<div>Dear all, I have already asked about a QM calculation of an isolated heme group some weeks before but I am still struggeling how to model an excited state with multiplicity of 5. I'll submit my input, output and coordinate file so that you can understand the errors. I submitted the coordinate file in .pdb and .xyz in case that you would like to open the structure in PYMOL/VMD. One comment: For the charge of -1, I am not sure at all! I'd tend to take 0 as charge as there are one Fe2+ and 2 COO- inside the molecule. I tried to change the charge as I thought that mybe the number of electrons is the reason why CP2K "hates" this S=2 for the heme group but this couldn't solve the issue neither. Maybe someone also knows a bit more on organic complexes with a transition metal core. As I am a physics student I am unfortunately not so familiar with coordination chemistry...<br></div><div><br></div><div>Many thanks for your help<br></div>
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