[CP2K-user] [CP2K:21737] MD dftd4 in version 2025.1

Frederick Stein f.stein at hzdr.de
Tue Aug 12 09:34:16 UTC 2025


Dear Somayeh,
If D4 is significantly more expensive than D3, how have you determined the 
cutoffs for D4? Have you made a convergence test on the accuracy of 
energies and forces?
Best,
Frederick

Somayeh Ahmadkhani schrieb am Dienstag, 12. August 2025 um 11:20:18 UTC+2:

> Dear Frederick,
>
> Thank you for your reply. Please find the details below:
>
>    - 
>    
>    *Hardware:* *I am running on an HPC cluster with CPU model and  I was 
>    shared my running script before.*
>    - 
>    
>    *System size:* My system contains *2454  molecules of water around 
>    7362 atoms* in total.
>    - 
>    
>    *Compilation details:*
>    - 
>       
>       For CP2K *version 7*, as follows
>       
>       CP2K version 7.1
>       
>        Source code revision git:e635599
>       
>        cp2kflags: omp libint fftw3 libxc elpa parallel mpi3 scalapack 
>       xsmm spglib mkl
>       
>        compiler: Intel(R) Fortran Intel(R) 64 Compiler Classic for 
>       applications running on Intel(R) 64, Version 2021.13.0 Build 20240602_000000
>       
>        compiler options:
>       
>          
>       -I/sw/chem/cp2k/2024.1/cpu-clx/intel_2024.2-impi_2021.13//spglib-2.5
>       
>          .0/install/include 
>       -I/sw/chem/cp2k/2024.1/cpu-clx/intel_2024.2-impi_
>       
>          
>       2021.13//elpa-new_release_2023.11.001/install/include/elpa_openmp-20
>       
>          23.11.001/modules 
>       -I/sw/chem/cp2k/2024.1/cpu-clx/intel_2024.2-impi_2
>       
>          
>       021.13//elpa-new_release_2023.11.001/install/include/elpa_openmp-202
>       
>          3.11.001/elpa 
>       -I/sw/chem/cp2k/2024.1/cpu-clx/intel_2024.2-impi_2021.
>       
>          13//libxsmm-1.17/install/include 
>       -I/sw/chem/cp2k/7.1/clx.el9/intel_2
>       
>          024.2-impi_2021.13//libxc-4.3.4/install/include 
>       -I/sw/chem/cp2k/2024
>       
>          
>       .1/cpu-clx/intel_2024.2-impi_2021.13//libint-v2.6.0-cp2k-lmax-5/inst
>       
>          all/include -I/sw/compiler/intel/oneapi/mkl/2024.2/include/fftw/ 
>       -I/
>       
>          sw/compiler/intel/oneapi/mkl/2024.2/include 
>       -I/sw/chem/cp2k/7.1/clx.
>       
>          el9/intel_2024.2-impi_2021.13/cp2k-7.1/src/start/ 
>       -I/sw/chem/cp2k/7.
>       
>          
>       1/clx.el9/intel_2024.2-impi_2021.13/cp2k-7.1/obj/local-static/psmp/e
>       
>          xts/dbcsr -I/sw/comm/impi/mpi/2021.13/include/mpi 
>       -I/sw/comm/impi/mp
>       
>          i/2021.13/include -I/sw/comm/impi/mpi/2021.13/include/mpi -c -O2 
>       -fP
>       
>          IC -fp-model precise -funroll-loops -qopenmp -qopenmp-simd 
>       -xCORE-AV
>       
>          X512 -m64 -D__parallel -D__MPI_F08 -D__SPGLIB -D__ELPA 
>       -D__LIBXSMM -
>       
>          D__LIBXC -D__LIBINT -D__FFTW3 -D__FFTW3_MKL -D__MKL 
>       -D__SCALAPACK -d
>       
>          iag-disable=8291 -diag-disable=8293 -diag-disable=10448 -fpp 
>       -fpscom
>       
>          p logicals -free -std08 -D__COMPILE_ARCH="local-static" 
>       "-D__COMPILE
>       
>          _DATE="Fri Sep 27 15:48:17 CEST 2024"" 
>       -D__COMPILE_HOST="bcn1357" -D
>       
>          __COMPILE_REVISION="git:e635599" 
>       -D__DATA_DIR="/sw/chem/cp2k/7.1/clx
>       
>          .el9/intel_2024.2-impi_2021.13/cp2k-7.1/data" 
>       -D__SHORT_FILE__="star
>       
>          t/cp2k.F" 
>       - 
>       
>       For CP2K *version 2025.1*,
>       
>        CP2K version 2025.1
>       
>        Source code revision git:9635df4
>       
>        cp2kflags: omp libint fftw3 fftw3_mkl libxc elpa parallel 
>       scalapack mpi_f08 cosma xsmm spglib mkl libdftd4 sirius hdf5
>       
>        compiler: Intel(R) Fortran Intel(R) 64 Compiler Classic for 
>       applications running on Intel(R) 64, Version 2021.13.1 Build 20240703_000000
>       
>        compiler options:
>       
>          
>       -I/home/bzfbpela/.local/easybuild/software/sirius/7.6.1-clx.el9.inte
>       
>          l//include/sirius 
>       -I/home/bzfbpela/.local/easybuild/software/pugixml
>       
>          /1.15-clx.el9.intel//include 
>       -I/home/bzfbpela/.local/easybuild/softw
>       
>          are/spla/1.6.1-clx.el9.intel//include 
>       -I/home/bzfbpela/.local/easybu
>       
>          ild/software/SpFFT/1.1.0-clx.el9.intel//include 
>       -I/sw/dataformats/hd
>       
>          f5/1.14.4.3/clx.el9/intel/include 
>       -I/sw/numerics/gsl/2.8/x86_64.el9/
>       
>          /include 
>       -I/home/bzfbpela/.local/easybuild/software/spglib/2.5.0-clx
>       
>          .el9.intel//include 
>       -I/home/bzfbpela/.local/easybuild/software/elpa/
>       
>          
>       2024.05.001-clx.el9.intel-ifort//include/elpa_openmp-2024.05.001/mod
>       
>          ules 
>       -I/home/bzfbpela/.local/easybuild/software/elpa/2024.05.001-clx
>       
>          .el9.intel-ifort//include/elpa_openmp-2024.05.001/elpa 
>       -I/home/bzfbp
>       
>          
>       ela/.local/easybuild/software/libxsmm/1.17-clx.el9.intel//include -I
>       
>          
>       /home/bzfbpela/.local/easybuild/software/libxc/6.2.2-clx.el9.intel//
>       
>          include 
>       -I/home/bzfbpela/.local/easybuild/software/libint-CP2K/2.6.0
>       
>          -clx.el9.intel//include 
>       -I/home/bzfbpela/.local/easybuild/software/C
>       
>          OSMA/2.6.6-clx.el9.intel//include/cosma 
>       -I/home/bzfbpela/.local/easy
>       
>          build/software/dftd4/3.7.0-clx.el9.intel//include/ 
>       -I/home/bzfbpela/
>       
>          
>       .local/easybuild/software/dftd4/3.7.0-clx.el9.intel//include//mctc-l
>       
>          ib/modules/ 
>       -I/home/bzfbpela/.local/easybuild/software/dftd4/3.7.0-c
>       
>          lx.el9.intel//include//dftd4/Intel-2021.1.0.20240703/ 
>       -I/sw/compiler
>       
>          /intel/oneapi/mkl/2024.2/include/fftw/ 
>       -I/sw/compiler/intel/oneapi/m
>       
>          kl/2024.2/include 
>       -I/home/bzfbpela/.local/easybuild/build/CP2K/2025.
>       
>          1/system-system-clx.el9.intel-ifort/cp2k-2025.1/src/start/ 
>       -I/home/b
>       
>          zfbpela/.local/easybuild/build/CP2K/2025.1/
>       system-system-clx.el9.int
>       
>          
>       el-ifort/cp2k-2025.1/obj/CP2K-2025.1-clx.el9.intel-ifort/psmp/exts/d
>       
>          bcsr -I/sw/comm/impi/mpi/2021.14/include/mpi 
>       -I/sw/comm/impi/mpi/202
>       
>          1.14/include -I/sw/comm/impi/mpi/2021.14/include/mpi -c -O2 
>       -fPIC -f
>       
>          p-model=precise -funroll-loops -qopenmp -qopenmp-simd 
>       -xCORE-AVX512 
>       
>          -m64 -traceback -D__parallel -D__MPI_F08 -D__INTEL_COMPILER 
>       -D__DATA
>       
>          _DIR= -D__SIRIUS -D__SPLA -D__SPFFT -D__HDF5 -D__GSL -D__SPGLIB 
>       -D__
>       
>          ELPA -D__LIBXSMM -D__LIBXC -D__LIBINT -D__COSMA -D__DFTD4 
>       -D__FFTW3 
>       
>          -D__FFTW3_MKL -D__MKL -D__SCALAPACK -diag-disable=8291 
>       -diag-disable
>       
>          =8293 -diag-disable=10448 -fpp -fpscomp logicals -free -std08 
>       -D__CO
>       
>          MPILE_ARCH="CP2K-2025.1-clx.el9.intel-ifort" 
>       "-D__COMPILE_DATE="Mon 
>       
>          Jun 16 17:51:46 CEST 2025"" -D__COMPILE_HOST="blogin7" 
>       -D__COMPILE_R
>       
>          EVISION="git:9635df4" 
>       -D__DATA_DIR="/home/bzfbpela/.local/easybuild/
>       
>          
>       build/CP2K/2025.1/system-system-clx.el9.intel-ifort/cp2k-2025.1/data
>       
>          " -D__SHORT_FILE__="start/cp2k.F" 
>       
>       
>       - 
>    
>    *Profiles:* I will prepare and share profiling results shortly. In the 
>    meantime, I will run CP2K in *ENERGY_FORCE*mode, as you suggested, to 
>    gather more information.
>    
> I was also shared input file earlier.
>
> Best regards,
> Somayeh Ahmadkhani
>
> On 12 Aug 2025, at 10:34 AM, Frederick Stein <f.s... at hzdr.de> wrote:
>
> Dear Somayeh,
> Generally, there a bunch of changes between versions 7 and 2025.2 making 
> it hard to tell what the exact issue is. Can you provide more details 
> regarding
> - What hardware are you running on?
>
> - How many atoms (or molecules etc.) does you system contain? My first 
> guess considering your box size size and your files names is ca. 4096 H2O 
> molecules.
>
> - How did you compile CP2K in both cases?
> - Can you provide profiles? It might already help to run CP2K in 
> ENERGE_FORCE mode instead of MD to get some ideas.
> Best,
> Frederick
>
>

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