<div dir="ltr">Dear cp2k users,<div> I'm doing a single point calculation (ENERGY) of neutral terbium phthalocyanine molecule, [TbPc2]. The neutral [TbPc2] contains 6 unpaired electrons on Tb 4f (4f8) and one unpaired electron on the nitrogen atom of the phthalocyanine ring (which is directly attached to the Tb metal centre). Both unpaired centres interact parallel to each other (total multiplicity 8). But I'm not getting correct spin densities. All the spin densities are getting transferred to the Tb centre only (7.06). I have attached here the input and corresponding output file. Can anyone please suggest how to resolve this issue? Can we fix it by changing the NEL values? or What should the NEL values be for the Tb atom and N atom which consists of unpaired electrons.</div><div> your help will be highly appreciated.<br clear="all"><div><br></div>Thanks and regards<br><div dir="ltr" class="gmail_signature" data-smartmail="gmail_signature"><div dir="ltr"><div><div dir="ltr"><font face="comic sans ms, sans-serif" style="background-color:rgb(255,255,255)" color="#ff00ff">Rupesh Kumar Tiwari </font><div><font face="comic sans ms, sans-serif" style="background-color:rgb(255,255,255)" color="#ff00ff">C/o: Prof. Gopalan Rajaraman</font></div><div style="text-align:left"><font face="comic sans ms, sans-serif" style="background-color:rgb(255,255,255)" color="#ff00ff">Senior Research Fellow (CSIR)</font></div><div><font face="comic sans ms, sans-serif" style="background-color:rgb(255,255,255)" color="#ff00ff">Department of Chemistry</font></div><div><font face="comic sans ms, sans-serif" style="background-color:rgb(255,255,255)" color="#ff00ff">IIT Bombay</font></div><div><font face="comic sans ms, sans-serif" style="background-color:rgb(255,255,255)" color="#ff00ff">Mumbai- 400076</font></div></div></div></div></div></div></div>
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