[CP2K-user] [CP2K:20169] Re: Vibrational Analysis

Muhammad Rafiq rafiq789.ra at gmail.com
Sat May 4 14:26:47 UTC 2024


Like what should I write in input file for thermochemistry calculation?

On Sat, 4 May 2024, 9:32 pm Marcella Iannuzzi, <marci.akira at gmail.com>
wrote:

> Hi...
>
>
> THERMOCHEMISTRY*: logical**= F*
> <https://manual.cp2k.org/trunk/CP2K_INPUT/VIBRATIONAL_ANALYSIS.html#CP2K_INPUT.VIBRATIONAL_ANALYSIS.THERMOCHEMISTRY>
>
> *Lone keyword:* T
>
> Calculation of the thermochemical data. *Valid for molecules in the gas
> phase.*
>
>
> Regards
>
> Marcella
> On Friday, May 3, 2024 at 2:23:20 PM UTC+2 rafiq... at gmail.com wrote:
>
>> &VIBRATIONAL_ANALYSIS
>>   DX 0.1
>>   NPROC_REP 48
>>   TC_PRESSURE 101325
>>   TC_TEMPERATURE 298.15
>>   THERMOCHEMISTRY T
>>   FULLY_PERIODIC T
>> &END VIBRATIONAL_ANALYSIS
>>
>> Why in output file no thermochemistry? See my output file.
>>
>> VIB|                       142                  143                  144
>>  VIB|Frequency (cm^-1)   439.322414           439.460912
>> 445.868786
>>  VIB|Red.Masses (a.u.)    34.271393            34.269852
>>  34.289785
>>  VIB|Frc consts (a.u.)     0.003268             0.003272
>> 0.003469
>>   ATOM  EL             X     Y     Z        X     Y     Z        X     Y
>>     Z
>>      3  Mo            0.01 -0.00  0.02    -0.00  0.00  0.03    -0.00
>> -0.00 -0.03
>>      4  Mo            0.02 -0.00 -0.03    -0.00  0.01 -0.07     0.00
>>  0.00 -0.05
>>      8  P            -0.28  0.04  0.00     0.08 -0.17  0.00     0.00
>>  0.00  0.24
>>     11  Mo           -0.01 -0.00 -0.00     0.00 -0.00 -0.03    -0.00
>> -0.00 -0.03
>>     12  Mo           -0.02 -0.01  0.00     0.00 -0.01  0.07     0.00
>>  0.00 -0.05
>>     16  P             0.28  0.12  0.00    -0.08  0.17 -0.00     0.00
>>  0.00  0.24
>>     19  Mo            0.01 -0.00  0.02    -0.00  0.00  0.03     0.00
>> -0.00 -0.03
>>     20  Mo            0.02 -0.00 -0.03    -0.00  0.01 -0.07    -0.00
>>  0.00 -0.05
>>     24  P            -0.28  0.04  0.00     0.08 -0.16  0.00     0.00
>> -0.00  0.24
>>     27  Mo           -0.01 -0.00 -0.00     0.00 -0.00 -0.03     0.00
>> -0.00 -0.03
>>     28  Mo           -0.02 -0.01  0.00     0.00 -0.01  0.07    -0.00
>>  0.00 -0.05
>>     32  P             0.28  0.12 -0.00    -0.08  0.16 -0.01    -0.00
>> -0.00  0.24
>>     35  Mo           -0.00 -0.00 -0.04    -0.01  0.00  0.01     0.00
>>  0.00 -0.03
>>     36  Mo           -0.00 -0.00  0.08    -0.02  0.00 -0.02    -0.00
>> -0.00 -0.05
>>     40  P             0.07  0.08 -0.01     0.29 -0.04  0.00     0.00
>> -0.00  0.24
>>     43  Mo            0.00  0.00  0.02     0.01 -0.00 -0.01     0.00
>>  0.00 -0.03
>>     44  Mo            0.00  0.01 -0.05     0.02 -0.00  0.02    -0.00
>> -0.00 -0.05
>>     48  P            -0.07 -0.24  0.00    -0.29  0.04  0.00    -0.00
>> -0.00  0.24
>>     51  Mo           -0.00 -0.00 -0.04    -0.01  0.00  0.01     0.00
>>  0.00 -0.03
>>     52  Mo           -0.00 -0.00  0.08    -0.02  0.00 -0.02     0.00
>> -0.00 -0.05
>>     56  P             0.07  0.08 -0.01     0.29 -0.04  0.00     0.00
>> -0.00  0.25
>>     59  Mo            0.00  0.00  0.02     0.01 -0.00 -0.01    -0.00
>>  0.00 -0.03
>>     60  Mo            0.00  0.01 -0.05     0.02 -0.00  0.02     0.00
>> -0.00 -0.05
>>     64  P            -0.07 -0.24  0.00    -0.29  0.04 -0.00     0.00
>>  0.00  0.24
>>     67  Mo            0.01 -0.00  0.02    -0.00  0.00  0.03    -0.00
>> -0.00 -0.03
>>     68  Mo            0.02 -0.00 -0.03    -0.00  0.01 -0.07     0.00
>> -0.00 -0.05
>>     72  P            -0.27  0.04  0.00     0.07 -0.17  0.00     0.00
>>  0.00  0.24
>>     75  Mo           -0.01 -0.00 -0.00     0.00 -0.00 -0.03     0.00
>> -0.00 -0.03
>>     76  Mo           -0.02 -0.01  0.00     0.00 -0.01  0.07    -0.00
>> -0.00 -0.05
>>     80  P             0.27  0.12  0.00    -0.07  0.17 -0.00     0.00
>>  0.00  0.24
>>     83  Mo            0.01 -0.00  0.02    -0.00  0.00  0.03    -0.00
>> -0.00 -0.03
>>     84  Mo            0.02 -0.00 -0.03    -0.00  0.01 -0.07    -0.00
>> -0.00 -0.05
>>     88  P            -0.27  0.04  0.00     0.07 -0.17  0.00    -0.00
>>  0.00  0.24
>>     91  Mo           -0.01 -0.00 -0.00     0.00 -0.00 -0.03     0.00
>>  0.00 -0.03
>>     92  Mo           -0.02 -0.01  0.00     0.00 -0.01  0.07     0.00
>> -0.00 -0.05
>>     96  P             0.27  0.12 -0.00    -0.07  0.17 -0.00    -0.00
>>  0.00  0.24
>>     99  Mo           -0.00 -0.00 -0.04    -0.01  0.00  0.01    -0.00
>>  0.00 -0.03
>>    100  Mo           -0.00 -0.00  0.08    -0.02  0.00 -0.02    -0.00
>>  0.00 -0.05
>>    104  P             0.07  0.08 -0.01     0.29 -0.04 -0.00    -0.00
>> -0.00  0.24
>>    107  Mo            0.00  0.01  0.02     0.01 -0.00 -0.01     0.00
>>  0.00 -0.03
>>    108  Mo            0.00  0.01 -0.05     0.02 -0.00  0.02    -0.00
>>  0.00 -0.05
>>    112  P            -0.07 -0.24  0.00    -0.29  0.04 -0.00    -0.00
>> -0.00  0.24
>>    115  Mo           -0.00 -0.00 -0.04    -0.01  0.00  0.01    -0.00
>> -0.00 -0.03
>>    116  Mo           -0.00 -0.00  0.08    -0.02  0.00 -0.02     0.00
>>  0.00 -0.05
>>    120  P             0.07  0.08 -0.00     0.29 -0.05  0.00     0.00
>> -0.00  0.24
>>    123  Mo            0.00  0.01  0.02     0.01 -0.00 -0.01     0.00
>>  0.00 -0.03
>>    124  Mo            0.00  0.01 -0.05     0.02 -0.00  0.02    -0.00
>> -0.00 -0.05
>>    128  P            -0.07 -0.24  0.00    -0.29  0.05 -0.00     0.00
>> -0.00  0.24
>>
>>
>>
>>
>>  -------------------------------------------------------------------------------
>>  -
>>       -
>>  -                                DBCSR STATISTICS
>>       -
>>  -
>>       -
>>
>>  -------------------------------------------------------------------------------
>>  COUNTER                                    TOTAL       BLAS       SMM
>>     ACC
>>  flops inhomo. stacks                           0       0.0%      0.0%
>>    0.0%
>>  flops total                         0.000000E+00       0.0%      0.0%
>>    0.0%
>>  flops max/rank                      0.000000E+00       0.0%      0.0%
>>    0.0%
>>  matmuls inhomo. stacks                         0       0.0%      0.0%
>>    0.0%
>>  matmuls total                                  0       0.0%      0.0%
>>    0.0%
>>  number of processed stacks                     0       0.0%      0.0%
>>    0.0%
>>  average stack size                                     0.0       0.0
>>   0.0
>>  marketing flops                     0.000000E+00
>>
>>  -------------------------------------------------------------------------------
>>  -
>>       -
>>  -                      DBCSR MESSAGE PASSING PERFORMANCE
>>      -
>>  -
>>       -
>>
>>  -------------------------------------------------------------------------------
>>  ROUTINE             CALLS      AVE VOLUME [Bytes]
>>  MP_Bcast                1                     12.
>>  MP_Allreduce      1316782                      8.
>>  MP_Alltoall      12045666                 733641.
>>
>>  -------------------------------------------------------------------------------
>>
>> --
> You received this message because you are subscribed to the Google Groups
> "cp2k" group.
> To unsubscribe from this group and stop receiving emails from it, send an
> email to cp2k+unsubscribe at googlegroups.com.
> To view this discussion on the web visit
> https://groups.google.com/d/msgid/cp2k/60f3a959-3150-421a-b591-4538d437b6b6n%40googlegroups.com
> <https://groups.google.com/d/msgid/cp2k/60f3a959-3150-421a-b591-4538d437b6b6n%40googlegroups.com?utm_medium=email&utm_source=footer>
> .
>

-- 
You received this message because you are subscribed to the Google Groups "cp2k" group.
To unsubscribe from this group and stop receiving emails from it, send an email to cp2k+unsubscribe at googlegroups.com.
To view this discussion on the web visit https://groups.google.com/d/msgid/cp2k/CALQB3441XQ-aTSYeWAbmTkLw%3D%2B8kKqw%3D88YoyDk%2BPm42G8cZ7A%40mail.gmail.com.
-------------- next part --------------
An HTML attachment was scrubbed...
URL: <https://lists.cp2k.org/archives/cp2k-user/attachments/20240504/b33007cb/attachment-0001.htm>


More information about the CP2K-user mailing list