Ah ok...so I do need to set the multiplicity to some high number! <div><br></div><div>Thanks for the help Chris! <br><br></div><div class="gmail_quote"><div dir="auto" class="gmail_attr">On Monday, September 26, 2022 at 12:17:34 PM UTC-4 uca...@ucl.ac.uk wrote:<br/></div><blockquote class="gmail_quote" style="margin: 0 0 0 0.8ex; border-left: 1px solid rgb(204, 204, 204); padding-left: 1ex;">Hi Frank,<br><br>I attach files where I have converged a spin moment of 0.72 in 36 SCF steps for your 5x5x5 supercell.<br><br>Indeed, Ni should be ferromagnetic and we can confirm this by converging a solution with a multiplicity of 1 and comparing this to the ferromagnetic solution with a multiplicity of 500*2+1=1001. The latter is -84660.541395560532692--84661.817516270704800=1.3 Ha or 35 eV lower in energy.<div><br></div><div>Hope this helps, <br>Chris<br><br><br><br></div><div class="gmail_quote"><div dir="auto" class="gmail_attr">On Sunday, 25 September 2022 at 19:28:54 UTC+1 <a href data-email-masked rel="nofollow">mdsimula...@gmail.com</a> wrote:<br></div><blockquote class="gmail_quote" style="margin:0 0 0 0.8ex;border-left:1px solid rgb(204,204,204);padding-left:1ex">Hello,<div><br></div><div>I am attempting an optimization of bulk nickel in a 5x5x5 super cell. Nickel is supposed to be ferromagnetic so I'm wondering how I set the appropriate magnetization for each Ni?</div><div><br></div><div>Based on literature, the magnetization should be ~0.64. </div><div><br></div><div>Do I need to set some crazy high multiplicity and the magnetization in the kind section?</div><div><br></div><div>My initial input is attached.</div><div><br></div><div>Thanks,</div><div>Frank</div></blockquote></div></blockquote></div>
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