006428E+03
 MD| Potential energy [hartree]         -0.491154359764E+04  -0.491156366707E+04
 MD| Kinetic energy [hartree]            0.342887334622E+00   0.374004193472E+00
 MD| Temperature [K]                             913.714155           996.633270
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.01998939     -4911.5425410719 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.5     0.08741176     -4911.5173432514  2.52E-02
     3 Broy./Diag. 0.40E+00    7.3     0.09946412     -4911.4100522574  1.07E-01
     4 Broy./Diag. 0.40E+00    7.0     0.04181708     -4911.6192216785 -2.09E-01
     5 Broy./Diag. 0.40E+00    7.7     0.01690362     -4911.4816158563  1.38E-01
     6 Broy./Diag. 0.40E+00    7.5     0.00645450     -4911.5621194744 -8.05E-02
     7 Broy./Diag. 0.40E+00    8.0     0.00337509     -4911.5442088980  1.79E-02
     8 Broy./Diag. 0.40E+00    7.3     0.00252658     -4911.5367751186  7.43E-03
     9 Broy./Diag. 0.40E+00    9.5     0.00122282     -4911.5456103650 -8.84E-03
    10 Broy./Diag. 0.40E+00    7.7     0.00150263     -4911.5380247767  7.59E-03
    11 Broy./Diag. 0.40E+00    7.5     0.00099238     -4911.5441191734 -6.09E-03
    12 Broy./Diag. 0.40E+00   10.7     0.00060132     -4911.5419101980  2.21E-03
    13 Broy./Diag. 0.40E+00    7.7     0.00031644     -4911.5440969678 -2.19E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00025640     -4911.5433290597  7.68E-04
    15 Broy./Diag. 0.40E+00    7.3     0.00022560     -4911.5426744709  6.55E-04
    16 Broy./Diag. 0.40E+00    7.1     0.00028114     -4911.5439715541 -1.30E-03
    17 Broy./Diag. 0.40E+00    7.7     0.00034983     -4911.5426585034  1.31E-03
    18 Broy./Diag. 0.40E+00    7.9     0.00015630     -4911.5437327723 -1.07E-03
    19 Broy./Diag. 0.40E+00    7.5     0.00017198     -4911.5433731170  3.60E-04
    20 Broy./Diag. 0.40E+00   10.0     0.00008640     -4911.5439130836 -5.40E-04
    21 Broy./Diag. 0.40E+00    7.6     0.00008916     -4911.5440169125 -1.04E-04
    22 Broy./Diag. 0.40E+00   10.3     0.00006440     -4911.5435841814  4.33E-04
    23 Broy./Diag. 0.40E+00    8.1     0.00010394     -4911.5440809540 -4.97E-04
    24 Broy./Diag. 0.40E+00    7.3     0.00005891     -4911.5437979955  2.83E-04
    25 Broy./Diag. 0.40E+00    7.5     0.00007242     -4911.5439643733 -1.66E-04
    26 Broy./Diag. 0.40E+00    8.8     0.00005206     -4911.5437341384  2.30E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00004827     -4911.5439152509 -1.81E-04
    28 Broy./Diag. 0.40E+00    9.8     0.00004323     -4911.5441369659 -2.22E-04
    29 Broy./Diag. 0.40E+00    7.8     0.00006721     -4911.5438345569  3.02E-04
    30 Broy./Diag. 0.40E+00    7.7     0.00003739     -4911.5440457217 -2.11E-04
    31 Broy./Diag. 0.40E+00   11.1     0.00002759     -4911.5439968156  4.89E-05
    32 Broy./Diag. 0.40E+00    7.5     0.00002588     -4911.5441153583 -1.19E-04
    33 Broy./Diag. 0.40E+00    7.2     0.00002259     -4911.5440411524  7.42E-05
    34 Broy./Diag. 0.40E+00    7.3     0.00002158     -4911.5439543736  8.68E-05
    35 Broy./Diag. 0.40E+00    7.2     0.00003915     -4911.5441517875 -1.97E-04
    36 Broy./Diag. 0.40E+00    7.1     0.00003333     -4911.5440282269  1.24E-04
    37 Broy./Diag. 0.40E+00    7.3     0.00001653     -4911.5440880563 -5.98E-05
    38 Broy./Diag. 0.40E+00    7.3     0.00002077     -4911.5440366829  5.14E-05
    39 Broy./Diag. 0.40E+00    7.7     0.00001018     -4911.5441038434 -6.72E-05
    40 Broy./Diag. 0.40E+00    7.6     0.00000877     -4911.5441429574 -3.91E-05
    41 Broy./Diag. 0.40E+00    6.9     0.00001486     -4911.5440653384  7.76E-05
    42 Broy./Diag. 0.40E+00    6.9     0.00001507     -4911.5441290564 -6.37E-05
    43 Broy./Diag. 0.40E+00    7.3     0.00000609     -4911.5441110978  1.80E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00001331     -4911.5441449059 -3.38E-05
    45 Broy./Diag. 0.40E+00    7.5     0.00000871     -4911.5441017538  4.32E-05
    46 Broy./Diag. 0.40E+00    6.9     0.00000637     -4911.5440966207  5.13E-06
    47 Broy./Diag. 0.40E+00    7.1     0.00000951     -4911.5441591118 -6.25E-05
    48 Broy./Diag. 0.40E+00    7.5     0.00000946     -4911.5441220504  3.71E-05
    49 Broy./Diag. 0.40E+00    7.0     0.00000340     -4911.5441378637 -1.58E-05
    50 Broy./Diag. 0.40E+00    7.1     0.00000545     -4911.5441296587  8.21E-06
    51 Broy./Diag. 0.40E+00    6.9     0.00000460     -4911.5441506681 -2.10E-05
    52 Broy./Diag. 0.40E+00    7.3     0.00000428     -4911.5441500478  6.20E-07
    53 Broy./Diag. 0.40E+00    6.9     0.00000577     -4911.5441161461  3.39E-05
    54 Broy./Diag. 0.40E+00    7.6     0.00000686     -4911.5441548056 -3.87E-05
    55 Broy./Diag. 0.40E+00    7.3     0.00000336     -4911.5441457119  9.09E-06
    56 Broy./Diag. 0.40E+00    7.5     0.00000377     -4911.5441548647 -9.15E-06
    57 Broy./Diag. 0.40E+00    7.1     0.00000320     -4911.5441434318  1.14E-05
    58 Broy./Diag. 0.40E+00    7.3     0.00000147     -4911.5441468316 -3.40E-06
    59 Broy./Diag. 0.40E+00    7.3     0.00000234     -4911.5441601592 -1.33E-05
    60 Broy./Diag. 0.40E+00    7.1     0.00000321     -4911.5441459733  1.42E-05
    61 Broy./Diag. 0.40E+00    7.1     0.00000205     -4911.5441529197 -6.95E-06
    62 Broy./Diag. 0.40E+00    7.7     0.00000218     -4911.5441501492  2.77E-06
    63 Broy./Diag. 0.40E+00    7.3     0.00000254     -4911.5441605532 -1.04E-05
    64 Broy./Diag. 0.40E+00    7.1     0.00000132     -4911.5441571952  3.36E-06
    65 Broy./Diag. 0.40E+00    6.9     0.00000148     -4911.5441480723  9.12E-06
    66 Broy./Diag. 0.40E+00    7.1     0.00000175     -4911.5441603041 -1.22E-05
    67 Broy./Diag. 0.40E+00    7.1     0.00000106     -4911.5441574701  2.83E-06
    68 Broy./Diag. 0.40E+00    7.1     0.00000091     -4911.5441593512 -1.88E-06

  *** SCF run converged in    68 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008247095288
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.49305543131959
  Hartree energy:                                            1781.65112677955563
  Exchange-correlation energy:                               -779.35432585442072
  Electronic entropic energy:                                  -0.24367564462680
  Fermi energy:                                                 0.08673654506076

  Total energy:                                             -4911.54415935118141

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.544163579296765

 MD| ***************************************************************************
 MD| Step number                                                            1199
 MD| Time [fs]                                                       2398.000000
 MD| Conserved quantity [hartree]                            -0.491120568374E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    524.996692           593.249905
 MD| Energy drift per atom [K]           0.236429858108E+03   0.269695238998E+03
 MD| Potential energy [hartree]         -0.491154416358E+04  -0.491156365080E+04
 MD| Kinetic energy [hartree]            0.338479841927E+00   0.373974565155E+00
 MD| Temperature [K]                             901.969223           996.554318
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.02923859     -4911.5434177344 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.9     0.13571820     -4911.5390604301  4.36E-03
     3 Broy./Diag. 0.40E+00    7.1     0.12658850     -4911.3102866231  2.29E-01
     4 Broy./Diag. 0.40E+00    6.7     0.02865787     -4911.6103239638 -3.00E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01523505     -4911.4889575773  1.21E-01
     6 Broy./Diag. 0.40E+00    7.5     0.00806468     -4911.5701666722 -8.12E-02
     7 Broy./Diag. 0.40E+00    7.4     0.00330149     -4911.5422216497  2.79E-02
     8 Broy./Diag. 0.40E+00    7.3     0.00203140     -4911.5432544695 -1.03E-03
     9 Broy./Diag. 0.40E+00    7.1     0.00104653     -4911.5471107296 -3.86E-03
    10 Broy./Diag. 0.40E+00    6.9     0.00149930     -4911.5380001860  9.11E-03
    11 Broy./Diag. 0.40E+00    7.3     0.00099928     -4911.5459224868 -7.92E-03
    12 Broy./Diag. 0.40E+00    7.3     0.00063219     -4911.5427500072  3.17E-03
    13 Broy./Diag. 0.40E+00    7.1     0.00033681     -4911.5452274075 -2.48E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00019818     -4911.5443808438  8.47E-04
    15 Broy./Diag. 0.40E+00    7.5     0.00015055     -4911.5441108480  2.70E-04
    16 Broy./Diag. 0.40E+00    7.3     0.00025262     -4911.5451329411 -1.02E-03
    17 Broy./Diag. 0.40E+00    7.1     0.00031185     -4911.5436116000  1.52E-03
    18 Broy./Diag. 0.40E+00    7.1     0.00019397     -4911.5447815002 -1.17E-03
    19 Broy./Diag. 0.40E+00    7.7     0.00017780     -4911.5442671833  5.14E-04
    20 Broy./Diag. 0.40E+00    7.5     0.00007567     -4911.5449094385 -6.42E-04
    21 Broy./Diag. 0.40E+00    6.9     0.00006990     -4911.5449393652 -2.99E-05
    22 Broy./Diag. 0.40E+00    7.3     0.00006129     -4911.5445996683  3.40E-04
    23 Broy./Diag. 0.40E+00    7.0     0.00009244     -4911.5451075569 -5.08E-04
    24 Broy./Diag. 0.40E+00    6.9     0.00004354     -4911.5447769828  3.31E-04
    25 Broy./Diag. 0.40E+00    7.0     0.00007743     -4911.5449663859 -1.89E-04
    26 Broy./Diag. 0.40E+00    6.9     0.00005323     -4911.5447147731  2.52E-04
    27 Broy./Diag. 0.40E+00    7.0     0.00004252     -4911.5449206414 -2.06E-04
    28 Broy./Diag. 0.40E+00    6.9     0.00004455     -4911.5451058985 -1.85E-04
    29 Broy./Diag. 0.40E+00    7.4     0.00007368     -4911.5447360549  3.70E-04
    30 Broy./Diag. 0.40E+00    7.1     0.00002954     -4911.5450401117 -3.04E-04
    31 Broy./Diag. 0.40E+00    7.1     0.00003001     -4911.5449775583  6.26E-05
    32 Broy./Diag. 0.40E+00    7.3     0.00002188     -4911.5450830811 -1.06E-04
    33 Broy./Diag. 0.40E+00    6.9     0.00001891     -4911.5450211158  6.20E-05
    34 Broy./Diag. 0.40E+00    7.3     0.00001680     -4911.5449494811  7.16E-05
    35 Broy./Diag. 0.40E+00    7.1     0.00003945     -4911.5451437323 -1.94E-04
    36 Broy./Diag. 0.40E+00    7.1     0.00002855     -4911.5449807488  1.63E-04
    37 Broy./Diag. 0.40E+00    7.0     0.00002197     -4911.5450557263 -7.50E-05
    38 Broy./Diag. 0.40E+00    6.9     0.00001891     -4911.5450107002  4.50E-05
    39 Broy./Diag. 0.40E+00    7.2     0.00000902     -4911.5450798079 -6.91E-05
    40 Broy./Diag. 0.40E+00    6.9     0.00000647     -4911.5451091097 -2.93E-05
    41 Broy./Diag. 0.40E+00    6.9     0.00001234     -4911.5450448222  6.43E-05
    42 Broy./Diag. 0.40E+00    7.3     0.00001080     -4911.5451089754 -6.42E-05
    43 Broy./Diag. 0.40E+00    6.9     0.00000700     -4911.5450881772  2.08E-05
    44 Broy./Diag. 0.40E+00    7.3     0.00001125     -4911.5451108260 -2.26E-05
    45 Broy./Diag. 0.40E+00    7.3     0.00000735     -4911.5450731894  3.76E-05
    46 Broy./Diag. 0.40E+00    8.1     0.00000680     -4911.5450769307 -3.74E-06
    47 Broy./Diag. 0.40E+00    6.8     0.00000984     -4911.5451326529 -5.57E-05
    48 Broy./Diag. 0.40E+00    6.9     0.00000838     -4911.5450865429  4.61E-05
    49 Broy./Diag. 0.40E+00    6.9     0.00000361     -4911.5451071775 -2.06E-05
    50 Broy./Diag. 0.40E+00    7.3     0.00000377     -4911.5451059134  1.26E-06
    51 Broy./Diag. 0.40E+00    6.7     0.00000300     -4911.5451192278 -1.33E-05
    52 Broy./Diag. 0.40E+00    7.1     0.00000368     -4911.5451166330  2.59E-06
    53 Broy./Diag. 0.40E+00    6.7     0.00000516     -4911.5450917519  2.49E-05
    54 Broy./Diag. 0.40E+00    7.7     0.00000570     -4911.5451305105 -3.88E-05
    55 Broy./Diag. 0.40E+00    7.5     0.00000321     -4911.5451181885  1.23E-05
    56 Broy./Diag. 0.40E+00    6.9     0.00000313     -4911.5451206489 -2.46E-06
    57 Broy./Diag. 0.40E+00    7.5     0.00000236     -4911.5451132621  7.39E-06
    58 Broy./Diag. 0.40E+00    7.3     0.00000131     -4911.5451191614 -5.90E-06
    59 Broy./Diag. 0.40E+00    7.3     0.00000193     -4911.5451273258 -8.16E-06
    60 Broy./Diag. 0.40E+00    7.1     0.00000230     -4911.5451153547  1.20E-05
    61 Broy./Diag. 0.40E+00    7.1     0.00000126     -4911.5451225315 -7.18E-06
    62 Broy./Diag. 0.40E+00    7.3     0.00000143     -4911.5451236823 -1.15E-06
    63 Broy./Diag. 0.40E+00    7.0     0.00000186     -4911.5451285465 -4.86E-06
    64 Broy./Diag. 0.40E+00    6.7     0.00000135     -4911.5451238347  4.71E-06
    65 Broy./Diag. 0.40E+00    7.1     0.00000145     -4911.5451189240  4.91E-06
    66 Broy./Diag. 0.40E+00    7.3     0.00000151     -4911.5451304543 -1.15E-05
    67 Broy./Diag. 0.40E+00    7.4     0.00000066     -4911.5451265976  3.86E-06

  *** SCF run converged in    67 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008243496096
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.46625263398164
  Hartree energy:                                            1781.66822108269616
  Exchange-correlation energy:                               -779.34566394136118
  Electronic entropic energy:                                  -0.24359630445423
  Fermi energy:                                                 0.08667857891995

  Total energy:                                             -4911.54512659756710

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.545131325096918

 MD| ***************************************************************************
 MD| Step number                                                            1200
 MD| Time [fs]                                                       2400.000000
 MD| Conserved quantity [hartree]                            -0.491120756867E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    486.906732           593.161286
 MD| Energy drift per atom [K]           0.232513967948E+03   0.269664254605E+03
 MD| Potential energy [hartree]         -0.491154513133E+04  -0.491156363537E+04
 MD| Kinetic energy [hartree]            0.337562650768E+00   0.373944221893E+00
 MD| Temperature [K]                             899.525124           996.473460
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.03394588     -4911.5438110296 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.15098730     -4911.5243301111  1.95E-02
     3 Broy./Diag. 0.40E+00    7.7     0.13225070     -4911.3856639338  1.39E-01
     4 Broy./Diag. 0.40E+00    7.5     0.03041628     -4911.6134152075 -2.28E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01854435     -4911.4605780433  1.53E-01
     6 Broy./Diag. 0.40E+00    7.1     0.00561972     -4911.5655924253 -1.05E-01
     7 Broy./Diag. 0.40E+00    7.1     0.00312733     -4911.5476570166  1.79E-02
     8 Broy./Diag. 0.40E+00    7.1     0.00240069     -4911.5408071700  6.85E-03
     9 Broy./Diag. 0.40E+00    7.1     0.00136740     -4911.5484553065 -7.65E-03
    10 Broy./Diag. 0.40E+00    7.3     0.00237351     -4911.5412665540  7.19E-03
    11 Broy./Diag. 0.40E+00    7.5     0.00117212     -4911.5484843578 -7.22E-03
    12 Broy./Diag. 0.40E+00    6.9     0.00069217     -4911.5418442523  6.64E-03
    13 Broy./Diag. 0.40E+00    7.3     0.00024548     -4911.5456605784 -3.82E-03
    14 Broy./Diag. 0.40E+00    6.8     0.00021612     -4911.5455923231  6.83E-05
    15 Broy./Diag. 0.40E+00    7.1     0.00016912     -4911.5448834918  7.09E-04
    16 Broy./Diag. 0.40E+00    7.0     0.00028803     -4911.5457576856 -8.74E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00021439     -4911.5446948803  1.06E-03
    18 Broy./Diag. 0.40E+00    7.7     0.00017408     -4911.5455813031 -8.86E-04
    19 Broy./Diag. 0.40E+00    7.3     0.00011026     -4911.5447744251  8.07E-04
    20 Broy./Diag. 0.40E+00    7.1     0.00008041     -4911.5452046993 -4.30E-04
    21 Broy./Diag. 0.40E+00    7.5     0.00007346     -4911.5454329300 -2.28E-04
    22 Broy./Diag. 0.40E+00    7.5     0.00009008     -4911.5451467744  2.86E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00008561     -4911.5455445101 -3.98E-04
    24 Broy./Diag. 0.40E+00    7.5     0.00005099     -4911.5452240416  3.20E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00004124     -4911.5454678691 -2.44E-04
    26 Broy./Diag. 0.40E+00    7.3     0.00005426     -4911.5453020441  1.66E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00004528     -4911.5452560498  4.60E-05
    28 Broy./Diag. 0.40E+00    6.8     0.00005298     -4911.5454653481 -2.09E-04
    29 Broy./Diag. 0.40E+00    7.3     0.00005758     -4911.5452084735  2.57E-04
    30 Broy./Diag. 0.40E+00    7.1     0.00002329     -4911.5454237675 -2.15E-04
    31 Broy./Diag. 0.40E+00    7.1     0.00001747     -4911.5453427879  8.10E-05
    32 Broy./Diag. 0.40E+00    6.9     0.00002329     -4911.5454246316 -8.18E-05
    33 Broy./Diag. 0.40E+00    6.9     0.00001891     -4911.5454226021  2.03E-06
    34 Broy./Diag. 0.40E+00    7.1     0.00001807     -4911.5453437000  7.89E-05
    35 Broy./Diag. 0.40E+00    6.9     0.00003109     -4911.5454821879 -1.38E-04
    36 Broy./Diag. 0.40E+00    7.0     0.00001442     -4911.5453700292  1.12E-04
    37 Broy./Diag. 0.40E+00    7.0     0.00001256     -4911.5454336911 -6.37E-05
    38 Broy./Diag. 0.40E+00    7.2     0.00001670     -4911.5453796230  5.41E-05
    39 Broy./Diag. 0.40E+00    7.2     0.00000957     -4911.5454112737 -3.17E-05
    40 Broy./Diag. 0.40E+00    6.9     0.00000774     -4911.5454571519 -4.59E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00001278     -4911.5453957206  6.14E-05
    42 Broy./Diag. 0.40E+00    7.2     0.00000683     -4911.5454459964 -5.03E-05
    43 Broy./Diag. 0.40E+00    7.3     0.00000594     -4911.5454240379  2.20E-05
    44 Broy./Diag. 0.40E+00    7.4     0.00000985     -4911.5454552843 -3.12E-05
    45 Broy./Diag. 0.40E+00    7.1     0.00000736     -4911.5454364268  1.89E-05
    46 Broy./Diag. 0.40E+00    6.9     0.00000558     -4911.5454069939  2.94E-05
    47 Broy./Diag. 0.40E+00    7.0     0.00000846     -4911.5454593416 -5.23E-05
    48 Broy./Diag. 0.40E+00    7.2     0.00000539     -4911.5454285770  3.08E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00000316     -4911.5454468965 -1.83E-05
    50 Broy./Diag. 0.40E+00    7.0     0.00000441     -4911.5454341795  1.27E-05
    51 Broy./Diag. 0.40E+00    7.3     0.00000313     -4911.5454456459 -1.15E-05
    52 Broy./Diag. 0.40E+00    6.8     0.00000314     -4911.5454573767 -1.17E-05
    53 Broy./Diag. 0.40E+00    7.4     0.00000469     -4911.5454292161  2.82E-05
    54 Broy./Diag. 0.40E+00    6.9     0.00000367     -4911.5454518898 -2.27E-05
    55 Broy./Diag. 0.40E+00    7.0     0.00000234     -4911.5454425022  9.39E-06
    56 Broy./Diag. 0.40E+00    7.1     0.00000319     -4911.5454539987 -1.15E-05
    57 Broy./Diag. 0.40E+00    7.1     0.00000202     -4911.5454470709  6.93E-06
    58 Broy./Diag. 0.40E+00    7.3     0.00000157     -4911.5454423776  4.69E-06
    59 Broy./Diag. 0.40E+00    7.3     0.00000237     -4911.5454569973 -1.46E-05
    60 Broy./Diag. 0.40E+00    7.1     0.00000208     -4911.5454463261  1.07E-05
    61 Broy./Diag. 0.40E+00    7.9     0.00000128     -4911.5454524507 -6.12E-06
    62 Broy./Diag. 0.40E+00    7.5     0.00000164     -4911.5454476677  4.78E-06
    63 Broy./Diag. 0.40E+00    7.1     0.00000117     -4911.5454527660 -5.10E-06
    64 Broy./Diag. 0.40E+00    6.9     0.00000122     -4911.5454557923 -3.03E-06
    65 Broy./Diag. 0.40E+00    7.1     0.00000149     -4911.5454454799  1.03E-05
    66 Broy./Diag. 0.40E+00    7.3     0.00000133     -4911.5454546210 -9.14E-06
    67 Broy./Diag. 0.40E+00    7.3     0.00000078     -4911.5454515832  3.04E-06

  *** SCF run converged in    67 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008242666784
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.44601507367952
  Hartree energy:                                            1781.68167735241559
  Exchange-correlation energy:                               -779.33933999173007
  Electronic entropic energy:                                  -0.24346395832491
  Fermi energy:                                                 0.08663054754998

  Total energy:                                             -4911.54545158324618

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.545456057842785

 MD| ***************************************************************************
 MD| Step number                                                            1201
 MD| Time [fs]                                                       2402.000000
 MD| Conserved quantity [hartree]                            -0.491120734036E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    488.994914           593.074553
 MD| Energy drift per atom [K]           0.232988278490E+03   0.269633716740E+03
 MD| Potential energy [hartree]         -0.491154545606E+04  -0.491156362023E+04
 MD| Kinetic energy [hartree]            0.338115695707E+00   0.373914389648E+00
 MD| Temperature [K]                             900.998859           996.393964
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.03523019     -4911.5435426815 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.7     0.15457078     -4911.5493494792 -5.81E-03
     3 Broy./Diag. 0.40E+00    7.2     0.13071849     -4911.3628744695  1.86E-01
     4 Broy./Diag. 0.40E+00    7.5     0.03230177     -4911.6003394519 -2.37E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01992889     -4911.4748068135  1.26E-01
     6 Broy./Diag. 0.40E+00    7.3     0.00577176     -4911.5634038237 -8.86E-02
     7 Broy./Diag. 0.40E+00    6.5     0.00354971     -4911.5415387365  2.19E-02
     8 Broy./Diag. 0.40E+00    7.2     0.00192861     -4911.5461996468 -4.66E-03
     9 Broy./Diag. 0.40E+00    7.7     0.00167560     -4911.5499464300 -3.75E-03
    10 Broy./Diag. 0.40E+00    7.3     0.00224456     -4911.5403799930  9.57E-03
    11 Broy./Diag. 0.40E+00    7.1     0.00117506     -4911.5462443795 -5.86E-03
    12 Broy./Diag. 0.40E+00    7.0     0.00065313     -4911.5423831628  3.86E-03
    13 Broy./Diag. 0.40E+00    7.2     0.00029274     -4911.5460943212 -3.71E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00018810     -4911.5452011409  8.93E-04
    15 Broy./Diag. 0.40E+00    7.1     0.00014743     -4911.5448496754  3.51E-04
    16 Broy./Diag. 0.40E+00    7.1     0.00025809     -4911.5457428383 -8.93E-04
    17 Broy./Diag. 0.40E+00    6.4     0.00017707     -4911.5448254426  9.17E-04
    18 Broy./Diag. 0.40E+00    8.5     0.00016059     -4911.5453391167 -5.14E-04
    19 Broy./Diag. 0.40E+00    7.3     0.00012806     -4911.5445401142  7.99E-04
    20 Broy./Diag. 0.40E+00    7.6     0.00007465     -4911.5450899941 -5.50E-04
    21 Broy./Diag. 0.40E+00    7.3     0.00005492     -4911.5452471275 -1.57E-04
    22 Broy./Diag. 0.40E+00    7.5     0.00008279     -4911.5449361814  3.11E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00007068     -4911.5452405680 -3.04E-04
    24 Broy./Diag. 0.40E+00    7.1     0.00004605     -4911.5450252609  2.15E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00005017     -4911.5452482821 -2.23E-04
    26 Broy./Diag. 0.40E+00    6.9     0.00004122     -4911.5450346597  2.14E-04
    27 Broy./Diag. 0.40E+00    6.9     0.00003649     -4911.5449661784  6.85E-05
    28 Broy./Diag. 0.40E+00    7.7     0.00005003     -4911.5451652350 -1.99E-04
    29 Broy./Diag. 0.40E+00    6.9     0.00005177     -4911.5449811902  1.84E-04
    30 Broy./Diag. 0.40E+00    6.9     0.00002216     -4911.5451444082 -1.63E-04
    31 Broy./Diag. 0.40E+00    7.3     0.00002033     -4911.5450324646  1.12E-04
    32 Broy./Diag. 0.40E+00    6.9     0.00001370     -4911.5451216183 -8.92E-05
    33 Broy./Diag. 0.40E+00    6.9     0.00001612     -4911.5451324352 -1.08E-05
    34 Broy./Diag. 0.40E+00    7.3     0.00001683     -4911.5450447189  8.77E-05
    35 Broy./Diag. 0.40E+00    7.1     0.00002702     -4911.5451306104 -8.59E-05
    36 Broy./Diag. 0.40E+00    6.9     0.00001317     -4911.5450529202  7.77E-05
    37 Broy./Diag. 0.40E+00    7.1     0.00001363     -4911.5451326963 -7.98E-05
    38 Broy./Diag. 0.40E+00    6.7     0.00001082     -4911.5450716806  6.10E-05
    39 Broy./Diag. 0.40E+00    7.2     0.00000888     -4911.5450715878  9.28E-08
    40 Broy./Diag. 0.40E+00    7.7     0.00000661     -4911.5451221490 -5.06E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00001159     -4911.5450818957  4.03E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00000581     -4911.5451147115 -3.28E-05
    43 Broy./Diag. 0.40E+00    6.9     0.00000534     -4911.5450792092  3.55E-05
    44 Broy./Diag. 0.40E+00    7.5     0.00000631     -4911.5451103541 -3.11E-05
    45 Broy./Diag. 0.40E+00    7.1     0.00000667     -4911.5451092933  1.06E-06
    46 Broy./Diag. 0.40E+00    7.2     0.00000475     -4911.5450731241  3.62E-05
    47 Broy./Diag. 0.40E+00    7.7     0.00000768     -4911.5451067497 -3.36E-05
    48 Broy./Diag. 0.40E+00    7.5     0.00000473     -4911.5450854946  2.13E-05
    49 Broy./Diag. 0.40E+00    7.8     0.00000271     -4911.5451099224 -2.44E-05
    50 Broy./Diag. 0.40E+00    7.3     0.00000290     -4911.5450936236  1.63E-05
    51 Broy./Diag. 0.40E+00    9.3     0.00000270     -4911.5450946891 -1.07E-06
    52 Broy./Diag. 0.40E+00    7.2     0.00000256     -4911.5451081802 -1.35E-05
    53 Broy./Diag. 0.40E+00   10.1     0.00000426     -4911.5450907701  1.74E-05
    54 Broy./Diag. 0.40E+00    9.0     0.00000338     -4911.5451040627 -1.33E-05
    55 Broy./Diag. 0.40E+00    7.5     0.00000187     -4911.5450899135  1.41E-05
    56 Broy./Diag. 0.40E+00    7.1     0.00000202     -4911.5451028282 -1.29E-05
    57 Broy./Diag. 0.40E+00    6.9     0.00000182     -4911.5451024574  3.71E-07
    58 Broy./Diag. 0.40E+00    6.9     0.00000124     -4911.5450940294  8.43E-06
    59 Broy./Diag. 0.40E+00    8.5     0.00000199     -4911.5451030030 -8.97E-06
    60 Broy./Diag. 0.40E+00    7.1     0.00000181     -4911.5450966877  6.32E-06
    61 Broy./Diag. 0.40E+00    8.3     0.00000099     -4911.5451031252 -6.44E-06

  *** SCF run converged in    61 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008248405583
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.43013320414775
  Hartree energy:                                            1781.69265259900044
  Exchange-correlation energy:                               -779.33426432913336
  Electronic entropic energy:                                  -0.24328453179119
  Fermi energy:                                                 0.08659152420292

  Total energy:                                             -4911.54510312520051

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.545100069635737

 MD| ***************************************************************************
 MD| Step number                                                            1202
 MD| Time [fs]                                                       2404.000000
 MD| Conserved quantity [hartree]                            -0.491121890576E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    457.668465           592.961902
 MD| Energy drift per atom [K]           0.208961570207E+03   0.269583240745E+03
 MD| Potential energy [hartree]         -0.491154510007E+04  -0.491156360483E+04
 MD| Kinetic energy [hartree]            0.326194308938E+00   0.373874689082E+00
 MD| Temperature [K]                             869.231165           996.288171
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    9.2     0.04121452     -4911.5422845809 -4.91E+03
     2 Broy./Diag. 0.40E+00    8.8     0.16973891     -4911.5545657318 -1.23E-02
     3 Broy./Diag. 0.40E+00    7.3     0.13853931     -4911.3401057831  2.14E-01
     4 Broy./Diag. 0.40E+00    7.3     0.03904321     -4911.5972955481 -2.57E-01
     5 Broy./Diag. 0.40E+00    7.1     0.02445609     -4911.4762853113  1.21E-01
     6 Broy./Diag. 0.40E+00    8.0     0.00590775     -4911.5595725015 -8.33E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00459926     -4911.5365280267  2.30E-02
     8 Broy./Diag. 0.40E+00    9.6     0.00230967     -4911.5467790651 -1.03E-02
     9 Broy./Diag. 0.40E+00    7.1     0.00179563     -4911.5495354862 -2.76E-03
    10 Broy./Diag. 0.40E+00    9.1     0.00232631     -4911.5391321122  1.04E-02
    11 Broy./Diag. 0.40E+00   10.5     0.00152370     -4911.5452569572 -6.12E-03
    12 Broy./Diag. 0.40E+00    7.1     0.00075781     -4911.5413313771  3.93E-03
    13 Broy./Diag. 0.40E+00    7.1     0.00034445     -4911.5449030461 -3.57E-03
    14 Broy./Diag. 0.40E+00    6.9     0.00020894     -4911.5439388696  9.64E-04
    15 Broy./Diag. 0.40E+00    7.1     0.00017171     -4911.5437473580  1.92E-04
    16 Broy./Diag. 0.40E+00    7.5     0.00025871     -4911.5445852593 -8.38E-04
    17 Broy./Diag. 0.40E+00    6.9     0.00018144     -4911.5436646001  9.21E-04
    18 Broy./Diag. 0.40E+00    7.2     0.00018578     -4911.5442257852 -5.61E-04
    19 Broy./Diag. 0.40E+00    7.2     0.00014249     -4911.5434829322  7.43E-04
    20 Broy./Diag. 0.40E+00    7.6     0.00007690     -4911.5439271253 -4.44E-04
    21 Broy./Diag. 0.40E+00    7.3     0.00005225     -4911.5440332762 -1.06E-04
    22 Broy./Diag. 0.40E+00    7.7     0.00008145     -4911.5437972414  2.36E-04
    23 Broy./Diag. 0.40E+00    7.3     0.00006088     -4911.5440771771 -2.80E-04
    24 Broy./Diag. 0.40E+00    7.3     0.00005526     -4911.5438411478  2.36E-04
    25 Broy./Diag. 0.40E+00    7.7     0.00005151     -4911.5440529095 -2.12E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00003960     -4911.5438979615  1.55E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00003355     -4911.5438392790  5.87E-05
    28 Broy./Diag. 0.40E+00    7.3     0.00004529     -4911.5439700660 -1.31E-04
    29 Broy./Diag. 0.40E+00    6.9     0.00004205     -4911.5438156309  1.54E-04
    30 Broy./Diag. 0.40E+00    6.9     0.00002546     -4911.5439749243 -1.59E-04
    31 Broy./Diag. 0.40E+00    7.3     0.00002070     -4911.5438722136  1.03E-04
    32 Broy./Diag. 0.40E+00    7.5     0.00001280     -4911.5439307331 -5.85E-05
    33 Broy./Diag. 0.40E+00    7.5     0.00001448     -4911.5439462574 -1.55E-05
    34 Broy./Diag. 0.40E+00    7.3     0.00001631     -4911.5438876418  5.86E-05
    35 Broy./Diag. 0.40E+00    7.5     0.00002336     -4911.5439555164 -6.79E-05
    36 Broy./Diag. 0.40E+00    7.7     0.00001555     -4911.5438746766  8.08E-05
    37 Broy./Diag. 0.40E+00    6.9     0.00001355     -4911.5439467255 -7.20E-05
    38 Broy./Diag. 0.40E+00    7.5     0.00000797     -4911.5439096652  3.71E-05
    39 Broy./Diag. 0.40E+00    7.0     0.00000744     -4911.5439007027  8.96E-06
    40 Broy./Diag. 0.40E+00    7.1     0.00000574     -4911.5439337000 -3.30E-05
    41 Broy./Diag. 0.40E+00    6.9     0.00001015     -4911.5439046581  2.90E-05
    42 Broy./Diag. 0.40E+00    7.3     0.00000643     -4911.5439382264 -3.36E-05
    43 Broy./Diag. 0.40E+00    7.5     0.00000589     -4911.5439034808  3.47E-05
    44 Broy./Diag. 0.40E+00    7.3     0.00000478     -4911.5439238348 -2.04E-05
    45 Broy./Diag. 0.40E+00    7.3     0.00000531     -4911.5439297393 -5.90E-06
    46 Broy./Diag. 0.40E+00    6.9     0.00000388     -4911.5439062003  2.35E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00000644     -4911.5439261038 -1.99E-05
    48 Broy./Diag. 0.40E+00    6.9     0.00000336     -4911.5439051322  2.10E-05
    49 Broy./Diag. 0.40E+00    7.3     0.00000287     -4911.5439281829 -2.31E-05
    50 Broy./Diag. 0.40E+00    6.9     0.00000244     -4911.5439175212  1.07E-05
    51 Broy./Diag. 0.40E+00    7.3     0.00000229     -4911.5439142694  3.25E-06
    52 Broy./Diag. 0.40E+00    7.5     0.00000212     -4911.5439246381 -1.04E-05
    53 Broy./Diag. 0.40E+00    6.9     0.00000365     -4911.5439142747  1.04E-05
    54 Broy./Diag. 0.40E+00    7.3     0.00000253     -4911.5439263748 -1.21E-05
    55 Broy./Diag. 0.40E+00    7.7     0.00000175     -4911.5439119230  1.45E-05
    56 Broy./Diag. 0.40E+00    7.5     0.00000168     -4911.5439201773 -8.25E-06
    57 Broy./Diag. 0.40E+00    7.1     0.00000144     -4911.5439230167 -2.84E-06
    58 Broy./Diag. 0.40E+00    6.5     0.00000104     -4911.5439166038  6.41E-06
    59 Broy./Diag. 0.40E+00    7.3     0.00000181     -4911.5439216783 -5.07E-06
    60 Broy./Diag. 0.40E+00    7.1     0.00000153     -4911.5439157383  5.94E-06
    61 Broy./Diag. 0.40E+00    7.5     0.00000093     -4911.5439230870 -7.35E-06

  *** SCF run converged in    61 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008264081652
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.41182637664497
  Hartree energy:                                            1781.70551098631677
  Exchange-correlation energy:                               -779.32782348017258
  Electronic entropic energy:                                  -0.24309707433975
  Fermi energy:                                                 0.08654572615042

  Total energy:                                             -4911.54392308695333

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.543919988199377

 MD| ***************************************************************************
 MD| Step number                                                            1203
 MD| Time [fs]                                                       2406.000000
 MD| Conserved quantity [hartree]                            -0.491121620815E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    462.110793           592.853131
 MD| Energy drift per atom [K]           0.214565757250E+03   0.269537507176E+03
 MD| Potential energy [hartree]         -0.491154391999E+04  -0.491156358846E+04
 MD| Kinetic energy [hartree]            0.327711836179E+00   0.373836315970E+00
 MD| Temperature [K]                             873.275018           996.185916
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.03519488     -4911.5408578790 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.14048392     -4911.5079533938  3.29E-02
     3 Broy./Diag. 0.40E+00    7.5     0.12017461     -4911.5139569457 -6.00E-03
     4 Broy./Diag. 0.40E+00    7.1     0.03939838     -4911.6032307027 -8.93E-02
     5 Broy./Diag. 0.40E+00    7.3     0.02518239     -4911.4432751210  1.60E-01
     6 Broy./Diag. 0.40E+00    6.9     0.00713755     -4911.5588396859 -1.16E-01
     7 Broy./Diag. 0.40E+00    7.1     0.00523043     -4911.5401572919  1.87E-02
     8 Broy./Diag. 0.40E+00    6.9     0.00252555     -4911.5436336196 -3.48E-03
     9 Broy./Diag. 0.40E+00    7.1     0.00203740     -4911.5451722774 -1.54E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00243330     -4911.5411403695  4.03E-03
    11 Broy./Diag. 0.40E+00    7.1     0.00186381     -4911.5471226731 -5.98E-03
    12 Broy./Diag. 0.40E+00    7.1     0.00089953     -4911.5393058666  7.82E-03
    13 Broy./Diag. 0.40E+00    7.6     0.00046352     -4911.5433809376 -4.08E-03
    14 Broy./Diag. 0.40E+00    7.4     0.00028719     -4911.5426955959  6.85E-04
    15 Broy./Diag. 0.40E+00    7.3     0.00020817     -4911.5425262796  1.69E-04
    16 Broy./Diag. 0.40E+00    6.8     0.00028589     -4911.5431164860 -5.90E-04
    17 Broy./Diag. 0.40E+00    6.9     0.00022361     -4911.5423272886  7.89E-04
    18 Broy./Diag. 0.40E+00    6.9     0.00021263     -4911.5431613969 -8.34E-04
    19 Broy./Diag. 0.40E+00    7.1     0.00012256     -4911.5422997693  8.62E-04
    20 Broy./Diag. 0.40E+00    7.1     0.00008841     -4911.5425977178 -2.98E-04
    21 Broy./Diag. 0.40E+00    7.1     0.00006251     -4911.5426495737 -5.19E-05
    22 Broy./Diag. 0.40E+00    7.5     0.00008915     -4911.5424313837  2.18E-04
    23 Broy./Diag. 0.40E+00    7.5     0.00006429     -4911.5427039383 -2.73E-04
    24 Broy./Diag. 0.40E+00    7.1     0.00006728     -4911.5424536812  2.50E-04
    25 Broy./Diag. 0.40E+00    7.5     0.00004987     -4911.5426844367 -2.31E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00003745     -4911.5425108536  1.74E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00003392     -4911.5424769294  3.39E-05
    28 Broy./Diag. 0.40E+00    7.9     0.00004404     -4911.5425716908 -9.48E-05
    29 Broy./Diag. 0.40E+00    7.3     0.00003855     -4911.5424290718  1.43E-04
    30 Broy./Diag. 0.40E+00    7.3     0.00002707     -4911.5425523295 -1.23E-04
    31 Broy./Diag. 0.40E+00    7.1     0.00002068     -4911.5424471661  1.05E-04
    32 Broy./Diag. 0.40E+00    7.6     0.00001218     -4911.5425123585 -6.52E-05
    33 Broy./Diag. 0.40E+00    7.1     0.00001415     -4911.5425101786  2.18E-06
    34 Broy./Diag. 0.40E+00    7.3     0.00002093     -4911.5424568869  5.33E-05
    35 Broy./Diag. 0.40E+00    7.1     0.00002497     -4911.5425234694 -6.66E-05
    36 Broy./Diag. 0.40E+00    7.1     0.00001664     -4911.5424437030  7.98E-05
    37 Broy./Diag. 0.40E+00    7.5     0.00001298     -4911.5425058998 -6.22E-05
    38 Broy./Diag. 0.40E+00    7.1     0.00000707     -4911.5424610343  4.49E-05
    39 Broy./Diag. 0.40E+00    7.1     0.00000664     -4911.5424529958  8.04E-06
    40 Broy./Diag. 0.40E+00    8.0     0.00000643     -4911.5424806676 -2.77E-05
    41 Broy./Diag. 0.40E+00    6.9     0.00001140     -4911.5424485976  3.21E-05
    42 Broy./Diag. 0.40E+00    7.3     0.00000723     -4911.5424824904 -3.39E-05
    43 Broy./Diag. 0.40E+00    6.7     0.00000702     -4911.5424441061  3.84E-05
    44 Broy./Diag. 0.40E+00    7.3     0.00000492     -4911.5424666048 -2.25E-05
    45 Broy./Diag. 0.40E+00    7.1     0.00000413     -4911.5424668936 -2.89E-07
    46 Broy./Diag. 0.40E+00    7.1     0.00000326     -4911.5424460929  2.08E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00000602     -4911.5424598850 -1.38E-05
    48 Broy./Diag. 0.40E+00    6.7     0.00000331     -4911.5424419170  1.80E-05
    49 Broy./Diag. 0.40E+00    6.8     0.00000293     -4911.5424605685 -1.87E-05
    50 Broy./Diag. 0.40E+00    7.1     0.00000244     -4911.5424475516  1.30E-05
    51 Broy./Diag. 0.40E+00    7.1     0.00000216     -4911.5424451662  2.39E-06
    52 Broy./Diag. 0.40E+00    7.5     0.00000209     -4911.5424539833 -8.82E-06
    53 Broy./Diag. 0.40E+00    7.5     0.00000388     -4911.5424441894  9.79E-06
    54 Broy./Diag. 0.40E+00    6.7     0.00000269     -4911.5424551403 -1.10E-05
    55 Broy./Diag. 0.40E+00    7.3     0.00000168     -4911.5424405425  1.46E-05
    56 Broy./Diag. 0.40E+00    7.7     0.00000151     -4911.5424469414 -6.40E-06
    57 Broy./Diag. 0.40E+00    7.9     0.00000113     -4911.5424484966 -1.56E-06
    58 Broy./Diag. 0.40E+00    6.9     0.00000106     -4911.5424423261  6.17E-06
    59 Broy./Diag. 0.40E+00    6.7     0.00000182     -4911.5424462416 -3.92E-06
    60 Broy./Diag. 0.40E+00    7.3     0.00000166     -4911.5424402181  6.02E-06
    61 Broy./Diag. 0.40E+00    7.5     0.00000093     -4911.5424480136 -7.80E-06

  *** SCF run converged in    61 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008284128458
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.39193651865025
  Hartree energy:                                            1781.71928831813557
  Exchange-correlation energy:                               -779.32042195896997
  Electronic entropic energy:                                  -0.24291119658306
  Fermi energy:                                                 0.08649583363213

  Total energy:                                             -4911.54244801359437

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.542438931155630

 MD| ***************************************************************************
 MD| Step number                                                            1204
 MD| Time [fs]                                                       2408.000000
 MD| Conserved quantity [hartree]                            -0.491123281233E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    447.764661           592.732626
 MD| Energy drift per atom [K]           0.180071152465E+03   0.269463199572E+03
 MD| Potential energy [hartree]         -0.491154243893E+04  -0.491156357090E+04
 MD| Kinetic energy [hartree]            0.309626596494E+00   0.373782985639E+00
 MD| Temperature [K]                             825.082105           996.043803
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02763770     -4911.5400431808 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.8     0.10388245     -4911.4815745314  5.85E-02
     3 Broy./Diag. 0.40E+00    7.3     0.09123081     -4911.7287858050 -2.47E-01
     4 Broy./Diag. 0.40E+00    7.1     0.02057184     -4911.5302878870  1.98E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01563556     -4911.4903575566  3.99E-02
     6 Broy./Diag. 0.40E+00    7.7     0.00710661     -4911.5691607770 -7.88E-02
     7 Broy./Diag. 0.40E+00    7.5     0.00371128     -4911.5431403797  2.60E-02
     8 Broy./Diag. 0.40E+00    7.1     0.00198519     -4911.5404769124  2.66E-03
     9 Broy./Diag. 0.40E+00    6.9     0.00120470     -4911.5445139820 -4.04E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00084675     -4911.5419432702  2.57E-03
    11 Broy./Diag. 0.40E+00    7.1     0.00074452     -4911.5421028392 -1.60E-04
    12 Broy./Diag. 0.40E+00    7.1     0.00056228     -4911.5413524146  7.50E-04
    13 Broy./Diag. 0.40E+00    7.5     0.00026972     -4911.5435709196 -2.22E-03
    14 Broy./Diag. 0.40E+00    6.7     0.00016234     -4911.5417708351  1.80E-03
    15 Broy./Diag. 0.40E+00    7.1     0.00015969     -4911.5416768038  9.40E-05
    16 Broy./Diag. 0.40E+00    7.3     0.00012603     -4911.5421593482 -4.83E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00018171     -4911.5417877993  3.72E-04
    18 Broy./Diag. 0.40E+00    7.5     0.00016618     -4911.5418306489 -4.28E-05
    19 Broy./Diag. 0.40E+00    7.5     0.00008898     -4911.5414363956  3.94E-04
    20 Broy./Diag. 0.40E+00    7.3     0.00008714     -4911.5420817022 -6.45E-04
    21 Broy./Diag. 0.40E+00    7.1     0.00006602     -4911.5418882567  1.93E-04
    22 Broy./Diag. 0.40E+00    6.9     0.00004445     -4911.5415788699  3.09E-04
    23 Broy./Diag. 0.40E+00    7.5     0.00006052     -4911.5417493798 -1.71E-04
    24 Broy./Diag. 0.40E+00    7.0     0.00007124     -4911.5417026521  4.67E-05
    25 Broy./Diag. 0.40E+00    7.1     0.00004428     -4911.5418268852 -1.24E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00004432     -4911.5414926366  3.34E-04
    27 Broy./Diag. 0.40E+00    7.3     0.00004113     -4911.5415960350 -1.03E-04
    28 Broy./Diag. 0.40E+00    7.3     0.00002963     -4911.5417817485 -1.86E-04
    29 Broy./Diag. 0.40E+00    7.7     0.00003289     -4911.5415976065  1.84E-04
    30 Broy./Diag. 0.40E+00    7.0     0.00003815     -4911.5415851168  1.25E-05
    31 Broy./Diag. 0.40E+00    6.7     0.00002547     -4911.5415253872  5.97E-05
    32 Broy./Diag. 0.40E+00    7.1     0.00002347     -4911.5416878544 -1.62E-04
    33 Broy./Diag. 0.40E+00    7.1     0.00001769     -4911.5415880353  9.98E-05
    34 Broy./Diag. 0.40E+00    7.5     0.00001527     -4911.5415000838  8.80E-05
    35 Broy./Diag. 0.40E+00    6.7     0.00001619     -4911.5415744710 -7.44E-05
    36 Broy./Diag. 0.40E+00    7.2     0.00002395     -4911.5415679331  6.54E-06
    37 Broy./Diag. 0.40E+00    7.1     0.00001660     -4911.5415962622 -2.83E-05
    38 Broy./Diag. 0.40E+00    7.1     0.00001507     -4911.5414895482  1.07E-04
    39 Broy./Diag. 0.40E+00    7.0     0.00001124     -4911.5415409359 -5.14E-05
    40 Broy./Diag. 0.40E+00    6.9     0.00000945     -4911.5415842919 -4.34E-05
    41 Broy./Diag. 0.40E+00    6.9     0.00000776     -4911.5415200843  6.42E-05
    42 Broy./Diag. 0.40E+00    7.3     0.00001060     -4911.5415190755  1.01E-06
    43 Broy./Diag. 0.40E+00    7.3     0.00000881     -4911.5415042783  1.48E-05
    44 Broy./Diag. 0.40E+00    7.5     0.00000815     -4911.5415538770 -4.96E-05
    45 Broy./Diag. 0.40E+00    6.8     0.00000532     -4911.5415163664  3.75E-05
    46 Broy./Diag. 0.40E+00    7.1     0.00000589     -4911.5414907483  2.56E-05
    47 Broy./Diag. 0.40E+00    7.5     0.00000507     -4911.5415254858 -3.47E-05
    48 Broy./Diag. 0.40E+00    7.3     0.00000701     -4911.5415180697  7.42E-06
    49 Broy./Diag. 0.40E+00    7.5     0.00000550     -4911.5415193121 -1.24E-06
    50 Broy./Diag. 0.40E+00    7.3     0.00000467     -4911.5414896055  2.97E-05
    51 Broy./Diag. 0.40E+00    6.8     0.00000294     -4911.5415071601 -1.76E-05
    52 Broy./Diag. 0.40E+00    7.3     0.00000303     -4911.5415143750 -7.21E-06
    53 Broy./Diag. 0.40E+00    8.0     0.00000268     -4911.5414936739  2.07E-05
    54 Broy./Diag. 0.40E+00    7.5     0.00000359     -4911.5414959079 -2.23E-06
    55 Broy./Diag. 0.40E+00    7.5     0.00000363     -4911.5414935676  2.34E-06
    56 Broy./Diag. 0.40E+00    6.7     0.00000274     -4911.5415106685 -1.71E-05
    57 Broy./Diag. 0.40E+00    7.1     0.00000178     -4911.5414940717  1.66E-05
    58 Broy./Diag. 0.40E+00    6.9     0.00000198     -4911.5414881185  5.95E-06
    59 Broy./Diag. 0.40E+00    7.1     0.00000171     -4911.5414993705 -1.13E-05
    60 Broy./Diag. 0.40E+00    7.3     0.00000205     -4911.5414941523  5.22E-06
    61 Broy./Diag. 0.40E+00    6.5     0.00000195     -4911.5414945035 -3.51E-07
    62 Broy./Diag. 0.40E+00    7.8     0.00000141     -4911.5414859220  8.58E-06
    63 Broy./Diag. 0.40E+00    7.3     0.00000110     -4911.5414928550 -6.93E-06
    64 Broy./Diag. 0.40E+00    6.9     0.00000116     -4911.5414947704 -1.92E-06
    65 Broy./Diag. 0.40E+00    7.3     0.00000111     -4911.5414863911  8.38E-06
    66 Broy./Diag. 0.40E+00    7.3     0.00000129     -4911.5414888643 -2.47E-06
    67 Broy./Diag. 0.40E+00    6.9     0.00000141     -4911.5414878336  1.03E-06
    68 Broy./Diag. 0.40E+00    7.2     0.00000073     -4911.5414925080 -4.67E-06

  *** SCF run converged in    68 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008297074032
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.37349616063057
  Hartree energy:                                            1781.73163782178176
  Exchange-correlation energy:                               -779.31359837804689
  Electronic entropic energy:                                  -0.24268854922618
  Fermi energy:                                                 0.08644879249941

  Total energy:                                             -4911.54149250803403

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.541482666055344

 MD| ***************************************************************************
 MD| Step number                                                            1205
 MD| Time [fs]                                                       2410.000000
 MD| Conserved quantity [hartree]                            -0.491122447318E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    496.277067           592.652580
 MD| Energy drift per atom [K]           0.197395458273E+03   0.269403392318E+03
 MD| Potential energy [hartree]         -0.491154148267E+04  -0.491156355257E+04
 MD| Kinetic energy [hartree]            0.317009488766E+00   0.373735870704E+00
 MD| Temperature [K]                             844.755778           995.918253
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02388976     -4911.5391499806 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.8     0.08739545     -4911.4632714562  7.59E-02
     3 Broy./Diag. 0.40E+00    6.9     0.08067067     -4911.8688177706 -4.06E-01
     4 Broy./Diag. 0.40E+00    7.1     0.03477778     -4911.4576306007  4.11E-01
     5 Broy./Diag. 0.40E+00    7.3     0.02266433     -4911.5757018527 -1.18E-01
     6 Broy./Diag. 0.40E+00    7.3     0.00431340     -4911.5388987757  3.68E-02
     7 Broy./Diag. 0.40E+00    6.8     0.00337246     -4911.5486592781 -9.76E-03
     8 Broy./Diag. 0.40E+00    7.1     0.00192486     -4911.5376040661  1.11E-02
     9 Broy./Diag. 0.40E+00    8.1     0.00132910     -4911.5436477848 -6.04E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00108781     -4911.5428913339  7.56E-04
    11 Broy./Diag. 0.40E+00    7.1     0.00099257     -4911.5374918809  5.40E-03
    12 Broy./Diag. 0.40E+00    6.9     0.00051596     -4911.5422267806 -4.73E-03
    13 Broy./Diag. 0.40E+00    7.1     0.00020880     -4911.5416828898  5.44E-04
    14 Broy./Diag. 0.40E+00    7.1     0.00018586     -4911.5412873257  3.96E-04
    15 Broy./Diag. 0.40E+00    6.7     0.00015303     -4911.5407919452  4.95E-04
    16 Broy./Diag. 0.40E+00    6.9     0.00022273     -4911.5412448085 -4.53E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00021955     -4911.5417884620 -5.44E-04
    18 Broy./Diag. 0.40E+00    7.3     0.00019098     -4911.5404738037  1.31E-03
    19 Broy./Diag. 0.40E+00    7.7     0.00011213     -4911.5408756450 -4.02E-04
    20 Broy./Diag. 0.40E+00    7.2     0.00009247     -4911.5410598366 -1.84E-04
    21 Broy./Diag. 0.40E+00    7.5     0.00006914     -4911.5410977635 -3.79E-05
    22 Broy./Diag. 0.40E+00    7.3     0.00006475     -4911.5407929902  3.05E-04
    23 Broy./Diag. 0.40E+00    7.3     0.00008192     -4911.5407091287  8.39E-05
    24 Broy./Diag. 0.40E+00    6.8     0.00008023     -4911.5411749147 -4.66E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00005303     -4911.5408162190  3.59E-04
    26 Broy./Diag. 0.40E+00    6.9     0.00005565     -4911.5407183836  9.78E-05
    27 Broy./Diag. 0.40E+00    7.5     0.00004564     -4911.5406945345  2.38E-05
    28 Broy./Diag. 0.40E+00    7.3     0.00004550     -4911.5408884596 -1.94E-04
    29 Broy./Diag. 0.40E+00    7.1     0.00004057     -4911.5408471230  4.13E-05
    30 Broy./Diag. 0.40E+00    6.9     0.00003943     -4911.5405853237  2.62E-04
    31 Broy./Diag. 0.40E+00    7.1     0.00002377     -4911.5407448586 -1.60E-04
    32 Broy./Diag. 0.40E+00    7.1     0.00002310     -4911.5407681722 -2.33E-05
    33 Broy./Diag. 0.40E+00    7.0     0.00002011     -4911.5407152014  5.30E-05
    34 Broy./Diag. 0.40E+00    7.3     0.00002171     -4911.5406244027  9.08E-05
    35 Broy./Diag. 0.40E+00    6.9     0.00002428     -4911.5406538277 -2.94E-05
    36 Broy./Diag. 0.40E+00    7.1     0.00002903     -4911.5407960481 -1.42E-04
    37 Broy./Diag. 0.40E+00    7.1     0.00001516     -4911.5406491527  1.47E-04
    38 Broy./Diag. 0.40E+00    7.1     0.00001474     -4911.5406273377  2.18E-05
    39 Broy./Diag. 0.40E+00    7.0     0.00000992     -4911.5406477896 -2.05E-05
    40 Broy./Diag. 0.40E+00    7.8     0.00000986     -4911.5406798204 -3.20E-05
    41 Broy./Diag. 0.40E+00    7.4     0.00000932     -4911.5406514518  2.84E-05
    42 Broy./Diag. 0.40E+00    8.4     0.00001400     -4911.5405955799  5.59E-05
    43 Broy./Diag. 0.40E+00    8.9     0.00001021     -4911.5406645621 -6.90E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00000961     -4911.5406523754  1.22E-05
    45 Broy./Diag. 0.40E+00   10.9     0.00000644     -4911.5406328835  1.95E-05
    46 Broy./Diag. 0.40E+00    7.4     0.00000628     -4911.5406039921  2.89E-05
    47 Broy./Diag. 0.40E+00    6.9     0.00000637     -4911.5406212862 -1.73E-05
    48 Broy./Diag. 0.40E+00    7.3     0.00000681     -4911.5406474224 -2.61E-05
    49 Broy./Diag. 0.40E+00    7.2     0.00000470     -4911.5406086604  3.88E-05
    50 Broy./Diag. 0.40E+00    6.9     0.00000440     -4911.5406107089 -2.05E-06
    51 Broy./Diag. 0.40E+00    8.0     0.00000344     -4911.5406162781 -5.57E-06
    52 Broy./Diag. 0.40E+00    6.9     0.00000338     -4911.5406231293 -6.85E-06
    53 Broy./Diag. 0.40E+00   10.0     0.00000430     -4911.5406096761  1.35E-05
    54 Broy./Diag. 0.40E+00    7.7     0.00000465     -4911.5405937481  1.59E-05
    55 Broy./Diag. 0.40E+00   10.7     0.00000384     -4911.5406177922 -2.40E-05
    56 Broy./Diag. 0.40E+00    7.6     0.00000229     -4911.5406108927  6.90E-06
    57 Broy./Diag. 0.40E+00    7.3     0.00000175     -4911.5406053303  5.56E-06
    58 Broy./Diag. 0.40E+00    7.5     0.00000160     -4911.5405999372  5.39E-06
    59 Broy./Diag. 0.40E+00    7.2     0.00000240     -4911.5406045796 -4.64E-06
    60 Broy./Diag. 0.40E+00    7.2     0.00000216     -4911.5406114168 -6.84E-06
    61 Broy./Diag. 0.40E+00    7.1     0.00000226     -4911.5405961417  1.53E-05
    62 Broy./Diag. 0.40E+00    9.6     0.00000146     -4911.5406001780 -4.04E-06
    63 Broy./Diag. 0.40E+00    7.2     0.00000139     -4911.5406010905 -9.12E-07
    64 Broy./Diag. 0.40E+00    9.6     0.00000113     -4911.5406039370 -2.85E-06
    65 Broy./Diag. 0.40E+00    9.6     0.00000135     -4911.5405986554  5.28E-06
    66 Broy./Diag. 0.40E+00    7.7     0.00000113     -4911.5405949897  3.67E-06
    67 Broy./Diag. 0.40E+00    6.7     0.00000123     -4911.5406015955 -6.61E-06
    68 Broy./Diag. 0.40E+00    6.9     0.00000060     -4911.5405985359  3.06E-06

  *** SCF run converged in    68 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008301201255
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.35722248737102
  Hartree energy:                                            1781.74235863133254
  Exchange-correlation energy:                               -779.30739705078850
  Electronic entropic energy:                                  -0.24244309943450
  Fermi energy:                                                 0.08640296350863

  Total energy:                                             -4911.54059853588569

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.540592710191049

 MD| ***************************************************************************
 MD| Step number                                                            1206
 MD| Time [fs]                                                       2412.000000
 MD| Conserved quantity [hartree]                            -0.491122960477E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    516.246104           592.589225
 MD| Energy drift per atom [K]           0.186734764696E+03   0.269334844534E+03
 MD| Potential energy [hartree]         -0.491154059271E+04  -0.491156353353E+04
 MD| Kinetic energy [hartree]            0.310987944807E+00   0.373683840914E+00
 MD| Temperature [K]                             828.709779           995.779606
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02545278     -4911.5381930114 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.2     0.10838307     -4911.4480266159  9.02E-02
     3 Broy./Diag. 0.40E+00    6.9     0.09824537     -4911.9606820455 -5.13E-01
     4 Broy./Diag. 0.40E+00    8.1     0.03981161     -4911.4539617399  5.07E-01
     5 Broy./Diag. 0.40E+00    7.3     0.02190920     -4911.5588710729 -1.05E-01
     6 Broy./Diag. 0.40E+00    7.3     0.00396891     -4911.5408136671  1.81E-02
     7 Broy./Diag. 0.40E+00    6.9     0.00366949     -4911.5481734370 -7.36E-03
     8 Broy./Diag. 0.40E+00    7.3     0.00209074     -4911.5361930050  1.20E-02
     9 Broy./Diag. 0.40E+00    7.3     0.00167625     -4911.5409585769 -4.77E-03
    10 Broy./Diag. 0.40E+00    6.7     0.00099525     -4911.5434797129 -2.52E-03
    11 Broy./Diag. 0.40E+00    7.1     0.00077507     -4911.5379596760  5.52E-03
    12 Broy./Diag. 0.40E+00    7.1     0.00040036     -4911.5413424523 -3.38E-03
    13 Broy./Diag. 0.40E+00    6.8     0.00029955     -4911.5411742108  1.68E-04
    14 Broy./Diag. 0.40E+00    7.1     0.00014606     -4911.5401238841  1.05E-03
    15 Broy./Diag. 0.40E+00    7.5     0.00016952     -4911.5396364060  4.87E-04
    16 Broy./Diag. 0.40E+00    7.0     0.00023743     -4911.5403068323 -6.70E-04
    17 Broy./Diag. 0.40E+00    7.0     0.00021811     -4911.5411761454 -8.69E-04
    18 Broy./Diag. 0.40E+00    7.3     0.00014815     -4911.5396773243  1.50E-03
    19 Broy./Diag. 0.40E+00    6.9     0.00011914     -4911.5398532993 -1.76E-04
    20 Broy./Diag. 0.40E+00    6.9     0.00010976     -4911.5401573093 -3.04E-04
    21 Broy./Diag. 0.40E+00    7.9     0.00005815     -4911.5401149825  4.23E-05
    22 Broy./Diag. 0.40E+00    6.7     0.00005954     -4911.5398638261  2.51E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00006110     -4911.5397401888  1.24E-04
    24 Broy./Diag. 0.40E+00    7.5     0.00005730     -4911.5401336711 -3.93E-04
    25 Broy./Diag. 0.40E+00    7.8     0.00004050     -4911.5399641956  1.69E-04
    26 Broy./Diag. 0.40E+00    7.2     0.00004872     -4911.5398228210  1.41E-04
    27 Broy./Diag. 0.40E+00    7.0     0.00003662     -4911.5398150158  7.81E-06
    28 Broy./Diag. 0.40E+00    7.1     0.00005040     -4911.5399531900 -1.38E-04
    29 Broy./Diag. 0.40E+00    7.5     0.00003768     -4911.5399657670 -1.26E-05
    30 Broy./Diag. 0.40E+00    7.1     0.00003322     -4911.5397133944  2.52E-04
    31 Broy./Diag. 0.40E+00    7.0     0.00001854     -4911.5397989535 -8.56E-05
    32 Broy./Diag. 0.40E+00    7.3     0.00001665     -4911.5398379864 -3.90E-05
    33 Broy./Diag. 0.40E+00    7.1     0.00001235     -4911.5398232297  1.48E-05
    34 Broy./Diag. 0.40E+00    7.1     0.00001895     -4911.5397623789  6.09E-05
    35 Broy./Diag. 0.40E+00    7.1     0.00002271     -4911.5397633343 -9.55E-07
    36 Broy./Diag. 0.40E+00    7.3     0.00002700     -4911.5398994310 -1.36E-04
    37 Broy./Diag. 0.40E+00    7.3     0.00001366     -4911.5397827194  1.17E-04
    38 Broy./Diag. 0.40E+00    7.3     0.00001273     -4911.5397506486  3.21E-05
    39 Broy./Diag. 0.40E+00    7.1     0.00000824     -4911.5397535170 -2.87E-06
    40 Broy./Diag. 0.40E+00    7.1     0.00000862     -4911.5397782397 -2.47E-05
    41 Broy./Diag. 0.40E+00    6.9     0.00000686     -4911.5397746554  3.58E-06
    42 Broy./Diag. 0.40E+00    7.1     0.00000909     -4911.5397333536  4.13E-05
    43 Broy./Diag. 0.40E+00    6.7     0.00000761     -4911.5397708053 -3.75E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00000744     -4911.5397733398 -2.53E-06
    45 Broy./Diag. 0.40E+00    7.1     0.00000603     -4911.5397552833  1.81E-05
    46 Broy./Diag. 0.40E+00    7.3     0.00000664     -4911.5397341615  2.11E-05
    47 Broy./Diag. 0.40E+00    7.3     0.00000620     -4911.5397375323 -3.37E-06
    48 Broy./Diag. 0.40E+00    7.3     0.00000499     -4911.5397628381 -2.53E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00000307     -4911.5397380046  2.48E-05
    50 Broy./Diag. 0.40E+00    6.7     0.00000252     -4911.5397363301  1.67E-06
    51 Broy./Diag. 0.40E+00    7.5     0.00000261     -4911.5397394512 -3.12E-06
    52 Broy./Diag. 0.40E+00    7.1     0.00000302     -4911.5397445961 -5.14E-06
    53 Broy./Diag. 0.40E+00    6.9     0.00000397     -4911.5397370390  7.56E-06
    54 Broy./Diag. 0.40E+00    7.7     0.00000383     -4911.5397230161  1.40E-05
    55 Broy./Diag. 0.40E+00    7.3     0.00000324     -4911.5397410736 -1.81E-05
    56 Broy./Diag. 0.40E+00    7.7     0.00000193     -4911.5397371553  3.92E-06
    57 Broy./Diag. 0.40E+00    6.9     0.00000133     -4911.5397318148  5.34E-06
    58 Broy./Diag. 0.40E+00    7.1     0.00000098     -4911.5397286351  3.18E-06

  *** SCF run converged in    58 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008294322354
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.34169055703069
  Hartree energy:                                            1781.75259181102638
  Exchange-correlation energy:                               -779.30152147220679
  Electronic entropic energy:                                  -0.24214997229747
  Fermi energy:                                                 0.08635458252026

  Total energy:                                             -4911.53972863512718

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.539722644053654

 MD| ***************************************************************************
 MD| Step number                                                            1207
 MD| Time [fs]                                                       2414.000000
 MD| Conserved quantity [hartree]                            -0.491123080679E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    424.672673           592.450106
 MD| Energy drift per atom [K]           0.184237594130E+03   0.269264341426E+03
 MD| Potential energy [hartree]         -0.491153972264E+04  -0.491156351380E+04
 MD| Kinetic energy [hartree]            0.308915850804E+00   0.373630180608E+00
 MD| Temperature [K]                             823.188135           995.636614
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.03380114     -4911.5372995506 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.14338255     -4911.4166164321  1.21E-01
     3 Broy./Diag. 0.40E+00    7.3     0.12968032     -4912.1511035798 -7.34E-01
     4 Broy./Diag. 0.40E+00    7.1     0.03987554     -4911.4631655870  6.88E-01
     5 Broy./Diag. 0.40E+00    6.9     0.02403622     -4911.5209073010 -5.77E-02
     6 Broy./Diag. 0.40E+00    7.1     0.00315990     -4911.5457389421 -2.48E-02
     7 Broy./Diag. 0.40E+00    7.4     0.00422331     -4911.5438567490  1.88E-03
     8 Broy./Diag. 0.40E+00    7.3     0.00262331     -4911.5381418448  5.71E-03
     9 Broy./Diag. 0.40E+00    7.2     0.00185512     -4911.5403912598 -2.25E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00117790     -4911.5423149409 -1.92E-03
    11 Broy./Diag. 0.40E+00    6.8     0.00073606     -4911.5370961574  5.22E-03
    12 Broy./Diag. 0.40E+00    7.2     0.00041073     -4911.5404471909 -3.35E-03
    13 Broy./Diag. 0.40E+00    6.8     0.00028066     -4911.5408234630 -3.76E-04
    14 Broy./Diag. 0.40E+00    7.3     0.00019304     -4911.5389942596  1.83E-03
    15 Broy./Diag. 0.40E+00    6.9     0.00019280     -4911.5388925272  1.02E-04
    16 Broy./Diag. 0.40E+00    7.1     0.00025416     -4911.5394872261 -5.95E-04
    17 Broy./Diag. 0.40E+00    6.9     0.00027234     -4911.5404265950 -9.39E-04
    18 Broy./Diag. 0.40E+00    7.5     0.00012324     -4911.5388226840  1.60E-03
    19 Broy./Diag. 0.40E+00    7.5     0.00014935     -4911.5389198390 -9.72E-05
    20 Broy./Diag. 0.40E+00    8.0     0.00012449     -4911.5395497826 -6.30E-04
    21 Broy./Diag. 0.40E+00    6.7     0.00006580     -4911.5392001126  3.50E-04
    22 Broy./Diag. 0.40E+00    7.5     0.00006154     -4911.5389913312  2.09E-04
    23 Broy./Diag. 0.40E+00    6.7     0.00007360     -4911.5388900745  1.01E-04
    24 Broy./Diag. 0.40E+00    7.3     0.00005170     -4911.5392984183 -4.08E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00004194     -4911.5391480500  1.50E-04
    26 Broy./Diag. 0.40E+00    7.5     0.00005230     -4911.5389295433  2.19E-04
    27 Broy./Diag. 0.40E+00    7.3     0.00004054     -4911.5390448217 -1.15E-04
    28 Broy./Diag. 0.40E+00    7.3     0.00004865     -4911.5391232433 -7.84E-05
    29 Broy./Diag. 0.40E+00    7.5     0.00004633     -4911.5391197598  3.48E-06
    30 Broy./Diag. 0.40E+00    6.9     0.00003296     -4911.5388626580  2.57E-04
    31 Broy./Diag. 0.40E+00    7.5     0.00002039     -4911.5389404699 -7.78E-05
    32 Broy./Diag. 0.40E+00    6.9     0.00001583     -4911.5390194418 -7.90E-05
    33 Broy./Diag. 0.40E+00    7.3     0.00001204     -4911.5389625506  5.69E-05
    34 Broy./Diag. 0.40E+00    7.1     0.00001762     -4911.5389235084  3.90E-05
    35 Broy./Diag. 0.40E+00    6.9     0.00002787     -4911.5389290692 -5.56E-06
    36 Broy./Diag. 0.40E+00    7.5     0.00002712     -4911.5390621748 -1.33E-04
    37 Broy./Diag. 0.40E+00    6.7     0.00001431     -4911.5389445549  1.18E-04
    38 Broy./Diag. 0.40E+00    7.7     0.00001295     -4911.5388868863  5.77E-05
    39 Broy./Diag. 0.40E+00    6.6     0.00000831     -4911.5389235574 -3.67E-05
    40 Broy./Diag. 0.40E+00    6.8     0.00000817     -4911.5389319881 -8.43E-06
    41 Broy./Diag. 0.40E+00    7.3     0.00000669     -4911.5389282588  3.73E-06
    42 Broy./Diag. 0.40E+00    7.7     0.00000890     -4911.5388896571  3.86E-05
    43 Broy./Diag. 0.40E+00    6.9     0.00000742     -4911.5389247635 -3.51E-05
    44 Broy./Diag. 0.40E+00    7.3     0.00000628     -4911.5389388824 -1.41E-05
    45 Broy./Diag. 0.40E+00    8.3     0.00000582     -4911.5388986391  4.02E-05
    46 Broy./Diag. 0.40E+00    6.9     0.00000638     -4911.5388916029  7.04E-06
    47 Broy./Diag. 0.40E+00    7.3     0.00000595     -4911.5388944479 -2.85E-06
    48 Broy./Diag. 0.40E+00    7.3     0.00000538     -4911.5389195046 -2.51E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00000267     -4911.5388931865  2.63E-05
    50 Broy./Diag. 0.40E+00    7.2     0.00000219     -4911.5388883632  4.82E-06
    51 Broy./Diag. 0.40E+00    7.1     0.00000225     -4911.5388979855 -9.62E-06
    52 Broy./Diag. 0.40E+00    7.1     0.00000270     -4911.5388957511  2.23E-06
    53 Broy./Diag. 0.40E+00    7.1     0.00000358     -4911.5388896782  6.07E-06
    54 Broy./Diag. 0.40E+00    7.1     0.00000416     -4911.5388773502  1.23E-05
    55 Broy./Diag. 0.40E+00    7.3     0.00000299     -4911.5388959466 -1.86E-05
    56 Broy./Diag. 0.40E+00    6.9     0.00000200     -4911.5388934022  2.54E-06
    57 Broy./Diag. 0.40E+00    7.1     0.00000131     -4911.5388826244  1.08E-05
    58 Broy./Diag. 0.40E+00    6.9     0.00000119     -4911.5388831878 -5.63E-07
    59 Broy./Diag. 0.40E+00    7.1     0.00000162     -4911.5388839733 -7.85E-07
    60 Broy./Diag. 0.40E+00    7.0     0.00000154     -4911.5388886175 -4.64E-06
    61 Broy./Diag. 0.40E+00    6.9     0.00000133     -4911.5388792033  9.41E-06
    62 Broy./Diag. 0.40E+00    6.8     0.00000132     -4911.5388804931 -1.29E-06
    63 Broy./Diag. 0.40E+00    7.5     0.00000121     -4911.5388861430 -5.65E-06
    64 Broy./Diag. 0.40E+00    6.9     0.00000108     -4911.5388820664  4.08E-06
    65 Broy./Diag. 0.40E+00    7.7     0.00000120     -4911.5388799566  2.11E-06
    66 Broy./Diag. 0.40E+00    7.3     0.00000102     -4911.5388770282  2.93E-06
    67 Broy./Diag. 0.40E+00    6.9     0.00000069     -4911.5388819029 -4.87E-06

  *** SCF run converged in    67 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008278205764
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.32226634179278
  Hartree energy:                                            1781.76512286061961
  Exchange-correlation energy:                               -779.29408290234710
  Electronic entropic energy:                                  -0.24184846960275
  Fermi energy:                                                 0.08629830638185

  Total energy:                                             -4911.53888190289945

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.538875406651641

 MD| ***************************************************************************
 MD| Step number                                                            1208
 MD| Time [fs]                                                       2416.000000
 MD| Conserved quantity [hartree]                            -0.491121915907E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    489.445215           592.364837
 MD| Energy drift per atom [K]           0.208435338084E+03   0.269213986291E+03
 MD| Potential energy [hartree]         -0.491153887541E+04  -0.491156349340E+04
 MD| Kinetic energy [hartree]            0.319716341000E+00   0.373585549946E+00
 MD| Temperature [K]                             851.968903           995.517684
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.03655478     -4911.5368513633 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.5     0.17207306     -4911.4023525421  1.34E-01
     3 Broy./Diag. 0.40E+00    7.2     0.16659680     -4912.2401267208 -8.38E-01
     4 Broy./Diag. 0.40E+00    7.1     0.03894857     -4911.4618348679  7.78E-01
     5 Broy./Diag. 0.40E+00    7.3     0.02589082     -4911.4999184329 -3.81E-02
     6 Broy./Diag. 0.40E+00    7.1     0.00305078     -4911.5464039312 -4.65E-02
     7 Broy./Diag. 0.40E+00    6.9     0.00376486     -4911.5445858548  1.82E-03
     8 Broy./Diag. 0.40E+00    7.1     0.00283123     -4911.5343816288  1.02E-02
     9 Broy./Diag. 0.40E+00    7.1     0.00156511     -4911.5388685153 -4.49E-03
    10 Broy./Diag. 0.40E+00    6.9     0.00088413     -4911.5421097582 -3.24E-03
    11 Broy./Diag. 0.40E+00    7.2     0.00046427     -4911.5386374647  3.47E-03
    12 Broy./Diag. 0.40E+00    6.9     0.00040485     -4911.5397403518 -1.10E-03
    13 Broy./Diag. 0.40E+00    6.5     0.00018875     -4911.5396596950  8.07E-05
    14 Broy./Diag. 0.40E+00    7.1     0.00020984     -4911.5384476457  1.21E-03
    15 Broy./Diag. 0.40E+00    7.3     0.00016116     -4911.5387357323 -2.88E-04
    16 Broy./Diag. 0.40E+00    6.9     0.00022345     -4911.5393068970 -5.71E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00023327     -4911.5396245435 -3.18E-04
    18 Broy./Diag. 0.40E+00    7.4     0.00013861     -4911.5383251901  1.30E-03
    19 Broy./Diag. 0.40E+00    7.5     0.00011979     -4911.5385139120 -1.89E-04
    20 Broy./Diag. 0.40E+00    7.1     0.00008469     -4911.5389507694 -4.37E-04
    21 Broy./Diag. 0.40E+00    7.3     0.00006750     -4911.5386295706  3.21E-04
    22 Broy./Diag. 0.40E+00    6.9     0.00003917     -4911.5384528418  1.77E-04
    23 Broy./Diag. 0.40E+00    7.5     0.00007906     -4911.5385262244 -7.34E-05
    24 Broy./Diag. 0.40E+00    7.1     0.00005153     -4911.5389305563 -4.04E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00004666     -4911.5386075139  3.23E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00004383     -4911.5384757882  1.32E-04
    27 Broy./Diag. 0.40E+00    7.3     0.00004437     -4911.5386382489 -1.62E-04
    28 Broy./Diag. 0.40E+00    6.7     0.00002404     -4911.5386474055 -9.16E-06
    29 Broy./Diag. 0.40E+00    6.9     0.00003034     -4911.5385686565  7.87E-05
    30 Broy./Diag. 0.40E+00    6.9     0.00002190     -4911.5384292715  1.39E-04
    31 Broy./Diag. 0.40E+00    7.2     0.00002275     -4911.5385525203 -1.23E-04
    32 Broy./Diag. 0.40E+00    6.9     0.00001764     -4911.5385892974 -3.68E-05
    33 Broy./Diag. 0.40E+00    7.1     0.00002044     -4911.5384815850  1.08E-04
    34 Broy./Diag. 0.40E+00    7.3     0.00001504     -4911.5384797380  1.85E-06
    35 Broy./Diag. 0.40E+00    7.3     0.00002306     -4911.5385298745 -5.01E-05
    36 Broy./Diag. 0.40E+00    7.9     0.00001720     -4911.5385859622 -5.61E-05
    37 Broy./Diag. 0.40E+00    7.1     0.00001469     -4911.5384657223  1.20E-04
    38 Broy./Diag. 0.40E+00    6.9     0.00001113     -4911.5384467686  1.90E-05
    39 Broy./Diag. 0.40E+00    6.9     0.00001105     -4911.5385023407 -5.56E-05
    40 Broy./Diag. 0.40E+00    7.1     0.00000702     -4911.5384855977  1.67E-05
    41 Broy./Diag. 0.40E+00    6.9     0.00000799     -4911.5384621378  2.35E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00000856     -4911.5384464111  1.57E-05
    43 Broy./Diag. 0.40E+00    7.7     0.00000943     -4911.5385012406 -5.48E-05
    44 Broy./Diag. 0.40E+00    7.8     0.00000698     -4911.5384941695  7.07E-06
    45 Broy./Diag. 0.40E+00    7.3     0.00000842     -4911.5384420096  5.22E-05
    46 Broy./Diag. 0.40E+00    7.3     0.00000533     -4911.5384528867 -1.09E-05
    47 Broy./Diag. 0.40E+00    6.7     0.00000544     -4911.5384647600 -1.19E-05
    48 Broy./Diag. 0.40E+00    7.5     0.00000364     -4911.5384712569 -6.50E-06
    49 Broy./Diag. 0.40E+00    7.1     0.00000232     -4911.5384466046  2.47E-05
    50 Broy./Diag. 0.40E+00    7.3     0.00000294     -4911.5384498817 -3.28E-06
    51 Broy./Diag. 0.40E+00    7.0     0.00000471     -4911.5384678888 -1.80E-05
    52 Broy./Diag. 0.40E+00    7.5     0.00000355     -4911.5384546314  1.33E-05
    53 Broy./Diag. 0.40E+00    6.6     0.00000388     -4911.5384429607  1.17E-05
    54 Broy./Diag. 0.40E+00    6.7     0.00000376     -4911.5384407630  2.20E-06
    55 Broy./Diag. 0.40E+00    7.3     0.00000221     -4911.5384604611 -1.97E-05
    56 Broy./Diag. 0.40E+00    7.1     0.00000180     -4911.5384517165  8.74E-06
    57 Broy./Diag. 0.40E+00    7.2     0.00000214     -4911.5384412271  1.05E-05
    58 Broy./Diag. 0.40E+00    6.9     0.00000150     -4911.5384455835 -4.36E-06
    59 Broy./Diag. 0.40E+00    7.1     0.00000202     -4911.5384467643 -1.18E-06
    60 Broy./Diag. 0.40E+00    7.3     0.00000212     -4911.5384492122 -2.45E-06
    61 Broy./Diag. 0.40E+00    7.7     0.00000132     -4911.5384385688  1.06E-05
    62 Broy./Diag. 0.40E+00    6.8     0.00000174     -4911.5384429618 -4.39E-06
    63 Broy./Diag. 0.40E+00    6.5     0.00000196     -4911.5384490841 -6.12E-06
    64 Broy./Diag. 0.40E+00    6.9     0.00000121     -4911.5384426021  6.48E-06
    65 Broy./Diag. 0.40E+00    7.1     0.00000086     -4911.5384412107  1.39E-06

  *** SCF run converged in    65 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008256473685
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.30021364155164
  Hartree energy:                                            1781.77887307943547
  Exchange-correlation energy:                               -779.28562423606661
  Electronic entropic energy:                                  -0.24156374370336
  Fermi energy:                                                 0.08624021753987

  Total energy:                                             -4911.53844121073962

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.538437116872956

 MD| ***************************************************************************
 MD| Step number                                                            1209
 MD| Time [fs]                                                       2418.000000
 MD| Conserved quantity [hartree]                            -0.491122003307E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    471.471730           592.264843
 MD| Energy drift per atom [K]           0.206619616483E+03   0.269162212619E+03
 MD| Potential energy [hartree]         -0.491153843712E+04  -0.491156347268E+04
 MD| Kinetic energy [hartree]            0.318404042857E+00   0.373539907673E+00
 MD| Temperature [K]                             848.471937           995.396058
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.04042407     -4911.5364547633 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.20826667     -4911.4124786829  1.24E-01
     3 Broy./Diag. 0.40E+00    7.3     0.19808386     -4912.2646127225 -8.52E-01
     4 Broy./Diag. 0.40E+00    7.2     0.03898913     -4911.4480061936  8.17E-01
     5 Broy./Diag. 0.40E+00    7.3     0.02704165     -4911.5017240252 -5.37E-02
     6 Broy./Diag. 0.40E+00    7.3     0.00424448     -4911.5475584299 -4.58E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00287489     -4911.5420951920  5.46E-03
     8 Broy./Diag. 0.40E+00    6.9     0.00263368     -4911.5403136377  1.78E-03
     9 Broy./Diag. 0.40E+00    6.8     0.00158149     -4911.5399375522  3.76E-04
    10 Broy./Diag. 0.40E+00    7.1     0.00094871     -4911.5390935262  8.44E-04
    11 Broy./Diag. 0.40E+00    7.1     0.00090083     -4911.5422808594 -3.19E-03
    12 Broy./Diag. 0.40E+00    6.6     0.00051992     -4911.5383597779  3.92E-03
    13 Broy./Diag. 0.40E+00    6.7     0.00039855     -4911.5389386865 -5.79E-04
    14 Broy./Diag. 0.40E+00    7.4     0.00019349     -4911.5394035254 -4.65E-04
    15 Broy./Diag. 0.40E+00    7.3     0.00027250     -4911.5387814051  6.22E-04
    16 Broy./Diag. 0.40E+00    7.0     0.00020432     -4911.5387350394  4.64E-05
    17 Broy./Diag. 0.40E+00    7.2     0.00031452     -4911.5386116026  1.23E-04
    18 Broy./Diag. 0.40E+00    7.1     0.00030520     -4911.5395505455 -9.39E-04
    19 Broy./Diag. 0.40E+00    7.7     0.00018234     -4911.5386268477  9.24E-04
    20 Broy./Diag. 0.40E+00    7.0     0.00007673     -4911.5384016538  2.25E-04
    21 Broy./Diag. 0.40E+00    7.4     0.00010792     -4911.5386648070 -2.63E-04
    22 Broy./Diag. 0.40E+00    7.5     0.00010176     -4911.5385959426  6.89E-05
    23 Broy./Diag. 0.40E+00    6.7     0.00007586     -4911.5384440412  1.52E-04
    24 Broy./Diag. 0.40E+00    7.3     0.00011745     -4911.5383086690  1.35E-04
    25 Broy./Diag. 0.40E+00    6.9     0.00012184     -4911.5385430455 -2.34E-04
    26 Broy./Diag. 0.40E+00    8.4     0.00008838     -4911.5386703917 -1.27E-04
    27 Broy./Diag. 0.40E+00    7.5     0.00005944     -4911.5381928842  4.78E-04
    28 Broy./Diag. 0.40E+00    8.1     0.00008293     -4911.5383200879 -1.27E-04
    29 Broy./Diag. 0.40E+00    8.8     0.00003859     -4911.5384137059 -9.36E-05
    30 Broy./Diag. 0.40E+00    7.5     0.00003812     -4911.5383493161  6.44E-05
    31 Broy./Diag. 0.40E+00   11.3     0.00002761     -4911.5382465509  1.03E-04
    32 Broy./Diag. 0.40E+00    8.3     0.00003167     -4911.5382208150  2.57E-05
    33 Broy./Diag. 0.40E+00    7.4     0.00002988     -4911.5383606713 -1.40E-04
    34 Broy./Diag. 0.40E+00    7.3     0.00004313     -4911.5382137649  1.47E-04
    35 Broy./Diag. 0.40E+00    7.1     0.00003128     -4911.5381470965  6.67E-05
    36 Broy./Diag. 0.40E+00    8.4     0.00003597     -4911.5382065353 -5.94E-05
    37 Broy./Diag. 0.40E+00    7.5     0.00002299     -4911.5382706307 -6.41E-05
    38 Broy./Diag. 0.40E+00    8.0     0.00002163     -4911.5382318214  3.88E-05
    39 Broy./Diag. 0.40E+00    9.2     0.00001225     -4911.5381303686  1.01E-04
    40 Broy./Diag. 0.40E+00    7.0     0.00001735     -4911.5381825885 -5.22E-05
    41 Broy./Diag. 0.40E+00    7.6     0.00001722     -4911.5381930467 -1.05E-05
    42 Broy./Diag. 0.40E+00   10.3     0.00001613     -4911.5381475620  4.55E-05
    43 Broy./Diag. 0.40E+00    7.4     0.00001439     -4911.5381106938  3.69E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00001822     -4911.5381325546 -2.19E-05
    45 Broy./Diag. 0.40E+00    7.8     0.00001224     -4911.5382161718 -8.36E-05
    46 Broy./Diag. 0.40E+00    7.1     0.00001088     -4911.5381255879  9.06E-05
    47 Broy./Diag. 0.40E+00    8.4     0.00001047     -4911.5381141325  1.15E-05
    48 Broy./Diag. 0.40E+00    8.7     0.00000807     -4911.5381340811 -1.99E-05
    49 Broy./Diag. 0.40E+00    7.2     0.00000634     -4911.5381409340 -6.85E-06
    50 Broy./Diag. 0.40E+00    9.6     0.00000648     -4911.5381236373  1.73E-05
    51 Broy./Diag. 0.40E+00    8.9     0.00000556     -4911.5380957559  2.79E-05
    52 Broy./Diag. 0.40E+00    7.1     0.00000740     -4911.5381329333 -3.72E-05
    53 Broy./Diag. 0.40E+00    6.7     0.00000880     -4911.5381321155  8.18E-07
    54 Broy./Diag. 0.40E+00    7.5     0.00000622     -4911.5381066092  2.55E-05
    55 Broy./Diag. 0.40E+00    7.1     0.00000553     -4911.5380987847  7.82E-06
    56 Broy./Diag. 0.40E+00    6.7     0.00000456     -4911.5381094164 -1.06E-05
    57 Broy./Diag. 0.40E+00    7.3     0.00000270     -4911.5381206418 -1.12E-05
    58 Broy./Diag. 0.40E+00    6.9     0.00000255     -4911.5380982980  2.23E-05
    59 Broy./Diag. 0.40E+00    8.0     0.00000383     -4911.5380983728 -7.48E-08
    60 Broy./Diag. 0.40E+00    7.5     0.00000335     -4911.5381052527 -6.88E-06
    61 Broy./Diag. 0.40E+00    7.3     0.00000391     -4911.5381056187 -3.66E-07
    62 Broy./Diag. 0.40E+00    7.1     0.00000324     -4911.5380957923  9.83E-06
    63 Broy./Diag. 0.40E+00    7.5     0.00000218     -4911.5380876922  8.10E-06
    64 Broy./Diag. 0.40E+00    7.1     0.00000212     -4911.5381038681 -1.62E-05
    65 Broy./Diag. 0.40E+00    7.3     0.00000261     -4911.5381001480  3.72E-06
    66 Broy./Diag. 0.40E+00    7.3     0.00000143     -4911.5380929324  7.22E-06
    67 Broy./Diag. 0.40E+00    7.1     0.00000181     -4911.5380918066  1.13E-06
    68 Broy./Diag. 0.40E+00    6.9     0.00000173     -4911.5380947677 -2.96E-06
    69 Broy./Diag. 0.40E+00    7.4     0.00000101     -4911.5380974454 -2.68E-06
    70 Broy./Diag. 0.40E+00    6.9     0.00000102     -4911.5380871942  1.03E-05
    71 Broy./Diag. 0.40E+00    7.3     0.00000204     -4911.5380894714 -2.28E-06
    72 Broy./Diag. 0.40E+00    7.1     0.00000118     -4911.5380938606 -4.39E-06
    73 Broy./Diag. 0.40E+00    7.1     0.00000134     -4911.5380924481  1.41E-06
    74 Broy./Diag. 0.40E+00    7.3     0.00000105     -4911.5380887229  3.73E-06
    75 Broy./Diag. 0.40E+00    7.5     0.00000062     -4911.5380870244  1.70E-06

  *** SCF run converged in    75 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008237255244
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.28392489536282
  Hartree energy:                                            1781.78891051822029
  Exchange-correlation energy:                               -779.27932910527750
  Electronic entropic energy:                                  -0.24125321952655
  Fermi energy:                                                 0.08619576213256

  Total energy:                                             -4911.53808702444530

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.538083780839770

 MD| ***************************************************************************
 MD| Step number                                                            1210
 MD| Time [fs]                                                       2420.000000
 MD| Conserved quantity [hartree]                            -0.491122363050E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    571.318647           592.247532
 MD| Energy drift per atom [K]           0.199146094320E+03   0.269104348058E+03
 MD| Potential energy [hartree]         -0.491153808378E+04  -0.491156345170E+04
 MD| Kinetic energy [hartree]            0.314453282596E+00   0.373491075752E+00
 MD| Temperature [K]                             837.944089           995.265932
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.04194753     -4911.5354107355 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.21049259     -4911.4357567118  9.97E-02
     3 Broy./Diag. 0.40E+00    7.1     0.20267826     -4912.2086184636 -7.73E-01
     4 Broy./Diag. 0.40E+00    6.9     0.04062441     -4911.4232695240  7.85E-01
     5 Broy./Diag. 0.40E+00    7.1     0.02446145     -4911.5158113644 -9.25E-02
     6 Broy./Diag. 0.40E+00    7.2     0.00641115     -4911.5487226341 -3.29E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00380370     -4911.5374713400  1.13E-02
     8 Broy./Diag. 0.40E+00    7.1     0.00279839     -4911.5456703862 -8.20E-03
     9 Broy./Diag. 0.40E+00    7.1     0.00179735     -4911.5400178684  5.65E-03
    10 Broy./Diag. 0.40E+00    7.4     0.00158797     -4911.5372352287  2.78E-03
    11 Broy./Diag. 0.40E+00    7.3     0.00123850     -4911.5445995828 -7.36E-03
    12 Broy./Diag. 0.40E+00    7.6     0.00072265     -4911.5382575066  6.34E-03
    13 Broy./Diag. 0.40E+00    6.9     0.00051243     -4911.5387932073 -5.36E-04
    14 Broy./Diag. 0.40E+00    7.3     0.00028219     -4911.5386497170  1.43E-04
    15 Broy./Diag. 0.40E+00    7.1     0.00036006     -4911.5387329842 -8.33E-05
    16 Broy./Diag. 0.40E+00    7.1     0.00024402     -4911.5384192230  3.14E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00035680     -4911.5376125910  8.07E-04
    18 Broy./Diag. 0.40E+00    6.7     0.00034506     -4911.5392626729 -1.65E-03
    19 Broy./Diag. 0.40E+00    6.9     0.00025038     -4911.5379518312  1.31E-03
    20 Broy./Diag. 0.40E+00    7.2     0.00012331     -4911.5379246191  2.72E-05
    21 Broy./Diag. 0.40E+00    7.7     0.00016793     -4911.5378410080  8.36E-05
    22 Broy./Diag. 0.40E+00    7.1     0.00010123     -4911.5378669360 -2.59E-05
    23 Broy./Diag. 0.40E+00    7.1     0.00009903     -4911.5379523108 -8.54E-05
    24 Broy./Diag. 0.40E+00    7.3     0.00011168     -4911.5374557318  4.97E-04
    25 Broy./Diag. 0.40E+00    6.8     0.00013638     -4911.5377714488 -3.16E-04
    26 Broy./Diag. 0.40E+00    7.2     0.00007927     -4911.5378501384 -7.87E-05
    27 Broy./Diag. 0.40E+00    7.3     0.00008784     -4911.5375180258  3.32E-04
    28 Broy./Diag. 0.40E+00    7.1     0.00008230     -4911.5375368864 -1.89E-05
    29 Broy./Diag. 0.40E+00    7.1     0.00007054     -4911.5374430997  9.38E-05
    30 Broy./Diag. 0.40E+00    7.1     0.00005479     -4911.5376665262 -2.23E-04
    31 Broy./Diag. 0.40E+00    6.9     0.00004289     -4911.5374174264  2.49E-04
    32 Broy./Diag. 0.40E+00    7.4     0.00003223     -4911.5373885803  2.88E-05
    33 Broy./Diag. 0.40E+00    7.5     0.00003195     -4911.5374673504 -7.88E-05
    34 Broy./Diag. 0.40E+00    6.9     0.00004043     -4911.5373784754  8.89E-05
    35 Broy./Diag. 0.40E+00    7.3     0.00003811     -4911.5373920373 -1.36E-05
    36 Broy./Diag. 0.40E+00    7.3     0.00004150     -4911.5372692475  1.23E-04
    37 Broy./Diag. 0.40E+00    7.0     0.00003198     -4911.5374382196 -1.69E-04
    38 Broy./Diag. 0.40E+00    6.9     0.00003000     -4911.5373761342  6.21E-05
    39 Broy./Diag. 0.40E+00    7.2     0.00001808     -4911.5372771187  9.90E-05
    40 Broy./Diag. 0.40E+00    7.3     0.00001865     -4911.5373218215 -4.47E-05
    41 Broy./Diag. 0.40E+00    7.3     0.00001828     -4911.5372897000  3.21E-05
    42 Broy./Diag. 0.40E+00    7.3     0.00001769     -4911.5373202195 -3.05E-05
    43 Broy./Diag. 0.40E+00    6.9     0.00001493     -4911.5372318137  8.84E-05
    44 Broy./Diag. 0.40E+00    6.7     0.00001986     -4911.5372555108 -2.37E-05
    45 Broy./Diag. 0.40E+00    6.9     0.00001606     -4911.5373274502 -7.19E-05
    46 Broy./Diag. 0.40E+00    7.5     0.00001521     -4911.5372313248  9.61E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00001248     -4911.5372456433 -1.43E-05
    48 Broy./Diag. 0.40E+00    7.3     0.00001144     -4911.5372242866  2.14E-05
    49 Broy./Diag. 0.40E+00    7.2     0.00000881     -4911.5372693467 -4.51E-05
    50 Broy./Diag. 0.40E+00    7.1     0.00000760     -4911.5372360985  3.32E-05
    51 Broy./Diag. 0.40E+00    6.9     0.00000628     -4911.5372077179  2.84E-05
    52 Broy./Diag. 0.40E+00    6.7     0.00000788     -4911.5372415141 -3.38E-05
    53 Broy./Diag. 0.40E+00    7.1     0.00000780     -4911.5372238890  1.76E-05
    54 Broy./Diag. 0.40E+00    7.1     0.00000778     -4911.5372282504 -4.36E-06
    55 Broy./Diag. 0.40E+00    6.9     0.00000760     -4911.5371929391  3.53E-05
    56 Broy./Diag. 0.40E+00    7.3     0.00000670     -4911.5372176403 -2.47E-05
    57 Broy./Diag. 0.40E+00    6.7     0.00000435     -4911.5372321909 -1.46E-05
    58 Broy./Diag. 0.40E+00    7.8     0.00000434     -4911.5372008829  3.13E-05
    59 Broy./Diag. 0.40E+00    6.9     0.00000312     -4911.5372066473 -5.76E-06
    60 Broy./Diag. 0.40E+00    7.1     0.00000382     -4911.5372020471  4.60E-06
    61 Broy./Diag. 0.40E+00    7.0     0.00000466     -4911.5372139459 -1.19E-05
    62 Broy./Diag. 0.40E+00    7.3     0.00000384     -4911.5371972054  1.67E-05
    63 Broy./Diag. 0.40E+00    7.1     0.00000318     -4911.5371882161  8.99E-06
    64 Broy./Diag. 0.40E+00    7.0     0.00000421     -4911.5372083242 -2.01E-05
    65 Broy./Diag. 0.40E+00    7.3     0.00000244     -4911.5371986005  9.72E-06
    66 Broy./Diag. 0.40E+00    8.0     0.00000227     -4911.5371982930  3.08E-07
    67 Broy./Diag. 0.40E+00    7.3     0.00000253     -4911.5371894944  8.80E-06
    68 Broy./Diag. 0.40E+00    7.5     0.00000207     -4911.5371970281 -7.53E-06
    69 Broy./Diag. 0.40E+00    7.1     0.00000136     -4911.5371985159 -1.49E-06
    70 Broy./Diag. 0.40E+00    7.3     0.00000219     -4911.5371877733  1.07E-05
    71 Broy./Diag. 0.40E+00    6.9     0.00000137     -4911.5371916088 -3.84E-06
    72 Broy./Diag. 0.40E+00    7.0     0.00000178     -4911.5371903985  1.21E-06
    73 Broy./Diag. 0.40E+00    7.1     0.00000199     -4911.5371954776 -5.08E-06
    74 Broy./Diag. 0.40E+00    7.1     0.00000150     -4911.5371874870  7.99E-06
    75 Broy./Diag. 0.40E+00    7.3     0.00000091     -4911.5371860473  1.44E-06

  *** SCF run converged in    75 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008224915806
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.27490235525465
  Hartree energy:                                            1781.79460532330518
  Exchange-correlation energy:                               -779.27546892690418
  Electronic entropic energy:                                  -0.24088456884050
  Fermi energy:                                                 0.08616806759448

  Total energy:                                             -4911.53718604730329

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.537181810231232

 MD| ***************************************************************************
 MD| Step number                                                            1211
 MD| Time [fs]                                                       2422.000000
 MD| Conserved quantity [hartree]                            -0.491120669195E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    544.948314           592.208474
 MD| Energy drift per atom [K]           0.234335327115E+03   0.269075637058E+03
 MD| Potential energy [hartree]         -0.491153718181E+04  -0.491156343000E+04
 MD| Kinetic energy [hartree]            0.330489857943E+00   0.373455566902E+00
 MD| Temperature [K]                             880.677793           995.171309
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.04181430     -4911.5331638036 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.5     0.20294734     -4911.4376625111  9.55E-02
     3 Broy./Diag. 0.40E+00    6.9     0.20068182     -4912.1779478424 -7.40E-01
     4 Broy./Diag. 0.40E+00    7.3     0.04586864     -4911.3901705700  7.88E-01
     5 Broy./Diag. 0.40E+00    7.3     0.02516652     -4911.5193774046 -1.29E-01
     6 Broy./Diag. 0.40E+00    7.1     0.00850891     -4911.5464215748 -2.70E-02
     7 Broy./Diag. 0.40E+00    7.8     0.00419543     -4911.5314763615  1.49E-02
     8 Broy./Diag. 0.40E+00    6.9     0.00276105     -4911.5440230544 -1.25E-02
     9 Broy./Diag. 0.40E+00    7.1     0.00186046     -4911.5394536705  4.57E-03
    10 Broy./Diag. 0.40E+00    7.0     0.00197306     -4911.5336905322  5.76E-03
    11 Broy./Diag. 0.40E+00    7.4     0.00146034     -4911.5440551000 -1.04E-02
    12 Broy./Diag. 0.40E+00    7.1     0.00089437     -4911.5365226669  7.53E-03
    13 Broy./Diag. 0.40E+00    7.1     0.00055885     -4911.5371607715 -6.38E-04
    14 Broy./Diag. 0.40E+00    7.5     0.00032817     -4911.5365330168  6.28E-04
    15 Broy./Diag. 0.40E+00    6.5     0.00038132     -4911.5368410976 -3.08E-04
    16 Broy./Diag. 0.40E+00    7.3     0.00029606     -4911.5367768153  6.43E-05
    17 Broy./Diag. 0.40E+00    7.3     0.00036260     -4911.5355341718  1.24E-03
    18 Broy./Diag. 0.40E+00    7.1     0.00037266     -4911.5372966342 -1.76E-03
    19 Broy./Diag. 0.40E+00    7.1     0.00027750     -4911.5359739013  1.32E-03
    20 Broy./Diag. 0.40E+00    6.9     0.00015953     -4911.5360349459 -6.10E-05
    21 Broy./Diag. 0.40E+00    6.7     0.00020120     -4911.5358440518  1.91E-04
    22 Broy./Diag. 0.40E+00    7.1     0.00013320     -4911.5357695969  7.45E-05
    23 Broy./Diag. 0.40E+00    7.3     0.00011168     -4911.5360766317 -3.07E-04
    24 Broy./Diag. 0.40E+00    6.6     0.00011308     -4911.5354449805  6.32E-04
    25 Broy./Diag. 0.40E+00    7.3     0.00013123     -4911.5357488101 -3.04E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00007836     -4911.5357759958 -2.72E-05
    27 Broy./Diag. 0.40E+00    7.3     0.00010878     -4911.5355443710  2.32E-04
    28 Broy./Diag. 0.40E+00    8.1     0.00009967     -4911.5355456054 -1.23E-06
    29 Broy./Diag. 0.40E+00    7.1     0.00009462     -4911.5353031668  2.42E-04
    30 Broy./Diag. 0.40E+00    7.1     0.00007292     -4911.5357101381 -4.07E-04
    31 Broy./Diag. 0.40E+00    7.3     0.00005484     -4911.5353746539  3.35E-04
    32 Broy./Diag. 0.40E+00    7.3     0.00003303     -4911.5353536059  2.10E-05
    33 Broy./Diag. 0.40E+00    7.1     0.00003719     -4911.5353891469 -3.55E-05
    34 Broy./Diag. 0.40E+00    7.4     0.00004583     -4911.5353224812  6.67E-05
    35 Broy./Diag. 0.40E+00    6.8     0.00004482     -4911.5354049974 -8.25E-05
    36 Broy./Diag. 0.40E+00    6.9     0.00004703     -4911.5351852092  2.20E-04
    37 Broy./Diag. 0.40E+00    7.7     0.00004430     -4911.5353832149 -1.98E-04
    38 Broy./Diag. 0.40E+00    7.3     0.00003534     -4911.5353163733  6.68E-05
    39 Broy./Diag. 0.40E+00    7.1     0.00002026     -4911.5352336803  8.27E-05
    40 Broy./Diag. 0.40E+00    7.4     0.00002247     -4911.5352648936 -3.12E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00002186     -4911.5352008298  6.41E-05
    42 Broy./Diag. 0.40E+00    7.4     0.00001858     -4911.5352758612 -7.50E-05
    43 Broy./Diag. 0.40E+00    7.6     0.00001577     -4911.5351774388  9.84E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00001958     -4911.5351929137 -1.55E-05
    45 Broy./Diag. 0.40E+00    7.3     0.00001803     -4911.5352371944 -4.43E-05
    46 Broy./Diag. 0.40E+00    6.9     0.00001661     -4911.5351628808  7.43E-05
    47 Broy./Diag. 0.40E+00    6.8     0.00001749     -4911.5351961018 -3.32E-05
    48 Broy./Diag. 0.40E+00    7.3     0.00001460     -4911.5351369238  5.92E-05
    49 Broy./Diag. 0.40E+00    7.2     0.00001019     -4911.5352013545 -6.44E-05
    50 Broy./Diag. 0.40E+00    7.0     0.00000849     -4911.5351633128  3.80E-05
    51 Broy./Diag. 0.40E+00    7.3     0.00000723     -4911.5351408720  2.24E-05
    52 Broy./Diag. 0.40E+00    7.1     0.00000651     -4911.5351640908 -2.32E-05
    53 Broy./Diag. 0.40E+00    7.1     0.00001028     -4911.5351390521  2.50E-05
    54 Broy./Diag. 0.40E+00    7.1     0.00000881     -4911.5351673998 -2.83E-05
    55 Broy./Diag. 0.40E+00    7.5     0.00000826     -4911.5351149122  5.25E-05
    56 Broy./Diag. 0.40E+00    7.1     0.00000802     -4911.5351428622 -2.80E-05
    57 Broy./Diag. 0.40E+00    7.4     0.00000610     -4911.5351546620 -1.18E-05
    58 Broy./Diag. 0.40E+00    7.1     0.00000384     -4911.5351239560  3.07E-05
    59 Broy./Diag. 0.40E+00    7.3     0.00000422     -4911.5351340902 -1.01E-05
    60 Broy./Diag. 0.40E+00    6.7     0.00000384     -4911.5351208161  1.33E-05
    61 Broy./Diag. 0.40E+00    7.4     0.00000433     -4911.5351373341 -1.65E-05
    62 Broy./Diag. 0.40E+00    6.8     0.00000389     -4911.5351199951  1.73E-05
    63 Broy./Diag. 0.40E+00    6.7     0.00000382     -4911.5351124811  7.51E-06
    64 Broy./Diag. 0.40E+00    7.2     0.00000342     -4911.5351302187 -1.77E-05
    65 Broy./Diag. 0.40E+00    7.8     0.00000387     -4911.5351167239  1.35E-05
    66 Broy./Diag. 0.40E+00    7.1     0.00000283     -4911.5351240625 -7.34E-06
    67 Broy./Diag. 0.40E+00    7.0     0.00000268     -4911.5351094517  1.46E-05
    68 Broy./Diag. 0.40E+00    7.1     0.00000213     -4911.5351185766 -9.12E-06
    69 Broy./Diag. 0.40E+00    7.3     0.00000150     -4911.5351188569 -2.80E-07
    70 Broy./Diag. 0.40E+00    7.3     0.00000159     -4911.5351093661  9.49E-06
    71 Broy./Diag. 0.40E+00    7.1     0.00000192     -4911.5351145621 -5.20E-06
    72 Broy./Diag. 0.40E+00    7.1     0.00000201     -4911.5351091941  5.37E-06
    73 Broy./Diag. 0.40E+00    7.1     0.00000228     -4911.5351181595 -8.97E-06
    74 Broy./Diag. 0.40E+00    7.7     0.00000172     -4911.5351077361  1.04E-05
    75 Broy./Diag. 0.40E+00    6.9     0.00000112     -4911.5351070304  7.06E-07
    76 Broy./Diag. 0.40E+00    7.3     0.00000104     -4911.5351127494 -5.72E-06
    77 Broy./Diag. 0.40E+00    7.1     0.00000102     -4911.5351078033  4.95E-06
    78 Broy./Diag. 0.40E+00    7.3     0.00000089     -4911.5351094123 -1.61E-06

  *** SCF run converged in    78 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008219788686
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.27278005328571
  Hartree energy:                                            1781.79650368509328
  Exchange-correlation energy:                               -779.27357637876491
  Electronic entropic energy:                                  -0.24047643534317
  Fermi energy:                                                 0.08615149861326

  Total energy:                                             -4911.53510941225250

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.535102129986626

 MD| ***************************************************************************
 MD| Step number                                                            1212
 MD| Time [fs]                                                       2424.000000
 MD| Conserved quantity [hartree]                            -0.491120479215E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    568.628797           592.189018
 MD| Energy drift per atom [K]           0.238282098775E+03   0.269050229849E+03
 MD| Potential energy [hartree]         -0.491153510213E+04  -0.491156340663E+04
 MD| Kinetic energy [hartree]            0.330309979650E+00   0.373419968232E+00
 MD| Temperature [K]                             880.198460           995.076447
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.03981236     -4911.5301399103 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.17445979     -4911.4633453467  6.68E-02
     3 Broy./Diag. 0.40E+00    7.1     0.17736280     -4912.0471389042 -5.84E-01
     4 Broy./Diag. 0.40E+00    6.9     0.04624613     -4911.3730704386  6.74E-01
     5 Broy./Diag. 0.40E+00    6.9     0.02385247     -4911.5376982325 -1.65E-01
     6 Broy./Diag. 0.40E+00    7.3     0.00969748     -4911.5393003783 -1.60E-03
     7 Broy./Diag. 0.40E+00    7.5     0.00412360     -4911.5251364370  1.42E-02
     8 Broy./Diag. 0.40E+00    7.1     0.00269562     -4911.5426711655 -1.75E-02
     9 Broy./Diag. 0.40E+00    7.2     0.00184978     -4911.5371861246  5.49E-03
    10 Broy./Diag. 0.40E+00    7.3     0.00191797     -4911.5307124515  6.47E-03
    11 Broy./Diag. 0.40E+00    8.3     0.00139187     -4911.5399000053 -9.19E-03
    12 Broy./Diag. 0.40E+00    7.1     0.00089781     -4911.5338439075  6.06E-03
    13 Broy./Diag. 0.40E+00    7.5     0.00060167     -4911.5341895095 -3.46E-04
    14 Broy./Diag. 0.40E+00    6.9     0.00035336     -4911.5334901875  6.99E-04
    15 Broy./Diag. 0.40E+00    6.9     0.00038836     -4911.5339555484 -4.65E-04
    16 Broy./Diag. 0.40E+00    7.7     0.00032429     -4911.5339104814  4.51E-05
    17 Broy./Diag. 0.40E+00    7.1     0.00035718     -4911.5326432460  1.27E-03
    18 Broy./Diag. 0.40E+00    7.1     0.00037189     -4911.5341801722 -1.54E-03
    19 Broy./Diag. 0.40E+00    7.1     0.00027323     -4911.5330143248  1.17E-03
    20 Broy./Diag. 0.40E+00    7.5     0.00016317     -4911.5330798372 -6.55E-05
    21 Broy./Diag. 0.40E+00    7.5     0.00020007     -4911.5328435738  2.36E-04
    22 Broy./Diag. 0.40E+00    7.3     0.00014893     -4911.5327761174  6.75E-05
    23 Broy./Diag. 0.40E+00    7.3     0.00011915     -4911.5330876063 -3.11E-04
    24 Broy./Diag. 0.40E+00    6.8     0.00011611     -4911.5324482747  6.39E-04
    25 Broy./Diag. 0.40E+00    7.3     0.00013148     -4911.5327155933 -2.67E-04
    26 Broy./Diag. 0.40E+00    7.3     0.00007755     -4911.5327739836 -5.84E-05
    27 Broy./Diag. 0.40E+00    6.9     0.00011287     -4911.5325784921  1.95E-04
    28 Broy./Diag. 0.40E+00    6.9     0.00010836     -4911.5324989104  7.96E-05
    29 Broy./Diag. 0.40E+00    6.9     0.00010064     -4911.5322737898  2.25E-04
    30 Broy./Diag. 0.40E+00    7.3     0.00007691     -4911.5326911092 -4.17E-04
    31 Broy./Diag. 0.40E+00    7.3     0.00006023     -4911.5323798196  3.11E-04
    32 Broy./Diag. 0.40E+00    7.1     0.00003939     -4911.5323250148  5.48E-05
    33 Broy./Diag. 0.40E+00    7.9     0.00004398     -4911.5323393452 -1.43E-05
    34 Broy./Diag. 0.40E+00    7.3     0.00005131     -4911.5323308997  8.45E-06
    35 Broy./Diag. 0.40E+00    7.5     0.00004800     -4911.5323973232 -6.64E-05
    36 Broy./Diag. 0.40E+00    7.1     0.00004784     -4911.5321513053  2.46E-04
    37 Broy./Diag. 0.40E+00    7.3     0.00005009     -4911.5323168144 -1.66E-04
    38 Broy./Diag. 0.40E+00    7.5     0.00003926     -4911.5322925436  2.43E-05
    39 Broy./Diag. 0.40E+00    6.7     0.00002733     -4911.5322385101  5.40E-05
    40 Broy./Diag. 0.40E+00    7.5     0.00002661     -4911.5322071466  3.14E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00002410     -4911.5321595612  4.76E-05
    42 Broy./Diag. 0.40E+00    7.6     0.00001938     -4911.5322505478 -9.10E-05
    43 Broy./Diag. 0.40E+00    6.9     0.00001800     -4911.5321667805  8.38E-05
    44 Broy./Diag. 0.40E+00   10.6     0.00002011     -4911.5321489959  1.78E-05
    45 Broy./Diag. 0.40E+00    6.9     0.00001874     -4911.5321742412 -2.52E-05
    46 Broy./Diag. 0.40E+00    7.1     0.00002197     -4911.5321606380  1.36E-05
    47 Broy./Diag. 0.40E+00   10.4     0.00001915     -4911.5321686338 -8.00E-06
    48 Broy./Diag. 0.40E+00    7.9     0.00001499     -4911.5320959437  7.27E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00001144     -4911.5321468189 -5.09E-05
    50 Broy./Diag. 0.40E+00    7.1     0.00000895     -4911.5321319669  1.49E-05
    51 Broy./Diag. 0.40E+00    7.1     0.00000613     -4911.5321151792  1.68E-05
    52 Broy./Diag. 0.40E+00    8.1     0.00000927     -4911.5321141521  1.03E-06
    53 Broy./Diag. 0.40E+00    7.1     0.00001106     -4911.5321025103  1.16E-05
    54 Broy./Diag. 0.40E+00    8.5     0.00000942     -4911.5321358423 -3.33E-05
    55 Broy./Diag. 0.40E+00    8.4     0.00000812     -4911.5320870194  4.88E-05
    56 Broy./Diag. 0.40E+00    8.4     0.00000799     -4911.5320961124 -9.09E-06
    57 Broy./Diag. 0.40E+00   10.0     0.00000531     -4911.5321043783 -8.27E-06
    58 Broy./Diag. 0.40E+00    6.9     0.00000596     -4911.5320938327  1.05E-05
    59 Broy./Diag. 0.40E+00    7.0     0.00000463     -4911.5320942008 -3.68E-07
    60 Broy./Diag. 0.40E+00    7.1     0.00000400     -4911.5320813992  1.28E-05
    61 Broy./Diag. 0.40E+00    8.1     0.00000381     -4911.5320945119 -1.31E-05
    62 Broy./Diag. 0.40E+00    6.9     0.00000379     -4911.5320863048  8.21E-06
    63 Broy./Diag. 0.40E+00    8.3     0.00000333     -4911.5320756796  1.06E-05
    64 Broy./Diag. 0.40E+00    8.4     0.00000510     -4911.5320821654 -6.49E-06
    65 Broy./Diag. 0.40E+00    7.7     0.00000425     -4911.5320797948  2.37E-06
    66 Broy./Diag. 0.40E+00    8.3     0.00000296     -4911.5320842561 -4.46E-06
    67 Broy./Diag. 0.40E+00    9.9     0.00000223     -4911.5320714417  1.28E-05
    68 Broy./Diag. 0.40E+00    7.3     0.00000204     -4911.5320752222 -3.78E-06
    69 Broy./Diag. 0.40E+00    6.9     0.00000159     -4911.5320779098 -2.69E-06
    70 Broy./Diag. 0.40E+00    7.2     0.00000240     -4911.5320721882  5.72E-06
    71 Broy./Diag. 0.40E+00    7.3     0.00000209     -4911.5320711724  1.02E-06
    72 Broy./Diag. 0.40E+00    7.1     0.00000205     -4911.5320686460  2.53E-06
    73 Broy./Diag. 0.40E+00    7.1     0.00000180     -4911.5320758666 -7.22E-06
    74 Broy./Diag. 0.40E+00    7.1     0.00000158     -4911.5320699014  5.97E-06
    75 Broy./Diag. 0.40E+00    7.9     0.00000129     -4911.5320660609  3.84E-06
    76 Broy./Diag. 0.40E+00    7.5     0.00000156     -4911.5320689831 -2.92E-06
    77 Broy./Diag. 0.40E+00    7.1     0.00000113     -4911.5320690851 -1.02E-07
    78 Broy./Diag. 0.40E+00    6.9     0.00000096     -4911.5320682698  8.15E-07

  *** SCF run converged in    78 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008220731025
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.28030880029110
  Hartree energy:                                            1781.79278464681670
  Exchange-correlation energy:                               -779.27476749572770
  Electronic entropic energy:                                  -0.24005389664096
  Fermi energy:                                                 0.08615234686723

  Total energy:                                             -4911.53206826975202

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.532060446464129

 MD| ***************************************************************************
 MD| Step number                                                            1213
 MD| Time [fs]                                                       2426.000000
 MD| Conserved quantity [hartree]                            -0.491120200697E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    592.678377           592.189422
 MD| Energy drift per atom [K]           0.244068216006E+03   0.269029634619E+03
 MD| Potential energy [hartree]         -0.491153206045E+04  -0.491156338079E+04
 MD| Kinetic energy [hartree]            0.330053477980E+00   0.373384216797E+00
 MD| Temperature [K]                             879.514943           994.981178
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.03710552     -4911.5267285293 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.11681719     -4911.5203565588  6.37E-03
     3 Broy./Diag. 0.40E+00    7.1     0.12994177     -4911.8116567525 -2.91E-01
     4 Broy./Diag. 0.40E+00    7.5     0.04509937     -4911.3685441415  4.43E-01
     5 Broy./Diag. 0.40E+00    7.3     0.01639578     -4911.5620837087 -1.94E-01
     6 Broy./Diag. 0.40E+00    7.3     0.01003794     -4911.5281659179  3.39E-02
     7 Broy./Diag. 0.40E+00    6.9     0.00455822     -4911.5173488428  1.08E-02
     8 Broy./Diag. 0.40E+00    7.4     0.00272096     -4911.5427335914 -2.54E-02
     9 Broy./Diag. 0.40E+00    7.6     0.00176617     -4911.5344775050  8.26E-03
    10 Broy./Diag. 0.40E+00    7.4     0.00137023     -4911.5285463330  5.93E-03
    11 Broy./Diag. 0.40E+00    7.1     0.00091980     -4911.5336142033 -5.07E-03
    12 Broy./Diag. 0.40E+00    8.0     0.00059990     -4911.5304756968  3.14E-03
    13 Broy./Diag. 0.40E+00    7.7     0.00043743     -4911.5308371373 -3.61E-04
    14 Broy./Diag. 0.40E+00    7.0     0.00026802     -4911.5303659170  4.71E-04
    15 Broy./Diag. 0.40E+00    8.1     0.00027285     -4911.5303219205  4.40E-05
    16 Broy./Diag. 0.40E+00    7.5     0.00031840     -4911.5303356134 -1.37E-05
    17 Broy./Diag. 0.40E+00    7.5     0.00036424     -4911.5294359395  9.00E-04
    18 Broy./Diag. 0.40E+00    7.1     0.00034643     -4911.5305915961 -1.16E-03
    19 Broy./Diag. 0.40E+00    7.1     0.00020971     -4911.5292942994  1.30E-03
    20 Broy./Diag. 0.40E+00    7.2     0.00017563     -4911.5295875787 -2.93E-04
    21 Broy./Diag. 0.40E+00    7.5     0.00010005     -4911.5296234295 -3.59E-05
    22 Broy./Diag. 0.40E+00    7.7     0.00012164     -4911.5293417858  2.82E-04
    23 Broy./Diag. 0.40E+00    7.5     0.00011405     -4911.5295122756 -1.70E-04
    24 Broy./Diag. 0.40E+00    7.3     0.00012311     -4911.5290472144  4.65E-04
    25 Broy./Diag. 0.40E+00    7.3     0.00012132     -4911.5294647065 -4.17E-04
    26 Broy./Diag. 0.40E+00    6.9     0.00012587     -4911.5293227623  1.42E-04
    27 Broy./Diag. 0.40E+00    6.6     0.00006426     -4911.5290283877  2.94E-04
    28 Broy./Diag. 0.40E+00    7.1     0.00009471     -4911.5291100005 -8.16E-05
    29 Broy./Diag. 0.40E+00    7.2     0.00008908     -4911.5289822787  1.28E-04
    30 Broy./Diag. 0.40E+00    7.3     0.00005865     -4911.5292173605 -2.35E-04
    31 Broy./Diag. 0.40E+00    6.9     0.00004333     -4911.5289241493  2.93E-04
    32 Broy./Diag. 0.40E+00    7.7     0.00004829     -4911.5289306383 -6.49E-06
    33 Broy./Diag. 0.40E+00    7.1     0.00002470     -4911.5290106333 -8.00E-05
    34 Broy./Diag. 0.40E+00    6.9     0.00004689     -4911.5289446259  6.60E-05
    35 Broy./Diag. 0.40E+00    7.0     0.00005216     -4911.5289232883  2.13E-05
    36 Broy./Diag. 0.40E+00    7.0     0.00004639     -4911.5287729699  1.50E-04
    37 Broy./Diag. 0.40E+00    7.4     0.00003688     -4911.5289778607 -2.05E-04
    38 Broy./Diag. 0.40E+00    7.3     0.00003971     -4911.5288980415  7.98E-05
    39 Broy./Diag. 0.40E+00    7.2     0.00001750     -4911.5288157442  8.23E-05
    40 Broy./Diag. 0.40E+00    7.1     0.00002377     -4911.5288045318  1.12E-05
    41 Broy./Diag. 0.40E+00    6.9     0.00002514     -4911.5288089612 -4.43E-06
    42 Broy./Diag. 0.40E+00    7.0     0.00001814     -4911.5288644604 -5.55E-05
    43 Broy./Diag. 0.40E+00    7.0     0.00001696     -4911.5287557562  1.09E-04
    44 Broy./Diag. 0.40E+00    7.1     0.00002552     -4911.5287633373 -7.58E-06
    45 Broy./Diag. 0.40E+00    7.2     0.00001975     -4911.5288223940 -5.91E-05
    46 Broy./Diag. 0.40E+00    7.2     0.00001850     -4911.5287967608  2.56E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00001816     -4911.5287634762  3.33E-05
    48 Broy./Diag. 0.40E+00    7.1     0.00001267     -4911.5287197791  4.37E-05
    49 Broy./Diag. 0.40E+00    7.3     0.00000983     -4911.5287799988 -6.02E-05
    50 Broy./Diag. 0.40E+00    7.2     0.00000774     -4911.5287589758  2.10E-05
    51 Broy./Diag. 0.40E+00    7.0     0.00000845     -4911.5287321727  2.68E-05
    52 Broy./Diag. 0.40E+00    6.9     0.00000821     -4911.5287349502 -2.78E-06
    53 Broy./Diag. 0.40E+00    7.3     0.00001146     -4911.5287422446 -7.29E-06
    54 Broy./Diag. 0.40E+00    7.0     0.00000977     -4911.5287586756 -1.64E-05
    55 Broy./Diag. 0.40E+00    7.0     0.00000884     -4911.5287082593  5.04E-05
    56 Broy./Diag. 0.40E+00    7.3     0.00000593     -4911.5287222473 -1.40E-05
    57 Broy./Diag. 0.40E+00    7.1     0.00000651     -4911.5287325123 -1.03E-05
    58 Broy./Diag. 0.40E+00    7.5     0.00000380     -4911.5287239360  8.58E-06
    59 Broy./Diag. 0.40E+00    7.1     0.00000463     -4911.5287175415  6.39E-06
    60 Broy./Diag. 0.40E+00    7.1     0.00000497     -4911.5287090324  8.51E-06
    61 Broy./Diag. 0.40E+00    7.3     0.00000550     -4911.5287269373 -1.79E-05
    62 Broy./Diag. 0.40E+00    7.5     0.00000330     -4911.5287131149  1.38E-05
    63 Broy./Diag. 0.40E+00    7.1     0.00000499     -4911.5287026601  1.05E-05
    64 Broy./Diag. 0.40E+00    6.9     0.00000366     -4911.5287093646 -6.70E-06
    65 Broy./Diag. 0.40E+00    7.3     0.00000381     -4911.5287102507 -8.86E-07
    66 Broy./Diag. 0.40E+00    7.0     0.00000305     -4911.5287112700 -1.02E-06
    67 Broy./Diag. 0.40E+00    7.3     0.00000295     -4911.5286993974  1.19E-05
    68 Broy./Diag. 0.40E+00    7.0     0.00000182     -4911.5287055082 -6.11E-06
    69 Broy./Diag. 0.40E+00    7.3     0.00000233     -4911.5287066213 -1.11E-06
    70 Broy./Diag. 0.40E+00    7.9     0.00000199     -4911.5287003854  6.24E-06
    71 Broy./Diag. 0.40E+00    7.3     0.00000234     -4911.5286987991  1.59E-06
    72 Broy./Diag. 0.40E+00    7.1     0.00000248     -4911.5286980804  7.19E-07
    73 Broy./Diag. 0.40E+00    7.1     0.00000225     -4911.5287048999 -6.82E-06
    74 Broy./Diag. 0.40E+00    7.3     0.00000137     -4911.5286969829  7.92E-06
    75 Broy./Diag. 0.40E+00    6.9     0.00000155     -4911.5286953968  1.59E-06
    76 Broy./Diag. 0.40E+00    6.7     0.00000113     -4911.5286984271 -3.03E-06
    77 Broy./Diag. 0.40E+00    7.6     0.00000120     -4911.5286977738  6.53E-07
    78 Broy./Diag. 0.40E+00    7.1     0.00000134     -4911.5286965501  1.22E-06
    79 Broy./Diag. 0.40E+00    8.2     0.00000135     -4911.5286925429  4.01E-06
    80 Broy./Diag. 0.40E+00    7.1     0.00000105     -4911.5286964042 -3.86E-06
    81 Broy./Diag. 0.40E+00    7.0     0.00000114     -4911.5286969640 -5.60E-07
    82 Broy./Diag. 0.40E+00    7.3     0.00000085     -4911.5286931272  3.84E-06

  *** SCF run converged in    82 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008225495367
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.29567641709582
  Hartree energy:                                            1781.78440954427288
  Exchange-correlation energy:                               -779.27879478156001
  Electronic entropic energy:                                  -0.23964405095931
  Fermi energy:                                                 0.08617215610839

  Total energy:                                             -4911.52869312718576

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.528689160590147

 MD| ***************************************************************************
 MD| Step number                                                            1214
 MD| Time [fs]                                                       2428.000000
 MD| Conserved quantity [hartree]                            -0.491119703049E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    601.539852           592.197124
 MD| Energy drift per atom [K]           0.254406665327E+03   0.269017589339E+03
 MD| Potential energy [hartree]         -0.491152868916E+04  -0.491156335221E+04
 MD| Kinetic energy [hartree]            0.331658666017E+00   0.373349846492E+00
 MD| Temperature [K]                             883.792392           994.889589
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.03491305     -4911.5229313517 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.9     0.09921157     -4911.5378585956 -1.49E-02
     3 Broy./Diag. 0.40E+00    7.5     0.11604601     -4911.7084572959 -1.71E-01
     4 Broy./Diag. 0.40E+00    6.7     0.04607894     -4911.3828978583  3.26E-01
     5 Broy./Diag. 0.40E+00    6.9     0.01239920     -4911.5628406536 -1.80E-01
     6 Broy./Diag. 0.40E+00    7.1     0.00986772     -4911.5206618055  4.22E-02
     7 Broy./Diag. 0.40E+00    6.6     0.00575692     -4911.5174583645  3.20E-03
     8 Broy./Diag. 0.40E+00    7.1     0.00268800     -4911.5388424029 -2.14E-02
     9 Broy./Diag. 0.40E+00    6.9     0.00157183     -4911.5305579581  8.28E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00102249     -4911.5261277057  4.43E-03
    11 Broy./Diag. 0.40E+00    7.7     0.00059867     -4911.5282572753 -2.13E-03
    12 Broy./Diag. 0.40E+00    8.1     0.00049691     -4911.5273373229  9.20E-04
    13 Broy./Diag. 0.40E+00    7.3     0.00034006     -4911.5274767135 -1.39E-04
    14 Broy./Diag. 0.40E+00    7.4     0.00028165     -4911.5268624473  6.14E-04
    15 Broy./Diag. 0.40E+00    6.9     0.00022182     -4911.5261383530  7.24E-04
    16 Broy./Diag. 0.40E+00    7.9     0.00026822     -4911.5265726061 -4.34E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00025924     -4911.5257533384  8.19E-04
    18 Broy./Diag. 0.40E+00    7.1     0.00020359     -4911.5258248212 -7.15E-05
    19 Broy./Diag. 0.40E+00    7.5     0.00019132     -4911.5252809207  5.44E-04
    20 Broy./Diag. 0.40E+00    7.5     0.00016251     -4911.5257122507 -4.31E-04
    21 Broy./Diag. 0.40E+00    7.1     0.00012815     -4911.5257313975 -1.91E-05
    22 Broy./Diag. 0.40E+00    7.5     0.00006982     -4911.5252721121  4.59E-04
    23 Broy./Diag. 0.40E+00    6.7     0.00007099     -4911.5254375896 -1.65E-04
    24 Broy./Diag. 0.40E+00    7.1     0.00006381     -4911.5253297965  1.08E-04
    25 Broy./Diag. 0.40E+00    6.9     0.00006949     -4911.5254717688 -1.42E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00005072     -4911.5251687946  3.03E-04
    27 Broy./Diag. 0.40E+00    6.7     0.00007627     -4911.5251572050  1.16E-05
    28 Broy./Diag. 0.40E+00    7.1     0.00004150     -4911.5253565860 -1.99E-04
    29 Broy./Diag. 0.40E+00    6.9     0.00005722     -4911.5251444411  2.12E-04
    30 Broy./Diag. 0.40E+00    7.3     0.00004176     -4911.5251856056 -4.12E-05
    31 Broy./Diag. 0.40E+00    6.6     0.00004434     -4911.5250076133  1.78E-04
    32 Broy./Diag. 0.40E+00    6.6     0.00002520     -4911.5251701186 -1.63E-04
    33 Broy./Diag. 0.40E+00    7.3     0.00003100     -4911.5251509737  1.91E-05
    34 Broy./Diag. 0.40E+00    7.1     0.00001452     -4911.5250306135  1.20E-04
    35 Broy./Diag. 0.40E+00    7.2     0.00002722     -4911.5250632296 -3.26E-05
    36 Broy./Diag. 0.40E+00    7.3     0.00002717     -4911.5250378638  2.54E-05
    37 Broy./Diag. 0.40E+00    7.1     0.00003240     -4911.5251220565 -8.42E-05
    38 Broy./Diag. 0.40E+00    7.2     0.00001947     -4911.5249590104  1.63E-04
    39 Broy./Diag. 0.40E+00    6.5     0.00002562     -4911.5249586590  3.51E-07
    40 Broy./Diag. 0.40E+00    7.0     0.00001205     -4911.5250329304 -7.43E-05
    41 Broy./Diag. 0.40E+00    7.3     0.00001285     -4911.5249951750  3.78E-05
    42 Broy./Diag. 0.40E+00    7.3     0.00001096     -4911.5249890031  6.17E-06
    43 Broy./Diag. 0.40E+00    6.7     0.00001521     -4911.5249367088  5.23E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00001294     -4911.5250071495 -7.04E-05
    45 Broy./Diag. 0.40E+00    7.3     0.00001451     -4911.5249876689  1.95E-05
    46 Broy./Diag. 0.40E+00    7.3     0.00000981     -4911.5249279408  5.97E-05
    47 Broy./Diag. 0.40E+00    7.3     0.00001099     -4911.5249396399 -1.17E-05
    48 Broy./Diag. 0.40E+00    7.1     0.00000984     -4911.5249375755  2.06E-06
    49 Broy./Diag. 0.40E+00    7.3     0.00000850     -4911.5249723280 -3.48E-05
    50 Broy./Diag. 0.40E+00    7.5     0.00000708     -4911.5249201266  5.22E-05
    51 Broy./Diag. 0.40E+00    7.9     0.00000728     -4911.5249229743 -2.85E-06
    52 Broy./Diag. 0.40E+00    7.3     0.00000585     -4911.5249476654 -2.47E-05
    53 Broy./Diag. 0.40E+00    7.1     0.00000609     -4911.5249322055  1.55E-05
    54 Broy./Diag. 0.40E+00    7.3     0.00000578     -4911.5249244264  7.78E-06
    55 Broy./Diag. 0.40E+00    7.4     0.00000628     -4911.5249030301  2.14E-05
    56 Broy./Diag. 0.40E+00    6.9     0.00000671     -4911.5249369172 -3.39E-05
    57 Broy./Diag. 0.40E+00    7.1     0.00000461     -4911.5249240041  1.29E-05
    58 Broy./Diag. 0.40E+00    6.9     0.00000407     -4911.5249056949  1.83E-05
    59 Broy./Diag. 0.40E+00    6.7     0.00000369     -4911.5249131481 -7.45E-06
    60 Broy./Diag. 0.40E+00    6.9     0.00000319     -4911.5249108298  2.32E-06
    61 Broy./Diag. 0.40E+00    6.9     0.00000289     -4911.5249194050 -8.58E-06
    62 Broy./Diag. 0.40E+00    7.2     0.00000368     -4911.5249016420  1.78E-05
    63 Broy./Diag. 0.40E+00    7.3     0.00000309     -4911.5249060425 -4.40E-06
    64 Broy./Diag. 0.40E+00    7.3     0.00000332     -4911.5249147409 -8.70E-06
    65 Broy./Diag. 0.40E+00    7.3     0.00000296     -4911.5249040083  1.07E-05
    66 Broy./Diag. 0.40E+00    7.3     0.00000245     -4911.5249049917 -9.83E-07
    67 Broy./Diag. 0.40E+00    7.1     0.00000219     -4911.5248981928  6.80E-06
    68 Broy./Diag. 0.40E+00    7.1     0.00000210     -4911.5249066576 -8.46E-06
    69 Broy./Diag. 0.40E+00    6.9     0.00000123     -4911.5249019807  4.68E-06
    70 Broy./Diag. 0.40E+00    6.9     0.00000177     -4911.5248977088  4.27E-06
    71 Broy./Diag. 0.40E+00    7.8     0.00000180     -4911.5249021495 -4.44E-06
    72 Broy./Diag. 0.40E+00    6.9     0.00000175     -4911.5248989050  3.24E-06
    73 Broy./Diag. 0.40E+00    7.2     0.00000170     -4911.5249014749 -2.57E-06
    74 Broy./Diag. 0.40E+00    7.1     0.00000163     -4911.5248950163  6.46E-06
    75 Broy./Diag. 0.40E+00    7.3     0.00000087     -4911.5248978964 -2.88E-06

  *** SCF run converged in    75 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008233472217
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.31989815591714
  Hartree energy:                                            1781.77067625743189
  Exchange-correlation energy:                               -779.28584130390618
  Electronic entropic energy:                                  -0.23929084094440
  Fermi energy:                                                 0.08621099688836

  Total energy:                                             -4911.52489789640094

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.524890913367017

 MD| ***************************************************************************
 MD| Step number                                                            1215
 MD| Time [fs]                                                       2430.000000
 MD| Conserved quantity [hartree]                            -0.491120497017E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    545.015575           592.158292
 MD| Energy drift per atom [K]           0.237912279293E+03   0.268991988261E+03
 MD| Potential energy [hartree]         -0.491152489091E+04  -0.491156332056E+04
 MD| Kinetic energy [hartree]            0.319920748228E+00   0.373305871926E+00
 MD| Temperature [K]                             852.513600           994.772407
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02840440     -4911.5190704758 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.9     0.05214460     -4911.5727906977 -5.37E-02
     3 Broy./Diag. 0.40E+00    8.0     0.06662915     -4911.5566377707  1.62E-02
     4 Broy./Diag. 0.40E+00    7.1     0.03155805     -4911.4510275589  1.06E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01100557     -4911.5609587455 -1.10E-01
     6 Broy./Diag. 0.40E+00    7.5     0.00673982     -4911.5114812951  4.95E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00483419     -4911.5172033083 -5.72E-03
     8 Broy./Diag. 0.40E+00    7.0     0.00222492     -4911.5332619907 -1.61E-02
     9 Broy./Diag. 0.40E+00    7.0     0.00199998     -4911.5283255803  4.94E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00146145     -4911.5213908596  6.93E-03
    11 Broy./Diag. 0.40E+00    7.1     0.00108566     -4911.5202900279  1.10E-03
    12 Broy./Diag. 0.40E+00    7.5     0.00059207     -4911.5252212941 -4.93E-03
    13 Broy./Diag. 0.40E+00    7.3     0.00052653     -4911.5233579122  1.86E-03
    14 Broy./Diag. 0.40E+00    6.7     0.00033912     -4911.5222467758  1.11E-03
    15 Broy./Diag. 0.40E+00    7.1     0.00039889     -4911.5233091796 -1.06E-03
    16 Broy./Diag. 0.40E+00    7.5     0.00048846     -4911.5235802870 -2.71E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00035857     -4911.5229804135  6.00E-04
    18 Broy./Diag. 0.40E+00    7.1     0.00030902     -4911.5214477545  1.53E-03
    19 Broy./Diag. 0.40E+00    7.1     0.00028822     -4911.5222838780 -8.36E-04
    20 Broy./Diag. 0.40E+00    7.3     0.00020286     -4911.5224550523 -1.71E-04
    21 Broy./Diag. 0.40E+00    6.9     0.00016257     -4911.5218311675  6.24E-04
    22 Broy./Diag. 0.40E+00    7.7     0.00020139     -4911.5215754961  2.56E-04
    23 Broy./Diag. 0.40E+00    7.6     0.00018842     -4911.5216872360 -1.12E-04
    24 Broy./Diag. 0.40E+00    7.3     0.00016448     -4911.5224167131 -7.29E-04
    25 Broy./Diag. 0.40E+00    6.9     0.00015105     -4911.5214190476  9.98E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00014613     -4911.5214576094 -3.86E-05
    27 Broy./Diag. 0.40E+00    7.3     0.00012678     -4911.5216816677 -2.24E-04
    28 Broy./Diag. 0.40E+00    7.1     0.00011537     -4911.5215260422  1.56E-04
    29 Broy./Diag. 0.40E+00    7.0     0.00008336     -4911.5213774432  1.49E-04
    30 Broy./Diag. 0.40E+00    6.9     0.00007793     -4911.5211186894  2.59E-04
    31 Broy./Diag. 0.40E+00    7.3     0.00006353     -4911.5214238971 -3.05E-04
    32 Broy./Diag. 0.40E+00    7.7     0.00006730     -4911.5212892558  1.35E-04
    33 Broy./Diag. 0.40E+00    6.9     0.00006747     -4911.5211219207  1.67E-04
    34 Broy./Diag. 0.40E+00    7.2     0.00006732     -4911.5212169186 -9.50E-05
    35 Broy./Diag. 0.40E+00    6.8     0.00005541     -4911.5212141412  2.78E-06
    36 Broy./Diag. 0.40E+00    7.5     0.00006271     -4911.5212479708 -3.38E-05
    37 Broy./Diag. 0.40E+00    7.2     0.00003899     -4911.5209787074  2.69E-04
    38 Broy./Diag. 0.40E+00    6.7     0.00004795     -4911.5210853139 -1.07E-04
    39 Broy./Diag. 0.40E+00    7.1     0.00003597     -4911.5211104758 -2.52E-05
    40 Broy./Diag. 0.40E+00    7.1     0.00003134     -4911.5210066225  1.04E-04
    41 Broy./Diag. 0.40E+00    7.3     0.00002199     -4911.5209920530  1.46E-05
    42 Broy./Diag. 0.40E+00    7.5     0.00003435     -4911.5209751541  1.69E-05
    43 Broy./Diag. 0.40E+00    7.1     0.00002571     -4911.5211135119 -1.38E-04
    44 Broy./Diag. 0.40E+00    7.0     0.00003453     -4911.5209283877  1.85E-04
    45 Broy./Diag. 0.40E+00    7.2     0.00002924     -4911.5209198124  8.58E-06
    46 Broy./Diag. 0.40E+00    6.7     0.00002816     -4911.5209950485 -7.52E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00001566     -4911.5209701186  2.49E-05
    48 Broy./Diag. 0.40E+00    7.1     0.00001438     -4911.5209416918  2.84E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00001086     -4911.5208838990  5.78E-05
    50 Broy./Diag. 0.40E+00    7.0     0.00001594     -4911.5209454812 -6.16E-05
    51 Broy./Diag. 0.40E+00    8.0     0.00001257     -4911.5209350160  1.05E-05
    52 Broy./Diag. 0.40E+00    6.9     0.00001788     -4911.5208724261  6.26E-05
    53 Broy./Diag. 0.40E+00    9.7     0.00001308     -4911.5208875049 -1.51E-05
    54 Broy./Diag. 0.40E+00    7.6     0.00001231     -4911.5209043685 -1.69E-05
    55 Broy./Diag. 0.40E+00   10.2     0.00000974     -4911.5209354502 -3.11E-05
    56 Broy./Diag. 0.40E+00    8.2     0.00000955     -4911.5208642229  7.12E-05
    57 Broy./Diag. 0.40E+00    7.1     0.00000635     -4911.5208695953 -5.37E-06
    58 Broy./Diag. 0.40E+00    6.9     0.00000857     -4911.5208923482 -2.28E-05
    59 Broy./Diag. 0.40E+00    7.5     0.00000635     -4911.5208761008  1.62E-05
    60 Broy./Diag. 0.40E+00    7.6     0.00000516     -4911.5208645300  1.16E-05
    61 Broy./Diag. 0.40E+00    8.2     0.00000610     -4911.5208496615  1.49E-05
    62 Broy./Diag. 0.40E+00    6.7     0.00000719     -4911.5208915823 -4.19E-05
    63 Broy./Diag. 0.40E+00    9.9     0.00000566     -4911.5208738504  1.77E-05
    64 Broy./Diag. 0.40E+00    6.9     0.00000680     -4911.5208481007  2.57E-05
    65 Broy./Diag. 0.40E+00    9.9     0.00000431     -4911.5208565113 -8.41E-06
    66 Broy./Diag. 0.40E+00    8.5     0.00000293     -4911.5208616650 -5.15E-06
    67 Broy./Diag. 0.40E+00    6.7     0.00000262     -4911.5208639112 -2.25E-06
    68 Broy./Diag. 0.40E+00    6.9     0.00000223     -4911.5208452542  1.87E-05
    69 Broy./Diag. 0.40E+00    7.1     0.00000305     -4911.5208508999 -5.65E-06
    70 Broy./Diag. 0.40E+00    8.0     0.00000428     -4911.5208613553 -1.05E-05
    71 Broy./Diag. 0.40E+00    7.3     0.00000298     -4911.5208500698  1.13E-05
    72 Broy./Diag. 0.40E+00    9.4     0.00000242     -4911.5208447151  5.35E-06
    73 Broy./Diag. 0.40E+00    7.6     0.00000234     -4911.5208424748  2.24E-06
    74 Broy./Diag. 0.40E+00    8.2     0.00000162     -4911.5208559468 -1.35E-05
    75 Broy./Diag. 0.40E+00   10.9     0.00000171     -4911.5208477215  8.23E-06
    76 Broy./Diag. 0.40E+00    7.1     0.00000192     -4911.5208419561  5.77E-06
    77 Broy./Diag. 0.40E+00    7.1     0.00000136     -4911.5208454089 -3.45E-06
    78 Broy./Diag. 0.40E+00    7.1     0.00000142     -4911.5208453934  1.55E-08
    79 Broy./Diag. 0.40E+00    7.1     0.00000145     -4911.5208463015 -9.08E-07
    80 Broy./Diag. 0.40E+00    6.9     0.00000121     -4911.5208374995  8.80E-06
    81 Broy./Diag. 0.40E+00    7.1     0.00000163     -4911.5208427065 -5.21E-06
    82 Broy./Diag. 0.40E+00    7.3     0.00000165     -4911.5208457673 -3.06E-06
    83 Broy./Diag. 0.40E+00    7.9     0.00000100     -4911.5208412204  4.55E-06

  *** SCF run converged in    83 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008244160782
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.35475762897659
  Hartree energy:                                            1781.75040471003808
  Exchange-correlation energy:                               -779.29666938871651
  Electronic entropic energy:                                  -0.23899410476505
  Fermi energy:                                                 0.08627165474163

  Total energy:                                             -4911.52084122043289

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.520835741713199

 MD| ***************************************************************************
 MD| Step number                                                            1216
 MD| Time [fs]                                                       2432.000000
 MD| Conserved quantity [hartree]                            -0.491120700481E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    626.120997           592.186221
 MD| Energy drift per atom [K]           0.233685374021E+03   0.268962953216E+03
 MD| Potential energy [hartree]         -0.491152083574E+04  -0.491156328562E+04
 MD| Kinetic energy [hartree]            0.313830930647E+00   0.373256961612E+00
 MD| Temperature [K]                             836.285668           994.642073
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02541756     -4911.5149478662 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.8     0.03510886     -4911.6174190069 -1.02E-01
     3 Broy./Diag. 0.40E+00    7.3     0.04202659     -4911.4110128643  2.06E-01
     4 Broy./Diag. 0.40E+00    7.3     0.02638324     -4911.5872813677 -1.76E-01
     5 Broy./Diag. 0.40E+00    6.9     0.00749673     -4911.5372813348  5.00E-02
     6 Broy./Diag. 0.40E+00    7.2     0.00514428     -4911.5124748812  2.48E-02
     7 Broy./Diag. 0.40E+00    7.6     0.00408560     -4911.5090094371  3.47E-03
     8 Broy./Diag. 0.40E+00    6.9     0.00262640     -4911.5387246998 -2.97E-02
     9 Broy./Diag. 0.40E+00    6.7     0.00148954     -4911.5199443284  1.88E-02
    10 Broy./Diag. 0.40E+00    7.3     0.00121820     -4911.5167216311  3.22E-03
    11 Broy./Diag. 0.40E+00    7.5     0.00070401     -4911.5207547136 -4.03E-03
    12 Broy./Diag. 0.40E+00    7.1     0.00044907     -4911.5198164755  9.38E-04
    13 Broy./Diag. 0.40E+00    7.3     0.00033201     -4911.5190571009  7.59E-04
    14 Broy./Diag. 0.40E+00    7.5     0.00035104     -4911.5174639701  1.59E-03
    15 Broy./Diag. 0.40E+00    7.5     0.00032909     -4911.5201618946 -2.70E-03
    16 Broy./Diag. 0.40E+00    8.1     0.00044489     -4911.5189477945  1.21E-03
    17 Broy./Diag. 0.40E+00    7.2     0.00023655     -4911.5173323734  1.62E-03
    18 Broy./Diag. 0.40E+00    7.5     0.00024173     -4911.5177328323 -4.00E-04
    19 Broy./Diag. 0.40E+00    7.1     0.00020569     -4911.5177925857 -5.98E-05
    20 Broy./Diag. 0.40E+00    7.1     0.00015509     -4911.5182280525 -4.35E-04
    21 Broy./Diag. 0.40E+00    7.3     0.00010866     -4911.5170531584  1.17E-03
    22 Broy./Diag. 0.40E+00    7.3     0.00017093     -4911.5173177347 -2.65E-04
    23 Broy./Diag. 0.40E+00    6.9     0.00011163     -4911.5176988277 -3.81E-04
    24 Broy./Diag. 0.40E+00    7.1     0.00009728     -4911.5173807863  3.18E-04
    25 Broy./Diag. 0.40E+00    7.3     0.00010144     -4911.5171447253  2.36E-04
    26 Broy./Diag. 0.40E+00    6.9     0.00011251     -4911.5169662611  1.78E-04
    27 Broy./Diag. 0.40E+00    7.7     0.00009498     -4911.5175348880 -5.69E-04
    28 Broy./Diag. 0.40E+00    7.3     0.00011850     -4911.5170632750  4.72E-04
    29 Broy./Diag. 0.40E+00    6.9     0.00008035     -4911.5168376275  2.26E-04
    30 Broy./Diag. 0.40E+00    6.9     0.00005407     -4911.5169975424 -1.60E-04
    31 Broy./Diag. 0.40E+00    7.9     0.00004044     -4911.5169513921  4.62E-05
    32 Broy./Diag. 0.40E+00    7.2     0.00003359     -4911.5169886494 -3.73E-05
    33 Broy./Diag. 0.40E+00    7.3     0.00003586     -4911.5168032617  1.85E-04
    34 Broy./Diag. 0.40E+00    7.3     0.00006305     -4911.5169401554 -1.37E-04
    35 Broy./Diag. 0.40E+00    7.3     0.00005763     -4911.5169118285  2.83E-05
    36 Broy./Diag. 0.40E+00    7.1     0.00004335     -4911.5167309235  1.81E-04
    37 Broy./Diag. 0.40E+00    7.1     0.00003223     -4911.5168070810 -7.62E-05
    38 Broy./Diag. 0.40E+00    7.1     0.00002431     -4911.5167622331  4.48E-05
    39 Broy./Diag. 0.40E+00    7.3     0.00001801     -4911.5168068401 -4.46E-05
    40 Broy./Diag. 0.40E+00    7.3     0.00002083     -4911.5167123557  9.45E-05
    41 Broy./Diag. 0.40E+00    7.3     0.00002169     -4911.5167227853 -1.04E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00001796     -4911.5167572725 -3.45E-05
    43 Broy./Diag. 0.40E+00    7.0     0.00001704     -4911.5166900626  6.72E-05
    44 Broy./Diag. 0.40E+00    6.7     0.00001485     -4911.5166651226  2.49E-05
    45 Broy./Diag. 0.40E+00    6.8     0.00001692     -4911.5166627662  2.36E-06
    46 Broy./Diag. 0.40E+00    7.1     0.00001640     -4911.5167259579 -6.32E-05
    47 Broy./Diag. 0.40E+00    7.4     0.00001557     -4911.5166703926  5.56E-05
    48 Broy./Diag. 0.40E+00    7.1     0.00000874     -4911.5166262197  4.42E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00000822     -4911.5166661134 -3.99E-05
    50 Broy./Diag. 0.40E+00    6.8     0.00000648     -4911.5166599790  6.13E-06
    51 Broy./Diag. 0.40E+00    7.5     0.00000780     -4911.5166455722  1.44E-05
    52 Broy./Diag. 0.40E+00    7.3     0.00000827     -4911.5166108358  3.47E-05
    53 Broy./Diag. 0.40E+00    7.0     0.00001155     -4911.5166408735 -3.00E-05
    54 Broy./Diag. 0.40E+00    6.7     0.00000654     -4911.5166627868 -2.19E-05
    55 Broy./Diag. 0.40E+00    7.1     0.00000754     -4911.5166113281  5.15E-05
    56 Broy./Diag. 0.40E+00    7.1     0.00000471     -4911.5166105964  7.32E-07
    57 Broy./Diag. 0.40E+00    7.3     0.00000535     -4911.5166191881 -8.59E-06
    58 Broy./Diag. 0.40E+00    7.2     0.00000366     -4911.5166312897 -1.21E-05
    59 Broy./Diag. 0.40E+00    7.5     0.00000452     -4911.5166107544  2.05E-05
    60 Broy./Diag. 0.40E+00    7.5     0.00000327     -4911.5166005682  1.02E-05
    61 Broy./Diag. 0.40E+00    6.7     0.00000440     -4911.5166178333 -1.73E-05
    62 Broy./Diag. 0.40E+00    7.2     0.00000323     -4911.5166149961  2.84E-06
    63 Broy./Diag. 0.40E+00    7.0     0.00000397     -4911.5166020773  1.29E-05
    64 Broy./Diag. 0.40E+00    7.2     0.00000297     -4911.5165933072  8.77E-06
    65 Broy./Diag. 0.40E+00    6.9     0.00000368     -4911.5166065966 -1.33E-05
    66 Broy./Diag. 0.40E+00    7.1     0.00000234     -4911.5166109622 -4.37E-06
    67 Broy./Diag. 0.40E+00    6.9     0.00000216     -4911.5165955993  1.54E-05
    68 Broy./Diag. 0.40E+00    7.1     0.00000148     -4911.5165967723 -1.17E-06
    69 Broy./Diag. 0.40E+00    7.1     0.00000207     -4911.5165994719 -2.70E-06
    70 Broy./Diag. 0.40E+00    7.1     0.00000133     -4911.5166025479 -3.08E-06
    71 Broy./Diag. 0.40E+00    7.5     0.00000205     -4911.5165922553  1.03E-05
    72 Broy./Diag. 0.40E+00    7.0     0.00000196     -4911.5165898728  2.38E-06
    73 Broy./Diag. 0.40E+00    7.1     0.00000167     -4911.5166000010 -1.01E-05
    74 Broy./Diag. 0.40E+00    7.9     0.00000111     -4911.5165958134  4.19E-06
    75 Broy./Diag. 0.40E+00    7.3     0.00000107     -4911.5165919173  3.90E-06
    76 Broy./Diag. 0.40E+00    6.9     0.00000077     -4911.5165903945  1.52E-06

  *** SCF run converged in    76 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008256943750
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.39700533680980
  Hartree energy:                                            1781.72567533473739
  Exchange-correlation energy:                               -779.31016693911215
  Electronic entropic energy:                                  -0.23876420699247
  Fermi energy:                                                 0.08634407149650

  Total energy:                                             -4911.51659039451715

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.516585170781582

 MD| ***************************************************************************
 MD| Step number                                                            1217
 MD| Time [fs]                                                       2434.000000
 MD| Conserved quantity [hartree]                            -0.491120718442E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    556.289543           592.156725
 MD| Energy drift per atom [K]           0.233312232603E+03   0.268933659280E+03
 MD| Potential energy [hartree]         -0.491151658517E+04  -0.491156324725E+04
 MD| Kinetic energy [hartree]            0.309400745881E+00   0.373204491427E+00
 MD| Temperature [K]                             824.480267           994.502252
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.01880924     -4911.5106873355 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.03687905     -4911.6306294925 -1.20E-01
     3 Broy./Diag. 0.40E+00    6.9     0.03832357     -4911.3605778160  2.70E-01
     4 Broy./Diag. 0.40E+00    7.6     0.02244211     -4911.5985361972 -2.38E-01
     5 Broy./Diag. 0.40E+00    8.3     0.00846436     -4911.5280259873  7.05E-02
     6 Broy./Diag. 0.40E+00    7.4     0.00441482     -4911.5101143957  1.79E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00346734     -4911.5064488175  3.67E-03
     8 Broy./Diag. 0.40E+00    7.1     0.00234566     -4911.5300312692 -2.36E-02
     9 Broy./Diag. 0.40E+00    7.1     0.00129574     -4911.5141652525  1.59E-02
    10 Broy./Diag. 0.40E+00    7.3     0.00116421     -4911.5128603035  1.30E-03
    11 Broy./Diag. 0.40E+00    6.8     0.00067484     -4911.5176973766 -4.84E-03
    12 Broy./Diag. 0.40E+00    7.6     0.00041197     -4911.5152627607  2.43E-03
    13 Broy./Diag. 0.40E+00    6.7     0.00030087     -4911.5144699110  7.93E-04
    14 Broy./Diag. 0.40E+00    7.3     0.00033122     -4911.5132983458  1.17E-03
    15 Broy./Diag. 0.40E+00    7.1     0.00029893     -4911.5154813595 -2.18E-03
    16 Broy./Diag. 0.40E+00    7.1     0.00037928     -4911.5144334542  1.05E-03
    17 Broy./Diag. 0.40E+00    7.3     0.00028848     -4911.5127995644  1.63E-03
    18 Broy./Diag. 0.40E+00    7.0     0.00023006     -4911.5137577369 -9.58E-04
    19 Broy./Diag. 0.40E+00    7.2     0.00018976     -4911.5137194219  3.83E-05
    20 Broy./Diag. 0.40E+00    7.2     0.00016103     -4911.5136580303  6.14E-05
    21 Broy./Diag. 0.40E+00    7.5     0.00011026     -4911.5127258890  9.32E-04
    22 Broy./Diag. 0.40E+00    8.0     0.00015279     -4911.5129914314 -2.66E-04
    23 Broy./Diag. 0.40E+00    7.3     0.00012951     -4911.5133864633 -3.95E-04
    24 Broy./Diag. 0.40E+00    7.6     0.00008013     -4911.5128673171  5.19E-04
    25 Broy./Diag. 0.40E+00    6.7     0.00008981     -4911.5127655469  1.02E-04
    26 Broy./Diag. 0.40E+00    7.0     0.00010975     -4911.5127853183 -1.98E-05
    27 Broy./Diag. 0.40E+00    7.1     0.00008742     -4911.5131207523 -3.35E-04
    28 Broy./Diag. 0.40E+00    6.8     0.00010460     -4911.5126475979  4.73E-04
    29 Broy./Diag. 0.40E+00    6.9     0.00009987     -4911.5124319244  2.16E-04
    30 Broy./Diag. 0.40E+00    7.1     0.00004611     -4911.5127327059 -3.01E-04
    31 Broy./Diag. 0.40E+00    6.9     0.00003882     -4911.5125831692  1.50E-04
    32 Broy./Diag. 0.40E+00    7.1     0.00003105     -4911.5125690693  1.41E-05
    33 Broy./Diag. 0.40E+00    6.9     0.00002906     -4911.5124803533  8.87E-05
    34 Broy./Diag. 0.40E+00    6.9     0.00004640     -4911.5125736973 -9.33E-05
    35 Broy./Diag. 0.40E+00    7.2     0.00005364     -4911.5125209684  5.27E-05
    36 Broy./Diag. 0.40E+00    6.9     0.00003269     -4911.5123340597  1.87E-04
    37 Broy./Diag. 0.40E+00    6.9     0.00003234     -4911.5124757679 -1.42E-04
    38 Broy./Diag. 0.40E+00    7.3     0.00002501     -4911.5124438630  3.19E-05
    39 Broy./Diag. 0.40E+00    7.3     0.00001866     -4911.5124064966  3.74E-05
    40 Broy./Diag. 0.40E+00    7.3     0.00001746     -4911.5123503030  5.62E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00001994     -4911.5123750579 -2.48E-05
    42 Broy./Diag. 0.40E+00    7.3     0.00001484     -4911.5124011270 -2.61E-05
    43 Broy./Diag. 0.40E+00    6.9     0.00001433     -4911.5123097468  9.14E-05
    44 Broy./Diag. 0.40E+00    7.5     0.00001315     -4911.5123116372 -1.89E-06
    45 Broy./Diag. 0.40E+00    7.1     0.00001473     -4911.5123379788 -2.63E-05
    46 Broy./Diag. 0.40E+00    7.3     0.00001433     -4911.5123561666 -1.82E-05
    47 Broy./Diag. 0.40E+00    7.5     0.00001477     -4911.5122912257  6.49E-05
    48 Broy./Diag. 0.40E+00    7.1     0.00001106     -4911.5122669302  2.43E-05
    49 Broy./Diag. 0.40E+00    7.3     0.00000839     -4911.5123275690 -6.06E-05
    50 Broy./Diag. 0.40E+00    7.1     0.00000591     -4911.5123001866  2.74E-05
    51 Broy./Diag. 0.40E+00    6.9     0.00000565     -4911.5122790705  2.11E-05
    52 Broy./Diag. 0.40E+00    7.2     0.00000636     -4911.5122685254  1.05E-05
    53 Broy./Diag. 0.40E+00    7.1     0.00000872     -4911.5122911849 -2.27E-05
    54 Broy./Diag. 0.40E+00    6.9     0.00000771     -4911.5122937011 -2.52E-06
    55 Broy./Diag. 0.40E+00    7.1     0.00000651     -4911.5122444457  4.93E-05
    56 Broy./Diag. 0.40E+00    6.9     0.00000495     -4911.5122622417 -1.78E-05
    57 Broy./Diag. 0.40E+00    7.3     0.00000471     -4911.5122741500 -1.19E-05
    58 Broy./Diag. 0.40E+00    7.5     0.00000412     -4911.5122699195  4.23E-06
    59 Broy./Diag. 0.40E+00    7.3     0.00000380     -4911.5122532412  1.67E-05
    60 Broy./Diag. 0.40E+00    7.1     0.00000358     -4911.5122504703  2.77E-06
    61 Broy./Diag. 0.40E+00    7.1     0.00000320     -4911.5122658910 -1.54E-05
    62 Broy./Diag. 0.40E+00    7.3     0.00000301     -4911.5122518250  1.41E-05
    63 Broy./Diag. 0.40E+00    7.1     0.00000320     -4911.5122430663  8.76E-06
    64 Broy./Diag. 0.40E+00    7.5     0.00000332     -4911.5122450549 -1.99E-06
    65 Broy./Diag. 0.40E+00    7.1     0.00000319     -4911.5122536933 -8.64E-06
    66 Broy./Diag. 0.40E+00    7.1     0.00000251     -4911.5122505841  3.11E-06
    67 Broy./Diag. 0.40E+00    7.3     0.00000200     -4911.5122377289  1.29E-05
    68 Broy./Diag. 0.40E+00    7.3     0.00000181     -4911.5122453026 -7.57E-06
    69 Broy./Diag. 0.40E+00    7.0     0.00000175     -4911.5122454486 -1.46E-07
    70 Broy./Diag. 0.40E+00    6.9     0.00000164     -4911.5122422954  3.15E-06
    71 Broy./Diag. 0.40E+00    6.9     0.00000180     -4911.5122371985  5.10E-06
    72 Broy./Diag. 0.40E+00    7.3     0.00000177     -4911.5122381918 -9.93E-07
    73 Broy./Diag. 0.40E+00    7.1     0.00000150     -4911.5122447435 -6.55E-06
    74 Broy./Diag. 0.40E+00    7.1     0.00000140     -4911.5122362364  8.51E-06
    75 Broy./Diag. 0.40E+00    6.9     0.00000125     -4911.5122352444  9.92E-07
    76 Broy./Diag. 0.40E+00    7.3     0.00000107     -4911.5122372135 -1.97E-06
    77 Broy./Diag. 0.40E+00    6.9     0.00000101     -4911.5122383827 -1.17E-06
    78 Broy./Diag. 0.40E+00    7.3     0.00000082     -4911.5122359849  2.40E-06

  *** SCF run converged in    78 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008271869510
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.44338492757697
  Hartree energy:                                            1781.69836703841497
  Exchange-correlation energy:                               -779.32503090891169
  Electronic entropic energy:                                  -0.23861723620533
  Fermi energy:                                                 0.08642344340986

  Total energy:                                             -4911.51223598489923

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.512229398363161

 MD| ***************************************************************************
 MD| Step number                                                            1218
 MD| Time [fs]                                                       2436.000000
 MD| Conserved quantity [hartree]                            -0.491120301938E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    567.820468           592.136745
 MD| Energy drift per atom [K]           0.241964965405E+03   0.268911517495E+03
 MD| Potential energy [hartree]         -0.491151222940E+04  -0.491156320536E+04
 MD| Kinetic energy [hartree]            0.309210017726E+00   0.373151950808E+00
 MD| Temperature [K]                             823.972021           994.362244
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.9     0.01975915     -4911.5070659857 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.04036529     -4911.6419192013 -1.35E-01
     3 Broy./Diag. 0.40E+00    7.7     0.03936559     -4911.3244045610  3.18E-01
     4 Broy./Diag. 0.40E+00    6.9     0.01942543     -4911.5941657955 -2.70E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01038190     -4911.5179378675  7.62E-02
     6 Broy./Diag. 0.40E+00    7.1     0.00353098     -4911.5092460126  8.69E-03
     7 Broy./Diag. 0.40E+00    6.6     0.00302967     -4911.5036023541  5.64E-03
     8 Broy./Diag. 0.40E+00    6.9     0.00210736     -4911.5247278272 -2.11E-02
     9 Broy./Diag. 0.40E+00    6.9     0.00116415     -4911.5097139361  1.50E-02
    10 Broy./Diag. 0.40E+00    7.8     0.00115785     -4911.5094283429  2.86E-04
    11 Broy./Diag. 0.40E+00    7.3     0.00084026     -4911.5143948462 -4.97E-03
    12 Broy./Diag. 0.40E+00    7.0     0.00033784     -4911.5113144706  3.08E-03
    13 Broy./Diag. 0.40E+00    7.3     0.00025508     -4911.5107060794  6.08E-04
    14 Broy./Diag. 0.40E+00    7.1     0.00031735     -4911.5096696486  1.04E-03
    15 Broy./Diag. 0.40E+00    7.2     0.00026293     -4911.5117317699 -2.06E-03
    16 Broy./Diag. 0.40E+00    7.7     0.00035451     -4911.5106533714  1.08E-03
    17 Broy./Diag. 0.40E+00    6.4     0.00034127     -4911.5090103848  1.64E-03
    18 Broy./Diag. 0.40E+00    7.3     0.00020064     -4911.5101756631 -1.17E-03
    19 Broy./Diag. 0.40E+00    7.1     0.00016965     -4911.5100405746  1.35E-04
    20 Broy./Diag. 0.40E+00    7.1     0.00016095     -4911.5098761329  1.64E-04
    21 Broy./Diag. 0.40E+00    7.3     0.00010526     -4911.5089999120  8.76E-04
    22 Broy./Diag. 0.40E+00    8.2     0.00013845     -4911.5092717397 -2.72E-04
    23 Broy./Diag. 0.40E+00    6.9     0.00013956     -4911.5096930595 -4.21E-04
    24 Broy./Diag. 0.40E+00    6.7     0.00007167     -4911.5091122776  5.81E-04
    25 Broy./Diag. 0.40E+00    7.2     0.00007980     -4911.5090441738  6.81E-05
    26 Broy./Diag. 0.40E+00    7.6     0.00010840     -4911.5091004120 -5.62E-05
    27 Broy./Diag. 0.40E+00    7.4     0.00008364     -4911.5094032604 -3.03E-04
    28 Broy./Diag. 0.40E+00    7.5     0.00009016     -4911.5089456996  4.58E-04
    29 Broy./Diag. 0.40E+00    7.0     0.00010101     -4911.5087016221  2.44E-04
    30 Broy./Diag. 0.40E+00    7.7     0.00005045     -4911.5090319817 -3.30E-04
    31 Broy./Diag. 0.40E+00    7.3     0.00003486     -4911.5088857097  1.46E-04
    32 Broy./Diag. 0.40E+00    7.3     0.00003033     -4911.5088628534  2.29E-05
    33 Broy./Diag. 0.40E+00    7.1     0.00002967     -4911.5087689807  9.39E-05
    34 Broy./Diag. 0.40E+00    7.1     0.00003858     -4911.5088643026 -9.53E-05
    35 Broy./Diag. 0.40E+00    6.9     0.00004960     -4911.5088352222  2.91E-05
    36 Broy./Diag. 0.40E+00    7.3     0.00003816     -4911.5086490896  1.86E-04
    37 Broy./Diag. 0.40E+00    7.3     0.00003047     -4911.5087640616 -1.15E-04
    38 Broy./Diag. 0.40E+00    6.9     0.00002489     -4911.5087277715  3.63E-05
    39 Broy./Diag. 0.40E+00    7.0     0.00001794     -4911.5087140862  1.37E-05
    40 Broy./Diag. 0.40E+00    7.3     0.00001486     -4911.5086661641  4.79E-05
    41 Broy./Diag. 0.40E+00    7.3     0.00001752     -4911.5086776754 -1.15E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00001651     -4911.5086982405 -2.06E-05
    43 Broy./Diag. 0.40E+00    7.5     0.00001186     -4911.5086275428  7.07E-05
    44 Broy./Diag. 0.40E+00    7.0     0.00001233     -4911.5086376119 -1.01E-05
    45 Broy./Diag. 0.40E+00    7.1     0.00001312     -4911.5086434504 -5.84E-06
    46 Broy./Diag. 0.40E+00    7.1     0.00001375     -4911.5086478359 -4.39E-06
    47 Broy./Diag. 0.40E+00    7.1     0.00001272     -4911.5086026632  4.52E-05
    48 Broy./Diag. 0.40E+00    7.3     0.00001226     -4911.5085891568  1.35E-05
    49 Broy./Diag. 0.40E+00    6.9     0.00000671     -4911.5086377386 -4.86E-05
    50 Broy./Diag. 0.40E+00    6.9     0.00000657     -4911.5086030757  3.47E-05
    51 Broy./Diag. 0.40E+00    6.9     0.00000519     -4911.5085952824  7.79E-06
    52 Broy./Diag. 0.40E+00    7.3     0.00000686     -4911.5085901571  5.13E-06
    53 Broy./Diag. 0.40E+00    7.5     0.00000679     -4911.5086025779 -1.24E-05
    54 Broy./Diag. 0.40E+00    7.1     0.00000755     -4911.5085954987  7.08E-06
    55 Broy./Diag. 0.40E+00    7.1     0.00000516     -4911.5085607003  3.48E-05
    56 Broy./Diag. 0.40E+00    6.7     0.00000596     -4911.5085842559 -2.36E-05
    57 Broy./Diag. 0.40E+00    8.0     0.00000425     -4911.5085862347 -1.98E-06
    58 Broy./Diag. 0.40E+00    6.9     0.00000425     -4911.5085785509  7.68E-06
    59 Broy./Diag. 0.40E+00    7.5     0.00000301     -4911.5085688903  9.66E-06
    60 Broy./Diag. 0.40E+00    9.5     0.00000329     -4911.5085699185 -1.03E-06
    61 Broy./Diag. 0.40E+00    7.4     0.00000244     -4911.5085792344 -9.32E-06
    62 Broy./Diag. 0.40E+00    7.9     0.00000320     -4911.5085635539  1.57E-05
    63 Broy./Diag. 0.40E+00   10.7     0.00000273     -4911.5085615693  1.98E-06
    64 Broy./Diag. 0.40E+00    7.3     0.00000325     -4911.5085646124 -3.04E-06
    65 Broy./Diag. 0.40E+00    6.9     0.00000236     -4911.5085683271 -3.71E-06
    66 Broy./Diag. 0.40E+00    7.3     0.00000223     -4911.5085627834  5.54E-06
    67 Broy./Diag. 0.40E+00    7.2     0.00000158     -4911.5085553020  7.48E-06
    68 Broy./Diag. 0.40E+00    8.3     0.00000165     -4911.5085639713 -8.67E-06
    69 Broy./Diag. 0.40E+00    7.0     0.00000136     -4911.5085606588  3.31E-06
    70 Broy./Diag. 0.40E+00   10.2     0.00000133     -4911.5085577277  2.93E-06
    71 Broy./Diag. 0.40E+00    7.3     0.00000126     -4911.5085555540  2.17E-06
    72 Broy./Diag. 0.40E+00   10.4     0.00000149     -4911.5085572849 -1.73E-06
    73 Broy./Diag. 0.40E+00    7.2     0.00000114     -4911.5085599906 -2.71E-06
    74 Broy./Diag. 0.40E+00    7.3     0.00000116     -4911.5085519738  8.02E-06
    75 Broy./Diag. 0.40E+00    7.6     0.00000098     -4911.5085538992 -1.93E-06

  *** SCF run converged in    75 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008287049863
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.49430286498318
  Hartree energy:                                            1781.66778740597783
  Exchange-correlation energy:                               -779.34175923169221
  Electronic entropic energy:                                  -0.23854530753397
  Fermi energy:                                                 0.08650995947206

  Total energy:                                             -4911.50855389919525

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.508548018332476

 MD| ***************************************************************************
 MD| Step number                                                            1219
 MD| Time [fs]                                                       2438.000000
 MD| Conserved quantity [hartree]                            -0.491120818755E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    563.091042           592.112917
 MD| Energy drift per atom [K]           0.231228285499E+03   0.268880604261E+03
 MD| Potential energy [hartree]         -0.491150854802E+04  -0.491156316052E+04
 MD| Kinetic energy [hartree]            0.300360473130E+00   0.373092236716E+00
 MD| Temperature [K]                             800.390065           994.203120
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02236787     -4911.5033013582 -4.91E+03
     2 Broy./Diag. 0.40E+00    8.5     0.05127543     -4911.6633883542 -1.60E-01
     3 Broy./Diag. 0.40E+00    8.8     0.04684061     -4911.2498902916  4.13E-01
     4 Broy./Diag. 0.40E+00    7.4     0.02892350     -4911.6004641671 -3.51E-01
     5 Broy./Diag. 0.40E+00    9.8     0.01765623     -4911.5022373843  9.82E-02
     6 Broy./Diag. 0.40E+00    8.8     0.00535914     -4911.5062321759 -3.99E-03
     7 Broy./Diag. 0.40E+00    7.2     0.00278097     -4911.5071968730 -9.65E-04
     8 Broy./Diag. 0.40E+00    7.3     0.00234199     -4911.5117025340 -4.51E-03
     9 Broy./Diag. 0.40E+00    6.9     0.00120411     -4911.5096491391  2.05E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00091645     -4911.5038716024  5.78E-03
    11 Broy./Diag. 0.40E+00    7.5     0.00114483     -4911.5102670699 -6.40E-03
    12 Broy./Diag. 0.40E+00    7.1     0.00064183     -4911.5073006850  2.97E-03
    13 Broy./Diag. 0.40E+00    7.3     0.00022877     -4911.5067951746  5.06E-04
    14 Broy./Diag. 0.40E+00    7.8     0.00028872     -4911.5064699340  3.25E-04
    15 Broy./Diag. 0.40E+00    7.5     0.00033173     -4911.5068676987 -3.98E-04
    16 Broy./Diag. 0.40E+00    7.1     0.00021980     -4911.5073798510 -5.12E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00037868     -4911.5051295034  2.25E-03
    18 Broy./Diag. 0.40E+00    7.1     0.00036167     -4911.5062693322 -1.14E-03
    19 Broy./Diag. 0.40E+00    7.1     0.00016247     -4911.5062101280  5.92E-05
    20 Broy./Diag. 0.40E+00    6.9     0.00015248     -4911.5057413317  4.69E-04
    21 Broy./Diag. 0.40E+00    6.9     0.00013408     -4911.5056592931  8.20E-05
    22 Broy./Diag. 0.40E+00    7.3     0.00008327     -4911.5052985007  3.61E-04
    23 Broy./Diag. 0.40E+00    7.3     0.00014159     -4911.5059996997 -7.01E-04
    24 Broy./Diag. 0.40E+00    6.9     0.00012679     -4911.5053775136  6.22E-04
    25 Broy./Diag. 0.40E+00    6.7     0.00007673     -4911.5052588929  1.19E-04
    26 Broy./Diag. 0.40E+00    7.0     0.00009210     -4911.5054218675 -1.63E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00009824     -4911.5053249781  9.69E-05
    28 Broy./Diag. 0.40E+00    7.1     0.00004869     -4911.5053816567 -5.67E-05
    29 Broy./Diag. 0.40E+00    7.1     0.00008299     -4911.5049302159  4.51E-04
    30 Broy./Diag. 0.40E+00    6.9     0.00006862     -4911.5052569032 -3.27E-04
    31 Broy./Diag. 0.40E+00    7.8     0.00003475     -4911.5051820802  7.48E-05
    32 Broy./Diag. 0.40E+00    7.3     0.00002620     -4911.5050919418  9.01E-05
    33 Broy./Diag. 0.40E+00    7.1     0.00003718     -4911.5050665975  2.53E-05
    34 Broy./Diag. 0.40E+00    6.9     0.00002716     -4911.5050345797  3.20E-05
    35 Broy./Diag. 0.40E+00    7.7     0.00004363     -4911.5051640877 -1.30E-04
    36 Broy./Diag. 0.40E+00    6.9     0.00004732     -4911.5049272707  2.37E-04
    37 Broy./Diag. 0.40E+00    7.0     0.00002632     -4911.5049828779 -5.56E-05
    38 Broy./Diag. 0.40E+00    7.3     0.00002632     -4911.5050159628 -3.31E-05
    39 Broy./Diag. 0.40E+00    7.0     0.00002263     -4911.5049593280  5.66E-05
    40 Broy./Diag. 0.40E+00    7.1     0.00001448     -4911.5049914363 -3.21E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00001568     -4911.5049257795  6.57E-05
    42 Broy./Diag. 0.40E+00    7.5     0.00002221     -4911.5049787394 -5.30E-05
    43 Broy./Diag. 0.40E+00    7.1     0.00001331     -4911.5049357662  4.30E-05
    44 Broy./Diag. 0.40E+00    6.9     0.00001588     -4911.5049068124  2.90E-05
    45 Broy./Diag. 0.40E+00    7.2     0.00001482     -4911.5049367139 -2.99E-05
    46 Broy./Diag. 0.40E+00    7.1     0.00001287     -4911.5048991579  3.76E-05
    47 Broy./Diag. 0.40E+00    7.3     0.00001002     -4911.5049223276 -2.32E-05
    48 Broy./Diag. 0.40E+00    7.1     0.00001440     -4911.5048748900  4.74E-05
    49 Broy./Diag. 0.40E+00    7.3     0.00000830     -4911.5049078598 -3.30E-05
    50 Broy./Diag. 0.40E+00    7.3     0.00000737     -4911.5049007836  7.08E-06
    51 Broy./Diag. 0.40E+00    6.9     0.00000589     -4911.5048773360  2.34E-05
    52 Broy./Diag. 0.40E+00    7.4     0.00000576     -4911.5048861914 -8.86E-06
    53 Broy./Diag. 0.40E+00    7.5     0.00000520     -4911.5048756908  1.05E-05
    54 Broy./Diag. 0.40E+00    7.3     0.00000932     -4911.5048906665 -1.50E-05
    55 Broy./Diag. 0.40E+00    7.1     0.00000663     -4911.5048588879  3.18E-05
    56 Broy./Diag. 0.40E+00    7.2     0.00000565     -4911.5048622977 -3.41E-06
    57 Broy./Diag. 0.40E+00    7.1     0.00000411     -4911.5048799336 -1.76E-05
    58 Broy./Diag. 0.40E+00    7.3     0.00000331     -4911.5048636597  1.63E-05
    59 Broy./Diag. 0.40E+00    7.3     0.00000239     -4911.5048661605 -2.50E-06
    60 Broy./Diag. 0.40E+00    7.0     0.00000405     -4911.5048554247  1.07E-05
    61 Broy./Diag. 0.40E+00    7.6     0.00000365     -4911.5048662942 -1.09E-05
    62 Broy./Diag. 0.40E+00    7.1     0.00000246     -4911.5048615935  4.70E-06
    63 Broy./Diag. 0.40E+00    7.1     0.00000262     -4911.5048488689  1.27E-05
    64 Broy./Diag. 0.40E+00    7.3     0.00000247     -4911.5048570817 -8.21E-06
    65 Broy./Diag. 0.40E+00    7.3     0.00000229     -4911.5048536860  3.40E-06
    66 Broy./Diag. 0.40E+00    7.1     0.00000272     -4911.5048589977 -5.31E-06
    67 Broy./Diag. 0.40E+00    6.9     0.00000227     -4911.5048478456  1.12E-05
    68 Broy./Diag. 0.40E+00    6.9     0.00000139     -4911.5048505193 -2.67E-06
    69 Broy./Diag. 0.40E+00    7.1     0.00000130     -4911.5048544238 -3.90E-06
    70 Broy./Diag. 0.40E+00    6.9     0.00000127     -4911.5048484056  6.02E-06
    71 Broy./Diag. 0.40E+00    7.1     0.00000149     -4911.5048485725 -1.67E-07
    72 Broy./Diag. 0.40E+00    7.0     0.00000177     -4911.5048451723  3.40E-06
    73 Broy./Diag. 0.40E+00    7.3     0.00000177     -4911.5048508481 -5.68E-06
    74 Broy./Diag. 0.40E+00    7.3     0.00000117     -4911.5048473704  3.48E-06
    75 Broy./Diag. 0.40E+00    7.1     0.00000093     -4911.5048435135  3.86E-06

  *** SCF run converged in    75 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008301210060
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.54924454942375
  Hartree energy:                                            1781.63435626711407
  Exchange-correlation energy:                               -779.35958479534008
  Electronic entropic energy:                                  -0.23852005938410
  Fermi energy:                                                 0.08659919264592

  Total energy:                                             -4911.50484351354044

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.504839721887947

 MD| ***************************************************************************
 MD| Step number                                                            1220
 MD| Time [fs]                                                       2440.000000
 MD| Conserved quantity [hartree]                            -0.491120607443E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    554.535792           592.082116
 MD| Energy drift per atom [K]           0.235618202151E+03   0.268853339997E+03
 MD| Potential energy [hartree]         -0.491150483972E+04  -0.491156311272E+04
 MD| Kinetic energy [hartree]            0.298765289108E+00   0.373031312989E+00
 MD| Temperature [K]                             796.139274           994.040772
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02436391     -4911.4997918255 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.05966187     -4911.6666614245 -1.67E-01
     3 Broy./Diag. 0.40E+00    7.3     0.05084357     -4911.2128421777  4.54E-01
     4 Broy./Diag. 0.40E+00    7.3     0.03476363     -4911.5816540161 -3.69E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01882580     -4911.5098989890  7.18E-02
     6 Broy./Diag. 0.40E+00    7.1     0.00326636     -4911.4992910619  1.06E-02
     7 Broy./Diag. 0.40E+00    6.5     0.00352119     -4911.5056841916 -6.39E-03
     8 Broy./Diag. 0.40E+00    6.9     0.00257572     -4911.5040800395  1.60E-03
     9 Broy./Diag. 0.40E+00    6.9     0.00132917     -4911.5084433488 -4.36E-03
    10 Broy./Diag. 0.40E+00    7.7     0.00135175     -4911.4990145746  9.43E-03
    11 Broy./Diag. 0.40E+00    7.3     0.00128834     -4911.5057650395 -6.75E-03
    12 Broy./Diag. 0.40E+00    6.9     0.00058952     -4911.5043502706  1.41E-03
    13 Broy./Diag. 0.40E+00    8.0     0.00025823     -4911.5030287846  1.32E-03
    14 Broy./Diag. 0.40E+00    7.3     0.00031647     -4911.5030392436 -1.05E-05
    15 Broy./Diag. 0.40E+00    7.3     0.00021807     -4911.5028692398  1.70E-04
    16 Broy./Diag. 0.40E+00    7.3     0.00031951     -4911.5040818275 -1.21E-03
    17 Broy./Diag. 0.40E+00    6.8     0.00037005     -4911.5017464520  2.34E-03
    18 Broy./Diag. 0.40E+00    7.7     0.00028954     -4911.5023063281 -5.60E-04
    19 Broy./Diag. 0.40E+00    6.9     0.00015559     -4911.5027409200 -4.35E-04
    20 Broy./Diag. 0.40E+00    7.1     0.00018970     -4911.5021392519  6.02E-04
    21 Broy./Diag. 0.40E+00    7.9     0.00011289     -4911.5023825376 -2.43E-04
    22 Broy./Diag. 0.40E+00    6.9     0.00012866     -4911.5016392332  7.43E-04
    23 Broy./Diag. 0.40E+00    6.7     0.00016468     -4911.5024823280 -8.43E-04
    24 Broy./Diag. 0.40E+00    6.9     0.00011543     -4911.5020510796  4.31E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00006059     -4911.5016825528  3.69E-04
    26 Broy./Diag. 0.40E+00    7.6     0.00010998     -4911.5017994714 -1.17E-04
    27 Broy./Diag. 0.40E+00    7.3     0.00008767     -4911.5017123282  8.71E-05
    28 Broy./Diag. 0.40E+00    7.1     0.00006891     -4911.5019482774 -2.36E-04
    29 Broy./Diag. 0.40E+00    7.1     0.00009066     -4911.5013593080  5.89E-04
    30 Broy./Diag. 0.40E+00    7.2     0.00006135     -4911.5016017564 -2.42E-04
    31 Broy./Diag. 0.40E+00    7.1     0.00003775     -4911.5016735655 -7.18E-05
    32 Broy./Diag. 0.40E+00    7.1     0.00003546     -4911.5015709037  1.03E-04
    33 Broy./Diag. 0.40E+00    7.3     0.00003368     -4911.5015179009  5.30E-05
    34 Broy./Diag. 0.40E+00    7.2     0.00003505     -4911.5014335539  8.43E-05
    35 Broy./Diag. 0.40E+00    6.9     0.00005663     -4911.5016737376 -2.40E-04
    36 Broy./Diag. 0.40E+00    7.3     0.00004451     -4911.5014338880  2.40E-04
    37 Broy./Diag. 0.40E+00    7.2     0.00003333     -4911.5013572368  7.67E-05
    38 Broy./Diag. 0.40E+00    7.6     0.00002390     -4911.5014344382 -7.72E-05
    39 Broy./Diag. 0.40E+00    6.8     0.00002232     -4911.5014107047  2.37E-05
    40 Broy./Diag. 0.40E+00    6.9     0.00001478     -4911.5014695748 -5.89E-05
    41 Broy./Diag. 0.40E+00    6.9     0.00002199     -4911.5013308138  1.39E-04
    42 Broy./Diag. 0.40E+00    7.9     0.00002221     -4911.5014133475 -8.25E-05
    43 Broy./Diag. 0.40E+00    7.1     0.00001561     -4911.5014222261 -8.88E-06
    44 Broy./Diag. 0.40E+00    7.5     0.00001164     -4911.5013528708  6.94E-05
    45 Broy./Diag. 0.40E+00    7.1     0.00001384     -4911.5013516901  1.18E-06
    46 Broy./Diag. 0.40E+00    7.5     0.00001129     -4911.5013217729  2.99E-05
    47 Broy./Diag. 0.40E+00    7.3     0.00001408     -4911.5013958165 -7.40E-05
    48 Broy./Diag. 0.40E+00    6.9     0.00001327     -4911.5013220451  7.38E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00000723     -4911.5013236051 -1.56E-06
    50 Broy./Diag. 0.40E+00    7.2     0.00000613     -4911.5013425880 -1.90E-05
    51 Broy./Diag. 0.40E+00    7.1     0.00000603     -4911.5013269469  1.56E-05
    52 Broy./Diag. 0.40E+00    6.9     0.00000587     -4911.5013330617 -6.11E-06
    53 Broy./Diag. 0.40E+00    7.1     0.00000793     -4911.5013003290  3.27E-05
    54 Broy./Diag. 0.40E+00    7.4     0.00000986     -4911.5013311833 -3.09E-05
    55 Broy./Diag. 0.40E+00    7.1     0.00000515     -4911.5013176449  1.35E-05
    56 Broy./Diag. 0.40E+00    7.0     0.00000508     -4911.5012986421  1.90E-05
    57 Broy./Diag. 0.40E+00    7.2     0.00000386     -4911.5013117723 -1.31E-05
    58 Broy./Diag. 0.40E+00    7.1     0.00000386     -4911.5012995043  1.23E-05
    59 Broy./Diag. 0.40E+00    7.3     0.00000387     -4911.5013132559 -1.38E-05
    60 Broy./Diag. 0.40E+00    7.4     0.00000456     -4911.5012939350  1.93E-05
    61 Broy./Diag. 0.40E+00    7.3     0.00000303     -4911.5012994918 -5.56E-06
    62 Broy./Diag. 0.40E+00    6.9     0.00000335     -4911.5013036454 -4.15E-06
    63 Broy./Diag. 0.40E+00    7.4     0.00000278     -4911.5012911007  1.25E-05
    64 Broy./Diag. 0.40E+00    7.5     0.00000289     -4911.5012953174 -4.22E-06
    65 Broy./Diag. 0.40E+00    7.1     0.00000286     -4911.5012866676  8.65E-06
    66 Broy./Diag. 0.40E+00    7.2     0.00000308     -4911.5012975571 -1.09E-05
    67 Broy./Diag. 0.40E+00    7.3     0.00000185     -4911.5012890197  8.54E-06
    68 Broy./Diag. 0.40E+00    7.0     0.00000184     -4911.5012861137  2.91E-06
    69 Broy./Diag. 0.40E+00    7.2     0.00000156     -4911.5012915507 -5.44E-06
    70 Broy./Diag. 0.40E+00    7.4     0.00000166     -4911.5012863716  5.18E-06
    71 Broy./Diag. 0.40E+00    7.5     0.00000169     -4911.5012886643 -2.29E-06
    72 Broy./Diag. 0.40E+00    7.1     0.00000208     -4911.5012811025  7.56E-06
    73 Broy./Diag. 0.40E+00    7.5     0.00000146     -4911.5012860558 -4.95E-06
    74 Broy./Diag. 0.40E+00    6.6     0.00000130     -4911.5012867706 -7.15E-07
    75 Broy./Diag. 0.40E+00    7.1     0.00000102     -4911.5012808489  5.92E-06
    76 Broy./Diag. 0.40E+00    6.7     0.00000095     -4911.5012837520 -2.90E-06

  *** SCF run converged in    76 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008314378839
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.60329960588297
  Hartree energy:                                            1781.60139892937173
  Exchange-correlation energy:                               -779.37711860372860
  Electronic entropic energy:                                  -0.23852430752986
  Fermi energy:                                                 0.08668777924340

  Total energy:                                             -4911.50128375202985

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.501275848291698

 MD| ***************************************************************************
 MD| Step number                                                            1221
 MD| Time [fs]                                                       2442.000000
 MD| Conserved quantity [hartree]                            -0.491122271227E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    554.697867           592.051499
 MD| Energy drift per atom [K]           0.201053674435E+03   0.268797812016E+03
 MD| Potential energy [hartree]         -0.491150127585E+04  -0.491156306207E+04
 MD| Kinetic energy [hartree]            0.278563575052E+00   0.372953943834E+00
 MD| Temperature [K]                             742.306454           993.834602
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.6     0.02450656     -4911.4977668659 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.05186247     -4911.6529637671 -1.55E-01
     3 Broy./Diag. 0.40E+00    7.3     0.04467165     -4911.2173957748  4.36E-01
     4 Broy./Diag. 0.40E+00    7.7     0.03073933     -4911.5933510437 -3.76E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01831717     -4911.4865369957  1.07E-01
     6 Broy./Diag. 0.40E+00    7.1     0.00385312     -4911.4998625243 -1.33E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00305428     -4911.5065476169 -6.69E-03
     8 Broy./Diag. 0.40E+00    6.9     0.00248917     -4911.4954252377  1.11E-02
     9 Broy./Diag. 0.40E+00    7.1     0.00102511     -4911.5047082557 -9.28E-03
    10 Broy./Diag. 0.40E+00    6.9     0.00092259     -4911.4976768297  7.03E-03
    11 Broy./Diag. 0.40E+00    7.1     0.00102788     -4911.5029285440 -5.25E-03
    12 Broy./Diag. 0.40E+00    6.9     0.00057826     -4911.5008478800  2.08E-03
    13 Broy./Diag. 0.40E+00    6.9     0.00019724     -4911.5007992032  4.87E-05
    14 Broy./Diag. 0.40E+00    7.3     0.00029618     -4911.5008322619 -3.31E-05
    15 Broy./Diag. 0.40E+00    7.7     0.00023214     -4911.5002553046  5.77E-04
    16 Broy./Diag. 0.40E+00    7.1     0.00019391     -4911.5011004282 -8.45E-04
    17 Broy./Diag. 0.40E+00    6.7     0.00030969     -4911.4997397207  1.36E-03
    18 Broy./Diag. 0.40E+00    7.3     0.00030806     -4911.5001292246 -3.90E-04
    19 Broy./Diag. 0.40E+00    8.1     0.00013078     -4911.4998687296  2.60E-04
    20 Broy./Diag. 0.40E+00    7.5     0.00016239     -4911.4998221645  4.66E-05
    21 Broy./Diag. 0.40E+00    7.3     0.00011513     -4911.5002053092 -3.83E-04
    22 Broy./Diag. 0.40E+00    7.1     0.00006626     -4911.4995059238  6.99E-04
    23 Broy./Diag. 0.40E+00    7.9     0.00011905     -4911.4998866228 -3.81E-04
    24 Broy./Diag. 0.40E+00    6.8     0.00013076     -4911.4997558869  1.31E-04
    25 Broy./Diag. 0.40E+00    7.3     0.00007611     -4911.4997130096  4.29E-05
    26 Broy./Diag. 0.40E+00    7.7     0.00008740     -4911.4994478104  2.65E-04
    27 Broy./Diag. 0.40E+00    8.1     0.00008300     -4911.4993223571  1.25E-04
    28 Broy./Diag. 0.40E+00    7.1     0.00003992     -4911.4996677054 -3.45E-04
    29 Broy./Diag. 0.40E+00    7.5     0.00005776     -4911.4993716564  2.96E-04
    30 Broy./Diag. 0.40E+00    7.1     0.00006070     -4911.4993560387  1.56E-05
    31 Broy./Diag. 0.40E+00    7.5     0.00004017     -4911.4993272584  2.88E-05
    32 Broy./Diag. 0.40E+00    7.1     0.00003171     -4911.4994732063 -1.46E-04
    33 Broy./Diag. 0.40E+00    7.1     0.00003771     -4911.4993833178  8.99E-05
    34 Broy./Diag. 0.40E+00    7.7     0.00002128     -4911.4992135153  1.70E-04
    35 Broy./Diag. 0.40E+00    6.6     0.00003633     -4911.4993475636 -1.34E-04
    36 Broy./Diag. 0.40E+00    6.9     0.00004406     -4911.4993229325  2.46E-05
    37 Broy./Diag. 0.40E+00    7.4     0.00002904     -4911.4992918952  3.10E-05
    38 Broy./Diag. 0.40E+00    6.5     0.00001653     -4911.4991713173  1.21E-04
    39 Broy./Diag. 0.40E+00    7.0     0.00002209     -4911.4992103324 -3.90E-05
    40 Broy./Diag. 0.40E+00    7.3     0.00001085     -4911.4993149675 -1.05E-04
    41 Broy./Diag. 0.40E+00    6.9     0.00001716     -4911.4992000352  1.15E-04
    42 Broy./Diag. 0.40E+00    6.9     0.00002166     -4911.4991948408  5.19E-06
    43 Broy./Diag. 0.40E+00    7.1     0.00001846     -4911.4992052436 -1.04E-05
    44 Broy./Diag. 0.40E+00    8.1     0.00001047     -4911.4992578540 -5.26E-05
    45 Broy./Diag. 0.40E+00    6.6     0.00001314     -4911.4991883985  6.95E-05
    46 Broy./Diag. 0.40E+00    7.0     0.00000845     -4911.4991290956  5.93E-05
    47 Broy./Diag. 0.40E+00    7.3     0.00001193     -4911.4991968961 -6.78E-05
    48 Broy./Diag. 0.40E+00    7.1     0.00001110     -4911.4991861827  1.07E-05
    49 Broy./Diag. 0.40E+00    7.0     0.00000831     -4911.4991720688  1.41E-05
    50 Broy./Diag. 0.40E+00    7.3     0.00000535     -4911.4991432131  2.89E-05
    51 Broy./Diag. 0.40E+00    7.3     0.00000715     -4911.4991736416 -3.04E-05
    52 Broy./Diag. 0.40E+00    7.3     0.00000589     -4911.4991920358 -1.84E-05
    53 Broy./Diag. 0.40E+00    7.1     0.00000778     -4911.4991378041  5.42E-05
    54 Broy./Diag. 0.40E+00    7.3     0.00000798     -4911.4991429093 -5.11E-06
    55 Broy./Diag. 0.40E+00    7.1     0.00000666     -4911.4991500732 -7.16E-06
    56 Broy./Diag. 0.40E+00    6.9     0.00000378     -4911.4991631886 -1.31E-05
    57 Broy./Diag. 0.40E+00    7.3     0.00000299     -4911.4991400501  2.31E-05
    58 Broy./Diag. 0.40E+00    7.5     0.00000298     -4911.4991306365  9.41E-06
    59 Broy./Diag. 0.40E+00    6.9     0.00000407     -4911.4991545943 -2.40E-05
    60 Broy./Diag. 0.40E+00    7.2     0.00000411     -4911.4991455185  9.08E-06
    61 Broy./Diag. 0.40E+00    7.1     0.00000394     -4911.4991360497  9.47E-06
    62 Broy./Diag. 0.40E+00    7.3     0.00000288     -4911.4991274669  8.58E-06
    63 Broy./Diag. 0.40E+00    7.3     0.00000263     -4911.4991427252 -1.53E-05
    64 Broy./Diag. 0.40E+00    7.1     0.00000211     -4911.4991442337 -1.51E-06
    65 Broy./Diag. 0.40E+00    7.0     0.00000193     -4911.4991264132  1.78E-05
    66 Broy./Diag. 0.40E+00    7.5     0.00000209     -4911.4991304202 -4.01E-06
    67 Broy./Diag. 0.40E+00    7.2     0.00000211     -4911.4991330557 -2.64E-06
    68 Broy./Diag. 0.40E+00    7.1     0.00000120     -4911.4991360256 -2.97E-06
    69 Broy./Diag. 0.40E+00    7.1     0.00000158     -4911.4991264923  9.53E-06
    70 Broy./Diag. 0.40E+00    7.0     0.00000147     -4911.4991253010  1.19E-06
    71 Broy./Diag. 0.40E+00    7.3     0.00000132     -4911.4991351831 -9.88E-06
    72 Broy./Diag. 0.40E+00    7.3     0.00000146     -4911.4991299017  5.28E-06
    73 Broy./Diag. 0.40E+00    7.3     0.00000144     -4911.4991267958  3.11E-06
    74 Broy./Diag. 0.40E+00    6.7     0.00000085     -4911.4991242246  2.57E-06

  *** SCF run converged in    74 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008324624567
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.64743890596856
  Hartree energy:                                            1781.57429343064041
  Exchange-correlation energy:                               -779.39195505106659
  Electronic entropic energy:                                  -0.23856227085683
  Fermi energy:                                                 0.08676318018197

  Total energy:                                             -4911.49912422458146

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.499121032792573

 MD| ***************************************************************************
 MD| Step number                                                            1222
 MD| Time [fs]                                                       2444.000000
 MD| Conserved quantity [hartree]                            -0.491120997282E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    542.893415           592.011271
 MD| Energy drift per atom [K]           0.227519439112E+03   0.268764032660E+03
 MD| Potential energy [hartree]         -0.491149912103E+04  -0.491156300975E+04
 MD| Kinetic energy [hartree]            0.289148212381E+00   0.372885363039E+00
 MD| Temperature [K]                             770.512025           993.651850
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.02483424     -4911.4966277752 -4.91E+03
     2 Broy./Diag. 0.40E+00    9.5     0.04022693     -4911.6144791785 -1.18E-01
     3 Broy./Diag. 0.40E+00    7.2     0.03457724     -4911.2877552674  3.27E-01
     4 Broy./Diag. 0.40E+00   10.5     0.02191645     -4911.5824251152 -2.95E-01
     5 Broy./Diag. 0.40E+00    9.2     0.01257534     -4911.4980776080  8.43E-02
     6 Broy./Diag. 0.40E+00    7.3     0.00461269     -4911.4926948685  5.38E-03
     7 Broy./Diag. 0.40E+00    7.0     0.00432467     -4911.5116820813 -1.90E-02
     8 Broy./Diag. 0.40E+00    7.1     0.00128789     -4911.4947582809  1.69E-02
     9 Broy./Diag. 0.40E+00    7.3     0.00145483     -4911.5038176209 -9.06E-03
    10 Broy./Diag. 0.40E+00    7.7     0.00117537     -4911.4948179498  9.00E-03
    11 Broy./Diag. 0.40E+00    6.7     0.00060550     -4911.5006889460 -5.87E-03
    12 Broy./Diag. 0.40E+00    9.8     0.00035553     -4911.4998424707  8.46E-04
    13 Broy./Diag. 0.40E+00    7.7     0.00023863     -4911.4992352006  6.07E-04
    14 Broy./Diag. 0.40E+00   10.1     0.00023972     -4911.4998220276 -5.87E-04
    15 Broy./Diag. 0.40E+00    8.5     0.00027475     -4911.4988598561  9.62E-04
    16 Broy./Diag. 0.40E+00    6.7     0.00033743     -4911.4999206331 -1.06E-03
    17 Broy./Diag. 0.40E+00    7.1     0.00024144     -4911.4985312862  1.39E-03
    18 Broy./Diag. 0.40E+00    6.7     0.00019373     -4911.4987184071 -1.87E-04
    19 Broy./Diag. 0.40E+00    8.3     0.00012596     -4911.4987147917  3.62E-06
    20 Broy./Diag. 0.40E+00    7.1     0.00014578     -4911.4984181656  2.97E-04
    21 Broy./Diag. 0.40E+00   10.4     0.00010588     -4911.4991247207 -7.07E-04
    22 Broy./Diag. 0.40E+00    7.2     0.00013474     -4911.4983082872  8.16E-04
    23 Broy./Diag. 0.40E+00    8.7     0.00010387     -4911.4987224643 -4.14E-04
    24 Broy./Diag. 0.40E+00    9.7     0.00007776     -4911.4985909970  1.31E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00005878     -4911.4984945085  9.65E-05
    26 Broy./Diag. 0.40E+00    7.3     0.00007395     -4911.4984919324  2.58E-06
    27 Broy./Diag. 0.40E+00    7.3     0.00005698     -4911.4981371695  3.55E-04
    28 Broy./Diag. 0.40E+00    7.1     0.00008181     -4911.4985454413 -4.08E-04
    29 Broy./Diag. 0.40E+00    7.5     0.00006446     -4911.4982930074  2.52E-04
    30 Broy./Diag. 0.40E+00    7.2     0.00004045     -4911.4982780061  1.50E-05
    31 Broy./Diag. 0.40E+00    6.8     0.00003364     -4911.4982783664 -3.60E-07
    32 Broy./Diag. 0.40E+00    7.6     0.00004146     -4911.4982652383  1.31E-05
    33 Broy./Diag. 0.40E+00    7.0     0.00002876     -4911.4983640318 -9.88E-05
    34 Broy./Diag. 0.40E+00    6.9     0.00004237     -4911.4981154193  2.49E-04
    35 Broy./Diag. 0.40E+00    7.5     0.00003736     -4911.4982240374 -1.09E-04
    36 Broy./Diag. 0.40E+00    7.1     0.00002547     -4911.4981968606  2.72E-05
    37 Broy./Diag. 0.40E+00    6.9     0.00002265     -4911.4981840309  1.28E-05
    38 Broy./Diag. 0.40E+00    7.1     0.00002367     -4911.4981676850  1.63E-05
    39 Broy./Diag. 0.40E+00    7.1     0.00001782     -4911.4980942669  7.34E-05
    40 Broy./Diag. 0.40E+00    7.5     0.00002663     -4911.4982417251 -1.47E-04
    41 Broy./Diag. 0.40E+00    7.1     0.00002128     -4911.4981301369  1.12E-04
    42 Broy./Diag. 0.40E+00    7.5     0.00001287     -4911.4981246284  5.51E-06
    43 Broy./Diag. 0.40E+00    6.9     0.00001295     -4911.4981234231  1.21E-06
    44 Broy./Diag. 0.40E+00    6.9     0.00001412     -4911.4981187562  4.67E-06
    45 Broy./Diag. 0.40E+00    7.7     0.00000824     -4911.4981456609 -2.69E-05
    46 Broy./Diag. 0.40E+00    7.0     0.00001306     -4911.4980666529  7.90E-05
    47 Broy./Diag. 0.40E+00    6.9     0.00001233     -4911.4981153787 -4.87E-05
    48 Broy./Diag. 0.40E+00    7.3     0.00000769     -4911.4981078626  7.52E-06
    49 Broy./Diag. 0.40E+00    8.1     0.00000801     -4911.4980973590  1.05E-05
    50 Broy./Diag. 0.40E+00    7.1     0.00000817     -4911.4980873931  9.97E-06
    51 Broy./Diag. 0.40E+00    6.7     0.00000599     -4911.4980708920  1.65E-05
    52 Broy./Diag. 0.40E+00    7.3     0.00000834     -4911.4981095409 -3.86E-05
    53 Broy./Diag. 0.40E+00    6.7     0.00000723     -4911.4980696825  3.99E-05
    54 Broy./Diag. 0.40E+00    6.8     0.00000421     -4911.4980713438 -1.66E-06
    55 Broy./Diag. 0.40E+00    7.1     0.00000442     -4911.4980727797 -1.44E-06
    56 Broy./Diag. 0.40E+00    7.5     0.00000451     -4911.4980726804  9.93E-08
    57 Broy./Diag. 0.40E+00    7.3     0.00000419     -4911.4980804106 -7.73E-06
    58 Broy./Diag. 0.40E+00    7.3     0.00000500     -4911.4980533917  2.70E-05
    59 Broy./Diag. 0.40E+00    7.1     0.00000527     -4911.4980763386 -2.29E-05
    60 Broy./Diag. 0.40E+00    6.5     0.00000306     -4911.4980696647  6.67E-06
    61 Broy./Diag. 0.40E+00    6.8     0.00000270     -4911.4980632640  6.40E-06
    62 Broy./Diag. 0.40E+00    7.3     0.00000237     -4911.4980608459  2.42E-06
    63 Broy./Diag. 0.40E+00    7.3     0.00000238     -4911.4980565235  4.32E-06
    64 Broy./Diag. 0.40E+00    7.5     0.00000254     -4911.4980678424 -1.13E-05
    65 Broy./Diag. 0.40E+00    7.1     0.00000269     -4911.4980533779  1.45E-05
    66 Broy./Diag. 0.40E+00    7.3     0.00000180     -4911.4980558772 -2.50E-06
    67 Broy./Diag. 0.40E+00    7.1     0.00000179     -4911.4980576865 -1.81E-06
    68 Broy./Diag. 0.40E+00    7.3     0.00000179     -4911.4980573283  3.58E-07
    69 Broy./Diag. 0.40E+00    7.0     0.00000169     -4911.4980576320 -3.04E-07
    70 Broy./Diag. 0.40E+00    6.9     0.00000159     -4911.4980493495  8.28E-06
    71 Broy./Diag. 0.40E+00    6.5     0.00000178     -4911.4980574658 -8.12E-06
    72 Broy./Diag. 0.40E+00    7.1     0.00000112     -4911.4980538318  3.63E-06
    73 Broy./Diag. 0.40E+00    6.7     0.00000095     -4911.4980518489  1.98E-06

  *** SCF run converged in    73 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008331519628
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.68277313797807
  Hartree energy:                                            1781.55230269647291
  Exchange-correlation energy:                               -779.40414663543288
  Electronic entropic energy:                                  -0.23864185863886
  Fermi energy:                                                 0.08682539658360

  Total energy:                                             -4911.49805184892739

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.498046055495251

 MD| ***************************************************************************
 MD| Step number                                                            1223
 MD| Time [fs]                                                       2446.000000
 MD| Conserved quantity [hartree]                            -0.491120249684E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    552.462292           591.978933
 MD| Energy drift per atom [K]           0.243050519071E+03   0.268743007710E+03
 MD| Potential energy [hartree]         -0.491149804606E+04  -0.491156295663E+04
 MD| Kinetic energy [hartree]            0.295549212555E+00   0.372822128247E+00
 MD| Temperature [K]                             787.569186           993.483344
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.02609821     -4911.4968977047 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.9     0.03784631     -4911.6029068815 -1.06E-01
     3 Broy./Diag. 0.40E+00    7.1     0.03909565     -4911.3160158303  2.87E-01
     4 Broy./Diag. 0.40E+00    6.8     0.02054062     -4911.5752596387 -2.59E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01076033     -4911.5061109452  6.91E-02
     6 Broy./Diag. 0.40E+00    6.9     0.00623704     -4911.4883314997  1.78E-02
     7 Broy./Diag. 0.40E+00    6.9     0.00484818     -4911.5131858440 -2.49E-02
     8 Broy./Diag. 0.40E+00    6.9     0.00146033     -4911.4966399296  1.65E-02
     9 Broy./Diag. 0.40E+00    7.3     0.00114871     -4911.5017696018 -5.13E-03
    10 Broy./Diag. 0.40E+00    6.7     0.00073423     -4911.4975338146  4.24E-03
    11 Broy./Diag. 0.40E+00    7.3     0.00036572     -4911.5003511775 -2.82E-03
    12 Broy./Diag. 0.40E+00    7.3     0.00034823     -4911.5004240263 -7.28E-05
    13 Broy./Diag. 0.40E+00    7.1     0.00021815     -4911.4994105328  1.01E-03
    14 Broy./Diag. 0.40E+00    7.3     0.00017922     -4911.4997678316 -3.57E-04
    15 Broy./Diag. 0.40E+00    6.9     0.00016569     -4911.4995701277  1.98E-04
    16 Broy./Diag. 0.40E+00    6.9     0.00015307     -4911.4994488787  1.21E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00013989     -4911.4992088540  2.40E-04
    18 Broy./Diag. 0.40E+00    7.1     0.00014473     -4911.4987868469  4.22E-04
    19 Broy./Diag. 0.40E+00    7.1     0.00011396     -4911.4990550605 -2.68E-04
    20 Broy./Diag. 0.40E+00    7.1     0.00009932     -4911.4989668884  8.82E-05
    21 Broy./Diag. 0.40E+00    6.9     0.00006462     -4911.4988983385  6.85E-05
    22 Broy./Diag. 0.40E+00    6.9     0.00007082     -4911.4987976084  1.01E-04
    23 Broy./Diag. 0.40E+00    6.7     0.00004512     -4911.4987532482  4.44E-05
    24 Broy./Diag. 0.40E+00    7.3     0.00004409     -4911.4988972452 -1.44E-04
    25 Broy./Diag. 0.40E+00    7.5     0.00004583     -4911.4987039986  1.93E-04
    26 Broy./Diag. 0.40E+00    7.3     0.00003944     -4911.4986932927  1.07E-05
    27 Broy./Diag. 0.40E+00    7.3     0.00004091     -4911.4986830987  1.02E-05
    28 Broy./Diag. 0.40E+00    6.7     0.00004344     -4911.4987312444 -4.81E-05
    29 Broy./Diag. 0.40E+00    6.7     0.00003341     -4911.4987122611  1.90E-05
    30 Broy./Diag. 0.40E+00    6.7     0.00002799     -4911.4985445702  1.68E-04
    31 Broy./Diag. 0.40E+00    6.7     0.00002672     -4911.4986554145 -1.11E-04
    32 Broy./Diag. 0.40E+00    7.1     0.00002230     -4911.4986503186  5.10E-06
    33 Broy./Diag. 0.40E+00    7.1     0.00002109     -4911.4986105921  3.97E-05
    34 Broy./Diag. 0.40E+00    7.9     0.00001704     -4911.4985663075  4.43E-05
    35 Broy./Diag. 0.40E+00    7.1     0.00001840     -4911.4985574083  8.90E-06
    36 Broy./Diag. 0.40E+00    7.3     0.00001653     -4911.4986430075 -8.56E-05
    37 Broy./Diag. 0.40E+00    7.7     0.00001485     -4911.4985504841  9.25E-05
    38 Broy./Diag. 0.40E+00    6.7     0.00001494     -4911.4985273145  2.32E-05
    39 Broy./Diag. 0.40E+00    7.5     0.00001702     -4911.4985527018 -2.54E-05
    40 Broy./Diag. 0.40E+00    7.3     0.00001027     -4911.4985723328 -1.96E-05
    41 Broy./Diag. 0.40E+00    7.3     0.00001040     -4911.4985509992  2.13E-05
    42 Broy./Diag. 0.40E+00    7.5     0.00000829     -4911.4984970545  5.39E-05
    43 Broy./Diag. 0.40E+00    7.8     0.00000689     -4911.4985372175 -4.02E-05
    44 Broy./Diag. 0.40E+00    7.7     0.00000725     -4911.4985377317 -5.14E-07
    45 Broy./Diag. 0.40E+00    7.2     0.00000709     -4911.4985205791  1.72E-05
    46 Broy./Diag. 0.40E+00    6.8     0.00000568     -4911.4985021438  1.84E-05
    47 Broy./Diag. 0.40E+00    7.3     0.00000739     -4911.4985112577 -9.11E-06
    48 Broy./Diag. 0.40E+00    7.1     0.00000587     -4911.4985413730 -3.01E-05
    49 Broy./Diag. 0.40E+00    6.9     0.00000459     -4911.4985014932  3.99E-05
    50 Broy./Diag. 0.40E+00    7.1     0.00000472     -4911.4984970965  4.40E-06
    51 Broy./Diag. 0.40E+00    6.8     0.00000387     -4911.4985033775 -6.28E-06
    52 Broy./Diag. 0.40E+00    6.8     0.00000326     -4911.4985101528 -6.78E-06
    53 Broy./Diag. 0.40E+00    7.2     0.00000312     -4911.4985020674  8.09E-06
    54 Broy./Diag. 0.40E+00    7.1     0.00000280     -4911.4984866222  1.54E-05
    55 Broy./Diag. 0.40E+00    7.3     0.00000268     -4911.4985030329 -1.64E-05
    56 Broy./Diag. 0.40E+00    7.1     0.00000325     -4911.4985039645 -9.32E-07
    57 Broy./Diag. 0.40E+00    7.3     0.00000255     -4911.4984944472  9.52E-06
    58 Broy./Diag. 0.40E+00    7.3     0.00000244     -4911.4984878860  6.56E-06
    59 Broy./Diag. 0.40E+00    8.0     0.00000227     -4911.4984918084 -3.92E-06
    60 Broy./Diag. 0.40E+00    7.5     0.00000159     -4911.4985000303 -8.22E-06
    61 Broy./Diag. 0.40E+00    7.5     0.00000135     -4911.4984882163  1.18E-05
    62 Broy./Diag. 0.40E+00    6.6     0.00000158     -4911.4984873070  9.09E-07
    63 Broy./Diag. 0.40E+00    7.1     0.00000154     -4911.4984898213 -2.51E-06
    64 Broy./Diag. 0.40E+00    7.3     0.00000129     -4911.4984922432 -2.42E-06
    65 Broy./Diag. 0.40E+00    7.3     0.00000128     -4911.4984879773  4.27E-06
    66 Broy./Diag. 0.40E+00    7.3     0.00000111     -4911.4984827324  5.24E-06
    67 Broy./Diag. 0.40E+00    7.1     0.00000104     -4911.4984897277 -7.00E-06
    68 Broy./Diag. 0.40E+00    7.1     0.00000116     -4911.4984885883  1.14E-06
    69 Broy./Diag. 0.40E+00    7.3     0.00000095     -4911.4984858136  2.77E-06

  *** SCF run converged in    69 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008334555239
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.71608526471209
  Hartree energy:                                            1781.53104254288701
  Exchange-correlation energy:                               -779.41650623975829
  Electronic entropic energy:                                  -0.23876820915498
  Fermi energy:                                                 0.08688912033386

  Total energy:                                             -4911.49848581357583

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.498481151180385

 MD| ***************************************************************************
 MD| Step number                                                            1224
 MD| Time [fs]                                                       2448.000000
 MD| Conserved quantity [hartree]                            -0.491118953286E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    501.714335           591.905188
 MD| Energy drift per atom [K]           0.269982737763E+03   0.268744020561E+03
 MD| Potential energy [hartree]         -0.491149848115E+04  -0.491156290395E+04
 MD| Kinetic energy [hartree]            0.308948291474E+00   0.372769943740E+00
 MD| Temperature [K]                             823.274582           993.344285
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02660120     -4911.4985770656 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.04917108     -4911.6315077778 -1.33E-01
     3 Broy./Diag. 0.40E+00    7.3     0.05741133     -4911.2706867913  3.61E-01
     4 Broy./Diag. 0.40E+00    7.3     0.02797570     -4911.6165733088 -3.46E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01180018     -4911.5190111154  9.76E-02
     6 Broy./Diag. 0.40E+00    7.2     0.00972144     -4911.4694421200  4.96E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00583695     -4911.5135548963 -4.41E-02
     8 Broy./Diag. 0.40E+00    7.1     0.00197404     -4911.5005620881  1.30E-02
     9 Broy./Diag. 0.40E+00    7.1     0.00095306     -4911.5014640271 -9.02E-04
    10 Broy./Diag. 0.40E+00    7.1     0.00071680     -4911.5014284471  3.56E-05
    11 Broy./Diag. 0.40E+00    7.4     0.00055761     -4911.5024033925 -9.75E-04
    12 Broy./Diag. 0.40E+00    7.3     0.00040007     -4911.5016468454  7.57E-04
    13 Broy./Diag. 0.40E+00    7.3     0.00028734     -4911.5006684232  9.78E-04
    14 Broy./Diag. 0.40E+00    7.1     0.00021980     -4911.5020137972 -1.35E-03
    15 Broy./Diag. 0.40E+00    7.3     0.00014347     -4911.5012332733  7.81E-04
    16 Broy./Diag. 0.40E+00    7.3     0.00019906     -4911.5006818934  5.51E-04
    17 Broy./Diag. 0.40E+00    7.5     0.00014440     -4911.5008194827 -1.38E-04
    18 Broy./Diag. 0.40E+00    7.2     0.00017657     -4911.5008288051 -9.32E-06
    19 Broy./Diag. 0.40E+00    7.1     0.00017081     -4911.5011542737 -3.25E-04
    20 Broy./Diag. 0.40E+00    7.3     0.00011262     -4911.5003290116  8.25E-04
    21 Broy./Diag. 0.40E+00    7.3     0.00006316     -4911.5006574862 -3.28E-04
    22 Broy./Diag. 0.40E+00    7.3     0.00007263     -4911.5007413280 -8.38E-05
    23 Broy./Diag. 0.40E+00    7.7     0.00004361     -4911.5006107584  1.31E-04
    24 Broy./Diag. 0.40E+00    7.2     0.00005287     -4911.5005835213  2.72E-05
    25 Broy./Diag. 0.40E+00    7.3     0.00006924     -4911.5004511894  1.32E-04
    26 Broy./Diag. 0.40E+00    7.3     0.00005397     -4911.5007090738 -2.58E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00003721     -4911.5004967916  2.12E-04
    28 Broy./Diag. 0.40E+00    7.1     0.00004634     -4911.5004422936  5.45E-05
    29 Broy./Diag. 0.40E+00    7.1     0.00003568     -4911.5005189917 -7.67E-05
    30 Broy./Diag. 0.40E+00    7.3     0.00002900     -4911.5004739304  4.51E-05
    31 Broy./Diag. 0.40E+00    7.1     0.00003353     -4911.5005125420 -3.86E-05
    32 Broy./Diag. 0.40E+00    7.1     0.00002800     -4911.5003858966  1.27E-04
    33 Broy./Diag. 0.40E+00    6.9     0.00001777     -4911.5004626185 -7.67E-05
    34 Broy./Diag. 0.40E+00    7.5     0.00002083     -4911.5004443165  1.83E-05
    35 Broy./Diag. 0.40E+00    7.5     0.00002213     -4911.5003858967  5.84E-05
    36 Broy./Diag. 0.40E+00    7.3     0.00001914     -4911.5004285385 -4.26E-05
    37 Broy./Diag. 0.40E+00    7.5     0.00002271     -4911.5003672610  6.13E-05
    38 Broy./Diag. 0.40E+00    7.3     0.00001976     -4911.5004280449 -6.08E-05
    39 Broy./Diag. 0.40E+00    7.5     0.00001171     -4911.5003742991  5.37E-05
    40 Broy./Diag. 0.40E+00    7.3     0.00001016     -4911.5003728473  1.45E-06
    41 Broy./Diag. 0.40E+00    7.2     0.00001079     -4911.5003852477 -1.24E-05
    42 Broy./Diag. 0.40E+00    7.3     0.00000883     -4911.5003556503  2.96E-05
    43 Broy./Diag. 0.40E+00    7.3     0.00001082     -4911.5003774914 -2.18E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00001164     -4911.5003424405  3.51E-05
    45 Broy./Diag. 0.40E+00    6.9     0.00000803     -4911.5003637739 -2.13E-05
    46 Broy./Diag. 0.40E+00    7.1     0.00000681     -4911.5003518876  1.19E-05
    47 Broy./Diag. 0.40E+00    8.1     0.00000755     -4911.5003405791  1.13E-05
    48 Broy./Diag. 0.40E+00    7.3     0.00000587     -4911.5003562884 -1.57E-05
    49 Broy./Diag. 0.40E+00    7.3     0.00000603     -4911.5003325712  2.37E-05
    50 Broy./Diag. 0.40E+00    6.7     0.00000557     -4911.5003456198 -1.30E-05
    51 Broy./Diag. 0.40E+00    7.3     0.00000422     -4911.5003338420  1.18E-05
    52 Broy./Diag. 0.40E+00    7.5     0.00000357     -4911.5003353973 -1.56E-06
    53 Broy./Diag. 0.40E+00    7.5     0.00000418     -4911.5003364596 -1.06E-06
    54 Broy./Diag. 0.40E+00    7.1     0.00000375     -4911.5003232388  1.32E-05
    55 Broy./Diag. 0.40E+00    7.8     0.00000454     -4911.5003391592 -1.59E-05
    56 Broy./Diag. 0.40E+00    7.1     0.00000387     -4911.5003252564  1.39E-05
    57 Broy./Diag. 0.40E+00    7.1     0.00000272     -4911.5003280218 -2.77E-06
    58 Broy./Diag. 0.40E+00    7.5     0.00000199     -4911.5003249076  3.11E-06
    59 Broy./Diag. 0.40E+00    7.3     0.00000228     -4911.5003237953  1.11E-06
    60 Broy./Diag. 0.40E+00    7.1     0.00000177     -4911.5003273831 -3.59E-06
    61 Broy./Diag. 0.40E+00    7.3     0.00000235     -4911.5003171202  1.03E-05
    62 Broy./Diag. 0.40E+00    7.7     0.00000218     -4911.5003231660 -6.05E-06
    63 Broy./Diag. 0.40E+00    7.1     0.00000176     -4911.5003205669  2.60E-06
    64 Broy./Diag. 0.40E+00    7.5     0.00000121     -4911.5003206996 -1.33E-07
    65 Broy./Diag. 0.40E+00    7.5     0.00000156     -4911.5003188363  1.86E-06
    66 Broy./Diag. 0.40E+00    7.1     0.00000111     -4911.5003158357  3.00E-06
    67 Broy./Diag. 0.40E+00    7.1     0.00000149     -4911.5003217984 -5.96E-06
    68 Broy./Diag. 0.40E+00    7.1     0.00000123     -4911.5003164712  5.33E-06
    69 Broy./Diag. 0.40E+00    7.1     0.00000093     -4911.5003165025 -3.13E-08

  *** SCF run converged in    69 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008335094018
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.74893137479194
  Hartree energy:                                            1781.50976285042179
  Exchange-correlation energy:                               -779.42976951905439
  Electronic entropic energy:                                  -0.23890205090443
  Fermi energy:                                                 0.08695758817032

  Total energy:                                             -4911.50031650251731

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.500311248362777

 MD| ***************************************************************************
 MD| Step number                                                            1225
 MD| Time [fs]                                                       2450.000000
 MD| Conserved quantity [hartree]                            -0.491119274593E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    509.865300           591.838217
 MD| Energy drift per atom [K]           0.263307704354E+03   0.268739582752E+03
 MD| Potential energy [hartree]         -0.491150031125E+04  -0.491156285286E+04
 MD| Kinetic energy [hartree]            0.307565321727E+00   0.372716715477E+00
 MD| Temperature [K]                             819.589293           993.202444
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.7     0.02667053     -4911.5006726605 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.8     0.06105066     -4911.6377094069 -1.37E-01
     3 Broy./Diag. 0.40E+00    7.3     0.06352240     -4911.2608665193  3.77E-01
     4 Broy./Diag. 0.40E+00    7.2     0.02726216     -4911.5927660085 -3.32E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01738658     -4911.5422032458  5.06E-02
     6 Broy./Diag. 0.40E+00    7.1     0.00837529     -4911.4710961178  7.11E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00304611     -4911.5025321960 -3.14E-02
     8 Broy./Diag. 0.40E+00    7.5     0.00214890     -4911.5127758542 -1.02E-02
     9 Broy./Diag. 0.40E+00    7.1     0.00144365     -4911.4998972440  1.29E-02
    10 Broy./Diag. 0.40E+00    6.9     0.00152311     -4911.5024290860 -2.53E-03
    11 Broy./Diag. 0.40E+00    7.5     0.00128751     -4911.5074698935 -5.04E-03
    12 Broy./Diag. 0.40E+00    7.1     0.00081177     -4911.5067756837  6.94E-04
    13 Broy./Diag. 0.40E+00    7.1     0.00033085     -4911.5024794202  4.30E-03
    14 Broy./Diag. 0.40E+00    6.9     0.00022199     -4911.5028026962 -3.23E-04
    15 Broy./Diag. 0.40E+00    7.1     0.00023706     -4911.5043254843 -1.52E-03
    16 Broy./Diag. 0.40E+00    6.8     0.00027169     -4911.5034490843  8.76E-04
    17 Broy./Diag. 0.40E+00    6.7     0.00026206     -4911.5027311347  7.18E-04
    18 Broy./Diag. 0.40E+00    7.3     0.00033827     -4911.5031181217 -3.87E-04
    19 Broy./Diag. 0.40E+00    6.9     0.00024339     -4911.5045262834 -1.41E-03
    20 Broy./Diag. 0.40E+00    7.3     0.00012097     -4911.5032412802  1.29E-03
    21 Broy./Diag. 0.40E+00    7.3     0.00012182     -4911.5025441034  6.97E-04
    22 Broy./Diag. 0.40E+00    6.9     0.00011536     -4911.5029582285 -4.14E-04
    23 Broy./Diag. 0.40E+00    7.4     0.00011910     -4911.5031125651 -1.54E-04
    24 Broy./Diag. 0.40E+00    7.1     0.00010011     -4911.5029722892  1.40E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00010292     -4911.5025476716  4.25E-04
    26 Broy./Diag. 0.40E+00    7.3     0.00007327     -4911.5029641827 -4.17E-04
    27 Broy./Diag. 0.40E+00    6.9     0.00008080     -4911.5031708107 -2.07E-04
    28 Broy./Diag. 0.40E+00    7.1     0.00007119     -4911.5027120340  4.59E-04
    29 Broy./Diag. 0.40E+00    7.1     0.00007576     -4911.5026615923  5.04E-05
    30 Broy./Diag. 0.40E+00    7.1     0.00005794     -4911.5026968116 -3.52E-05
    31 Broy./Diag. 0.40E+00    7.1     0.00004502     -4911.5028139237 -1.17E-04
    32 Broy./Diag. 0.40E+00    7.7     0.00002328     -4911.5026696223  1.44E-04
    33 Broy./Diag. 0.40E+00    7.8     0.00003009     -4911.5026087072  6.09E-05
    34 Broy./Diag. 0.40E+00    7.7     0.00003553     -4911.5027301500 -1.21E-04
    35 Broy./Diag. 0.40E+00    9.7     0.00004322     -4911.5026617762  6.84E-05
    36 Broy./Diag. 0.40E+00    7.5     0.00003760     -4911.5026356392  2.61E-05
    37 Broy./Diag. 0.40E+00   11.2     0.00003550     -4911.5025725110  6.31E-05
    38 Broy./Diag. 0.40E+00    7.5     0.00002064     -4911.5026364894 -6.40E-05
    39 Broy./Diag. 0.40E+00    7.1     0.00002280     -4911.5026015861  3.49E-05
    40 Broy./Diag. 0.40E+00    7.3     0.00001733     -4911.5025568868  4.47E-05
    41 Broy./Diag. 0.40E+00    6.9     0.00001660     -4911.5025944339 -3.75E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00001630     -4911.5025551530  3.93E-05
    43 Broy./Diag. 0.40E+00    8.5     0.00001278     -4911.5025720799 -1.69E-05
    44 Broy./Diag. 0.40E+00    7.0     0.00001196     -4911.5025445125  2.76E-05
    45 Broy./Diag. 0.40E+00   10.3     0.00001742     -4911.5025529378 -8.43E-06
    46 Broy./Diag. 0.40E+00    7.4     0.00001421     -4911.5025593080 -6.37E-06
    47 Broy./Diag. 0.40E+00   10.9     0.00001318     -4911.5025064222  5.29E-05
    48 Broy./Diag. 0.40E+00    7.7     0.00001033     -4911.5025371309 -3.07E-05
    49 Broy./Diag. 0.40E+00    6.9     0.00000700     -4911.5025341783  2.95E-06
    50 Broy./Diag. 0.40E+00    7.5     0.00000591     -4911.5025279518  6.23E-06
    51 Broy./Diag. 0.40E+00    7.5     0.00000685     -4911.5025138139  1.41E-05
    52 Broy./Diag. 0.40E+00    7.3     0.00000619     -4911.5025141293 -3.15E-07
    53 Broy./Diag. 0.40E+00    6.7     0.00000760     -4911.5025326430 -1.85E-05
    54 Broy./Diag. 0.40E+00    9.9     0.00000678     -4911.5025049826  2.77E-05
    55 Broy./Diag. 0.40E+00    6.7     0.00000543     -4911.5024983943  6.59E-06
    56 Broy./Diag. 0.40E+00   10.3     0.00000546     -4911.5025033068 -4.91E-06
    57 Broy./Diag. 0.40E+00    8.7     0.00000493     -4911.5025164021 -1.31E-05
    58 Broy./Diag. 0.40E+00    7.3     0.00000321     -4911.5025047714  1.16E-05
    59 Broy./Diag. 0.40E+00    7.5     0.00000380     -4911.5024917071  1.31E-05
    60 Broy./Diag. 0.40E+00    6.9     0.00000303     -4911.5025040135 -1.23E-05
    61 Broy./Diag. 0.40E+00    7.3     0.00000274     -4911.5025032325  7.81E-07
    62 Broy./Diag. 0.40E+00    6.9     0.00000327     -4911.5024978611  5.37E-06
    63 Broy./Diag. 0.40E+00    7.1     0.00000325     -4911.5024868425  1.10E-05
    64 Broy./Diag. 0.40E+00    6.7     0.00000236     -4911.5024943666 -7.52E-06
    65 Broy./Diag. 0.40E+00    8.0     0.00000303     -4911.5025029170 -8.55E-06
    66 Broy./Diag. 0.40E+00    7.5     0.00000204     -4911.5024908581  1.21E-05
    67 Broy./Diag. 0.40E+00    7.3     0.00000159     -4911.5024884134  2.44E-06
    68 Broy./Diag. 0.40E+00    7.1     0.00000183     -4911.5024909703 -2.56E-06
    69 Broy./Diag. 0.40E+00    6.9     0.00000160     -4911.5024952555 -4.29E-06
    70 Broy./Diag. 0.40E+00    7.1     0.00000114     -4911.5024890929  6.16E-06
    71 Broy./Diag. 0.40E+00    7.5     0.00000177     -4911.5024842675  4.83E-06
    72 Broy./Diag. 0.40E+00    7.1     0.00000147     -4911.5024904248 -6.16E-06
    73 Broy./Diag. 0.40E+00    7.1     0.00000116     -4911.5024908427 -4.18E-07
    74 Broy./Diag. 0.40E+00    7.5     0.00000127     -4911.5024880889  2.75E-06
    75 Broy./Diag. 0.40E+00    7.1     0.00000108     -4911.5024840391  4.05E-06
    76 Broy./Diag. 0.40E+00    7.1     0.00000072     -4911.5024876712 -3.63E-06

  *** SCF run converged in    76 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008335047513
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.78392221822196
  Hartree energy:                                            1781.48718133154307
  Exchange-correlation energy:                               -779.44422547588692
  Electronic entropic energy:                                  -0.23902660053813
  Fermi energy:                                                 0.08702944291308

  Total energy:                                             -4911.50248767119592

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.502482092616447

 MD| ***************************************************************************
 MD| Step number                                                            1226
 MD| Time [fs]                                                       2452.000000
 MD| Conserved quantity [hartree]                            -0.491118522114E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    578.325938           591.827195
 MD| Energy drift per atom [K]           0.278940191869E+03   0.268747902988E+03
 MD| Potential energy [hartree]         -0.491150248209E+04  -0.491156280362E+04
 MD| Kinetic energy [hartree]            0.317260956581E+00   0.372671482395E+00
 MD| Temperature [K]                             845.425881           993.081908
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.02806079     -4911.5029007694 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.07505127     -4911.6478630992 -1.45E-01
     3 Broy./Diag. 0.40E+00    7.1     0.06986027     -4911.2235105655  4.24E-01
     4 Broy./Diag. 0.40E+00    6.9     0.03304868     -4911.5810833054 -3.58E-01
     5 Broy./Diag. 0.40E+00    8.0     0.01709148     -4911.5560242059  2.51E-02
     6 Broy./Diag. 0.40E+00    7.1     0.00621362     -4911.4822684587  7.38E-02
     7 Broy./Diag. 0.40E+00    6.7     0.00274492     -4911.4985339418 -1.63E-02
     8 Broy./Diag. 0.40E+00    6.9     0.00232874     -4911.5195994639 -2.11E-02
     9 Broy./Diag. 0.40E+00    7.5     0.00206452     -4911.5016921687  1.79E-02
    10 Broy./Diag. 0.40E+00    6.9     0.00178852     -4911.5032296932 -1.54E-03
    11 Broy./Diag. 0.40E+00    7.3     0.00137835     -4911.5087693779 -5.54E-03
    12 Broy./Diag. 0.40E+00    7.9     0.00071156     -4911.5092564918 -4.87E-04
    13 Broy./Diag. 0.40E+00    7.4     0.00032471     -4911.5050659870  4.19E-03
    14 Broy./Diag. 0.40E+00    7.0     0.00023571     -4911.5043900236  6.76E-04
    15 Broy./Diag. 0.40E+00    7.1     0.00026922     -4911.5064559307 -2.07E-03
    16 Broy./Diag. 0.40E+00    7.3     0.00031806     -4911.5056784777  7.77E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00026822     -4911.5048296137  8.49E-04
    18 Broy./Diag. 0.40E+00    7.1     0.00025003     -4911.5050669195 -2.37E-04
    19 Broy./Diag. 0.40E+00    7.5     0.00024549     -4911.5063559958 -1.29E-03
    20 Broy./Diag. 0.40E+00    6.9     0.00012317     -4911.5056145720  7.41E-04
    21 Broy./Diag. 0.40E+00    7.5     0.00013505     -4911.5046517437  9.63E-04
    22 Broy./Diag. 0.40E+00    7.2     0.00012460     -4911.5051041884 -4.52E-04
    23 Broy./Diag. 0.40E+00    7.3     0.00011289     -4911.5052716248 -1.67E-04
    24 Broy./Diag. 0.40E+00    7.2     0.00008362     -4911.5051889327  8.27E-05
    25 Broy./Diag. 0.40E+00    7.5     0.00010621     -4911.5047712304  4.18E-04
    26 Broy./Diag. 0.40E+00    7.3     0.00007077     -4911.5050268209 -2.56E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00009089     -4911.5054758002 -4.49E-04
    28 Broy./Diag. 0.40E+00    6.9     0.00008216     -4911.5049437179  5.32E-04
    29 Broy./Diag. 0.40E+00    7.1     0.00007379     -4911.5048529137  9.08E-05
    30 Broy./Diag. 0.40E+00    6.9     0.00005012     -4911.5049009536 -4.80E-05
    31 Broy./Diag. 0.40E+00    7.1     0.00005113     -4911.5050306343 -1.30E-04
    32 Broy./Diag. 0.40E+00    7.1     0.00002036     -4911.5049165939  1.14E-04
    33 Broy./Diag. 0.40E+00    6.7     0.00003432     -4911.5047860820  1.31E-04
    34 Broy./Diag. 0.40E+00    7.2     0.00004080     -4911.5049564797 -1.70E-04
    35 Broy./Diag. 0.40E+00    7.3     0.00004102     -4911.5049174489  3.90E-05
    36 Broy./Diag. 0.40E+00    7.7     0.00003246     -4911.5048676699  4.98E-05
    37 Broy./Diag. 0.40E+00    7.0     0.00004012     -4911.5047938323  7.38E-05
    38 Broy./Diag. 0.40E+00    7.1     0.00001766     -4911.5048531059 -5.93E-05
    39 Broy./Diag. 0.40E+00    7.7     0.00002104     -4911.5048758397 -2.27E-05
    40 Broy./Diag. 0.40E+00    7.1     0.00002205     -4911.5047823233  9.35E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00001708     -4911.5048115813 -2.93E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00001415     -4911.5047979736  1.36E-05
    43 Broy./Diag. 0.40E+00    7.1     0.00001570     -4911.5048147156 -1.67E-05
    44 Broy./Diag. 0.40E+00    7.3     0.00001049     -4911.5047860480  2.87E-05
    45 Broy./Diag. 0.40E+00    7.5     0.00001379     -4911.5047694735  1.66E-05
    46 Broy./Diag. 0.40E+00    6.9     0.00001847     -4911.5048185966 -4.91E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00001348     -4911.5047631780  5.54E-05
    48 Broy./Diag. 0.40E+00    7.1     0.00000970     -4911.5047740274 -1.08E-05
    49 Broy./Diag. 0.40E+00    6.8     0.00000828     -4911.5047708486  3.18E-06
    50 Broy./Diag. 0.40E+00    6.7     0.00000567     -4911.5047689882  1.86E-06
    51 Broy./Diag. 0.40E+00    7.1     0.00000530     -4911.5047655992  3.39E-06
    52 Broy./Diag. 0.40E+00    7.3     0.00000822     -4911.5047502401  1.54E-05
    53 Broy./Diag. 0.40E+00    7.3     0.00000767     -4911.5047718486 -2.16E-05
    54 Broy./Diag. 0.40E+00    7.7     0.00000605     -4911.5047538646  1.80E-05
    55 Broy./Diag. 0.40E+00    7.2     0.00000508     -4911.5047477249  6.14E-06
    56 Broy./Diag. 0.40E+00    7.5     0.00000513     -4911.5047487846 -1.06E-06
    57 Broy./Diag. 0.40E+00    7.1     0.00000436     -4911.5047530309 -4.25E-06
    58 Broy./Diag. 0.40E+00    7.3     0.00000474     -4911.5047544425 -1.41E-06
    59 Broy./Diag. 0.40E+00    7.5     0.00000407     -4911.5047370416  1.74E-05
    60 Broy./Diag. 0.40E+00    7.1     0.00000282     -4911.5047469228 -9.88E-06
    61 Broy./Diag. 0.40E+00    7.3     0.00000233     -4911.5047479796 -1.06E-06
    62 Broy./Diag. 0.40E+00    7.3     0.00000313     -4911.5047428509  5.13E-06
    63 Broy./Diag. 0.40E+00    8.1     0.00000280     -4911.5047363053  6.55E-06
    64 Broy./Diag. 0.40E+00    7.5     0.00000346     -4911.5047364935 -1.88E-07
    65 Broy./Diag. 0.40E+00    7.7     0.00000332     -4911.5047483644 -1.19E-05
    66 Broy./Diag. 0.40E+00    7.5     0.00000199     -4911.5047372667  1.11E-05
    67 Broy./Diag. 0.40E+00    7.1     0.00000152     -4911.5047337860  3.48E-06
    68 Broy./Diag. 0.40E+00    7.1     0.00000194     -4911.5047366525 -2.87E-06
    69 Broy./Diag. 0.40E+00    7.4     0.00000149     -4911.5047395405 -2.89E-06
    70 Broy./Diag. 0.40E+00    7.3     0.00000162     -4911.5047367561  2.78E-06
    71 Broy./Diag. 0.40E+00    7.7     0.00000185     -4911.5047300940  6.66E-06
    72 Broy./Diag. 0.40E+00    6.9     0.00000134     -4911.5047358871 -5.79E-06
    73 Broy./Diag. 0.40E+00    7.3     0.00000109     -4911.5047370209 -1.13E-06
    74 Broy./Diag. 0.40E+00    7.1     0.00000142     -4911.5047339936  3.03E-06
    75 Broy./Diag. 0.40E+00    7.3     0.00000102     -4911.5047305169  3.48E-06
    76 Broy./Diag. 0.40E+00    7.1     0.00000108     -4911.5047323934 -1.88E-06
    77 Broy./Diag. 0.40E+00    7.4     0.00000107     -4911.5047360663 -3.67E-06
    78 Broy./Diag. 0.40E+00    7.1     0.00000072     -4911.5047315747  4.49E-06

  *** SCF run converged in    78 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008334315576
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.82029569050883
  Hartree energy:                                            1781.46389545319107
  Exchange-correlation energy:                               -779.45940211070490
  Electronic entropic energy:                                  -0.23918143534780
  Fermi energy:                                                 0.08710018136928

  Total energy:                                             -4911.50473157470333

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.504728532515401

 MD| ***************************************************************************
 MD| Step number                                                            1227
 MD| Time [fs]                                                       2454.000000
 MD| Conserved quantity [hartree]                            -0.491118460371E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    572.683667           591.811593
 MD| Energy drift per atom [K]           0.280222880219E+03   0.268757255048E+03
 MD| Potential energy [hartree]         -0.491150472853E+04  -0.491156275629E+04
 MD| Kinetic energy [hartree]            0.320124826127E+00   0.372628657084E+00
 MD| Temperature [K]                             853.057420           992.967789
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.02928729     -4911.5049359060 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.08281973     -4911.6661915830 -1.61E-01
     3 Broy./Diag. 0.40E+00    7.1     0.07119143     -4911.1711700886  4.95E-01
     4 Broy./Diag. 0.40E+00    7.1     0.03608737     -4911.5727613000 -4.02E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01812509     -4911.5697391566  3.02E-03
     6 Broy./Diag. 0.40E+00    7.2     0.00537080     -4911.4847546254  8.50E-02
     7 Broy./Diag. 0.40E+00    7.0     0.00298646     -4911.4973510512 -1.26E-02
     8 Broy./Diag. 0.40E+00    7.9     0.00259536     -4911.5246282719 -2.73E-02
     9 Broy./Diag. 0.40E+00    7.2     0.00215066     -4911.5038274651  2.08E-02
    10 Broy./Diag. 0.40E+00    7.3     0.00197052     -4911.5037596767  6.78E-05
    11 Broy./Diag. 0.40E+00    7.1     0.00154006     -4911.5099893018 -6.23E-03
    12 Broy./Diag. 0.40E+00    7.2     0.00075946     -4911.5116868080 -1.70E-03
    13 Broy./Diag. 0.40E+00    7.3     0.00023537     -4911.5070308860  4.66E-03
    14 Broy./Diag. 0.40E+00    7.3     0.00027311     -4911.5058218419  1.21E-03
    15 Broy./Diag. 0.40E+00    7.3     0.00026776     -4911.5083903711 -2.57E-03
    16 Broy./Diag. 0.40E+00    7.3     0.00032936     -4911.5077764219  6.14E-04
    17 Broy./Diag. 0.40E+00    6.7     0.00030724     -4911.5067408370  1.04E-03
    18 Broy./Diag. 0.40E+00    6.7     0.00026496     -4911.5068169236 -7.61E-05
    19 Broy./Diag. 0.40E+00    7.3     0.00020015     -4911.5082923522 -1.48E-03
    20 Broy./Diag. 0.40E+00    7.0     0.00013905     -4911.5077496476  5.43E-04
    21 Broy./Diag. 0.40E+00    7.3     0.00014778     -4911.5065552968  1.19E-03
    22 Broy./Diag. 0.40E+00    7.3     0.00012297     -4911.5070323850 -4.77E-04
    23 Broy./Diag. 0.40E+00    6.8     0.00012083     -4911.5073073631 -2.75E-04
    24 Broy./Diag. 0.40E+00    7.3     0.00008840     -4911.5072791948  2.82E-05
    25 Broy./Diag. 0.40E+00    7.2     0.00009307     -4911.5067966456  4.83E-04
    26 Broy./Diag. 0.40E+00    6.9     0.00007416     -4911.5070179645 -2.21E-04
    27 Broy./Diag. 0.40E+00    6.9     0.00009210     -4911.5075802154 -5.62E-04
    28 Broy./Diag. 0.40E+00    6.8     0.00007914     -4911.5070693996  5.11E-04
    29 Broy./Diag. 0.40E+00    7.5     0.00007671     -4911.5069181312  1.51E-04
    30 Broy./Diag. 0.40E+00    7.1     0.00005280     -4911.5069512569 -3.31E-05
    31 Broy./Diag. 0.40E+00    7.1     0.00004933     -4911.5071423259 -1.91E-04
    32 Broy./Diag. 0.40E+00    6.7     0.00002462     -4911.5070275154  1.15E-04
    33 Broy./Diag. 0.40E+00    7.3     0.00003920     -4911.5068488270  1.79E-04
    34 Broy./Diag. 0.40E+00    6.9     0.00003998     -4911.5070438378 -1.95E-04
    35 Broy./Diag. 0.40E+00    7.1     0.00004097     -4911.5070421559  1.68E-06
    36 Broy./Diag. 0.40E+00    7.6     0.00003293     -4911.5070020690  4.01E-05
    37 Broy./Diag. 0.40E+00    7.1     0.00003706     -4911.5069007118  1.01E-04
    38 Broy./Diag. 0.40E+00    6.9     0.00001942     -4911.5069622626 -6.16E-05
    39 Broy./Diag. 0.40E+00    7.0     0.00002378     -4911.5070161152 -5.39E-05
    40 Broy./Diag. 0.40E+00    7.3     0.00002366     -4911.5069056943  1.10E-04
    41 Broy./Diag. 0.40E+00    7.3     0.00001938     -4911.5069259230 -2.02E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00001542     -4911.5069220610  3.86E-06
    43 Broy./Diag. 0.40E+00    7.3     0.00001593     -4911.5069479345 -2.59E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00000982     -4911.5069184521  2.95E-05
    45 Broy./Diag. 0.40E+00    7.1     0.00001494     -4911.5068950375  2.34E-05
    46 Broy./Diag. 0.40E+00    7.1     0.00001777     -4911.5069537644 -5.87E-05
    47 Broy./Diag. 0.40E+00    7.5     0.00001399     -4911.5069041832  4.96E-05
    48 Broy./Diag. 0.40E+00    6.9     0.00001080     -4911.5069103477 -6.16E-06
    49 Broy./Diag. 0.40E+00    7.5     0.00000966     -4911.5069029265  7.42E-06
    50 Broy./Diag. 0.40E+00    6.9     0.00000546     -4911.5069075961 -4.67E-06
    51 Broy./Diag. 0.40E+00    7.2     0.00000572     -4911.5069061221  1.47E-06
    52 Broy./Diag. 0.40E+00    7.0     0.00000841     -4911.5068857156  2.04E-05
    53 Broy./Diag. 0.40E+00    7.3     0.00000777     -4911.5069094166 -2.37E-05
    54 Broy./Diag. 0.40E+00    7.1     0.00000650     -4911.5068958983  1.35E-05
    55 Broy./Diag. 0.40E+00    7.2     0.00000577     -4911.5068918628  4.04E-06
    56 Broy./Diag. 0.40E+00    7.1     0.00000450     -4911.5068877692  4.09E-06
    57 Broy./Diag. 0.40E+00    7.1     0.00000414     -4911.5068926264 -4.86E-06
    58 Broy./Diag. 0.40E+00    7.5     0.00000527     -4911.5069003983 -7.77E-06
    59 Broy./Diag. 0.40E+00    7.2     0.00000441     -4911.5068788824  2.15E-05
    60 Broy./Diag. 0.40E+00    7.1     0.00000330     -4911.5068875363 -8.65E-06
    61 Broy./Diag. 0.40E+00    7.0     0.00000270     -4911.5068897841 -2.25E-06
    62 Broy./Diag. 0.40E+00    6.9     0.00000289     -4911.5068877430  2.04E-06
    63 Broy./Diag. 0.40E+00    7.9     0.00000264     -4911.5068804786  7.26E-06
    64 Broy./Diag. 0.40E+00    7.1     0.00000355     -4911.5068778081  2.67E-06
    65 Broy./Diag. 0.40E+00    6.9     0.00000336     -4911.5068921334 -1.43E-05
    66 Broy./Diag. 0.40E+00    7.1     0.00000230     -4911.5068826968  9.44E-06
    67 Broy./Diag. 0.40E+00    7.8     0.00000165     -4911.5068784589  4.24E-06
    68 Broy./Diag. 0.40E+00    7.3     0.00000197     -4911.5068793022 -8.43E-07
    69 Broy./Diag. 0.40E+00    6.9     0.00000161     -4911.5068837221 -4.42E-06
    70 Broy./Diag. 0.40E+00    6.6     0.00000177     -4911.5068829794  7.43E-07
    71 Broy./Diag. 0.40E+00    6.7     0.00000182     -4911.5068745416  8.44E-06
    72 Broy./Diag. 0.40E+00    7.3     0.00000142     -4911.5068795050 -4.96E-06
    73 Broy./Diag. 0.40E+00    7.6     0.00000104     -4911.5068813482 -1.84E-06
    74 Broy./Diag. 0.40E+00    7.3     0.00000147     -4911.5068800638  1.28E-06
    75 Broy./Diag. 0.40E+00    8.3     0.00000111     -4911.5068754552  4.61E-06
    76 Broy./Diag. 0.40E+00    7.1     0.00000124     -4911.5068762105 -7.55E-07
    77 Broy./Diag. 0.40E+00    7.1     0.00000114     -4911.5068815863 -5.38E-06
    78 Broy./Diag. 0.40E+00    7.1     0.00000080     -4911.5068773404  4.25E-06

  *** SCF run converged in    78 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008333314851
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.85453530717905
  Hartree energy:                                            1781.44223177922913
  Exchange-correlation energy:                               -779.47396341166780
  Electronic entropic energy:                                  -0.23934182989444
  Fermi energy:                                                 0.08716590210260

  Total energy:                                             -4911.50687734042549

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.506874345957840

 MD| ***************************************************************************
 MD| Step number                                                            1228
 MD| Time [fs]                                                       2456.000000
 MD| Conserved quantity [hartree]                            -0.491117333513E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    567.880106           591.792105
 MD| Energy drift per atom [K]           0.303632944091E+03   0.268785655446E+03
 MD| Potential energy [hartree]         -0.491150687435E+04  -0.491156271078E+04
 MD| Kinetic energy [hartree]            0.333539212686E+00   0.372596825289E+00
 MD| Temperature [K]                             888.803607           992.882965
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02959437     -4911.5068503533 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.08911025     -4911.6623164351 -1.55E-01
     3 Broy./Diag. 0.40E+00    6.9     0.07207741     -4911.1582499205  5.04E-01
     4 Broy./Diag. 0.40E+00    7.5     0.03631362     -4911.5722859303 -4.14E-01
     5 Broy./Diag. 0.40E+00    7.0     0.01775939     -4911.5654242813  6.86E-03
     6 Broy./Diag. 0.40E+00    7.5     0.00475027     -4911.4896798638  7.57E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00294432     -4911.5032708707 -1.36E-02
     8 Broy./Diag. 0.40E+00    7.1     0.00244125     -4911.5228416245 -1.96E-02
     9 Broy./Diag. 0.40E+00    7.1     0.00238918     -4911.5042232722  1.86E-02
    10 Broy./Diag. 0.40E+00    7.1     0.00204844     -4911.5065847728 -2.36E-03
    11 Broy./Diag. 0.40E+00    7.0     0.00137491     -4911.5121513463 -5.57E-03
    12 Broy./Diag. 0.40E+00    7.3     0.00074935     -4911.5126867299 -5.35E-04
    13 Broy./Diag. 0.40E+00    8.1     0.00026175     -4911.5085044917  4.18E-03
    14 Broy./Diag. 0.40E+00    7.5     0.00026270     -4911.5079585327  5.46E-04
    15 Broy./Diag. 0.40E+00    6.9     0.00029591     -4911.5101376859 -2.18E-03
    16 Broy./Diag. 0.40E+00    7.3     0.00036768     -4911.5092402529  8.97E-04
    17 Broy./Diag. 0.40E+00    7.2     0.00031507     -4911.5084951647  7.45E-04
    18 Broy./Diag. 0.40E+00    7.0     0.00028566     -4911.5088114304 -3.16E-04
    19 Broy./Diag. 0.40E+00    7.1     0.00017017     -4911.5101825180 -1.37E-03
    20 Broy./Diag. 0.40E+00    7.1     0.00014104     -4911.5094381432  7.44E-04
    21 Broy./Diag. 0.40E+00    6.4     0.00017808     -4911.5084128545  1.03E-03
    22 Broy./Diag. 0.40E+00    6.9     0.00013296     -4911.5090907415 -6.78E-04
    23 Broy./Diag. 0.40E+00    6.9     0.00011860     -4911.5092332014 -1.42E-04
    24 Broy./Diag. 0.40E+00    6.8     0.00009758     -4911.5091078473  1.25E-04
    25 Broy./Diag. 0.40E+00    7.3     0.00008350     -4911.5087066199  4.01E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00006642     -4911.5090508465 -3.44E-04
    27 Broy./Diag. 0.40E+00    7.2     0.00010442     -4911.5094706057 -4.20E-04
    28 Broy./Diag. 0.40E+00    7.5     0.00008460     -4911.5089587464  5.12E-04
    29 Broy./Diag. 0.40E+00    7.7     0.00007254     -4911.5088987945  6.00E-05
    30 Broy./Diag. 0.40E+00    7.4     0.00005131     -4911.5089989342 -1.00E-04
    31 Broy./Diag. 0.40E+00    7.3     0.00004710     -4911.5091544954 -1.56E-04
    32 Broy./Diag. 0.40E+00    7.2     0.00002386     -4911.5089725578  1.82E-04
    33 Broy./Diag. 0.40E+00    7.3     0.00004969     -4911.5088590481  1.14E-04
    34 Broy./Diag. 0.40E+00    6.9     0.00004584     -4911.5090877908 -2.29E-04
    35 Broy./Diag. 0.40E+00    7.0     0.00004029     -4911.5090509807  3.68E-05
    36 Broy./Diag. 0.40E+00    6.7     0.00003124     -4911.5089836214  6.74E-05
    37 Broy./Diag. 0.40E+00    7.3     0.00003583     -4911.5089150103  6.86E-05
    38 Broy./Diag. 0.40E+00    7.1     0.00002156     -4911.5090352490 -1.20E-04
    39 Broy./Diag. 0.40E+00    7.3     0.00002806     -4911.5090419229 -6.67E-06
    40 Broy./Diag. 0.40E+00    7.1     0.00002740     -4911.5089190474  1.23E-04
    41 Broy./Diag. 0.40E+00    6.9     0.00001953     -4911.5089567500 -3.77E-05
    42 Broy./Diag. 0.40E+00    6.7     0.00001456     -4911.5089773045 -2.06E-05
    43 Broy./Diag. 0.40E+00    7.3     0.00001696     -4911.5089914834 -1.42E-05
    44 Broy./Diag. 0.40E+00    8.3     0.00001153     -4911.5089391310  5.24E-05
    45 Broy./Diag. 0.40E+00    7.7     0.00001694     -4911.5089455439 -6.41E-06
    46 Broy./Diag. 0.40E+00   10.1     0.00001920     -4911.5090112949 -6.58E-05
    47 Broy./Diag. 0.40E+00    7.0     0.00001361     -4911.5089586309  5.27E-05
    48 Broy./Diag. 0.40E+00    8.0     0.00000982     -4911.5089491484  9.48E-06
    49 Broy./Diag. 0.40E+00   10.6     0.00001025     -4911.5089489476  2.01E-07
    50 Broy./Diag. 0.40E+00    7.5     0.00000680     -4911.5089709327 -2.20E-05
    51 Broy./Diag. 0.40E+00    7.3     0.00000680     -4911.5089578535  1.31E-05
    52 Broy./Diag. 0.40E+00    7.2     0.00000969     -4911.5089345345  2.33E-05
    53 Broy./Diag. 0.40E+00    6.6     0.00000803     -4911.5089625640 -2.80E-05
    54 Broy./Diag. 0.40E+00    8.4     0.00000642     -4911.5089593933  3.17E-06
    55 Broy./Diag. 0.40E+00    6.5     0.00000625     -4911.5089531582  6.24E-06
    56 Broy./Diag. 0.40E+00    9.5     0.00000505     -4911.5089409703  1.22E-05
    57 Broy./Diag. 0.40E+00    7.7     0.00000453     -4911.5089532460 -1.23E-05
    58 Broy./Diag. 0.40E+00    8.3     0.00000586     -4911.5089631958 -9.95E-06
    59 Broy./Diag. 0.40E+00    9.9     0.00000464     -4911.5089411944  2.20E-05
    60 Broy./Diag. 0.40E+00    6.9     0.00000349     -4911.5089451325 -3.94E-06
    61 Broy./Diag. 0.40E+00    7.2     0.00000300     -4911.5089498567 -4.72E-06
    62 Broy./Diag. 0.40E+00    7.5     0.00000248     -4911.5089523559 -2.50E-06
    63 Broy./Diag. 0.40E+00    7.9     0.00000288     -4911.5089425477  9.81E-06
    64 Broy./Diag. 0.40E+00    7.3     0.00000379     -4911.5089396626  2.89E-06
    65 Broy./Diag. 0.40E+00    9.5     0.00000333     -4911.5089539375 -1.43E-05
    66 Broy./Diag. 0.40E+00    7.9     0.00000240     -4911.5089480625  5.87E-06
    67 Broy./Diag. 0.40E+00    8.0     0.00000183     -4911.5089430781  4.98E-06
    68 Broy./Diag. 0.40E+00   10.4     0.00000165     -4911.5089418661  1.21E-06
    69 Broy./Diag. 0.40E+00    6.9     0.00000181     -4911.5089480176 -6.15E-06
    70 Broy./Diag. 0.40E+00    7.1     0.00000197     -4911.5089478908  1.27E-07
    71 Broy./Diag. 0.40E+00    7.7     0.00000186     -4911.5089395803  8.31E-06
    72 Broy./Diag. 0.40E+00    7.3     0.00000141     -4911.5089432569 -3.68E-06
    73 Broy./Diag. 0.40E+00    7.0     0.00000115     -4911.5089459889 -2.73E-06
    74 Broy./Diag. 0.40E+00    7.5     0.00000129     -4911.5089461033 -1.14E-07
    75 Broy./Diag. 0.40E+00    7.9     0.00000123     -4911.5089408533  5.25E-06
    76 Broy./Diag. 0.40E+00    7.6     0.00000135     -4911.5089415343 -6.81E-07
    77 Broy./Diag. 0.40E+00    7.2     0.00000117     -4911.5089469152 -5.38E-06
    78 Broy./Diag. 0.40E+00    7.1     0.00000079     -4911.5089435715  3.34E-06

  *** SCF run converged in    78 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008332160187
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.88587013528786
  Hartree energy:                                            1781.42282900327473
  Exchange-correlation energy:                               -779.48780655545647
  Electronic entropic energy:                                  -0.23949695524873
  Fermi energy:                                                 0.08722843138506

  Total energy:                                             -4911.50894357152447

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.508941426462115

 MD| ***************************************************************************
 MD| Step number                                                            1229
 MD| Time [fs]                                                       2458.000000
 MD| Conserved quantity [hartree]                            -0.491116998467E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    592.204199           591.792440
 MD| Energy drift per atom [K]           0.310593410644E+03   0.268819673148E+03
 MD| Potential energy [hartree]         -0.491150894143E+04  -0.491156266703E+04
 MD| Kinetic energy [hartree]            0.338956755056E+00   0.372569453385E+00
 MD| Temperature [K]                             903.240084           992.810025
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.03049942     -4911.5090510062 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.09512465     -4911.6780993447 -1.69E-01
     3 Broy./Diag. 0.40E+00    7.1     0.07143629     -4911.0934582497  5.85E-01
     4 Broy./Diag. 0.40E+00    7.0     0.03360845     -4911.5793417775 -4.86E-01
     5 Broy./Diag. 0.40E+00    7.0     0.01572986     -4911.5643065079  1.50E-02
     6 Broy./Diag. 0.40E+00    6.9     0.00485297     -4911.4916695839  7.26E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00438418     -4911.5111388971 -1.95E-02
     8 Broy./Diag. 0.40E+00    7.5     0.00177013     -4911.5165739496 -5.44E-03
     9 Broy./Diag. 0.40E+00    7.0     0.00207576     -4911.5080981758  8.48E-03
    10 Broy./Diag. 0.40E+00    7.5     0.00184417     -4911.5125065221 -4.41E-03
    11 Broy./Diag. 0.40E+00    7.2     0.00076203     -4911.5126712645 -1.65E-04
    12 Broy./Diag. 0.40E+00    7.1     0.00050264     -4911.5117474761  9.24E-04
    13 Broy./Diag. 0.40E+00    7.1     0.00025921     -4911.5096988043  2.05E-03
    14 Broy./Diag. 0.40E+00    7.8     0.00025312     -4911.5110662201 -1.37E-03
    15 Broy./Diag. 0.40E+00    6.8     0.00021804     -4911.5117804074 -7.14E-04
    16 Broy./Diag. 0.40E+00    7.1     0.00041892     -4911.5107365946  1.04E-03
    17 Broy./Diag. 0.40E+00    7.3     0.00030192     -4911.5109916611 -2.55E-04
    18 Broy./Diag. 0.40E+00    7.8     0.00019694     -4911.5114853447 -4.94E-04
    19 Broy./Diag. 0.40E+00    7.3     0.00016411     -4911.5118553191 -3.70E-04
    20 Broy./Diag. 0.40E+00    7.5     0.00012229     -4911.5109141872  9.41E-04
    21 Broy./Diag. 0.40E+00    7.1     0.00009712     -4911.5108222469  9.19E-05
    22 Broy./Diag. 0.40E+00    6.9     0.00010166     -4911.5113438422 -5.22E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00008080     -4911.5111947672  1.49E-04
    24 Broy./Diag. 0.40E+00    6.4     0.00006122     -4911.5110771128  1.18E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00006956     -4911.5110675798  9.53E-06
    26 Broy./Diag. 0.40E+00    7.3     0.00005416     -4911.5114245716 -3.57E-04
    27 Broy./Diag. 0.40E+00    7.5     0.00006568     -4911.5112614876  1.63E-04
    28 Broy./Diag. 0.40E+00    7.3     0.00009083     -4911.5109615665  3.00E-04
    29 Broy./Diag. 0.40E+00    7.3     0.00006600     -4911.5111629123 -2.01E-04
    30 Broy./Diag. 0.40E+00    7.1     0.00004522     -4911.5112465498 -8.36E-05
    31 Broy./Diag. 0.40E+00    7.2     0.00003817     -4911.5112318979  1.47E-05
    32 Broy./Diag. 0.40E+00    7.5     0.00002027     -4911.5110606661  1.71E-04
    33 Broy./Diag. 0.40E+00    6.9     0.00002635     -4911.5111683720 -1.08E-04
    34 Broy./Diag. 0.40E+00    7.3     0.00003355     -4911.5112761693 -1.08E-04
    35 Broy./Diag. 0.40E+00    7.3     0.00002894     -4911.5111658855  1.10E-04
    36 Broy./Diag. 0.40E+00    6.9     0.00002677     -4911.5111380333  2.79E-05
    37 Broy./Diag. 0.40E+00    7.4     0.00002693     -4911.5111650461 -2.70E-05
    38 Broy./Diag. 0.40E+00    7.9     0.00001439     -4911.5112629603 -9.79E-05
    39 Broy./Diag. 0.40E+00    7.5     0.00001171     -4911.5111703630  9.26E-05
    40 Broy./Diag. 0.40E+00    6.7     0.00001835     -4911.5111291610  4.12E-05
    41 Broy./Diag. 0.40E+00    6.9     0.00001152     -4911.5111890169 -5.99E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00000977     -4911.5111943411 -5.32E-06
    43 Broy./Diag. 0.40E+00    7.1     0.00001032     -4911.5111812085  1.31E-05
    44 Broy./Diag. 0.40E+00    6.9     0.00000763     -4911.5111525180  2.87E-05
    45 Broy./Diag. 0.40E+00    7.1     0.00000689     -4911.5112030052 -5.05E-05
    46 Broy./Diag. 0.40E+00    7.2     0.00001323     -4911.5112070720 -4.07E-06
    47 Broy./Diag. 0.40E+00    6.9     0.00001067     -4911.5111640310  4.30E-05
    48 Broy./Diag. 0.40E+00    7.6     0.00000785     -4911.5111636076  4.23E-07
    49 Broy./Diag. 0.40E+00    6.8     0.00000653     -4911.5111760744 -1.25E-05
    50 Broy./Diag. 0.40E+00    6.9     0.00000333     -4911.5111905358 -1.45E-05
    51 Broy./Diag. 0.40E+00    7.1     0.00000310     -4911.5111686578  2.19E-05
    52 Broy./Diag. 0.40E+00    6.7     0.00000586     -4911.5111727712 -4.11E-06
    53 Broy./Diag. 0.40E+00    7.1     0.00000602     -4911.5111903024 -1.75E-05
    54 Broy./Diag. 0.40E+00    7.1     0.00000418     -4911.5111826772  7.63E-06
    55 Broy./Diag. 0.40E+00    7.5     0.00000430     -4911.5111755842  7.09E-06
    56 Broy./Diag. 0.40E+00    6.9     0.00000283     -4911.5111695740  6.01E-06
    57 Broy./Diag. 0.40E+00    7.1     0.00000286     -4911.5111857189 -1.61E-05
    58 Broy./Diag. 0.40E+00    7.0     0.00000242     -4911.5111794430  6.28E-06
    59 Broy./Diag. 0.40E+00    7.1     0.00000269     -4911.5111728083  6.63E-06
    60 Broy./Diag. 0.40E+00    6.7     0.00000161     -4911.5111766658 -3.86E-06
    61 Broy./Diag. 0.40E+00    7.3     0.00000165     -4911.5111791369 -2.47E-06
    62 Broy./Diag. 0.40E+00    6.9     0.00000147     -4911.5111799032 -7.66E-07
    63 Broy./Diag. 0.40E+00    7.3     0.00000198     -4911.5111731799  6.72E-06
    64 Broy./Diag. 0.40E+00    7.4     0.00000172     -4911.5111784124 -5.23E-06
    65 Broy./Diag. 0.40E+00    6.7     0.00000232     -4911.5111818752 -3.46E-06
    66 Broy./Diag. 0.40E+00    7.5     0.00000122     -4911.5111772108  4.66E-06
    67 Broy./Diag. 0.40E+00    7.5     0.00000096     -4911.5111754187  1.79E-06

  *** SCF run converged in    67 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008330419332
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.91510890605150
  Hartree energy:                                            1781.40479293794260
  Exchange-correlation energy:                               -779.50108608202299
  Electronic entropic energy:                                  -0.23965197741096
  Fermi energy:                                                 0.08729101472155

  Total energy:                                             -4911.51117541867006

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.511176499163412

 MD| ***************************************************************************
 MD| Step number                                                            1230
 MD| Time [fs]                                                       2460.000000
 MD| Conserved quantity [hartree]                            -0.491116209319E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    488.440989           591.708415
 MD| Energy drift per atom [K]           0.326987687934E+03   0.268866964217E+03
 MD| Potential energy [hartree]         -0.491151117650E+04  -0.491156262517E+04
 MD| Kinetic energy [hartree]            0.349083310385E+00   0.372550358959E+00
 MD| Temperature [K]                             930.224974           992.759143
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.03337329     -4911.5112129284 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.09845106     -4911.6864662196 -1.75E-01
     3 Broy./Diag. 0.40E+00    7.1     0.07663406     -4911.0522826172  6.34E-01
     4 Broy./Diag. 0.40E+00    7.4     0.03615978     -4911.5471900545 -4.95E-01
     5 Broy./Diag. 0.40E+00    7.5     0.01674821     -4911.5822449205 -3.51E-02
     6 Broy./Diag. 0.40E+00    7.0     0.00482643     -4911.4913293719  9.09E-02
     7 Broy./Diag. 0.40E+00    7.5     0.00435125     -4911.5178747335 -2.65E-02
     8 Broy./Diag. 0.40E+00    6.8     0.00173821     -4911.5121592322  5.72E-03
     9 Broy./Diag. 0.40E+00    7.1     0.00177293     -4911.5150810325 -2.92E-03
    10 Broy./Diag. 0.40E+00    7.3     0.00176568     -4911.5049518813  1.01E-02
    11 Broy./Diag. 0.40E+00    7.1     0.00128333     -4911.5132338229 -8.28E-03
    12 Broy./Diag. 0.40E+00    8.0     0.00054625     -4911.5149905269 -1.76E-03
    13 Broy./Diag. 0.40E+00    8.2     0.00031657     -4911.5118489519  3.14E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00024472     -4911.5131513334 -1.30E-03
    15 Broy./Diag. 0.40E+00    7.3     0.00023386     -4911.5130437323  1.08E-04
    16 Broy./Diag. 0.40E+00    7.5     0.00036770     -4911.5141654472 -1.12E-03
    17 Broy./Diag. 0.40E+00    7.5     0.00034453     -4911.5124251429  1.74E-03
    18 Broy./Diag. 0.40E+00    7.5     0.00020193     -4911.5124455765 -2.04E-05
    19 Broy./Diag. 0.40E+00    7.3     0.00017511     -4911.5137441818 -1.30E-03
    20 Broy./Diag. 0.40E+00    7.3     0.00014187     -4911.5130015337  7.43E-04
    21 Broy./Diag. 0.40E+00    7.0     0.00011774     -4911.5132088927 -2.07E-04
    22 Broy./Diag. 0.40E+00    7.1     0.00013124     -4911.5128679451  3.41E-04
    23 Broy./Diag. 0.40E+00    6.7     0.00015044     -4911.5135061632 -6.38E-04
    24 Broy./Diag. 0.40E+00    7.5     0.00011405     -4911.5134726218  3.35E-05
    25 Broy./Diag. 0.40E+00    7.1     0.00008102     -4911.5129448835  5.28E-04
    26 Broy./Diag. 0.40E+00    6.9     0.00005457     -4911.5133025014 -3.58E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00005419     -4911.5132086853  9.38E-05
    28 Broy./Diag. 0.40E+00    6.9     0.00006157     -4911.5133821369 -1.73E-04
    29 Broy./Diag. 0.40E+00    8.1     0.00006039     -4911.5130981383  2.84E-04
    30 Broy./Diag. 0.40E+00    6.9     0.00005916     -4911.5131784519 -8.03E-05
    31 Broy./Diag. 0.40E+00    7.1     0.00005071     -4911.5134052518 -2.27E-04
    32 Broy./Diag. 0.40E+00    7.3     0.00003368     -4911.5131876881  2.18E-04
    33 Broy./Diag. 0.40E+00    7.1     0.00003457     -4911.5132734449 -8.58E-05
    34 Broy./Diag. 0.40E+00    7.0     0.00003553     -4911.5131611903  1.12E-04
    35 Broy./Diag. 0.40E+00    7.1     0.00003188     -4911.5133316764 -1.70E-04
    36 Broy./Diag. 0.40E+00    6.8     0.00003438     -4911.5132812377  5.04E-05
    37 Broy./Diag. 0.40E+00    7.3     0.00002732     -4911.5131784607  1.03E-04
    38 Broy./Diag. 0.40E+00    7.2     0.00001562     -4911.5133008749 -1.22E-04
    39 Broy./Diag. 0.40E+00    6.9     0.00001969     -4911.5132579910  4.29E-05
    40 Broy./Diag. 0.40E+00    7.1     0.00002351     -4911.5133259663 -6.80E-05
    41 Broy./Diag. 0.40E+00    7.4     0.00001647     -4911.5132184913  1.07E-04
    42 Broy./Diag. 0.40E+00    7.2     0.00002001     -4911.5132635179 -4.50E-05
    43 Broy./Diag. 0.40E+00    7.2     0.00001592     -4911.5133154486 -5.19E-05
    44 Broy./Diag. 0.40E+00    7.7     0.00000959     -4911.5132443430  7.11E-05
    45 Broy./Diag. 0.40E+00    6.9     0.00000684     -4911.5132769368 -3.26E-05
    46 Broy./Diag. 0.40E+00    7.1     0.00000965     -4911.5132528076  2.41E-05
    47 Broy./Diag. 0.40E+00    7.3     0.00000832     -4911.5132975229 -4.47E-05
    48 Broy./Diag. 0.40E+00    7.3     0.00001090     -4911.5132743925  2.31E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00000830     -4911.5132537849  2.06E-05
    50 Broy./Diag. 0.40E+00    6.8     0.00000677     -4911.5132917982 -3.80E-05
    51 Broy./Diag. 0.40E+00    7.8     0.00000418     -4911.5132698220  2.20E-05
    52 Broy./Diag. 0.40E+00    7.3     0.00000658     -4911.5132872994 -1.75E-05
    53 Broy./Diag. 0.40E+00    7.6     0.00000526     -4911.5132573603  2.99E-05
    54 Broy./Diag. 0.40E+00    6.9     0.00000604     -4911.5132745745 -1.72E-05
    55 Broy./Diag. 0.40E+00    7.3     0.00000394     -4911.5132849337 -1.04E-05
    56 Broy./Diag. 0.40E+00    7.5     0.00000368     -4911.5132674628  1.75E-05
    57 Broy./Diag. 0.40E+00    7.1     0.00000196     -4911.5132795190 -1.21E-05
    58 Broy./Diag. 0.40E+00    7.1     0.00000346     -4911.5132719305  7.59E-06
    59 Broy./Diag. 0.40E+00    7.3     0.00000368     -4911.5132875654 -1.56E-05
    60 Broy./Diag. 0.40E+00    7.1     0.00000430     -4911.5132753814  1.22E-05
    61 Broy./Diag. 0.40E+00    6.9     0.00000257     -4911.5132705119  4.87E-06
    62 Broy./Diag. 0.40E+00    6.9     0.00000226     -4911.5132819580 -1.14E-05
    63 Broy./Diag. 0.40E+00    7.3     0.00000113     -4911.5132750524  6.91E-06
    64 Broy./Diag. 0.40E+00    7.1     0.00000153     -4911.5132797002 -4.65E-06
    65 Broy./Diag. 0.40E+00    7.7     0.00000157     -4911.5132727813  6.92E-06
    66 Broy./Diag. 0.40E+00    7.1     0.00000204     -4911.5132785314 -5.75E-06
    67 Broy./Diag. 0.40E+00    7.1     0.00000145     -4911.5132803123 -1.78E-06
    68 Broy./Diag. 0.40E+00    7.1     0.00000156     -4911.5132741267  6.19E-06
    69 Broy./Diag. 0.40E+00    7.5     0.00000080     -4911.5132786368 -4.51E-06

  *** SCF run converged in    69 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008328354028
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.94047116776301
  Hartree energy:                                            1781.38906379376067
  Exchange-correlation energy:                               -779.51268848127029
  Electronic entropic energy:                                  -0.23978586470476
  Fermi energy:                                                 0.08735029042795

  Total energy:                                             -4911.51327863682127

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.513277776872201

 MD| ***************************************************************************
 MD| Step number                                                            1231
 MD| Time [fs]                                                       2462.000000
 MD| Conserved quantity [hartree]                            -0.491115924682E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    507.453799           591.639971
 MD| Energy drift per atom [K]           0.332900918443E+03   0.268918982051E+03
 MD| Potential energy [hartree]         -0.491151327778E+04  -0.491156258508E+04
 MD| Kinetic energy [hartree]            0.354030956678E+00   0.372535314766E+00
 MD| Temperature [K]                             943.409289           992.719054
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.03783937     -4911.5130106361 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.11285917     -4911.6686970964 -1.56E-01
     3 Broy./Diag. 0.40E+00    7.1     0.08757332     -4911.0849906363  5.84E-01
     4 Broy./Diag. 0.40E+00    7.1     0.03752088     -4911.5268781437 -4.42E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01787267     -4911.5857045201 -5.88E-02
     6 Broy./Diag. 0.40E+00    7.3     0.00591807     -4911.4923213357  9.34E-02
     7 Broy./Diag. 0.40E+00    6.8     0.00357450     -4911.5262342766 -3.39E-02
     8 Broy./Diag. 0.40E+00    7.5     0.00308067     -4911.5087357861  1.75E-02
     9 Broy./Diag. 0.40E+00    7.6     0.00223374     -4911.5182919531 -9.56E-03
    10 Broy./Diag. 0.40E+00    7.0     0.00198449     -4911.5086198661  9.67E-03
    11 Broy./Diag. 0.40E+00    6.7     0.00198552     -4911.5137241188 -5.10E-03
    12 Broy./Diag. 0.40E+00    7.3     0.00094162     -4911.5184707211 -4.75E-03
    13 Broy./Diag. 0.40E+00    6.7     0.00035295     -4911.5132862450  5.18E-03
    14 Broy./Diag. 0.40E+00    7.3     0.00032295     -4911.5155194631 -2.23E-03
    15 Broy./Diag. 0.40E+00    7.1     0.00025698     -4911.5145712130  9.48E-04
    16 Broy./Diag. 0.40E+00    7.1     0.00034853     -4911.5156103563 -1.04E-03
    17 Broy./Diag. 0.40E+00    7.9     0.00041318     -4911.5145465114  1.06E-03
    18 Broy./Diag. 0.40E+00    7.3     0.00026337     -4911.5141709829  3.76E-04
    19 Broy./Diag. 0.40E+00    7.3     0.00020092     -4911.5157119225 -1.54E-03
    20 Broy./Diag. 0.40E+00    7.5     0.00017119     -4911.5147046449  1.01E-03
    21 Broy./Diag. 0.40E+00    7.3     0.00013459     -4911.5152471248 -5.42E-04
    22 Broy./Diag. 0.40E+00    6.9     0.00011868     -4911.5147685224  4.79E-04
    23 Broy./Diag. 0.40E+00    7.0     0.00016068     -4911.5152083302 -4.40E-04
    24 Broy./Diag. 0.40E+00    7.7     0.00011182     -4911.5153021684 -9.38E-05
    25 Broy./Diag. 0.40E+00    8.0     0.00010963     -4911.5146236812  6.78E-04
    26 Broy./Diag. 0.40E+00    7.6     0.00007515     -4911.5151808056 -5.57E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00006674     -4911.5149272106  2.54E-04
    28 Broy./Diag. 0.40E+00    7.1     0.00006103     -4911.5151743854 -2.47E-04
    29 Broy./Diag. 0.40E+00    7.3     0.00006962     -4911.5149640982  2.10E-04
    30 Broy./Diag. 0.40E+00    7.5     0.00004567     -4911.5149702260 -6.13E-06
    31 Broy./Diag. 0.40E+00    6.9     0.00005191     -4911.5152220208 -2.52E-04
    32 Broy./Diag. 0.40E+00    7.3     0.00003425     -4911.5149652817  2.57E-04
    33 Broy./Diag. 0.40E+00    7.3     0.00003996     -4911.5151189703 -1.54E-04
    34 Broy./Diag. 0.40E+00    6.7     0.00003585     -4911.5149947727  1.24E-04
    35 Broy./Diag. 0.40E+00    6.7     0.00004307     -4911.5151340769 -1.39E-04
    36 Broy./Diag. 0.40E+00    7.1     0.00003168     -4911.5151263357  7.74E-06
    37 Broy./Diag. 0.40E+00    7.1     0.00003025     -4911.5149888969  1.37E-04
    38 Broy./Diag. 0.40E+00    7.4     0.00001246     -4911.5151499175 -1.61E-04
    39 Broy./Diag. 0.40E+00    6.9     0.00001903     -4911.5150832549  6.67E-05
    40 Broy./Diag. 0.40E+00    7.4     0.00002133     -4911.5151394251 -5.62E-05
    41 Broy./Diag. 0.40E+00    7.3     0.00002179     -4911.5150636787  7.57E-05
    42 Broy./Diag. 0.40E+00    8.4     0.00001829     -4911.5150898284 -2.61E-05
    43 Broy./Diag. 0.40E+00    7.7     0.00001797     -4911.5151598220 -7.00E-05
    44 Broy./Diag. 0.40E+00    7.3     0.00001048     -4911.5150607925  9.90E-05
    45 Broy./Diag. 0.40E+00    7.3     0.00001006     -4911.5151158898 -5.51E-05
    46 Broy./Diag. 0.40E+00    7.2     0.00000953     -4911.5150882929  2.76E-05
    47 Broy./Diag. 0.40E+00    6.9     0.00000978     -4911.5151249317 -3.66E-05
    48 Broy./Diag. 0.40E+00    7.6     0.00000960     -4911.5151121250  1.28E-05
    49 Broy./Diag. 0.40E+00    7.4     0.00000713     -4911.5150827438  2.94E-05
    50 Broy./Diag. 0.40E+00    7.1     0.00000626     -4911.5151320695 -4.93E-05
    51 Broy./Diag. 0.40E+00    7.3     0.00000607     -4911.5151019238  3.01E-05
    52 Broy./Diag. 0.40E+00    6.9     0.00000692     -4911.5151192512 -1.73E-05
    53 Broy./Diag. 0.40E+00    7.2     0.00000573     -4911.5150957264  2.35E-05
    54 Broy./Diag. 0.40E+00    7.1     0.00000624     -4911.5151094479 -1.37E-05
    55 Broy./Diag. 0.40E+00    7.2     0.00000365     -4911.5151275370 -1.81E-05
    56 Broy./Diag. 0.40E+00    6.8     0.00000341     -4911.5151014326  2.61E-05
    57 Broy./Diag. 0.40E+00    7.5     0.00000256     -4911.5151188749 -1.74E-05
    58 Broy./Diag. 0.40E+00    7.5     0.00000308     -4911.5151118135  7.06E-06
    59 Broy./Diag. 0.40E+00    7.1     0.00000322     -4911.5151219748 -1.02E-05
    60 Broy./Diag. 0.40E+00    7.3     0.00000445     -4911.5151137556  8.22E-06
    61 Broy./Diag. 0.40E+00    7.1     0.00000273     -4911.5151050160  8.74E-06
    62 Broy./Diag. 0.40E+00    7.1     0.00000220     -4911.5151234059 -1.84E-05
    63 Broy./Diag. 0.40E+00    7.3     0.00000162     -4911.5151119652  1.14E-05
    64 Broy./Diag. 0.40E+00    7.3     0.00000169     -4911.5151171263 -5.16E-06
    65 Broy./Diag. 0.40E+00    7.1     0.00000150     -4911.5151120451  5.08E-06
    66 Broy./Diag. 0.40E+00    7.4     0.00000201     -4911.5151166369 -4.59E-06
    67 Broy./Diag. 0.40E+00    7.1     0.00000146     -4911.5151199335 -3.30E-06
    68 Broy./Diag. 0.40E+00    7.1     0.00000121     -4911.5151109679  8.97E-06
    69 Broy./Diag. 0.40E+00    7.5     0.00000101     -4911.5151182759 -7.31E-06
    70 Broy./Diag. 0.40E+00    6.7     0.00000110     -4911.5151149424  3.33E-06
    71 Broy./Diag. 0.40E+00    7.3     0.00000112     -4911.5151182984 -3.36E-06
    72 Broy./Diag. 0.40E+00    7.1     0.00000134     -4911.5151152948  3.00E-06
    73 Broy./Diag. 0.40E+00    8.3     0.00000082     -4911.5151140876  1.21E-06

  *** SCF run converged in    73 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008326806811
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.96284728121600
  Hartree energy:                                            1781.37510356958182
  Exchange-correlation energy:                               -779.52279572072553
  Electronic entropic energy:                                  -0.23993000619003
  Fermi energy:                                                 0.08740454537677

  Total energy:                                             -4911.51511408763599

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.515117482091227

 MD| ***************************************************************************
 MD| Step number                                                            1232
 MD| Time [fs]                                                       2464.000000
 MD| Conserved quantity [hartree]                            -0.491116748416E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    537.437477           591.595975
 MD| Energy drift per atom [K]           0.315788143506E+03   0.268957025202E+03
 MD| Potential energy [hartree]         -0.491151511748E+04  -0.491156254655E+04
 MD| Kinetic energy [hartree]            0.347633326165E+00   0.372515102113E+00
 MD| Temperature [K]                             926.361107           992.665192
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    7.8     0.03773948     -4911.5145148522 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.2     0.11560396     -4911.6801276851 -1.66E-01
     3 Broy./Diag. 0.40E+00   10.4     0.10002782     -4911.0235279628  6.57E-01
     4 Broy./Diag. 0.40E+00    8.3     0.02986436     -4911.5363298899 -5.13E-01
     5 Broy./Diag. 0.40E+00    7.2     0.01680272     -4911.5728597410 -3.65E-02
     6 Broy./Diag. 0.40E+00    7.4     0.00578653     -4911.4921380137  8.07E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00508200     -4911.5309956942 -3.89E-02
     8 Broy./Diag. 0.40E+00    7.5     0.00332712     -4911.5091919201  2.18E-02
     9 Broy./Diag. 0.40E+00    8.1     0.00206647     -4911.5162458590 -7.05E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00203117     -4911.5108869360  5.36E-03
    11 Broy./Diag. 0.40E+00   10.2     0.00172368     -4911.5162411327 -5.35E-03
    12 Broy./Diag. 0.40E+00    7.2     0.00088096     -4911.5196368172 -3.40E-03
    13 Broy./Diag. 0.40E+00    9.8     0.00046296     -4911.5142509534  5.39E-03
    14 Broy./Diag. 0.40E+00    8.2     0.00038199     -4911.5168423956 -2.59E-03
    15 Broy./Diag. 0.40E+00    6.7     0.00023052     -4911.5159712887  8.71E-04
    16 Broy./Diag. 0.40E+00    7.3     0.00030941     -4911.5165426344 -5.71E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00032096     -4911.5157095179  8.33E-04
    18 Broy./Diag. 0.40E+00    8.2     0.00022762     -4911.5156267378  8.28E-05
    19 Broy./Diag. 0.40E+00    6.8     0.00016593     -4911.5170697488 -1.44E-03
    20 Broy./Diag. 0.40E+00    9.9     0.00019026     -4911.5159946397  1.08E-03
    21 Broy./Diag. 0.40E+00    7.4     0.00010843     -4911.5164365570 -4.42E-04
    22 Broy./Diag. 0.40E+00    8.8     0.00010085     -4911.5162452124  1.91E-04
    23 Broy./Diag. 0.40E+00    9.5     0.00012084     -4911.5165726978 -3.27E-04
    24 Broy./Diag. 0.40E+00    6.9     0.00009933     -4911.5165551984  1.75E-05
    25 Broy./Diag. 0.40E+00    7.3     0.00009469     -4911.5159507903  6.04E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00008386     -4911.5165662571 -6.15E-04
    27 Broy./Diag. 0.40E+00    7.3     0.00006493     -4911.5163540385  2.12E-04
    28 Broy./Diag. 0.40E+00    7.3     0.00005280     -4911.5164915184 -1.37E-04
    29 Broy./Diag. 0.40E+00    6.9     0.00005271     -4911.5163449328  1.47E-04
    30 Broy./Diag. 0.40E+00    7.1     0.00004061     -4911.5163983560 -5.34E-05
    31 Broy./Diag. 0.40E+00    8.0     0.00004522     -4911.5166126837 -2.14E-04
    32 Broy./Diag. 0.40E+00    7.5     0.00003969     -4911.5163381272  2.75E-04
    33 Broy./Diag. 0.40E+00    6.9     0.00003849     -4911.5164926733 -1.55E-04
    34 Broy./Diag. 0.40E+00    7.1     0.00002797     -4911.5164407248  5.19E-05
    35 Broy./Diag. 0.40E+00    7.1     0.00003240     -4911.5165357743 -9.50E-05
    36 Broy./Diag. 0.40E+00    7.3     0.00002706     -4911.5165091023  2.67E-05
    37 Broy./Diag. 0.40E+00    7.1     0.00002595     -4911.5164071730  1.02E-04
    38 Broy./Diag. 0.40E+00    6.9     0.00001440     -4911.5165687108 -1.62E-04
    39 Broy./Diag. 0.40E+00    6.9     0.00001812     -4911.5165061584  6.26E-05
    40 Broy./Diag. 0.40E+00    7.5     0.00001549     -4911.5165320075 -2.58E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00001596     -4911.5164921517  3.99E-05
    42 Broy./Diag. 0.40E+00    6.9     0.00001476     -4911.5165228289 -3.07E-05
    43 Broy./Diag. 0.40E+00    7.7     0.00001642     -4911.5165721217 -4.93E-05
    44 Broy./Diag. 0.40E+00    6.9     0.00000916     -4911.5164751929  9.69E-05
    45 Broy./Diag. 0.40E+00    7.1     0.00000995     -4911.5165375146 -6.23E-05
    46 Broy./Diag. 0.40E+00    7.1     0.00000662     -4911.5165248672  1.26E-05
    47 Broy./Diag. 0.40E+00    6.9     0.00000734     -4911.5165472312 -2.24E-05
    48 Broy./Diag. 0.40E+00    8.0     0.00000759     -4911.5165348748  1.24E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00000647     -4911.5165167748  1.81E-05
    50 Broy./Diag. 0.40E+00    7.3     0.00000446     -4911.5165610376 -4.43E-05
    51 Broy./Diag. 0.40E+00    7.3     0.00000608     -4911.5165308536  3.02E-05
    52 Broy./Diag. 0.40E+00    7.1     0.00000467     -4911.5165420545 -1.12E-05
    53 Broy./Diag. 0.40E+00    6.5     0.00000486     -4911.5165310933  1.10E-05
    54 Broy./Diag. 0.40E+00    7.1     0.00000486     -4911.5165436412 -1.25E-05
    55 Broy./Diag. 0.40E+00    7.5     0.00000349     -4911.5165552374 -1.16E-05
    56 Broy./Diag. 0.40E+00    6.5     0.00000231     -4911.5165332298  2.20E-05
    57 Broy./Diag. 0.40E+00    6.9     0.00000254     -4911.5165504581 -1.72E-05
    58 Broy./Diag. 0.40E+00    7.3     0.00000189     -4911.5165471121  3.35E-06
    59 Broy./Diag. 0.40E+00    7.5     0.00000281     -4911.5165520077 -4.90E-06
    60 Broy./Diag. 0.40E+00    6.9     0.00000332     -4911.5165456546  6.35E-06
    61 Broy./Diag. 0.40E+00    7.1     0.00000202     -4911.5165415456  4.11E-06
    62 Broy./Diag. 0.40E+00    7.1     0.00000161     -4911.5165569957 -1.55E-05
    63 Broy./Diag. 0.40E+00    7.1     0.00000170     -4911.5165459389  1.11E-05
    64 Broy./Diag. 0.40E+00    7.1     0.00000108     -4911.5165498920 -3.95E-06
    65 Broy./Diag. 0.40E+00    7.2     0.00000119     -4911.5165478719  2.02E-06
    66 Broy./Diag. 0.40E+00    7.3     0.00000137     -4911.5165515985 -3.73E-06
    67 Broy./Diag. 0.40E+00    7.3     0.00000093     -4911.5165530860 -1.49E-06

  *** SCF run converged in    67 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008327598235
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.98212544645867
  Hartree energy:                                            1781.36320347908259
  Exchange-correlation energy:                               -779.53147542811257
  Electronic entropic energy:                                  -0.24006730318349
  Fermi energy:                                                 0.08744894389679

  Total energy:                                             -4911.51655308595491

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.516553628538531

 MD| ***************************************************************************
 MD| Step number                                                            1233
 MD| Time [fs]                                                       2466.000000
 MD| Conserved quantity [hartree]                            -0.491115760092E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    510.581839           591.530270
 MD| Energy drift per atom [K]           0.336320224353E+03   0.269011658777E+03
 MD| Potential energy [hartree]         -0.491151655363E+04  -0.491156250925E+04
 MD| Kinetic energy [hartree]            0.358952711528E+00   0.372504102607E+00
 MD| Temperature [K]                             956.524608           992.635881
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.03469596     -4911.5157851227 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.11092754     -4911.6632905596 -1.48E-01
     3 Broy./Diag. 0.40E+00    7.1     0.09877496     -4911.0277931989  6.35E-01
     4 Broy./Diag. 0.40E+00    7.3     0.02469815     -4911.5391147774 -5.11E-01
     5 Broy./Diag. 0.40E+00    7.3     0.01380471     -4911.5621551842 -2.30E-02
     6 Broy./Diag. 0.40E+00    6.9     0.00514425     -4911.4957115928  6.64E-02
     7 Broy./Diag. 0.40E+00    6.6     0.00473454     -4911.5321410231 -3.64E-02
     8 Broy./Diag. 0.40E+00    7.1     0.00326828     -4911.5094053442  2.27E-02
     9 Broy./Diag. 0.40E+00    6.9     0.00185600     -4911.5166669985 -7.26E-03
    10 Broy./Diag. 0.40E+00    7.5     0.00190916     -4911.5124814483  4.19E-03
    11 Broy./Diag. 0.40E+00    7.3     0.00137775     -4911.5177249138 -5.24E-03
    12 Broy./Diag. 0.40E+00    7.4     0.00073278     -4911.5197495837 -2.02E-03
    13 Broy./Diag. 0.40E+00    7.2     0.00040917     -4911.5151996515  4.55E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00034814     -4911.5177812628 -2.58E-03
    15 Broy./Diag. 0.40E+00    6.9     0.00020637     -4911.5168966809  8.85E-04
    16 Broy./Diag. 0.40E+00    7.3     0.00030032     -4911.5173878906 -4.91E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00027038     -4911.5166116193  7.76E-04
    18 Broy./Diag. 0.40E+00    6.8     0.00019041     -4911.5167039695 -9.24E-05
    19 Broy./Diag. 0.40E+00    7.3     0.00015003     -4911.5179243851 -1.22E-03
    20 Broy./Diag. 0.40E+00    7.1     0.00018267     -4911.5169223229  1.00E-03
    21 Broy./Diag. 0.40E+00    7.4     0.00010931     -4911.5173840490 -4.62E-04
    22 Broy./Diag. 0.40E+00    7.2     0.00009423     -4911.5172578829  1.26E-04
    23 Broy./Diag. 0.40E+00    6.9     0.00010323     -4911.5175610320 -3.03E-04
    24 Broy./Diag. 0.40E+00    7.3     0.00008999     -4911.5174920545  6.90E-05
    25 Broy./Diag. 0.40E+00    7.1     0.00008878     -4911.5169728619  5.19E-04
    26 Broy./Diag. 0.40E+00    6.9     0.00008256     -4911.5175785449 -6.06E-04
    27 Broy./Diag. 0.40E+00    7.3     0.00006757     -4911.5173470599  2.31E-04
    28 Broy./Diag. 0.40E+00    7.3     0.00004914     -4911.5174842934 -1.37E-04
    29 Broy./Diag. 0.40E+00    7.2     0.00004544     -4911.5173604055  1.24E-04
    30 Broy./Diag. 0.40E+00    7.4     0.00003482     -4911.5174306963 -7.03E-05
    31 Broy./Diag. 0.40E+00    6.9     0.00004149     -4911.5176053732 -1.75E-04
    32 Broy./Diag. 0.40E+00    7.1     0.00003825     -4911.5173553264  2.50E-04
    33 Broy./Diag. 0.40E+00    7.3     0.00003889     -4911.5175282097 -1.73E-04
    34 Broy./Diag. 0.40E+00    6.9     0.00002636     -4911.5174747999  5.34E-05
    35 Broy./Diag. 0.40E+00    6.7     0.00003024     -4911.5175598135 -8.50E-05
    36 Broy./Diag. 0.40E+00    6.8     0.00002507     -4911.5175265062  3.33E-05
    37 Broy./Diag. 0.40E+00    6.9     0.00002520     -4911.5174475315  7.90E-05
    38 Broy./Diag. 0.40E+00    6.9     0.00001369     -4911.5175956151 -1.48E-04
    39 Broy./Diag. 0.40E+00    8.2     0.00001807     -4911.5175340143  6.16E-05
    40 Broy./Diag. 0.40E+00    6.9     0.00001385     -4911.5175645057 -3.05E-05
    41 Broy./Diag. 0.40E+00    6.8     0.00001457     -4911.5175360097  2.85E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00001301     -4911.5175667023 -3.07E-05
    43 Broy./Diag. 0.40E+00    7.0     0.00001742     -4911.5176008789 -3.42E-05
    44 Broy./Diag. 0.40E+00    7.7     0.00000938     -4911.5175125097  8.84E-05
    45 Broy./Diag. 0.40E+00    7.3     0.00001037     -4911.5175837389 -7.12E-05
    46 Broy./Diag. 0.40E+00    6.6     0.00000653     -4911.5175651257  1.86E-05
    47 Broy./Diag. 0.40E+00    7.9     0.00000693     -4911.5175851823 -2.01E-05
    48 Broy./Diag. 0.40E+00    7.1     0.00000629     -4911.5175757257  9.46E-06
    49 Broy./Diag. 0.40E+00    7.3     0.00000647     -4911.5175671984  8.53E-06
    50 Broy./Diag. 0.40E+00    7.1     0.00000423     -4911.5175993022 -3.21E-05
    51 Broy./Diag. 0.40E+00    6.7     0.00000631     -4911.5175703571  2.89E-05
    52 Broy./Diag. 0.40E+00    7.3     0.00000455     -4911.5175895789 -1.92E-05
    53 Broy./Diag. 0.40E+00    7.3     0.00000477     -4911.5175800709  9.51E-06
    54 Broy./Diag. 0.40E+00    7.5     0.00000449     -4911.5175896317 -9.56E-06
    55 Broy./Diag. 0.40E+00    6.7     0.00000422     -4911.5175956341 -6.00E-06
    56 Broy./Diag. 0.40E+00    7.3     0.00000215     -4911.5175818440  1.38E-05
    57 Broy./Diag. 0.40E+00    7.0     0.00000237     -4911.5175979404 -1.61E-05
    58 Broy./Diag. 0.40E+00    6.8     0.00000163     -4911.5175911020  6.84E-06
    59 Broy./Diag. 0.40E+00    7.1     0.00000251     -4911.5175969690 -5.87E-06
    60 Broy./Diag. 0.40E+00    7.1     0.00000286     -4911.5175936299  3.34E-06
    61 Broy./Diag. 0.40E+00    7.0     0.00000254     -4911.5175937811 -1.51E-07
    62 Broy./Diag. 0.40E+00    7.1     0.00000163     -4911.5176013675 -7.59E-06
    63 Broy./Diag. 0.40E+00    6.9     0.00000185     -4911.5175911775  1.02E-05
    64 Broy./Diag. 0.40E+00    7.8     0.00000103     -4911.5175999226 -8.75E-06
    65 Broy./Diag. 0.40E+00    7.3     0.00000103     -4911.5175968062  3.12E-06
    66 Broy./Diag. 0.40E+00    7.2     0.00000116     -4911.5175986721 -1.87E-06
    67 Broy./Diag. 0.40E+00    7.1     0.00000111     -4911.5175991645 -4.92E-07
    68 Broy./Diag. 0.40E+00    7.1     0.00000087     -4911.5175973144  1.85E-06

  *** SCF run converged in    68 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008331334232
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.99503727433921
  Hartree energy:                                            1781.35531354083037
  Exchange-correlation energy:                               -779.53739752018475
  Electronic entropic energy:                                  -0.24021144217207
  Fermi energy:                                                 0.08747843230256

  Total energy:                                             -4911.51759731436505

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.517603398699976

 MD| ***************************************************************************
 MD| Step number                                                            1234
 MD| Time [fs]                                                       2468.000000
 MD| Conserved quantity [hartree]                            -0.491117181647E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    494.005105           591.451239
 MD| Energy drift per atom [K]           0.306787912542E+03   0.269042271625E+03
 MD| Potential energy [hartree]         -0.491151760340E+04  -0.491156247286E+04
 MD| Kinetic energy [hartree]            0.345786928208E+00   0.372482451736E+00
 MD| Temperature [K]                             921.440890           992.578186
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.03274346     -4911.5167297651 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.2     0.10659956     -4911.6301002242 -1.13E-01
     3 Broy./Diag. 0.40E+00    6.5     0.09674928     -4911.0849786574  5.45E-01
     4 Broy./Diag. 0.40E+00    7.3     0.02456262     -4911.5441914356 -4.59E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01260585     -4911.5536301778 -9.44E-03
     6 Broy./Diag. 0.40E+00    6.8     0.00482509     -4911.4969392247  5.67E-02
     7 Broy./Diag. 0.40E+00    6.9     0.00426094     -4911.5325745685 -3.56E-02
     8 Broy./Diag. 0.40E+00    7.3     0.00318499     -4911.5075854011  2.50E-02
     9 Broy./Diag. 0.40E+00    6.9     0.00172982     -4911.5167728962 -9.19E-03
    10 Broy./Diag. 0.40E+00    6.9     0.00181870     -4911.5139966182  2.78E-03
    11 Broy./Diag. 0.40E+00    7.3     0.00123756     -4911.5183047537 -4.31E-03
    12 Broy./Diag. 0.40E+00    7.3     0.00067971     -4911.5195608174 -1.26E-03
    13 Broy./Diag. 0.40E+00    7.5     0.00034804     -4911.5156842325  3.88E-03
    14 Broy./Diag. 0.40E+00    7.2     0.00032292     -4911.5184687337 -2.78E-03
    15 Broy./Diag. 0.40E+00    7.1     0.00020602     -4911.5174087677  1.06E-03
    16 Broy./Diag. 0.40E+00    6.9     0.00031646     -4911.5179016022 -4.93E-04
    17 Broy./Diag. 0.40E+00    7.5     0.00028045     -4911.5172774315  6.24E-04
    18 Broy./Diag. 0.40E+00    7.1     0.00019776     -4911.5174197739 -1.42E-04
    19 Broy./Diag. 0.40E+00    6.9     0.00016733     -4911.5186031457 -1.18E-03
    20 Broy./Diag. 0.40E+00    7.1     0.00019418     -4911.5174831966  1.12E-03
    21 Broy./Diag. 0.40E+00    7.1     0.00011600     -4911.5180938815 -6.11E-04
    22 Broy./Diag. 0.40E+00    6.7     0.00010194     -4911.5180153766  7.85E-05
    23 Broy./Diag. 0.40E+00    7.2     0.00011069     -4911.5182909843 -2.76E-04
    24 Broy./Diag. 0.40E+00    7.3     0.00009676     -4911.5182182089  7.28E-05
    25 Broy./Diag. 0.40E+00    7.5     0.00009587     -4911.5177309029  4.87E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00009113     -4911.5183941384 -6.63E-04
    27 Broy./Diag. 0.40E+00    7.3     0.00007788     -4911.5180750129  3.19E-04
    28 Broy./Diag. 0.40E+00    7.4     0.00005484     -4911.5182441973 -1.69E-04
    29 Broy./Diag. 0.40E+00    7.3     0.00005104     -4911.5181456851  9.85E-05
    30 Broy./Diag. 0.40E+00    7.5     0.00003725     -4911.5182236870 -7.80E-05
    31 Broy./Diag. 0.40E+00    7.0     0.00004495     -4911.5183997169 -1.76E-04
    32 Broy./Diag. 0.40E+00    7.3     0.00003893     -4911.5181394602  2.60E-04
    33 Broy./Diag. 0.40E+00    7.0     0.00004150     -4911.5183571382 -2.18E-04
    34 Broy./Diag. 0.40E+00    7.1     0.00002929     -4911.5182888769  6.83E-05
    35 Broy./Diag. 0.40E+00    7.1     0.00003370     -4911.5183653695 -7.65E-05
    36 Broy./Diag. 0.40E+00    7.3     0.00002832     -4911.5183352715  3.01E-05
    37 Broy./Diag. 0.40E+00    7.5     0.00002989     -4911.5182589520  7.63E-05
    38 Broy./Diag. 0.40E+00    7.7     0.00001524     -4911.5184244646 -1.66E-04
    39 Broy./Diag. 0.40E+00    7.3     0.00002090     -4911.5183465379  7.79E-05
    40 Broy./Diag. 0.40E+00    7.1     0.00001512     -4911.5183897181 -4.32E-05
    41 Broy./Diag. 0.40E+00    7.0     0.00001531     -4911.5183712948  1.84E-05
    42 Broy./Diag. 0.40E+00    7.4     0.00001404     -4911.5183997359 -2.84E-05
    43 Broy./Diag. 0.40E+00    6.9     0.00002065     -4911.5184306714 -3.09E-05
    44 Broy./Diag. 0.40E+00    7.5     0.00000991     -4911.5183357411  9.49E-05
    45 Broy./Diag. 0.40E+00    6.8     0.00001223     -4911.5184279073 -9.22E-05
    46 Broy./Diag. 0.40E+00    7.5     0.00000803     -4911.5183986045  2.93E-05
    47 Broy./Diag. 0.40E+00    6.9     0.00000804     -4911.5184192927 -2.07E-05
    48 Broy./Diag. 0.40E+00    6.7     0.00000703     -4911.5184129833  6.31E-06
    49 Broy./Diag. 0.40E+00    7.7     0.00000729     -4911.5184083617  4.62E-06
    50 Broy./Diag. 0.40E+00    7.1     0.00000435     -4911.5184393057 -3.09E-05
    51 Broy./Diag. 0.40E+00    7.3     0.00000691     -4911.5184051337  3.42E-05
    52 Broy./Diag. 0.40E+00    7.3     0.00000505     -4911.5184342702 -2.91E-05
    53 Broy./Diag. 0.40E+00    7.8     0.00000539     -4911.5184259244  8.35E-06
    54 Broy./Diag. 0.40E+00    7.3     0.00000536     -4911.5184329038 -6.98E-06
    55 Broy./Diag. 0.40E+00    7.1     0.00000524     -4911.5184364822 -3.58E-06
    56 Broy./Diag. 0.40E+00    7.3     0.00000252     -4911.5184245127  1.20E-05
    57 Broy./Diag. 0.40E+00    7.1     0.00000267     -4911.5184455055 -2.10E-05
    58 Broy./Diag. 0.40E+00    7.3     0.00000189     -4911.5184346869  1.08E-05
    59 Broy./Diag. 0.40E+00    7.1     0.00000269     -4911.5184413754 -6.69E-06
    60 Broy./Diag. 0.40E+00    7.1     0.00000313     -4911.5184405311  8.44E-07
    61 Broy./Diag. 0.40E+00    7.0     0.00000274     -4911.5184425572 -2.03E-06
    62 Broy./Diag. 0.40E+00    7.7     0.00000195     -4911.5184479988 -5.44E-06
    63 Broy./Diag. 0.40E+00    6.9     0.00000220     -4911.5184341712  1.38E-05
    64 Broy./Diag. 0.40E+00    7.3     0.00000126     -4911.5184486031 -1.44E-05
    65 Broy./Diag. 0.40E+00    7.1     0.00000127     -4911.5184451410  3.46E-06
    66 Broy./Diag. 0.40E+00    6.8     0.00000145     -4911.5184461500 -1.01E-06
    67 Broy./Diag. 0.40E+00    7.1     0.00000116     -4911.5184461950 -4.51E-08
    68 Broy./Diag. 0.40E+00    7.0     0.00000094     -4911.5184457504  4.45E-07

  *** SCF run converged in    68 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008338360799
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2750.00300801986987
  Hartree energy:                                            1781.35053347011171
  Exchange-correlation energy:                               -779.54125038488428
  Electronic entropic energy:                                  -0.24039776292170
  Fermi energy:                                                 0.08749659200862

  Total energy:                                             -4911.51844575039286

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.518453488149135

 MD| ***************************************************************************
 MD| Step number                                                            1235
 MD| Time [fs]                                                       2470.000000
 MD| Conserved quantity [hartree]                            -0.491117514845E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    496.395455           591.374270
 MD| Energy drift per atom [K]           0.299865847649E+03   0.269067229986E+03
 MD| Potential energy [hartree]         -0.491151845349E+04  -0.491156243721E+04
 MD| Kinetic energy [hartree]            0.343305040658E+00   0.372458826302E+00
 MD| Temperature [K]                             914.827243           992.515230
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02855630     -4911.5177195865 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.5     0.10809133     -4911.6145898560 -9.69E-02
     3 Broy./Diag. 0.40E+00    6.8     0.09921239     -4911.1071967368  5.07E-01
     4 Broy./Diag. 0.40E+00    6.7     0.02619735     -4911.5587993603 -4.52E-01
     5 Broy./Diag. 0.40E+00    6.5     0.01554926     -4911.5416175492  1.72E-02
     6 Broy./Diag. 0.40E+00    7.0     0.00426470     -4911.4984479709  4.32E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00415894     -4911.5352508756 -3.68E-02
     8 Broy./Diag. 0.40E+00    7.0     0.00279997     -4911.5051484335  3.01E-02
     9 Broy./Diag. 0.40E+00    8.2     0.00152610     -4911.5182513951 -1.31E-02
    10 Broy./Diag. 0.40E+00    6.8     0.00177461     -4911.5145496958  3.70E-03
    11 Broy./Diag. 0.40E+00    7.4     0.00101762     -4911.5190653900 -4.52E-03
    12 Broy./Diag. 0.40E+00    6.9     0.00062925     -4911.5193857336 -3.20E-04
    13 Broy./Diag. 0.40E+00    7.1     0.00030521     -4911.5161366076  3.25E-03
    14 Broy./Diag. 0.40E+00    6.9     0.00028164     -4911.5193052833 -3.17E-03
    15 Broy./Diag. 0.40E+00    7.1     0.00027060     -4911.5178182016  1.49E-03
    16 Broy./Diag. 0.40E+00    7.2     0.00036717     -4911.5187063166 -8.88E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00028373     -4911.5179115283  7.95E-04
    18 Broy./Diag. 0.40E+00    7.6     0.00020466     -4911.5182422157 -3.31E-04
    19 Broy./Diag. 0.40E+00    6.9     0.00017249     -4911.5194074382 -1.17E-03
    20 Broy./Diag. 0.40E+00    6.9     0.00018842     -4911.5179819972  1.43E-03
    21 Broy./Diag. 0.40E+00    7.5     0.00014695     -4911.5189942111 -1.01E-03
    22 Broy./Diag. 0.40E+00    7.3     0.00012771     -4911.5187982114  1.96E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00012531     -4911.5191661801 -3.68E-04
    24 Broy./Diag. 0.40E+00    7.7     0.00009300     -4911.5190293770  1.37E-04
    25 Broy./Diag. 0.40E+00    7.3     0.00008988     -4911.5186123100  4.17E-04
    26 Broy./Diag. 0.40E+00    6.9     0.00008725     -4911.5193305053 -7.18E-04
    27 Broy./Diag. 0.40E+00    7.5     0.00009692     -4911.5188396037  4.91E-04
    28 Broy./Diag. 0.40E+00    7.1     0.00007060     -4911.5191328017 -2.93E-04
    29 Broy./Diag. 0.40E+00    7.1     0.00006631     -4911.5189935254  1.39E-04
    30 Broy./Diag. 0.40E+00    6.6     0.00004754     -4911.5191214346 -1.28E-04
    31 Broy./Diag. 0.40E+00    7.1     0.00004832     -4911.5193105189 -1.89E-04
    32 Broy./Diag. 0.40E+00    7.7     0.00003594     -4911.5190050733  3.05E-04
    33 Broy./Diag. 0.40E+00    7.1     0.00004688     -4911.5193029343 -2.98E-04
    34 Broy./Diag. 0.40E+00    7.3     0.00003385     -4911.5191721538  1.31E-04
    35 Broy./Diag. 0.40E+00    6.6     0.00003978     -4911.5192824073 -1.10E-04
    36 Broy./Diag. 0.40E+00    7.3     0.00003615     -4911.5192355873  4.68E-05
    37 Broy./Diag. 0.40E+00    7.3     0.00003533     -4911.5191558954  7.97E-05
    38 Broy./Diag. 0.40E+00    7.3     0.00002032     -4911.5193653472 -2.09E-04
    39 Broy./Diag. 0.40E+00    6.7     0.00002768     -4911.5192400851  1.25E-04
    40 Broy./Diag. 0.40E+00    8.5     0.00001880     -4911.5193282453 -8.82E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00001786     -4911.5192927901  3.55E-05
    42 Broy./Diag. 0.40E+00   10.8     0.00001735     -4911.5193335117 -4.07E-05
    43 Broy./Diag. 0.40E+00    7.6     0.00002305     -4911.5193644243 -3.09E-05
    44 Broy./Diag. 0.40E+00    9.5     0.00001275     -4911.5192542330  1.10E-04
    45 Broy./Diag. 0.40E+00    9.0     0.00001524     -4911.5193747688 -1.21E-04
    46 Broy./Diag. 0.40E+00    7.1     0.00001125     -4911.5193208489  5.39E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00001107     -4911.5193584635 -3.76E-05
    48 Broy./Diag. 0.40E+00    7.1     0.00001008     -4911.5193464376  1.20E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00000946     -4911.5193436604  2.78E-06
    50 Broy./Diag. 0.40E+00    7.2     0.00000603     -4911.5193854937 -4.18E-05
    51 Broy./Diag. 0.40E+00    7.8     0.00000743     -4911.5193371158  4.84E-05
    52 Broy./Diag. 0.40E+00    7.2     0.00000649     -4911.5193816517 -4.45E-05
    53 Broy./Diag. 0.40E+00    9.8     0.00000683     -4911.5193647209  1.69E-05
    54 Broy./Diag. 0.40E+00    8.1     0.00000723     -4911.5193771012 -1.24E-05
    55 Broy./Diag. 0.40E+00    9.9     0.00000714     -4911.5193808794 -3.78E-06
    56 Broy./Diag. 0.40E+00    8.1     0.00000360     -4911.5193613702  1.95E-05
    57 Broy./Diag. 0.40E+00    7.7     0.00000335     -4911.5193960513 -3.47E-05
    58 Broy./Diag. 0.40E+00    7.1     0.00000295     -4911.5193772280  1.88E-05
    59 Broy./Diag. 0.40E+00    8.1     0.00000361     -4911.5193889819 -1.18E-05
    60 Broy./Diag. 0.40E+00    7.4     0.00000399     -4911.5193860199  2.96E-06
    61 Broy./Diag. 0.40E+00    9.4     0.00000338     -4911.5193887634 -2.74E-06
    62 Broy./Diag. 0.40E+00    7.5     0.00000244     -4911.5193981968 -9.43E-06
    63 Broy./Diag. 0.40E+00    8.6     0.00000248     -4911.5193761888  2.20E-05
    64 Broy./Diag. 0.40E+00    9.9     0.00000212     -4911.5193987825 -2.26E-05
    65 Broy./Diag. 0.40E+00    6.8     0.00000208     -4911.5193923686  6.41E-06
    66 Broy./Diag. 0.40E+00    7.3     0.00000228     -4911.5193956670 -3.30E-06
    67 Broy./Diag. 0.40E+00    6.7     0.00000171     -4911.5193956278  3.92E-08
    68 Broy./Diag. 0.40E+00    7.5     0.00000125     -4911.5193930937  2.53E-06
    69 Broy./Diag. 0.40E+00    6.9     0.00000114     -4911.5194028436 -9.75E-06
    70 Broy./Diag. 0.40E+00    6.7     0.00000129     -4911.5193930099  9.83E-06
    71 Broy./Diag. 0.40E+00    6.7     0.00000140     -4911.5193988599 -5.85E-06
    72 Broy./Diag. 0.40E+00    7.1     0.00000156     -4911.5193984373  4.23E-07
    73 Broy./Diag. 0.40E+00    7.5     0.00000116     -4911.5194000305 -1.59E-06
    74 Broy./Diag. 0.40E+00    6.7     0.00000103     -4911.5194021310 -2.10E-06
    75 Broy./Diag. 0.40E+00    6.9     0.00000071     -4911.5193964899  5.64E-06

  *** SCF run converged in    75 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008346895478
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2750.00043757136245
  Hartree energy:                                            1781.35267260984892
  Exchange-correlation energy:                               -779.54162848068233
  Electronic entropic energy:                                  -0.24053918744301
  Fermi energy:                                                 0.08749404782533

  Total energy:                                             -4911.51939648992993

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.519405775213272

 MD| ***************************************************************************
 MD| Step number                                                            1236
 MD| Time [fs]                                                       2472.000000
 MD| Conserved quantity [hartree]                            -0.491117371415E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    568.719625           591.355941
 MD| Energy drift per atom [K]           0.302845539846E+03   0.269094558716E+03
 MD| Potential energy [hartree]         -0.491151940578E+04  -0.491156240240E+04
 MD| Kinetic energy [hartree]            0.345691620238E+00   0.372437169987E+00
 MD| Temperature [K]                             921.186917           992.457521
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.02019026     -4911.5190820870 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.9     0.06827776     -4911.5508363643 -3.18E-02
     3 Broy./Diag. 0.40E+00    7.1     0.07343442     -4911.3195471995  2.31E-01
     4 Broy./Diag. 0.40E+00    7.7     0.03079437     -4911.5818115456 -2.62E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01409103     -4911.5063974706  7.54E-02
     6 Broy./Diag. 0.40E+00    7.1     0.00526738     -4911.5124645919 -6.07E-03
     7 Broy./Diag. 0.40E+00    7.1     0.00405245     -4911.5256522153 -1.32E-02
     8 Broy./Diag. 0.40E+00    7.7     0.00295194     -4911.5167483646  8.90E-03
     9 Broy./Diag. 0.40E+00    6.9     0.00216086     -4911.5110318248  5.72E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00154114     -4911.5219479073 -1.09E-02
    11 Broy./Diag. 0.40E+00    7.1     0.00110811     -4911.5243017871 -2.35E-03
    12 Broy./Diag. 0.40E+00    6.9     0.00060775     -4911.5195701052  4.73E-03
    13 Broy./Diag. 0.40E+00    8.3     0.00032399     -4911.5180481343  1.52E-03
    14 Broy./Diag. 0.40E+00    7.4     0.00035085     -4911.5197328303 -1.68E-03
    15 Broy./Diag. 0.40E+00    7.3     0.00034820     -4911.5200523775 -3.20E-04
    16 Broy./Diag. 0.40E+00    7.1     0.00029848     -4911.5187502852  1.30E-03
    17 Broy./Diag. 0.40E+00    6.9     0.00033317     -4911.5189596392 -2.09E-04
    18 Broy./Diag. 0.40E+00    7.3     0.00018757     -4911.5204546612 -1.50E-03
    19 Broy./Diag. 0.40E+00    7.6     0.00018111     -4911.5206700823 -2.15E-04
    20 Broy./Diag. 0.40E+00    7.3     0.00022941     -4911.5198227897  8.47E-04
    21 Broy./Diag. 0.40E+00    7.3     0.00017790     -4911.5195343431  2.88E-04
    22 Broy./Diag. 0.40E+00    7.1     0.00011058     -4911.5204961841 -9.62E-04
    23 Broy./Diag. 0.40E+00    7.3     0.00014834     -4911.5203888625  1.07E-04
    24 Broy./Diag. 0.40E+00    7.5     0.00007501     -4911.5197778640  6.11E-04
    25 Broy./Diag. 0.40E+00    7.3     0.00007777     -4911.5199992469 -2.21E-04
    26 Broy./Diag. 0.40E+00    7.9     0.00011110     -4911.5204705086 -4.71E-04
    27 Broy./Diag. 0.40E+00    6.9     0.00011575     -4911.5205886101 -1.18E-04
    28 Broy./Diag. 0.40E+00    7.0     0.00006290     -4911.5201346469  4.54E-04
    29 Broy./Diag. 0.40E+00    7.1     0.00007234     -4911.5202869524 -1.52E-04
    30 Broy./Diag. 0.40E+00    7.5     0.00003917     -4911.5205871940 -3.00E-04
    31 Broy./Diag. 0.40E+00    7.1     0.00004154     -4911.5204903352  9.69E-05
    32 Broy./Diag. 0.40E+00    7.3     0.00004146     -4911.5203263840  1.64E-04
    33 Broy./Diag. 0.40E+00    7.0     0.00005553     -4911.5203946675 -6.83E-05
    34 Broy./Diag. 0.40E+00    7.3     0.00003556     -4911.5206185609 -2.24E-04
    35 Broy./Diag. 0.40E+00    6.9     0.00004257     -4911.5205420707  7.65E-05
    36 Broy./Diag. 0.40E+00    7.7     0.00003120     -4911.5204107098  1.31E-04
    37 Broy./Diag. 0.40E+00    7.3     0.00002937     -4911.5205217923 -1.11E-04
    38 Broy./Diag. 0.40E+00    7.1     0.00002086     -4911.5206202697 -9.85E-05
    39 Broy./Diag. 0.40E+00    7.1     0.00003333     -4911.5206058445  1.44E-05
    40 Broy./Diag. 0.40E+00    7.9     0.00002247     -4911.5204764756  1.29E-04
    41 Broy./Diag. 0.40E+00    6.9     0.00001803     -4911.5205621822 -8.57E-05
    42 Broy./Diag. 0.40E+00    6.9     0.00001543     -4911.5206290537 -6.69E-05
    43 Broy./Diag. 0.40E+00    7.1     0.00001910     -4911.5205788196  5.02E-05
    44 Broy./Diag. 0.40E+00    7.5     0.00001113     -4911.5205447039  3.41E-05
    45 Broy./Diag. 0.40E+00    6.9     0.00001791     -4911.5205926523 -4.79E-05
    46 Broy./Diag. 0.40E+00    6.9     0.00001462     -4911.5206586455 -6.60E-05
    47 Broy./Diag. 0.40E+00    7.3     0.00001114     -4911.5206105478  4.81E-05
    48 Broy./Diag. 0.40E+00    7.3     0.00000891     -4911.5205826551  2.79E-05
    49 Broy./Diag. 0.40E+00    7.3     0.00000811     -4911.5206240923 -4.14E-05
    50 Broy./Diag. 0.40E+00    7.1     0.00000554     -4911.5206353070 -1.12E-05
    51 Broy./Diag. 0.40E+00    7.3     0.00000885     -4911.5206214581  1.38E-05
    52 Broy./Diag. 0.40E+00    7.3     0.00000863     -4911.5206053092  1.61E-05
    53 Broy./Diag. 0.40E+00    7.1     0.00000648     -4911.5206396578 -3.43E-05
    54 Broy./Diag. 0.40E+00    7.3     0.00000632     -4911.5206538169 -1.42E-05
    55 Broy./Diag. 0.40E+00    7.3     0.00000594     -4911.5206290857  2.47E-05
    56 Broy./Diag. 0.40E+00    7.3     0.00000345     -4911.5206333905 -4.30E-06
    57 Broy./Diag. 0.40E+00    6.9     0.00000429     -4911.5206431975 -9.81E-06
    58 Broy./Diag. 0.40E+00    7.1     0.00000415     -4911.5206533411 -1.01E-05
    59 Broy./Diag. 0.40E+00    7.5     0.00000360     -4911.5206397924  1.35E-05
    60 Broy./Diag. 0.40E+00    7.1     0.00000365     -4911.5206349372  4.86E-06
    61 Broy./Diag. 0.40E+00    7.3     0.00000276     -4911.5206544183 -1.95E-05
    62 Broy./Diag. 0.40E+00    7.1     0.00000234     -4911.5206510138  3.40E-06
    63 Broy./Diag. 0.40E+00    6.9     0.00000321     -4911.5206471725  3.84E-06
    64 Broy./Diag. 0.40E+00    7.1     0.00000274     -4911.5206458041  1.37E-06
    65 Broy./Diag. 0.40E+00    7.0     0.00000180     -4911.5206566599 -1.09E-05
    66 Broy./Diag. 0.40E+00    7.1     0.00000208     -4911.5206580176 -1.36E-06
    67 Broy./Diag. 0.40E+00    6.9     0.00000129     -4911.5206487391  9.28E-06
    68 Broy./Diag. 0.40E+00    7.5     0.00000113     -4911.5206541363 -5.40E-06
    69 Broy./Diag. 0.40E+00    7.1     0.00000156     -4911.5206568316 -2.70E-06
    70 Broy./Diag. 0.40E+00    7.1     0.00000162     -4911.5206578340 -1.00E-06
    71 Broy./Diag. 0.40E+00    8.3     0.00000118     -4911.5206533205  4.51E-06
    72 Broy./Diag. 0.40E+00    7.3     0.00000149     -4911.5206546338 -1.31E-06
    73 Broy./Diag. 0.40E+00    7.5     0.00000084     -4911.5206618325 -7.20E-06

  *** SCF run converged in    73 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008354314366
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.98770332005824
  Hartree energy:                                            1781.36139112622618
  Exchange-correlation energy:                               -779.53885614625676
  Electronic entropic energy:                                  -0.24056114223387
  Fermi energy:                                                 0.08747134899659

  Total energy:                                             -4911.52066183245370

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.520663095647251

 MD| ***************************************************************************
 MD| Step number                                                            1237
 MD| Time [fs]                                                       2474.000000
 MD| Conserved quantity [hartree]                            -0.491117262194E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    537.629024           591.312508
 MD| Energy drift per atom [K]           0.305114577498E+03   0.269123677567E+03
 MD| Potential energy [hartree]         -0.491152066310E+04  -0.491156236866E+04
 MD| Kinetic energy [hartree]            0.348041155405E+00   0.372417448067E+00
 MD| Temperature [K]                             927.447876           992.404967
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.01787086     -4911.5209204893 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.04099639     -4911.5116849329  9.24E-03
     3 Broy./Diag. 0.40E+00    7.5     0.04638524     -4911.4756680922  3.60E-02
     4 Broy./Diag. 0.40E+00    7.3     0.02739707     -4911.5664285810 -9.08E-02
     5 Broy./Diag. 0.40E+00    7.8     0.01104836     -4911.4905214961  7.59E-02
     6 Broy./Diag. 0.40E+00    7.3     0.00444573     -4911.5263462059 -3.58E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00457449     -4911.5200187839  6.33E-03
     8 Broy./Diag. 0.40E+00    7.0     0.00259060     -4911.5218957387 -1.88E-03
     9 Broy./Diag. 0.40E+00    7.0     0.00155790     -4911.5132074803  8.69E-03
    10 Broy./Diag. 0.40E+00    6.9     0.00116737     -4911.5242091600 -1.10E-02
    11 Broy./Diag. 0.40E+00    6.7     0.00091810     -4911.5258015792 -1.59E-03
    12 Broy./Diag. 0.40E+00    7.3     0.00044225     -4911.5201276180  5.67E-03
    13 Broy./Diag. 0.40E+00    7.7     0.00031153     -4911.5206769612 -5.49E-04
    14 Broy./Diag. 0.40E+00    7.1     0.00033343     -4911.5211290403 -4.52E-04
    15 Broy./Diag. 0.40E+00    6.9     0.00028517     -4911.5218090944 -6.80E-04
    16 Broy./Diag. 0.40E+00    7.0     0.00026331     -4911.5203892655  1.42E-03
    17 Broy./Diag. 0.40E+00    7.1     0.00026623     -4911.5208674135 -4.78E-04
    18 Broy./Diag. 0.40E+00    7.1     0.00015038     -4911.5224301891 -1.56E-03
    19 Broy./Diag. 0.40E+00    7.1     0.00014378     -4911.5219967010  4.33E-04
    20 Broy./Diag. 0.40E+00    7.2     0.00021120     -4911.5218298571  1.67E-04
    21 Broy./Diag. 0.40E+00    7.3     0.00014210     -4911.5213498526  4.80E-04
    22 Broy./Diag. 0.40E+00    7.7     0.00009574     -4911.5222938468 -9.44E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00012772     -4911.5220943728  1.99E-04
    24 Broy./Diag. 0.40E+00    6.9     0.00008670     -4911.5213535576  7.41E-04
    25 Broy./Diag. 0.40E+00    6.8     0.00005546     -4911.5219827294 -6.29E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00009136     -4911.5221076650 -1.25E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00008048     -4911.5223097918 -2.02E-04
    28 Broy./Diag. 0.40E+00    7.3     0.00004515     -4911.5219018863  4.08E-04
    29 Broy./Diag. 0.40E+00    7.5     0.00004734     -4911.5220841218 -1.82E-04
    30 Broy./Diag. 0.40E+00    7.2     0.00003793     -4911.5223507051 -2.67E-04
    31 Broy./Diag. 0.40E+00    7.0     0.00002714     -4911.5221234024  2.27E-04
    32 Broy./Diag. 0.40E+00    7.1     0.00004292     -4911.5221238528 -4.50E-07
    33 Broy./Diag. 0.40E+00    7.3     0.00004573     -4911.5221336147 -9.76E-06
    34 Broy./Diag. 0.40E+00    6.9     0.00003017     -4911.5223634080 -2.30E-04
    35 Broy./Diag. 0.40E+00    7.3     0.00003090     -4911.5222663972  9.70E-05
    36 Broy./Diag. 0.40E+00    6.9     0.00002731     -4911.5221470302  1.19E-04
    37 Broy./Diag. 0.40E+00    6.7     0.00001460     -4911.5223185328 -1.72E-04
    38 Broy./Diag. 0.40E+00    7.3     0.00001914     -4911.5223218585 -3.33E-06
    39 Broy./Diag. 0.40E+00    7.0     0.00002468     -4911.5223407770 -1.89E-05
    40 Broy./Diag. 0.40E+00    7.1     0.00001795     -4911.5222259128  1.15E-04
    41 Broy./Diag. 0.40E+00    7.3     0.00001304     -4911.5223160760 -9.02E-05
    42 Broy./Diag. 0.40E+00    6.7     0.00001492     -4911.5223744615 -5.84E-05
    43 Broy./Diag. 0.40E+00    6.9     0.00001148     -4911.5222888258  8.56E-05
    44 Broy./Diag. 0.40E+00    7.7     0.00001216     -4911.5223187486 -2.99E-05
    45 Broy./Diag. 0.40E+00    6.9     0.00001212     -4911.5223256601 -6.91E-06
    46 Broy./Diag. 0.40E+00    7.3     0.00000954     -4911.5223837965 -5.81E-05
    47 Broy./Diag. 0.40E+00    7.5     0.00000669     -4911.5223445824  3.92E-05
    48 Broy./Diag. 0.40E+00    7.4     0.00000616     -4911.5223264931  1.81E-05
    49 Broy./Diag. 0.40E+00    7.3     0.00000488     -4911.5223702069 -4.37E-05
    50 Broy./Diag. 0.40E+00    8.3     0.00000657     -4911.5223614333  8.77E-06
    51 Broy./Diag. 0.40E+00    6.9     0.00000758     -4911.5223639090 -2.48E-06
    52 Broy./Diag. 0.40E+00    7.1     0.00000651     -4911.5223454490  1.85E-05
    53 Broy./Diag. 0.40E+00    7.1     0.00000463     -4911.5223767300 -3.13E-05
    54 Broy./Diag. 0.40E+00    6.8     0.00000432     -4911.5223876106 -1.09E-05
    55 Broy./Diag. 0.40E+00    7.3     0.00000331     -4911.5223645668  2.30E-05
    56 Broy./Diag. 0.40E+00    7.1     0.00000325     -4911.5223774633 -1.29E-05
    57 Broy./Diag. 0.40E+00    7.1     0.00000310     -4911.5223764817  9.82E-07
    58 Broy./Diag. 0.40E+00    6.8     0.00000285     -4911.5223867040 -1.02E-05
    59 Broy./Diag. 0.40E+00    6.9     0.00000267     -4911.5223764232  1.03E-05
    60 Broy./Diag. 0.40E+00    6.9     0.00000255     -4911.5223724565  3.97E-06
    61 Broy./Diag. 0.40E+00    7.1     0.00000207     -4911.5223904663 -1.80E-05
    62 Broy./Diag. 0.40E+00    7.3     0.00000242     -4911.5223828751  7.59E-06
    63 Broy./Diag. 0.40E+00    6.9     0.00000249     -4911.5223867236 -3.85E-06
    64 Broy./Diag. 0.40E+00    6.7     0.00000160     -4911.5223822557  4.47E-06
    65 Broy./Diag. 0.40E+00    6.9     0.00000109     -4911.5223894543 -7.20E-06
    66 Broy./Diag. 0.40E+00    7.1     0.00000116     -4911.5223908016 -1.35E-06
    67 Broy./Diag. 0.40E+00    7.1     0.00000095     -4911.5223846244  6.18E-06

  *** SCF run converged in    67 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008357610667
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.96727822102730
  Hartree energy:                                            1781.37493630710856
  Exchange-correlation energy:                               -779.53376461775929
  Electronic entropic energy:                                  -0.24049562940565
  Fermi energy:                                                 0.08743357362418

  Total energy:                                             -4911.52238462438163

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.522396258201297

 MD| ***************************************************************************
 MD| Step number                                                            1238
 MD| Time [fs]                                                       2476.000000
 MD| Conserved quantity [hartree]                            -0.491119237836E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    486.969228           591.228224
 MD| Energy drift per atom [K]           0.264071302402E+03   0.269119596488E+03
 MD| Potential energy [hartree]         -0.491152239626E+04  -0.491156233637E+04
 MD| Kinetic energy [hartree]            0.330017894017E+00   0.372383199639E+00
 MD| Temperature [K]                             879.420121           992.313703
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.01745125     -4911.5232788315 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.04731703     -4911.4845195585  3.88E-02
     3 Broy./Diag. 0.40E+00    7.5     0.04777483     -4911.5601093373 -7.56E-02
     4 Broy./Diag. 0.40E+00    7.1     0.02672572     -4911.5005574234  5.96E-02
     5 Broy./Diag. 0.40E+00    7.5     0.01252691     -4911.5195344236 -1.90E-02
     6 Broy./Diag. 0.40E+00    7.1     0.00481110     -4911.5209679117 -1.43E-03
     7 Broy./Diag. 0.40E+00    7.7     0.00363126     -4911.5265717494 -5.60E-03
     8 Broy./Diag. 0.40E+00    7.0     0.00263725     -4911.5194348830  7.14E-03
     9 Broy./Diag. 0.40E+00    7.5     0.00104371     -4911.5155411997  3.89E-03
    10 Broy./Diag. 0.40E+00    7.3     0.00108608     -4911.5275074559 -1.20E-02
    11 Broy./Diag. 0.40E+00    7.3     0.00072434     -4911.5241762413  3.33E-03
    12 Broy./Diag. 0.40E+00    7.0     0.00045707     -4911.5226836516  1.49E-03
    13 Broy./Diag. 0.40E+00    7.4     0.00024468     -4911.5224323581  2.51E-04
    14 Broy./Diag. 0.40E+00    6.9     0.00030782     -4911.5237718096 -1.34E-03
    15 Broy./Diag. 0.40E+00    7.3     0.00026362     -4911.5237949565 -2.31E-05
    16 Broy./Diag. 0.40E+00    7.1     0.00031600     -4911.5221659027  1.63E-03
    17 Broy./Diag. 0.40E+00    6.8     0.00027525     -4911.5240581271 -1.89E-03
    18 Broy./Diag. 0.40E+00    7.1     0.00019556     -4911.5244725621 -4.14E-04
    19 Broy./Diag. 0.40E+00    7.5     0.00012958     -4911.5244400757  3.25E-05
    20 Broy./Diag. 0.40E+00    7.2     0.00014459     -4911.5238121735  6.28E-04
    21 Broy./Diag. 0.40E+00    7.9     0.00009812     -4911.5238768501 -6.47E-05
    22 Broy./Diag. 0.40E+00    7.3     0.00009032     -4911.5246321159 -7.55E-04
    23 Broy./Diag. 0.40E+00    6.9     0.00013101     -4911.5241077321  5.24E-04
    24 Broy./Diag. 0.40E+00    7.3     0.00009718     -4911.5238913615  2.16E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00006225     -4911.5243955709 -5.04E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00008194     -4911.5246469387 -2.51E-04
    27 Broy./Diag. 0.40E+00    6.5     0.00006719     -4911.5246448181  2.12E-06
    28 Broy./Diag. 0.40E+00    7.4     0.00004305     -4911.5242074228  4.37E-04
    29 Broy./Diag. 0.40E+00    7.1     0.00003884     -4911.5245599761 -3.53E-04
    30 Broy./Diag. 0.40E+00    7.3     0.00003373     -4911.5246154273 -5.55E-05
    31 Broy./Diag. 0.40E+00    6.5     0.00002550     -4911.5244966073  1.19E-04
    32 Broy./Diag. 0.40E+00    6.8     0.00002952     -4911.5244565255  4.01E-05
    33 Broy./Diag. 0.40E+00    6.9     0.00003361     -4911.5245847036 -1.28E-04
    34 Broy./Diag. 0.40E+00    7.9     0.00003177     -4911.5247767885 -1.92E-04
    35 Broy./Diag. 0.40E+00    7.3     0.00003167     -4911.5245606048  2.16E-04
    36 Broy./Diag. 0.40E+00    6.9     0.00002784     -4911.5245953241 -3.47E-05
    37 Broy./Diag. 0.40E+00    7.3     0.00001438     -4911.5246825042 -8.72E-05
    38 Broy./Diag. 0.40E+00    7.4     0.00001361     -4911.5247183714 -3.59E-05
    39 Broy./Diag. 0.40E+00    7.1     0.00001458     -4911.5246844756  3.39E-05
    40 Broy./Diag. 0.40E+00    7.1     0.00001294     -4911.5246102282  7.42E-05
    41 Broy./Diag. 0.40E+00    6.8     0.00001046     -4911.5247215291 -1.11E-04
    42 Broy./Diag. 0.40E+00    6.8     0.00001569     -4911.5247165553  4.97E-06
    43 Broy./Diag. 0.40E+00    6.9     0.00001253     -4911.5246706309  4.59E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00000992     -4911.5246942546 -2.36E-05
    45 Broy./Diag. 0.40E+00    7.3     0.00000911     -4911.5247237224 -2.95E-05
    46 Broy./Diag. 0.40E+00    7.5     0.00000829     -4911.5247690921 -4.54E-05
    47 Broy./Diag. 0.40E+00    6.9     0.00000555     -4911.5247060916  6.30E-05
    48 Broy./Diag. 0.40E+00    7.1     0.00000419     -4911.5247221202 -1.60E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00000382     -4911.5247393061 -1.72E-05
    50 Broy./Diag. 0.40E+00    6.8     0.00000453     -4911.5247375131  1.79E-06
    51 Broy./Diag. 0.40E+00    7.1     0.00000501     -4911.5247297299  7.78E-06
    52 Broy./Diag. 0.40E+00    6.7     0.00000488     -4911.5247236702  6.06E-06
    53 Broy./Diag. 0.40E+00    7.1     0.00000460     -4911.5247640491 -4.04E-05
    54 Broy./Diag. 0.40E+00    6.9     0.00000382     -4911.5247496894  1.44E-05
    55 Broy./Diag. 0.40E+00    7.5     0.00000290     -4911.5247437075  5.98E-06
    56 Broy./Diag. 0.40E+00    7.0     0.00000203     -4911.5247483622 -4.65E-06
    57 Broy./Diag. 0.40E+00    6.7     0.00000175     -4911.5247531028 -4.74E-06
    58 Broy./Diag. 0.40E+00    7.1     0.00000171     -4911.5247573622 -4.26E-06
    59 Broy./Diag. 0.40E+00    7.1     0.00000215     -4911.5247458869  1.15E-05
    60 Broy./Diag. 0.40E+00    6.9     0.00000187     -4911.5247553970 -9.51E-06
    61 Broy./Diag. 0.40E+00    7.1     0.00000184     -4911.5247601255 -4.73E-06
    62 Broy./Diag. 0.40E+00    7.5     0.00000181     -4911.5247573115  2.81E-06
    63 Broy./Diag. 0.40E+00    7.1     0.00000165     -4911.5247575458 -2.34E-07
    64 Broy./Diag. 0.40E+00    7.3     0.00000110     -4911.5247547250  2.82E-06
    65 Broy./Diag. 0.40E+00    6.9     0.00000104     -4911.5247636397 -8.91E-06
    66 Broy./Diag. 0.40E+00    6.9     0.00000088     -4911.5247595722  4.07E-06

  *** SCF run converged in    66 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008355396645
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.93936304192721
  Hartree energy:                                            1781.39271499906909
  Exchange-correlation energy:                               -779.52611827531848
  Electronic entropic energy:                                  -0.24038037681211
  Fermi energy:                                                 0.08738086848659

  Total energy:                                             -4911.52475957222032

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.524766192592324

 MD| ***************************************************************************
 MD| Step number                                                            1239
 MD| Time [fs]                                                       2478.000000
 MD| Conserved quantity [hartree]                            -0.491120209603E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    479.347146           591.137925
 MD| Energy drift per atom [K]           0.243883194527E+03   0.269099228125E+03
 MD| Potential energy [hartree]         -0.491152476619E+04  -0.491156230605E+04
 MD| Kinetic energy [hartree]            0.322670162922E+00   0.372343076123E+00
 MD| Temperature [K]                             859.840144           992.206783
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.6     0.01408931     -4911.5260219681 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.9     0.03110124     -4911.4603908997  6.56E-02
     3 Broy./Diag. 0.40E+00    7.1     0.03539675     -4911.6449299278 -1.85E-01
     4 Broy./Diag. 0.40E+00    8.6     0.02122109     -4911.4176430876  2.27E-01
     5 Broy./Diag. 0.40E+00    8.6     0.00886666     -4911.5387674660 -1.21E-01
     6 Broy./Diag. 0.40E+00    6.9     0.00462473     -4911.5174793502  2.13E-02
     7 Broy./Diag. 0.40E+00    7.4     0.00447188     -4911.5316340275 -1.42E-02
     8 Broy./Diag. 0.40E+00   10.9     0.00309492     -4911.5174069593  1.42E-02
     9 Broy./Diag. 0.40E+00    7.3     0.00097374     -4911.5220605636 -4.65E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00072595     -4911.5308693043 -8.81E-03
    11 Broy./Diag. 0.40E+00    7.1     0.00046353     -4911.5246257644  6.24E-03
    12 Broy./Diag. 0.40E+00    7.6     0.00033104     -4911.5258204427 -1.19E-03
    13 Broy./Diag. 0.40E+00    8.1     0.00019842     -4911.5254256260  3.95E-04
    14 Broy./Diag. 0.40E+00    8.1     0.00031978     -4911.5266122534 -1.19E-03
    15 Broy./Diag. 0.40E+00    8.9     0.00036771     -4911.5260047699  6.07E-04
    16 Broy./Diag. 0.40E+00    7.6     0.00021938     -4911.5259259781  7.88E-05
    17 Broy./Diag. 0.40E+00   11.1     0.00017036     -4911.5279881091 -2.06E-03
    18 Broy./Diag. 0.40E+00    7.5     0.00014511     -4911.5271459021  8.42E-04
    19 Broy./Diag. 0.40E+00    7.2     0.00010134     -4911.5273241576 -1.78E-04
    20 Broy./Diag. 0.40E+00    7.1     0.00009378     -4911.5267981878  5.26E-04
    21 Broy./Diag. 0.40E+00    7.7     0.00011458     -4911.5274585923 -6.60E-04
    22 Broy./Diag. 0.40E+00    7.2     0.00008482     -4911.5275475325 -8.89E-05
    23 Broy./Diag. 0.40E+00    7.8     0.00006142     -4911.5269232444  6.24E-04
    24 Broy./Diag. 0.40E+00    8.8     0.00004604     -4911.5273953530 -4.72E-04
    25 Broy./Diag. 0.40E+00    7.3     0.00003323     -4911.5274452711 -4.99E-05
    26 Broy./Diag. 0.40E+00   10.6     0.00003451     -4911.5275672630 -1.22E-04
    27 Broy./Diag. 0.40E+00    8.1     0.00005091     -4911.5273933741  1.74E-04
    28 Broy./Diag. 0.40E+00    7.1     0.00003695     -4911.5273769955  1.64E-05
    29 Broy./Diag. 0.40E+00    7.1     0.00002787     -4911.5276520916 -2.75E-04
    30 Broy./Diag. 0.40E+00    6.9     0.00003084     -4911.5274437548  2.08E-04
    31 Broy./Diag. 0.40E+00    6.9     0.00002048     -4911.5274696586 -2.59E-05
    32 Broy./Diag. 0.40E+00    7.1     0.00002132     -4911.5274835573 -1.39E-05
    33 Broy./Diag. 0.40E+00    7.1     0.00002881     -4911.5276030668 -1.20E-04
    34 Broy./Diag. 0.40E+00    7.1     0.00002303     -4911.5276181186 -1.51E-05
    35 Broy./Diag. 0.40E+00    7.4     0.00001262     -4911.5275013580  1.17E-04
    36 Broy./Diag. 0.40E+00    6.7     0.00001546     -4911.5276264093 -1.25E-04
    37 Broy./Diag. 0.40E+00    7.1     0.00000892     -4911.5276095457  1.69E-05
    38 Broy./Diag. 0.40E+00    7.3     0.00001251     -4911.5276266285 -1.71E-05
    39 Broy./Diag. 0.40E+00    7.2     0.00001683     -4911.5275629518  6.37E-05
    40 Broy./Diag. 0.40E+00    7.3     0.00001395     -4911.5275970648 -3.41E-05
    41 Broy./Diag. 0.40E+00    6.9     0.00000786     -4911.5276699801 -7.29E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00001088     -4911.5276061667  6.38E-05
    43 Broy./Diag. 0.40E+00    7.1     0.00000631     -4911.5276264690 -2.03E-05
    44 Broy./Diag. 0.40E+00    7.2     0.00000526     -4911.5276325638 -6.09E-06
    45 Broy./Diag. 0.40E+00    7.0     0.00000663     -4911.5276595011 -2.69E-05
    46 Broy./Diag. 0.40E+00    7.5     0.00000653     -4911.5276519214  7.58E-06
    47 Broy./Diag. 0.40E+00    7.1     0.00000377     -4911.5276227660  2.92E-05
    48 Broy./Diag. 0.40E+00    6.8     0.00000485     -4911.5276612185 -3.85E-05
    49 Broy./Diag. 0.40E+00    7.7     0.00000401     -4911.5276540197  7.20E-06
    50 Broy./Diag. 0.40E+00    7.1     0.00000398     -4911.5276542128 -1.93E-07
    51 Broy./Diag. 0.40E+00    6.9     0.00000478     -4911.5276448622  9.35E-06
    52 Broy./Diag. 0.40E+00    7.5     0.00000433     -4911.5276576827 -1.28E-05
    53 Broy./Diag. 0.40E+00    7.3     0.00000252     -4911.5276756934 -1.80E-05
    54 Broy./Diag. 0.40E+00    7.5     0.00000232     -4911.5276557640  1.99E-05
    55 Broy./Diag. 0.40E+00    7.5     0.00000183     -4911.5276647976 -9.03E-06
    56 Broy./Diag. 0.40E+00    7.1     0.00000132     -4911.5276646193  1.78E-07
    57 Broy./Diag. 0.40E+00    7.1     0.00000232     -4911.5276706005 -5.98E-06
    58 Broy./Diag. 0.40E+00    7.2     0.00000280     -4911.5276657454  4.86E-06
    59 Broy./Diag. 0.40E+00    6.8     0.00000185     -4911.5276601269  5.62E-06
    60 Broy./Diag. 0.40E+00    7.1     0.00000166     -4911.5276758217 -1.57E-05
    61 Broy./Diag. 0.40E+00    7.0     0.00000140     -4911.5276701963  5.63E-06
    62 Broy./Diag. 0.40E+00    6.9     0.00000093     -4911.5276715301 -1.33E-06

  *** SCF run converged in    62 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999974       -0.0000000026
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008349434831
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.90776310088904
  Hartree energy:                                            1781.41245907068924
  Exchange-correlation energy:                               -779.51739026053076
  Electronic entropic energy:                                  -0.24016441485099
  Fermi energy:                                                 0.08732198937513

  Total energy:                                             -4911.52767153014884

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.527678335411110

 MD| ***************************************************************************
 MD| Step number                                                            1240
 MD| Time [fs]                                                       2480.000000
 MD| Conserved quantity [hartree]                            -0.491118744644E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    474.543309           591.043897
 MD| Energy drift per atom [K]           0.274317204651E+03   0.269103436171E+03
 MD| Potential energy [hartree]         -0.491152767834E+04  -0.491156227812E+04
 MD| Kinetic energy [hartree]            0.340231897054E+00   0.372317180010E+00
 MD| Temperature [K]                             906.638038           992.137776
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.6     0.01639712     -4911.5289080951 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.03784255     -4911.4466284389  8.23E-02
     3 Broy./Diag. 0.40E+00    6.9     0.05309806     -4911.7218505762 -2.75E-01
     4 Broy./Diag. 0.40E+00    6.9     0.03043673     -4911.3624454361  3.59E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01161102     -4911.5241660918 -1.62E-01
     6 Broy./Diag. 0.40E+00    7.3     0.00554615     -4911.5428854356 -1.87E-02
     7 Broy./Diag. 0.40E+00    7.6     0.00496211     -4911.5258908920  1.70E-02
     8 Broy./Diag. 0.40E+00    7.3     0.00354467     -4911.5333389875 -7.45E-03
     9 Broy./Diag. 0.40E+00    7.1     0.00093452     -4911.5278964986  5.44E-03
    10 Broy./Diag. 0.40E+00    7.2     0.00062261     -4911.5295311634 -1.63E-03
    11 Broy./Diag. 0.40E+00    7.1     0.00037293     -4911.5281862777  1.34E-03
    12 Broy./Diag. 0.40E+00    7.3     0.00032099     -4911.5293517189 -1.17E-03
    13 Broy./Diag. 0.40E+00    7.1     0.00018254     -4911.5289234128  4.28E-04
    14 Broy./Diag. 0.40E+00    7.1     0.00028896     -4911.5292666393 -3.43E-04
    15 Broy./Diag. 0.40E+00    7.3     0.00024891     -4911.5298535089 -5.87E-04
    16 Broy./Diag. 0.40E+00    6.7     0.00017530     -4911.5296321988  2.21E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00015541     -4911.5302886051 -6.56E-04
    18 Broy./Diag. 0.40E+00    7.0     0.00013881     -4911.5301365314  1.52E-04
    19 Broy./Diag. 0.40E+00    7.3     0.00009727     -4911.5304902819 -3.54E-04
    20 Broy./Diag. 0.40E+00    6.9     0.00009019     -4911.5303300754  1.60E-04
    21 Broy./Diag. 0.40E+00    7.1     0.00010604     -4911.5303756016 -4.55E-05
    22 Broy./Diag. 0.40E+00    6.9     0.00005360     -4911.5305816095 -2.06E-04
    23 Broy./Diag. 0.40E+00    7.3     0.00005076     -4911.5304896836  9.19E-05
    24 Broy./Diag. 0.40E+00    6.9     0.00003992     -4911.5305428480 -5.32E-05
    25 Broy./Diag. 0.40E+00    7.3     0.00002884     -4911.5304713984  7.14E-05
    26 Broy./Diag. 0.40E+00    7.2     0.00002508     -4911.5306042604 -1.33E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00003933     -4911.5305912127  1.30E-05
    28 Broy./Diag. 0.40E+00    7.1     0.00002678     -4911.5305209466  7.03E-05
    29 Broy./Diag. 0.40E+00    7.3     0.00002731     -4911.5306225207 -1.02E-04
    30 Broy./Diag. 0.40E+00    6.9     0.00002048     -4911.5306166083  5.91E-06
    31 Broy./Diag. 0.40E+00    6.8     0.00001732     -4911.5306684208 -5.18E-05
    32 Broy./Diag. 0.40E+00    6.8     0.00001321     -4911.5305888844  7.95E-05
    33 Broy./Diag. 0.40E+00    7.2     0.00001821     -4911.5306335850 -4.47E-05
    34 Broy./Diag. 0.40E+00    6.9     0.00001365     -4911.5306874187 -5.38E-05
    35 Broy./Diag. 0.40E+00    7.3     0.00001302     -4911.5306405066  4.69E-05
    36 Broy./Diag. 0.40E+00    7.0     0.00001051     -4911.5306562517 -1.57E-05
    37 Broy./Diag. 0.40E+00    6.7     0.00000938     -4911.5306524484  3.80E-06
    38 Broy./Diag. 0.40E+00    7.1     0.00000697     -4911.5307047619 -5.23E-05
    39 Broy./Diag. 0.40E+00    7.0     0.00001062     -4911.5306813249  2.34E-05
    40 Broy./Diag. 0.40E+00    7.0     0.00000892     -4911.5306645369  1.68E-05
    41 Broy./Diag. 0.40E+00    7.2     0.00000671     -4911.5306999500 -3.54E-05
    42 Broy./Diag. 0.40E+00    6.9     0.00000553     -4911.5307028977 -2.95E-06
    43 Broy./Diag. 0.40E+00    7.3     0.00000543     -4911.5307047631 -1.87E-06
    44 Broy./Diag. 0.40E+00    7.2     0.00000354     -4911.5306806524  2.41E-05
    45 Broy./Diag. 0.40E+00    6.9     0.00000543     -4911.5307057959 -2.51E-05
    46 Broy./Diag. 0.40E+00    7.3     0.00000492     -4911.5307183110 -1.25E-05
    47 Broy./Diag. 0.40E+00    7.5     0.00000358     -4911.5307011042  1.72E-05
    48 Broy./Diag. 0.40E+00    8.6     0.00000333     -4911.5307070799 -5.98E-06
    49 Broy./Diag. 0.40E+00    7.1     0.00000299     -4911.5307082792 -1.20E-06
    50 Broy./Diag. 0.40E+00    7.3     0.00000198     -4911.5307244466 -1.62E-05
    51 Broy./Diag. 0.40E+00    7.1     0.00000336     -4911.5307119583  1.25E-05
    52 Broy./Diag. 0.40E+00    7.3     0.00000298     -4911.5307074730  4.49E-06
    53 Broy./Diag. 0.40E+00    7.1     0.00000170     -4911.5307219150 -1.44E-05
    54 Broy./Diag. 0.40E+00    7.3     0.00000180     -4911.5307204825  1.43E-06
    55 Broy./Diag. 0.40E+00    7.0     0.00000186     -4911.5307204750  7.59E-09
    56 Broy./Diag. 0.40E+00    7.3     0.00000107     -4911.5307135720  6.90E-06
    57 Broy./Diag. 0.40E+00    7.3     0.00000178     -4911.5307237874 -1.02E-05
    58 Broy./Diag. 0.40E+00    6.7     0.00000171     -4911.5307263919 -2.60E-06
    59 Broy./Diag. 0.40E+00    7.1     0.00000087     -4911.5307203133  6.08E-06

  *** SCF run converged in    59 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008340900527
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.87234411292457
  Hartree energy:                                            1781.43476450308594
  Exchange-correlation energy:                               -779.50761464270408
  Electronic entropic energy:                                  -0.23987519067266
  Fermi energy:                                                 0.08725879936937

  Total energy:                                             -4911.53072031330976

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.530730478001715

 MD| ***************************************************************************
 MD| Step number                                                            1241
 MD| Time [fs]                                                       2482.000000
 MD| Conserved quantity [hartree]                            -0.491117140354E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    429.980415           590.914112
 MD| Energy drift per atom [K]           0.307645769025E+03   0.269134493651E+03
 MD| Potential energy [hartree]         -0.491153073048E+04  -0.491156225270E+04
 MD| Kinetic energy [hartree]            0.359326941817E+00   0.372306712454E+00
 MD| Temperature [K]                             957.521844           992.109882
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.01660589     -4911.5315743324 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.5     0.04586670     -4911.4393419617  9.22E-02
     3 Broy./Diag. 0.40E+00    7.1     0.05857409     -4911.7640019690 -3.25E-01
     4 Broy./Diag. 0.40E+00    6.9     0.02971391     -4911.3696954847  3.94E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01023679     -4911.5109260039 -1.41E-01
     6 Broy./Diag. 0.40E+00    6.8     0.00498058     -4911.5620871592 -5.12E-02
     7 Broy./Diag. 0.40E+00    6.7     0.00321241     -4911.5290755780  3.30E-02
     8 Broy./Diag. 0.40E+00    7.2     0.00212551     -4911.5349177136 -5.84E-03
     9 Broy./Diag. 0.40E+00    7.0     0.00089587     -4911.5303143355  4.60E-03
    10 Broy./Diag. 0.40E+00    7.2     0.00053486     -4911.5334728769 -3.16E-03
    11 Broy./Diag. 0.40E+00    7.1     0.00018619     -4911.5316185314  1.85E-03
    12 Broy./Diag. 0.40E+00    7.1     0.00015508     -4911.5307743655  8.44E-04
    13 Broy./Diag. 0.40E+00    7.7     0.00010696     -4911.5327540071 -1.98E-03
    14 Broy./Diag. 0.40E+00    6.8     0.00010729     -4911.5321862984  5.68E-04
    15 Broy./Diag. 0.40E+00    7.0     0.00007562     -4911.5326901611 -5.04E-04
    16 Broy./Diag. 0.40E+00    7.3     0.00005525     -4911.5329792448 -2.89E-04
    17 Broy./Diag. 0.40E+00    6.9     0.00006588     -4911.5329700396  9.21E-06
    18 Broy./Diag. 0.40E+00    7.5     0.00004492     -4911.5331288863 -1.59E-04
    19 Broy./Diag. 0.40E+00    6.9     0.00002243     -4911.5333358863 -2.07E-04
    20 Broy./Diag. 0.40E+00    6.8     0.00002022     -4911.5333744177 -3.85E-05
    21 Broy./Diag. 0.40E+00    7.1     0.00001430     -4911.5333265347  4.79E-05
    22 Broy./Diag. 0.40E+00    7.3     0.00001212     -4911.5334349134 -1.08E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00000766     -4911.5334390573 -4.14E-06
    24 Broy./Diag. 0.40E+00    6.9     0.00000779     -4911.5334194109  1.96E-05
    25 Broy./Diag. 0.40E+00    7.1     0.00000773     -4911.5334708712 -5.15E-05
    26 Broy./Diag. 0.40E+00    7.5     0.00000402     -4911.5334424825  2.84E-05
    27 Broy./Diag. 0.40E+00    6.8     0.00000449     -4911.5334474563 -4.97E-06
    28 Broy./Diag. 0.40E+00    7.0     0.00000285     -4911.5334486357 -1.18E-06
    29 Broy./Diag. 0.40E+00    7.3     0.00000264     -4911.5334471827  1.45E-06
    30 Broy./Diag. 0.40E+00    7.3     0.00000285     -4911.5334343068  1.29E-05
    31 Broy./Diag. 0.40E+00    6.5     0.00000228     -4911.5334450229 -1.07E-05
    32 Broy./Diag. 0.40E+00    7.1     0.00000206     -4911.5334282068  1.68E-05
    33 Broy./Diag. 0.40E+00    7.7     0.00000182     -4911.5334279404  2.66E-07
    34 Broy./Diag. 0.40E+00    6.6     0.00000140     -4911.5334204545  7.49E-06
    35 Broy./Diag. 0.40E+00    7.1     0.00000089     -4911.5334194390  1.02E-06

  *** SCF run converged in    35 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008331249396
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.83531858322704
  Hartree energy:                                            1781.45850538747982
  Exchange-correlation energy:                               -779.49737861998381
  Electronic entropic energy:                                  -0.23952559690184
  Fermi energy:                                                 0.08719702769714

  Total energy:                                             -4911.53341943903524

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.533410006930353

 MD| ***************************************************************************
 MD| Step number                                                            1242
 MD| Time [fs]                                                       2484.000000
 MD| Conserved quantity [hartree]                            -0.491118755151E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    256.118646           590.644550
 MD| Energy drift per atom [K]           0.274098915946E+03   0.269138490770E+03
 MD| Potential energy [hartree]         -0.491153341001E+04  -0.491156222948E+04
 MD| Kinetic energy [hartree]            0.345858494010E+00   0.372285417592E+00
 MD| Temperature [K]                             921.631596           992.053136
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.6     0.01904259     -4911.5339456686 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.8     0.04647716     -4911.4402641393  9.37E-02
     3 Broy./Diag. 0.40E+00    7.3     0.05461318     -4911.7520280377 -3.12E-01
     4 Broy./Diag. 0.40E+00    6.9     0.02118267     -4911.3666744515  3.85E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01032739     -4911.5368751642 -1.70E-01
     6 Broy./Diag. 0.40E+00    7.3     0.00611696     -4911.5492098113 -1.23E-02
     7 Broy./Diag. 0.40E+00    6.9     0.00235230     -4911.5355820773  1.36E-02
     8 Broy./Diag. 0.40E+00    7.0     0.00164081     -4911.5284368161  7.15E-03
     9 Broy./Diag. 0.40E+00    6.9     0.00038715     -4911.5343056772 -5.87E-03
    10 Broy./Diag. 0.40E+00    6.8     0.00032890     -4911.5348766835 -5.71E-04
    11 Broy./Diag. 0.40E+00    7.1     0.00016361     -4911.5335497474  1.33E-03
    12 Broy./Diag. 0.40E+00    7.3     0.00012592     -4911.5344880000 -9.38E-04
    13 Broy./Diag. 0.40E+00    7.1     0.00013757     -4911.5349475219 -4.60E-04
    14 Broy./Diag. 0.40E+00    7.1     0.00012348     -4911.5346636735  2.84E-04
    15 Broy./Diag. 0.40E+00    6.8     0.00008006     -4911.5353481813 -6.85E-04
    16 Broy./Diag. 0.40E+00    7.3     0.00006915     -4911.5353678586 -1.97E-05
    17 Broy./Diag. 0.40E+00    7.1     0.00006558     -4911.5355492215 -1.81E-04
    18 Broy./Diag. 0.40E+00    6.7     0.00003300     -4911.5357391528 -1.90E-04
    19 Broy./Diag. 0.40E+00    6.9     0.00002959     -4911.5358407487 -1.02E-04
    20 Broy./Diag. 0.40E+00    7.3     0.00002062     -4911.5358556777 -1.49E-05
    21 Broy./Diag. 0.40E+00    7.5     0.00001402     -4911.5358960485 -4.04E-05
    22 Broy./Diag. 0.40E+00    7.0     0.00000969     -4911.5359354189 -3.94E-05
    23 Broy./Diag. 0.40E+00    6.9     0.00001138     -4911.5359479310 -1.25E-05
    24 Broy./Diag. 0.40E+00    7.1     0.00000711     -4911.5359425233  5.41E-06
    25 Broy./Diag. 0.40E+00    7.1     0.00000768     -4911.5359564485 -1.39E-05
    26 Broy./Diag. 0.40E+00    7.3     0.00000629     -4911.5359568126 -3.64E-07
    27 Broy./Diag. 0.40E+00    7.0     0.00000332     -4911.5359463955  1.04E-05
    28 Broy./Diag. 0.40E+00    6.9     0.00000278     -4911.5359501565 -3.76E-06
    29 Broy./Diag. 0.40E+00    7.3     0.00000345     -4911.5359488356  1.32E-06
    30 Broy./Diag. 0.40E+00    6.9     0.00000336     -4911.5359279147  2.09E-05
    31 Broy./Diag. 0.40E+00    6.8     0.00000225     -4911.5359400453 -1.21E-05
    32 Broy./Diag. 0.40E+00    7.1     0.00000201     -4911.5359279888  1.21E-05
    33 Broy./Diag. 0.40E+00    7.1     0.00000177     -4911.5359225966  5.39E-06
    34 Broy./Diag. 0.40E+00    7.3     0.00000127     -4911.5359187595  3.84E-06
    35 Broy./Diag. 0.40E+00    7.1     0.00000108     -4911.5359189528 -1.93E-07
    36 Broy./Diag. 0.40E+00    7.8     0.00000124     -4911.5359072636  1.17E-05
    37 Broy./Diag. 0.40E+00    7.1     0.00000062     -4911.5359127420 -5.48E-06

  *** SCF run converged in    37 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008318534905
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.79202605733599
  Hartree energy:                                            1781.48627831285012
  Exchange-correlation energy:                               -779.48479450245895
  Electronic entropic energy:                                  -0.23908327546236
  Fermi energy:                                                 0.08712972472096

  Total energy:                                             -4911.53591274197515

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.535907502189730

 MD| ***************************************************************************
 MD| Step number                                                            1243
 MD| Time [fs]                                                       2486.000000
 MD| Conserved quantity [hartree]                            -0.491117432834E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    271.682109           590.387943
 MD| Energy drift per atom [K]           0.301569599793E+03   0.269164581767E+03
 MD| Potential energy [hartree]         -0.491153590750E+04  -0.491156220830E+04
 MD| Kinetic energy [hartree]            0.361579165900E+00   0.372276804356E+00
 MD| Temperature [K]                             963.523492           992.030184
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    5.8     0.02877478     -4911.5359331621 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.09852220     -4911.4159252537  1.20E-01
     3 Broy./Diag. 0.40E+00    7.1     0.09724214     -4911.8144074472 -3.98E-01
     4 Broy./Diag. 0.40E+00    7.3     0.02783366     -4911.4234203192  3.91E-01
     5 Broy./Diag. 0.40E+00    7.1     0.01410217     -4911.5218256267 -9.84E-02
     6 Broy./Diag. 0.40E+00    7.5     0.00980165     -4911.5731774504 -5.14E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00214563     -4911.5369745154  3.62E-02
     8 Broy./Diag. 0.40E+00    7.2     0.00177189     -4911.5286849748  8.29E-03
     9 Broy./Diag. 0.40E+00    7.0     0.00057075     -4911.5371608769 -8.48E-03
    10 Broy./Diag. 0.40E+00    6.9     0.00047458     -4911.5370714551  8.94E-05
    11 Broy./Diag. 0.40E+00    7.4     0.00025705     -4911.5366531171  4.18E-04
    12 Broy./Diag. 0.40E+00    7.1     0.00025849     -4911.5348786048  1.77E-03
    13 Broy./Diag. 0.40E+00    6.9     0.00029457     -4911.5374834515 -2.60E-03
    14 Broy./Diag. 0.40E+00    7.2     0.00017153     -4911.5371118711  3.72E-04
    15 Broy./Diag. 0.40E+00    6.9     0.00016406     -4911.5367281162  3.84E-04
    16 Broy./Diag. 0.40E+00    7.0     0.00014617     -4911.5373558470 -6.28E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00013580     -4911.5375698169 -2.14E-04
    18 Broy./Diag. 0.40E+00    7.1     0.00011050     -4911.5378673531 -2.98E-04
    19 Broy./Diag. 0.40E+00    7.1     0.00016370     -4911.5368326692  1.03E-03
    20 Broy./Diag. 0.40E+00    7.1     0.00008927     -4911.5375469950 -7.14E-04
    21 Broy./Diag. 0.40E+00    7.1     0.00007330     -4911.5378389827 -2.92E-04
    22 Broy./Diag. 0.40E+00    7.3     0.00005127     -4911.5376302229  2.09E-04
    23 Broy./Diag. 0.40E+00    7.9     0.00005002     -4911.5376651656 -3.49E-05
    24 Broy./Diag. 0.40E+00    6.7     0.00003092     -4911.5376133798  5.18E-05
    25 Broy./Diag. 0.40E+00    7.5     0.00005736     -4911.5379389119 -3.26E-04
    26 Broy./Diag. 0.40E+00    7.5     0.00004898     -4911.5377014953  2.37E-04
    27 Broy./Diag. 0.40E+00    6.8     0.00004606     -4911.5376065282  9.50E-05
    28 Broy./Diag. 0.40E+00    7.1     0.00003309     -4911.5378633395 -2.57E-04
    29 Broy./Diag. 0.40E+00    6.7     0.00003916     -4911.5378608502  2.49E-06
    30 Broy./Diag. 0.40E+00    7.1     0.00002298     -4911.5379129779 -5.21E-05
    31 Broy./Diag. 0.40E+00    7.1     0.00003023     -4911.5377355201  1.77E-04
    32 Broy./Diag. 0.40E+00    7.0     0.00002117     -4911.5378999782 -1.64E-04
    33 Broy./Diag. 0.40E+00    6.8     0.00001816     -4911.5379388348 -3.89E-05
    34 Broy./Diag. 0.40E+00    6.9     0.00001306     -4911.5378708774  6.80E-05
    35 Broy./Diag. 0.40E+00    7.5     0.00001816     -4911.5378937925 -2.29E-05
    36 Broy./Diag. 0.40E+00    6.9     0.00001275     -4911.5378936358  1.57E-07
    37 Broy./Diag. 0.40E+00    6.9     0.00002047     -4911.5379934477 -9.98E-05
    38 Broy./Diag. 0.40E+00    7.3     0.00001881     -4911.5378903487  1.03E-04
    39 Broy./Diag. 0.40E+00    7.0     0.00001482     -4911.5378921916 -1.84E-06
    40 Broy./Diag. 0.40E+00    7.0     0.00000777     -4911.5379648915 -7.27E-05
    41 Broy./Diag. 0.40E+00    7.3     0.00000874     -4911.5379570439  7.85E-06
    42 Broy./Diag. 0.40E+00    7.1     0.00000615     -4911.5379651922 -8.15E-06
    43 Broy./Diag. 0.40E+00    6.5     0.00000764     -4911.5379277985  3.74E-05
    44 Broy./Diag. 0.40E+00    6.7     0.00000773     -4911.5379790151 -5.12E-05
    45 Broy./Diag. 0.40E+00    6.9     0.00000849     -4911.5379792923 -2.77E-07
    46 Broy./Diag. 0.40E+00    7.6     0.00000630     -4911.5379444517  3.48E-05
    47 Broy./Diag. 0.40E+00    7.5     0.00000621     -4911.5379664585 -2.20E-05
    48 Broy./Diag. 0.40E+00    7.5     0.00000494     -4911.5379708316 -4.37E-06
    49 Broy./Diag. 0.40E+00    7.3     0.00000537     -4911.5379990140 -2.82E-05
    50 Broy./Diag. 0.40E+00    6.8     0.00000487     -4911.5379672690  3.17E-05
    51 Broy./Diag. 0.40E+00    7.1     0.00000333     -4911.5379742122 -6.94E-06
    52 Broy./Diag. 0.40E+00    7.2     0.00000267     -4911.5379908167 -1.66E-05
    53 Broy./Diag. 0.40E+00    7.3     0.00000245     -4911.5379852541  5.56E-06
    54 Broy./Diag. 0.40E+00    7.8     0.00000258     -4911.5379860181 -7.64E-07
    55 Broy./Diag. 0.40E+00    7.3     0.00000281     -4911.5379757781  1.02E-05
    56 Broy./Diag. 0.40E+00    9.6     0.00000341     -4911.5379989763 -2.32E-05
    57 Broy./Diag. 0.40E+00    7.2     0.00000273     -4911.5379939914  4.98E-06
    58 Broy./Diag. 0.40E+00    9.4     0.00000243     -4911.5379839352  1.01E-05
    59 Broy./Diag. 0.40E+00    8.8     0.00000154     -4911.5379920114 -8.08E-06
    60 Broy./Diag. 0.40E+00    7.5     0.00000125     -4911.5379927135 -7.02E-07
    61 Broy./Diag. 0.40E+00    7.0     0.00000117     -4911.5379982955 -5.58E-06
    62 Broy./Diag. 0.40E+00    7.5     0.00000160     -4911.5379900143  8.28E-06
    63 Broy./Diag. 0.40E+00    6.9     0.00000095     -4911.5379934286 -3.41E-06

  *** SCF run converged in    63 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008304770955
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.74617908981054
  Hartree energy:                                            1781.51565262041731
  Exchange-correlation energy:                               -779.47083235492789
  Electronic entropic energy:                                  -0.23865334358133
  Fermi energy:                                                 0.08706166916681

  Total energy:                                             -4911.53799342860111

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.538001653314495

 MD| ***************************************************************************
 MD| Step number                                                            1244
 MD| Time [fs]                                                       2488.000000
 MD| Conserved quantity [hartree]                            -0.491118914655E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    464.707928           590.286914
 MD| Energy drift per atom [K]           0.270785277956E+03   0.269165884578E+03
 MD| Potential energy [hartree]         -0.491153800165E+04  -0.491156218884E+04
 MD| Kinetic energy [hartree]            0.348855101091E+00   0.372257976620E+00
 MD| Temperature [K]                             929.616850           991.980013
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.03012525     -4911.5373202720 -4.91E+03
     2 Broy./Diag. 0.40E+00    8.9     0.10402049     -4911.4327103810  1.05E-01
     3 Broy./Diag. 0.40E+00    7.2     0.10021490     -4911.7713903254 -3.39E-01
     4 Broy./Diag. 0.40E+00    7.9     0.02622436     -4911.4595517975  3.12E-01
     5 Broy./Diag. 0.40E+00   10.5     0.01243138     -4911.5101684345 -5.06E-02
     6 Broy./Diag. 0.40E+00    7.1     0.00777519     -4911.5840699794 -7.39E-02
     7 Broy./Diag. 0.40E+00    7.5     0.00169490     -4911.5368070021  4.73E-02
     8 Broy./Diag. 0.40E+00    6.5     0.00149556     -4911.5347638800  2.04E-03
     9 Broy./Diag. 0.40E+00    8.0     0.00058214     -4911.5383241715 -3.56E-03
    10 Broy./Diag. 0.40E+00    6.9     0.00030793     -4911.5386644257 -3.40E-04
    11 Broy./Diag. 0.40E+00    9.5     0.00029765     -4911.5378298556  8.35E-04
    12 Broy./Diag. 0.40E+00    7.5     0.00023955     -4911.5372553223  5.75E-04
    13 Broy./Diag. 0.40E+00    8.2     0.00016317     -4911.5386989878 -1.44E-03
    14 Broy./Diag. 0.40E+00   10.8     0.00019321     -4911.5379514636  7.48E-04
    15 Broy./Diag. 0.40E+00    7.7     0.00006975     -4911.5385498300 -5.98E-04
    16 Broy./Diag. 0.40E+00    7.3     0.00008193     -4911.5389802253 -4.30E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00007219     -4911.5387871957  1.93E-04
    18 Broy./Diag. 0.40E+00    7.1     0.00006398     -4911.5388764804 -8.93E-05
    19 Broy./Diag. 0.40E+00    7.1     0.00006111     -4911.5391054775 -2.29E-04
    20 Broy./Diag. 0.40E+00    7.0     0.00003556     -4911.5394151518 -3.10E-04
    21 Broy./Diag. 0.40E+00    6.9     0.00004415     -4911.5391463577  2.69E-04
    22 Broy./Diag. 0.40E+00    8.0     0.00002689     -4911.5391869421 -4.06E-05
    23 Broy./Diag. 0.40E+00    7.6     0.00002569     -4911.5393248700 -1.38E-04
    24 Broy./Diag. 0.40E+00    6.9     0.00002037     -4911.5392884058  3.65E-05
    25 Broy./Diag. 0.40E+00    7.0     0.00002362     -4911.5392437845  4.46E-05
    26 Broy./Diag. 0.40E+00    7.5     0.00001463     -4911.5392070296  3.68E-05
    27 Broy./Diag. 0.40E+00    7.1     0.00001511     -4911.5393395179 -1.32E-04
    28 Broy./Diag. 0.40E+00    7.2     0.00000905     -4911.5392974980  4.20E-05
    29 Broy./Diag. 0.40E+00    7.5     0.00000885     -4911.5392586601  3.88E-05
    30 Broy./Diag. 0.40E+00    7.1     0.00000648     -4911.5392834657 -2.48E-05
    31 Broy./Diag. 0.40E+00    7.3     0.00000739     -4911.5392969357 -1.35E-05
    32 Broy./Diag. 0.40E+00    6.9     0.00000596     -4911.5392972072 -2.72E-07
    33 Broy./Diag. 0.40E+00    7.5     0.00000706     -4911.5392469844  5.02E-05
    34 Broy./Diag. 0.40E+00    7.1     0.00000329     -4911.5392813608 -3.44E-05
    35 Broy./Diag. 0.40E+00    7.5     0.00000421     -4911.5392951827 -1.38E-05
    36 Broy./Diag. 0.40E+00    6.7     0.00000247     -4911.5392834449  1.17E-05
    37 Broy./Diag. 0.40E+00    6.4     0.00000311     -4911.5392802069  3.24E-06
    38 Broy./Diag. 0.40E+00    7.1     0.00000229     -4911.5392806007 -3.94E-07
    39 Broy./Diag. 0.40E+00    8.4     0.00000292     -4911.5392961876 -1.56E-05
    40 Broy./Diag. 0.40E+00    7.1     0.00000168     -4911.5392820066  1.42E-05
    41 Broy./Diag. 0.40E+00    6.7     0.00000209     -4911.5392788835  3.12E-06
    42 Broy./Diag. 0.40E+00    7.3     0.00000146     -4911.5392868945 -8.01E-06
    43 Broy./Diag. 0.40E+00    7.6     0.00000182     -4911.5392888568 -1.96E-06
    44 Broy./Diag. 0.40E+00    7.5     0.00000138     -4911.5392881983  6.59E-07
    45 Broy./Diag. 0.40E+00    6.9     0.00000154     -4911.5392812843  6.91E-06
    46 Broy./Diag. 0.40E+00    7.1     0.00000097     -4911.5392890836 -7.80E-06

  *** SCF run converged in    46 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008293852658
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.70644929602440
  Hartree energy:                                            1781.54115570627346
  Exchange-correlation energy:                               -779.45824845371737
  Electronic entropic energy:                                  -0.23830606085634
  Fermi energy:                                                 0.08700494921168

  Total energy:                                             -4911.53928908363105

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.539289849245506

 MD| ***************************************************************************
 MD| Step number                                                            1245
 MD| Time [fs]                                                       2490.000000
 MD| Conserved quantity [hartree]                            -0.491119684699E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    354.747121           590.097726
 MD| Energy drift per atom [K]           0.254787899174E+03   0.269154335995E+03
 MD| Potential energy [hartree]         -0.491153928985E+04  -0.491156217045E+04
 MD| Kinetic energy [hartree]            0.342442863846E+00   0.372234028739E+00
 MD| Temperature [K]                             912.529745           991.916197
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.02417923     -4911.5375944298 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.08446985     -4911.4667347731  7.09E-02
     3 Broy./Diag. 0.40E+00    7.1     0.08577422     -4911.6653395618 -1.99E-01
     4 Broy./Diag. 0.40E+00    7.1     0.02452609     -4911.4841164733  1.81E-01
     5 Broy./Diag. 0.40E+00    6.9     0.01106562     -4911.5109567735 -2.68E-02
     6 Broy./Diag. 0.40E+00    7.1     0.00630034     -4911.5795587701 -6.86E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00153107     -4911.5353461865  4.42E-02
     8 Broy./Diag. 0.40E+00    7.5     0.00130109     -4911.5381656857 -2.82E-03
     9 Broy./Diag. 0.40E+00    7.5     0.00064000     -4911.5386501567 -4.84E-04
    10 Broy./Diag. 0.40E+00    6.9     0.00050126     -4911.5375655628  1.08E-03
    11 Broy./Diag. 0.40E+00    7.3     0.00026121     -4911.5379307686 -3.65E-04
    12 Broy./Diag. 0.40E+00    6.9     0.00018434     -4911.5383137276 -3.83E-04
    13 Broy./Diag. 0.40E+00    7.1     0.00012868     -4911.5384121880 -9.85E-05
    14 Broy./Diag. 0.40E+00    7.2     0.00008649     -4911.5381170200  2.95E-04
    15 Broy./Diag. 0.40E+00    7.2     0.00009477     -4911.5394600628 -1.34E-03
    16 Broy./Diag. 0.40E+00    7.3     0.00007256     -4911.5389420091  5.18E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00004778     -4911.5390907187 -1.49E-04
    18 Broy./Diag. 0.40E+00    6.6     0.00004309     -4911.5394148389 -3.24E-04
    19 Broy./Diag. 0.40E+00    7.3     0.00002293     -4911.5395182499 -1.03E-04
    20 Broy./Diag. 0.40E+00    7.5     0.00001315     -4911.5394837053  3.45E-05
    21 Broy./Diag. 0.40E+00    7.3     0.00001648     -4911.5396914502 -2.08E-04
    22 Broy./Diag. 0.40E+00    6.8     0.00001379     -4911.5395534769  1.38E-04
    23 Broy./Diag. 0.40E+00    6.9     0.00000997     -4911.5396075032 -5.40E-05
    24 Broy./Diag. 0.40E+00    6.9     0.00000650     -4911.5396311289 -2.36E-05
    25 Broy./Diag. 0.40E+00    7.6     0.00000640     -4911.5396287651  2.36E-06
    26 Broy./Diag. 0.40E+00    7.0     0.00000441     -4911.5396069669  2.18E-05
    27 Broy./Diag. 0.40E+00    7.5     0.00000373     -4911.5396488408 -4.19E-05
    28 Broy./Diag. 0.40E+00    6.9     0.00000326     -4911.5396062867  4.26E-05
    29 Broy./Diag. 0.40E+00    7.1     0.00000333     -4911.5396150668 -8.78E-06
    30 Broy./Diag. 0.40E+00    7.1     0.00000251     -4911.5396144537  6.13E-07
    31 Broy./Diag. 0.40E+00    7.1     0.00000239     -4911.5396061998  8.25E-06
    32 Broy./Diag. 0.40E+00    7.1     0.00000159     -4911.5395960796  1.01E-05
    33 Broy./Diag. 0.40E+00    6.9     0.00000184     -4911.5396049420 -8.86E-06
    34 Broy./Diag. 0.40E+00    7.5     0.00000185     -4911.5395875822  1.74E-05
    35 Broy./Diag. 0.40E+00    6.9     0.00000154     -4911.5395902458 -2.66E-06
    36 Broy./Diag. 0.40E+00    7.2     0.00000100     -4911.5395882889  1.96E-06
    37 Broy./Diag. 0.40E+00    7.8     0.00000098     -4911.5395849511  3.34E-06

  *** SCF run converged in    37 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008286234832
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.66804153818157
  Hartree energy:                                            1781.56582876373841
  Exchange-correlation energy:                               -779.44510988991897
  Electronic entropic energy:                                  -0.23800570934763
  Fermi energy:                                                 0.08694683770471

  Total energy:                                             -4911.53958495110510

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.539582607838383

 MD| ***************************************************************************
 MD| Step number                                                            1246
 MD| Time [fs]                                                       2492.000000
 MD| Conserved quantity [hartree]                            -0.491119116812E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    272.904703           589.843157
 MD| Energy drift per atom [K]           0.266585551602E+03   0.269152274370E+03
 MD| Potential energy [hartree]         -0.491153958261E+04  -0.491156215232E+04
 MD| Kinetic energy [hartree]            0.348414492421E+00   0.372214911936E+00
 MD| Temperature [K]                             928.442731           991.865255
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.03202221     -4911.5369550572 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.11021641     -4911.4528800181  8.41E-02
     3 Broy./Diag. 0.40E+00    7.1     0.10545408     -4911.6893253593 -2.36E-01
     4 Broy./Diag. 0.40E+00    7.2     0.02542818     -4911.4827409249  2.07E-01
     5 Broy./Diag. 0.40E+00    7.1     0.00946263     -4911.5114373220 -2.87E-02
     6 Broy./Diag. 0.40E+00    7.1     0.00570205     -4911.5760159361 -6.46E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00219778     -4911.5339368057  4.21E-02
     8 Broy./Diag. 0.40E+00    7.5     0.00138405     -4911.5395137762 -5.58E-03
     9 Broy./Diag. 0.40E+00    7.5     0.00057429     -4911.5378652263  1.65E-03
    10 Broy./Diag. 0.40E+00    6.7     0.00038300     -4911.5368515213  1.01E-03
    11 Broy./Diag. 0.40E+00    6.9     0.00033517     -4911.5375768111 -7.25E-04
    12 Broy./Diag. 0.40E+00    7.8     0.00027351     -4911.5369414448  6.35E-04
    13 Broy./Diag. 0.40E+00    7.2     0.00027140     -4911.5383641414 -1.42E-03
    14 Broy./Diag. 0.40E+00    7.5     0.00018819     -4911.5371506239  1.21E-03
    15 Broy./Diag. 0.40E+00    7.4     0.00018857     -4911.5378934640 -7.43E-04
    16 Broy./Diag. 0.40E+00    7.3     0.00015078     -4911.5385006058 -6.07E-04
    17 Broy./Diag. 0.40E+00    6.9     0.00016684     -4911.5384576606  4.29E-05
    18 Broy./Diag. 0.40E+00    7.3     0.00014935     -4911.5385547567 -9.71E-05
    19 Broy./Diag. 0.40E+00    6.8     0.00011707     -4911.5379658564  5.89E-04
    20 Broy./Diag. 0.40E+00    7.6     0.00008244     -4911.5387988522 -8.33E-04
    21 Broy./Diag. 0.40E+00    8.0     0.00008436     -4911.5386328540  1.66E-04
    22 Broy./Diag. 0.40E+00    7.1     0.00005480     -4911.5384049776  2.28E-04
    23 Broy./Diag. 0.40E+00    7.7     0.00005852     -4911.5385499272 -1.45E-04
    24 Broy./Diag. 0.40E+00    7.1     0.00006112     -4911.5386843282 -1.34E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00005441     -4911.5389099661 -2.26E-04
    26 Broy./Diag. 0.40E+00    6.9     0.00004921     -4911.5385519839  3.58E-04
    27 Broy./Diag. 0.40E+00    7.3     0.00004696     -4911.5386819354 -1.30E-04
    28 Broy./Diag. 0.40E+00    7.1     0.00003565     -4911.5388913152 -2.09E-04
    29 Broy./Diag. 0.40E+00    7.2     0.00003646     -4911.5388373900  5.39E-05
    30 Broy./Diag. 0.40E+00    7.1     0.00003117     -4911.5387661197  7.13E-05
    31 Broy./Diag. 0.40E+00    7.1     0.00002700     -4911.5387134121  5.27E-05
    32 Broy./Diag. 0.40E+00    7.1     0.00002511     -4911.5389246937 -2.11E-04
    33 Broy./Diag. 0.40E+00    7.1     0.00002472     -4911.5388850642  3.96E-05
    34 Broy./Diag. 0.40E+00    7.3     0.00002134     -4911.5388016882  8.34E-05
    35 Broy./Diag. 0.40E+00    6.9     0.00002112     -4911.5388611752 -5.95E-05
    36 Broy./Diag. 0.40E+00    6.8     0.00001845     -4911.5389233227 -6.21E-05
    37 Broy./Diag. 0.40E+00    8.2     0.00001821     -4911.5389646345 -4.13E-05
    38 Broy./Diag. 0.40E+00    7.3     0.00001773     -4911.5388293749  1.35E-04
    39 Broy./Diag. 0.40E+00    7.5     0.00001246     -4911.5388816736 -5.23E-05
    40 Broy./Diag. 0.40E+00    7.1     0.00001238     -4911.5389516722 -7.00E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00001101     -4911.5389289685  2.27E-05
    42 Broy./Diag. 0.40E+00    7.2     0.00000947     -4911.5389041565  2.48E-05
    43 Broy./Diag. 0.40E+00    7.3     0.00000875     -4911.5389054345 -1.28E-06
    44 Broy./Diag. 0.40E+00    7.1     0.00000982     -4911.5389767094 -7.13E-05
    45 Broy./Diag. 0.40E+00    7.3     0.00000770     -4911.5389525909  2.41E-05
    46 Broy./Diag. 0.40E+00    7.3     0.00000758     -4911.5389194581  3.31E-05
    47 Broy./Diag. 0.40E+00    6.8     0.00000600     -4911.5389447216 -2.53E-05
    48 Broy./Diag. 0.40E+00    7.3     0.00000577     -4911.5389652612 -2.05E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00000522     -4911.5389671459 -1.88E-06
    50 Broy./Diag. 0.40E+00    7.1     0.00000564     -4911.5389323729  3.48E-05
    51 Broy./Diag. 0.40E+00    7.3     0.00000391     -4911.5389551611 -2.28E-05
    52 Broy./Diag. 0.40E+00    7.3     0.00000463     -4911.5389754831 -2.03E-05
    53 Broy./Diag. 0.40E+00    7.0     0.00000338     -4911.5389645299  1.10E-05
    54 Broy./Diag. 0.40E+00    7.1     0.00000343     -4911.5389580412  6.49E-06
    55 Broy./Diag. 0.40E+00    7.5     0.00000295     -4911.5389597075 -1.67E-06
    56 Broy./Diag. 0.40E+00    7.1     0.00000335     -4911.5389817518 -2.20E-05
    57 Broy./Diag. 0.40E+00    7.0     0.00000247     -4911.5389699607  1.18E-05
    58 Broy./Diag. 0.40E+00    6.9     0.00000276     -4911.5389606756  9.29E-06
    59 Broy./Diag. 0.40E+00    6.9     0.00000180     -4911.5389716514 -1.10E-05
    60 Broy./Diag. 0.40E+00    6.9     0.00000196     -4911.5389771275 -5.48E-06
    61 Broy./Diag. 0.40E+00    7.1     0.00000178     -4911.5389765249  6.03E-07
    62 Broy./Diag. 0.40E+00    7.1     0.00000183     -4911.5389664357  1.01E-05
    63 Broy./Diag. 0.40E+00    7.2     0.00000118     -4911.5389754253 -8.99E-06
    64 Broy./Diag. 0.40E+00    7.1     0.00000172     -4911.5389806517 -5.23E-06
    65 Broy./Diag. 0.40E+00    7.1     0.00000107     -4911.5389754079  5.24E-06
    66 Broy./Diag. 0.40E+00    7.1     0.00000109     -4911.5389742015  1.21E-06
    67 Broy./Diag. 0.40E+00    6.9     0.00000102     -4911.5389762037 -2.00E-06
    68 Broy./Diag. 0.40E+00    7.5     0.00000112     -4911.5389823193 -6.12E-06
    69 Broy./Diag. 0.40E+00    7.1     0.00000069     -4911.5389774495  4.87E-06

  *** SCF run converged in    69 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008281524711
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.63005079517916
  Hartree energy:                                            1781.59024956772328
  Exchange-correlation energy:                               -779.43121046560736
  Electronic entropic energy:                                  -0.23772764437261
  Fermi energy:                                                 0.08688376751511

  Total energy:                                             -4911.53897744945971

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.538983063187516

 MD| ***************************************************************************
 MD| Step number                                                            1247
 MD| Time [fs]                                                       2494.000000
 MD| Conserved quantity [hartree]                            -0.491119249527E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    504.433064           589.774664
 MD| Energy drift per atom [K]           0.263828436568E+03   0.269148005054E+03
 MD| Potential energy [hartree]         -0.491153898306E+04  -0.491156213374E+04
 MD| Kinetic energy [hartree]            0.346487794092E+00   0.372194280727E+00
 MD| Temperature [K]                             923.308533           991.810278
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.03320130     -4911.5356417097 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.0     0.11627243     -4911.4444194143  9.12E-02
     3 Broy./Diag. 0.40E+00    7.3     0.10880652     -4911.6913575442 -2.47E-01
     4 Broy./Diag. 0.40E+00    7.2     0.02555841     -4911.4844066795  2.07E-01
     5 Broy./Diag. 0.40E+00    6.9     0.01020943     -4911.5151331140 -3.07E-02
     6 Broy./Diag. 0.40E+00    7.6     0.00703416     -4911.5667452730 -5.16E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00298535     -4911.5295290487  3.72E-02
     8 Broy./Diag. 0.40E+00    7.2     0.00159369     -4911.5413198822 -1.18E-02
     9 Broy./Diag. 0.40E+00    6.9     0.00071951     -4911.5375470295  3.77E-03
    10 Broy./Diag. 0.40E+00    7.3     0.00061486     -4911.5349095280  2.64E-03
    11 Broy./Diag. 0.40E+00    6.9     0.00043187     -4911.5369390076 -2.03E-03
    12 Broy./Diag. 0.40E+00    7.0     0.00029044     -4911.5357081244  1.23E-03
    13 Broy./Diag. 0.40E+00    7.6     0.00036075     -4911.5374016475 -1.69E-03
    14 Broy./Diag. 0.40E+00    7.5     0.00018073     -4911.5361757709  1.23E-03
    15 Broy./Diag. 0.40E+00    7.1     0.00021890     -4911.5367379490 -5.62E-04
    16 Broy./Diag. 0.40E+00    7.0     0.00022629     -4911.5372096278 -4.72E-04
    17 Broy./Diag. 0.40E+00    7.0     0.00021477     -4911.5368071653  4.02E-04
    18 Broy./Diag. 0.40E+00    7.1     0.00014890     -4911.5373379964 -5.31E-04
    19 Broy./Diag. 0.40E+00    7.1     0.00017683     -4911.5366468976  6.91E-04
    20 Broy./Diag. 0.40E+00    6.9     0.00008234     -4911.5374233284 -7.76E-04
    21 Broy./Diag. 0.40E+00    6.9     0.00009169     -4911.5373022092  1.21E-04
    22 Broy./Diag. 0.40E+00    7.3     0.00007853     -4911.5371522048  1.50E-04
    23 Broy./Diag. 0.40E+00    7.3     0.00007246     -4911.5373138148 -1.62E-04
    24 Broy./Diag. 0.40E+00    6.9     0.00006070     -4911.5373098355  3.98E-06
    25 Broy./Diag. 0.40E+00    7.1     0.00009806     -4911.5376148728 -3.05E-04
    26 Broy./Diag. 0.40E+00    7.8     0.00006158     -4911.5372050389  4.10E-04
    27 Broy./Diag. 0.40E+00    7.3     0.00005320     -4911.5373924971 -1.87E-04
    28 Broy./Diag. 0.40E+00    6.9     0.00005600     -4911.5375437094 -1.51E-04
    29 Broy./Diag. 0.40E+00    6.9     0.00005004     -4911.5374994363  4.43E-05
    30 Broy./Diag. 0.40E+00    7.1     0.00003017     -4911.5375216547 -2.22E-05
    31 Broy./Diag. 0.40E+00    7.3     0.00003831     -4911.5374084209  1.13E-04
    32 Broy./Diag. 0.40E+00    6.8     0.00002621     -4911.5375977999 -1.89E-04
    33 Broy./Diag. 0.40E+00    7.1     0.00002064     -4911.5375620816  3.57E-05
    34 Broy./Diag. 0.40E+00    8.0     0.00002418     -4911.5375105307  5.16E-05
    35 Broy./Diag. 0.40E+00    7.1     0.00002797     -4911.5375563337 -4.58E-05
    36 Broy./Diag. 0.40E+00    7.5     0.00002107     -4911.5375696298 -1.33E-05
    37 Broy./Diag. 0.40E+00    6.7     0.00002793     -4911.5376654719 -9.58E-05
    38 Broy./Diag. 0.40E+00    7.3     0.00002192     -4911.5375357471  1.30E-04
    39 Broy./Diag. 0.40E+00    7.3     0.00001090     -4911.5375784918 -4.27E-05
    40 Broy./Diag. 0.40E+00    7.1     0.00001189     -4911.5376255085 -4.70E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00001281     -4911.5376168424  8.67E-06
    42 Broy./Diag. 0.40E+00    7.2     0.00000925     -4911.5376169619 -1.20E-07
    43 Broy./Diag. 0.40E+00    7.2     0.00001029     -4911.5375893500  2.76E-05
    44 Broy./Diag. 0.40E+00    6.9     0.00001217     -4911.5376558302 -6.65E-05
    45 Broy./Diag. 0.40E+00    6.9     0.00000808     -4911.5376368131  1.90E-05
    46 Broy./Diag. 0.40E+00    7.1     0.00000815     -4911.5376221884  1.46E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00000884     -4911.5376329011 -1.07E-05
    48 Broy./Diag. 0.40E+00    7.0     0.00000652     -4911.5376400064 -7.11E-06
    49 Broy./Diag. 0.40E+00    7.2     0.00000539     -4911.5376639090 -2.39E-05
    50 Broy./Diag. 0.40E+00    6.7     0.00000547     -4911.5376335545  3.04E-05
    51 Broy./Diag. 0.40E+00    7.3     0.00000332     -4911.5376459864 -1.24E-05
    52 Broy./Diag. 0.40E+00    6.7     0.00000389     -4911.5376554416 -9.46E-06
    53 Broy./Diag. 0.40E+00    7.3     0.00000433     -4911.5376544801  9.62E-07
    54 Broy./Diag. 0.40E+00    7.1     0.00000382     -4911.5376547405 -2.60E-07
    55 Broy./Diag. 0.40E+00    7.1     0.00000331     -4911.5376442254  1.05E-05
    56 Broy./Diag. 0.40E+00    6.4     0.00000415     -4911.5376675436 -2.33E-05
    57 Broy./Diag. 0.40E+00    6.8     0.00000257     -4911.5376606277  6.92E-06
    58 Broy./Diag. 0.40E+00    7.1     0.00000230     -4911.5376576578  2.97E-06
    59 Broy./Diag. 0.40E+00    6.9     0.00000215     -4911.5376594287 -1.77E-06
    60 Broy./Diag. 0.40E+00    7.3     0.00000172     -4911.5376613626 -1.93E-06
    61 Broy./Diag. 0.40E+00    7.3     0.00000146     -4911.5376672195 -5.86E-06
    62 Broy./Diag. 0.40E+00    7.5     0.00000189     -4911.5376578053  9.41E-06
    63 Broy./Diag. 0.40E+00    7.1     0.00000138     -4911.5376641829 -6.38E-06
    64 Broy./Diag. 0.40E+00    6.9     0.00000165     -4911.5376659142 -1.73E-06
    65 Broy./Diag. 0.40E+00    7.1     0.00000159     -4911.5376666799 -7.66E-07
    66 Broy./Diag. 0.40E+00    7.5     0.00000123     -4911.5376662491  4.31E-07
    67 Broy./Diag. 0.40E+00    7.3     0.00000084     -4911.5376634005  2.85E-06

  *** SCF run converged in    67 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008278505879
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.59270283446131
  Hartree energy:                                            1781.61410305123536
  Exchange-correlation energy:                               -779.41662690727526
  Electronic entropic energy:                                  -0.23750268415945
  Fermi energy:                                                 0.08681726137275

  Total energy:                                             -4911.53766340048696

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.537671468597182

 MD| ***************************************************************************
 MD| Step number                                                            1248
 MD| Time [fs]                                                       2496.000000
 MD| Conserved quantity [hartree]                            -0.491118631213E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    486.238716           589.691703
 MD| Energy drift per atom [K]           0.276673681729E+03   0.269154035243E+03
 MD| Potential energy [hartree]         -0.491153767147E+04  -0.491156211414E+04
 MD| Kinetic energy [hartree]            0.351359334460E+00   0.372177586058E+00
 MD| Temperature [K]                             936.290043           991.765791
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02782447     -4911.5339889393 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.9     0.09984010     -4911.4319971919  1.02E-01
     3 Broy./Diag. 0.40E+00    7.5     0.09788990     -4911.6787820936 -2.47E-01
     4 Broy./Diag. 0.40E+00    7.3     0.02709214     -4911.4752957792  2.03E-01
     5 Broy./Diag. 0.40E+00    7.7     0.00841397     -4911.5173785870 -4.21E-02
     6 Broy./Diag. 0.40E+00    7.3     0.00612737     -4911.5664461839 -4.91E-02
     7 Broy./Diag. 0.40E+00    7.4     0.00192138     -4911.5291519562  3.73E-02
     8 Broy./Diag. 0.40E+00    7.3     0.00135054     -4911.5373290023 -8.18E-03
     9 Broy./Diag. 0.40E+00    7.3     0.00055634     -4911.5346644493  2.66E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00035993     -4911.5335601340  1.10E-03
    11 Broy./Diag. 0.40E+00    7.3     0.00035184     -4911.5345835979 -1.02E-03
    12 Broy./Diag. 0.40E+00    7.0     0.00031746     -4911.5339180599  6.66E-04
    13 Broy./Diag. 0.40E+00    7.3     0.00026469     -4911.5351455595 -1.23E-03
    14 Broy./Diag. 0.40E+00    8.0     0.00020990     -4911.5340460805  1.10E-03
    15 Broy./Diag. 0.40E+00    7.5     0.00020481     -4911.5349910557 -9.45E-04
    16 Broy./Diag. 0.40E+00    9.7     0.00015051     -4911.5353703791 -3.79E-04
    17 Broy./Diag. 0.40E+00    7.2     0.00018356     -4911.5353143699  5.60E-05
    18 Broy./Diag. 0.40E+00    9.9     0.00016946     -4911.5354931548 -1.79E-04
    19 Broy./Diag. 0.40E+00    8.9     0.00012236     -4911.5350610022  4.32E-04
    20 Broy./Diag. 0.40E+00    7.3     0.00009423     -4911.5358045670 -7.44E-04
    21 Broy./Diag. 0.40E+00    7.3     0.00007929     -4911.5354939611  3.11E-04
    22 Broy./Diag. 0.40E+00    6.4     0.00006421     -4911.5354273188  6.66E-05
    23 Broy./Diag. 0.40E+00    7.3     0.00005812     -4911.5355431796 -1.16E-04
    24 Broy./Diag. 0.40E+00    7.7     0.00006524     -4911.5356250885 -8.19E-05
    25 Broy./Diag. 0.40E+00    7.3     0.00005560     -4911.5357857719 -1.61E-04
    26 Broy./Diag. 0.40E+00    9.0     0.00004950     -4911.5355201352  2.66E-04
    27 Broy./Diag. 0.40E+00    8.3     0.00003755     -4911.5357078709 -1.88E-04
    28 Broy./Diag. 0.40E+00    7.4     0.00004665     -4911.5357842856 -7.64E-05
    29 Broy./Diag. 0.40E+00   10.6     0.00003414     -4911.5357645610  1.97E-05
    30 Broy./Diag. 0.40E+00    7.1     0.00003230     -4911.5357267326  3.78E-05
    31 Broy./Diag. 0.40E+00    7.4     0.00002764     -4911.5356946456  3.21E-05
    32 Broy./Diag. 0.40E+00    7.3     0.00002472     -4911.5358517708 -1.57E-04
    33 Broy./Diag. 0.40E+00    8.1     0.00001734     -4911.5357853173  6.65E-05
    34 Broy./Diag. 0.40E+00    6.9     0.00002546     -4911.5357850014  3.16E-07
    35 Broy./Diag. 0.40E+00    8.9     0.00001991     -4911.5358034499 -1.84E-05
    36 Broy./Diag. 0.40E+00    7.7     0.00001962     -4911.5358477727 -4.43E-05
    37 Broy./Diag. 0.40E+00    8.9     0.00001900     -4911.5358818165 -3.40E-05
    38 Broy./Diag. 0.40E+00   10.4     0.00001664     -4911.5357802166  1.02E-04
    39 Broy./Diag. 0.40E+00    7.3     0.00000991     -4911.5358469594 -6.67E-05
    40 Broy./Diag. 0.40E+00    6.9     0.00001456     -4911.5358614831 -1.45E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00000914     -4911.5358667290 -5.25E-06
    42 Broy./Diag. 0.40E+00    6.9     0.00000907     -4911.5358535312  1.32E-05
    43 Broy./Diag. 0.40E+00    7.3     0.00000906     -4911.5358519331  1.60E-06
    44 Broy./Diag. 0.40E+00    6.9     0.00000950     -4911.5359030665 -5.11E-05
    45 Broy./Diag. 0.40E+00    7.1     0.00000587     -4911.5358727314  3.03E-05
    46 Broy./Diag. 0.40E+00    7.3     0.00000853     -4911.5358776150 -4.88E-06
    47 Broy./Diag. 0.40E+00    7.5     0.00000556     -4911.5358774345  1.80E-07
    48 Broy./Diag. 0.40E+00    7.1     0.00000579     -4911.5358930207 -1.56E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00000499     -4911.5358987782 -5.76E-06
    50 Broy./Diag. 0.40E+00    7.1     0.00000475     -4911.5358777722  2.10E-05
    51 Broy./Diag. 0.40E+00    7.3     0.00000322     -4911.5358980436 -2.03E-05
    52 Broy./Diag. 0.40E+00    7.1     0.00000465     -4911.5358966900  1.35E-06
    53 Broy./Diag. 0.40E+00    6.7     0.00000279     -4911.5359033649 -6.67E-06
    54 Broy./Diag. 0.40E+00    7.1     0.00000351     -4911.5358978434  5.52E-06
    55 Broy./Diag. 0.40E+00    7.1     0.00000309     -4911.5358954765  2.37E-06
    56 Broy./Diag. 0.40E+00    7.1     0.00000305     -4911.5359110314 -1.56E-05
    57 Broy./Diag. 0.40E+00    6.9     0.00000227     -4911.5359006546  1.04E-05
    58 Broy./Diag. 0.40E+00    7.3     0.00000255     -4911.5359058876 -5.23E-06
    59 Broy./Diag. 0.40E+00    6.7     0.00000148     -4911.5359033171  2.57E-06
    60 Broy./Diag. 0.40E+00    7.7     0.00000186     -4911.5359086784 -5.36E-06
    61 Broy./Diag. 0.40E+00    7.3     0.00000163     -4911.5359109808 -2.30E-06
    62 Broy./Diag. 0.40E+00    7.1     0.00000146     -4911.5359053770  5.60E-06
    63 Broy./Diag. 0.40E+00    7.6     0.00000139     -4911.5359116730 -6.30E-06
    64 Broy./Diag. 0.40E+00    6.9     0.00000157     -4911.5359091456  2.53E-06
    65 Broy./Diag. 0.40E+00    7.5     0.00000104     -4911.5359131250 -3.98E-06
    66 Broy./Diag. 0.40E+00    6.9     0.00000113     -4911.5359107906  2.33E-06
    67 Broy./Diag. 0.40E+00    6.9     0.00000103     -4911.5359102644  5.26E-07
    68 Broy./Diag. 0.40E+00    7.3     0.00000084     -4911.5359144594 -4.19E-06

  *** SCF run converged in    68 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008276019697
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.55395183900782
  Hartree energy:                                            1781.63846447342485
  Exchange-correlation energy:                               -779.40062451195035
  Electronic entropic energy:                                  -0.23736649160920
  Fermi energy:                                                 0.08674493237796

  Total energy:                                             -4911.53591445935126

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.535917278247325

 MD| ***************************************************************************
 MD| Step number                                                            1249
 MD| Time [fs]                                                       2498.000000
 MD| Conserved quantity [hartree]                            -0.491119019102E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    519.222764           589.635282
 MD| Energy drift per atom [K]           0.268615426333E+03   0.269153604011E+03
 MD| Potential energy [hartree]         -0.491153591728E+04  -0.491156209317E+04
 MD| Kinetic energy [hartree]            0.345726255073E+00   0.372156408051E+00
 MD| Temperature [K]                             921.279211           991.709356
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.8     0.02408831     -4911.5325388776 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.5     0.08890923     -4911.4289874875  1.04E-01
     3 Broy./Diag. 0.40E+00    7.7     0.08881361     -4911.6666899319 -2.38E-01
     4 Broy./Diag. 0.40E+00    7.1     0.02636409     -4911.4702337305  1.96E-01
     5 Broy./Diag. 0.40E+00    7.1     0.00675947     -4911.5223888616 -5.22E-02
     6 Broy./Diag. 0.40E+00    6.8     0.00641142     -4911.5576030745 -3.52E-02
     7 Broy./Diag. 0.40E+00    6.8     0.00327623     -4911.5273510104  3.03E-02
     8 Broy./Diag. 0.40E+00    6.9     0.00182366     -4911.5340188073 -6.67E-03
     9 Broy./Diag. 0.40E+00    7.3     0.00050662     -4911.5324508151  1.57E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00034596     -4911.5319004416  5.50E-04
    11 Broy./Diag. 0.40E+00    7.3     0.00036229     -4911.5326342659 -7.34E-04
    12 Broy./Diag. 0.40E+00    7.1     0.00028881     -4911.5320166990  6.18E-04
    13 Broy./Diag. 0.40E+00    7.4     0.00025483     -4911.5332922127 -1.28E-03
    14 Broy./Diag. 0.40E+00    7.5     0.00028400     -4911.5324507374  8.41E-04
    15 Broy./Diag. 0.40E+00    7.3     0.00011456     -4911.5334418140 -9.91E-04
    16 Broy./Diag. 0.40E+00    7.0     0.00013175     -4911.5338301348 -3.88E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00011046     -4911.5337456170  8.45E-05
    18 Broy./Diag. 0.40E+00    7.5     0.00012743     -4911.5338749824 -1.29E-04
    19 Broy./Diag. 0.40E+00    7.6     0.00007132     -4911.5338375590  3.74E-05
    20 Broy./Diag. 0.40E+00    7.5     0.00010699     -4911.5343338125 -4.96E-04
    21 Broy./Diag. 0.40E+00    7.0     0.00007719     -4911.5340087271  3.25E-04
    22 Broy./Diag. 0.40E+00    6.9     0.00004083     -4911.5340428890 -3.42E-05
    23 Broy./Diag. 0.40E+00    7.5     0.00003787     -4911.5341425795 -9.97E-05
    24 Broy./Diag. 0.40E+00    7.5     0.00003613     -4911.5341417336  8.46E-07
    25 Broy./Diag. 0.40E+00    7.3     0.00002184     -4911.5341826708 -4.09E-05
    26 Broy./Diag. 0.40E+00    7.1     0.00002580     -4911.5340591224  1.24E-04
    27 Broy./Diag. 0.40E+00    7.3     0.00002415     -4911.5341784400 -1.19E-04
    28 Broy./Diag. 0.40E+00    6.9     0.00001498     -4911.5341748171  3.62E-06
    29 Broy./Diag. 0.40E+00    6.8     0.00001940     -4911.5341586802  1.61E-05
    30 Broy./Diag. 0.40E+00    6.8     0.00001976     -4911.5341649370 -6.26E-06
    31 Broy./Diag. 0.40E+00    7.2     0.00001449     -4911.5341503297  1.46E-05
    32 Broy./Diag. 0.40E+00    6.9     0.00001330     -4911.5342277127 -7.74E-05
    33 Broy./Diag. 0.40E+00    7.1     0.00001293     -4911.5341704720  5.72E-05
    34 Broy./Diag. 0.40E+00    7.5     0.00000612     -4911.5341809775 -1.05E-05
    35 Broy./Diag. 0.40E+00    7.1     0.00000969     -4911.5341939659 -1.30E-05
    36 Broy./Diag. 0.40E+00    7.3     0.00000859     -4911.5342037640 -9.80E-06
    37 Broy./Diag. 0.40E+00    7.1     0.00000783     -4911.5342122882 -8.52E-06
    38 Broy./Diag. 0.40E+00    7.7     0.00000717     -4911.5341818793  3.04E-05
    39 Broy./Diag. 0.40E+00    6.7     0.00000809     -4911.5342192509 -3.74E-05
    40 Broy./Diag. 0.40E+00    7.1     0.00000394     -4911.5342157670  3.48E-06
    41 Broy./Diag. 0.40E+00    7.3     0.00000625     -4911.5342170253 -1.26E-06
    42 Broy./Diag. 0.40E+00    6.8     0.00000528     -4911.5342118829  5.14E-06
    43 Broy./Diag. 0.40E+00    7.5     0.00000469     -4911.5342104012  1.48E-06
    44 Broy./Diag. 0.40E+00    7.1     0.00000368     -4911.5342309081 -2.05E-05
    45 Broy./Diag. 0.40E+00    7.1     0.00000434     -4911.5342145328  1.64E-05
    46 Broy./Diag. 0.40E+00    7.1     0.00000235     -4911.5342213116 -6.78E-06
    47 Broy./Diag. 0.40E+00    6.7     0.00000382     -4911.5342224444 -1.13E-06
    48 Broy./Diag. 0.40E+00    7.4     0.00000272     -4911.5342287395 -6.30E-06
    49 Broy./Diag. 0.40E+00    7.7     0.00000297     -4911.5342312775 -2.54E-06
    50 Broy./Diag. 0.40E+00    6.9     0.00000223     -4911.5342201282  1.11E-05
    51 Broy./Diag. 0.40E+00    7.3     0.00000277     -4911.5342323048 -1.22E-05
    52 Broy./Diag. 0.40E+00    8.2     0.00000153     -4911.5342300321  2.27E-06
    53 Broy./Diag. 0.40E+00    7.4     0.00000201     -4911.5342322873 -2.26E-06
    54 Broy./Diag. 0.40E+00    6.7     0.00000150     -4911.5342294047  2.88E-06
    55 Broy./Diag. 0.40E+00    7.3     0.00000160     -4911.5342299108 -5.06E-07
    56 Broy./Diag. 0.40E+00    7.3     0.00000108     -4911.5342364487 -6.54E-06
    57 Broy./Diag. 0.40E+00    6.9     0.00000159     -4911.5342316336  4.82E-06
    58 Broy./Diag. 0.40E+00    7.4     0.00000104     -4911.5342340538 -2.42E-06
    59 Broy./Diag. 0.40E+00    7.3     0.00000126     -4911.5342330836  9.70E-07
    60 Broy./Diag. 0.40E+00    7.3     0.00000084     -4911.5342364259 -3.34E-06

  *** SCF run converged in    60 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008273736391
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.51497657537448
  Hartree energy:                                            1781.66249631923984
  Exchange-correlation energy:                               -779.38406200555289
  Electronic entropic energy:                                  -0.23730754451363
  Fermi energy:                                                 0.08667111444476

  Total energy:                                             -4911.53423642590133

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.534239656299178

 MD| ***************************************************************************
 MD| Step number                                                            1250
 MD| Time [fs]                                                       2500.000000
 MD| Conserved quantity [hartree]                            -0.491118388918E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    442.276348           589.517395
 MD| Energy drift per atom [K]           0.281707291361E+03   0.269163646961E+03
 MD| Potential energy [hartree]         -0.491153423966E+04  -0.491156207088E+04
 MD| Kinetic energy [hartree]            0.350350480019E+00   0.372138963309E+00
 MD| Temperature [K]                             933.601683           991.662870
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02104527     -4911.5314229690 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.07470674     -4911.4443522836  8.71E-02
     3 Broy./Diag. 0.40E+00    6.7     0.07467839     -4911.6190457588 -1.75E-01
     4 Broy./Diag. 0.40E+00    7.4     0.02267650     -4911.4861049216  1.33E-01
     5 Broy./Diag. 0.40E+00    6.7     0.00643042     -4911.5232308002 -3.71E-02
     6 Broy./Diag. 0.40E+00    7.1     0.00595524     -4911.5433955075 -2.02E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00299059     -4911.5298144727  1.36E-02
     8 Broy./Diag. 0.40E+00    7.1     0.00162960     -4911.5292499017  5.65E-04
     9 Broy./Diag. 0.40E+00    7.7     0.00057083     -4911.5301508266 -9.01E-04
    10 Broy./Diag. 0.40E+00    6.9     0.00043731     -4911.5324321129 -2.28E-03
    11 Broy./Diag. 0.40E+00    6.9     0.00017121     -4911.5307295191  1.70E-03
    12 Broy./Diag. 0.40E+00    7.0     0.00020981     -4911.5311255630 -3.96E-04
    13 Broy./Diag. 0.40E+00    7.0     0.00018839     -4911.5318378421 -7.12E-04
    14 Broy./Diag. 0.40E+00    7.3     0.00016256     -4911.5319229751 -8.51E-05
    15 Broy./Diag. 0.40E+00    7.4     0.00012020     -4911.5320415467 -1.19E-04
    16 Broy./Diag. 0.40E+00    8.2     0.00008701     -4911.5323063125 -2.65E-04
    17 Broy./Diag. 0.40E+00    7.5     0.00005424     -4911.5327451573 -4.39E-04
    18 Broy./Diag. 0.40E+00    7.1     0.00004730     -4911.5325266202  2.19E-04
    19 Broy./Diag. 0.40E+00    7.3     0.00005133     -4911.5328909504 -3.64E-04
    20 Broy./Diag. 0.40E+00    7.1     0.00004282     -4911.5329053004 -1.44E-05
    21 Broy./Diag. 0.40E+00    7.2     0.00003512     -4911.5328940188  1.13E-05
    22 Broy./Diag. 0.40E+00    6.7     0.00003140     -4911.5328915414  2.48E-06
    23 Broy./Diag. 0.40E+00    7.1     0.00002006     -4911.5328902564  1.28E-06
    24 Broy./Diag. 0.40E+00    7.0     0.00001731     -4911.5330018569 -1.12E-04
    25 Broy./Diag. 0.40E+00    7.3     0.00001601     -4911.5328901288  1.12E-04
    26 Broy./Diag. 0.40E+00    7.0     0.00001663     -4911.5329306376 -4.05E-05
    27 Broy./Diag. 0.40E+00    7.1     0.00001503     -4911.5329450737 -1.44E-05
    28 Broy./Diag. 0.40E+00    7.5     0.00001305     -4911.5329475897 -2.52E-06
    29 Broy./Diag. 0.40E+00    7.1     0.00000864     -4911.5329497703 -2.18E-06
    30 Broy./Diag. 0.40E+00    7.1     0.00000633     -4911.5329093335  4.04E-05
    31 Broy./Diag. 0.40E+00    7.1     0.00000681     -4911.5329524192 -4.31E-05
    32 Broy./Diag. 0.40E+00    6.9     0.00000613     -4911.5329369609  1.55E-05
    33 Broy./Diag. 0.40E+00    7.1     0.00000542     -4911.5329325356  4.43E-06
    34 Broy./Diag. 0.40E+00    7.7     0.00000606     -4911.5329323954  1.40E-07
    35 Broy./Diag. 0.40E+00    7.1     0.00000467     -4911.5329310954  1.30E-06
    36 Broy./Diag. 0.40E+00    6.9     0.00000310     -4911.5329487112 -1.76E-05
    37 Broy./Diag. 0.40E+00    7.3     0.00000315     -4911.5329276576  2.11E-05
    38 Broy./Diag. 0.40E+00    7.2     0.00000305     -4911.5329358400 -8.18E-06
    39 Broy./Diag. 0.40E+00    6.9     0.00000250     -4911.5329366487 -8.09E-07
    40 Broy./Diag. 0.40E+00    7.7     0.00000248     -4911.5329364080  2.41E-07
    41 Broy./Diag. 0.40E+00    7.1     0.00000193     -4911.5329372750 -8.67E-07
    42 Broy./Diag. 0.40E+00    7.5     0.00000139     -4911.5329307861  6.49E-06
    43 Broy./Diag. 0.40E+00    6.7     0.00000167     -4911.5329394999 -8.71E-06
    44 Broy./Diag. 0.40E+00    7.1     0.00000159     -4911.5329352046  4.30E-06
    45 Broy./Diag. 0.40E+00    7.1     0.00000134     -4911.5329357851 -5.81E-07
    46 Broy./Diag. 0.40E+00    6.7     0.00000152     -4911.5329355746  2.11E-07
    47 Broy./Diag. 0.40E+00    7.5     0.00000113     -4911.5329346683  9.06E-07
    48 Broy./Diag. 0.40E+00    7.1     0.00000072     -4911.5329384560 -3.79E-06

  *** SCF run converged in    48 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008271961586
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.48262962546141
  Hartree energy:                                            1781.68209393584425
  Exchange-correlation energy:                               -779.37002854377170
  Electronic entropic energy:                                  -0.23729365926834
  Fermi energy:                                                 0.08660895655762

  Total energy:                                             -4911.53293845603548

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.532937126741672

 MD| ***************************************************************************
 MD| Step number                                                            1251
 MD| Time [fs]                                                       2502.000000
 MD| Conserved quantity [hartree]                            -0.491119420576E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    352.973421           589.328311
 MD| Energy drift per atom [K]           0.260274942396E+03   0.269156541682E+03
 MD| Potential energy [hartree]         -0.491153293713E+04  -0.491156204759E+04
 MD| Kinetic energy [hartree]            0.338731362147E+00   0.372112258591E+00
 MD| Temperature [K]                             902.639465           991.591708
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.01975626     -4911.5301531199 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.04564877     -4911.4755655943  5.46E-02
     3 Broy./Diag. 0.40E+00    6.9     0.04965700     -4911.5403347083 -6.48E-02
     4 Broy./Diag. 0.40E+00    6.7     0.01911573     -4911.5035240448  3.68E-02
     5 Broy./Diag. 0.40E+00    7.1     0.00691092     -4911.5311877638 -2.77E-02
     6 Broy./Diag. 0.40E+00    7.5     0.00531991     -4911.5206239995  1.06E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00233425     -4911.5296075215 -8.98E-03
     8 Broy./Diag. 0.40E+00    7.1     0.00155119     -4911.5308892792 -1.28E-03
     9 Broy./Diag. 0.40E+00    7.3     0.00050184     -4911.5286997634  2.19E-03
    10 Broy./Diag. 0.40E+00    7.3     0.00034112     -4911.5309871487 -2.29E-03
    11 Broy./Diag. 0.40E+00    7.5     0.00020758     -4911.5295858536  1.40E-03
    12 Broy./Diag. 0.40E+00    7.5     0.00025767     -4911.5298930801 -3.07E-04
    13 Broy./Diag. 0.40E+00    7.1     0.00022034     -4911.5298558098  3.73E-05
    14 Broy./Diag. 0.40E+00    6.7     0.00016690     -4911.5306291382 -7.73E-04
    15 Broy./Diag. 0.40E+00    7.3     0.00016627     -4911.5309178883 -2.89E-04
    16 Broy./Diag. 0.40E+00    7.3     0.00014515     -4911.5304064617  5.11E-04
    17 Broy./Diag. 0.40E+00    7.4     0.00011468     -4911.5311893315 -7.83E-04
    18 Broy./Diag. 0.40E+00    7.1     0.00010867     -4911.5311681269  2.12E-05
    19 Broy./Diag. 0.40E+00    7.3     0.00011124     -4911.5314199763 -2.52E-04
    20 Broy./Diag. 0.40E+00    6.9     0.00008228     -4911.5311106530  3.09E-04
    21 Broy./Diag. 0.40E+00    7.7     0.00006383     -4911.5312003522 -8.97E-05
    22 Broy./Diag. 0.40E+00    7.1     0.00004998     -4911.5315062934 -3.06E-04
    23 Broy./Diag. 0.40E+00    7.5     0.00003495     -4911.5313085592  1.98E-04
    24 Broy./Diag. 0.40E+00    7.3     0.00002858     -4911.5313570158 -4.85E-05
    25 Broy./Diag. 0.40E+00    7.6     0.00002656     -4911.5313262930  3.07E-05
    26 Broy./Diag. 0.40E+00    7.3     0.00002920     -4911.5314688866 -1.43E-04
    27 Broy./Diag. 0.40E+00    6.9     0.00003169     -4911.5314410030  2.79E-05
    28 Broy./Diag. 0.40E+00    7.4     0.00002583     -4911.5313395229  1.01E-04
    29 Broy./Diag. 0.40E+00    7.1     0.00002270     -4911.5314833750 -1.44E-04
    30 Broy./Diag. 0.40E+00    7.3     0.00002181     -4911.5314680503  1.53E-05
    31 Broy./Diag. 0.40E+00    6.9     0.00001646     -4911.5315206823 -5.26E-05
    32 Broy./Diag. 0.40E+00    7.1     0.00001338     -4911.5314372566  8.34E-05
    33 Broy./Diag. 0.40E+00    7.3     0.00001268     -4911.5314638813 -2.66E-05
    34 Broy./Diag. 0.40E+00    8.5     0.00000993     -4911.5315260469 -6.22E-05
    35 Broy./Diag. 0.40E+00    6.9     0.00000846     -4911.5314813118  4.47E-05
    36 Broy./Diag. 0.40E+00    7.1     0.00001063     -4911.5314976249 -1.63E-05
    37 Broy./Diag. 0.40E+00    7.1     0.00000969     -4911.5314866478  1.10E-05
    38 Broy./Diag. 0.40E+00    6.9     0.00000864     -4911.5315482857 -6.16E-05
    39 Broy./Diag. 0.40E+00    6.8     0.00001022     -4911.5315349551  1.33E-05
    40 Broy./Diag. 0.40E+00    7.3     0.00000720     -4911.5314914982  4.35E-05
    41 Broy./Diag. 0.40E+00    6.8     0.00000461     -4911.5315330835 -4.16E-05
    42 Broy./Diag. 0.40E+00    7.3     0.00000503     -4911.5315334293 -3.46E-07
    43 Broy./Diag. 0.40E+00    7.2     0.00000452     -4911.5315422634 -8.83E-06
    44 Broy./Diag. 0.40E+00    7.3     0.00000337     -4911.5315177681  2.45E-05
    45 Broy./Diag. 0.40E+00    6.5     0.00000452     -4911.5315343249 -1.66E-05
    46 Broy./Diag. 0.40E+00    6.9     0.00000420     -4911.5315552939 -2.10E-05
    47 Broy./Diag. 0.40E+00    7.0     0.00000298     -4911.5315351198  2.02E-05
    48 Broy./Diag. 0.40E+00    7.1     0.00000360     -4911.5315411313 -6.01E-06
    49 Broy./Diag. 0.40E+00    7.5     0.00000319     -4911.5315375812  3.55E-06
    50 Broy./Diag. 0.40E+00    7.4     0.00000218     -4911.5315572802 -1.97E-05
    51 Broy./Diag. 0.40E+00    7.8     0.00000253     -4911.5315493674  7.91E-06
    52 Broy./Diag. 0.40E+00    7.1     0.00000192     -4911.5315401766  9.19E-06
    53 Broy./Diag. 0.40E+00    7.1     0.00000131     -4911.5315523975 -1.22E-05
    54 Broy./Diag. 0.40E+00    7.1     0.00000153     -4911.5315513646  1.03E-06
    55 Broy./Diag. 0.40E+00    7.2     0.00000170     -4911.5315538461 -2.48E-06
    56 Broy./Diag. 0.40E+00    7.5     0.00000142     -4911.5315456944  8.15E-06
    57 Broy./Diag. 0.40E+00    7.1     0.00000161     -4911.5315530640 -7.37E-06
    58 Broy./Diag. 0.40E+00    7.3     0.00000141     -4911.5315592257 -6.16E-06
    59 Broy./Diag. 0.40E+00    7.5     0.00000098     -4911.5315519916  7.23E-06

  *** SCF run converged in    59 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008271353943
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.45378345933932
  Hartree energy:                                            1781.69956531804314
  Exchange-correlation energy:                               -779.35726166775498
  Electronic entropic energy:                                  -0.23729932166284
  Fermi energy:                                                 0.08655202725163

  Total energy:                                             -4911.53155199158664

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.531560204808557

 MD| ***************************************************************************
 MD| Step number                                                            1252
 MD| Time [fs]                                                       2504.000000
 MD| Conserved quantity [hartree]                            -0.491118494463E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    433.902622           589.204169
 MD| Energy drift per atom [K]           0.279514615291E+03   0.269164814903E+03
 MD| Potential energy [hartree]         -0.491153156020E+04  -0.491156202324E+04
 MD| Kinetic energy [hartree]            0.346615570895E+00   0.372091893825E+00
 MD| Temperature [K]                             923.649028           991.537441
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.01923873     -4911.5285784260 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.7     0.04123780     -4911.4714420971  5.71E-02
     3 Broy./Diag. 0.40E+00    6.8     0.04603638     -4911.5546146232 -8.32E-02
     4 Broy./Diag. 0.40E+00    6.9     0.01874186     -4911.4908602684  6.38E-02
     5 Broy./Diag. 0.40E+00    7.1     0.00747944     -4911.5337983450 -4.29E-02
     6 Broy./Diag. 0.40E+00    7.1     0.00553178     -4911.5149028741  1.89E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00268412     -4911.5291848822 -1.43E-02
     8 Broy./Diag. 0.40E+00    7.7     0.00165229     -4911.5287347870  4.50E-04
     9 Broy./Diag. 0.40E+00    6.7     0.00051414     -4911.5279460853  7.89E-04
    10 Broy./Diag. 0.40E+00    7.5     0.00042823     -4911.5290210109 -1.07E-03
    11 Broy./Diag. 0.40E+00    7.1     0.00017040     -4911.5281447033  8.76E-04
    12 Broy./Diag. 0.40E+00    7.6     0.00019209     -4911.5289253898 -7.81E-04
    13 Broy./Diag. 0.40E+00    7.1     0.00020366     -4911.5282959203  6.29E-04
    14 Broy./Diag. 0.40E+00    7.3     0.00016676     -4911.5293517548 -1.06E-03
    15 Broy./Diag. 0.40E+00    7.2     0.00010930     -4911.5292552124  9.65E-05
    16 Broy./Diag. 0.40E+00    7.7     0.00012391     -4911.5290929889  1.62E-04
    17 Broy./Diag. 0.40E+00    7.2     0.00009944     -4911.5296308702 -5.38E-04
    18 Broy./Diag. 0.40E+00    7.0     0.00007239     -4911.5296207392  1.01E-05
    19 Broy./Diag. 0.40E+00    7.5     0.00007139     -4911.5299077754 -2.87E-04
    20 Broy./Diag. 0.40E+00    7.3     0.00007372     -4911.5295447929  3.63E-04
    21 Broy./Diag. 0.40E+00    7.9     0.00004413     -4911.5298055600 -2.61E-04
    22 Broy./Diag. 0.40E+00    7.2     0.00004377     -4911.5299256331 -1.20E-04
    23 Broy./Diag. 0.40E+00    9.9     0.00003364     -4911.5297895526  1.36E-04
    24 Broy./Diag. 0.40E+00    7.5     0.00002124     -4911.5298223193 -3.28E-05
    25 Broy./Diag. 0.40E+00    9.9     0.00001553     -4911.5297866844  3.56E-05
    26 Broy./Diag. 0.40E+00    8.9     0.00002140     -4911.5299035443 -1.17E-04
    27 Broy./Diag. 0.40E+00    6.7     0.00001680     -4911.5298188388  8.47E-05
    28 Broy./Diag. 0.40E+00    6.9     0.00001610     -4911.5298173229  1.52E-06
    29 Broy./Diag. 0.40E+00    7.1     0.00001543     -4911.5298777658 -6.04E-05
    30 Broy./Diag. 0.40E+00    7.5     0.00001053     -4911.5298749241  2.84E-06
    31 Broy./Diag. 0.40E+00    7.2     0.00000819     -4911.5298909762 -1.61E-05
    32 Broy./Diag. 0.40E+00    7.7     0.00000850     -4911.5298345154  5.65E-05
    33 Broy./Diag. 0.40E+00    8.6     0.00000760     -4911.5298866028 -5.21E-05
    34 Broy./Diag. 0.40E+00    8.8     0.00000676     -4911.5298918475 -5.24E-06
    35 Broy./Diag. 0.40E+00    7.7     0.00000698     -4911.5298741608  1.77E-05
    36 Broy./Diag. 0.40E+00   10.3     0.00000568     -4911.5298805282 -6.37E-06
    37 Broy./Diag. 0.40E+00    7.4     0.00000446     -4911.5298788358  1.69E-06
    38 Broy./Diag. 0.40E+00    7.5     0.00000518     -4911.5299121349 -3.33E-05
    39 Broy./Diag. 0.40E+00    7.1     0.00000526     -4911.5298851586  2.70E-05
    40 Broy./Diag. 0.40E+00    8.2     0.00000395     -4911.5298845516  6.07E-07
    41 Broy./Diag. 0.40E+00    7.1     0.00000383     -4911.5299014474 -1.69E-05
    42 Broy./Diag. 0.40E+00    8.0     0.00000293     -4911.5299005208  9.27E-07
    43 Broy./Diag. 0.40E+00    9.0     0.00000236     -4911.5299038084 -3.29E-06
    44 Broy./Diag. 0.40E+00    7.5     0.00000230     -4911.5298882718  1.55E-05
    45 Broy./Diag. 0.40E+00   10.5     0.00000268     -4911.5299063019 -1.80E-05
    46 Broy./Diag. 0.40E+00    7.2     0.00000241     -4911.5299076606 -1.36E-06
    47 Broy./Diag. 0.40E+00    6.9     0.00000237     -4911.5299008793  6.78E-06
    48 Broy./Diag. 0.40E+00    7.3     0.00000193     -4911.5299035806 -2.70E-06
    49 Broy./Diag. 0.40E+00    7.1     0.00000130     -4911.5299034211  1.60E-07
    50 Broy./Diag. 0.40E+00    7.1     0.00000137     -4911.5299128207 -9.40E-06
    51 Broy./Diag. 0.40E+00    7.1     0.00000132     -4911.5299041833  8.64E-06
    52 Broy./Diag. 0.40E+00    7.3     0.00000112     -4911.5299058908 -1.71E-06
    53 Broy./Diag. 0.40E+00    7.1     0.00000118     -4911.5299098356 -3.94E-06
    54 Broy./Diag. 0.40E+00    7.9     0.00000104     -4911.5299096638  1.72E-07
    55 Broy./Diag. 0.40E+00    7.3     0.00000080     -4911.5299106259 -9.62E-07

  *** SCF run converged in    55 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008271994764
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.42652143001123
  Hartree energy:                                            1781.71621956146214
  Exchange-correlation energy:                               -779.34500939256338
  Electronic entropic energy:                                  -0.23730240739526
  Fermi energy:                                                 0.08649748514134

  Total energy:                                             -4911.52991062586443

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.529914510701929

 MD| ***************************************************************************
 MD| Step number                                                            1253
 MD| Time [fs]                                                       2506.000000
 MD| Conserved quantity [hartree]                            -0.491116931041E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    426.469151           589.074293
 MD| Energy drift per atom [K]           0.311994170644E+03   0.269198996352E+03
 MD| Potential energy [hartree]         -0.491152991451E+04  -0.491156199762E+04
 MD| Kinetic energy [hartree]            0.360604103432E+00   0.372082725596E+00
 MD| Temperature [K]                             960.925180           991.513010
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.6     0.01811548     -4911.5274294186 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.9     0.04127825     -4911.4701991131  5.72E-02
     3 Broy./Diag. 0.40E+00    7.3     0.04068152     -4911.5550973675 -8.49E-02
     4 Broy./Diag. 0.40E+00    7.3     0.01756342     -4911.4909634703  6.41E-02
     5 Broy./Diag. 0.40E+00    6.9     0.00968205     -4911.5322227993 -4.13E-02
     6 Broy./Diag. 0.40E+00    7.2     0.00531520     -4911.5180216976  1.42E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00283682     -4911.5268877570 -8.87E-03
     8 Broy./Diag. 0.40E+00    7.1     0.00177888     -4911.5284749532 -1.59E-03
     9 Broy./Diag. 0.40E+00    6.7     0.00088089     -4911.5255659356  2.91E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00054831     -4911.5294954974 -3.93E-03
    11 Broy./Diag. 0.40E+00    7.3     0.00029823     -4911.5273539626  2.14E-03
    12 Broy./Diag. 0.40E+00    7.3     0.00033203     -4911.5274162877 -6.23E-05
    13 Broy./Diag. 0.40E+00    6.9     0.00024067     -4911.5271032456  3.13E-04
    14 Broy./Diag. 0.40E+00    7.8     0.00017382     -4911.5278653830 -7.62E-04
    15 Broy./Diag. 0.40E+00    7.0     0.00020893     -4911.5283236379 -4.58E-04
    16 Broy./Diag. 0.40E+00    7.0     0.00018354     -4911.5276556616  6.68E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00015001     -4911.5283653316 -7.10E-04
    18 Broy./Diag. 0.40E+00    7.0     0.00011524     -4911.5283410949  2.42E-05
    19 Broy./Diag. 0.40E+00    7.3     0.00012133     -4911.5285710963 -2.30E-04
    20 Broy./Diag. 0.40E+00    7.2     0.00008289     -4911.5282823500  2.89E-04
    21 Broy./Diag. 0.40E+00    6.7     0.00006323     -4911.5283440168 -6.17E-05
    22 Broy./Diag. 0.40E+00    7.3     0.00006896     -4911.5286416731 -2.98E-04
    23 Broy./Diag. 0.40E+00    7.7     0.00005428     -4911.5284265181  2.15E-04
    24 Broy./Diag. 0.40E+00    6.9     0.00003309     -4911.5285419230 -1.15E-04
    25 Broy./Diag. 0.40E+00    7.0     0.00003076     -4911.5285016963  4.02E-05
    26 Broy./Diag. 0.40E+00    7.6     0.00002704     -4911.5285985896 -9.69E-05
    27 Broy./Diag. 0.40E+00    6.9     0.00003142     -4911.5286279607 -2.94E-05
    28 Broy./Diag. 0.40E+00    7.3     0.00003556     -4911.5285175896  1.10E-04
    29 Broy./Diag. 0.40E+00    7.1     0.00003449     -4911.5286700098 -1.52E-04
    30 Broy./Diag. 0.40E+00    7.8     0.00002876     -4911.5285944446  7.56E-05
    31 Broy./Diag. 0.40E+00    7.2     0.00002029     -4911.5286778108 -8.34E-05
    32 Broy./Diag. 0.40E+00    7.3     0.00001335     -4911.5286524408  2.54E-05
    33 Broy./Diag. 0.40E+00    7.1     0.00001494     -4911.5286312364  2.12E-05
    34 Broy./Diag. 0.40E+00    7.1     0.00001415     -4911.5286948713 -6.36E-05
    35 Broy./Diag. 0.40E+00    7.1     0.00001369     -4911.5286579583  3.69E-05
    36 Broy./Diag. 0.40E+00    7.1     0.00001363     -4911.5287054565 -4.75E-05
    37 Broy./Diag. 0.40E+00    7.5     0.00001070     -4911.5286675946  3.79E-05
    38 Broy./Diag. 0.40E+00    7.1     0.00000911     -4911.5286981682 -3.06E-05
    39 Broy./Diag. 0.40E+00    7.4     0.00001225     -4911.5287283559 -3.02E-05
    40 Broy./Diag. 0.40E+00    7.3     0.00000981     -4911.5286921256  3.62E-05
    41 Broy./Diag. 0.40E+00    6.9     0.00000834     -4911.5287227182 -3.06E-05
    42 Broy./Diag. 0.40E+00    6.9     0.00000768     -4911.5286993497  2.34E-05
    43 Broy./Diag. 0.40E+00    7.0     0.00000522     -4911.5287325489 -3.32E-05
    44 Broy./Diag. 0.40E+00    6.8     0.00000390     -4911.5287237658  8.78E-06
    45 Broy./Diag. 0.40E+00    7.5     0.00000532     -4911.5287162159  7.55E-06
    46 Broy./Diag. 0.40E+00    6.9     0.00000567     -4911.5287380427 -2.18E-05
    47 Broy./Diag. 0.40E+00    7.5     0.00000498     -4911.5287245972  1.34E-05
    48 Broy./Diag. 0.40E+00    7.5     0.00000510     -4911.5287458374 -2.12E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00000409     -4911.5287251336  2.07E-05
    50 Broy./Diag. 0.40E+00    7.4     0.00000316     -4911.5287344822 -9.35E-06
    51 Broy./Diag. 0.40E+00    7.3     0.00000306     -4911.5287469454 -1.25E-05
    52 Broy./Diag. 0.40E+00    7.3     0.00000244     -4911.5287374697  9.48E-06
    53 Broy./Diag. 0.40E+00    6.9     0.00000220     -4911.5287442951 -6.83E-06
    54 Broy./Diag. 0.40E+00    6.9     0.00000208     -4911.5287376862  6.61E-06
    55 Broy./Diag. 0.40E+00    7.0     0.00000191     -4911.5287496087 -1.19E-05
    56 Broy./Diag. 0.40E+00    7.1     0.00000185     -4911.5287456669  3.94E-06
    57 Broy./Diag. 0.40E+00    7.0     0.00000199     -4911.5287417954  3.87E-06
    58 Broy./Diag. 0.40E+00    6.9     0.00000180     -4911.5287499920 -8.20E-06
    59 Broy./Diag. 0.40E+00    7.1     0.00000159     -4911.5287468730  3.12E-06
    60 Broy./Diag. 0.40E+00    7.6     0.00000137     -4911.5287525339 -5.66E-06
    61 Broy./Diag. 0.40E+00    7.4     0.00000103     -4911.5287461451  6.39E-06
    62 Broy./Diag. 0.40E+00    6.8     0.00000093     -4911.5287495716 -3.43E-06

  *** SCF run converged in    62 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008272546186
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.40245553322120
  Hartree energy:                                            1781.73079328434960
  Exchange-correlation energy:                               -779.33431119578506
  Electronic entropic energy:                                  -0.23734741875356
  Fermi energy:                                                 0.08644866640089

  Total energy:                                             -4911.52874957162931

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.528755965991877

 MD| ***************************************************************************
 MD| Step number                                                            1254
 MD| Time [fs]                                                       2508.000000
 MD| Conserved quantity [hartree]                            -0.491115858869E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    452.836709           588.965651
 MD| Energy drift per atom [K]           0.334268159856E+03   0.269250885637E+03
 MD| Potential energy [hartree]         -0.491152875597E+04  -0.491156197111E+04
 MD| Kinetic energy [hartree]            0.370167275562E+00   0.372081198124E+00
 MD| Temperature [K]                             986.408786           991.508939
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.01853220     -4911.5269371877 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.2     0.04854809     -4911.4972132109  2.97E-02
     3 Broy./Diag. 0.40E+00    6.9     0.04513423     -4911.5062287957 -9.02E-03
     4 Broy./Diag. 0.40E+00    7.5     0.02620274     -4911.5053649585  8.64E-04
     5 Broy./Diag. 0.40E+00    7.1     0.01063446     -4911.5381055185 -3.27E-02
     6 Broy./Diag. 0.40E+00    6.9     0.00419307     -4911.5187466077  1.94E-02
     7 Broy./Diag. 0.40E+00    7.7     0.00376504     -4911.5220549527 -3.31E-03
     8 Broy./Diag. 0.40E+00    7.5     0.00237041     -4911.5334511330 -1.14E-02
     9 Broy./Diag. 0.40E+00    7.1     0.00088514     -4911.5254189303  8.03E-03
    10 Broy./Diag. 0.40E+00    8.0     0.00083788     -4911.5281325854 -2.71E-03
    11 Broy./Diag. 0.40E+00    6.8     0.00041177     -4911.5272034151  9.29E-04
    12 Broy./Diag. 0.40E+00    7.3     0.00026525     -4911.5271675022  3.59E-05
    13 Broy./Diag. 0.40E+00    7.4     0.00020608     -4911.5268152318  3.52E-04
    14 Broy./Diag. 0.40E+00    7.5     0.00023037     -4911.5272335249 -4.18E-04
    15 Broy./Diag. 0.40E+00    7.3     0.00022681     -4911.5281661776 -9.33E-04
    16 Broy./Diag. 0.40E+00    7.3     0.00021208     -4911.5273355822  8.31E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00017486     -4911.5276657950 -3.30E-04
    18 Broy./Diag. 0.40E+00    8.0     0.00012011     -4911.5277482750 -8.25E-05
    19 Broy./Diag. 0.40E+00    7.5     0.00009989     -4911.5279843727 -2.36E-04
    20 Broy./Diag. 0.40E+00    7.2     0.00010926     -4911.5278709796  1.13E-04
    21 Broy./Diag. 0.40E+00    6.6     0.00008029     -4911.5275934026  2.78E-04
    22 Broy./Diag. 0.40E+00    8.1     0.00007357     -4911.5280180898 -4.25E-04
    23 Broy./Diag. 0.40E+00    6.9     0.00007287     -4911.5279144295  1.04E-04
    24 Broy./Diag. 0.40E+00    6.7     0.00004753     -4911.5279617933 -4.74E-05
    25 Broy./Diag. 0.40E+00    7.1     0.00004011     -4911.5279455460  1.62E-05
    26 Broy./Diag. 0.40E+00    6.8     0.00004375     -4911.5279869228 -4.14E-05
    27 Broy./Diag. 0.40E+00    7.0     0.00004418     -4911.5281310052 -1.44E-04
    28 Broy./Diag. 0.40E+00    7.3     0.00003827     -4911.5279234743  2.08E-04
    29 Broy./Diag. 0.40E+00    7.5     0.00003676     -4911.5280601695 -1.37E-04
    30 Broy./Diag. 0.40E+00    6.6     0.00002982     -4911.5280472450  1.29E-05
    31 Broy./Diag. 0.40E+00    6.8     0.00002641     -4911.5280775366 -3.03E-05
    32 Broy./Diag. 0.40E+00    7.1     0.00002415     -4911.5281034521 -2.59E-05
    33 Broy./Diag. 0.40E+00    7.1     0.00002345     -4911.5280442919  5.92E-05
    34 Broy./Diag. 0.40E+00    6.9     0.00002029     -4911.5281492178 -1.05E-04
    35 Broy./Diag. 0.40E+00    7.9     0.00001790     -4911.5281013818  4.78E-05
    36 Broy./Diag. 0.40E+00    7.2     0.00001518     -4911.5281351371 -3.38E-05
    37 Broy./Diag. 0.40E+00    7.5     0.00001324     -4911.5281197149  1.54E-05
    38 Broy./Diag. 0.40E+00    7.5     0.00001253     -4911.5281278493 -8.13E-06
    39 Broy./Diag. 0.40E+00    6.9     0.00001557     -4911.5281702841 -4.24E-05
    40 Broy./Diag. 0.40E+00    6.7     0.00001388     -4911.5281146441  5.56E-05
    41 Broy./Diag. 0.40E+00    7.5     0.00001046     -4911.5281640078 -4.94E-05
    42 Broy./Diag. 0.40E+00    7.3     0.00000898     -4911.5281473084  1.67E-05
    43 Broy./Diag. 0.40E+00    7.2     0.00000818     -4911.5281619185 -1.46E-05
    44 Broy./Diag. 0.40E+00    7.2     0.00000585     -4911.5281706506 -8.73E-06
    45 Broy./Diag. 0.40E+00    7.1     0.00000544     -4911.5281525895  1.81E-05
    46 Broy./Diag. 0.40E+00    7.5     0.00000662     -4911.5281775503 -2.50E-05
    47 Broy./Diag. 0.40E+00    6.9     0.00000622     -4911.5281587611  1.88E-05
    48 Broy./Diag. 0.40E+00    7.3     0.00000484     -4911.5281792687 -2.05E-05
    49 Broy./Diag. 0.40E+00    7.3     0.00000534     -4911.5281743947  4.87E-06
    50 Broy./Diag. 0.40E+00    7.3     0.00000446     -4911.5281702273  4.17E-06
    51 Broy./Diag. 0.40E+00    6.8     0.00000388     -4911.5281884369 -1.82E-05
    52 Broy./Diag. 0.40E+00    7.1     0.00000341     -4911.5281759575  1.25E-05
    53 Broy./Diag. 0.40E+00    6.6     0.00000305     -4911.5281869160 -1.10E-05
    54 Broy./Diag. 0.40E+00    6.6     0.00000203     -4911.5281790285  7.89E-06
    55 Broy./Diag. 0.40E+00    7.0     0.00000239     -4911.5281854497 -6.42E-06
    56 Broy./Diag. 0.40E+00    7.3     0.00000212     -4911.5281885250 -3.08E-06
    57 Broy./Diag. 0.40E+00    7.1     0.00000197     -4911.5281828830  5.64E-06
    58 Broy./Diag. 0.40E+00    7.1     0.00000238     -4911.5281906284 -7.75E-06
    59 Broy./Diag. 0.40E+00    6.8     0.00000253     -4911.5281848827  5.75E-06
    60 Broy./Diag. 0.40E+00    7.2     0.00000150     -4911.5281933582 -8.48E-06
    61 Broy./Diag. 0.40E+00    7.3     0.00000148     -4911.5281897470  3.61E-06
    62 Broy./Diag. 0.40E+00    7.5     0.00000116     -4911.5281885110  1.24E-06
    63 Broy./Diag. 0.40E+00    6.9     0.00000096     -4911.5281934137 -4.90E-06

  *** SCF run converged in    63 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008272363425
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.38245478964927
  Hartree energy:                                            1781.74234413335125
  Exchange-correlation energy:                               -779.32520762893796
  Electronic entropic energy:                                  -0.23744490127222
  Fermi energy:                                                 0.08641192751731

  Total energy:                                             -4911.52819341371833

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.528197021554661

 MD| ***************************************************************************
 MD| Step number                                                            1255
 MD| Time [fs]                                                       2510.000000
 MD| Conserved quantity [hartree]                            -0.491116102273E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    460.912798           588.863616
 MD| Energy drift per atom [K]           0.329211532928E+03   0.269298663046E+03
 MD| Potential energy [hartree]         -0.491152819702E+04  -0.491156194420E+04
 MD| Kinetic energy [hartree]            0.367174293757E+00   0.372077288240E+00
 MD| Temperature [K]                             978.433193           991.498521
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.01807069     -4911.5265336999 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.04404621     -4911.5153498473  1.12E-02
     3 Broy./Diag. 0.40E+00    6.9     0.04176672     -4911.4929989456  2.24E-02
     4 Broy./Diag. 0.40E+00    7.2     0.02549228     -4911.5111487216 -1.81E-02
     5 Broy./Diag. 0.40E+00    7.3     0.01012709     -4911.5425340006 -3.14E-02
     6 Broy./Diag. 0.40E+00    7.1     0.00388094     -4911.5179965876  2.45E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00388475     -4911.5219117761 -3.92E-03
     8 Broy./Diag. 0.40E+00    7.1     0.00245649     -4911.5361435839 -1.42E-02
     9 Broy./Diag. 0.40E+00    6.7     0.00081692     -4911.5267746307  9.37E-03
    10 Broy./Diag. 0.40E+00    7.3     0.00074286     -4911.5275181360 -7.44E-04
    11 Broy./Diag. 0.40E+00    7.4     0.00039408     -4911.5270257724  4.92E-04
    12 Broy./Diag. 0.40E+00    6.9     0.00024177     -4911.5274379213 -4.12E-04
    13 Broy./Diag. 0.40E+00    7.3     0.00017816     -4911.5270443087  3.94E-04
    14 Broy./Diag. 0.40E+00    7.7     0.00021833     -4911.5271082597 -6.40E-05
    15 Broy./Diag. 0.40E+00    7.3     0.00019147     -4911.5279273919 -8.19E-04
    16 Broy./Diag. 0.40E+00    7.1     0.00015842     -4911.5272822560  6.45E-04
    17 Broy./Diag. 0.40E+00    6.8     0.00014685     -4911.5274610317 -1.79E-04
    18 Broy./Diag. 0.40E+00    7.4     0.00010341     -4911.5273644833  9.65E-05
    19 Broy./Diag. 0.40E+00    7.5     0.00007931     -4911.5275771092 -2.13E-04
    20 Broy./Diag. 0.40E+00    7.2     0.00009828     -4911.5275889995 -1.19E-05
    21 Broy./Diag. 0.40E+00    7.4     0.00007273     -4911.5272884230  3.01E-04
    22 Broy./Diag. 0.40E+00    7.5     0.00005859     -4911.5275982990 -3.10E-04
    23 Broy./Diag. 0.40E+00    7.5     0.00006473     -4911.5275159910  8.23E-05
    24 Broy./Diag. 0.40E+00    7.1     0.00004345     -4911.5275965820 -8.06E-05
    25 Broy./Diag. 0.40E+00    7.1     0.00003483     -4911.5275387941  5.78E-05
    26 Broy./Diag. 0.40E+00    7.1     0.00004109     -4911.5275359689  2.83E-06
    27 Broy./Diag. 0.40E+00    7.1     0.00004081     -4911.5276722560 -1.36E-04
    28 Broy./Diag. 0.40E+00    6.6     0.00002956     -4911.5275103481  1.62E-04
    29 Broy./Diag. 0.40E+00    7.8     0.00003053     -4911.5276007263 -9.04E-05
    30 Broy./Diag. 0.40E+00    7.1     0.00002631     -4911.5275670038  3.37E-05
    31 Broy./Diag. 0.40E+00    7.9     0.00002134     -4911.5276095523 -4.25E-05
    32 Broy./Diag. 0.40E+00    7.1     0.00002202     -4911.5276300489 -2.05E-05
    33 Broy./Diag. 0.40E+00    7.3     0.00002166     -4911.5275661141  6.39E-05
    34 Broy./Diag. 0.40E+00    7.2     0.00001597     -4911.5276502997 -8.42E-05
    35 Broy./Diag. 0.40E+00    6.7     0.00001498     -4911.5276091480  4.12E-05
    36 Broy./Diag. 0.40E+00    6.8     0.00001350     -4911.5276373363 -2.82E-05
    37 Broy./Diag. 0.40E+00    8.0     0.00000992     -4911.5276181170  1.92E-05
    38 Broy./Diag. 0.40E+00    7.0     0.00001095     -4911.5276191666 -1.05E-06
    39 Broy./Diag. 0.40E+00    6.9     0.00001394     -4911.5276555154 -3.63E-05
    40 Broy./Diag. 0.40E+00    6.9     0.00001069     -4911.5276072145  4.83E-05
    41 Broy./Diag. 0.40E+00    7.0     0.00000862     -4911.5276437105 -3.65E-05
    42 Broy./Diag. 0.40E+00    7.3     0.00000834     -4911.5276275537  1.62E-05
    43 Broy./Diag. 0.40E+00    7.3     0.00000614     -4911.5276422765 -1.47E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00000531     -4911.5276468008 -4.52E-06
    45 Broy./Diag. 0.40E+00    7.3     0.00000486     -4911.5276289522  1.78E-05
    46 Broy./Diag. 0.40E+00    7.3     0.00000494     -4911.5276482464 -1.93E-05
    47 Broy./Diag. 0.40E+00    7.2     0.00000491     -4911.5276340387  1.42E-05
    48 Broy./Diag. 0.40E+00    7.1     0.00000436     -4911.5276482272 -1.42E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00000382     -4911.5276410066  7.22E-06
    50 Broy./Diag. 0.40E+00    6.9     0.00000388     -4911.5276396184  1.39E-06
    51 Broy./Diag. 0.40E+00    7.3     0.00000360     -4911.5276545583 -1.49E-05
    52 Broy./Diag. 0.40E+00    7.1     0.00000258     -4911.5276419293  1.26E-05
    53 Broy./Diag. 0.40E+00    7.7     0.00000229     -4911.5276500693 -8.14E-06
    54 Broy./Diag. 0.40E+00    8.0     0.00000178     -4911.5276442677  5.80E-06
    55 Broy./Diag. 0.40E+00    7.1     0.00000168     -4911.5276491078 -4.84E-06
    56 Broy./Diag. 0.40E+00    7.3     0.00000175     -4911.5276502650 -1.16E-06
    57 Broy./Diag. 0.40E+00    7.1     0.00000178     -4911.5276446313  5.63E-06
    58 Broy./Diag. 0.40E+00    6.9     0.00000181     -4911.5276516350 -7.00E-06
    59 Broy./Diag. 0.40E+00    7.0     0.00000195     -4911.5276468461  4.79E-06
    60 Broy./Diag. 0.40E+00    7.5     0.00000132     -4911.5276526303 -5.78E-06
    61 Broy./Diag. 0.40E+00    7.3     0.00000105     -4911.5276490981  3.53E-06
    62 Broy./Diag. 0.40E+00    6.9     0.00000091     -4911.5276487646  3.34E-07

  *** SCF run converged in    62 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008271861167
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.37142591690690
  Hartree energy:                                            1781.74781199683775
  Exchange-correlation energy:                               -779.31903217776630
  Electronic entropic energy:                                  -0.23751472587683
  Fermi energy:                                                 0.08639683691617

  Total energy:                                             -4911.52764876455694

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.527652507425955

 MD| ***************************************************************************
 MD| Step number                                                            1256
 MD| Time [fs]                                                       2512.000000
 MD| Conserved quantity [hartree]                            -0.491116613530E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    455.376229           588.757337
 MD| Energy drift per atom [K]           0.318590341942E+03   0.269337908013E+03
 MD| Potential energy [hartree]         -0.491152765251E+04  -0.491156191690E+04
 MD| Kinetic energy [hartree]            0.361517206340E+00   0.372068880532E+00
 MD| Temperature [K]                             963.358384           991.476116
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.6     0.01932857     -4911.5260293936 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.8     0.04136835     -4911.5318322161 -5.80E-03
     3 Broy./Diag. 0.40E+00    7.0     0.04084227     -4911.4794448819  5.24E-02
     4 Broy./Diag. 0.40E+00    6.8     0.02526801     -4911.5104181553 -3.10E-02
     5 Broy./Diag. 0.40E+00    7.5     0.01009718     -4911.5540982448 -4.37E-02
     6 Broy./Diag. 0.40E+00    7.1     0.00362580     -4911.5108205202  4.33E-02
     7 Broy./Diag. 0.40E+00    7.5     0.00277109     -4911.5261355604 -1.53E-02
     8 Broy./Diag. 0.40E+00    7.1     0.00183857     -4911.5331031153 -6.97E-03
     9 Broy./Diag. 0.40E+00    7.1     0.00100617     -4911.5270613563  6.04E-03
    10 Broy./Diag. 0.40E+00    6.9     0.00055736     -4911.5274568788 -3.96E-04
    11 Broy./Diag. 0.40E+00    6.9     0.00040882     -4911.5265421097  9.15E-04
    12 Broy./Diag. 0.40E+00    7.5     0.00026429     -4911.5274110485 -8.69E-04
    13 Broy./Diag. 0.40E+00    7.0     0.00014653     -4911.5267459362  6.65E-04
    14 Broy./Diag. 0.40E+00    6.9     0.00013788     -4911.5270550053 -3.09E-04
    15 Broy./Diag. 0.40E+00    7.1     0.00019478     -4911.5272407262 -1.86E-04
    16 Broy./Diag. 0.40E+00    7.1     0.00014331     -4911.5268933000  3.47E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00013884     -4911.5272676273 -3.74E-04
    18 Broy./Diag. 0.40E+00    7.2     0.00011104     -4911.5269180377  3.50E-04
    19 Broy./Diag. 0.40E+00    7.2     0.00006789     -4911.5271382879 -2.20E-04
    20 Broy./Diag. 0.40E+00    7.1     0.00006737     -4911.5270712633  6.70E-05
    21 Broy./Diag. 0.40E+00    6.9     0.00006430     -4911.5270579017  1.34E-05
    22 Broy./Diag. 0.40E+00    8.1     0.00005971     -4911.5271623319 -1.04E-04
    23 Broy./Diag. 0.40E+00    6.9     0.00005460     -4911.5269786628  1.84E-04
    24 Broy./Diag. 0.40E+00   10.2     0.00004290     -4911.5271511548 -1.72E-04
    25 Broy./Diag. 0.40E+00    7.4     0.00002532     -4911.5270808961  7.03E-05
    26 Broy./Diag. 0.40E+00    7.5     0.00003012     -4911.5270963082 -1.54E-05
    27 Broy./Diag. 0.40E+00   10.6     0.00003327     -4911.5271074949 -1.12E-05
    28 Broy./Diag. 0.40E+00    8.0     0.00003097     -4911.5270533202  5.42E-05
    29 Broy./Diag. 0.40E+00    6.9     0.00002666     -4911.5271476631 -9.43E-05
    30 Broy./Diag. 0.40E+00    7.3     0.00002802     -4911.5270525417  9.51E-05
    31 Broy./Diag. 0.40E+00    7.1     0.00001726     -4911.5270998120 -4.73E-05
    32 Broy./Diag. 0.40E+00    8.3     0.00001855     -4911.5270972823  2.53E-06
    33 Broy./Diag. 0.40E+00    7.7     0.00001682     -4911.5270925647  4.72E-06
    34 Broy./Diag. 0.40E+00    8.5     0.00001704     -4911.5271210071 -2.84E-05
    35 Broy./Diag. 0.40E+00    8.0     0.00001213     -4911.5270710735  4.99E-05
    36 Broy./Diag. 0.40E+00    7.8     0.00001353     -4911.5271199738 -4.89E-05
    37 Broy./Diag. 0.40E+00   10.0     0.00000812     -4911.5270974449  2.25E-05
    38 Broy./Diag. 0.40E+00    8.2     0.00001077     -4911.5270985130 -1.07E-06
    39 Broy./Diag. 0.40E+00    7.1     0.00001022     -4911.5271034326 -4.92E-06
    40 Broy./Diag. 0.40E+00    7.1     0.00001128     -4911.5270869674  1.65E-05
    41 Broy./Diag. 0.40E+00    8.0     0.00000723     -4911.5271174784 -3.05E-05
    42 Broy./Diag. 0.40E+00    7.3     0.00000835     -4911.5270866381  3.08E-05
    43 Broy./Diag. 0.40E+00    9.3     0.00000506     -4911.5271027928 -1.62E-05
    44 Broy./Diag. 0.40E+00    7.9     0.00000406     -4911.5271029572 -1.64E-07
    45 Broy./Diag. 0.40E+00    7.9     0.00000320     -4911.5270999632  2.99E-06
    46 Broy./Diag. 0.40E+00   10.7     0.00000539     -4911.5271048743 -4.91E-06
    47 Broy./Diag. 0.40E+00    6.9     0.00000366     -4911.5270907656  1.41E-05
    48 Broy./Diag. 0.40E+00    6.9     0.00000441     -4911.5271080061 -1.72E-05
    49 Broy./Diag. 0.40E+00    6.9     0.00000344     -4911.5270976771  1.03E-05
    50 Broy./Diag. 0.40E+00    7.1     0.00000322     -4911.5270983954 -7.18E-07
    51 Broy./Diag. 0.40E+00    6.9     0.00000260     -4911.5271019544 -3.56E-06
    52 Broy./Diag. 0.40E+00    7.1     0.00000286     -4911.5270980300  3.92E-06
    53 Broy./Diag. 0.40E+00    7.5     0.00000168     -4911.5271052002 -7.17E-06
    54 Broy./Diag. 0.40E+00    7.0     0.00000180     -4911.5270970821  8.12E-06
    55 Broy./Diag. 0.40E+00    7.8     0.00000157     -4911.5271020513 -4.97E-06
    56 Broy./Diag. 0.40E+00    6.9     0.00000114     -4911.5271016764  3.75E-07
    57 Broy./Diag. 0.40E+00    7.3     0.00000148     -4911.5270996990  1.98E-06
    58 Broy./Diag. 0.40E+00    7.3     0.00000213     -4911.5271020071 -2.31E-06
    59 Broy./Diag. 0.40E+00    6.9     0.00000138     -4911.5270969621  5.04E-06
    60 Broy./Diag. 0.40E+00    6.9     0.00000129     -4911.5271036107 -6.65E-06
    61 Broy./Diag. 0.40E+00    6.9     0.00000095     -4911.5270994921  4.12E-06

  *** SCF run converged in    61 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008270318380
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.36439529838754
  Hartree energy:                                            1781.75046357008068
  Exchange-correlation energy:                               -779.31403326015936
  Electronic entropic energy:                                  -0.23758529725680
  Fermi energy:                                                 0.08639093640285

  Total energy:                                             -4911.52709949209293

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.527100311079266

 MD| ***************************************************************************
 MD| Step number                                                            1257
 MD| Time [fs]                                                       2514.000000
 MD| Conserved quantity [hartree]                            -0.491117560832E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    467.488696           588.660862
 MD| Energy drift per atom [K]           0.298910478776E+03   0.269361434322E+03
 MD| Potential energy [hartree]         -0.491152710031E+04  -0.491156188920E+04
 MD| Kinetic energy [hartree]            0.351491991114E+00   0.372052510691E+00
 MD| Temperature [K]                             936.643542           991.432494
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02002731     -4911.5254180273 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.5     0.03805653     -4911.5318493529 -6.43E-03
     3 Broy./Diag. 0.40E+00    7.1     0.05262528     -4911.4897871908  4.21E-02
     4 Broy./Diag. 0.40E+00    7.5     0.02919219     -4911.5017461037 -1.20E-02
     5 Broy./Diag. 0.40E+00    7.7     0.00945516     -4911.5560086143 -5.43E-02
     6 Broy./Diag. 0.40E+00    7.1     0.00341885     -4911.5093719970  4.66E-02
     7 Broy./Diag. 0.40E+00    7.5     0.00295298     -4911.5258390107 -1.65E-02
     8 Broy./Diag. 0.40E+00    6.9     0.00243589     -4911.5328217636 -6.98E-03
     9 Broy./Diag. 0.40E+00    7.5     0.00101364     -4911.5261744399  6.65E-03
    10 Broy./Diag. 0.40E+00    7.5     0.00076711     -4911.5275842823 -1.41E-03
    11 Broy./Diag. 0.40E+00    7.3     0.00052211     -4911.5261779708  1.41E-03
    12 Broy./Diag. 0.40E+00    7.5     0.00024326     -4911.5269676132 -7.90E-04
    13 Broy./Diag. 0.40E+00    7.3     0.00013724     -4911.5262413660  7.26E-04
    14 Broy./Diag. 0.40E+00    7.1     0.00017110     -4911.5266677606 -4.26E-04
    15 Broy./Diag. 0.40E+00    6.9     0.00022990     -4911.5268942814 -2.27E-04
    16 Broy./Diag. 0.40E+00    7.2     0.00012793     -4911.5263553115  5.39E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00016411     -4911.5268028562 -4.48E-04
    18 Broy./Diag. 0.40E+00    6.9     0.00011562     -4911.5265230165  2.80E-04
    19 Broy./Diag. 0.40E+00    7.3     0.00006406     -4911.5266770116 -1.54E-04
    20 Broy./Diag. 0.40E+00    6.5     0.00006516     -4911.5265402890  1.37E-04
    21 Broy./Diag. 0.40E+00    7.5     0.00007605     -4911.5265192268  2.11E-05
    22 Broy./Diag. 0.40E+00    7.3     0.00004951     -4911.5266878494 -1.69E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00006757     -4911.5264815209  2.06E-04
    24 Broy./Diag. 0.40E+00    6.9     0.00004779     -4911.5266113095 -1.30E-04
    25 Broy./Diag. 0.40E+00    7.9     0.00002919     -4911.5265631650  4.81E-05
    26 Broy./Diag. 0.40E+00    7.0     0.00003333     -4911.5266177424 -5.46E-05
    27 Broy./Diag. 0.40E+00    6.7     0.00004284     -4911.5266015611  1.62E-05
    28 Broy./Diag. 0.40E+00    6.9     0.00002814     -4911.5265059084  9.57E-05
    29 Broy./Diag. 0.40E+00    7.3     0.00003035     -4911.5266131775 -1.07E-04
    30 Broy./Diag. 0.40E+00    7.1     0.00002716     -4911.5265461002  6.71E-05
    31 Broy./Diag. 0.40E+00    6.9     0.00001532     -4911.5265728410 -2.67E-05
    32 Broy./Diag. 0.40E+00    7.3     0.00001708     -4911.5265458190  2.70E-05
    33 Broy./Diag. 0.40E+00    7.4     0.00002300     -4911.5265595029 -1.37E-05
    34 Broy./Diag. 0.40E+00    7.6     0.00001837     -4911.5266101485 -5.06E-05
    35 Broy./Diag. 0.40E+00    7.1     0.00001594     -4911.5265381705  7.20E-05
    36 Broy./Diag. 0.40E+00    7.1     0.00001483     -4911.5265752462 -3.71E-05
    37 Broy./Diag. 0.40E+00    7.2     0.00000751     -4911.5265620352  1.32E-05
    38 Broy./Diag. 0.40E+00    6.9     0.00000850     -4911.5265692155 -7.18E-06
    39 Broy./Diag. 0.40E+00    6.9     0.00001235     -4911.5265623523  6.86E-06
    40 Broy./Diag. 0.40E+00    7.1     0.00001064     -4911.5265357584  2.66E-05
    41 Broy./Diag. 0.40E+00    7.5     0.00000856     -4911.5265739699 -3.82E-05
    42 Broy./Diag. 0.40E+00    7.3     0.00000927     -4911.5265518548  2.21E-05
    43 Broy./Diag. 0.40E+00    7.0     0.00000512     -4911.5265605677 -8.71E-06
    44 Broy./Diag. 0.40E+00    7.1     0.00000425     -4911.5265548343  5.73E-06
    45 Broy./Diag. 0.40E+00    6.9     0.00000503     -4911.5265575757 -2.74E-06
    46 Broy./Diag. 0.40E+00    6.9     0.00000543     -4911.5265657320 -8.16E-06
    47 Broy./Diag. 0.40E+00    6.9     0.00000415     -4911.5265464038  1.93E-05
    48 Broy./Diag. 0.40E+00    6.6     0.00000425     -4911.5265583376 -1.19E-05
    49 Broy./Diag. 0.40E+00    7.5     0.00000295     -4911.5265531171  5.22E-06
    50 Broy./Diag. 0.40E+00    7.5     0.00000289     -4911.5265562229 -3.11E-06
    51 Broy./Diag. 0.40E+00    7.1     0.00000314     -4911.5265545263  1.70E-06
    52 Broy./Diag. 0.40E+00    7.5     0.00000338     -4911.5265487070  5.82E-06
    53 Broy./Diag. 0.40E+00    7.1     0.00000250     -4911.5265600474 -1.13E-05
    54 Broy./Diag. 0.40E+00    7.3     0.00000230     -4911.5265518828  8.16E-06
    55 Broy./Diag. 0.40E+00    7.1     0.00000151     -4911.5265546242 -2.74E-06
    56 Broy./Diag. 0.40E+00    6.7     0.00000121     -4911.5265530130  1.61E-06
    57 Broy./Diag. 0.40E+00    7.7     0.00000141     -4911.5265529049  1.08E-07
    58 Broy./Diag. 0.40E+00    7.3     0.00000205     -4911.5265553490 -2.44E-06
    59 Broy./Diag. 0.40E+00    7.5     0.00000157     -4911.5265486302  6.72E-06
    60 Broy./Diag. 0.40E+00    7.3     0.00000150     -4911.5265541667 -5.54E-06
    61 Broy./Diag. 0.40E+00    6.7     0.00000104     -4911.5265516645  2.50E-06
    62 Broy./Diag. 0.40E+00    7.1     0.00000081     -4911.5265526332 -9.69E-07

  *** SCF run converged in    62 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008267578872
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.36290757039296
  Hartree energy:                                            1781.74975856404149
  Exchange-correlation energy:                               -779.31115113796977
  Electronic entropic energy:                                  -0.23772780058420
  Fermi energy:                                                 0.08639081391929

  Total energy:                                             -4911.52655263319048

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.526550576989393

 MD| ***************************************************************************
 MD| Step number                                                            1258
 MD| Time [fs]                                                       2516.000000
 MD| Conserved quantity [hartree]                            -0.491117746365E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    452.882159           588.552930
 MD| Energy drift per atom [K]           0.295056100794E+03   0.269381859335E+03
 MD| Potential energy [hartree]         -0.491152655058E+04  -0.491156186111E+04
 MD| Kinetic energy [hartree]            0.349086929317E+00   0.372034255062E+00
 MD| Temperature [K]                             930.234618           991.383847
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.01772291     -4911.5247522417 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.03515789     -4911.5565308506 -3.18E-02
     3 Broy./Diag. 0.40E+00    6.7     0.04921781     -4911.4285450267  1.28E-01
     4 Broy./Diag. 0.40E+00    7.1     0.02920120     -4911.5257489817 -9.72E-02
     5 Broy./Diag. 0.40E+00    7.6     0.01057065     -4911.5581485558 -3.24E-02
     6 Broy./Diag. 0.40E+00    7.3     0.00421641     -4911.5103741951  4.78E-02
     7 Broy./Diag. 0.40E+00    6.9     0.00420923     -4911.5191171675 -8.74E-03
     8 Broy./Diag. 0.40E+00    7.1     0.00260229     -4911.5347213781 -1.56E-02
     9 Broy./Diag. 0.40E+00    6.8     0.00094853     -4911.5257329265  8.99E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00118037     -4911.5259107218 -1.78E-04
    11 Broy./Diag. 0.40E+00    7.2     0.00072020     -4911.5252998363  6.11E-04
    12 Broy./Diag. 0.40E+00    7.3     0.00026533     -4911.5262812785 -9.81E-04
    13 Broy./Diag. 0.40E+00    7.8     0.00023925     -4911.5255891477  6.92E-04
    14 Broy./Diag. 0.40E+00    6.9     0.00024279     -4911.5254596156  1.30E-04
    15 Broy./Diag. 0.40E+00    7.2     0.00017550     -4911.5262012374 -7.42E-04
    16 Broy./Diag. 0.40E+00    7.1     0.00019464     -4911.5256945100  5.07E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00017931     -4911.5260193788 -3.25E-04
    18 Broy./Diag. 0.40E+00    7.1     0.00010759     -4911.5257800227  2.39E-04
    19 Broy./Diag. 0.40E+00    6.9     0.00008653     -4911.5258963138 -1.16E-04
    20 Broy./Diag. 0.40E+00    7.3     0.00011965     -4911.5259478497 -5.15E-05
    21 Broy./Diag. 0.40E+00    7.5     0.00008825     -4911.5256455463  3.02E-04
    22 Broy./Diag. 0.40E+00    7.5     0.00007187     -4911.5259604911 -3.15E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00008644     -4911.5257577914  2.03E-04
    24 Broy./Diag. 0.40E+00    7.4     0.00005249     -4911.5258872092 -1.29E-04
    25 Broy./Diag. 0.40E+00    7.6     0.00003914     -4911.5258714279  1.58E-05
    26 Broy./Diag. 0.40E+00    7.1     0.00004970     -4911.5258407898  3.06E-05
    27 Broy./Diag. 0.40E+00    7.5     0.00004682     -4911.5259372011 -9.64E-05
    28 Broy./Diag. 0.40E+00    7.3     0.00003452     -4911.5257833035  1.54E-04
    29 Broy./Diag. 0.40E+00    7.3     0.00003726     -4911.5259133998 -1.30E-04
    30 Broy./Diag. 0.40E+00    8.2     0.00002784     -4911.5258487801  6.46E-05
    31 Broy./Diag. 0.40E+00    7.3     0.00002178     -4911.5258530619 -4.28E-06
    32 Broy./Diag. 0.40E+00    6.7     0.00002400     -4911.5258802562 -2.72E-05
    33 Broy./Diag. 0.40E+00    7.3     0.00002540     -4911.5258423470  3.79E-05
    34 Broy./Diag. 0.40E+00    7.0     0.00002089     -4911.5259222411 -7.99E-05
    35 Broy./Diag. 0.40E+00    7.3     0.00002055     -4911.5258379230  8.43E-05
    36 Broy./Diag. 0.40E+00    7.1     0.00001608     -4911.5258820802 -4.42E-05
    37 Broy./Diag. 0.40E+00    7.1     0.00001164     -4911.5258837414 -1.66E-06
    38 Broy./Diag. 0.40E+00    7.3     0.00001155     -4911.5258674022  1.63E-05
    39 Broy./Diag. 0.40E+00    6.9     0.00001465     -4911.5258843149 -1.69E-05
    40 Broy./Diag. 0.40E+00    7.1     0.00001196     -4911.5258398420  4.45E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00001047     -4911.5258924550 -5.26E-05
    42 Broy./Diag. 0.40E+00    7.3     0.00000968     -4911.5258655731  2.69E-05
    43 Broy./Diag. 0.40E+00    6.8     0.00000752     -4911.5258654594  1.14E-07
    44 Broy./Diag. 0.40E+00    7.3     0.00000661     -4911.5258778747 -1.24E-05
    45 Broy./Diag. 0.40E+00    7.1     0.00000660     -4911.5258670916  1.08E-05
    46 Broy./Diag. 0.40E+00    7.1     0.00000610     -4911.5258841444 -1.71E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00000573     -4911.5258583268  2.58E-05
    48 Broy./Diag. 0.40E+00    7.3     0.00000460     -4911.5258753685 -1.70E-05
    49 Broy./Diag. 0.40E+00    7.5     0.00000386     -4911.5258738977  1.47E-06
    50 Broy./Diag. 0.40E+00    7.1     0.00000407     -4911.5258674471  6.45E-06
    51 Broy./Diag. 0.40E+00    7.3     0.00000434     -4911.5258752300 -7.78E-06
    52 Broy./Diag. 0.40E+00    7.3     0.00000352     -4911.5258644736  1.08E-05
    53 Broy./Diag. 0.40E+00    7.3     0.00000355     -4911.5258793250 -1.49E-05
    54 Broy./Diag. 0.40E+00    6.7     0.00000272     -4911.5258682432  1.11E-05
    55 Broy./Diag. 0.40E+00    7.1     0.00000214     -4911.5258701870 -1.94E-06
    56 Broy./Diag. 0.40E+00    7.1     0.00000207     -4911.5258739724 -3.79E-06
    57 Broy./Diag. 0.40E+00    7.3     0.00000201     -4911.5258693228  4.65E-06
    58 Broy./Diag. 0.40E+00    6.5     0.00000196     -4911.5258737655 -4.44E-06
    59 Broy./Diag. 0.40E+00    7.1     0.00000234     -4911.5258660262  7.74E-06
    60 Broy./Diag. 0.40E+00    7.3     0.00000172     -4911.5258740274 -8.00E-06
    61 Broy./Diag. 0.40E+00    7.1     0.00000140     -4911.5258715099  2.52E-06
    62 Broy./Diag. 0.40E+00    7.3     0.00000133     -4911.5258690602  2.45E-06
    63 Broy./Diag. 0.40E+00    7.3     0.00000126     -4911.5258724655 -3.41E-06
    64 Broy./Diag. 0.40E+00    7.1     0.00000088     -4911.5258694047  3.06E-06

  *** SCF run converged in    64 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008264628718
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.36455635153197
  Hartree energy:                                            1781.74727470515654
  Exchange-correlation energy:                               -779.30945070633220
  Electronic entropic energy:                                  -0.23790991370846
  Fermi energy:                                                 0.08639219466528

  Total energy:                                             -4911.52586940470337

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.525869946759485

 MD| ***************************************************************************
 MD| Step number                                                            1259
 MD| Time [fs]                                                       2518.000000
 MD| Conserved quantity [hartree]                            -0.491116725776E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    468.196631           588.457333
 MD| Energy drift per atom [K]           0.316258467453E+03   0.269419092543E+03
 MD| Potential energy [hartree]         -0.491152586995E+04  -0.491156183252E+04
 MD| Kinetic energy [hartree]            0.358612184055E+00   0.372023594164E+00
 MD| Temperature [K]                             955.617183           991.355438
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.01266038     -4911.5244503618 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.9     0.03247085     -4911.5611885210 -3.67E-02
     3 Broy./Diag. 0.40E+00    7.4     0.03967428     -4911.4271078425  1.34E-01
     4 Broy./Diag. 0.40E+00    6.7     0.02621334     -4911.5340572212 -1.07E-01
     5 Broy./Diag. 0.40E+00    7.3     0.01043866     -4911.5570230086 -2.30E-02
     6 Broy./Diag. 0.40E+00    7.1     0.00401096     -4911.5083500699  4.87E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00412453     -4911.5180327967 -9.68E-03
     8 Broy./Diag. 0.40E+00    7.7     0.00267252     -4911.5361265307 -1.81E-02
     9 Broy./Diag. 0.40E+00    7.1     0.00090263     -4911.5259107096  1.02E-02
    10 Broy./Diag. 0.40E+00    6.9     0.00114995     -4911.5250182685  8.92E-04
    11 Broy./Diag. 0.40E+00    6.7     0.00074250     -4911.5249754205  4.28E-05
    12 Broy./Diag. 0.40E+00    6.6     0.00029385     -4911.5262721252 -1.30E-03
    13 Broy./Diag. 0.40E+00    7.5     0.00028055     -4911.5252637334  1.01E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00027991     -4911.5248505935  4.13E-04
    15 Broy./Diag. 0.40E+00    7.0     0.00018839     -4911.5260035260 -1.15E-03
    16 Broy./Diag. 0.40E+00    7.1     0.00022051     -4911.5255957654  4.08E-04
    17 Broy./Diag. 0.40E+00    7.4     0.00020811     -4911.5257517688 -1.56E-04
    18 Broy./Diag. 0.40E+00    6.7     0.00012408     -4911.5253786920  3.73E-04
    19 Broy./Diag. 0.40E+00    6.8     0.00009926     -4911.5256282409 -2.50E-04
    20 Broy./Diag. 0.40E+00    7.3     0.00014650     -4911.5257474127 -1.19E-04
    21 Broy./Diag. 0.40E+00    7.1     0.00010484     -4911.5252333658  5.14E-04
    22 Broy./Diag. 0.40E+00    7.3     0.00008008     -4911.5256030115 -3.70E-04
    23 Broy./Diag. 0.40E+00    7.8     0.00010585     -4911.5254490420  1.54E-04
    24 Broy./Diag. 0.40E+00    7.1     0.00006843     -4911.5256668724 -2.18E-04
    25 Broy./Diag. 0.40E+00    6.5     0.00004579     -4911.5255734977  9.34E-05
    26 Broy./Diag. 0.40E+00    7.3     0.00005572     -4911.5254893508  8.41E-05
    27 Broy./Diag. 0.40E+00    6.9     0.00005052     -4911.5256568187 -1.67E-04
    28 Broy./Diag. 0.40E+00    6.9     0.00003544     -4911.5255009342  1.56E-04
    29 Broy./Diag. 0.40E+00    7.1     0.00004128     -4911.5256086960 -1.08E-04
    30 Broy./Diag. 0.40E+00    6.9     0.00003324     -4911.5255065143  1.02E-04
    31 Broy./Diag. 0.40E+00    7.3     0.00002723     -4911.5255501644 -4.37E-05
    32 Broy./Diag. 0.40E+00    8.0     0.00003144     -4911.5256152415 -6.51E-05
    33 Broy./Diag. 0.40E+00    7.3     0.00003124     -4911.5255218207  9.34E-05
    34 Broy./Diag. 0.40E+00    7.5     0.00002348     -4911.5256096211 -8.78E-05
    35 Broy./Diag. 0.40E+00    7.5     0.00002395     -4911.5255274699  8.22E-05
    36 Broy./Diag. 0.40E+00    7.1     0.00001919     -4911.5255983516 -7.09E-05
    37 Broy./Diag. 0.40E+00    7.1     0.00001395     -4911.5255772509  2.11E-05
    38 Broy./Diag. 0.40E+00    7.1     0.00001321     -4911.5255408747  3.64E-05
    39 Broy./Diag. 0.40E+00    6.9     0.00001769     -4911.5255826160 -4.17E-05
    40 Broy./Diag. 0.40E+00    7.1     0.00001470     -4911.5255362955  4.63E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00001312     -4911.5255917138 -5.54E-05
    42 Broy./Diag. 0.40E+00    7.3     0.00001251     -4911.5255449453  4.68E-05
    43 Broy./Diag. 0.40E+00    7.5     0.00000996     -4911.5255586252 -1.37E-05
    44 Broy./Diag. 0.40E+00    7.7     0.00000806     -4911.5255852244 -2.66E-05
    45 Broy./Diag. 0.40E+00    8.2     0.00000727     -4911.5255566249  2.86E-05
    46 Broy./Diag. 0.40E+00    7.2     0.00000653     -4911.5255735402 -1.69E-05
    47 Broy./Diag. 0.40E+00    7.3     0.00000635     -4911.5255501542  2.34E-05
    48 Broy./Diag. 0.40E+00    7.9     0.00000572     -4911.5255749589 -2.48E-05
    49 Broy./Diag. 0.40E+00    6.9     0.00000515     -4911.5255660328  8.93E-06
    50 Broy./Diag. 0.40E+00    7.1     0.00000532     -4911.5255531184  1.29E-05
    51 Broy./Diag. 0.40E+00    7.1     0.00000547     -4911.5255726071 -1.95E-05
    52 Broy./Diag. 0.40E+00    7.3     0.00000437     -4911.5255593091  1.33E-05
    53 Broy./Diag. 0.40E+00    7.5     0.00000415     -4911.5255742989 -1.50E-05
    54 Broy./Diag. 0.40E+00    7.1     0.00000329     -4911.5255573426  1.70E-05
    55 Broy./Diag. 0.40E+00    7.5     0.00000262     -4911.5255634475 -6.10E-06
    56 Broy./Diag. 0.40E+00    7.1     0.00000264     -4911.5255695395 -6.09E-06
    57 Broy./Diag. 0.40E+00    7.1     0.00000244     -4911.5255597050  9.83E-06
    58 Broy./Diag. 0.40E+00    7.1     0.00000243     -4911.5255656086 -5.90E-06
    59 Broy./Diag. 0.40E+00    6.7     0.00000295     -4911.5255577586  7.85E-06
    60 Broy./Diag. 0.40E+00    7.1     0.00000230     -4911.5255698858 -1.21E-05
    61 Broy./Diag. 0.40E+00    7.1     0.00000184     -4911.5255639253  5.96E-06
    62 Broy./Diag. 0.40E+00    7.1     0.00000172     -4911.5255598854  4.04E-06
    63 Broy./Diag. 0.40E+00    6.9     0.00000150     -4911.5255663664 -6.48E-06
    64 Broy./Diag. 0.40E+00    7.1     0.00000103     -4911.5255622963  4.07E-06
    65 Broy./Diag. 0.40E+00    7.5     0.00000126     -4911.5255653918 -3.10E-06
    66 Broy./Diag. 0.40E+00    7.3     0.00000121     -4911.5255602895  5.10E-06
    67 Broy./Diag. 0.40E+00    7.1     0.00000106     -4911.5255636486 -3.36E-06
    68 Broy./Diag. 0.40E+00    7.1     0.00000104     -4911.5255653804 -1.73E-06
    69 Broy./Diag. 0.40E+00    7.3     0.00000104     -4911.5255613000  4.08E-06
    70 Broy./Diag. 0.40E+00    7.1     0.00000080     -4911.5255642139 -2.91E-06

  *** SCF run converged in    70 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008261581491
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.36645514531938
  Hartree energy:                                            1781.74451624060339
  Exchange-correlation energy:                               -779.30811222187594
  Electronic entropic energy:                                  -0.23808346458334
  Fermi energy:                                                 0.08639836634233

  Total energy:                                             -4911.52556421392728

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.525562303072547

 MD| ***************************************************************************
 MD| Step number                                                            1260
 MD| Time [fs]                                                       2520.000000
 MD| Conserved quantity [hartree]                            -0.491116658469E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    511.634359           588.396362
 MD| Energy drift per atom [K]           0.317656749832E+03   0.269457376398E+03
 MD| Potential energy [hartree]         -0.491152556230E+04  -0.491156180373E+04
 MD| Kinetic energy [hartree]            0.358977611886E+00   0.372013240210E+00
 MD| Temperature [K]                             956.590962           991.327848
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.01205073     -4911.5243867798 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.9     0.01885497     -4911.5599467448 -3.56E-02
     3 Broy./Diag. 0.40E+00    7.3     0.03085169     -4911.4475812460  1.12E-01
     4 Broy./Diag. 0.40E+00    7.1     0.02263157     -4911.5316913119 -8.41E-02
     5 Broy./Diag. 0.40E+00    7.1     0.01060056     -4911.5586990858 -2.70E-02
     6 Broy./Diag. 0.40E+00    7.2     0.00413583     -4911.5008006650  5.79E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00317881     -4911.5261986073 -2.54E-02
     8 Broy./Diag. 0.40E+00    7.9     0.00214540     -4911.5281930842 -1.99E-03
     9 Broy./Diag. 0.40E+00    7.9     0.00069781     -4911.5275485222  6.45E-04
    10 Broy./Diag. 0.40E+00    9.7     0.00046223     -4911.5228442288  4.70E-03
    11 Broy./Diag. 0.40E+00    7.0     0.00041847     -4911.5255052594 -2.66E-03
    12 Broy./Diag. 0.40E+00   10.1     0.00028263     -4911.5265215685 -1.02E-03
    13 Broy./Diag. 0.40E+00    8.7     0.00016214     -4911.5247732282  1.75E-03
    14 Broy./Diag. 0.40E+00    7.3     0.00017697     -4911.5257357384 -9.63E-04
    15 Broy./Diag. 0.40E+00    6.9     0.00018232     -4911.5258302857 -9.45E-05
    16 Broy./Diag. 0.40E+00    7.1     0.00010237     -4911.5259012482 -7.10E-05
    17 Broy./Diag. 0.40E+00    7.5     0.00012680     -4911.5252161077  6.85E-04
    18 Broy./Diag. 0.40E+00    7.6     0.00011809     -4911.5252849134 -6.88E-05
    19 Broy./Diag. 0.40E+00    7.1     0.00007009     -4911.5259098344 -6.25E-04
    20 Broy./Diag. 0.40E+00    9.2     0.00005443     -4911.5254664488  4.43E-04
    21 Broy./Diag. 0.40E+00    8.4     0.00006901     -4911.5254873194 -2.09E-05
    22 Broy./Diag. 0.40E+00    7.8     0.00004751     -4911.5254720659  1.53E-05
    23 Broy./Diag. 0.40E+00    9.7     0.00003736     -4911.5257148092 -2.43E-04
    24 Broy./Diag. 0.40E+00    8.8     0.00003965     -4911.5256088691  1.06E-04
    25 Broy./Diag. 0.40E+00    6.9     0.00002469     -4911.5254124477  1.96E-04
    26 Broy./Diag. 0.40E+00    7.3     0.00001954     -4911.5255883608 -1.76E-04
    27 Broy./Diag. 0.40E+00    8.0     0.00002700     -4911.5255670276  2.13E-05
    28 Broy./Diag. 0.40E+00    7.1     0.00002154     -4911.5255697068 -2.68E-06
    29 Broy./Diag. 0.40E+00    9.7     0.00001740     -4911.5254819553  8.78E-05
    30 Broy./Diag. 0.40E+00    7.2     0.00002240     -4911.5255437214 -6.18E-05
    31 Broy./Diag. 0.40E+00    9.2     0.00001468     -4911.5256373398 -9.36E-05
    32 Broy./Diag. 0.40E+00    9.4     0.00001122     -4911.5255225315  1.15E-04
    33 Broy./Diag. 0.40E+00    7.3     0.00001283     -4911.5255387223 -1.62E-05
    34 Broy./Diag. 0.40E+00    6.7     0.00001071     -4911.5255394368 -7.14E-07
    35 Broy./Diag. 0.40E+00    7.3     0.00000719     -4911.5255780767 -3.86E-05
    36 Broy./Diag. 0.40E+00    6.9     0.00000987     -4911.5255438527  3.42E-05
    37 Broy./Diag. 0.40E+00    7.1     0.00000717     -4911.5255089186  3.49E-05
    38 Broy./Diag. 0.40E+00    6.9     0.00000577     -4911.5255632056 -5.43E-05
    39 Broy./Diag. 0.40E+00    7.5     0.00000649     -4911.5255517064  1.15E-05
    40 Broy./Diag. 0.40E+00    7.7     0.00000582     -4911.5255463587  5.35E-06
    41 Broy./Diag. 0.40E+00    7.3     0.00000431     -4911.5255256830  2.07E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00000546     -4911.5255476033 -2.19E-05
    43 Broy./Diag. 0.40E+00    7.2     0.00000392     -4911.5255605356 -1.29E-05
    44 Broy./Diag. 0.40E+00    6.9     0.00000242     -4911.5255313368  2.92E-05
    45 Broy./Diag. 0.40E+00    7.1     0.00000288     -4911.5255387823 -7.45E-06
    46 Broy./Diag. 0.40E+00    6.9     0.00000257     -4911.5255408067 -2.02E-06
    47 Broy./Diag. 0.40E+00    7.3     0.00000182     -4911.5255496098 -8.80E-06
    48 Broy./Diag. 0.40E+00    6.9     0.00000263     -4911.5255375827  1.20E-05
    49 Broy./Diag. 0.40E+00    7.3     0.00000237     -4911.5255332535  4.33E-06
    50 Broy./Diag. 0.40E+00    6.9     0.00000127     -4911.5255496410 -1.64E-05
    51 Broy./Diag. 0.40E+00    7.3     0.00000166     -4911.5255421882  7.45E-06
    52 Broy./Diag. 0.40E+00    7.3     0.00000141     -4911.5255410223  1.17E-06
    53 Broy./Diag. 0.40E+00    6.9     0.00000099     -4911.5255357847  5.24E-06

  *** SCF run converged in    53 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008257944791
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.37207533957417
  Hartree energy:                                            1781.73935876524024
  Exchange-correlation energy:                               -779.30839886035074
  Electronic entropic energy:                                  -0.23823112449818
  Fermi energy:                                                 0.08641397095197

  Total energy:                                             -4911.52553578470724

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.525538714859067

 MD| ***************************************************************************
 MD| Step number                                                            1261
 MD| Time [fs]                                                       2522.000000
 MD| Conserved quantity [hartree]                            -0.491115437216E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    411.753761           588.256281
 MD| Energy drift per atom [K]           0.343027856730E+03   0.269515719364E+03
 MD| Potential energy [hartree]         -0.491152553871E+04  -0.491156177497E+04
 MD| Kinetic energy [hartree]            0.371166556484E+00   0.372012568771E+00
 MD| Temperature [K]                             989.071634           991.326058
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.01337521     -4911.5245476688 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.02370611     -4911.5726413499 -4.81E-02
     3 Broy./Diag. 0.40E+00    8.0     0.02339067     -4911.4271634511  1.45E-01
     4 Broy./Diag. 0.40E+00    7.1     0.01370000     -4911.5439334998 -1.17E-01
     5 Broy./Diag. 0.40E+00    7.1     0.00823882     -4911.5555724845 -1.16E-02
     6 Broy./Diag. 0.40E+00    7.1     0.00503710     -4911.5008278828  5.47E-02
     7 Broy./Diag. 0.40E+00    7.3     0.00347067     -4911.5271734895 -2.63E-02
     8 Broy./Diag. 0.40E+00    7.5     0.00221867     -4911.5269248536  2.49E-04
     9 Broy./Diag. 0.40E+00    7.1     0.00121323     -4911.5293400568 -2.42E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00088487     -4911.5240720635  5.27E-03
    11 Broy./Diag. 0.40E+00    7.0     0.00054441     -4911.5241773734 -1.05E-04
    12 Broy./Diag. 0.40E+00    6.9     0.00036060     -4911.5272179412 -3.04E-03
    13 Broy./Diag. 0.40E+00    6.7     0.00026668     -4911.5254080950  1.81E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00020918     -4911.5258120128 -4.04E-04
    15 Broy./Diag. 0.40E+00    7.3     0.00019084     -4911.5257303522  8.17E-05
    16 Broy./Diag. 0.40E+00    6.9     0.00020279     -4911.5261556757 -4.25E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00013367     -4911.5261556707  5.02E-09
    18 Broy./Diag. 0.40E+00    7.3     0.00014161     -4911.5252609982  8.95E-04
    19 Broy./Diag. 0.40E+00    7.1     0.00010830     -4911.5258400143 -5.79E-04
    20 Broy./Diag. 0.40E+00    7.3     0.00009421     -4911.5257635595  7.65E-05
    21 Broy./Diag. 0.40E+00    7.5     0.00007841     -4911.5258830554 -1.19E-04
    22 Broy./Diag. 0.40E+00    7.7     0.00007902     -4911.5256933864  1.90E-04
    23 Broy./Diag. 0.40E+00    6.9     0.00005879     -4911.5256118273  8.16E-05
    24 Broy./Diag. 0.40E+00    7.1     0.00006454     -4911.5260152652 -4.03E-04
    25 Broy./Diag. 0.40E+00    7.2     0.00004972     -4911.5257272856  2.88E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00005028     -4911.5257160077  1.13E-05
    27 Broy./Diag. 0.40E+00    7.7     0.00004676     -4911.5256383556  7.77E-05
    28 Broy./Diag. 0.40E+00    7.1     0.00004854     -4911.5257681162 -1.30E-04
    29 Broy./Diag. 0.40E+00    6.9     0.00003332     -4911.5258326971 -6.46E-05
    30 Broy./Diag. 0.40E+00    7.3     0.00003088     -4911.5255945538  2.38E-04
    31 Broy./Diag. 0.40E+00    7.3     0.00002597     -4911.5257374546 -1.43E-04
    32 Broy./Diag. 0.40E+00    7.2     0.00002161     -4911.5257451925 -7.74E-06
    33 Broy./Diag. 0.40E+00    6.9     0.00002188     -4911.5257608223 -1.56E-05
    34 Broy./Diag. 0.40E+00    7.3     0.00002868     -4911.5256804672  8.04E-05
    35 Broy./Diag. 0.40E+00    7.2     0.00002141     -4911.5256414944  3.90E-05
    36 Broy./Diag. 0.40E+00    7.3     0.00002097     -4911.5257820568 -1.41E-04
    37 Broy./Diag. 0.40E+00    6.9     0.00001720     -4911.5256858378  9.62E-05
    38 Broy./Diag. 0.40E+00    6.9     0.00001187     -4911.5256844967  1.34E-06
    39 Broy./Diag. 0.40E+00    6.9     0.00001148     -4911.5256734340  1.11E-05
    40 Broy./Diag. 0.40E+00    6.9     0.00001430     -4911.5257160405 -4.26E-05
    41 Broy./Diag. 0.40E+00    7.3     0.00001022     -4911.5257282207 -1.22E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00000990     -4911.5256613483  6.69E-05
    43 Broy./Diag. 0.40E+00    7.1     0.00001073     -4911.5257093956 -4.80E-05
    44 Broy./Diag. 0.40E+00    7.9     0.00000760     -4911.5257052928  4.10E-06
    45 Broy./Diag. 0.40E+00    7.2     0.00000695     -4911.5257068204 -1.53E-06
    46 Broy./Diag. 0.40E+00    6.9     0.00000915     -4911.5256800480  2.68E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00000651     -4911.5256740147  6.03E-06
    48 Broy./Diag. 0.40E+00    7.1     0.00000524     -4911.5257126911 -3.87E-05
    49 Broy./Diag. 0.40E+00    6.8     0.00000508     -4911.5256853863  2.73E-05
    50 Broy./Diag. 0.40E+00    7.0     0.00000419     -4911.5256885416 -3.16E-06
    51 Broy./Diag. 0.40E+00    6.9     0.00000391     -4911.5256853278  3.21E-06
    52 Broy./Diag. 0.40E+00    7.3     0.00000525     -4911.5256975085 -1.22E-05
    53 Broy./Diag. 0.40E+00    7.1     0.00000437     -4911.5256977783 -2.70E-07
    54 Broy./Diag. 0.40E+00    7.1     0.00000320     -4911.5256739602  2.38E-05
    55 Broy./Diag. 0.40E+00    6.9     0.00000351     -4911.5256918925 -1.79E-05
    56 Broy./Diag. 0.40E+00    7.0     0.00000251     -4911.5256881147  3.78E-06
    57 Broy./Diag. 0.40E+00    7.1     0.00000198     -4911.5256899049 -1.79E-06
    58 Broy./Diag. 0.40E+00    7.1     0.00000262     -4911.5256831895  6.72E-06
    59 Broy./Diag. 0.40E+00    7.1     0.00000243     -4911.5256832989 -1.09E-07
    60 Broy./Diag. 0.40E+00    7.8     0.00000174     -4911.5256946271 -1.13E-05
    61 Broy./Diag. 0.40E+00    7.5     0.00000201     -4911.5256832946  1.13E-05
    62 Broy./Diag. 0.40E+00    7.7     0.00000174     -4911.5256860319 -2.74E-06
    63 Broy./Diag. 0.40E+00    7.4     0.00000144     -4911.5256840173  2.01E-06
    64 Broy./Diag. 0.40E+00    6.9     0.00000165     -4911.5256879173 -3.90E-06
    65 Broy./Diag. 0.40E+00    7.1     0.00000146     -4911.5256873447  5.73E-07
    66 Broy./Diag. 0.40E+00    7.1     0.00000089     -4911.5256811278  6.22E-06

  *** SCF run converged in    66 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008253942322
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.38187257289655
  Hartree energy:                                            1781.73164736377635
  Exchange-correlation energy:                               -779.31049294910940
  Electronic entropic energy:                                  -0.23836818197302
  Fermi energy:                                                 0.08643663673887

  Total energy:                                             -4911.52568112776044

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.525682883010631

 MD| ***************************************************************************
 MD| Step number                                                            1262
 MD| Time [fs]                                                       2524.000000
 MD| Conserved quantity [hartree]                            -0.491114669679E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    481.668505           588.171822
 MD| Energy drift per atom [K]           0.358973158395E+03   0.269586604815E+03
 MD| Potential energy [hartree]         -0.491152568288E+04  -0.491156174638E+04
 MD| Kinetic energy [hartree]            0.378986090182E+00   0.372018094541E+00
 MD| Temperature [K]                            1009.908854           991.340783
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    5.8     0.01247769     -4911.5246395353 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.01833994     -4911.5807935755 -5.62E-02
     3 Broy./Diag. 0.40E+00    7.7     0.01996310     -4911.4178097224  1.63E-01
     4 Broy./Diag. 0.40E+00    7.4     0.01240671     -4911.5769673614 -1.59E-01
     5 Broy./Diag. 0.40E+00    7.6     0.00746945     -4911.5301608569  4.68E-02
     6 Broy./Diag. 0.40E+00    6.9     0.00400682     -4911.5096907848  2.05E-02
     7 Broy./Diag. 0.40E+00    6.6     0.00274073     -4911.5275202313 -1.78E-02
     8 Broy./Diag. 0.40E+00    7.2     0.00193152     -4911.5275193087  9.23E-07
     9 Broy./Diag. 0.40E+00    7.3     0.00069944     -4911.5291929960 -1.67E-03
    10 Broy./Diag. 0.40E+00    7.3     0.00047783     -4911.5225879028  6.61E-03
    11 Broy./Diag. 0.40E+00    7.1     0.00024589     -4911.5269166135 -4.33E-03
    12 Broy./Diag. 0.40E+00    6.8     0.00025043     -4911.5267023347  2.14E-04
    13 Broy./Diag. 0.40E+00    7.3     0.00017504     -4911.5256846160  1.02E-03
    14 Broy./Diag. 0.40E+00    7.7     0.00018578     -4911.5261031880 -4.19E-04
    15 Broy./Diag. 0.40E+00    6.9     0.00015128     -4911.5260667982  3.64E-05
    16 Broy./Diag. 0.40E+00    7.1     0.00010929     -4911.5267219660 -6.55E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00007284     -4911.5255322120  1.19E-03
    18 Broy./Diag. 0.40E+00    7.3     0.00009160     -4911.5258244720 -2.92E-04
    19 Broy./Diag. 0.40E+00    7.5     0.00007477     -4911.5260879228 -2.63E-04
    20 Broy./Diag. 0.40E+00    7.3     0.00006238     -4911.5258982105  1.90E-04
    21 Broy./Diag. 0.40E+00    7.1     0.00004817     -4911.5258685629  2.96E-05
    22 Broy./Diag. 0.40E+00    7.2     0.00004244     -4911.5256690177  2.00E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00004058     -4911.5261402582 -4.71E-04
    24 Broy./Diag. 0.40E+00    7.1     0.00003920     -4911.5258873442  2.53E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00003465     -4911.5257479721  1.39E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00003243     -4911.5258433973 -9.54E-05
    27 Broy./Diag. 0.40E+00    7.5     0.00002628     -4911.5258095579  3.38E-05
    28 Broy./Diag. 0.40E+00    7.1     0.00002050     -4911.5259145617 -1.05E-04
    29 Broy./Diag. 0.40E+00    6.7     0.00001868     -4911.5257172135  1.97E-04
    30 Broy./Diag. 0.40E+00    7.3     0.00001811     -4911.5258135590 -9.63E-05
    31 Broy./Diag. 0.40E+00    7.2     0.00001678     -4911.5258634132 -4.99E-05
    32 Broy./Diag. 0.40E+00    7.0     0.00001489     -4911.5257878447  7.56E-05
    33 Broy./Diag. 0.40E+00    7.5     0.00001654     -4911.5257815309  6.31E-06
    34 Broy./Diag. 0.40E+00    6.9     0.00001601     -4911.5257232950  5.82E-05
    35 Broy./Diag. 0.40E+00    7.5     0.00001256     -4911.5258395385 -1.16E-04
    36 Broy./Diag. 0.40E+00    6.9     0.00001035     -4911.5257624019  7.71E-05
    37 Broy./Diag. 0.40E+00    6.7     0.00000756     -4911.5257366592  2.57E-05
    38 Broy./Diag. 0.40E+00    7.3     0.00000723     -4911.5257645085 -2.78E-05
    39 Broy./Diag. 0.40E+00    7.4     0.00000688     -4911.5257626700  1.84E-06
    40 Broy./Diag. 0.40E+00    7.3     0.00000682     -4911.5257798992 -1.72E-05
    41 Broy./Diag. 0.40E+00    7.4     0.00000605     -4911.5257296923  5.02E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00000713     -4911.5257665444 -3.69E-05
    43 Broy./Diag. 0.40E+00    6.9     0.00000559     -4911.5257783542 -1.18E-05
    44 Broy./Diag. 0.40E+00    7.3     0.00000461     -4911.5257464950  3.19E-05
    45 Broy./Diag. 0.40E+00    7.3     0.00000438     -4911.5257472744 -7.79E-07
    46 Broy./Diag. 0.40E+00    7.1     0.00000415     -4911.5257349986  1.23E-05
    47 Broy./Diag. 0.40E+00    7.3     0.00000261     -4911.5257628187 -2.78E-05
    48 Broy./Diag. 0.40E+00    6.9     0.00000228     -4911.5257439672  1.89E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00000234     -4911.5257408649  3.10E-06
    50 Broy./Diag. 0.40E+00    7.3     0.00000248     -4911.5257519578 -1.11E-05
    51 Broy./Diag. 0.40E+00    7.3     0.00000251     -4911.5257478009  4.16E-06
    52 Broy./Diag. 0.40E+00    7.3     0.00000275     -4911.5257488641 -1.06E-06
    53 Broy./Diag. 0.40E+00    7.5     0.00000221     -4911.5257311399  1.77E-05
    54 Broy./Diag. 0.40E+00    7.1     0.00000182     -4911.5257456796 -1.45E-05
    55 Broy./Diag. 0.40E+00    6.9     0.00000144     -4911.5257457683 -8.87E-08
    56 Broy./Diag. 0.40E+00    6.8     0.00000101     -4911.5257387566  7.01E-06
    57 Broy./Diag. 0.40E+00    7.5     0.00000103     -4911.5257396844 -9.28E-07
    58 Broy./Diag. 0.40E+00    7.4     0.00000119     -4911.5257384911  1.19E-06
    59 Broy./Diag. 0.40E+00    7.3     0.00000103     -4911.5257450368 -6.55E-06
    60 Broy./Diag. 0.40E+00    7.3     0.00000091     -4911.5257369623  8.07E-06

  *** SCF run converged in    60 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008251083903
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.40056748727784
  Hartree energy:                                            1781.71859595525166
  Exchange-correlation energy:                               -779.31607904446992
  Electronic entropic energy:                                  -0.23848136294543
  Fermi energy:                                                 0.08647212303085

  Total energy:                                             -4911.52573696232685

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.525735811912455

 MD| ***************************************************************************
 MD| Step number                                                            1263
 MD| Time [fs]                                                       2526.000000
 MD| Conserved quantity [hartree]                            -0.491115431943E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    439.382394           588.054015
 MD| Energy drift per atom [K]           0.343137393492E+03   0.269644839802E+03
 MD| Potential energy [hartree]         -0.491152573581E+04  -0.491156171786E+04
 MD| Kinetic energy [hartree]            0.371416379708E+00   0.372017618124E+00
 MD| Temperature [K]                             989.737355           991.339514
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.01296964     -4911.5246386502 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.01989290     -4911.5961096101 -7.15E-02
     3 Broy./Diag. 0.40E+00    6.9     0.02024125     -4911.4079036745  1.88E-01
     4 Broy./Diag. 0.40E+00    7.1     0.01408726     -4911.5574988393 -1.50E-01
     5 Broy./Diag. 0.40E+00    7.7     0.00908392     -4911.5559118602  1.59E-03
     6 Broy./Diag. 0.40E+00    7.3     0.00440395     -4911.5013749354  5.45E-02
     7 Broy./Diag. 0.40E+00    7.4     0.00331806     -4911.5297997263 -2.84E-02
     8 Broy./Diag. 0.40E+00    7.7     0.00236128     -4911.5264751767  3.32E-03
     9 Broy./Diag. 0.40E+00    7.1     0.00117987     -4911.5301258187 -3.65E-03
    10 Broy./Diag. 0.40E+00    7.7     0.00090558     -4911.5247111341  5.41E-03
    11 Broy./Diag. 0.40E+00    7.3     0.00062009     -4911.5254346594 -7.24E-04
    12 Broy./Diag. 0.40E+00    6.8     0.00032359     -4911.5281281712 -2.69E-03
    13 Broy./Diag. 0.40E+00    6.7     0.00026652     -4911.5259212954  2.21E-03
    14 Broy./Diag. 0.40E+00    7.5     0.00023813     -4911.5263775267 -4.56E-04
    15 Broy./Diag. 0.40E+00    7.1     0.00017978     -4911.5262737559  1.04E-04
    16 Broy./Diag. 0.40E+00    6.9     0.00020356     -4911.5267057737 -4.32E-04
    17 Broy./Diag. 0.40E+00    7.5     0.00016547     -4911.5265137722  1.92E-04
    18 Broy./Diag. 0.40E+00    7.3     0.00013208     -4911.5256674794  8.46E-04
    19 Broy./Diag. 0.40E+00    6.9     0.00010954     -4911.5263294851 -6.62E-04
    20 Broy./Diag. 0.40E+00    7.1     0.00011105     -4911.5260804019  2.49E-04
    21 Broy./Diag. 0.40E+00    7.3     0.00008548     -4911.5262086688 -1.28E-04
    22 Broy./Diag. 0.40E+00    6.9     0.00007691     -4911.5259476605  2.61E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00007149     -4911.5258998860  4.78E-05
    24 Broy./Diag. 0.40E+00    7.1     0.00006335     -4911.5263041174 -4.04E-04
    25 Broy./Diag. 0.40E+00    7.9     0.00005217     -4911.5259340781  3.70E-04
    26 Broy./Diag. 0.40E+00    7.5     0.00005899     -4911.5259421981 -8.12E-06
    27 Broy./Diag. 0.40E+00    7.3     0.00005313     -4911.5258355750  1.07E-04
    28 Broy./Diag. 0.40E+00    6.9     0.00004760     -4911.5259614060 -1.26E-04
    29 Broy./Diag. 0.40E+00    7.0     0.00003757     -4911.5260071692 -4.58E-05
    30 Broy./Diag. 0.40E+00    7.2     0.00002771     -4911.5257616477  2.46E-04
    31 Broy./Diag. 0.40E+00    7.1     0.00002706     -4911.5259029235 -1.41E-04
    32 Broy./Diag. 0.40E+00    7.0     0.00002753     -4911.5258906495  1.23E-05
    33 Broy./Diag. 0.40E+00    7.3     0.00002782     -4911.5259119234 -2.13E-05
    34 Broy./Diag. 0.40E+00    7.1     0.00002716     -4911.5258110218  1.01E-04
    35 Broy./Diag. 0.40E+00    6.9     0.00002382     -4911.5257744832  3.65E-05
    36 Broy./Diag. 0.40E+00    7.1     0.00001846     -4911.5259031392 -1.29E-04
    37 Broy./Diag. 0.40E+00    7.1     0.00001730     -4911.5258008584  1.02E-04
    38 Broy./Diag. 0.40E+00    6.9     0.00001393     -4911.5258043030 -3.44E-06
    39 Broy./Diag. 0.40E+00    7.2     0.00001476     -4911.5257714298  3.29E-05
    40 Broy./Diag. 0.40E+00    7.1     0.00001582     -4911.5258244142 -5.30E-05
    41 Broy./Diag. 0.40E+00    7.4     0.00001265     -4911.5258386465 -1.42E-05
    42 Broy./Diag. 0.40E+00    7.8     0.00000949     -4911.5257588612  7.98E-05
    43 Broy./Diag. 0.40E+00    6.8     0.00001141     -4911.5258038465 -4.50E-05
    44 Broy./Diag. 0.40E+00    6.9     0.00000949     -4911.5257894520  1.44E-05
    45 Broy./Diag. 0.40E+00    6.9     0.00000906     -4911.5258035018 -1.40E-05
    46 Broy./Diag. 0.40E+00    7.3     0.00000853     -4911.5257673054  3.62E-05
    47 Broy./Diag. 0.40E+00    6.7     0.00000706     -4911.5257568738  1.04E-05
    48 Broy./Diag. 0.40E+00    6.9     0.00000534     -4911.5257953362 -3.85E-05
    49 Broy./Diag. 0.40E+00    6.8     0.00000577     -4911.5257681821  2.72E-05
    50 Broy./Diag. 0.40E+00    7.3     0.00000523     -4911.5257711425 -2.96E-06
    51 Broy./Diag. 0.40E+00    7.3     0.00000539     -4911.5257564994  1.46E-05
    52 Broy./Diag. 0.40E+00    7.2     0.00000585     -4911.5257745349 -1.80E-05
    53 Broy./Diag. 0.40E+00    7.1     0.00000488     -4911.5257772496 -2.71E-06
    54 Broy./Diag. 0.40E+00    7.3     0.00000326     -4911.5257504351  2.68E-05
    55 Broy./Diag. 0.40E+00    7.5     0.00000355     -4911.5257630907 -1.27E-05
    56 Broy./Diag. 0.40E+00    7.1     0.00000323     -4911.5257574049  5.69E-06
    57 Broy./Diag. 0.40E+00    7.5     0.00000289     -4911.5257661946 -8.79E-06
    58 Broy./Diag. 0.40E+00    6.6     0.00000284     -4911.5257533285  1.29E-05
    59 Broy./Diag. 0.40E+00    7.3     0.00000297     -4911.5257513259  2.00E-06
    60 Broy./Diag. 0.40E+00    7.7     0.00000231     -4911.5257654056 -1.41E-05
    61 Broy./Diag. 0.40E+00    7.1     0.00000234     -4911.5257535841  1.18E-05
    62 Broy./Diag. 0.40E+00    6.7     0.00000216     -4911.5257559148 -2.33E-06
    63 Broy./Diag. 0.40E+00    7.3     0.00000191     -4911.5257482424  7.67E-06
    64 Broy./Diag. 0.40E+00    6.8     0.00000182     -4911.5257551852 -6.94E-06
    65 Broy./Diag. 0.40E+00    6.4     0.00000159     -4911.5257556037 -4.18E-07
    66 Broy./Diag. 0.40E+00    7.5     0.00000114     -4911.5257477863  7.82E-06
    67 Broy./Diag. 0.40E+00    7.1     0.00000132     -4911.5257521577 -4.37E-06
    68 Broy./Diag. 0.40E+00    7.3     0.00000134     -4911.5257498104  2.35E-06
    69 Broy./Diag. 0.40E+00    7.3     0.00000125     -4911.5257532815 -3.47E-06
    70 Broy./Diag. 0.40E+00    7.3     0.00000115     -4911.5257476324  5.65E-06
    71 Broy./Diag. 0.40E+00    6.9     0.00000114     -4911.5257473345  2.98E-07
    72 Broy./Diag. 0.40E+00    7.2     0.00000083     -4911.5257517926 -4.46E-06

  *** SCF run converged in    72 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008249487920
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.42791286850115
  Hartree energy:                                            1781.70037609057317
  Exchange-correlation energy:                               -779.32515801636305
  Electronic entropic energy:                                  -0.23854269637538
  Fermi energy:                                                 0.08651848858686

  Total energy:                                             -4911.52575179260111

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.525744667007530

 MD| ***************************************************************************
 MD| Step number                                                            1264
 MD| Time [fs]                                                       2528.000000
 MD| Conserved quantity [hartree]                            -0.491115002420E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    524.936523           588.004081
 MD| Energy drift per atom [K]           0.352060596400E+03   0.269710042141E+03
 MD| Potential energy [hartree]         -0.491152574467E+04  -0.491156168940E+04
 MD| Kinetic energy [hartree]            0.375720471457E+00   0.372020547597E+00
 MD| Temperature [K]                            1001.206748           991.347320
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.6     0.01416164     -4911.5248710385 -4.91E+03
     2 Broy./Diag. 0.40E+00    9.7     0.01922027     -4911.6029012322 -7.80E-02
     3 Broy./Diag. 0.40E+00    7.4     0.02014165     -4911.3953537937  2.08E-01
     4 Broy./Diag. 0.40E+00    9.4     0.01403455     -4911.5575475115 -1.62E-01
     5 Broy./Diag. 0.40E+00    8.7     0.01099801     -4911.5639796099 -6.43E-03
     6 Broy./Diag. 0.40E+00    6.9     0.00644968     -4911.5013848873  6.26E-02
     7 Broy./Diag. 0.40E+00    6.9     0.00356640     -4911.5269475895 -2.56E-02
     8 Broy./Diag. 0.40E+00    6.9     0.00237489     -4911.5297546647 -2.81E-03
     9 Broy./Diag. 0.40E+00    7.1     0.00160013     -4911.5283882337  1.37E-03
    10 Broy./Diag. 0.40E+00    7.4     0.00083494     -4911.5253950071  2.99E-03
    11 Broy./Diag. 0.40E+00    7.1     0.00094088     -4911.5255476916 -1.53E-04
    12 Broy./Diag. 0.40E+00    7.1     0.00055551     -4911.5288071267 -3.26E-03
    13 Broy./Diag. 0.40E+00   10.2     0.00034677     -4911.5260899721  2.72E-03
    14 Broy./Diag. 0.40E+00    7.4     0.00026711     -4911.5262146014 -1.25E-04
    15 Broy./Diag. 0.40E+00    8.1     0.00023776     -4911.5266280000 -4.13E-04
    16 Broy./Diag. 0.40E+00   10.2     0.00019723     -4911.5267079822 -8.00E-05
    17 Broy./Diag. 0.40E+00    6.9     0.00019975     -4911.5267723578 -6.44E-05
    18 Broy./Diag. 0.40E+00    6.9     0.00020653     -4911.5258010239  9.71E-04
    19 Broy./Diag. 0.40E+00    8.6     0.00014334     -4911.5265581222 -7.57E-04
    20 Broy./Diag. 0.40E+00    7.1     0.00012298     -4911.5263828914  1.75E-04
    21 Broy./Diag. 0.40E+00    9.5     0.00012160     -4911.5262908698  9.20E-05
    22 Broy./Diag. 0.40E+00    7.8     0.00008249     -4911.5262500933  4.08E-05
    23 Broy./Diag. 0.40E+00    8.1     0.00007534     -4911.5260670855  1.83E-04
    24 Broy./Diag. 0.40E+00   10.4     0.00009694     -4911.5265281144 -4.61E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00006508     -4911.5261699968  3.58E-04
    26 Broy./Diag. 0.40E+00    7.3     0.00005825     -4911.5261518856  1.81E-05
    27 Broy./Diag. 0.40E+00    6.9     0.00006785     -4911.5261497695  2.12E-06
    28 Broy./Diag. 0.40E+00    6.9     0.00005002     -4911.5261457355  4.03E-06
    29 Broy./Diag. 0.40E+00    7.1     0.00003568     -4911.5262847091 -1.39E-04
    30 Broy./Diag. 0.40E+00    7.3     0.00004438     -4911.5259972784  2.87E-04
    31 Broy./Diag. 0.40E+00    7.5     0.00003423     -4911.5261418524 -1.45E-04
    32 Broy./Diag. 0.40E+00    7.5     0.00002498     -4911.5261477350 -5.88E-06
    33 Broy./Diag. 0.40E+00    7.9     0.00003367     -4911.5261434411  4.29E-06
    34 Broy./Diag. 0.40E+00    7.1     0.00002737     -4911.5261067241  3.67E-05
    35 Broy./Diag. 0.40E+00    7.3     0.00001861     -4911.5260161764  9.05E-05
    36 Broy./Diag. 0.40E+00    6.9     0.00002808     -4911.5261649300 -1.49E-04
    37 Broy./Diag. 0.40E+00    7.5     0.00002264     -4911.5260691794  9.58E-05
    38 Broy./Diag. 0.40E+00    7.1     0.00001345     -4911.5260633881  5.79E-06
    39 Broy./Diag. 0.40E+00    6.9     0.00001846     -4911.5260460053  1.74E-05
    40 Broy./Diag. 0.40E+00    7.7     0.00001708     -4911.5260662789 -2.03E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00001045     -4911.5261194903 -5.32E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00001395     -4911.5260243565  9.51E-05
    43 Broy./Diag. 0.40E+00    7.1     0.00001419     -4911.5260655117 -4.12E-05
    44 Broy./Diag. 0.40E+00    7.5     0.00000908     -4911.5260605946  4.92E-06
    45 Broy./Diag. 0.40E+00    6.7     0.00001095     -4911.5260648087 -4.21E-06
    46 Broy./Diag. 0.40E+00    6.9     0.00000953     -4911.5260507392  1.41E-05
    47 Broy./Diag. 0.40E+00    7.3     0.00000587     -4911.5260195555  3.12E-05
    48 Broy./Diag. 0.40E+00    7.3     0.00000801     -4911.5260686682 -4.91E-05
    49 Broy./Diag. 0.40E+00    7.9     0.00000748     -4911.5260422040  2.65E-05
    50 Broy./Diag. 0.40E+00    7.3     0.00000512     -4911.5260426986 -4.95E-07
    51 Broy./Diag. 0.40E+00    7.3     0.00000620     -4911.5260333253  9.37E-06
    52 Broy./Diag. 0.40E+00    7.3     0.00000635     -4911.5260389808 -5.66E-06
    53 Broy./Diag. 0.40E+00    7.3     0.00000392     -4911.5260557185 -1.67E-05
    54 Broy./Diag. 0.40E+00    7.1     0.00000447     -4911.5260234236  3.23E-05
    55 Broy./Diag. 0.40E+00    7.5     0.00000453     -4911.5260361709 -1.27E-05
    56 Broy./Diag. 0.40E+00    7.1     0.00000329     -4911.5260324187  3.75E-06
    57 Broy./Diag. 0.40E+00    7.1     0.00000337     -4911.5260381432 -5.72E-06
    58 Broy./Diag. 0.40E+00    7.5     0.00000335     -4911.5260325963  5.55E-06
    59 Broy./Diag. 0.40E+00    7.3     0.00000239     -4911.5260232481  9.35E-06
    60 Broy./Diag. 0.40E+00    7.3     0.00000304     -4911.5260408016 -1.76E-05
    61 Broy./Diag. 0.40E+00    6.9     0.00000288     -4911.5260295585  1.12E-05
    62 Broy./Diag. 0.40E+00    7.1     0.00000215     -4911.5260306987 -1.14E-06
    63 Broy./Diag. 0.40E+00    6.7     0.00000205     -4911.5260254179  5.28E-06
    64 Broy./Diag. 0.40E+00    7.1     0.00000216     -4911.5260278573 -2.44E-06
    65 Broy./Diag. 0.40E+00    6.8     0.00000137     -4911.5260333275 -5.47E-06
    66 Broy./Diag. 0.40E+00    7.5     0.00000146     -4911.5260233005  1.00E-05
    67 Broy./Diag. 0.40E+00    6.9     0.00000167     -4911.5260279766 -4.68E-06
    68 Broy./Diag. 0.40E+00    7.1     0.00000135     -4911.5260262687  1.71E-06
    69 Broy./Diag. 0.40E+00    6.7     0.00000126     -4911.5260286410 -2.37E-06
    70 Broy./Diag. 0.40E+00    7.4     0.00000137     -4911.5260260054  2.64E-06
    71 Broy./Diag. 0.40E+00    7.0     0.00000094     -4911.5260225561  3.45E-06

  *** SCF run converged in    71 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008248053308
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.45599697760281
  Hartree energy:                                            1781.68173953193150
  Exchange-correlation energy:                               -779.33481851837132
  Electronic entropic energy:                                  -0.23860055629298
  Fermi energy:                                                 0.08656271562807

  Total energy:                                             -4911.52602255606962

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.526021872033198

 MD| ***************************************************************************
 MD| Step number                                                            1265
 MD| Time [fs]                                                       2530.000000
 MD| Conserved quantity [hartree]                            -0.491114562753E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    540.122972           587.966230
 MD| Energy drift per atom [K]           0.361194509447E+03   0.269782361878E+03
 MD| Potential energy [hartree]         -0.491152602187E+04  -0.491156166121E+04
 MD| Kinetic energy [hartree]            0.380394339712E+00   0.372027167195E+00
 MD| Temperature [K]                            1013.661508           991.364960
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.01609056     -4911.5254415794 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.9     0.02028751     -4911.5928736478 -6.74E-02
     3 Broy./Diag. 0.40E+00    7.0     0.02399852     -4911.4080948648  1.85E-01
     4 Broy./Diag. 0.40E+00    7.1     0.01630107     -4911.5825234860 -1.74E-01
     5 Broy./Diag. 0.40E+00    7.7     0.01302312     -4911.5490950377  3.34E-02
     6 Broy./Diag. 0.40E+00    7.3     0.00669950     -4911.4997198075  4.94E-02
     7 Broy./Diag. 0.40E+00    7.2     0.00280934     -4911.5269516890 -2.72E-02
     8 Broy./Diag. 0.40E+00    7.2     0.00185286     -4911.5309016671 -3.95E-03
     9 Broy./Diag. 0.40E+00    7.3     0.00128618     -4911.5271537349  3.75E-03
    10 Broy./Diag. 0.40E+00    7.3     0.00061676     -4911.5260231195  1.13E-03
    11 Broy./Diag. 0.40E+00    6.9     0.00078279     -4911.5273010307 -1.28E-03
    12 Broy./Diag. 0.40E+00    6.8     0.00054236     -4911.5283852633 -1.08E-03
    13 Broy./Diag. 0.40E+00    7.3     0.00026592     -4911.5262075181  2.18E-03
    14 Broy./Diag. 0.40E+00    7.4     0.00022240     -4911.5266054813 -3.98E-04
    15 Broy./Diag. 0.40E+00    6.9     0.00027179     -4911.5273791541 -7.74E-04
    16 Broy./Diag. 0.40E+00    7.5     0.00020045     -4911.5270526466  3.27E-04
    17 Broy./Diag. 0.40E+00    7.1     0.00022347     -4911.5269899220  6.27E-05
    18 Broy./Diag. 0.40E+00    7.1     0.00023456     -4911.5264118182  5.78E-04
    19 Broy./Diag. 0.40E+00    7.1     0.00012979     -4911.5270941465 -6.82E-04
    20 Broy./Diag. 0.40E+00    6.9     0.00010456     -4911.5269245816  1.70E-04
    21 Broy./Diag. 0.40E+00    7.6     0.00010307     -4911.5266304095  2.94E-04
    22 Broy./Diag. 0.40E+00    6.7     0.00007909     -4911.5267580869 -1.28E-04
    23 Broy./Diag. 0.40E+00    7.7     0.00008290     -4911.5266850552  7.30E-05
    24 Broy./Diag. 0.40E+00    7.1     0.00009638     -4911.5270087594 -3.24E-04
    25 Broy./Diag. 0.40E+00    7.3     0.00006129     -4911.5266762420  3.33E-04
    26 Broy./Diag. 0.40E+00    6.9     0.00004633     -4911.5266854745 -9.23E-06
    27 Broy./Diag. 0.40E+00    7.1     0.00005605     -4911.5267941672 -1.09E-04
    28 Broy./Diag. 0.40E+00    7.0     0.00004655     -4911.5267289150  6.53E-05
    29 Broy./Diag. 0.40E+00    7.3     0.00003705     -4911.5268019138 -7.30E-05
    30 Broy./Diag. 0.40E+00    6.9     0.00004439     -4911.5265906416  2.11E-04
    31 Broy./Diag. 0.40E+00    7.3     0.00003377     -4911.5267537322 -1.63E-04
    32 Broy./Diag. 0.40E+00    7.3     0.00002071     -4911.5267632049 -9.47E-06
    33 Broy./Diag. 0.40E+00    7.3     0.00002853     -4911.5267034910  5.97E-05
    34 Broy./Diag. 0.40E+00    7.3     0.00002785     -4911.5267090433 -5.55E-06
    35 Broy./Diag. 0.40E+00    8.0     0.00001999     -4911.5266494842  5.96E-05
    36 Broy./Diag. 0.40E+00    7.3     0.00002752     -4911.5267767579 -1.27E-04
    37 Broy./Diag. 0.40E+00    7.1     0.00002049     -4911.5266767149  1.00E-04
    38 Broy./Diag. 0.40E+00    6.8     0.00000973     -4911.5266687831  7.93E-06
    39 Broy./Diag. 0.40E+00    6.8     0.00001549     -4911.5266898852 -2.11E-05
    40 Broy./Diag. 0.40E+00    7.5     0.00001584     -4911.5266918403 -1.96E-06
    41 Broy./Diag. 0.40E+00    6.8     0.00000945     -4911.5267198475 -2.80E-05
    42 Broy./Diag. 0.40E+00    7.3     0.00001408     -4911.5266466254  7.32E-05
    43 Broy./Diag. 0.40E+00    7.3     0.00001268     -4911.5266960281 -4.94E-05
    44 Broy./Diag. 0.40E+00    7.7     0.00000624     -4911.5266971693 -1.14E-06
    45 Broy./Diag. 0.40E+00    7.3     0.00000764     -4911.5266855919  1.16E-05
    46 Broy./Diag. 0.40E+00    7.3     0.00000837     -4911.5266790241  6.57E-06
    47 Broy./Diag. 0.40E+00    7.5     0.00000507     -4911.5266636615  1.54E-05
    48 Broy./Diag. 0.40E+00    7.0     0.00000767     -4911.5267038599 -4.02E-05
    49 Broy./Diag. 0.40E+00    7.5     0.00000676     -4911.5266754904  2.84E-05
    50 Broy./Diag. 0.40E+00    7.1     0.00000383     -4911.5266747532  7.37E-07
    51 Broy./Diag. 0.40E+00    7.2     0.00000467     -4911.5266771951 -2.44E-06
    52 Broy./Diag. 0.40E+00    7.4     0.00000551     -4911.5266804541 -3.26E-06
    53 Broy./Diag. 0.40E+00    7.3     0.00000334     -4911.5266892229 -8.77E-06
    54 Broy./Diag. 0.40E+00    6.8     0.00000410     -4911.5266628669  2.64E-05
    55 Broy./Diag. 0.40E+00    7.2     0.00000397     -4911.5266782329 -1.54E-05
    56 Broy./Diag. 0.40E+00    6.6     0.00000222     -4911.5266780014  2.31E-07
    57 Broy./Diag. 0.40E+00    7.1     0.00000217     -4911.5266773060  6.95E-07
    58 Broy./Diag. 0.40E+00    7.1     0.00000293     -4911.5266736036  3.70E-06
    59 Broy./Diag. 0.40E+00    7.5     0.00000222     -4911.5266687304  4.87E-06
    60 Broy./Diag. 0.40E+00    7.4     0.00000267     -4911.5266842969 -1.56E-05
    61 Broy./Diag. 0.40E+00    7.6     0.00000247     -4911.5266727879  1.15E-05
    62 Broy./Diag. 0.40E+00    7.1     0.00000144     -4911.5266729910 -2.03E-07
    63 Broy./Diag. 0.40E+00    7.3     0.00000133     -4911.5266724755  5.16E-07
    64 Broy./Diag. 0.40E+00    6.5     0.00000162     -4911.5266744382 -1.96E-06
    65 Broy./Diag. 0.40E+00    7.0     0.00000119     -4911.5266767933 -2.36E-06
    66 Broy./Diag. 0.40E+00    7.3     0.00000130     -4911.5266688735  7.92E-06
    67 Broy./Diag. 0.40E+00    7.3     0.00000152     -4911.5266745598 -5.69E-06
    68 Broy./Diag. 0.40E+00    7.5     0.00000100     -4911.5266740201  5.40E-07

  *** SCF run converged in    68 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008246343325
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.48045120508823
  Hartree energy:                                            1781.66520929003195
  Exchange-correlation energy:                               -779.34331573812710
  Electronic entropic energy:                                  -0.23867873180939
  Fermi energy:                                                 0.08659983547381

  Total energy:                                             -4911.52667402013776

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.526671272029489

 MD| ***************************************************************************
 MD| Step number                                                            1266
 MD| Time [fs]                                                       2532.000000
 MD| Conserved quantity [hartree]                            -0.491114870628E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    497.655427           587.894894
 MD| Energy drift per atom [K]           0.354798529648E+03   0.269849515249E+03
 MD| Potential energy [hartree]         -0.491152667127E+04  -0.491156163357E+04
 MD| Kinetic energy [hartree]            0.377964996889E+00   0.372031857424E+00
 MD| Temperature [K]                            1007.187880           991.377458
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.01799498     -4911.5263729333 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.02576203     -4911.5825520098 -5.62E-02
     3 Broy./Diag. 0.40E+00    6.9     0.03114209     -4911.4285214512  1.54E-01
     4 Broy./Diag. 0.40E+00    7.1     0.01590167     -4911.5739836085 -1.45E-01
     5 Broy./Diag. 0.40E+00    7.1     0.00624416     -4911.5380238968  3.60E-02
     6 Broy./Diag. 0.40E+00    7.5     0.00618386     -4911.4968136116  4.12E-02
     7 Broy./Diag. 0.40E+00    6.8     0.00405391     -4911.5328922202 -3.61E-02
     8 Broy./Diag. 0.40E+00    7.3     0.00251138     -4911.5287121521  4.18E-03
     9 Broy./Diag. 0.40E+00    7.1     0.00134047     -4911.5301219214 -1.41E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00067219     -4911.5265534731  3.57E-03
    11 Broy./Diag. 0.40E+00    7.6     0.00051873     -4911.5280285955 -1.48E-03
    12 Broy./Diag. 0.40E+00    6.9     0.00042368     -4911.5291811885 -1.15E-03
    13 Broy./Diag. 0.40E+00    6.9     0.00038201     -4911.5266699185  2.51E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00031190     -4911.5279782831 -1.31E-03
    15 Broy./Diag. 0.40E+00    7.3     0.00029693     -4911.5280798018 -1.02E-04
    16 Broy./Diag. 0.40E+00    7.1     0.00023932     -4911.5282961722 -2.16E-04
    17 Broy./Diag. 0.40E+00    7.3     0.00018323     -4911.5279374304  3.59E-04
    18 Broy./Diag. 0.40E+00    6.9     0.00016608     -4911.5273030411  6.34E-04
    19 Broy./Diag. 0.40E+00    6.9     0.00016496     -4911.5282092064 -9.06E-04
    20 Broy./Diag. 0.40E+00    7.4     0.00013826     -4911.5276704997  5.39E-04
    21 Broy./Diag. 0.40E+00    7.0     0.00010252     -4911.5277305885 -6.01E-05
    22 Broy./Diag. 0.40E+00    7.5     0.00008735     -4911.5276719452  5.86E-05
    23 Broy./Diag. 0.40E+00    7.3     0.00006866     -4911.5276923973 -2.05E-05
    24 Broy./Diag. 0.40E+00    7.3     0.00006609     -4911.5280345273 -3.42E-04
    25 Broy./Diag. 0.40E+00    7.3     0.00007460     -4911.5275991135  4.35E-04
    26 Broy./Diag. 0.40E+00    8.1     0.00007241     -4911.5277990538 -2.00E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00005617     -4911.5277166352  8.24E-05
    28 Broy./Diag. 0.40E+00    6.8     0.00005125     -4911.5277652232 -4.86E-05
    29 Broy./Diag. 0.40E+00    7.1     0.00002816     -4911.5277973217 -3.21E-05
    30 Broy./Diag. 0.40E+00    7.3     0.00002764     -4911.5276066554  1.91E-04
    31 Broy./Diag. 0.40E+00    6.9     0.00003833     -4911.5278037018 -1.97E-04
    32 Broy./Diag. 0.40E+00    7.1     0.00003519     -4911.5277109696  9.27E-05
    33 Broy./Diag. 0.40E+00    7.3     0.00002877     -4911.5277497896 -3.88E-05
    34 Broy./Diag. 0.40E+00    6.9     0.00003332     -4911.5276960819  5.37E-05
    35 Broy./Diag. 0.40E+00    6.7     0.00001977     -4911.5276599626  3.61E-05
    36 Broy./Diag. 0.40E+00    7.3     0.00001705     -4911.5277852823 -1.25E-04
    37 Broy./Diag. 0.40E+00    7.3     0.00001867     -4911.5276648598  1.20E-04
    38 Broy./Diag. 0.40E+00    7.0     0.00001639     -4911.5277038463 -3.90E-05
    39 Broy./Diag. 0.40E+00    7.1     0.00001437     -4911.5276814746  2.24E-05
    40 Broy./Diag. 0.40E+00    6.9     0.00001760     -4911.5277149869 -3.35E-05
    41 Broy./Diag. 0.40E+00    7.3     0.00000971     -4911.5277289184 -1.39E-05
    42 Broy./Diag. 0.40E+00    7.8     0.00000881     -4911.5276628699  6.60E-05
    43 Broy./Diag. 0.40E+00    6.9     0.00001205     -4911.5277216768 -5.88E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00001050     -4911.5276957222  2.60E-05
    45 Broy./Diag. 0.40E+00    7.5     0.00000797     -4911.5277126982 -1.70E-05
    46 Broy./Diag. 0.40E+00    7.5     0.00000936     -4911.5276881994  2.45E-05
    47 Broy./Diag. 0.40E+00    7.2     0.00000550     -4911.5276822828  5.92E-06
    48 Broy./Diag. 0.40E+00    7.8     0.00000424     -4911.5277190516 -3.68E-05
    49 Broy./Diag. 0.40E+00    7.3     0.00000565     -4911.5276893062  2.97E-05
    50 Broy./Diag. 0.40E+00    7.5     0.00000615     -4911.5276987755 -9.47E-06
    51 Broy./Diag. 0.40E+00    6.9     0.00000529     -4911.5276861939  1.26E-05
    52 Broy./Diag. 0.40E+00    7.0     0.00000625     -4911.5277031890 -1.70E-05
    53 Broy./Diag. 0.40E+00    7.0     0.00000393     -4911.5277056596 -2.47E-06
    54 Broy./Diag. 0.40E+00    7.4     0.00000296     -4911.5276810461  2.46E-05
    55 Broy./Diag. 0.40E+00    7.5     0.00000332     -4911.5276976099 -1.66E-05
    56 Broy./Diag. 0.40E+00    6.9     0.00000327     -4911.5276922469  5.36E-06
    57 Broy./Diag. 0.40E+00    6.9     0.00000255     -4911.5276992160 -6.97E-06
    58 Broy./Diag. 0.40E+00    7.9     0.00000311     -4911.5276895141  9.70E-06
    59 Broy./Diag. 0.40E+00    6.7     0.00000251     -4911.5276890144  5.00E-07
    60 Broy./Diag. 0.40E+00    7.1     0.00000218     -4911.5277030285 -1.40E-05
    61 Broy./Diag. 0.40E+00    7.3     0.00000198     -4911.5276913554  1.17E-05
    62 Broy./Diag. 0.40E+00    7.1     0.00000209     -4911.5276944021 -3.05E-06
    63 Broy./Diag. 0.40E+00    7.3     0.00000165     -4911.5276895954  4.81E-06
    64 Broy./Diag. 0.40E+00    7.4     0.00000169     -4911.5276957697 -6.17E-06
    65 Broy./Diag. 0.40E+00    7.1     0.00000132     -4911.5276957281  4.16E-08
    66 Broy./Diag. 0.40E+00    6.8     0.00000115     -4911.5276893188  6.41E-06
    67 Broy./Diag. 0.40E+00    7.1     0.00000118     -4911.5276949915 -5.67E-06
    68 Broy./Diag. 0.40E+00    7.3     0.00000126     -4911.5276928047  2.19E-06
    69 Broy./Diag. 0.40E+00    6.9     0.00000107     -4911.5276951813 -2.38E-06
    70 Broy./Diag. 0.40E+00    6.7     0.00000110     -4911.5276910546  4.13E-06
    71 Broy./Diag. 0.40E+00    7.3     0.00000094     -4911.5276914122 -3.58E-07

  *** SCF run converged in    71 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008244823787
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.50392279700600
  Hartree energy:                                            1781.64903321063275
  Exchange-correlation energy:                               -779.35160084038910
  Electronic entropic energy:                                  -0.23870654361004
  Fermi energy:                                                 0.08663699678073

  Total energy:                                             -4911.52769141216322

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.527692471295268

 MD| ***************************************************************************
 MD| Step number                                                            1267
 MD| Time [fs]                                                       2534.000000
 MD| Conserved quantity [hartree]                            -0.491116386797E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    517.724011           587.839511
 MD| Energy drift per atom [K]           0.323300648932E+03   0.269891702411E+03
 MD| Potential energy [hartree]         -0.491152769247E+04  -0.491156160678E+04
 MD| Kinetic energy [hartree]            0.363824504421E+00   0.372025379639E+00
 MD| Temperature [K]                             969.506791           991.360196
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02008846     -4911.5274397197 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.5     0.02456915     -4911.5796949394 -5.23E-02
     3 Broy./Diag. 0.40E+00    7.3     0.03182178     -4911.4324462020  1.47E-01
     4 Broy./Diag. 0.40E+00    7.3     0.01700109     -4911.5927737199 -1.60E-01
     5 Broy./Diag. 0.40E+00    6.9     0.00975194     -4911.5300531257  6.27E-02
     6 Broy./Diag. 0.40E+00    6.9     0.00785050     -4911.5139665696  1.61E-02
     7 Broy./Diag. 0.40E+00    6.8     0.00353907     -4911.5296532766 -1.57E-02
     8 Broy./Diag. 0.40E+00    7.3     0.00211394     -4911.5291664738  4.87E-04
     9 Broy./Diag. 0.40E+00    7.3     0.00150044     -4911.5358129592 -6.65E-03
    10 Broy./Diag. 0.40E+00    7.3     0.00076386     -4911.5252508111  1.06E-02
    11 Broy./Diag. 0.40E+00    7.1     0.00069310     -4911.5298926318 -4.64E-03
    12 Broy./Diag. 0.40E+00    7.1     0.00062888     -4911.5302363762 -3.44E-04
    13 Broy./Diag. 0.40E+00    7.3     0.00038354     -4911.5289979439  1.24E-03
    14 Broy./Diag. 0.40E+00    7.5     0.00030346     -4911.5291715166 -1.74E-04
    15 Broy./Diag. 0.40E+00    6.8     0.00037292     -4911.5284948273  6.77E-04
    16 Broy./Diag. 0.40E+00    7.1     0.00023407     -4911.5304109000 -1.92E-03
    17 Broy./Diag. 0.40E+00    7.5     0.00022052     -4911.5287322823  1.68E-03
    18 Broy./Diag. 0.40E+00    7.7     0.00030381     -4911.5286079036  1.24E-04
    19 Broy./Diag. 0.40E+00    7.3     0.00021136     -4911.5291625248 -5.55E-04
    20 Broy./Diag. 0.40E+00    7.3     0.00013352     -4911.5290357128  1.27E-04
    21 Broy./Diag. 0.40E+00    7.1     0.00014503     -4911.5293431273 -3.07E-04
    22 Broy./Diag. 0.40E+00    7.1     0.00008235     -4911.5286158020  7.27E-04
    23 Broy./Diag. 0.40E+00    6.9     0.00007520     -4911.5290936809 -4.78E-04
    24 Broy./Diag. 0.40E+00    7.2     0.00011716     -4911.5291641763 -7.05E-05
    25 Broy./Diag. 0.40E+00    7.1     0.00009740     -4911.5288969528  2.67E-04
    26 Broy./Diag. 0.40E+00    7.2     0.00007755     -4911.5289048317 -7.88E-06
    27 Broy./Diag. 0.40E+00    7.2     0.00009562     -4911.5287201967  1.85E-04
    28 Broy./Diag. 0.40E+00    7.3     0.00005974     -4911.5291774265 -4.57E-04
    29 Broy./Diag. 0.40E+00    6.9     0.00003832     -4911.5288833624  2.94E-04
    30 Broy./Diag. 0.40E+00    6.8     0.00004995     -4911.5288152992  6.81E-05
    31 Broy./Diag. 0.40E+00    7.1     0.00004528     -4911.5289358264 -1.21E-04
    32 Broy./Diag. 0.40E+00    7.5     0.00003059     -4911.5289375070 -1.68E-06
    33 Broy./Diag. 0.40E+00    6.6     0.00004168     -4911.5289704763 -3.30E-05
    34 Broy./Diag. 0.40E+00    7.9     0.00003578     -4911.5287538738  2.17E-04
    35 Broy./Diag. 0.40E+00    7.7     0.00002404     -4911.5288959320 -1.42E-04
    36 Broy./Diag. 0.40E+00    9.7     0.00003262     -4911.5289473479 -5.14E-05
    37 Broy./Diag. 0.40E+00    7.9     0.00002831     -4911.5288654954  8.19E-05
    38 Broy./Diag. 0.40E+00    8.5     0.00001734     -4911.5288558606  9.63E-06
    39 Broy./Diag. 0.40E+00    9.9     0.00001894     -4911.5288371855  1.87E-05
    40 Broy./Diag. 0.40E+00    7.3     0.00001691     -4911.5289402378 -1.03E-04
    41 Broy./Diag. 0.40E+00    7.1     0.00000940     -4911.5288761709  6.41E-05
    42 Broy./Diag. 0.40E+00    7.3     0.00001449     -4911.5288482937  2.79E-05
    43 Broy./Diag. 0.40E+00    7.5     0.00001616     -4911.5288859727 -3.77E-05
    44 Broy./Diag. 0.40E+00    8.4     0.00001124     -4911.5288900543 -4.08E-06
    45 Broy./Diag. 0.40E+00    7.5     0.00001158     -4911.5288955790 -5.52E-06
    46 Broy./Diag. 0.40E+00    9.7     0.00001135     -4911.5288272607  6.83E-05
    47 Broy./Diag. 0.40E+00    7.0     0.00000603     -4911.5288704060 -4.31E-05
    48 Broy./Diag. 0.40E+00    7.9     0.00000742     -4911.5288901798 -1.98E-05
    49 Broy./Diag. 0.40E+00   10.5     0.00000701     -4911.5288692455  2.09E-05
    50 Broy./Diag. 0.40E+00    7.1     0.00000544     -4911.5288654683  3.78E-06
    51 Broy./Diag. 0.40E+00    6.7     0.00000531     -4911.5288609955  4.47E-06
    52 Broy./Diag. 0.40E+00    6.7     0.00000658     -4911.5288934417 -3.24E-05
    53 Broy./Diag. 0.40E+00    7.8     0.00000381     -4911.5288671964  2.62E-05
    54 Broy./Diag. 0.40E+00    7.2     0.00000449     -4911.5288556202  1.16E-05
    55 Broy./Diag. 0.40E+00    9.5     0.00000482     -4911.5288699655 -1.43E-05
    56 Broy./Diag. 0.40E+00    8.1     0.00000327     -4911.5288723344 -2.37E-06
    57 Broy./Diag. 0.40E+00    7.8     0.00000248     -4911.5288745142 -2.18E-06
    58 Broy./Diag. 0.40E+00   10.5     0.00000299     -4911.5288579166  1.66E-05
    59 Broy./Diag. 0.40E+00    7.1     0.00000201     -4911.5288705651 -1.26E-05
    60 Broy./Diag. 0.40E+00    7.3     0.00000231     -4911.5288757604 -5.20E-06
    61 Broy./Diag. 0.40E+00    7.3     0.00000276     -4911.5288669279  8.83E-06
    62 Broy./Diag. 0.40E+00    7.3     0.00000213     -4911.5288658147  1.11E-06
    63 Broy./Diag. 0.40E+00    7.5     0.00000162     -4911.5288647446  1.07E-06
    64 Broy./Diag. 0.40E+00    6.5     0.00000206     -4911.5288758933 -1.11E-05
    65 Broy./Diag. 0.40E+00    7.1     0.00000123     -4911.5288670211  8.87E-06
    66 Broy./Diag. 0.40E+00    8.0     0.00000111     -4911.5288651454  1.88E-06
    67 Broy./Diag. 0.40E+00    7.2     0.00000152     -4911.5288697089 -4.56E-06
    68 Broy./Diag. 0.40E+00    7.3     0.00000114     -4911.5288698844 -1.75E-07
    69 Broy./Diag. 0.40E+00    7.1     0.00000083     -4911.5288696205  2.64E-07

  *** SCF run converged in    69 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008243273012
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.52561183815624
  Hartree energy:                                            1781.63352912827099
  Exchange-correlation energy:                               -779.35898602764860
  Electronic entropic energy:                                  -0.23868444761779
  Fermi energy:                                                 0.08667371348316

  Total energy:                                             -4911.52886962045613

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.528868372772195

 MD| ***************************************************************************
 MD| Step number                                                            1268
 MD| Time [fs]                                                       2536.000000
 MD| Conserved quantity [hartree]                            -0.491114572063E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    527.402841           587.791848
 MD| Energy drift per atom [K]           0.361001094283E+03   0.269963555243E+03
 MD| Potential energy [hartree]         -0.491152886837E+04  -0.491156158096E+04
 MD| Kinetic energy [hartree]            0.383147738914E+00   0.372034151216E+00
 MD| Temperature [K]                            1020.998670           991.383571
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02331079     -4911.5283551401 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.03050519     -4911.5683827929 -4.00E-02
     3 Broy./Diag. 0.40E+00    6.9     0.03580088     -4911.4512930631  1.17E-01
     4 Broy./Diag. 0.40E+00    6.9     0.03213482     -4911.5447598476 -9.35E-02
     5 Broy./Diag. 0.40E+00    6.7     0.01509166     -4911.5625647460 -1.78E-02
     6 Broy./Diag. 0.40E+00    6.8     0.00586135     -4911.5123650353  5.02E-02
     7 Broy./Diag. 0.40E+00    7.5     0.00448410     -4911.5321232393 -1.98E-02
     8 Broy./Diag. 0.40E+00    7.1     0.00328898     -4911.5276842280  4.44E-03
     9 Broy./Diag. 0.40E+00    7.1     0.00166393     -4911.5388291560 -1.11E-02
    10 Broy./Diag. 0.40E+00    6.7     0.00166588     -4911.5269626698  1.19E-02
    11 Broy./Diag. 0.40E+00    7.5     0.00166823     -4911.5277983049 -8.36E-04
    12 Broy./Diag. 0.40E+00    7.1     0.00067875     -4911.5320765988 -4.28E-03
    13 Broy./Diag. 0.40E+00    8.3     0.00034801     -4911.5295690262  2.51E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00044327     -4911.5303038973 -7.35E-04
    15 Broy./Diag. 0.40E+00    6.9     0.00032146     -4911.5293662094  9.38E-04
    16 Broy./Diag. 0.40E+00    6.7     0.00025150     -4911.5311784805 -1.81E-03
    17 Broy./Diag. 0.40E+00    7.3     0.00042464     -4911.5301978377  9.81E-04
    18 Broy./Diag. 0.40E+00    7.2     0.00031119     -4911.5292495780  9.48E-04
    19 Broy./Diag. 0.40E+00    7.4     0.00017759     -4911.5303317042 -1.08E-03
    20 Broy./Diag. 0.40E+00    7.4     0.00025289     -4911.5298374657  4.94E-04
    21 Broy./Diag. 0.40E+00    7.3     0.00016263     -4911.5303836891 -5.46E-04
    22 Broy./Diag. 0.40E+00    6.6     0.00008319     -4911.5295991532  7.85E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00017088     -4911.5300169234 -4.18E-04
    24 Broy./Diag. 0.40E+00    7.3     0.00014502     -4911.5303509838 -3.34E-04
    25 Broy./Diag. 0.40E+00    6.9     0.00007442     -4911.5298564023  4.95E-04
    26 Broy./Diag. 0.40E+00    7.0     0.00013231     -4911.5300544488 -1.98E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00011525     -4911.5297394642  3.15E-04
    28 Broy./Diag. 0.40E+00    7.1     0.00006011     -4911.5301797573 -4.40E-04
    29 Broy./Diag. 0.40E+00    7.4     0.00009147     -4911.5299298211  2.50E-04
    30 Broy./Diag. 0.40E+00    7.5     0.00008173     -4911.5297832897  1.47E-04
    31 Broy./Diag. 0.40E+00    7.3     0.00003756     -4911.5300286461 -2.45E-04
    32 Broy./Diag. 0.40E+00    7.1     0.00004772     -4911.5299068480  1.22E-04
    33 Broy./Diag. 0.40E+00    7.1     0.00004656     -4911.5300358623 -1.29E-04
    34 Broy./Diag. 0.40E+00    7.1     0.00003102     -4911.5298720208  1.64E-04
    35 Broy./Diag. 0.40E+00    7.3     0.00004442     -4911.5299723093 -1.00E-04
    36 Broy./Diag. 0.40E+00    7.7     0.00005167     -4911.5300086251 -3.63E-05
    37 Broy./Diag. 0.40E+00    7.1     0.00002890     -4911.5298745996  1.34E-04
    38 Broy./Diag. 0.40E+00    7.4     0.00003075     -4911.5299801551 -1.06E-04
    39 Broy./Diag. 0.40E+00    6.9     0.00003001     -4911.5298790058  1.01E-04
    40 Broy./Diag. 0.40E+00    6.9     0.00001417     -4911.5299752620 -9.63E-05
    41 Broy./Diag. 0.40E+00    7.0     0.00001770     -4911.5299350719  4.02E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00002324     -4911.5299278126  7.26E-06
    43 Broy./Diag. 0.40E+00    7.3     0.00001587     -4911.5299753974 -4.76E-05
    44 Broy./Diag. 0.40E+00    7.3     0.00001460     -4911.5299129161  6.25E-05
    45 Broy./Diag. 0.40E+00    6.7     0.00001830     -4911.5299737541 -6.08E-05
    46 Broy./Diag. 0.40E+00    7.1     0.00001084     -4911.5299196887  5.41E-05
    47 Broy./Diag. 0.40E+00    7.3     0.00001145     -4911.5299433551 -2.37E-05
    48 Broy./Diag. 0.40E+00    7.4     0.00001381     -4911.5299454745 -2.12E-06
    49 Broy./Diag. 0.40E+00    7.1     0.00000901     -4911.5299218573  2.36E-05
    50 Broy./Diag. 0.40E+00    7.1     0.00000694     -4911.5299586286 -3.68E-05
    51 Broy./Diag. 0.40E+00    7.1     0.00000855     -4911.5299232614  3.54E-05
    52 Broy./Diag. 0.40E+00    7.3     0.00000543     -4911.5299469615 -2.37E-05
    53 Broy./Diag. 0.40E+00    7.3     0.00000637     -4911.5299396445  7.32E-06
    54 Broy./Diag. 0.40E+00    7.3     0.00000855     -4911.5299395238  1.21E-07
    55 Broy./Diag. 0.40E+00    6.9     0.00000630     -4911.5299503302 -1.08E-05
    56 Broy./Diag. 0.40E+00    7.1     0.00000446     -4911.5299251541  2.52E-05
    57 Broy./Diag. 0.40E+00    6.9     0.00000554     -4911.5299527198 -2.76E-05
    58 Broy./Diag. 0.40E+00    7.1     0.00000330     -4911.5299378054  1.49E-05
    59 Broy./Diag. 0.40E+00    7.4     0.00000306     -4911.5299415780 -3.77E-06
    60 Broy./Diag. 0.40E+00    7.3     0.00000413     -4911.5299410287  5.49E-07
    61 Broy./Diag. 0.40E+00    7.3     0.00000319     -4911.5299375660  3.46E-06
    62 Broy./Diag. 0.40E+00    7.5     0.00000244     -4911.5299497532 -1.22E-05
    63 Broy./Diag. 0.40E+00    7.3     0.00000342     -4911.5299330895  1.67E-05
    64 Broy./Diag. 0.40E+00    7.3     0.00000226     -4911.5299433063 -1.02E-05
    65 Broy./Diag. 0.40E+00    7.3     0.00000213     -4911.5299416006  1.71E-06
    66 Broy./Diag. 0.40E+00    7.1     0.00000270     -4911.5299425377 -9.37E-07
    67 Broy./Diag. 0.40E+00    7.5     0.00000192     -4911.5299443039 -1.77E-06
    68 Broy./Diag. 0.40E+00    7.1     0.00000109     -4911.5299370632  7.24E-06
    69 Broy./Diag. 0.40E+00    7.1     0.00000177     -4911.5299461322 -9.07E-06
    70 Broy./Diag. 0.40E+00    7.3     0.00000128     -4911.5299409304  5.20E-06
    71 Broy./Diag. 0.40E+00    7.6     0.00000110     -4911.5299421476 -1.22E-06
    72 Broy./Diag. 0.40E+00    7.7     0.00000167     -4911.5299417933  3.54E-07
    73 Broy./Diag. 0.40E+00    7.3     0.00000134     -4911.5299410656  7.28E-07
    74 Broy./Diag. 0.40E+00    7.3     0.00000068     -4911.5299458109 -4.75E-06

  *** SCF run converged in    74 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008241840498
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.54488937460337
  Hartree energy:                                            1781.61934272723374
  Exchange-correlation energy:                               -779.36515580956711
  Electronic entropic energy:                                  -0.23868197509317
  Fermi energy:                                                 0.08670611319887

  Total energy:                                             -4911.52994581086568

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.529943653987175

 MD| ***************************************************************************
 MD| Step number                                                            1269
 MD| Time [fs]                                                       2538.000000
 MD| Conserved quantity [hartree]                            -0.491116225694E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    540.652521           587.754701
 MD| Energy drift per atom [K]           0.326647494614E+03   0.270008223438E+03
 MD| Potential energy [hartree]         -0.491152994365E+04  -0.491156155603E+04
 MD| Kinetic energy [hartree]            0.367686711136E+00   0.372030725337E+00
 MD| Temperature [K]                             979.798665           991.374441
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.02522630     -4911.5289072208 -4.91E+03
     2 Broy./Diag. 0.40E+00    6.9     0.03247458     -4911.5711144622 -4.22E-02
     3 Broy./Diag. 0.40E+00    7.1     0.04431983     -4911.4336845429  1.37E-01
     4 Broy./Diag. 0.40E+00    7.7     0.03784722     -4911.5451203596 -1.11E-01
     5 Broy./Diag. 0.40E+00    7.5     0.01677709     -4911.5717318445 -2.66E-02
     6 Broy./Diag. 0.40E+00    6.7     0.00604748     -4911.5102044146  6.15E-02
     7 Broy./Diag. 0.40E+00    7.1     0.00506924     -4911.5383882108 -2.82E-02
     8 Broy./Diag. 0.40E+00    7.1     0.00327664     -4911.5252298474  1.32E-02
     9 Broy./Diag. 0.40E+00    7.1     0.00163767     -4911.5385171545 -1.33E-02
    10 Broy./Diag. 0.40E+00    7.4     0.00201221     -4911.5283503677  1.02E-02
    11 Broy./Diag. 0.40E+00    7.1     0.00185307     -4911.5280885739  2.62E-04
    12 Broy./Diag. 0.40E+00    6.9     0.00065723     -4911.5325294416 -4.44E-03
    13 Broy./Diag. 0.40E+00    7.1     0.00042889     -4911.5297591245  2.77E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00043418     -4911.5313032228 -1.54E-03
    15 Broy./Diag. 0.40E+00    7.3     0.00026810     -4911.5299910660  1.31E-03
    16 Broy./Diag. 0.40E+00    6.7     0.00027026     -4911.5312812426 -1.29E-03
    17 Broy./Diag. 0.40E+00    7.2     0.00041486     -4911.5309080118  3.73E-04
    18 Broy./Diag. 0.40E+00    7.3     0.00027753     -4911.5299725019  9.36E-04
    19 Broy./Diag. 0.40E+00    7.1     0.00018831     -4911.5308917479 -9.19E-04
    20 Broy./Diag. 0.40E+00    7.3     0.00024243     -4911.5302223262  6.69E-04
    21 Broy./Diag. 0.40E+00    7.9     0.00015068     -4911.5310082524 -7.86E-04
    22 Broy./Diag. 0.40E+00    7.0     0.00009268     -4911.5303717684  6.36E-04
    23 Broy./Diag. 0.40E+00    7.5     0.00016495     -4911.5305176458 -1.46E-04
    24 Broy./Diag. 0.40E+00    6.9     0.00012321     -4911.5308769826 -3.59E-04
    25 Broy./Diag. 0.40E+00    7.0     0.00006259     -4911.5305363928  3.41E-04
    26 Broy./Diag. 0.40E+00    7.2     0.00011235     -4911.5307208101 -1.84E-04
    27 Broy./Diag. 0.40E+00    7.5     0.00008967     -4911.5303307563  3.90E-04
    28 Broy./Diag. 0.40E+00    7.2     0.00004905     -4911.5306944640 -3.64E-04
    29 Broy./Diag. 0.40E+00    6.9     0.00009425     -4911.5306452509  4.92E-05
    30 Broy./Diag. 0.40E+00    7.1     0.00007520     -4911.5304401495  2.05E-04
    31 Broy./Diag. 0.40E+00    6.9     0.00003212     -4911.5306119128 -1.72E-04
    32 Broy./Diag. 0.40E+00    7.0     0.00004696     -4911.5305287768  8.31E-05
    33 Broy./Diag. 0.40E+00    7.3     0.00003726     -4911.5307049071 -1.76E-04
    34 Broy./Diag. 0.40E+00    7.1     0.00002297     -4911.5305412032  1.64E-04
    35 Broy./Diag. 0.40E+00    7.3     0.00004086     -4911.5305469837 -5.78E-06
    36 Broy./Diag. 0.40E+00    7.5     0.00004232     -4911.5306461191 -9.91E-05
    37 Broy./Diag. 0.40E+00    7.3     0.00002260     -4911.5305667397  7.94E-05
    38 Broy./Diag. 0.40E+00    7.1     0.00002871     -4911.5306133051 -4.66E-05
    39 Broy./Diag. 0.40E+00    7.1     0.00002442     -4911.5305089771  1.04E-04
    40 Broy./Diag. 0.40E+00    7.1     0.00001365     -4911.5306202944 -1.11E-04
    41 Broy./Diag. 0.40E+00    6.9     0.00001918     -4911.5306214895 -1.20E-06
    42 Broy./Diag. 0.40E+00    6.7     0.00001938     -4911.5305693634  5.21E-05
    43 Broy./Diag. 0.40E+00    7.1     0.00001164     -4911.5305998416 -3.05E-05
    44 Broy./Diag. 0.40E+00    7.5     0.00001346     -4911.5305810729  1.88E-05
    45 Broy./Diag. 0.40E+00    7.3     0.00001311     -4911.5306313438 -5.03E-05
    46 Broy./Diag. 0.40E+00    7.3     0.00000876     -4911.5305699037  6.14E-05
    47 Broy./Diag. 0.40E+00    7.2     0.00001192     -4911.5305748060 -4.90E-06
    48 Broy./Diag. 0.40E+00    7.2     0.00001256     -4911.5306129909 -3.82E-05
    49 Broy./Diag. 0.40E+00    6.8     0.00000724     -4911.5305955322  1.75E-05
    50 Broy./Diag. 0.40E+00    7.3     0.00000726     -4911.5306044205 -8.89E-06
    51 Broy./Diag. 0.40E+00    7.1     0.00000666     -4911.5305775293  2.69E-05
    52 Broy./Diag. 0.40E+00    7.3     0.00000427     -4911.5306093961 -3.19E-05
    53 Broy./Diag. 0.40E+00    7.6     0.00000612     -4911.5306058859  3.51E-06
    54 Broy./Diag. 0.40E+00    7.3     0.00000692     -4911.5305855556  2.03E-05
    55 Broy./Diag. 0.40E+00    7.7     0.00000453     -4911.5305977264 -1.22E-05
    56 Broy./Diag. 0.40E+00    7.1     0.00000469     -4911.5305943558  3.37E-06
    57 Broy./Diag. 0.40E+00    7.1     0.00000435     -4911.5306119495 -1.76E-05
    58 Broy./Diag. 0.40E+00    6.9     0.00000273     -4911.5305917094  2.02E-05
    59 Broy./Diag. 0.40E+00    7.1     0.00000329     -4911.5305962632 -4.55E-06
    60 Broy./Diag. 0.40E+00    6.9     0.00000380     -4911.5306076445 -1.14E-05
    61 Broy./Diag. 0.40E+00    7.3     0.00000231     -4911.5306008056  6.84E-06
    62 Broy./Diag. 0.40E+00    7.3     0.00000242     -4911.5306026577 -1.85E-06
    63 Broy./Diag. 0.40E+00    7.1     0.00000246     -4911.5305941492  8.51E-06
    64 Broy./Diag. 0.40E+00    7.0     0.00000164     -4911.5306062376 -1.21E-05
    65 Broy./Diag. 0.40E+00    7.3     0.00000194     -4911.5306030704  3.17E-06
    66 Broy./Diag. 0.40E+00    7.1     0.00000251     -4911.5305969611  6.11E-06
    67 Broy./Diag. 0.40E+00    7.0     0.00000156     -4911.5306024475 -5.49E-06
    68 Broy./Diag. 0.40E+00    7.3     0.00000132     -4911.5306012729  1.17E-06
    69 Broy./Diag. 0.40E+00    7.3     0.00000135     -4911.5306058174 -4.54E-06
    70 Broy./Diag. 0.40E+00    7.3     0.00000089     -4911.5305996969  6.12E-06

  *** SCF run converged in    70 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008241269925
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.56315941134017
  Hartree energy:                                            1781.60605512193433
  Exchange-correlation energy:                               -779.37077987216378
  Electronic entropic energy:                                  -0.23869427552844
  Fermi energy:                                                 0.08673526466590

  Total energy:                                             -4911.53059969686819

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.530604416971073

 MD| ***************************************************************************
 MD| Step number                                                            1270
 MD| Time [fs]                                                       2540.000000
 MD| Conserved quantity [hartree]                            -0.491116310750E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    510.974816           587.694244
 MD| Energy drift per atom [K]           0.324880494796E+03   0.270051429951E+03
 MD| Potential energy [hartree]         -0.491153060442E+04  -0.491156153166E+04
 MD| Kinetic energy [hartree]            0.367496918276E+00   0.372027155411E+00
 MD| Temperature [K]                             979.292911           991.364928
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.02486999     -4911.5286957801 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.3     0.02926565     -4911.5734681406 -4.48E-02
     3 Broy./Diag. 0.40E+00    7.6     0.03769119     -4911.4042026282  1.69E-01
     4 Broy./Diag. 0.40E+00    6.9     0.02969250     -4911.5853568523 -1.81E-01
     5 Broy./Diag. 0.40E+00    7.3     0.01674570     -4911.5609815978  2.44E-02
     6 Broy./Diag. 0.40E+00    6.8     0.00847558     -4911.5065807587  5.44E-02
     7 Broy./Diag. 0.40E+00    7.7     0.00525056     -4911.5423814317 -3.58E-02
     8 Broy./Diag. 0.40E+00    8.1     0.00256669     -4911.5252323090  1.71E-02
     9 Broy./Diag. 0.40E+00    7.5     0.00149668     -4911.5367232718 -1.15E-02
    10 Broy./Diag. 0.40E+00    7.3     0.00164394     -4911.5267682008  9.96E-03
    11 Broy./Diag. 0.40E+00    7.3     0.00169440     -4911.5295369601 -2.77E-03
    12 Broy./Diag. 0.40E+00    7.3     0.00086700     -4911.5325009306 -2.96E-03
    13 Broy./Diag. 0.40E+00    6.7     0.00048908     -4911.5289275668  3.57E-03
    14 Broy./Diag. 0.40E+00    7.4     0.00038882     -4911.5310105050 -2.08E-03
    15 Broy./Diag. 0.40E+00    6.9     0.00021647     -4911.5298351302  1.18E-03
    16 Broy./Diag. 0.40E+00    7.1     0.00024172     -4911.5309927706 -1.16E-03
    17 Broy./Diag. 0.40E+00    7.9     0.00035691     -4911.5302726367  7.20E-04
    18 Broy./Diag. 0.40E+00    7.3     0.00030467     -4911.5297923084  4.80E-04
    19 Broy./Diag. 0.40E+00    7.3     0.00021908     -4911.5308521066 -1.06E-03
    20 Broy./Diag. 0.40E+00    7.1     0.00021210     -4911.5299473998  9.05E-04
    21 Broy./Diag. 0.40E+00    7.1     0.00011927     -4911.5306378198 -6.90E-04
    22 Broy./Diag. 0.40E+00    7.1     0.00009630     -4911.5301166787  5.21E-04
    23 Broy./Diag. 0.40E+00    7.3     0.00014350     -4911.5304126790 -2.96E-04
    24 Broy./Diag. 0.40E+00    7.2     0.00013172     -4911.5305818306 -1.69E-04
    25 Broy./Diag. 0.40E+00    7.1     0.00008359     -4911.5301998700  3.82E-04
    26 Broy./Diag. 0.40E+00    6.9     0.00009877     -4911.5305262598 -3.26E-04
    27 Broy./Diag. 0.40E+00    7.0     0.00007237     -4911.5301692944  3.57E-04
    28 Broy./Diag. 0.40E+00    7.4     0.00005302     -4911.5304698756 -3.01E-04
    29 Broy./Diag. 0.40E+00    7.1     0.00008108     -4911.5303537543  1.16E-04
    30 Broy./Diag. 0.40E+00    7.1     0.00007669     -4911.5302674939  8.63E-05
    31 Broy./Diag. 0.40E+00    6.9     0.00004404     -4911.5304530823 -1.86E-04
    32 Broy./Diag. 0.40E+00    7.1     0.00004111     -4911.5302991361  1.54E-04
    33 Broy./Diag. 0.40E+00    7.8     0.00002963     -4911.5304730697 -1.74E-04
    34 Broy./Diag. 0.40E+00    6.9     0.00002340     -4911.5303471054  1.26E-04
    35 Broy./Diag. 0.40E+00    7.1     0.00003477     -4911.5303808201 -3.37E-05
    36 Broy./Diag. 0.40E+00    7.1     0.00004211     -4911.5304257404 -4.49E-05
    37 Broy./Diag. 0.40E+00    7.7     0.00002973     -4911.5303480060  7.77E-05
    38 Broy./Diag. 0.40E+00    7.1     0.00002608     -4911.5304422017 -9.42E-05
    39 Broy./Diag. 0.40E+00    7.3     0.00001962     -4911.5303331080  1.09E-04
    40 Broy./Diag. 0.40E+00    7.1     0.00001334     -4911.5304233733 -9.03E-05
    41 Broy./Diag. 0.40E+00    6.9     0.00001626     -4911.5304145941  8.78E-06
    42 Broy./Diag. 0.40E+00    7.1     0.00001884     -4911.5303913795  2.32E-05
    43 Broy./Diag. 0.40E+00    6.9     0.00001482     -4911.5304184227 -2.70E-05
    44 Broy./Diag. 0.40E+00    7.5     0.00001238     -4911.5303781768  4.02E-05
    45 Broy./Diag. 0.40E+00    7.0     0.00001022     -4911.5304369003 -5.87E-05
    46 Broy./Diag. 0.40E+00    7.1     0.00000817     -4911.5303880107  4.89E-05
    47 Broy./Diag. 0.40E+00    7.2     0.00001006     -4911.5303960456 -8.03E-06
    48 Broy./Diag. 0.40E+00    7.2     0.00001185     -4911.5304168006 -2.08E-05
    49 Broy./Diag. 0.40E+00    7.1     0.00000879     -4911.5304045386  1.23E-05
    50 Broy./Diag. 0.40E+00    7.1     0.00000689     -4911.5304256768 -2.11E-05
    51 Broy./Diag. 0.40E+00    7.3     0.00000507     -4911.5303933065  3.24E-05
    52 Broy./Diag. 0.40E+00    7.1     0.00000357     -4911.5304193110 -2.60E-05
    53 Broy./Diag. 0.40E+00    6.9     0.00000497     -4911.5304169860  2.32E-06
    54 Broy./Diag. 0.40E+00    7.3     0.00000640     -4911.5304065550  1.04E-05
    55 Broy./Diag. 0.40E+00    7.1     0.00000541     -4911.5304142638 -7.71E-06
    56 Broy./Diag. 0.40E+00    7.1     0.00000460     -4911.5304045495  9.71E-06
    57 Broy./Diag. 0.40E+00    7.7     0.00000342     -4911.5304270427 -2.25E-05
    58 Broy./Diag. 0.40E+00    7.1     0.00000221     -4911.5304104724  1.66E-05
    59 Broy./Diag. 0.40E+00    6.9     0.00000266     -4911.5304136022 -3.13E-06
    60 Broy./Diag. 0.40E+00    6.7     0.00000335     -4911.5304196538 -6.05E-06
    61 Broy./Diag. 0.40E+00    6.9     0.00000258     -4911.5304162109  3.44E-06
    62 Broy./Diag. 0.40E+00    7.1     0.00000240     -4911.5304209201 -4.71E-06
    63 Broy./Diag. 0.40E+00    7.1     0.00000204     -4911.5304095275  1.14E-05
    64 Broy./Diag. 0.40E+00    7.3     0.00000126     -4911.5304203472 -1.08E-05
    65 Broy./Diag. 0.40E+00    7.8     0.00000160     -4911.5304185021  1.85E-06
    66 Broy./Diag. 0.40E+00    7.1     0.00000226     -4911.5304157662  2.74E-06
    67 Broy./Diag. 0.40E+00    9.8     0.00000171     -4911.5304187352 -2.97E-06
    68 Broy./Diag. 0.40E+00    7.2     0.00000128     -4911.5304159392  2.80E-06
    69 Broy./Diag. 0.40E+00    9.9     0.00000111     -4911.5304221570 -6.22E-06
    70 Broy./Diag. 0.40E+00    8.3     0.00000073     -4911.5304169516  5.21E-06

  *** SCF run converged in    70 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008241738866
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.58253744305694
  Hartree energy:                                            1781.59267234216350
  Exchange-correlation energy:                               -779.37655827089384
  Electronic entropic energy:                                  -0.23872838439397
  Fermi energy:                                                 0.08676125768510

  Total energy:                                             -4911.53041695160118

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.530421044488321

 MD| ***************************************************************************
 MD| Step number                                                            1271
 MD| Time [fs]                                                       2542.000000
 MD| Conserved quantity [hartree]                            -0.491115756384E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    518.419062           587.639740
 MD| Energy drift per atom [K]           0.336397254484E+03   0.270103629656E+03
 MD| Potential energy [hartree]         -0.491153042104E+04  -0.491156150718E+04
 MD| Kinetic energy [hartree]            0.372857206388E+00   0.372027808480E+00
 MD| Temperature [K]                             993.576819           991.366669
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.0     0.02214944     -4911.5276008541 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.02890901     -4911.5857319162 -5.81E-02
     3 Broy./Diag. 0.40E+00    7.5     0.03373108     -4911.3884396638  1.97E-01
     4 Broy./Diag. 0.40E+00    7.7     0.02664140     -4911.6001463820 -2.12E-01
     5 Broy./Diag. 0.40E+00    7.3     0.01680597     -4911.5602245906  3.99E-02
     6 Broy./Diag. 0.40E+00   10.3     0.00830432     -4911.5045026647  5.57E-02
     7 Broy./Diag. 0.40E+00    7.2     0.00504865     -4911.5391504832 -3.46E-02
     8 Broy./Diag. 0.40E+00    8.0     0.00273189     -4911.5251609202  1.40E-02
     9 Broy./Diag. 0.40E+00   11.0     0.00145681     -4911.5360179651 -1.09E-02
    10 Broy./Diag. 0.40E+00    7.5     0.00142323     -4911.5253043028  1.07E-02
    11 Broy./Diag. 0.40E+00    7.0     0.00160041     -4911.5294134825 -4.11E-03
    12 Broy./Diag. 0.40E+00    7.7     0.00086626     -4911.5318431866 -2.43E-03
    13 Broy./Diag. 0.40E+00    7.8     0.00043552     -4911.5280064965  3.84E-03
    14 Broy./Diag. 0.40E+00    8.9     0.00039291     -4911.5297610648 -1.75E-03
    15 Broy./Diag. 0.40E+00    8.5     0.00022050     -4911.5288538958  9.07E-04
    16 Broy./Diag. 0.40E+00    7.7     0.00020620     -4911.5301563074 -1.30E-03
    17 Broy./Diag. 0.40E+00   10.7     0.00034250     -4911.5290738272  1.08E-03
    18 Broy./Diag. 0.40E+00    7.5     0.00031448     -4911.5287421378  3.32E-04
    19 Broy./Diag. 0.40E+00    7.1     0.00021376     -4911.5299625244 -1.22E-03
    20 Broy./Diag. 0.40E+00    6.9     0.00021493     -4911.5290457632  9.17E-04
    21 Broy./Diag. 0.40E+00    7.5     0.00011853     -4911.5295617748 -5.16E-04
    22 Broy./Diag. 0.40E+00    7.1     0.00008031     -4911.5290007463  5.61E-04
    23 Broy./Diag. 0.40E+00    6.9     0.00013473     -4911.5294591174 -4.58E-04
    24 Broy./Diag. 0.40E+00    6.9     0.00013000     -4911.5295555081 -9.64E-05
    25 Broy./Diag. 0.40E+00    7.1     0.00008092     -4911.5290950311  4.60E-04
    26 Broy./Diag. 0.40E+00    8.1     0.00010305     -4911.5294362943 -3.41E-04
    27 Broy./Diag. 0.40E+00    7.2     0.00007804     -4911.5291695459  2.67E-04
    28 Broy./Diag. 0.40E+00    6.9     0.00004491     -4911.5294660594 -2.97E-04
    29 Broy./Diag. 0.40E+00    7.3     0.00007498     -4911.5292237705  2.42E-04
    30 Broy./Diag. 0.40E+00    7.0     0.00007519     -4911.5291827659  4.10E-05
    31 Broy./Diag. 0.40E+00    6.7     0.00004174     -4911.5294202410 -2.37E-04
    32 Broy./Diag. 0.40E+00    7.3     0.00003866     -4911.5292497425  1.70E-04
    33 Broy./Diag. 0.40E+00    7.4     0.00002992     -4911.5293678145 -1.18E-04
    34 Broy./Diag. 0.40E+00    7.3     0.00002019     -4911.5292607566  1.07E-04
    35 Broy./Diag. 0.40E+00    6.9     0.00003199     -4911.5293490301 -8.83E-05
    36 Broy./Diag. 0.40E+00    6.8     0.00004108     -4911.5293545561 -5.53E-06
    37 Broy./Diag. 0.40E+00    6.8     0.00002906     -4911.5292429616  1.12E-04
    38 Broy./Diag. 0.40E+00    7.5     0.00002553     -4911.5293532450 -1.10E-04
    39 Broy./Diag. 0.40E+00    6.9     0.00002060     -4911.5292708029  8.24E-05
    40 Broy./Diag. 0.40E+00    6.9     0.00001114     -4911.5293478898 -7.71E-05
    41 Broy./Diag. 0.40E+00    7.3     0.00001365     -4911.5293099236  3.80E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00001747     -4911.5293053265  4.60E-06
    43 Broy./Diag. 0.40E+00    7.7     0.00001381     -4911.5293442830 -3.90E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00001102     -4911.5292980699  4.62E-05
    45 Broy./Diag. 0.40E+00    7.0     0.00001077     -4911.5293400474 -4.20E-05
    46 Broy./Diag. 0.40E+00    7.3     0.00000756     -4911.5292985170  4.15E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00000863     -4911.5293206661 -2.21E-05
    48 Broy./Diag. 0.40E+00    6.7     0.00001094     -4911.5293281061 -7.44E-06
    49 Broy./Diag. 0.40E+00    6.7     0.00000823     -4911.5293083614  1.97E-05
    50 Broy./Diag. 0.40E+00    7.3     0.00000591     -4911.5293326632 -2.43E-05
    51 Broy./Diag. 0.40E+00    6.7     0.00000492     -4911.5293084993  2.42E-05
    52 Broy./Diag. 0.40E+00    7.5     0.00000314     -4911.5293284983 -2.00E-05
    53 Broy./Diag. 0.40E+00    7.4     0.00000409     -4911.5293217172  6.78E-06
    54 Broy./Diag. 0.40E+00    7.3     0.00000586     -4911.5293165349  5.18E-06
    55 Broy./Diag. 0.40E+00    7.3     0.00000514     -4911.5293257201 -9.19E-06
    56 Broy./Diag. 0.40E+00    7.1     0.00000396     -4911.5293140766  1.16E-05
    57 Broy./Diag. 0.40E+00    6.5     0.00000346     -4911.5293321323 -1.81E-05
    58 Broy./Diag. 0.40E+00    7.3     0.00000230     -4911.5293183653  1.38E-05
    59 Broy./Diag. 0.40E+00    7.3     0.00000203     -4911.5293223647 -4.00E-06
    60 Broy./Diag. 0.40E+00    7.5     0.00000276     -4911.5293258523 -3.49E-06
    61 Broy./Diag. 0.40E+00    7.0     0.00000229     -4911.5293222252  3.63E-06
    62 Broy./Diag. 0.40E+00    7.3     0.00000197     -4911.5293267911 -4.57E-06
    63 Broy./Diag. 0.40E+00    7.0     0.00000197     -4911.5293174216  9.37E-06
    64 Broy./Diag. 0.40E+00    7.3     0.00000142     -4911.5293260419 -8.62E-06
    65 Broy./Diag. 0.40E+00    6.8     0.00000129     -4911.5293242907  1.75E-06
    66 Broy./Diag. 0.40E+00    7.1     0.00000191     -4911.5293222585  2.03E-06
    67 Broy./Diag. 0.40E+00    7.1     0.00000154     -4911.5293247733 -2.51E-06
    68 Broy./Diag. 0.40E+00    7.1     0.00000099     -4911.5293220740  2.70E-06

  *** SCF run converged in    68 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008243822795
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.60980944383755
  Hartree energy:                                            1781.57469736215990
  Exchange-correlation energy:                               -779.38469607488605
  Electronic entropic energy:                                  -0.23879276773320
  Fermi energy:                                                 0.08679509798770

  Total energy:                                             -4911.52932207397953

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.529325476006306

 MD| ***************************************************************************
 MD| Step number                                                            1272
 MD| Time [fs]                                                       2544.000000
 MD| Conserved quantity [hartree]                            -0.491115816755E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    511.175516           587.579627
 MD| Energy drift per atom [K]           0.335143055859E+03   0.270154761280E+03
 MD| Potential energy [hartree]         -0.491152932548E+04  -0.491156148188E+04
 MD| Kinetic energy [hartree]            0.371157921958E+00   0.372027124607E+00
 MD| Temperature [K]                             989.048626           991.364846
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.4     0.02031390     -4911.5256902006 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.5     0.03782749     -4911.6073047626 -8.16E-02
     3 Broy./Diag. 0.40E+00    7.5     0.05665722     -4911.3826268006  2.25E-01
     4 Broy./Diag. 0.40E+00    7.5     0.04536439     -4911.5494805991 -1.67E-01
     5 Broy./Diag. 0.40E+00    7.5     0.01828891     -4911.6015797857 -5.21E-02
     6 Broy./Diag. 0.40E+00    6.9     0.00534202     -4911.4993506702  1.02E-01
     7 Broy./Diag. 0.40E+00    6.8     0.00381076     -4911.5323147786 -3.30E-02
     8 Broy./Diag. 0.40E+00    7.3     0.00316117     -4911.5272894349  5.03E-03
     9 Broy./Diag. 0.40E+00    7.5     0.00185445     -4911.5358574092 -8.57E-03
    10 Broy./Diag. 0.40E+00    7.1     0.00216560     -4911.5251836758  1.07E-02
    11 Broy./Diag. 0.40E+00    7.0     0.00195948     -4911.5257763195 -5.93E-04
    12 Broy./Diag. 0.40E+00    7.1     0.00059169     -4911.5309170328 -5.14E-03
    13 Broy./Diag. 0.40E+00    6.9     0.00027374     -4911.5267969156  4.12E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00033737     -4911.5279893341 -1.19E-03
    15 Broy./Diag. 0.40E+00    7.4     0.00031879     -4911.5275898412  3.99E-04
    16 Broy./Diag. 0.40E+00    7.5     0.00025546     -4911.5289153746 -1.33E-03
    17 Broy./Diag. 0.40E+00    7.4     0.00040827     -4911.5279448885  9.70E-04
    18 Broy./Diag. 0.40E+00    7.1     0.00028055     -4911.5269399464  1.00E-03
    19 Broy./Diag. 0.40E+00    7.3     0.00013693     -4911.5283440053 -1.40E-03
    20 Broy./Diag. 0.40E+00    7.1     0.00017540     -4911.5276590202  6.85E-04
    21 Broy./Diag. 0.40E+00    6.9     0.00015235     -4911.5279407727 -2.82E-04
    22 Broy./Diag. 0.40E+00    7.1     0.00009399     -4911.5273492611  5.92E-04
    23 Broy./Diag. 0.40E+00    7.0     0.00015809     -4911.5276968902 -3.48E-04
    24 Broy./Diag. 0.40E+00    7.0     0.00011592     -4911.5280885817 -3.92E-04
    25 Broy./Diag. 0.40E+00    7.3     0.00005021     -4911.5275582494  5.30E-04
    26 Broy./Diag. 0.40E+00    7.3     0.00008356     -4911.5277076452 -1.49E-04
    27 Broy./Diag. 0.40E+00    7.3     0.00008847     -4911.5275292451  1.78E-04
    28 Broy./Diag. 0.40E+00    7.3     0.00006196     -4911.5278146152 -2.85E-04
    29 Broy./Diag. 0.40E+00    7.5     0.00009054     -4911.5276229373  1.92E-04
    30 Broy./Diag. 0.40E+00    6.9     0.00007143     -4911.5273886712  2.34E-04
    31 Broy./Diag. 0.40E+00    7.3     0.00002566     -4911.5276574946 -2.69E-04
    32 Broy./Diag. 0.40E+00    8.1     0.00003168     -4911.5275839040  7.36E-05
    33 Broy./Diag. 0.40E+00    7.3     0.00003371     -4911.5276536734 -6.98E-05
    34 Broy./Diag. 0.40E+00    7.0     0.00003101     -4911.5275129235  1.41E-04
    35 Broy./Diag. 0.40E+00    7.2     0.00004250     -4911.5275763364 -6.34E-05
    36 Broy./Diag. 0.40E+00    6.6     0.00004281     -4911.5276576426 -8.13E-05
    37 Broy./Diag. 0.40E+00    7.1     0.00002019     -4911.5275103970  1.47E-04
    38 Broy./Diag. 0.40E+00    7.3     0.00001952     -4911.5275540266 -4.36E-05
    39 Broy./Diag. 0.40E+00    6.9     0.00002150     -4911.5274965074  5.75E-05
    40 Broy./Diag. 0.40E+00    7.5     0.00001647     -4911.5275871394 -9.06E-05
    41 Broy./Diag. 0.40E+00    7.4     0.00001783     -4911.5275548524  3.23E-05
    42 Broy./Diag. 0.40E+00    7.2     0.00001914     -4911.5275111068  4.37E-05
    43 Broy./Diag. 0.40E+00    6.9     0.00001092     -4911.5275663079 -5.52E-05
    44 Broy./Diag. 0.40E+00    7.1     0.00000957     -4911.5275372339  2.91E-05
    45 Broy./Diag. 0.40E+00    7.0     0.00001204     -4911.5275635694 -2.63E-05
    46 Broy./Diag. 0.40E+00    6.9     0.00001089     -4911.5275088017  5.48E-05
    47 Broy./Diag. 0.40E+00    7.1     0.00001158     -4911.5275246968 -1.59E-05
    48 Broy./Diag. 0.40E+00    7.5     0.00001182     -4911.5275516147 -2.69E-05
    49 Broy./Diag. 0.40E+00    7.7     0.00000667     -4911.5275194180  3.22E-05
    50 Broy./Diag. 0.40E+00    7.2     0.00000479     -4911.5275340513 -1.46E-05
    51 Broy./Diag. 0.40E+00    6.7     0.00000594     -4911.5275153056  1.87E-05
    52 Broy./Diag. 0.40E+00    7.5     0.00000540     -4911.5275404072 -2.51E-05
    53 Broy./Diag. 0.40E+00    7.5     0.00000628     -4911.5275299741  1.04E-05
    54 Broy./Diag. 0.40E+00    6.9     0.00000683     -4911.5275143803  1.56E-05
    55 Broy./Diag. 0.40E+00    7.1     0.00000446     -4911.5275296564 -1.53E-05
    56 Broy./Diag. 0.40E+00    6.8     0.00000324     -4911.5275188895  1.08E-05
    57 Broy./Diag. 0.40E+00    7.8     0.00000346     -4911.5275325101 -1.36E-05
    58 Broy./Diag. 0.40E+00    7.1     0.00000310     -4911.5275162911  1.62E-05
    59 Broy./Diag. 0.40E+00    7.1     0.00000331     -4911.5275207918 -4.50E-06
    60 Broy./Diag. 0.40E+00    7.2     0.00000356     -4911.5275281226 -7.33E-06
    61 Broy./Diag. 0.40E+00    7.0     0.00000232     -4911.5275195400  8.58E-06
    62 Broy./Diag. 0.40E+00    7.1     0.00000179     -4911.5275245155 -4.98E-06
    63 Broy./Diag. 0.40E+00    7.6     0.00000205     -4911.5275156724  8.84E-06
    64 Broy./Diag. 0.40E+00    7.3     0.00000195     -4911.5275247875 -9.12E-06
    65 Broy./Diag. 0.40E+00    6.9     0.00000202     -4911.5275215934  3.19E-06
    66 Broy./Diag. 0.40E+00    7.1     0.00000226     -4911.5275170568  4.54E-06
    67 Broy./Diag. 0.40E+00    7.3     0.00000145     -4911.5275218343 -4.78E-06
    68 Broy./Diag. 0.40E+00    7.1     0.00000099     -4911.5275180985  3.74E-06

  *** SCF run converged in    68 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999974       -0.0000000026
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008248697051
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.65196277902760
  Hartree energy:                                            1781.54750487269530
  Exchange-correlation energy:                               -779.39781185571144
  Electronic entropic energy:                                  -0.23883390590481
  Fermi energy:                                                 0.08685167856168

  Total energy:                                             -4911.52751809853999

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.527518159877218

 MD| ***************************************************************************
 MD| Step number                                                            1273
 MD| Time [fs]                                                       2546.000000
 MD| Conserved quantity [hartree]                            -0.491114501483E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    498.172034           587.509393
 MD| Energy drift per atom [K]           0.362467384204E+03   0.270227277088E+03
 MD| Potential energy [hartree]         -0.491152751816E+04  -0.491156145520E+04
 MD| Kinetic energy [hartree]            0.382503333371E+00   0.372035354150E+00
 MD| Temperature [K]                            1019.281480           991.386776
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.2     0.01888663     -4911.5227911324 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.04437662     -4911.6300908416 -1.07E-01
     3 Broy./Diag. 0.40E+00    6.4     0.04272113     -4911.3104629105  3.20E-01
     4 Broy./Diag. 0.40E+00    7.3     0.03783235     -4911.5895373176 -2.79E-01
     5 Broy./Diag. 0.40E+00    7.4     0.02116416     -4911.5919705470 -2.43E-03
     6 Broy./Diag. 0.40E+00    7.1     0.00770429     -4911.4963514601  9.56E-02
     7 Broy./Diag. 0.40E+00    7.5     0.00516010     -4911.5313318542 -3.50E-02
     8 Broy./Diag. 0.40E+00    7.4     0.00289648     -4911.5243721672  6.96E-03
     9 Broy./Diag. 0.40E+00    6.9     0.00187157     -4911.5344553839 -1.01E-02
    10 Broy./Diag. 0.40E+00    7.3     0.00201947     -4911.5204262585  1.40E-02
    11 Broy./Diag. 0.40E+00    6.8     0.00209865     -4911.5240059500 -3.58E-03
    12 Broy./Diag. 0.40E+00    7.1     0.00095019     -4911.5294249034 -5.42E-03
    13 Broy./Diag. 0.40E+00    7.5     0.00048832     -4911.5240973183  5.33E-03
    14 Broy./Diag. 0.40E+00    7.0     0.00038572     -4911.5253277376 -1.23E-03
    15 Broy./Diag. 0.40E+00    7.4     0.00028647     -4911.5248523863  4.75E-04
    16 Broy./Diag. 0.40E+00    7.1     0.00025092     -4911.5264752810 -1.62E-03
    17 Broy./Diag. 0.40E+00    7.3     0.00040327     -4911.5250958946  1.38E-03
    18 Broy./Diag. 0.40E+00    7.5     0.00031933     -4911.5242237385  8.72E-04
    19 Broy./Diag. 0.40E+00    7.0     0.00019594     -4911.5256826533 -1.46E-03
    20 Broy./Diag. 0.40E+00    6.8     0.00021178     -4911.5248667760  8.16E-04
    21 Broy./Diag. 0.40E+00    7.1     0.00013903     -4911.5252117888 -3.45E-04
    22 Broy./Diag. 0.40E+00    7.1     0.00010743     -4911.5245191724  6.93E-04
    23 Broy./Diag. 0.40E+00    7.5     0.00016515     -4911.5249821458 -4.63E-04
    24 Broy./Diag. 0.40E+00    7.0     0.00013762     -4911.5252993960 -3.17E-04
    25 Broy./Diag. 0.40E+00    7.3     0.00006857     -4911.5246895641  6.10E-04
    26 Broy./Diag. 0.40E+00    7.1     0.00010008     -4911.5248939343 -2.04E-04
    27 Broy./Diag. 0.40E+00    6.9     0.00009229     -4911.5246776858  2.16E-04
    28 Broy./Diag. 0.40E+00    7.1     0.00006573     -4911.5249609582 -2.83E-04
    29 Broy./Diag. 0.40E+00    6.9     0.00009184     -4911.5247234420  2.38E-04
    30 Broy./Diag. 0.40E+00    7.3     0.00007941     -4911.5245485909  1.75E-04
    31 Broy./Diag. 0.40E+00    7.1     0.00003446     -4911.5248126592 -2.64E-04
    32 Broy./Diag. 0.40E+00    7.1     0.00003566     -4911.5246799797  1.33E-04
    33 Broy./Diag. 0.40E+00    6.9     0.00003385     -4911.5247781138 -9.81E-05
    34 Broy./Diag. 0.40E+00    7.2     0.00002959     -4911.5246464379  1.32E-04
    35 Broy./Diag. 0.40E+00    7.3     0.00004326     -4911.5247015931 -5.52E-05
    36 Broy./Diag. 0.40E+00    7.5     0.00004781     -4911.5247467766 -4.52E-05
    37 Broy./Diag. 0.40E+00    7.3     0.00002684     -4911.5246060202  1.41E-04
    38 Broy./Diag. 0.40E+00    7.1     0.00002230     -4911.5246989103 -9.29E-05
    39 Broy./Diag. 0.40E+00    7.1     0.00002238     -4911.5246014412  9.75E-05
    40 Broy./Diag. 0.40E+00    7.2     0.00001624     -4911.5246828202 -8.14E-05
    41 Broy./Diag. 0.40E+00    7.1     0.00001763     -4911.5246543291  2.85E-05
    42 Broy./Diag. 0.40E+00    7.3     0.00002031     -4911.5246230043  3.13E-05
    43 Broy./Diag. 0.40E+00    6.9     0.00001423     -4911.5246649320 -4.19E-05
    44 Broy./Diag. 0.40E+00    6.9     0.00001138     -4911.5246102310  5.47E-05
    45 Broy./Diag. 0.40E+00    7.3     0.00001292     -4911.5246551458 -4.49E-05
    46 Broy./Diag. 0.40E+00    7.7     0.00001128     -4911.5246065702  4.86E-05
    47 Broy./Diag. 0.40E+00    7.6     0.00001125     -4911.5246154421 -8.87E-06
    48 Broy./Diag. 0.40E+00    7.3     0.00001212     -4911.5246302566 -1.48E-05
    49 Broy./Diag. 0.40E+00    7.0     0.00000783     -4911.5246052337  2.50E-05
    50 Broy./Diag. 0.40E+00    6.9     0.00000532     -4911.5246306037 -2.54E-05
    51 Broy./Diag. 0.40E+00    7.3     0.00000589     -4911.5246018260  2.88E-05
    52 Broy./Diag. 0.40E+00    7.1     0.00000562     -4911.5246201465 -1.83E-05
    53 Broy./Diag. 0.40E+00    6.9     0.00000603     -4911.5246131217  7.02E-06
    54 Broy./Diag. 0.40E+00    7.5     0.00000720     -4911.5246035821  9.54E-06
    55 Broy./Diag. 0.40E+00    7.6     0.00000535     -4911.5246137066 -1.01E-05
    56 Broy./Diag. 0.40E+00    7.5     0.00000384     -4911.5245945937  1.91E-05
    57 Broy./Diag. 0.40E+00    7.3     0.00000349     -4911.5246156232 -2.10E-05
    58 Broy./Diag. 0.40E+00    6.7     0.00000305     -4911.5246020447  1.36E-05
    59 Broy./Diag. 0.40E+00    7.0     0.00000304     -4911.5246033279 -1.28E-06
    60 Broy./Diag. 0.40E+00    7.5     0.00000373     -4911.5246064632 -3.14E-06
    61 Broy./Diag. 0.40E+00    7.7     0.00000274     -4911.5246000664  6.40E-06
    62 Broy./Diag. 0.40E+00    7.3     0.00000212     -4911.5246073974 -7.33E-06
    63 Broy./Diag. 0.40E+00    7.5     0.00000219     -4911.5245947096  1.27E-05
    64 Broy./Diag. 0.40E+00    7.1     0.00000196     -4911.5246019760 -7.27E-06
    65 Broy./Diag. 0.40E+00    7.0     0.00000185     -4911.5246005438  1.43E-06
    66 Broy./Diag. 0.40E+00    7.3     0.00000227     -4911.5245981703  2.37E-06
    67 Broy./Diag. 0.40E+00    6.8     0.00000162     -4911.5246010134 -2.84E-06
    68 Broy./Diag. 0.40E+00    7.2     0.00000109     -4911.5245958531  5.16E-06
    69 Broy./Diag. 0.40E+00    7.1     0.00000111     -4911.5246021064 -6.25E-06
    70 Broy./Diag. 0.40E+00    6.9     0.00000102     -4911.5245974980  4.61E-06
    71 Broy./Diag. 0.40E+00    8.0     0.00000095     -4911.5245977236 -2.26E-07

  *** SCF run converged in    71 steps ***


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999974       -0.0000000026
  Total charge density on r-space grids:       -0.0000000020
  Total charge density g-space grids:          -0.0000000020

  Overlap energy of the core charge distribution:               0.00008256901183
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.70369366054183
  Hartree energy:                                            1781.51477734506943
  Exchange-correlation energy:                               -779.41387160596082
  Electronic entropic energy:                                  -0.23885718986280
  Fermi energy:                                                 0.08691680233055

  Total energy:                                             -4911.52459772356815

 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.524595239166956

 MD| ***************************************************************************
 MD| Step number                                                            1274
 MD| Time [fs]                                                       2548.000000
 MD| Conserved quantity [hartree]                            -0.491114935203E+04
 MD| ---------------------------------------------------------------------------
 MD|                                          Instantaneous             Averages
 MD| CPU time per MD step [s]                    519.109287           587.455704
 MD| Energy drift per atom [K]           0.353456994903E+03   0.270292606536E+03
 MD| Potential energy [hartree]         -0.491152459524E+04  -0.491156142627E+04
 MD| Kinetic energy [hartree]            0.375243208319E+00   0.372037872089E+00
 MD| Temperature [K]                             999.934953           991.393486
 MD| ***************************************************************************

 Number of electrons:                                                       1632
 Number of occupied orbitals:                                                931
 Number of molecular orbitals:                                              1016

 Number of orbital functions:                                               3704
 Number of independent orbital functions:                                   3704

 Extrapolation method: ASPC


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00    6.6     0.01746708     -4911.5191700564 -4.91E+03
     2 Broy./Diag. 0.40E+00    7.1     0.04236523     -4911.6299172685 -1.11E-01
     3 Broy./Diag. 0.40E+00    6.9     0.04080150     -4911.2994328707  3.30E-01
     4 Broy./Diag. 0.40E+00    7.3     0.02764331     -4911.5935596090 -2.94E-01
     5 Broy./Diag. 0.40E+00    6.9     0.01973653     -4911.5688544446  2.47E-02
     6 Broy./Diag. 0.40E+00    7.0     0.00860617     -4911.4974374064  7.14E-02
     7 Broy./Diag. 0.40E+00    7.0     0.00471099     -4911.5284479215 -3.10E-02
     8 Broy./Diag. 0.40E+00    7.5     0.00282007     -4911.5201092057  8.34E-03
     9 Broy./Diag. 0.40E+00    6.7     0.00180512     -4911.5311687431 -1.11E-02
    10 Broy./Diag. 0.40E+00    7.1     0.00148618     -4911.5168405680  1.43E-02
    11 Broy./Diag. 0.40E+00    7.3     0.00185894     -4911.5218027895 -4.96E-03
    12 Broy./Diag. 0.40E+00    7.3     0.00107080     -4911.5256074298 -3.80E-03
    13 Broy./Diag. 0.40E+00    7.3     0.00044325     -4911.5206892815  4.92E-03
    14 Broy./Diag. 0.40E+00    7.1     0.00039536     -4911.5218422838 -1.15E-03
    15 Broy./Diag. 0.40E+00    7.1     0.00028628     -4911.5211667611  6.76E-04
    16 Broy./Diag. 0.40E+00    6.9     0.00024788     -4911.5229471896 -1.78E-03
    17 Broy./Diag. 0.40E+00    7.7     0.00038314     -4911.5212592595  1.69E-03
    18 Broy./Diag. 0.40E+00    6.7     0.00036212     -4911.5206544956  6.05E-04
    19 Broy./Diag. 0.40E+00    7.1     0.00022575     -4911.5220966358 -1.44E-03
    20 Broy./Diag. 0.40E+00    7.1     0.00022115     -4911.5212323285  8.64E-04
    21 Broy./Diag. 0.40E+00    7.5     0.00014364     -4911.5216201791 -3.88E-04
    22 Broy./Diag. 0.40E+00    6.7     0.00010564     -4911.5208162080  8.04E-04
    23 Broy./Diag. 0.40E+00    7.1     0.00015139     -4911.5213988266 -5.83E-04
    24 Broy./Diag. 0.40E+00    7.2     0.00015029     -4911.5215873769 -1.89E-04
    25 Broy./Diag. 0.40E+00    6.9     0.00008604     -4911.5209727316  6.15E-04
    26 Broy./Diag. 0.40E+00    6.9     0.00010410     -4911.5211930665 -2.20E-04
    27 Broy./Diag. 0.40E+00    7.1     0.00009875     -4911.5209778751  2.15E-04
    28 Broy./Diag. 0.40E+00    7.4     0.00006754     -4911.5213198248 -3.42E-04
    29 Broy./Diag. 0.40E+00    6.8     0.00008459     -4911.5209751552  3.45E-04
    30 Broy./Diag. 0.40E+00    8.0     0.00008544     -4911.5208575200  1.18E-04
    31 Broy./Diag. 0.40E+00    7.4     0.00004352     -4911.5211288492 -2.71E-04
    32 Broy./Diag. 0.40E+00    9.8     0.00003702     -4911.5209804449  1.48E-04
    33 Broy./Diag. 0.40E+00    8.2     0.00003587     -4911.5210733856 -9.29E-05
    34 Broy./Diag. 0.40E+00    7.8     0.00003030     -4911.5209271262  1.46E-04
    35 Broy./Diag. 0.40E+00   10.5     0.00003912     -4911.5210217886 -9.47E-05
    36 Broy./Diag. 0.40E+00    6.8     0.00005011     -4911.5210337837 -1.20E-05
    37 Broy./Diag. 0.40E+00    7.3     0.00003290     -4911.5208861479  1.48E-04
    38 Broy./Diag. 0.40E+00    7.3     0.00002282     -4911.5209848571 -9.87E-05
    39 Broy./Diag. 0.40E+00    6.9     0.00002413     -4911.5208876611  9.72E-05
    40 Broy./Diag. 0.40E+00    7.6     0.00001694     -4911.5209794387 -9.18E-05
    41 Broy./Diag. 0.40E+00    7.8     0.00001571     -4911.5209300526  4.94E-05
    42 Broy./Diag. 0.40E+00    7.1     0.00002076     -4911.5209091111  2.09E-05
    43 Broy./Diag. 0.40E+00    8.0     0.00001681     -4911.5209517686 -4.27E-05
    44 Broy./Diag. 0.40E+00    9.0     0.00001103     -4911.5208962155  5.56E-05
    45 Broy./Diag. 0.40E+00    7.7     0.00001361     -4911.5209366172 -4.04E-05
    46 Broy./Diag. 0.40E+00    9.7     0.00001183     -4911.5208827131  5.39E-05
    47 Broy./Diag. 0.40E+00    7.9     0.00001007     -4911.5209025533 -1.98E-05
    48 Broy./Diag. 0.40E+00    7.3     0.00001246     -4911.5209095353 -6.98E-06

 *** SCF run terminated - exceeded requested execution time:   84600.000 seconds.

 *** Execution time now:    84604.484 seconds.

  Leaving inner SCF loop after reaching    48 steps.


  Electronic density on regular grids:      -1631.9999999994        0.0000000006
  Core density on regular grids:             1631.9999999973       -0.0000000027
  Total charge density on r-space grids:       -0.0000000021
  Total charge density g-space grids:          -0.0000000021

  Overlap energy of the core charge distribution:               0.00008267414570
  Self energy of the core charge distribution:              -8663.09042251004757
  Core Hamiltonian energy:                                   2749.75777985380364
  Hartree energy:                                            1781.48108711311102
  Exchange-correlation energy:                               -779.43057818953639
  Electronic entropic energy:                                  -0.23885832025094
  Fermi energy:                                                 0.08698135123960

  Total energy:                                             -4911.52090953534935

 *** WARNING in qs_scf.F:576 :: SCF run NOT converged ***


 ENERGY| Total FORCE_EVAL ( QS ) energy [a.u.]:            -4911.520870597699286

 *** MD run terminated - exceeded requested execution time:   84600.000 seconds.

 *** Execution time now:    84608.323 seconds.

 -------------------------------------------------------------------------------
 -                                                                             -
 -                                DBCSR STATISTICS                             -
 -                                                                             -
 -------------------------------------------------------------------------------
 COUNTER                                    TOTAL       BLAS       SMM       ACC
 flops    13 x    24 x    13            387039744     100.0%      0.0%      0.0%
 flops    13 x    13 x    56           7036938272     100.0%      0.0%      0.0%
 flops    13 x    24 x    25          14364682800     100.0%      0.0%      0.0%
 flops    25 x    24 x    13          14364682800     100.0%      0.0%      0.0%
 flops    13 x    32 x    13          15997642752     100.0%      0.0%      0.0%
 flops    13 x    13 x    32          16084430336     100.0%      0.0%      0.0%
 flops    13 x    13 x    64         104548797184     100.0%      0.0%      0.0%
 flops    25 x    13 x    56         225431715600     100.0%      0.0%      0.0%
 flops    13 x    25 x    56         230981951200     100.0%      0.0%      0.0%
 flops    25 x    13 x    32         515272492800     100.0%      0.0%      0.0%
 flops    13 x    25 x    32         527958745600     100.0%      0.0%      0.0%
 flops    25 x    24 x    25         538099200000     100.0%      0.0%      0.0%
 flops    13 x    32 x    25         593740222400     100.0%      0.0%      0.0%
 flops    25 x    32 x    13         593740222400     100.0%      0.0%      0.0%
 flops    25 x    13 x    64        3349271203200     100.0%      0.0%      0.0%
 flops    13 x    25 x    64        3431731846400     100.0%      0.0%      0.0%
 flops    25 x    25 x    56        8609554800000     100.0%      0.0%      0.0%
 flops    25 x    25 x    32       19678982400000     100.0%      0.0%      0.0%
 flops    25 x    32 x    25       22241433600000     100.0%      0.0%      0.0%
 flops    25 x    25 x    64      127913385600000     100.0%      0.0%      0.0%
 flops inhomo. stacks                           0       0.0%      0.0%      0.0%
 flops total                       188.622368E+12     100.0%      0.0%      0.0%
 flops max/rank                      2.106146E+12     100.0%      0.0%      0.0%
 matmuls inhomo. stacks                         0       0.0%      0.0%      0.0%
 matmuls total                         3080707814     100.0%      0.0%      0.0%
 number of processed stacks              60734950     100.0%      0.0%      0.0%
 average stack size                                    50.7       0.0       0.0
 marketing flops                   325.087618E+12
 -------------------------------------------------------------------------------
 # multiplications                          12646
 max memory usage/rank             222.113792E+06
 # max total images/rank                        3
 # max 3D layers                                1
 # MPI messages exchanged                43704576
 MPI messages size (bytes):
  total size                         9.541009E+12
  min size                          51.200000E+03
  max size                           1.088856E+06
  average size                     218.306859E+03
 MPI breakdown and total messages size (bytes):
             size <=      128                   0                        0
       128 < size <=     8192                   0                        0
      8192 < size <=    32768                   0                        0
     32768 < size <=   131072            20486520            1903609461760
    131072 < size <=  4194304            23218056            7636672674832
   4194304 < size <= 16777216                   0                        0
  16777216 < size                               0                        0
 -------------------------------------------------------------------------------

 *** WARNING in dbcsr_mm.F:294 :: Using a non-square number of MPI ranks ***
 *** might lead to poor performance. Used ranks: 108 Suggested: 100 225  ***

 -------------------------------------------------------------------------------
 -                                                                             -
 -                      DBCSR MESSAGE PASSING PERFORMANCE                      -
 -                                                                             -
 -------------------------------------------------------------------------------
 ROUTINE             CALLS      AVE VOLUME [Bytes]
 MP_Bcast               21                     12.
 MP_Allreduce        84772                      8.
 MP_Alltoall        345933                 271948.
 MP_ISend           910512                 105809.
 MP_IRecv           910512                 101693.
 -------------------------------------------------------------------------------

 -------------------------------------------------------------------------------
 -                                                                             -
 -                                GRID STATISTICS                              -
 -                                                                             -
 -------------------------------------------------------------------------------
 LP    KERNEL             BACKEND                              COUNT     PERCENT
 6     collocate ortho    REF                             1456675780      47.46%
 6     integrate ortho    REF                             1435664265      46.78%
 5     collocate ortho    REF                               71097336       2.32%
 5     integrate ortho    REF                               70077393       2.28%
 7     integrate ortho    REF                               22090231       0.72%
 4     collocate ortho    REF                                3878008       0.13%
 4     integrate ortho    REF                                3819235       0.12%
 0     collocate general  REF                                2889216       0.09%
 1     integrate general  REF                                2889216       0.09%
 -------------------------------------------------------------------------------

 MEMORY| Estimated peak process memory [MiB]                                 212

 -------------------------------------------------------------------------------
 -                                                                             -
 -                         MESSAGE PASSING PERFORMANCE                         -
 -                                                                             -
 -------------------------------------------------------------------------------

 ROUTINE             CALLS      AVE VOLUME [Bytes]
 MP_Group                4
 MP_Bcast            23583                   8352.
 MP_Allreduce       124549                    200.
 MP_Sync                 4
 MP_Alltoall        246190                5201608.
 MP_SendRecv         46424                 460800.
 MP_ISendRecv      4967368                  33700.
 MP_Wait           7258336
 MP_ISend          2057440                 213720.
 MP_IRecv          2057440                 213720.
 -------------------------------------------------------------------------------


 -------------------------------------------------------------------------------
 -                                                                             -
 -                           R E F E R E N C E S                               -
 -                                                                             -
 -------------------------------------------------------------------------------
 
 CP2K version 8.1, the CP2K developers group (2020).
 CP2K is freely available from https://www.cp2k.org/ .

 Kuehne,Thomas D.; Iannuzzi,Marcella; Del Ben,Mauro;
 Rybkin,Vladimir V.; Seewald,Patrick; Stein,Frederick; Laino,Teodoro;
 Khaliullin,Rustam Z.; Schuett,Ole; Schiffmann,Florian; Golze,Dorothea;
 Wilhelm,Jan; Chulkov,Sergey; Bani-Hashemian,Mohammad Hossein;
 Weber,Valery; Borstnik,Urban; Taillefumier,Mathieu;
 Jakobovits,Alice Shoshana; Lazzaro,Alfio; Pabst,Hans; Mueller,Tiziano;
 Schade,Robert; Guidon,Manuel; Andermatt,Samuel; Holmberg,Nico;
 Schenter,Gregory K.; Hehn,Anna; Bussy,Augustin; Belleflamme,Fabian;
 Tabacchi,Gloria; Gloess,Andreas; Lass,Michael; Bethune,Iain;
 Mundy,Christopher J.; Plessl,Christian; Watkins,Matt;
 VandeVondele,Joost; Krack,Matthias; Hutter,Juerg. 
 The Journal of Chemical Physics, 152 (19), (2020). 
 CP2K: An electronic structure and molecular dynamics software package -
 Quickstep: Efficient and accurate electronic structure calculations.
 https://doi.org/10.1063/5.0007045

 Schuett, Ole; Messmer, Peter; Hutter, Juerg; VandeVondele, Joost. 
 Electronic Structure Calculations on Graphics Processing Units, John
 Wiley & Sons, Ltd, 173-190 (2016). 
 GPU-Accelerated Sparse Matrix-Matrix Multiplication for
 Linear Scaling Density Functional Theory.
 https://doi.org/10.1002/9781118670712.ch8

 Borstnik, U; VandeVondele, J; Weber, V; Hutter, J. 
 PARALLEL COMPUTING, 40 (5-6), 47-58 (2014). 
 Sparse matrix multiplication: The distributed block-compressed sparse
 row library.
 https://doi.org/10.1016/j.parco.2014.03.012

 Hutter, J; Iannuzzi, M; Schiffmann, F; VandeVondele, J. 
 WIREs Comput Mol Sci., 4 (1), 15-25 (2014). 
 CP2K: atomistic simulations of condensed matter systems.
 https://doi.org/10.1002/wcms.1159

 Marek, A; Blum, V; Johanni, R; Havu, V; Lang, B; Auckenthaler, T;
 Heinecke, A; Bungartz, H; Lederer, H. 
 Journal of Physics: Condensed Matter, 26 (21), (2014). 
 The ELPA library: scalable parallel eigenvalue solutions for
 electronic structure
 theory and computational science.
 https://doi.org/10.1088/0953-8984/26/21/213201

 VandeVondele, J; Hutter, J. 
 JOURNAL OF CHEMICAL PHYSICS, 127 (11), 114105 (2007). 
 Gaussian basis sets for accurate calculations on molecular systems in
 gas and condensed phases.
 https://doi.org/10.1063/1.2770708

 Kuhne, TD; Krack, M; Mohamed, FR; Parrinello, M. 
 PHYSICAL REVIEW LETTERS, 98 (6), 066401 (2007). 
 Efficient and accurate Car-Parrinello-like approach to
 Born-Oppenheimer molecular dynamics.
 https://doi.org/10.1103/PhysRevLett.98.066401

 Krack, M. 
 THEORETICAL CHEMISTRY ACCOUNTS, 114 (1-3), 145-152 (2005). 
 Pseudopotentials for H to Kr optimized for gradient-corrected
 exchange-correlation functionals.
 https://doi.org/10.1007/s00214-005-0655-y

 VandeVondele, J; Krack, M; Mohamed, F; Parrinello, M; Chassaing, T;
 Hutter, J. COMPUTER PHYSICS COMMUNICATIONS, 167 (2), 103-128 (2005). 
 QUICKSTEP: Fast and accurate density functional calculations using a
 mixed Gaussian and plane waves approach.
 https://doi.org/10.1016/j.cpc.2004.12.014

 Frigo, M; Johnson, SG. 
 PROCEEDINGS OF THE IEEE, 93 (2), 216-231 (2005). 
 The design and implementation of FFTW3.
 https://doi.org/10.1109/JPROC.2004.840301

 Kolafa, J. 
 JOURNAL OF COMPUTATIONAL CHEMISTRY, 25 (3), 335-342 (2004). 
 Time-reversible always stable predictor-corrector method for molecular dynamics of polarizable molecules.
 https://doi.org/10.1002/jcc.10385

 Ricci, A; Ciccotti, G. 
 MOLECULAR PHYSICS, 101 (12), 1927-1931 (2003). 
 Algorithms for Brownian dynamics.
 https://doi.org/10.1080/0026897031000108113

 Hartwigsen, C; Goedecker, S; Hutter, J. 
 PHYSICAL REVIEW B, 58 (7), 3641-3662 (1998). 
 Relativistic separable dual-space Gaussian pseudopotentials from H to Rn.
 https://doi.org/10.1103/PhysRevB.58.3641

 Lippert, G; Hutter, J; Parrinello, M. 
 MOLECULAR PHYSICS, 92 (3), 477-487 (1997). 
 A hybrid Gaussian and plane wave density functional scheme.
 https://doi.org/10.1080/002689797170220

 Perdew, JP; Burke, K; Ernzerhof, M. 
 PHYSICAL REVIEW LETTERS, 77 (18), 3865-3868 (1996). 
 Generalized gradient approximation made simple.
 https://doi.org/10.1103/PhysRevLett.77.3865

 Goedecker, S; Teter, M; Hutter, J. 
 PHYSICAL REVIEW B, 54 (3), 1703-1710 (1996). 
 Separable dual-space Gaussian pseudopotentials.
 https://doi.org/10.1103/PhysRevB.54.1703


 -------------------------------------------------------------------------------
 -                                                                             -
 -                                T I M I N G                                  -
 -                                                                             -
 -------------------------------------------------------------------------------
 SUBROUTINE                       CALLS  ASD         SELF TIME        TOTAL TIME
                                MAXIMUM       AVERAGE  MAXIMUM  AVERAGE  MAXIMUM
 CP2K                                 1  1.0     0.59     0.63 84609.11 84609.16
 qs_mol_dyn_low                       1  2.0     0.11     0.14 84607.44 84607.44
 qs_forces                          176  4.0     0.08     0.10 84603.59 84603.61
 qs_energies                        176  5.0     0.13     0.16 84034.70 84035.70
 velocity_verlet                    175  3.0     0.16     0.19 83902.39 83902.45
 scf_env_do_scf                     176  6.0     0.06     0.08 83186.90 83187.03
 scf_env_do_scf_inner_loop        11430  7.0     0.52     1.60 83186.42 83186.52
 qs_scf_new_mos                   11430  8.0     0.18     0.24 55843.31 55907.93
 eigensolver                      11430  9.0     0.51     0.85 53578.63 53594.29
 cp_fm_diag_elpa                  11605 10.0     0.05     0.07 40196.31 40345.84
 cp_fm_diag_elpa_base             11605 11.0 39836.86 40226.19 40196.24 40345.75
 rebuild_ks_matrix                11606  8.9     0.04     0.05 17145.78 17149.72
 qs_ks_build_kohn_sham_matrix     11606  9.9     1.17     1.28 17145.74 17149.68
 qs_ks_update_qs_env              11430  8.0     0.06     0.07 16816.69 16820.60
 cp_fm_triangular_multiply        34290 10.0 13239.60 13526.52 13239.60 13526.52
 rs_pw_transfer                   93200 12.5     1.06     1.23 11295.57 11510.33
 sum_up_and_integrate             11606 10.9     5.42     6.86  9901.93  9908.04
 integrate_v_rspace               11606 11.9     0.26     0.29  9896.50  9902.92
 qs_rho_update_rho                11606  8.0     0.06     0.08  9674.55  9676.51
 calculate_rho_elec               11606  9.0     6.45     8.67  9674.49  9676.44
 pw_transfer                     243550 12.5    11.00    12.46  9486.66  9551.21
 fft_wrap_pw1pw2                 220338 13.5     1.88     2.11  9453.78  9516.82
 mp_waitany                     2057440 14.5  9093.61  9301.48  9093.61  9301.48
 fft3d_ps                        220338 15.5   903.70  1089.75  8965.26  9053.85
 fft_wrap_pw1pw2_250             150702 14.6   164.79   193.14  8828.45  8882.73
 mp_alltoall_z22v                220338 17.5  7824.99  7989.05  7824.99  7989.05
 density_rs2pw                    11606 10.0     0.45     0.52  6961.08  7191.18
 potential_pw2rs                  11606 12.9     0.94     1.07  6975.87  6979.02
 qs_vxc_create                    11606 10.9     0.17     0.20  6452.62  6461.47
 xc_vxc_pw_create                 11606 11.9    20.13    23.71  6452.46  6461.28
 x_to_yz                         115708 16.8   143.57   202.53  4123.92  4151.57
 yz_to_x                         104630 16.3    86.09    92.29  3930.72  4049.15
 xc_rho_set_and_dset_create       11606 12.9     8.36     8.87  3384.35  3586.05
 rs_pw_transfer_PW2RS_90          11606 14.9    41.63    44.17  2919.49  3011.09
 rs_pw_transfer_RS2PW_250         11782 12.0   193.80   233.45  2412.78  2636.53
 grid_collocate_task_list         11606 10.0  2340.87  2625.94  2340.87  2625.94
 grid_integrate_task_list         11606 12.9  2270.40  2559.85  2270.40  2559.85
 rs_pw_transfer_PW2RS_250         11782 14.9   233.27   242.08  2265.33  2351.70
 mp_alltoall_d11v                171495 12.3  2015.81  2245.61  2015.81  2245.61
 rs_pw_transfer_RS2PW_90          11606 12.0    57.05    62.88  2125.46  2145.20
 mp_waitall_1                   6617248 14.6  1673.74  1889.34  1673.74  1889.34
 -------------------------------------------------------------------------------

 The number of warnings for this run is : 3
 
 -------------------------------------------------------------------------------
  **** **** ******  **  PROGRAM ENDED AT                 2022-06-08 03:40:16.152
 ***** ** ***  *** **   PROGRAM RAN ON                                    acc104
 **    ****   ******    PROGRAM RAN BY                                 icre12895
 ***** **    ** ** **   PROGRAM PROCESS ID                                 89786
  **** **  *******  **  PROGRAM STOPPED IN /ws/icre12/copy/AIMD/NONE-WITHOUT/CON
                                           T/Continue
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