hi <div>I am using SCAN to optimize bulk metal and oxide systems with SCAN. </div><div><div>After completing 2 steps in the SCF wavefunction optimization, it gives error </div><div><br></div><div><div>*******************************************************************************</div><div> * ___ *</div><div> * / \ *</div><div> * [ABORT] *</div><div> * \___/ KS energy is an abnormal value (NaN/Inf). *</div><div> * | *</div><div> * O/| *</div><div> * /| | *</div><div> * / \ qs_ks_methods.F:890 *</div><p> ******************************************************************************* </p></div></div><div><br></div><div><b>Input </b>is here:</div>
<p>&GLOBAL</p><p> PROJECT_NAME Ni</p>
<p> RUN_TYPE CELL_OPT</p>
<p> PRINT_LEVEL LOW</p>
<p> FLUSH_SHOULD_FLUSH .TRUE.</p>
<p>&END GLOBAL</p>
<p><br></p>
<p>&MOTION</p>
<p> &CELL_OPT</p>
<p> TYPE DIRECT_CELL_OPT</p>
<p> MAX_DR 4.5E-04</p>
<p> MAX_FORCE 1.0E-04</p>
<p> RMS_DR 4.5E-04</p>
<p> RMS_FORCE 4.5E-04</p>
<p> MAX_ITER 200</p>
<p> OPTIMIZER BFGS</p>
<p> &END CELL_OPT</p>
<p> &GEO_OPT</p>
<p> OPTIMIZER BFGS</p>
<p> &END GEO_OPT</p>
<p>&END MOTION</p>
<p><br></p>
<p>&FORCE_EVAL</p>
<p> METHOD QS</p>
<p> STRESS_TENSOR ANALYTICAL</p>
<p><br></p>
<p> &DFT</p>
<p> BASIS_SET_FILE_NAME BASIS_MOLOPT</p>
<p> BASIS_SET_FILE_NAME BASIS_MOLOPT_UCL</p>
<p> POTENTIAL_FILE_NAME GTH_POTENTIALS</p>
<p> UKS</p>
<p> </p>
<p> &MGRID</p>
<p> NGRIDS 5</p>
<p> CUTOFF 400</p>
<p> REL_CUTOFF 60</p>
<p> &END MGRID</p>
<p><br></p>
<p> &QS</p>
<p> METHOD GPW ! to optimize the geometry the GPW method will be used</p>
<p> &END QS</p>
<p><br></p>
<p> &SCF</p>
<p> MAX_SCF 400</p>
<p> EPS_SCF 1.0E-6</p>
<p> SCF_GUESS ATOMIC</p>
<p> &DIAGONALIZATION ON</p>
<p> &END DIAGONALIZATION</p>
<p> &MIXING </p>
<p> ALPHA 0.1 </p>
<p> &END MIXING </p>
<p> &SMEAR </p>
<p> METHOD FERMI_DIRAC </p>
<p> &END SMEAR</p>
<p> &END SCF</p>
<p><br></p>
<p> &XC</p>
<p> &XC_FUNCTIONAL</p>
<p> &LIBXC</p>
<p> FUNCTIONAL MGGA_X_SCAN</p>
<p> &END LIBXC</p>
<p> &LIBXC</p>
<p> FUNCTIONAL MGGA_C_SCAN</p>
<p> &END LIBXC</p>
<p> &END XC_FUNCTIONAL</p>
<p> &XC_GRID</p>
<p> XC_DERIV NN50_SMOOTH</p>
<p> XC_SMOOTH_RHO NONE</p>
<p> &END XC_GRID</p>
<p><br></p>
<p> &vdW_POTENTIAL</p>
<p> POTENTIAL_TYPE NON_LOCAL</p>
<p> &NON_LOCAL</p>
<p> TYPE RVV10</p>
<p> PARAMETERS 15.7 0.0093</p>
<p> KERNEL_FILE_NAME rVV10_kernel_table.dat</p>
<p> &END</p>
<p> &END vdW_POTENTIAL</p>
<p> &END XC</p>
<p><br></p>
<p> &END DFT</p>
<p><br></p>
<p> &SUBSYS</p>
<p> &TOPOLOGY</p>
<p> COORD_FILE_FORMAT xyz</p>
<p> COORD_FILE_NAME NiNiO-pos-1.xyz</p>
<p> &END TOPOLOGY</p>
<p> &CELL</p>
<p> PERIODIC XYZ ! we are considering the system periodic in the three directions </p>
<p> ALPHA_BETA_GAMMA 90 90 90</p>
<p> ABC 3.505798 3.505798 3.505798</p>
<p> &END CELL</p>
<p><br></p>
<p> &KIND Ni</p>
<p> ELEMENT Ni</p>
<p> BASIS_SET DZVP-MOLOPT-SR-GTH</p>
<p> POTENTIAL GTH-PBE-q18 </p>
<p> &END KIND</p>
<p><br></p>
<p> &END SUBSYS</p>
<div>&END FORCE_EVAL. </div>