What are the column labels for the overlap matrix? I assume that the setup is [orbital number, atom number, atom type, orbital type, matrix ...] but for the orbital type the label does not seem to be n and l. What is the number affixed before the l then?<div><br /></div><div>Overlap matrix output head for CsF:</div><div><font face="Courier New">OVERLAP MATRIX<br /><br /> 1 2 3 4<br /> 1 1 Cs 2s 1.632390 2.621122 1.273099 -0.000000<br /> 2 1 Cs 3s 2.621122 8.007919 4.342380 0.000000<br /> 3 1 Cs 4s 1.273099 4.342380 2.948680 -0.000000<br /> 4 1 Cs 3py -0.000000 0.000000 -0.000000 0.966199<br /> 5 1 Cs 3pz 0.000000 0.000000 -0.000000 -0.000000<br /> 6 1 Cs 3px -0.000000 -0.000000 -0.000000 0.000000<br /> 7 1 Cs 4py -0.000000 -0.000000 0.000000 -0.124733<br /> 8 1 Cs 4pz -0.000000 0.000000 0.000000 -0.000000<br /> 9 1 Cs 4px -0.000000 0.000000 0.000000 0.000000<br /> 10 1 Cs 4d-2 -0.000000 0.000000 -0.000000 0.000000<br /> 11 1 Cs 4d-1 -0.000000 0.000000 -0.000000 0.000000<br /> 12 1 Cs 4d0 0.000000 -0.000000 0.000000 -0.000000<br /> 13 1 Cs 4d+1 0.000000 0.000000 -0.000000 0.000000<br /> 14 1 Cs 4d+2 0.000000 -0.000000 0.000000 0.000000<br /><br /> 15 2 F 2s 0.389074 0.899446 0.553087 0.000000<br /> 16 2 F 3s 0.331211 0.719056 0.306653 0.000000<br /> 17 2 F 3py 0.000000 0.000000 0.000000 -0.065002<br /> 18 2 F 3pz -0.000000 0.000000 -0.000000 0.000000<br /> 19 2 F 3px -0.000000 -0.000000 -0.000000 -0.000000<br /> 20 2 F 4py 0.000000 0.000000 0.000000 -0.128646<br /> 21 2 F 4pz -0.000000 -0.000000 -0.000000 0.000000<br /> 22 2 F 4px -0.000000 -0.000000 -0.000000 -0.000000<br /> 23 2 F 4d-2 -0.000000 0.000000 -0.000000 -0.000000<br /> 24 2 F 4d-1 0.000000 0.000000 0.000000 0.000000<br /> 25 2 F 4d0 -0.000000 -0.000000 0.000000 0.066629<br /> 26 2 F 4d+1 0.000000 0.000000 0.000000 -0.000000<br /> 27 2 F 4d+2 -0.000000 -0.000000 -0.000000 0.115404</font><br /></div><div><br /></div><div>I do not believe F has 3p orbitals and no 2p orbitals nor does Cs stop at n=4.<br /></div>
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