[CP2K-user] [CP2K:20168] Re: Vibrational Analysis

Marcella Iannuzzi marci.akira at gmail.com
Sat May 4 13:32:34 UTC 2024


Hi...


THERMOCHEMISTRY*: logical**= F* 
<https://manual.cp2k.org/trunk/CP2K_INPUT/VIBRATIONAL_ANALYSIS.html#CP2K_INPUT.VIBRATIONAL_ANALYSIS.THERMOCHEMISTRY>

*Lone keyword:* T

Calculation of the thermochemical data. *Valid for molecules in the gas 
phase.*


Regards

Marcella
On Friday, May 3, 2024 at 2:23:20 PM UTC+2 rafiq... at gmail.com wrote:

> &VIBRATIONAL_ANALYSIS
>   DX 0.1 
>   NPROC_REP 48
>   TC_PRESSURE 101325 
>   TC_TEMPERATURE 298.15 
>   THERMOCHEMISTRY T
>   FULLY_PERIODIC T
> &END VIBRATIONAL_ANALYSIS
>
> Why in output file no thermochemistry? See my output file.
>
> VIB|                       142                  143                  144
>  VIB|Frequency (cm^-1)   439.322414           439.460912           
> 445.868786
>  VIB|Red.Masses (a.u.)    34.271393            34.269852           
>  34.289785
>  VIB|Frc consts (a.u.)     0.003268             0.003272             
> 0.003469
>   ATOM  EL             X     Y     Z        X     Y     Z        X     Y   
>   Z  
>      3  Mo            0.01 -0.00  0.02    -0.00  0.00  0.03    -0.00 -0.00 
> -0.03
>      4  Mo            0.02 -0.00 -0.03    -0.00  0.01 -0.07     0.00  0.00 
> -0.05
>      8  P            -0.28  0.04  0.00     0.08 -0.17  0.00     0.00  0.00 
>  0.24
>     11  Mo           -0.01 -0.00 -0.00     0.00 -0.00 -0.03    -0.00 -0.00 
> -0.03
>     12  Mo           -0.02 -0.01  0.00     0.00 -0.01  0.07     0.00  0.00 
> -0.05
>     16  P             0.28  0.12  0.00    -0.08  0.17 -0.00     0.00  0.00 
>  0.24
>     19  Mo            0.01 -0.00  0.02    -0.00  0.00  0.03     0.00 -0.00 
> -0.03
>     20  Mo            0.02 -0.00 -0.03    -0.00  0.01 -0.07    -0.00  0.00 
> -0.05
>     24  P            -0.28  0.04  0.00     0.08 -0.16  0.00     0.00 -0.00 
>  0.24
>     27  Mo           -0.01 -0.00 -0.00     0.00 -0.00 -0.03     0.00 -0.00 
> -0.03
>     28  Mo           -0.02 -0.01  0.00     0.00 -0.01  0.07    -0.00  0.00 
> -0.05
>     32  P             0.28  0.12 -0.00    -0.08  0.16 -0.01    -0.00 -0.00 
>  0.24
>     35  Mo           -0.00 -0.00 -0.04    -0.01  0.00  0.01     0.00  0.00 
> -0.03
>     36  Mo           -0.00 -0.00  0.08    -0.02  0.00 -0.02    -0.00 -0.00 
> -0.05
>     40  P             0.07  0.08 -0.01     0.29 -0.04  0.00     0.00 -0.00 
>  0.24
>     43  Mo            0.00  0.00  0.02     0.01 -0.00 -0.01     0.00  0.00 
> -0.03
>     44  Mo            0.00  0.01 -0.05     0.02 -0.00  0.02    -0.00 -0.00 
> -0.05
>     48  P            -0.07 -0.24  0.00    -0.29  0.04  0.00    -0.00 -0.00 
>  0.24
>     51  Mo           -0.00 -0.00 -0.04    -0.01  0.00  0.01     0.00  0.00 
> -0.03
>     52  Mo           -0.00 -0.00  0.08    -0.02  0.00 -0.02     0.00 -0.00 
> -0.05
>     56  P             0.07  0.08 -0.01     0.29 -0.04  0.00     0.00 -0.00 
>  0.25
>     59  Mo            0.00  0.00  0.02     0.01 -0.00 -0.01    -0.00  0.00 
> -0.03
>     60  Mo            0.00  0.01 -0.05     0.02 -0.00  0.02     0.00 -0.00 
> -0.05
>     64  P            -0.07 -0.24  0.00    -0.29  0.04 -0.00     0.00  0.00 
>  0.24
>     67  Mo            0.01 -0.00  0.02    -0.00  0.00  0.03    -0.00 -0.00 
> -0.03
>     68  Mo            0.02 -0.00 -0.03    -0.00  0.01 -0.07     0.00 -0.00 
> -0.05
>     72  P            -0.27  0.04  0.00     0.07 -0.17  0.00     0.00  0.00 
>  0.24
>     75  Mo           -0.01 -0.00 -0.00     0.00 -0.00 -0.03     0.00 -0.00 
> -0.03
>     76  Mo           -0.02 -0.01  0.00     0.00 -0.01  0.07    -0.00 -0.00 
> -0.05
>     80  P             0.27  0.12  0.00    -0.07  0.17 -0.00     0.00  0.00 
>  0.24
>     83  Mo            0.01 -0.00  0.02    -0.00  0.00  0.03    -0.00 -0.00 
> -0.03
>     84  Mo            0.02 -0.00 -0.03    -0.00  0.01 -0.07    -0.00 -0.00 
> -0.05
>     88  P            -0.27  0.04  0.00     0.07 -0.17  0.00    -0.00  0.00 
>  0.24
>     91  Mo           -0.01 -0.00 -0.00     0.00 -0.00 -0.03     0.00  0.00 
> -0.03
>     92  Mo           -0.02 -0.01  0.00     0.00 -0.01  0.07     0.00 -0.00 
> -0.05
>     96  P             0.27  0.12 -0.00    -0.07  0.17 -0.00    -0.00  0.00 
>  0.24
>     99  Mo           -0.00 -0.00 -0.04    -0.01  0.00  0.01    -0.00  0.00 
> -0.03
>    100  Mo           -0.00 -0.00  0.08    -0.02  0.00 -0.02    -0.00  0.00 
> -0.05
>    104  P             0.07  0.08 -0.01     0.29 -0.04 -0.00    -0.00 -0.00 
>  0.24
>    107  Mo            0.00  0.01  0.02     0.01 -0.00 -0.01     0.00  0.00 
> -0.03
>    108  Mo            0.00  0.01 -0.05     0.02 -0.00  0.02    -0.00  0.00 
> -0.05
>    112  P            -0.07 -0.24  0.00    -0.29  0.04 -0.00    -0.00 -0.00 
>  0.24
>    115  Mo           -0.00 -0.00 -0.04    -0.01  0.00  0.01    -0.00 -0.00 
> -0.03
>    116  Mo           -0.00 -0.00  0.08    -0.02  0.00 -0.02     0.00  0.00 
> -0.05
>    120  P             0.07  0.08 -0.00     0.29 -0.05  0.00     0.00 -0.00 
>  0.24
>    123  Mo            0.00  0.01  0.02     0.01 -0.00 -0.01     0.00  0.00 
> -0.03
>    124  Mo            0.00  0.01 -0.05     0.02 -0.00  0.02    -0.00 -0.00 
> -0.05
>    128  P            -0.07 -0.24  0.00    -0.29  0.05 -0.00     0.00 -0.00 
>  0.24
>
>
>
>
>  -------------------------------------------------------------------------------
>  -                                                                         
>     -
>  -                                DBCSR STATISTICS                         
>     -
>  -                                                                         
>     -
>
>  -------------------------------------------------------------------------------
>  COUNTER                                    TOTAL       BLAS       SMM     
>   ACC
>  flops inhomo. stacks                           0       0.0%      0.0%     
>  0.0%
>  flops total                         0.000000E+00       0.0%      0.0%     
>  0.0%
>  flops max/rank                      0.000000E+00       0.0%      0.0%     
>  0.0%
>  matmuls inhomo. stacks                         0       0.0%      0.0%     
>  0.0%
>  matmuls total                                  0       0.0%      0.0%     
>  0.0%
>  number of processed stacks                     0       0.0%      0.0%     
>  0.0%
>  average stack size                                     0.0       0.0     
>   0.0
>  marketing flops                     0.000000E+00
>
>  -------------------------------------------------------------------------------
>  -                                                                         
>     -
>  -                      DBCSR MESSAGE PASSING PERFORMANCE                 
>      -
>  -                                                                         
>     -
>
>  -------------------------------------------------------------------------------
>  ROUTINE             CALLS      AVE VOLUME [Bytes]
>  MP_Bcast                1                     12.
>  MP_Allreduce      1316782                      8.
>  MP_Alltoall      12045666                 733641.
>
>  -------------------------------------------------------------------------------
>
>

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