<div dir="ltr"><br><p class="MsoNormal">Dear Matt<o:p></o:p></p>
<p class="MsoNormal">Thank you for your answer. However, I still believe that the printed formats do not differ only for the ordering. Furthermore, modifying NDIGITS does not fix the issue. </p><p class="MsoNormal">This means that the printed MOLDEN file cannot be used for quantitative post-processing.<o:p></o:p></p>
<p class="MsoNormal">I performed tests on H atoms and the H2 molecule, and in both the cases, the MOLDEN-file does not contain the right orbitals. </p><p class="MsoNormal">Below I will report the H case. The orbital printed in the MOLDEN FORMAT is not normalized, as you can easily check by printing the OVERLAP matrix. </p><p class="MsoNormal">Please find below the different formats and the overlap (NDIGITS = 12) :<o:p></o:p></p>
<p class="MsoNormal"><o:p> </o:p></p>
<p class="MsoNormal">CP2K-FORMAT : Occupied orbital of H<o:p></o:p></p>
<p class="MsoNormal"> 1 1 H 1s 0.860523926375 <o:p></o:p></p>
<p class="MsoNormal"> 2 1 H 2s -0.147897200557 <o:p></o:p></p>
<p class="MsoNormal"> 3 1 H 2px -0.000000000000 <o:p></o:p></p>
<p class="MsoNormal"> 4 1 H 2py -0.000000000000 <o:p></o:p></p>
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<p class="MsoNormal" style="border-width: initial; border-style: none; padding: 0in;"> 5 1 H 2pz -0.000000000000 <o:p></o:p></p>
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<p class="MsoNormal"><o:p> </o:p></p>
<p class="MsoNormal">MOLDEN-Format :Occupied orbital of H <o:p></o:p></p>
<p class="MsoNormal">Ene= -0.25103226963873182<o:p></o:p></p>
<p class="MsoNormal"> Spin= Alpha<o:p></o:p></p>
<p class="MsoNormal"> Occup= 1.0000000000000000<o:p></o:p></p>
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<p class="MsoNormal" style="border-width: initial; border-style: none; padding: 0in;"> 2 8.605239264E-01<o:p></o:p></p>
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<p class="MsoNormal"><o:p> </o:p></p>
<p class="MsoNormal">OVERLAP<o:p></o:p></p>
<p class="MsoNormal"> 1s 2s <o:p></o:p></p>
<p class="MsoNormal">1 1 H 1s 1.000000008914 -0.933553473764<o:p></o:p></p>
<p class="MsoNormal">2 1 H 2s -0.933553473764 1.000000029566<o:p></o:p></p>
<p class="MsoNormal">-----------------------------------------------------------------------------------------------------------------------------------------<o:p></o:p></p>
<p class="MsoNormal"><o:p> </o:p></p>
<p class="MsoNormal">The right MOLDEN FORMAT should be (I tested it):<o:p></o:p></p>
<p class="MsoNormal"> 1 0.860523926375 <o:p></o:p></p>
<p class="MsoNormal"> 2 -0.147897200557 <o:p></o:p></p>
<p class="MsoNormal"><o:p> </o:p></p>
<p class="MsoNormal">Best Regards.<o:p></o:p></p>
<p class="MsoNormal">Luca <o:p></o:p></p></div>