Dear all<div> I want to calculate the atomic frequency of diamond silicon by CP2K.<br> My supercell contains N=8 atoms (a PBC system), and I will get the 3N=24 frequencies.<br> </div><div> However, I only get the 21 frequencies, The frequencies of the rotations are obtained, but the part of translations are not obtained.</div><div><br></div><div> I use the VASP to calcualte the vibrational analysis, I get the 24 frequencies.</div><div> I compare the two results:</div><div> </div><div> VASP: (unit: cm-1, 24 frequencies ) </div> 513.100912 513.097046 513.092040 <br> 461.327377 461.230874 461.217489 461.210747 461.189027 461.185948<div> 409.422422 409.414429 409.406072 409.397086 409.393930 409.387741 </div><div> 140.194017 140.189188 140.187673 140.182783 140.175562 140.172242 </div><div><div> 0.006451 0.010431 0.055547 <br> </div><div> CP2K: (unit: cm-1, 21 frequencies) </div><div> 515.944308 515.944308 515.944308<div> 463.042397 463.042397 463.042397 463.042397 463.042397 463.042397<br></div><div> 412.993772 412.993772 412.993772 412.993772 412.993772 412.993772</div><div><div> 139.536054 139.536054 139.536054 139.536054 139.536054 139.536054</div><div> </div><div> The results are similar, but the number is different, how do I get 24 frequencies by CP2K. </div></div><div><br></div><div> The part input:</div><div> "</div><div> &GLOBAL</div> PROJECT system<br> RUN_TYPE VIBRATIONAL_ANALYSIS<br> PRINT_LEVEL MEDIUM<br> &END GLOBAL<br><br> &VIBRATIONAL_ANALYSIS<br> NPROC_REP 3<br> DX 0.001<br> FULLY_PERIODIC .TRUE.<br>&END VIBRATIONAL_ANALYSIS<br><div> "</div></div></div><div><br></div><div> Thank you for your help.</div><div> Best,</div><div> Mengchao.</div>
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