Dear Ron<div><br></div><div>Could you check the ground state electronic structure with the different basis sets? </div><div>For instance PDOS, population etc. Are they different? </div><div>You could also check and compare the localisation and the position of the Wannier centres with the different basis sets. </div><div>Best </div><div>Marcella<br><br></div><div class="gmail_quote"><div dir="auto" class="gmail_attr">On Thursday, August 11, 2022 at 9:27:43 PM UTC+2 reco...@gmail.com wrote:<br/></div><blockquote class="gmail_quote" style="margin: 0 0 0 0.8ex; border-left: 1px solid rgb(204, 204, 204); padding-left: 1ex;">I am reposting this with a proper subject from conversation"REFTRAJ for LINRES".<div>When I use the EMSL 6-31G** basis sets I get reasonable nmr shifts, but with basis sets that are supposed to be optimal for nmr from <a href="http://basissetexchange.org" target="_blank" rel="nofollow" data-saferedirecturl="https://www.google.com/url?hl=en&q=http://basissetexchange.org&source=gmail&ust=1660374621452000&usg=AOvVaw29Wy3BWNpiHL1P0BEFsK36">basissetexchange.org</a> like pcSseg and x2c-tavpall-s.1 I get crazy huge NMR shifts (printed as ****). It is not a cut off issue because results change little doubling the cutoff from 100 to 200 Ryd.</div><div><br></div>Is there an issue with what basis sets are supported, or is there a problem with the cp2k formats from <a href="http://www.basissetexchange.org" target="_blank" rel="nofollow" data-saferedirecturl="https://www.google.com/url?hl=en&q=http://www.basissetexchange.org&source=gmail&ust=1660374621452000&usg=AOvVaw1rv9zClVf-LNAAUoBkCd5E">www.basissetexchange.org</a>?<div><br>There are no error messages.<br></div><div><br></div><div>Thanks for any help.</div><div><br></div><div>Sincerely,</div><div><br></div><div>Ron</div><div><br></div></blockquote></div>
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