<div>Dear CP2K community,</div><div><br></div><div>I am new both to CP2K and ab initio, and I seem to be running into a bit of an issue when it comes to picking potentials. I am running a simple bond formation test in a vacuum. I adapted the ab initio script from the water box exercise, but when I made adjustments to include different kinds of atoms (or tried a different basis set) I ran into some issues. had to switch basis files, as my test molecule has chlorine. I tried a couple different basis files, including GTH_BASIS_SETS and GTH_MOLOPT. I always get some variant of the following error message.</div><div><br></div><div> *******************************************************************************<br> * ___ *<br> * / \ *<br> * [ABORT] *<br> * \___/ An invalid potential type <TZV2P-MOLOPT-GTH-q4> was specified for *<br> * | the atomic kind <C *<br> * O/| *<br> * /| | *<br> * / \ qs_kind_types.F:2354 *<br> *******************************************************************************<br><br>Does any one have any clues as to what I am doing wrong? here are the basis file selection segments and the atom definition section of my input script.</div><div><br></div><div> &DFT<br> ! basis sets and pseudopotential files can be found in cp2k/data<br> BASIS_SET_FILE_NAME BASIS_MOLOPT<br> POTENTIAL_FILE_NAME GTH_POTENTIALS<br><br> ! Charge and multiplicity<br> CHARGE 0<br> MULTIPLICITY 1</div><div><br></div><div>... [skipping to kind section] ...<br></div><div><br></div><div> ! atom coordinates can be in the &COORD section,<br> ! or provided as an external file.<br> &TOPOLOGY<br> COORD_FILE_NAME vac.xyz<br> COORD_FILE_FORMAT XYZ<br> &END<br><br> ! MOLOPT basis sets are fairly costly,<br> ! but in the 'DZVP-MOLOPT-SR-GTH' available for all elements<br> ! their contracted nature makes them suitable<br> ! for condensed and gas phase systems alike.<br> &KIND H<br> BASIS_SET TZV2P-MOLOPT-GTH<br> POTENTIAL TZV2P-MOLOPT-GTH-q1<br> &END KIND<br> &KIND O<br> BASIS_SET TZV2P-MOLOPT-GTH<br> POTENTIAL TZV2P-MOLOPT-GTH-q6<br> &END KIND<br> &KIND C<br> BASIS_SET TZV2P-MOLOPT-GTH<br> POTENTIAL TZV2P-MOLOPT-GTH-q4<br> &END KIND<br> &KIND N<br> BASIS_SET DZVP-MOLOPT-SR-GTH<br> POTENTIAL DZVT-MOLOPT-SR-GTH-q5<br> &END KIND<br> &KIND Cl<br> BASIS_SET DZVP-MOLOPT-SR-GTH<br> POTENTIAL DZVP-MOLOPT-SR-GTH-q7<br> &END KIND<br> &END SUBSYS</div><div><br></div><div><br></div><div>any help or leads would be much appreciated, thank you.</div><div>-Eric<br></div><div><br></div>
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