<div>Hi all,<br /></div><div><br /></div><div>I am trying to compare some ground state XAS and TDDFT XAS for a few systems and it was going great on other systems until I started on a relatively simple graphite cell. <br /></div><div>I performed cell optimization and used the resulting structure of 64 C atoms for XAS calculation but i am having issues with ground state calculation of a system which would be compatible with further TDDFT,. SCF does not seem to converge and either diverges wildly or oscillates around 0. <br /></div><div><br /></div><div>I have included a sample input file, I have tried also with the DIIS OT, denationalization, and with a PBE functional but the issue persist. I am hoping someone might have an idea if I missed something obvious. It seems that the problem might be in the HF part, as the convergence is slightly better if I change the HF fraction, but it ultimately always diverges. <br /></div><div><br /></div><div>I would be grateful f anyone has any comments on the issue I am facing and I apologize if I missed something obvious. <br /></div><div>kind regards, Ava<br /></div>
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