PS: when DZVP used, the wavefunctions converged well.<br>but TZVP, TZV2p cannot work. Any suggestions are appreciated.<br><br><br><div class="gmail_quote">2009/9/18 Dong <span dir="ltr"><<a href="mailto:xiand...@gmail.com">xiand...@gmail.com</a>></span><br>
<blockquote class="gmail_quote" style="border-left: 1px solid rgb(204, 204, 204); margin: 0pt 0pt 0pt 0.8ex; padding-left: 1ex;"><br>
Hi all,<br>
<br>
when I move from DZVP to TZVP,<br>
got this err: *** 21:37:57 ERRORL2 in<br>
cp_fm_cholesky:cp_fm_cholesky_decompose processor ***<br>
*** 0 err=-300 condition FAILED at line 92<br>
<br>
<br>
the input is following.<br>
<br>
&FORCE_EVAL<br>
METHOD Quickstep<br>
&DFT<br>
POTENTIAL_FILE_NAME GTH_POTENTIALS<br>
BASIS_SET_FILE_NAME GTH_BASIS_SETS<br>
&MGRID<br>
CUTOFF 280<br>
&END MGRID<br>
&QS<br>
&END QS<br>
&SCF<br>
&OT F<br>
MINIMIZER DIIS<br>
&END OT<br>
EPS_SCF 1.0E-6<br>
SCF_GUESS ATOMIC<br>
&END SCF<br>
&XC<br>
&XC_FUNCTIONAL BLYP<br>
&END XC_FUNCTIONAL<br>
&END XC<br>
&END DFT<br>
&SUBSYS<br>
&CELL<br>
ABC 10.3070 8.9419 7.3906<br>
ALPHA_BETA_GAMMA 91.9260 105.0460 89.7970<br>
&END CELL<br>
&COORD<br>
O -0.3895619913 3.0934925555 3.0934925555<br>
......<br>
......<br>
&END COORD<br>
&KIND H<br>
BASIS_SET TZVP-GTH<br>
POTENTIAL GTH-BLYP-q1<br>
&END KIND<br>
&KIND O<br>
BASIS_SET TZVP-GTH<br>
POTENTIAL GTH-BLYP-q6<br>
&END KIND<br>
&KIND Si<br>
BASIS_SET TZVP-GTH<br>
POTENTIAL GTH-BLYP-q4<br>
&END KIND<br>
&KIND Al<br>
BASIS_SET TZVP-GTH<br>
POTENTIAL GTH-BLYP-q3<br>
&END KIND<br>
&END SUBSYS<br>
&END FORCE_EVAL<br>
&GLOBAL<br>
<br>
PROJECT kao<br>
RUN_TYPE GEO_OPT<br>
PRINT_LEVEL MEDIUM<br>
&END GLOBAL<br>
&MOTION<br>
&GEO_OPT<br>
MAX_ITER 300<br>
MAX_DR 2.0E-3<br>
MAX_FORCE 2.0E-4<br>
RMS_DR 1.0E-3<br>
RMS_FORCE 1.0E-4<br>
OPTIMIZER BFGS<br>
&BFGS<br>
<br>
<br>
&RESTART<br>
<br>
&END RESTART<br>
&END BFGS<br>
&END GEO_OPT<br>
&END MOTION<br>
<br>
<br>
<br>
<br>
</blockquote></div><br>