[CP2K:2037] optimisation problem of F compound

Fawzi Mohamed fa... at gmx.ch
Thu Apr 23 19:50:22 UTC 2009


I would say that the cutoff of 500 might be too small for the F  
element. Have you tested the cutoff needed for it?

Fawzi
On 23-apr-09, at 18:12, Jörg Saßmannshausen wrote:

> Dear all,
>
> I am struggling to optimise a molecular structure with a F atom in it.
> Whereas I manage to get the optimisation converged, the frequency
> calculation clearly indicates I am not at the local minimum. Replacing
> the F atom in the molecule with H (and leave everything else the same)
> results in a converged structure. I got the gutt-feeling that the
> problem is the basis set / pseudopotential I am using for F. Would
> somebody mind to give me a helping hand here?
>
> I have enclosed the following files:
> - mol file of the frequency calculation (so you see what I mean)
> - force_eval section
> - subsys section
> - fluor-geo.inp
> - fluor-freq.inp
>
> I had no problems with the molecule using a different program, so I am
> quite confident about the structure. Note: it is a cation, I left the
> anion out for computational reasons.
>
> Thanks for your help!
>
> Jörg
>
>
>
> -- 
> *************************************************************
> Jörg Saßmannshausen
> Research Fellow
> University of Strathclyde
> Department of Pure and Applied Chemistry
> 295 Cathedral St.
> Glasgow
> G1 1XL
>
> email: jorg.sassm... at strath.ac.uk
> web: http://sassy.formativ.net
>
> Please avoid sending me Word or PowerPoint attachments.
> See http://www.gnu.org/philosophy/no-word-attachments.html
>
>
> >
> ! -*- cp2k -*-
>
> ! Possibly restart (if explicitly requested)
> @IF 1
> &EXT_RESTART ON
>  RESTART_DEFAULT F
>  RESTART_FILE_NAME FLUORGEOM-cat-1-1.restart
>  RESTART_POS T
>  RESTART_COUNTERS T
> &END EXT_RESTART
> @ENDIF
>
> &GLOBAL
>  PROJECT  FLUORGEOM-cat-1
>  RUN_TYPE NORMAL_MODES
>  PRINT_LEVEL LOW
> &END GLOBAL
>
> &VIBRATIONAL_ANALYSIS
>   NPROC_REP 4
>   DX 0.001
>   &PRINT
>     &PROGRAM_RUN_INFO ON
>     &END
>     &MOLDEN_VIB
> !      FILENAME=frequencies.mol
>     &END
>   &END
>
> &END
>
> @INCLUDE 'force_eval.inc'
> ! -*- cp2k -*-
>
> ! Possibly restart (if explicitly requested)
> @IF 0
> &EXT_RESTART ON
>  RESTART_DEFAULT F
>  RESTART_FILE_NAME GEOMETRY-1.restart
>  RESTART_POS T
>  RESTART_COUNTERS T
> &END EXT_RESTART
> @ENDIF
>
> &GLOBAL
>  PROJECT  FLUORGEOM-cat-1
>  RUN_TYPE GEO_OPT
>  PRINT_LEVEL LOW
> &END GLOBAL
>
> &MOTION
>  &GEO_OPT
>    MINIMIZER BFGS
>    MAX_ITER   300
>    MAX_DR     3.00E-4
>    RMS_DR     1.50E-4
>    MAX_FORCE  4.50E-5
>    RMS_FORCE  3.00E-5
>    &BFGS
>    &END
>  &END GEO_OPT
>
>  &PRINT
>    &RESTART
>      LOG_PRINT_KEY T
>      &EACH
>        GEO_OPT 5
>      &END EACH
>      ADD_LAST NUMERIC
>    &END RESTART
>
>    &TRAJECTORY
>      LOG_PRINT_KEY T
>      FORMAT XYZ
>      &EACH
>        GEO_OPT 5
>      &END EACH
>      ADD_LAST NUMERIC
>    &END TRAJECTORY
>
>  &END PRINT
> &END MOTION
>
> @INCLUDE 'force_eval.inc'
> [Molden Format]
> [FREQ]
>     -274.409318
>      -57.992302
>      135.560409
>      186.170853
>      238.725327
>      357.486039
>      395.439424
>      409.902389
>      414.706174
>      419.210285
>      459.032418
>      465.347279
>      598.487557
>      655.381027
>      779.314037
>      784.697746
>      786.373971
>      810.393240
>      894.399628
>      898.196794
>      953.267199
>      953.876508
>      956.257316
>      962.101306
>      966.949993
>      968.971747
>      991.688123
>     1107.055816
>     1108.650040
>     1119.887480
>     1122.085459
>     1161.283534
>     1215.065563
>     1215.662228
>     1252.367400
>     1253.951906
>     1261.728188
>     1261.910793
>     1304.225192
>     1309.977360
>     1311.971137
>     1330.994678
>     1412.769171
>     1412.858912
>     1427.901347
>     1428.064447
>     1436.240241
>     1471.377403
>     3040.541421
>     3040.646057
>     3045.360349
>     3057.620692
>     3057.808489
>     3061.322192
>     3103.286410
>     3107.877236
>     3107.987765
>     3124.837066
>     3129.048992
>     3129.342494
> [FR-COORD]
> C       22.166876      18.598207      10.585820
> C       25.105156      18.619118      10.593103
> H       21.369889      19.057006       8.711827
> H       21.357665      19.899948      12.002958
> H       25.944138      19.059974       8.729855
> H       25.929634      19.883362      12.039488
> C       22.167427      14.078066       9.315559
> H       21.370629      12.225396       9.854412
> H       21.358712      14.654770       7.479677
> C       25.105683      14.074079       9.294884
> H       25.944098      12.240094       9.845829
> H       25.931441      14.694126       7.477313
> C       25.105335      15.222588      13.879855
> H       25.930958      13.338531      14.252415
> H       25.942903      16.617217      15.192703
> C       22.166999      15.237908      13.865063
> H       21.358330      13.359546      14.283999
> H       21.369665      16.631116      15.199400
> N       25.952304      15.971741      11.255974
> N       21.097260      15.971151      11.255540
> O       18.591768      15.970888      11.255521
> F       28.651385      15.971159      11.255076
> [FR-NORM-COORD]
> vibration      1
>    -0.002106       0.022607       0.134629
>    -0.006541       0.057738       0.217092
>     0.051657       0.062908       0.121556
>    -0.069764      -0.029286       0.143256
>     0.020921       0.132542       0.247700
>    -0.037352       0.008301       0.278757
>     0.047620      -0.006553       0.112705
>     0.027108       0.007382       0.127209
>     0.068181      -0.045701       0.092148
>    -0.004739       0.022684       0.180821
>     0.028014       0.051136       0.226807
>     0.036416       0.002605       0.192601
>     0.016624       0.070342       0.171386
>     0.015925       0.080707       0.224861
>    -0.032887       0.109920       0.162267
>    -0.031558       0.026375       0.103357
>     0.009839       0.008243       0.105646
>    -0.068821       0.031064       0.076977
>    -0.005290       0.034345       0.118998
>     0.006868      -0.007006      -0.000246
>     0.006657      -0.060827      -0.385926
>    -0.021584      -0.113345      -0.450279
> vibration      2
>    -0.000437       0.027945       0.109234
>     0.000779      -0.026647      -0.108084
>    -0.119617       0.163559       0.193450
>     0.117319      -0.050644       0.249060
>    -0.123835      -0.161674      -0.196021
>     0.126924       0.051241      -0.247968
>    -0.000595       0.079300      -0.076589
>    -0.117486       0.084286      -0.233380
>     0.114583       0.237051      -0.078078
>     0.000598      -0.078747       0.075724
>    -0.121778      -0.087063       0.233874
>     0.123864      -0.236563       0.077812
>     0.000298       0.105651       0.029705
>     0.124136       0.186601       0.164892
>    -0.121372       0.246695      -0.042632
>    -0.000689      -0.105798      -0.028874
>     0.115186      -0.186063      -0.163588
>    -0.116986      -0.243560       0.044981
>    -0.000057       0.000055      -0.000654
>     0.000046      -0.000084       0.000536
>    -0.000058      -0.001064      -0.001759
>     0.000036      -0.000365       0.000735
> vibration      3
>     0.001537      -0.028170       0.146764
>    -0.026395      -0.097568      -0.078995
>    -0.139056       0.097269       0.238071
>     0.127127      -0.092242       0.277623
>    -0.160485      -0.191920      -0.161461
>     0.120844      -0.056198      -0.199635
>    -0.027684      -0.093220       0.136894
>    -0.000711      -0.062844       0.282426
>    -0.108483      -0.203828       0.137765
>    -0.005087      -0.099038      -0.019732
>     0.027724      -0.094758      -0.055472
>    -0.121485      -0.099744      -0.072282
>     0.028214      -0.150945      -0.055955
>    -0.016700      -0.194433      -0.173774
>     0.122397      -0.242538      -0.018911
>     0.012666      -0.047446       0.079192
>    -0.028598      -0.022144       0.113242
>     0.135435      -0.014410       0.118996
>     0.006661      -0.059785      -0.052016
>    -0.007620       0.015849       0.047978
>    -0.008663       0.205084      -0.226312
>     0.020819       0.248641       0.036140
> vibration      4
>    -0.002778       0.061449       0.143214
>     0.021779       0.037964      -0.116542
>    -0.152749       0.201972       0.241819
>     0.137621      -0.029202       0.307650
>    -0.147560      -0.064330      -0.217007
>     0.163621       0.099309      -0.250705
>    -0.000683       0.014495       0.083367
>     0.090988       0.006170       0.191171
>    -0.152109      -0.070948       0.123997
>    -0.013069       0.107976      -0.119681
>     0.082294       0.104009      -0.278827
>    -0.150950       0.244824      -0.135523
>    -0.007191       0.070340      -0.057880
>    -0.014188       0.063749      -0.075821
>     0.074964       0.062121      -0.101208
>     0.007447       0.094453       0.075001
>     0.011161       0.118150       0.188059
>     0.070486       0.159509       0.044869
>    -0.001513       0.031244      -0.070162
>     0.002094      -0.006172       0.050256
>     0.001316      -0.175574      -0.133276
>    -0.005738      -0.162593       0.120144
> vibration      5
>     0.032306      -0.053680      -0.018704
>     0.029972       0.044150       0.002126
>     0.027951      -0.109409      -0.030406
>    -0.022552      -0.056713      -0.047702
>     0.035844       0.077711       0.012659
>    -0.018125       0.049949       0.024413
>    -0.017374      -0.117884       0.068497
>     0.133256      -0.134851       0.234981
>    -0.130530      -0.302965       0.060594
>    -0.017889       0.087786      -0.052194
>     0.135884       0.115244      -0.194046
>    -0.143831       0.242603      -0.056523
>    -0.012130       0.113354       0.014606
>     0.165949       0.218257       0.151383
>    -0.170025       0.277619      -0.059417
>    -0.011718      -0.162827      -0.028624
>     0.155096      -0.275346      -0.207902
>    -0.161075      -0.353998       0.080845
>    -0.002114       0.048838      -0.006242
>     0.002270      -0.038253       0.004358
>     0.003287       0.142086      -0.002492
>    -0.005302      -0.057765       0.014175
> vibration      6
>    -0.015510      -0.031562      -0.083970
>    -0.009844       0.020752       0.079522
>     0.088835      -0.219345      -0.174985
>    -0.116253       0.092200      -0.255833
>     0.087552       0.210188       0.167738
>    -0.125634      -0.091058       0.242371
>    -0.150771       0.095435       0.010222
>    -0.235090       0.096157      -0.112133
>    -0.119216       0.235104       0.039480
>    -0.133460      -0.047581       0.001860
>    -0.245394      -0.074511       0.079066
>    -0.123249      -0.178548      -0.037847
>     0.143786       0.056012      -0.024782
>     0.239674       0.108275       0.030646
>     0.146343       0.144893      -0.120401
>     0.155456      -0.047506       0.064195
>     0.233504      -0.092486       0.013009
>     0.143754      -0.116901       0.128943
>     0.008145      -0.008757      -0.048604
>    -0.008568       0.001222       0.027049
>    -0.010977      -0.038948      -0.129513
>     0.017432       0.003511       0.095214
> vibration      7
>    -0.185852      -0.113776       0.011746
>    -0.180513       0.061870      -0.039671
>    -0.253150      -0.174256       0.025527
>    -0.245545      -0.143835       0.005249
>    -0.249083       0.071047      -0.067640
>    -0.239042       0.136960      -0.072880
>     0.124564      -0.007081      -0.097413
>     0.090189      -0.040742      -0.267545
>     0.185937       0.159287      -0.072078
>     0.095641       0.012056       0.028783
>     0.106715       0.057799       0.164669
>     0.202153      -0.059056       0.051731
>     0.076354      -0.031849      -0.014532
>     0.076274      -0.066653      -0.189139
>     0.182342      -0.133011       0.027208
>     0.106100       0.022538       0.090144
>     0.061930       0.073817       0.230643
>     0.165293       0.145023      -0.002308
>    -0.038548       0.070333      -0.005955
>     0.043060      -0.044044       0.017359
>     0.053149       0.191409      -0.028034
>    -0.075490      -0.146418       0.037280
> vibration      8
>    -0.015945       0.028474       0.124292
>    -0.011418       0.057466       0.152452
>    -0.004896       0.191799       0.160399
>    -0.035818      -0.104262       0.236194
>     0.014412       0.376334       0.239939
>    -0.055740      -0.170481       0.377818
>     0.027617      -0.115657      -0.018254
>     0.002926      -0.076691       0.081668
>     0.025507      -0.179485      -0.037123
>     0.032633      -0.158023      -0.028122
>     0.017002      -0.105977       0.176774
>     0.062772      -0.334692      -0.076460
>    -0.020347       0.107378      -0.128839
>    -0.012289       0.140747       0.010033
>    -0.037140       0.189326      -0.207829
>    -0.017578       0.081162      -0.076816
>     0.010350       0.094568       0.034841
>     0.001045       0.125940      -0.111973
>     0.005265      -0.012111      -0.123132
>    -0.005730      -0.009672      -0.032364
>    -0.006757       0.021523       0.030380
>     0.009847      -0.010378       0.026516
> vibration      9
>    -0.054152      -0.132901       0.045144
>    -0.031369      -0.181018       0.054649
>    -0.013507      -0.057827       0.045920
>    -0.006651      -0.102816       0.045124
>    -0.067253      -0.131279       0.053088
>    -0.064259      -0.149309       0.042182
>     0.001936       0.037438      -0.104704
>     0.029906      -0.011676      -0.232582
>     0.003622       0.158518      -0.068912
>     0.031793       0.045708      -0.138606
>     0.046971      -0.029522      -0.409637
>    -0.016177       0.303272      -0.074138
>     0.016599       0.116205       0.096679
>     0.021269       0.175521       0.387357
>    -0.039267       0.316113      -0.078048
>    -0.015856       0.101138       0.050266
>     0.005554       0.127787       0.209467
>    -0.015801       0.207400      -0.058635
>     0.062277      -0.117865       0.029804
>    -0.069590      -0.032424       0.000336
>    -0.084978       0.055711      -0.001278
>     0.115362       0.029604      -0.015947
> vibration     10
>     0.117485       0.043034       0.004594
>     0.009716      -0.081468       0.044613
>     0.082014       0.021271       0.016303
>     0.071911      -0.003325       0.018873
>     0.126905      -0.108559       0.091715
>     0.108084      -0.214107       0.103548
>     0.036174      -0.034146      -0.105340
>    -0.047706       0.014598      -0.068369
>    -0.083974       0.066743      -0.019664
>    -0.045669      -0.063484      -0.180323
>     0.048161      -0.067060      -0.328963
>    -0.013897       0.189396      -0.081696
>    -0.026686       0.069024       0.136239
>     0.087116       0.155127       0.325358
>     0.010734       0.290044      -0.120352
>     0.061291       0.037801       0.100537
>    -0.005127       0.061897       0.070346
>    -0.046951       0.088665      -0.018739
>    -0.202538      -0.126415       0.002432
>     0.228550       0.002172      -0.001049
>     0.279453      -0.021979      -0.002005
>    -0.368705       0.102349       0.001085
> vibration     11
>    -0.030761       0.036933       0.038082
>    -0.027318      -0.005168       0.018146
>    -0.072255       0.398159       0.142031
>     0.023046      -0.219666       0.303543
>    -0.061490      -0.174736      -0.036342
>     0.014960       0.114832      -0.110615
>    -0.122448      -0.104909      -0.062493
>    -0.049343      -0.075711       0.153734
>    -0.108955      -0.356157      -0.151520
>    -0.113149       0.043824       0.063157
>    -0.065596       0.036114      -0.040487
>    -0.116309       0.152511       0.101267
>     0.139142      -0.020071       0.085195
>     0.101701      -0.049753       0.029110
>     0.126788      -0.064901       0.144404
>     0.153439       0.052516      -0.133641
>     0.083505       0.106182      -0.043370
>     0.119505       0.150946      -0.262763
>    -0.001623       0.014016       0.124116
>     0.002293      -0.017308      -0.208062
>     0.002595       0.003703       0.019580
>    -0.001751      -0.003612       0.027912
> vibration     12
>     0.162356      -0.149641       0.046079
>     0.144585       0.087666      -0.018359
>     0.099694      -0.127312       0.082087
>     0.111823      -0.236953       0.091612
>     0.111131       0.067179      -0.040710
>     0.126113       0.123991      -0.036213
>    -0.102539      -0.049168      -0.097857
>    -0.106978      -0.137234      -0.394468
>    -0.030178       0.219583      -0.046915
>    -0.093591       0.047312       0.033622
>    -0.101418       0.086193       0.167875
>    -0.045477      -0.078674       0.013707
>    -0.053699       0.020862      -0.023416
>    -0.080847      -0.021902      -0.186558
>    -0.008691      -0.105259       0.081376
>    -0.058130       0.024820       0.064002
>    -0.085496       0.112629       0.417224
>     0.005356       0.282145      -0.166526
>    -0.003190       0.119799      -0.007319
>     0.004186      -0.206546       0.016426
>     0.004898       0.031786      -0.001714
>    -0.003952       0.038878      -0.006916
> vibration     13
>    -0.103643      -0.147823       0.037441
>    -0.110686       0.013086      -0.002514
>    -0.193381      -0.207172       0.061779
>    -0.193015      -0.213701       0.045927
>    -0.185821       0.069573      -0.020575
>    -0.186816       0.070094      -0.012066
>    -0.098467       0.107974       0.110974
>    -0.187300       0.158515       0.150281
>    -0.187461       0.146721       0.163131
>    -0.107650      -0.005897      -0.006415
>    -0.182125      -0.049013      -0.044923
>    -0.181805      -0.043262      -0.050377
>    -0.110871      -0.001903       0.011535
>    -0.186195      -0.022038       0.064391
>    -0.185322      -0.015279       0.069769
>    -0.102353       0.041737      -0.147069
>    -0.190499       0.066061      -0.211585
>    -0.194230       0.047661      -0.209184
>     0.040827       0.001455       0.000433
>     0.250316       0.000698      -0.000192
>     0.204684      -0.001566      -0.000167
>     0.133183      -0.005237      -0.002884
> vibration     14
>     0.073371      -0.244778       0.061961
>     0.052089      -0.241372       0.059689
>     0.147887      -0.156322       0.056433
>     0.150669      -0.166294       0.027769
>     0.009747      -0.203555       0.053518
>     0.013890      -0.205178       0.044703
>     0.067431       0.175305       0.179583
>     0.141603       0.128051       0.110846
>     0.141887       0.104184       0.129069
>     0.048880       0.168555       0.174593
>     0.003850       0.143771       0.146993
>     0.010439       0.134400       0.149434
>     0.050643       0.065650      -0.237539
>     0.013055       0.060759      -0.198611
>     0.009050       0.052356      -0.202436
>     0.071987       0.067355      -0.241956
>     0.145768       0.059326      -0.156441
>     0.147033       0.030858      -0.165427
>    -0.007350      -0.001119      -0.001553
>     0.012924       0.000330      -0.001035
>    -0.093534       0.001352       0.001108
>    -0.205322       0.006248       0.003515
> vibration     15
>     0.000230       0.009701       0.048143
>     0.000510       0.012534       0.039578
>     0.207208      -0.201912      -0.091008
>    -0.205852       0.128384      -0.177689
>    -0.215272      -0.149500      -0.094644
>     0.216137       0.094166      -0.152897
>    -0.000095       0.034914      -0.033569
>     0.203247       0.020972       0.217073
>    -0.205090      -0.215527      -0.022603
>     0.000371       0.026525      -0.031234
>    -0.211432      -0.007557       0.173651
>     0.214906      -0.176862      -0.004596
>     0.000905      -0.039176      -0.008492
>     0.210226       0.083080       0.152376
>    -0.208856       0.151193      -0.078562
>    -0.000110      -0.045009      -0.015084
>    -0.200571       0.087220       0.193497
>     0.201124       0.174364      -0.124698
>     0.001083       0.000616       0.000709
>     0.000241       0.000792       0.000767
>    -0.001666      -0.000135      -0.000144
>    -0.001023       0.000034      -0.000015
> vibration     16
>     0.000441       0.043437       0.057188
>    -0.009740       0.034842       0.056692
>     0.218386      -0.261482      -0.107419
>    -0.253225       0.192590      -0.221118
>    -0.247858      -0.243378      -0.113498
>     0.273694       0.163980      -0.213250
>     0.002850      -0.089612      -0.021016
>    -0.229602      -0.050016      -0.222177
>     0.127157       0.203114       0.018272
>    -0.024753      -0.072483      -0.005686
>     0.232648      -0.017990      -0.204590
>    -0.165267       0.197756       0.024104
>     0.034281       0.036775      -0.067147
>    -0.117541      -0.028433      -0.070774
>     0.022987      -0.057098       0.039137
>    -0.002927       0.046606      -0.098225
>     0.134333      -0.012371      -0.100303
>     0.002890      -0.062496       0.020429
>     0.000037      -0.001635       0.082202
>     0.000180       0.000247       0.090571
>    -0.000065       0.000024      -0.019706
>    -0.000127      -0.000005      -0.000271
> vibration     17
>    -0.003161      -0.093962       0.041721
>     0.033602      -0.065038       0.034108
>     0.129551      -0.091923      -0.013744
>     0.004486       0.021525      -0.058926
>    -0.115299      -0.068824      -0.031736
>     0.027354       0.040361      -0.054966
>     0.001507      -0.017616      -0.087353
>     0.124593       0.013885       0.196174
>    -0.221819      -0.215542      -0.053056
>    -0.024812      -0.003769      -0.069640
>    -0.157451       0.015429       0.191808
>     0.223830      -0.194835      -0.025083
>    -0.008884       0.057160       0.035859
>    -0.260302      -0.106890      -0.250642
>     0.282817      -0.226449       0.155991
>     0.001506       0.057439       0.044929
>     0.226122      -0.106332      -0.267809
>    -0.262915      -0.228026       0.188519
>    -0.000475       0.078246       0.001701
>    -0.000023       0.086691       0.000230
>     0.000175      -0.021448      -0.000103
>     0.000321      -0.001059       0.000146
> vibration     18
>    -0.018330       0.139550      -0.032646
>    -0.078643      -0.233719       0.061495
>     0.066799       0.136680      -0.069923
>     0.047046       0.168704      -0.021511
>    -0.038969      -0.271632       0.078700
>    -0.017145      -0.264839       0.043097
>    -0.015312      -0.097457      -0.102919
>     0.069651      -0.129385      -0.085761
>     0.051922      -0.100421      -0.133813
>    -0.078424       0.171790       0.174278
>    -0.036824       0.206249       0.197515
>    -0.017996       0.172132       0.210238
>    -0.079095       0.065556      -0.233424
>    -0.017761       0.097045      -0.251083
>    -0.039662       0.069075      -0.274032
>    -0.016865      -0.040376       0.135837
>     0.049934      -0.064997       0.156158
>     0.068233      -0.007845       0.153139
>    -0.192859       0.001019       0.000372
>    -0.012789      -0.000635       0.000632
>     0.185706      -0.001144      -0.000896
>     0.166635      -0.003270      -0.001787
> vibration     19
>     0.002382       0.020135      -0.036206
>    -0.009037      -0.000239      -0.047585
>    -0.374333      -0.025898       0.115211
>     0.319589       0.069446       0.102622
>     0.361779       0.011891       0.121227
>    -0.325393       0.019059       0.115607
>     0.005359      -0.043637      -0.076258
>     0.170169      -0.078685       0.052234
>    -0.330680      -0.014220       0.082855
>    -0.027319      -0.002414      -0.050102
>    -0.185579      -0.034292       0.087426
>     0.304572      -0.032205       0.088733
>     0.036757       0.001192      -0.050902
>     0.020456       0.016834       0.056989
>    -0.175497       0.017721       0.064386
>    -0.008297       0.022776      -0.112233
>     0.010447       0.044687       0.020541
>     0.202488       0.003132       0.035614
>    -0.000069       0.001266       0.125466
>     0.000209       0.001013       0.174996
>     0.000116      -0.000250      -0.035500
>     0.000002       0.000047      -0.005679
> vibration     20
>    -0.010366      -0.115302       0.021827
>     0.041302      -0.051082       0.000898
>     0.020297       0.020162       0.042113
>     0.198564       0.039434       0.000288
>     0.006843       0.061772       0.013550
>    -0.162115       0.062313       0.015429
>     0.007188      -0.072945      -0.045905
>    -0.334344       0.088951      -0.001500
>     0.175801       0.047445      -0.083956
>    -0.028939      -0.048579      -0.001865
>     0.308413       0.097097      -0.024505
>    -0.198773       0.081693      -0.035316
>    -0.011992      -0.047649       0.002144
>     0.361932       0.116199       0.007236
>    -0.314606       0.112958       0.024416
>     0.002635      -0.035711       0.024774
>    -0.375917       0.116559      -0.034594
>     0.313608       0.092972       0.079446
>    -0.000703       0.127146      -0.001410
>     0.000247       0.179399      -0.000966
>     0.000026      -0.040153       0.000284
>     0.000437      -0.007208       0.000190
> vibration     21
>     0.051715       0.013651       0.025786
>    -0.055056      -0.018809      -0.024639
>     0.065899      -0.073873       0.001512
>     0.080593       0.109193      -0.047310
>    -0.070780       0.110490      -0.000816
>    -0.093666      -0.075917       0.042618
>     0.167253      -0.025732      -0.009955
>     0.241969      -0.074702      -0.091228
>     0.232986      -0.022484      -0.030074
>    -0.178498       0.039122       0.022307
>    -0.266169       0.003817       0.013110
>    -0.266948      -0.070958      -0.049778
>     0.236688      -0.018802       0.053663
>     0.347382       0.002548      -0.038747
>     0.362523       0.023728      -0.060309
>    -0.219641       0.012710      -0.031825
>    -0.314843       0.027333      -0.107985
>    -0.311656       0.029983      -0.091127
>    -0.003752      -0.000853      -0.050827
>     0.001026       0.000806       0.020785
>    -0.000887      -0.000364       0.002308
>     0.000815      -0.000436       0.022276
> vibration     22
>    -0.228709      -0.023647       0.009224
>     0.244540       0.044472      -0.014180
>    -0.321854      -0.111288       0.017583
>    -0.321826      -0.081195       0.021975
>     0.371966      -0.049265       0.012095
>     0.365225      -0.073339       0.030769
>     0.159947      -0.000932      -0.021780
>     0.219926      -0.016669      -0.012465
>     0.227142      -0.086305      -0.071685
>    -0.168523       0.010638       0.032723
>    -0.252223      -0.054884      -0.074157
>    -0.252388       0.007990       0.000914
>    -0.070411      -0.015352      -0.018008
>    -0.099497      -0.005965       0.087625
>    -0.110980       0.028421      -0.044098
>     0.066938       0.016053       0.011376
>     0.089470      -0.000730      -0.036197
>     0.098227      -0.037582       0.082836
>    -0.004693      -0.043279       0.001434
>     0.001385       0.012855       0.000085
>    -0.001607       0.005014      -0.000319
>     0.000703       0.023972      -0.001249
> vibration     23
>     0.001248       0.020310       0.081672
>    -0.002969      -0.018797      -0.078652
>     0.011656      -0.295950       0.001167
>    -0.007201       0.260951      -0.142316
>     0.113757       0.242850       0.034346
>    -0.128805      -0.188753       0.139851
>    -0.002666       0.059181      -0.060944
>     0.008488       0.147891       0.256268
>    -0.008452      -0.257347      -0.159422
>    -0.000162      -0.056240       0.059252
>     0.117934      -0.089760      -0.226943
>    -0.125736       0.220558       0.098082
>    -0.010887       0.077078       0.019019
>    -0.141164      -0.027159      -0.227524
>     0.102523      -0.148874       0.188207
>     0.008235      -0.079989      -0.020341
>     0.005353      -0.009001       0.297209
>     0.021654       0.142991      -0.247388
>     0.012583      -0.002339       0.000309
>    -0.003779       0.001024      -0.000360
>     0.003945      -0.000266      -0.000166
>    -0.003670       0.000303      -0.000438
> vibration     24
>     0.079162       0.031182      -0.012891
>    -0.137203      -0.035528       0.013609
>     0.146597       0.113331      -0.019859
>     0.150853       0.078068      -0.017113
>    -0.293160       0.107455      -0.019872
>    -0.259688       0.120027      -0.056282
>     0.083650      -0.033404      -0.022224
>     0.155462      -0.086078      -0.102968
>     0.160084      -0.048869      -0.058750
>    -0.145517       0.036640       0.025934
>    -0.304071      -0.061595      -0.071286
>    -0.273551      -0.118548      -0.081949
>    -0.139705      -0.000179      -0.035275
>    -0.263716      -0.015060       0.150948
>    -0.294761      -0.030792       0.091652
>     0.081912       0.000639       0.032799
>     0.150740      -0.021437       0.058370
>     0.149166      -0.046243       0.119789
>     0.330498      -0.002384      -0.004737
>    -0.112869       0.001897       0.002703
>     0.100536      -0.000353      -0.000633
>    -0.091595       0.001584       0.001188
> vibration     25
>    -0.020309       0.046916       0.086683
>     0.013518      -0.053286      -0.073202
>     0.022990      -0.283257      -0.010651
>    -0.038868       0.292150      -0.145080
>    -0.034199       0.302132      -0.014564
>     0.067016      -0.335609       0.137624
>    -0.078175      -0.121945      -0.033885
>    -0.033888      -0.204737      -0.239191
>     0.002254       0.109435       0.002684
>     0.044318       0.150275       0.073775
>     0.074627       0.225241       0.264165
>     0.017549      -0.099658      -0.025250
>    -0.049062      -0.081922       0.178296
>    -0.063526      -0.074693       0.260954
>    -0.027570       0.029532       0.046176
>     0.093456       0.070291      -0.121246
>     0.024970       0.075418      -0.247431
>     0.001267      -0.049054      -0.054438
>    -0.006146      -0.013403      -0.172639
>     0.002536       0.006532       0.090068
>    -0.002129      -0.001870      -0.024463
>     0.001417       0.000805       0.012994
> vibration     26
>    -0.086202       0.130862      -0.048964
>     0.039898      -0.191801       0.062173
>    -0.003513       0.187797      -0.073100
>     0.003897       0.119756       0.015384
>     0.036816      -0.198541       0.061918
>     0.019129      -0.103059      -0.005192
>     0.054862       0.008848       0.116399
>    -0.028187      -0.032729      -0.147829
>     0.024222       0.255583       0.210948
>    -0.026217      -0.043256      -0.139079
>     0.021248       0.067507       0.151199
>    -0.060564      -0.269916      -0.236583
>    -0.014610       0.062817       0.090577
>     0.028886       0.011988      -0.279535
>    -0.053385      -0.153964       0.352234
>     0.029909      -0.080160      -0.072191
>    -0.030378       0.017392       0.256130
>     0.031819       0.153352      -0.319413
>     0.004145       0.173192      -0.013208
>    -0.000715      -0.088256       0.006471
>     0.000764       0.025365      -0.001705
>    -0.001148      -0.015662       0.001500
> vibration     27
>     0.198173      -0.082795       0.022049
>    -0.121855       0.085585      -0.022555
>     0.263413      -0.008569       0.022129
>     0.270234      -0.014823      -0.011842
>    -0.177442       0.087933      -0.042475
>    -0.183014       0.093268      -0.000389
>     0.199232       0.061644       0.062832
>     0.263495       0.024395      -0.003390
>     0.269758      -0.000829       0.021850
>    -0.119898      -0.062841      -0.064342
>    -0.175986      -0.079975      -0.051243
>    -0.178752      -0.049663      -0.081885
>    -0.122289      -0.022407       0.087752
>    -0.182246      -0.045389       0.081210
>    -0.180392      -0.006385       0.101351
>     0.199959       0.022201      -0.084725
>     0.271801       0.018601      -0.005051
>     0.264917      -0.013233      -0.022465
>    -0.293875       0.001801       0.000405
>    -0.059032      -0.000806      -0.000083
>    -0.052358      -0.000100      -0.000216
>     0.128870      -0.001809      -0.001109
> vibration     28
>    -0.001289       0.026000       0.140302
>    -0.000229      -0.018632      -0.121080
>     0.305576      -0.181743      -0.037745
>    -0.300198       0.144093      -0.133988
>     0.385754       0.072343       0.070676
>    -0.387924      -0.019897       0.096331
>    -0.004198      -0.051832       0.090496
>    -0.210187      -0.036287      -0.149066
>     0.222052       0.105388       0.041821
>    -0.000391       0.035236      -0.087807
>    -0.270196      -0.040342       0.062433
>     0.271367      -0.075138      -0.004602
>     0.000270      -0.021131      -0.058614
>     0.114186       0.039582       0.001512
>    -0.114726       0.024093      -0.034706
>     0.005522       0.030195       0.048890
>     0.080757      -0.028268      -0.077459
>    -0.098782      -0.012538       0.031151
>     0.000297       0.001872       0.096431
>     0.000755      -0.001291      -0.103371
>    -0.000613       0.000221       0.013787
>     0.000062      -0.000049      -0.007108
> vibration     29
>     0.005416       0.046400       0.022400
>     0.000415      -0.057540      -0.014944
>     0.063025      -0.065244      -0.027494
>    -0.083208       0.018944      -0.003370
>     0.089218      -0.006677       0.036242
>    -0.093914      -0.031178       0.014656
>    -0.003774       0.094882      -0.053541
>     0.236552       0.041537       0.111699
>    -0.220724      -0.151462      -0.038752
>    -0.000523      -0.089842       0.036616
>     0.292711       0.008841      -0.072145
>    -0.291676       0.060304      -0.041638
>    -0.000135      -0.118926      -0.017385
>     0.382190       0.062462       0.070252
>    -0.380175       0.096066      -0.008361
>    -0.001563       0.136473       0.026684
>     0.305567      -0.036089      -0.167967
>    -0.301596      -0.132469       0.133652
>     0.000216       0.097076      -0.002071
>     0.000277      -0.103281       0.001561
>    -0.000326       0.014638      -0.000186
>     0.000122      -0.007830       0.000280
> vibration     30
>    -0.002547      -0.003993       0.006567
>     0.003829       0.012738       0.039405
>    -0.242240      -0.194909       0.061385
>     0.239981       0.193922      -0.037111
>     0.124399      -0.226719       0.036613
>    -0.112852       0.218856      -0.074050
>    -0.002904       0.007910      -0.000167
>    -0.242236       0.150966       0.139075
>     0.239046      -0.129506      -0.149619
>     0.004165       0.027940      -0.030215
>     0.125413       0.145416       0.177852
>    -0.113544      -0.173586      -0.152595
>     0.003856      -0.039918      -0.008456
>    -0.115297      -0.045709       0.226875
>     0.125279       0.081028      -0.213766
>    -0.002545      -0.004361      -0.006900
>     0.238777      -0.064546       0.187911
>    -0.239799       0.044748      -0.199410
>    -0.002720      -0.000294      -0.000442
>    -0.022432       0.000119       0.000065
>     0.017721      -0.000084      -0.000060
>    -0.000246       0.000001       0.000013
> vibration     31
>     0.067102       0.137386      -0.033704
>    -0.103616      -0.059818       0.030902
>    -0.075380       0.012911      -0.002159
>     0.098983       0.152362      -0.031303
>    -0.108609      -0.100992       0.026106
>    -0.190589       0.060005      -0.033479
>     0.067717      -0.097124      -0.104099
>    -0.070004      -0.008764      -0.008850
>     0.095870      -0.105820      -0.117721
>    -0.103056       0.055869       0.037377
>    -0.103403       0.073824       0.073720
>    -0.194221      -0.057671      -0.035371
>    -0.103310       0.004709      -0.066545
>    -0.195994      -0.002325       0.067235
>    -0.103423       0.026016      -0.099181
>     0.067059      -0.042252       0.134997
>     0.094389      -0.049038       0.150644
>    -0.068361      -0.003984       0.012132
>     0.084264      -0.000300      -0.000523
>     0.591787       0.000207       0.000613
>    -0.462096       0.000981       0.000459
>     0.002618       0.000204       0.000131
> vibration     32
>    -0.000346      -0.008223      -0.033410
>     0.000447       0.005387       0.021747
>    -0.220218      -0.079646       0.040294
>     0.219030       0.090363      -0.001659
>    -0.273467       0.176614      -0.059233
>     0.274872      -0.182840       0.032320
>    -0.000298      -0.024734       0.023812
>    -0.220586       0.074944       0.048844
>     0.218981      -0.046924      -0.077462
>     0.000334       0.016070      -0.015790
>    -0.272813      -0.139091      -0.123021
>     0.274378       0.119106       0.141866
>     0.000308      -0.021874      -0.006067
>     0.274334       0.063188      -0.173644
>    -0.273654      -0.036764       0.181833
>    -0.000294       0.033236       0.009556
>     0.219992      -0.043754       0.079544
>    -0.219821       0.004450      -0.088263
>    -0.000763       0.000226       0.000110
>     0.001014      -0.000116      -0.000090
>    -0.000410       0.000018       0.000002
>     0.000011       0.000009       0.000004
> vibration     33
>     0.002723       0.009340       0.024798
>    -0.001331       0.008343       0.040231
>    -0.332188      -0.323029       0.083208
>     0.309976       0.300644      -0.071206
>    -0.016847      -0.090106       0.011694
>     0.022584       0.077667      -0.031570
>    -0.048484       0.019856       0.037052
>     0.338197      -0.234690      -0.266455
>     0.054718      -0.063945      -0.037192
>     0.020766      -0.031407      -0.005544
>    -0.037485      -0.076118      -0.064285
>    -0.053187       0.002788      -0.026358
>    -0.019389       0.027943      -0.016946
>     0.031145       0.035717      -0.093659
>     0.054228      -0.017501      -0.013899
>     0.045472       0.004169       0.039996
>    -0.362400       0.088224      -0.368582
>    -0.005642       0.023510      -0.014492
>    -0.000043       0.005768       0.015630
>    -0.000049      -0.019329      -0.054517
>     0.000023       0.001831       0.004376
>     0.000038      -0.001035      -0.003253
> vibration     34
>    -0.055587      -0.043793       0.013121
>     0.023194       0.028864      -0.005013
>     0.200542       0.217392      -0.033411
>     0.249671       0.255329      -0.085938
>    -0.053364       0.056890      -0.032490
>    -0.044520       0.066479       0.000555
>     0.025856      -0.031270       0.001961
>     0.181215      -0.129563      -0.116588
>    -0.391128       0.283219       0.282349
>    -0.010479      -0.016924       0.034833
>     0.038128      -0.020944      -0.046716
>     0.005476       0.075269       0.075116
>    -0.012655      -0.028693      -0.024712
>     0.038994       0.006277       0.045993
>     0.014879       0.030543      -0.106957
>     0.029417      -0.027918       0.018181
>     0.143981      -0.050256       0.125545
>    -0.381017       0.115773      -0.374949
>    -0.000045      -0.015639       0.005804
>     0.000171       0.053268      -0.019952
>    -0.000032      -0.004353       0.001742
>    -0.000056       0.003532      -0.001104
> vibration     35
>    -0.016339      -0.004756      -0.006294
>     0.002381       0.004664       0.021700
>     0.257119       0.237013      -0.058954
>    -0.109062      -0.115946       0.046185
>     0.226843      -0.266384       0.056455
>    -0.227060       0.271476      -0.082187
>    -0.041652       0.003975      -0.003103
>     0.053296      -0.032915       0.010508
>     0.310598      -0.178444      -0.210490
>     0.014076      -0.005077       0.017645
>    -0.188629      -0.156765      -0.179207
>     0.132337       0.112856       0.109252
>    -0.016578       0.003160       0.011492
>     0.095467       0.026492      -0.124473
>    -0.038902      -0.007743       0.034266
>     0.057625      -0.003010       0.002583
>    -0.198184       0.074395      -0.133321
>    -0.309717       0.041342      -0.256902
>    -0.000067      -0.000061      -0.070771
>     0.000229       0.000761       0.107642
>    -0.000030      -0.000029      -0.017098
>    -0.000005      -0.000117       0.001239
> vibration     36
>     0.057805       0.001286      -0.002469
>    -0.016639       0.012163       0.002648
>    -0.210686      -0.142420       0.073864
>    -0.297918      -0.248313       0.029540
>     0.082227      -0.111652       0.019119
>    -0.024171       0.019601      -0.002143
>    -0.042778      -0.002585       0.007032
>     0.331395      -0.218230      -0.199648
>     0.048197       0.018238      -0.026416
>     0.010101       0.015757      -0.006082
>     0.152137       0.118149       0.127134
>    -0.177975      -0.168358      -0.154360
>     0.006136       0.021516       0.001452
>     0.204069       0.058010      -0.242659
>    -0.233460      -0.090576       0.271447
>    -0.014764      -0.008828      -0.000928
>     0.249250      -0.066322       0.231187
>    -0.121979       0.056985      -0.130035
>     0.000035      -0.071138      -0.000244
>    -0.000042       0.112640      -0.001073
>     0.000034      -0.018692       0.000081
>     0.000006       0.001404       0.000016
> vibration     37
>    -0.010998      -0.015515       0.021904
>    -0.032783       0.033461       0.025717
>     0.023728      -0.028500       0.005272
>     0.126938       0.141028      -0.044937
>     0.263750      -0.301960       0.077551
>    -0.001118       0.094674      -0.042976
>     0.033747      -0.037593      -0.035352
>    -0.200928       0.103447       0.114260
>    -0.224787       0.134552       0.128899
>     0.076990       0.042204       0.048523
>    -0.325919      -0.203401      -0.174919
>    -0.302899      -0.140615      -0.180606
>    -0.044705       0.018134       0.044852
>     0.305958       0.096815      -0.317157
>     0.063280      -0.034417       0.036470
>    -0.022322       0.023039      -0.025689
>     0.096602      -0.012374       0.035108
>     0.176083      -0.056622       0.173105
>     0.000081      -0.025490      -0.031738
>    -0.000087      -0.016706      -0.027412
>    -0.000050       0.003088       0.004797
>     0.000055      -0.000780      -0.000904
> vibration     38
>     0.030919       0.047815      -0.004311
>     0.071682      -0.053729       0.029200
>    -0.213692      -0.187304       0.039021
>    -0.177727      -0.117556       0.032802
>    -0.229802       0.121961      -0.059792
>    -0.355323       0.321293      -0.062039
>    -0.004275      -0.009577       0.017018
>     0.078222      -0.074440      -0.085174
>    -0.026170       0.053786       0.047003
>    -0.008574      -0.030969       0.020348
>    -0.111371      -0.130941      -0.153950
>     0.182688       0.183098       0.179436
>    -0.062767      -0.034768       0.044190
>     0.170945       0.042840      -0.058837
>     0.340102       0.077112      -0.325148
>    -0.026233       0.000543      -0.043050
>     0.202475      -0.043841       0.186630
>     0.133814      -0.022542       0.072806
>    -0.000083       0.031432      -0.025806
>    -0.000101       0.025698      -0.017719
>    -0.000023      -0.004685       0.003167
>    -0.000010       0.000981      -0.000723
> vibration     39
>     0.080101       0.037264      -0.009096
>    -0.024336      -0.012324       0.003716
>    -0.287474      -0.263764       0.071452
>    -0.284833      -0.263310       0.061452
>     0.050010      -0.053646       0.027370
>     0.047443      -0.054062      -0.000705
>     0.080524      -0.026751      -0.027297
>    -0.287095       0.192636       0.190816
>    -0.288583       0.186465       0.199970
>    -0.024712       0.008528       0.009596
>     0.047032       0.046933       0.028416
>     0.052995       0.032754       0.053062
>    -0.022813       0.003649      -0.012604
>     0.042996       0.025937      -0.046195
>     0.041307       0.001837      -0.051776
>     0.080244      -0.010697       0.037420
>    -0.287821       0.079386      -0.259058
>    -0.288303       0.068701      -0.262488
>     0.015949       0.000371      -0.001847
>    -0.051987       0.000085      -0.000801
>    -0.013260      -0.000048       0.000080
>     0.007408      -0.000080       0.000133
> vibration     40
>    -0.007500      -0.002982      -0.023746
>     0.019464      -0.008737      -0.039966
>     0.092120       0.144055      -0.030217
>    -0.054048      -0.086852       0.027693
>    -0.241938       0.309135      -0.078309
>     0.082298      -0.190462       0.083530
>    -0.024427       0.006521      -0.017840
>     0.013664      -0.005512       0.001198
>     0.116024      -0.122661      -0.121079
>     0.057804       0.019320      -0.023045
>    -0.119248      -0.032210       0.061508
>    -0.358624      -0.223809      -0.287723
>    -0.077493      -0.009254      -0.008308
>     0.275232       0.114657      -0.129531
>     0.361068       0.017228      -0.304759
>     0.035449      -0.003951      -0.010665
>    -0.074710       0.027425      -0.089063
>    -0.120168       0.045743      -0.157153
>     0.000012      -0.001617       0.139079
>    -0.000767       0.000628       0.068576
>    -0.000210       0.000001      -0.010719
>     0.000152       0.000321      -0.011622
> vibration     41
>     0.034120      -0.010741      -0.003622
>    -0.076843      -0.009413      -0.009284
>    -0.075688      -0.092337       0.024500
>    -0.110185      -0.149663       0.039926
>     0.272467      -0.129522       0.112694
>     0.361666      -0.302010       0.006979
>    -0.025007      -0.017382       0.007584
>     0.122335      -0.122103      -0.132182
>     0.013151       0.001139      -0.004635
>     0.055252      -0.025640       0.017805
>    -0.348311      -0.277320      -0.230100
>    -0.106917       0.070587      -0.019264
>     0.021880      -0.040872      -0.009881
>    -0.256546      -0.093710       0.317711
>     0.075028       0.093140      -0.185885
>    -0.009740      -0.023811      -0.003873
>     0.098466      -0.036184       0.149738
>    -0.045067       0.028206      -0.078372
>    -0.000008       0.143320       0.001019
>     0.000116       0.069301      -0.000372
>     0.000044      -0.011447       0.000112
>     0.000076      -0.012707       0.000174
> vibration     42
>    -0.002859      -0.025467       0.006301
>    -0.091301       0.035719      -0.009435
>     0.072875       0.038661      -0.007284
>     0.073568       0.037194      -0.011463
>     0.329743      -0.168763       0.122553
>     0.331831      -0.208133      -0.025588
>    -0.002914       0.018364       0.018992
>     0.072887      -0.025535      -0.029994
>     0.074294      -0.029442      -0.027070
>    -0.091394      -0.026072      -0.026628
>     0.330610       0.191436       0.086356
>     0.331617       0.081532       0.192765
>    -0.091751      -0.010192       0.035707
>     0.332611       0.126774      -0.165653
>     0.333495      -0.021238      -0.210622
>    -0.002869       0.007206      -0.025518
>     0.074139      -0.008790       0.038317
>     0.073048      -0.012764       0.036586
>     0.056835       0.000379       0.000439
>     0.005072      -0.000016       0.000185
>    -0.003563       0.000004      -0.000012
>     0.007371      -0.000042      -0.000024
> vibration     43
>     0.038109      -0.030165       0.009582
>     0.010117       0.006901      -0.003363
>    -0.247242       0.322594       0.201099
>    -0.228858       0.209513      -0.344297
>    -0.074752      -0.127486      -0.068870
>    -0.059205      -0.104340       0.128526
>    -0.039159      -0.022128      -0.024445
>     0.238377       0.001585       0.415843
>     0.252925       0.396978      -0.004541
>    -0.010606       0.004254       0.006492
>     0.061102      -0.019244      -0.167404
>     0.077083      -0.149097      -0.010652
>     0.000305      -0.002979      -0.000712
>    -0.017642      -0.005993       0.019874
>     0.013800       0.011980      -0.024391
>     0.001277       0.003288      -0.000283
>    -0.024347       0.008946      -0.013482
>     0.008517      -0.023024       0.029552
>     0.000031       0.018952       0.005845
>    -0.000055      -0.020894      -0.006384
>    -0.000023       0.001526       0.000450
>     0.000022      -0.001758      -0.000489
> vibration     44
>    -0.023624       0.019681      -0.002462
>    -0.006284      -0.005141      -0.001297
>     0.134110      -0.229803      -0.122804
>     0.160825      -0.103265       0.201236
>     0.028536       0.105853       0.038629
>     0.054924       0.038804      -0.070544
>    -0.021303      -0.014437      -0.010787
>     0.148025      -0.015332       0.201003
>     0.118728       0.238117       0.013837
>    -0.005871       0.005005       0.001402
>     0.051822       0.006290      -0.072029
>     0.024984      -0.103576      -0.023420
>     0.012004      -0.002347       0.008750
>    -0.078908      -0.072502      -0.168744
>    -0.079336       0.150547      -0.102385
>     0.044372       0.009728      -0.035880
>    -0.276465       0.227368       0.399761
>    -0.278669      -0.399471       0.223354
>    -0.000010      -0.006166       0.018421
>     0.000021       0.006454      -0.020542
>    -0.000010      -0.000450       0.001411
>    -0.000009       0.000600      -0.001640
> vibration     45
>     0.011216      -0.013355       0.004126
>    -0.028336      -0.043011       0.012124
>    -0.082583       0.131399       0.072864
>    -0.079049       0.086249      -0.131595
>     0.201971       0.378129       0.200576
>     0.195793       0.259043      -0.362812
>    -0.010887      -0.008996      -0.009999
>     0.076184       0.005790       0.151254
>     0.079458       0.144460       0.004920
>     0.026973      -0.028112      -0.031595
>    -0.183688       0.024576       0.423237
>    -0.193636       0.402422       0.029681
>     0.001363       0.002345       0.002938
>    -0.001235      -0.008683      -0.040555
>    -0.017859       0.007022       0.006460
>    -0.000536       0.001024       0.000991
>     0.000633      -0.003704      -0.014430
>     0.007213       0.002235       0.002398
>    -0.000050      -0.018225      -0.004472
>    -0.000006      -0.008909      -0.002089
>     0.000003       0.001062       0.000233
>     0.000000       0.000264       0.000035
> vibration     46
>     0.005969      -0.007508       0.000903
>    -0.014693      -0.023192       0.003091
>    -0.040412       0.078383       0.039401
>    -0.045823       0.038641      -0.065554
>     0.096112       0.219856       0.104951
>     0.111002       0.114407      -0.177190
>     0.006907       0.006694       0.005272
>    -0.051872       0.000469      -0.086950
>    -0.046180      -0.098546      -0.007218
>    -0.017329       0.020702       0.017883
>     0.127549      -0.003798      -0.249768
>     0.114689      -0.279433      -0.031535
>     0.031680      -0.013924       0.048122
>    -0.223640      -0.207285      -0.442425
>    -0.221707       0.412346      -0.265092
>    -0.012938      -0.004276       0.015555
>     0.092569      -0.081280      -0.157150
>     0.092963       0.150612      -0.092625
>    -0.000031      -0.004586       0.017706
>    -0.000005      -0.002186       0.008803
>    -0.000008       0.000277      -0.001003
>     0.000010       0.000084      -0.000191
> vibration     47
>     0.028761      -0.029605       0.007718
>     0.005840       0.013825      -0.003459
>    -0.184715       0.276968       0.162379
>    -0.183567       0.164405      -0.277030
>    -0.053828      -0.142530      -0.063682
>    -0.054220      -0.096923       0.122912
>     0.028570       0.021433       0.021724
>    -0.183653       0.001892      -0.320459
>    -0.182965      -0.321171      -0.004004
>     0.005991      -0.009985      -0.010382
>    -0.054314       0.016549       0.157255
>    -0.055087       0.156085       0.022295
>     0.006039      -0.004038       0.014062
>    -0.055834      -0.059697      -0.148966
>    -0.055244       0.129996      -0.094539
>     0.028894       0.008153      -0.029637
>    -0.184546       0.158503       0.282544
>    -0.185358      -0.280906       0.159902
>     0.008071      -0.000041       0.000180
>    -0.000096       0.000012      -0.000075
>     0.003171       0.000009      -0.000001
>     0.001686      -0.000017      -0.000019
> vibration     48
>    -0.012572       0.012609      -0.003318
>     0.011999       0.040741      -0.010107
>     0.088207      -0.120843      -0.073807
>     0.087850      -0.070362       0.123668
>    -0.126775      -0.314094      -0.147906
>    -0.127938      -0.209297       0.277073
>    -0.012632      -0.009153      -0.009236
>     0.088085      -0.003476       0.141671
>     0.087821       0.142132      -0.000867
>     0.012093      -0.029165      -0.030288
>    -0.127158       0.029235       0.346823
>    -0.128124       0.345131       0.042526
>     0.012025      -0.011694       0.040507
>    -0.128230      -0.136132      -0.321275
>    -0.127202       0.286657      -0.199860
>    -0.012652      -0.003464       0.012632
>     0.088207      -0.072232      -0.123465
>     0.088508       0.125171      -0.068340
>     0.024721       0.000009       0.000095
>    -0.002100      -0.000012       0.000039
>    -0.000652      -0.000011      -0.000010
>    -0.002468      -0.000009      -0.000010
> vibration     49
>    -0.000403      -0.000438      -0.000125
>     0.024454       0.025803      -0.005270
>    -0.000025       0.000291       0.000795
>    -0.001416       0.001752       0.001702
>    -0.138982      -0.072978       0.332811
>    -0.141400      -0.225209      -0.267653
>    -0.000241       0.000300      -0.000072
>    -0.000996      -0.001716       0.000569
>     0.000731      -0.000978       0.001686
>     0.012431      -0.010134      -0.008788
>    -0.074944       0.171272      -0.055367
>    -0.067606      -0.057424       0.160781
>    -0.037282       0.011192      -0.038537
>     0.212254      -0.519501       0.093483
>     0.215308       0.388790       0.353088
>     0.000608      -0.000202       0.000567
>     0.001130       0.001471      -0.000884
>     0.001019      -0.000555      -0.001093
>    -0.000003       0.000054      -0.000105
>     0.000004      -0.000152       0.000305
>     0.000001      -0.000018       0.000041
>     0.000003       0.000021      -0.000054
> vibration     50
>     0.000334       0.000559      -0.000256
>    -0.029201      -0.030365       0.008335
>     0.001972      -0.001013       0.003614
>     0.001110      -0.001763      -0.001167
>     0.171310       0.088112      -0.405996
>     0.163811       0.264554       0.312936
>    -0.000498       0.000341       0.000505
>    -0.000976      -0.001327      -0.000094
>    -0.001612       0.000481      -0.002675
>     0.035118      -0.025897      -0.027494
>    -0.202271       0.470695      -0.150292
>    -0.200516      -0.168989       0.467816
>    -0.007467       0.003529      -0.007356
>     0.045771      -0.109223       0.019062
>     0.039764       0.073581       0.067637
>     0.000173      -0.000289      -0.000020
>     0.000827       0.001475      -0.000189
>    -0.000992       0.002072       0.001472
>    -0.000015      -0.000103      -0.000042
>     0.000014       0.000310       0.000155
>     0.000001       0.000042       0.000018
>     0.000009      -0.000058      -0.000040
> vibration     51
>     0.000691      -0.001811       0.000457
>     0.026089       0.028260      -0.006855
>    -0.007254       0.004303      -0.017939
>    -0.007427       0.012521       0.013703
>    -0.151773      -0.079565       0.361053
>    -0.149268      -0.240183      -0.283321
>     0.000883       0.001431       0.001491
>    -0.008284      -0.020155       0.006038
>    -0.008468       0.006476      -0.020212
>     0.027292      -0.021076      -0.021845
>    -0.159009       0.369498      -0.117195
>    -0.155911      -0.130613       0.364784
>     0.026188      -0.008370       0.027960
>    -0.150713       0.368263      -0.067130
>    -0.151516      -0.273150      -0.249381
>     0.000759       0.000550      -0.001863
>    -0.007845      -0.019245       0.004231
>    -0.007648       0.014115       0.013314
>     0.000750       0.000000       0.000011
>    -0.000692       0.000008       0.000007
>    -0.000078       0.000001      -0.000002
>    -0.000553      -0.000015      -0.000019
> vibration     52
>     0.037174      -0.039983       0.010214
>    -0.001663       0.000346       0.000016
>    -0.206774       0.115061      -0.521036
>    -0.211123       0.351604       0.400953
>     0.001663       0.000219      -0.003707
>     0.000779       0.000921       0.001959
>    -0.007372      -0.005113      -0.006414
>     0.038783       0.097713      -0.030812
>     0.044134      -0.035326       0.103524
>     0.000385      -0.000404       0.000399
>    -0.002467       0.005162      -0.001715
>     0.001310       0.000670      -0.002510
>     0.001022      -0.000312      -0.000472
>    -0.001447       0.003260      -0.000257
>     0.001252       0.001689       0.002190
>    -0.025666      -0.007202       0.027518
>     0.144221       0.359722      -0.071627
>     0.144144      -0.272968      -0.249530
>    -0.000041       0.000249      -0.000148
>     0.000015      -0.000425       0.000249
>    -0.000014       0.000099      -0.000054
>    -0.000006       0.000040      -0.000025
> vibration     53
>    -0.011261       0.011882      -0.004151
>     0.000472       0.000033       0.000607
>     0.065687      -0.035922       0.162921
>     0.061070      -0.103546      -0.117881
>     0.001681       0.001007      -0.003428
>    -0.002138      -0.003052      -0.003700
>     0.035499       0.028154       0.027617
>    -0.199926      -0.490807       0.155026
>    -0.199210       0.162525      -0.478259
>    -0.001509      -0.000550      -0.000014
>    -0.000314       0.000883       0.000406
>     0.001790       0.001950      -0.003950
>     0.001075       0.000554      -0.000220
>     0.001361      -0.002826       0.000982
>    -0.001780      -0.003040      -0.002235
>    -0.026552      -0.008873       0.028132
>     0.153265       0.378607      -0.075311
>     0.145191      -0.277435      -0.253864
>     0.000023      -0.000150      -0.000249
>    -0.000008       0.000240       0.000411
>     0.000008      -0.000059      -0.000093
>     0.000006      -0.000023      -0.000041
> vibration     54
>    -0.024101       0.026542      -0.006974
>     0.002283       0.001183      -0.000230
>     0.135270      -0.075938       0.339382
>     0.136947      -0.228614      -0.259225
>    -0.007937      -0.003772       0.018052
>    -0.008014      -0.012257      -0.014698
>    -0.027749      -0.022451      -0.022181
>     0.156758       0.384878      -0.120373
>     0.156737      -0.126476       0.375318
>     0.002476      -0.000798      -0.000927
>    -0.008297       0.018300      -0.006101
>    -0.008396      -0.006971       0.018898
>     0.002433      -0.000439       0.001120
>    -0.008458       0.019819      -0.003428
>    -0.007947      -0.013891      -0.012360
>    -0.026945      -0.008433       0.029407
>     0.153981       0.381354      -0.076960
>     0.150113      -0.284024      -0.261211
>     0.000804       0.000018       0.000001
>    -0.000318      -0.000034       0.000009
>     0.000246       0.000010       0.000003
>     0.000096       0.000002      -0.000001
> vibration     55
>     0.000113      -0.005082      -0.019703
>    -0.000260       0.012898       0.051963
>     0.054900      -0.032078       0.131068
>    -0.056217       0.091728       0.099920
>     0.153647       0.081907      -0.346756
>    -0.150539      -0.234567      -0.268571
>     0.000197      -0.013755       0.013690
>     0.051767       0.122057      -0.035507
>    -0.054208       0.039279      -0.124930
>    -0.000179       0.037170      -0.035887
>     0.147985      -0.328914       0.098900
>    -0.145739      -0.111338       0.326098
>    -0.000270      -0.050412      -0.014577
>    -0.147431       0.341898      -0.067567
>     0.150693       0.255126       0.239994
>     0.000018       0.018939       0.005356
>    -0.053854      -0.126864       0.028303
>     0.053604      -0.095170      -0.091089
>    -0.000007      -0.000001       0.000010
>     0.000010      -0.000002      -0.000007
>    -0.000001      -0.000005       0.000003
>    -0.000005      -0.000003      -0.000001
> vibration     56
>     0.000260      -0.006572      -0.025073
>    -0.000213       0.017411       0.069883
>     0.068253      -0.040533       0.165237
>    -0.071226       0.117951       0.128149
>     0.204449       0.108351      -0.462503
>    -0.202197      -0.315844      -0.361518
>    -0.000590       0.004842      -0.005306
>    -0.016358      -0.039225       0.011513
>     0.022217      -0.016100       0.051876
>    -0.000238      -0.014857       0.014461
>    -0.056367       0.124632      -0.039445
>     0.060753       0.045050      -0.137103
>     0.000510       0.051203       0.014863
>     0.146902      -0.341427       0.065805
>    -0.154161      -0.261042      -0.246960
>     0.000372      -0.018210      -0.005422
>     0.049350       0.117903      -0.026311
>    -0.052796       0.094839       0.091097
>     0.000000       0.000436       0.000790
>     0.000000      -0.000206      -0.000379
>    -0.000001       0.000037       0.000065
>     0.000000      -0.000068      -0.000114
> vibration     57
>     0.000478       0.001352       0.006553
>     0.000397      -0.004334      -0.017760
>    -0.020149       0.012089      -0.048642
>     0.015802      -0.026099      -0.028591
>    -0.054775      -0.030986       0.123920
>     0.048506       0.074062       0.087701
>     0.000085      -0.018562       0.018281
>     0.069282       0.165790      -0.048048
>    -0.070821       0.051896      -0.165488
>    -0.000275       0.052402      -0.050641
>     0.207819      -0.462992       0.139183
>    -0.203893      -0.156950       0.456905
>     0.000062       0.051014       0.014712
>     0.150011      -0.348709       0.069893
>    -0.149717      -0.254899      -0.237626
>    -0.000404      -0.018219      -0.004884
>     0.052653       0.125691      -0.028263
>    -0.048757       0.087810       0.084055
>    -0.000001       0.000785      -0.000418
>    -0.000001      -0.000376       0.000205
>     0.000000       0.000067      -0.000043
>    -0.000001      -0.000104       0.000037
> vibration     58
>     0.000216      -0.013491      -0.052408
>     0.000105      -0.004899      -0.019621
>     0.148751      -0.086031       0.353024
>    -0.151574       0.245771       0.268087
>    -0.060180      -0.030918       0.132752
>     0.059158       0.089671       0.103321
>     0.000318      -0.036446       0.035864
>     0.140032       0.328294      -0.095834
>    -0.143710       0.103799      -0.329150
>     0.000075      -0.013562       0.013087
>    -0.056125       0.121724      -0.037006
>     0.055197       0.041569      -0.120415
>     0.000075       0.018256       0.005250
>     0.055690      -0.126076       0.024527
>    -0.056461      -0.093662      -0.087504
>     0.000076       0.049783       0.014061
>    -0.143969      -0.337298       0.074967
>     0.143061      -0.252642      -0.241375
>    -0.000009      -0.000001      -0.000011
>    -0.000003       0.000001      -0.000030
>     0.000003       0.000003       0.000006
>    -0.000003       0.000002      -0.000001
> vibration     59
>    -0.000327       0.018169       0.070739
>    -0.000095       0.006256       0.025076
>    -0.200060       0.116693      -0.476443
>     0.203887      -0.332205      -0.361366
>     0.076914       0.039181      -0.168958
>    -0.076011      -0.114523      -0.132024
>     0.000628      -0.025379       0.024596
>     0.094601       0.223609      -0.066420
>    -0.100911       0.071119      -0.231061
>     0.000018      -0.009129       0.008505
>    -0.036576       0.079615      -0.025188
>     0.037240       0.026790      -0.080226
>     0.000065       0.013962       0.003777
>     0.042078      -0.095871       0.017702
>    -0.043605      -0.070732      -0.067167
>    -0.000339       0.040196       0.011116
>    -0.113774      -0.269009       0.058800
>     0.116821      -0.204873      -0.198102
>     0.000000       0.000077       0.000270
>    -0.000002       0.000379       0.001191
>     0.000000      -0.000072      -0.000202
>     0.000000      -0.000011      -0.000016
> vibration     60
>     0.000449       0.001096       0.003189
>    -0.000026       0.000498       0.000958
>    -0.011387       0.007802      -0.025241
>     0.007138      -0.011574      -0.014860
>     0.003804       0.002646      -0.007075
>    -0.002501      -0.003691      -0.005814
>     0.000258      -0.047344       0.046804
>     0.182402       0.428885      -0.123848
>    -0.185682       0.134922      -0.427466
>     0.000036      -0.016663       0.016308
>    -0.069527       0.149662      -0.045159
>     0.068547       0.052024      -0.149112
>    -0.000108      -0.021037      -0.006222
>    -0.064607       0.144866      -0.028609
>     0.065226       0.108536       0.100611
>    -0.000239      -0.059924      -0.017183
>     0.173512       0.406837      -0.091753
>    -0.171231       0.304285       0.290389
>    -0.000004      -0.000269       0.000074
>    -0.000001      -0.001188       0.000378
>    -0.000001       0.000207      -0.000060
>    -0.000001       0.000013       0.000002
>  &SUBSYS
>    &CELL
> #      ABC [angstrom] 23 15 10.0
>      ABC [angstrom] 25 17 12
>      PERIODIC NONE
>    &END CELL
>    &TOPOLOGY
>      CONNECTIVITY OFF
>      COORDINATE   XYZ
>      COORD_FILE_NAME fluor.xyz
>      CENTER_COORDINATES
>    &END TOPOLOGY
>    &KIND C
>      POTENTIAL GTH
>      &POTENTIAL
>        # C GTH-PBE-q4
>    2    2
>     0.33847124    2    -8.80367398     1.33921085
>    2
>     0.30257575    1     9.62248665
>     0.29150694    0
>      &END POTENTIAL
>      &BASIS
>       # C DZVP-GTH-PBE
>  2
>  2  0  1  4  2  2
>        4.3657614966   0.1476030280   0.0000000000  -0.0864171061    
> 0.0000000000
>        1.2749626469  -0.0210014779   0.0000000000  -0.2743211800    
> 0.0000000000
>        0.4052884311  -0.7098993929   0.0000000000  -0.4772572587    
> 0.0000000000
>        0.1172717248  -0.3801259461   1.0000000000  -0.4035098365    
> 1.0000000000
>  3  2  2  1  1
>        0.6000000000   1.0000000000
>      &END BASIS
>    &END KIND
>    &KIND F
>      POTENTIAL GTH
>      &POTENTIAL
>        # F GTH-PBE-q7
>    2    5
>     0.21492959    2   -21.57302836     3.19977615
>    2
>     0.19468402    1    23.74354045
>     0.18615608    0
>      &END POTENTIAL
>      &BASIS
>        # F aug-DZVP-GTH
>  4
>  2  0  1  4  2  2
>       10.7079832847   0.1525178777   0.0000000000  -0.1028649478    
> 0.0000000000
>        3.1757210204  -0.0450363043   0.0000000000  -0.3085265610    
> 0.0000000000
>        0.9750975650  -0.6987425604   0.0000000000  -0.4757649909    
> 0.0000000000
>        0.2701246771  -0.3801470341   1.0000000000  -0.3724954705    
> 1.0000000000
>  3  2  2  1  1
>        1.6400000000   1.0000000000
>  2  0  0  1  1
>        0.09863000     1.0000000000
>  2  1  1  1  1
>        0.08502000     1.0000000000
>      &END BASIS
>    &END KIND
>    &KIND H
>      POTENTIAL GTH
>      &POTENTIAL
>        # H GTH-PBE-q1
>    1
>     0.20000000    2    -4.17890044     0.72446331
>    0
>      &END POTENTIAL
>      &BASIS
>       # H DZVP-GTH-PBE
>  2
>  1  0  0  4  2
>        8.4486934208  -0.0290463773   0.0000000000
>        1.8581649215  -0.1327955318   0.0000000000
>        0.5076108225  -0.4061407363   0.0000000000
>        0.1673904511  -0.5490803703   1.0000000000
>  2  1  1  1  1
>        0.7000000000   1.0000000000
>      &END BASIS
>    &END KIND
>    &KIND N
>      POTENTIAL GTH
>      &POTENTIAL
>       # N GTH-PBE-q5
>    2    3
>     0.28379052    2   -12.41522559     1.86809592
>    2
>     0.25540500    1    13.63026257
>     0.24549453    0
>      &END POTENTIAL
>      &BASIS
>       # N DZVP-GTH-PBE
>  2
>  2  0  1  4  2  2
>        6.1646187898   0.1507499417   0.0000000000  -0.0938164220    
> 0.0000000000
>        1.8037211883  -0.0339053520   0.0000000000  -0.2912161121    
> 0.0000000000
>        0.5658506122  -0.7128963473   0.0000000000  -0.4795028541    
> 0.0000000000
>        0.1603297607  -0.3703029459   1.0000000000  -0.3849298984    
> 1.0000000000
>  3  2  2  1  1
>        0.7000000000   1.0000000000
>      &END BASIS
>    &END KIND
>    &KIND O
>      POTENTIAL GTH
>      &POTENTIAL
>       # O GTH-PBE-q6
>    2    4
>     0.24455430    2   -16.66721480     2.48731132
>    2
>     0.22095592    1    18.33745811
>     0.21133247    0
>      &END POTENTIAL
>      &BASIS
>        # O DZVP-GTH-PBE
>  2
>  2  0  1  4  2  2
>        8.2968917719   0.1521363234   0.0000000000  -0.0985730287    
> 0.0000000000
>        2.4314066255  -0.0407682329   0.0000000000  -0.3018606942    
> 0.0000000000
>        0.7547606612  -0.7133526943   0.0000000000  -0.4800913367    
> 0.0000000000
>        0.2102342150  -0.3666620394   1.0000000000  -0.3745464613    
> 1.0000000000
>  3  2  2  1  1
>        0.8000000000   1.0000000000
>      &END BASIS
>    &END KIND
>    &KIND Si
>      POTENTIAL GTH
>      &POTENTIAL
>       # Si GTH-PBE-q4
>    2    2
>     0.44000000    1    -6.26928833
>    2
>     0.43563383    2     8.95174150    -2.70627082
>                                        3.49378060
>     0.49794218    1     2.43127673
>      &END POTENTIAL
>      &BASIS
>        # Si DZVP-GTH-PBE
>  2
>  3  0  1  4  2  2
>        1.1815290892   0.3214648125   0.0000000000   0.0458533253    
> 0.0000000000
>        0.4454622072  -0.2454343061   0.0000000000  -0.2633419994    
> 0.0000000000
>        0.1674585747  -0.7952663455   0.0000000000  -0.5433222352    
> 0.0000000000
>        0.0564288769  -0.1828967955   1.0000000000  -0.3560783416    
> 1.0000000000
>  3  2  2  1  1
>        0.4500000000   1.0000000000
>      &END BASIS
>    &END KIND
>  &END SUBSYS
> ! -*- cp2k -*-
> @SET SCF_CONV   1.0E-8
> @SET CUTOFF        500
> @SET FUNCTIONAL    PBE
> @SET DECOUPLING     MT
> @SET CHARGE          1
>
> &FORCE_EVAL
>  &PRINT
>    &FORCES OFF
>    &END
>  &END
>
>  METHOD QS
>
>  &DFT
>    CHARGE ${CHARGE}
>    &MGRID
>      CUTOFF ${CUTOFF}
>      NGRIDS 5
>    &END MGRID
>    &QS
>      EPS_DEFAULT 1.0E-12
>    &END QS
>    &SCF
>      SCF_GUESS RESTART
>      EPS_SCF       ${SCF_CONV}
>      MAX_SCF      30
>      &PRINT
>        &RESTART
>          LOG_PRINT_KEY T
>          FILENAME =./WFN_restart-1.wfn
>          &EACH
>            QS_SCF  0
>          &END EACH
>          ADD_LAST NUMERIC
>          COMMON_ITERATION_LEVELS 1
>        &END RESTART
>      &END PRINT
>      &OT ON
>        MINIMIZER DIIS
>           ! MINIMIZER CG
>           ! PRECONDITIONER FULL_ALL
>           ! PRECONDITIONER FULL_KINETIC
>        PRECONDITIONER FULL_SINGLE_INVERSE
>           !ENERGY_GAP  0.001
>      &END OT
>      &OUTER_SCF
>        EPS_SCF ${SCF_CONV}
>        MAX_SCF 5
>      &END OUTER_SCF
>    &END SCF
>    &XC
>      &XC_FUNCTIONAL ${FUNCTIONAL}
>      &END XC_FUNCTIONAL
>    &END XC
> @IF ( ${DECOUPLING} == NONE )
>    &POISSON
>    &END
> @ENDIF
> @IF ( ${DECOUPLING} == MT )
>    &POISSON
>       POISSON_SOLVER MT
>       PERIODIC NONE
>       &MT
>       &END
>    &END
> @ENDIF
> @IF ( ${DECOUPLING} == WAVELET )
>    &POISSON
>       POISSON_SOLVER WAVELET
>       PERIODIC NONE
>       &WAVELET
>         SCF_TYPE 60
>       &END
>    &END
> @ENDIF
>  &END DFT
>
>  ! Include subsys
> @INCLUDE 'subsys.inc'
> &END FORCE_EVAL




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