[CP2K-user] [CP2K:16263] error when using surface dipole correction in geometry optimization

'zhang yipu' via cp2k cp2k at googlegroups.com
Thu Nov 18 09:14:56 UTC 2021


Dear all:
    It's ok that I used the surface dipole correction when  geometric 
optimization for pure ceria (1 1 1) surface, however, there is an error 
when I put a single atom Pd on the surface.
 [image: 1.png]
Any help would be very much appreciated!!!

-- 
You received this message because you are subscribed to the Google Groups "cp2k" group.
To unsubscribe from this group and stop receiving emails from it, send an email to cp2k+unsubscribe at googlegroups.com.
To view this discussion on the web visit https://groups.google.com/d/msgid/cp2k/8a0738f5-7533-49d6-aa9c-964bf0e0e14dn%40googlegroups.com.
-------------- next part --------------
An HTML attachment was scrubbed...
URL: <https://lists.cp2k.org/archives/cp2k-user/attachments/20211118/0e34b0dd/attachment.htm>
-------------- next part --------------
A non-text attachment was scrubbed...
Name: 1.png
Type: image/png
Size: 5340 bytes
Desc: not available
URL: <https://lists.cp2k.org/archives/cp2k-user/attachments/20211118/0e34b0dd/attachment.png>
-------------- next part --------------
A non-text attachment was scrubbed...
Name: CeO2single.xyz
Type: chemical/x-xyz
Size: 9877 bytes
Desc: not available
URL: <https://lists.cp2k.org/archives/cp2k-user/attachments/20211118/0e34b0dd/attachment.xyz>
-------------- next part --------------
SIRIUS 7.0.0, git hash: https://api.github.com/repos/electronic-structure/SIRIUS/git/ref/tags/v7.0.0
 DBCSR| CPU Multiplication driver                                           XSMM
 DBCSR| Multrec recursion limit                                              512
 DBCSR| Multiplication stack size                                           1000
 DBCSR| Maximum elements for images                                    UNLIMITED
 DBCSR| Multiplicative factor virtual images                                   1
 DBCSR| Use multiplication densification                                       T
 DBCSR| Multiplication size stacks                                             3
 DBCSR| Use memory pool for CPU allocation                                     F
 DBCSR| Number of 3D layers                                               SINGLE
 DBCSR| Use MPI memory allocation                                              F
 DBCSR| Use RMA algorithm                                                      F
 DBCSR| Use Communication thread                                               T
 DBCSR| Communication thread load                                             87
 DBCSR| MPI: My node id                                                        0
 DBCSR| MPI: Number of nodes                                                  18
 DBCSR| OMP: Current number of threads                                         1
 DBCSR| OMP: Max number of threads                                             1
 DBCSR| Split modifier for TAS multiplication algorithm                  1.0E+00


  **** **** ******  **  PROGRAM STARTED AT               2021-11-17 21:03:46.562
 ***** ** ***  *** **   PROGRAM STARTED ON                                master
 **    ****   ******    PROGRAM STARTED BY                                   zyp
 ***** **    ** ** **   PROGRAM PROCESS ID                                162665
  **** **  *******  **  PROGRAM STARTED IN /public/home/zyp/postgraduate3/1116_1
                                           10_7layer/pd42_surface

 CP2K| version string:                                          CP2K version 8.1
 CP2K| source code revision number:                                  git:0b61f2f
 CP2K| cp2kflags: omp libint fftw3 libxc elpa parallel mpi3 scalapack xsmm spgli
 CP2K|            b mkl sirius libvori libbqb
 CP2K| is freely available from                            https://www.cp2k.org/
 CP2K| Program compiled at                          Sun May 30 09:33:47 CST 2021
 CP2K| Program compiled on                                                master
 CP2K| Program compiled for                                                local
 CP2K| Data directory path                        /public/software/cp2k-8.1/data
 CP2K| Input file name                                              ceo2cp2k.inp

 GLOBAL| Force Environment number                                              1
 GLOBAL| Basis set file name                                      ./BASIS_MOLOPT
 GLOBAL| Potential file name                                          ./POTENIAL
 GLOBAL| MM Potential file name                                     MM_POTENTIAL
 GLOBAL| Coordinate file name                                   ./CeO2single.xyz
 GLOBAL| Method name                                                        CP2K
 GLOBAL| Project name                                                   ceria-01
 GLOBAL| Preferred FFT library                                             FFTW3
 GLOBAL| Preferred diagonalization lib.                                     ELPA
 GLOBAL| Run type                                                        GEO_OPT
 GLOBAL| All-to-all communication in single precision                          F
 GLOBAL| FFTs using library dependent lengths                                  F
 GLOBAL| Global print level                                                  LOW
 GLOBAL| MPI I/O enabled                                                       T
 GLOBAL| Total number of message passing processes                            18
 GLOBAL| Number of threads for this process                                    1
 GLOBAL| This output is from process                                           0
 GLOBAL| CPU model name            Intel(R) Xeon(R) Platinum 8171M CPU @ 2.60GHz
 GLOBAL| CPUID                                                              1003

 MEMORY| system memory details [Kb]
 MEMORY|                        rank 0           min           max       average
 MEMORY| MemTotal            196513016     196512976     196513016     196512996
 MEMORY| MemFree              82003160      73063004      82003160      77533082
 MEMORY| Buffers                  1080           212          1080           646
 MEMORY| Cached               14846864      14846864      28652420      21749642
 MEMORY| Slab                  1286164        974176       1286164       1130170
 MEMORY| SReclaimable           705916        590648        705916        648282
 MEMORY| MemLikelyFree        97557020      97557020     102306284      99931652


 GENERATE|  Preliminary Number of Bonds generated:                             0
 GENERATE|  Achieved consistency in connectivity generation.

 *******************************************************************************
 *******************************************************************************
 **                                                                           **
 **     #####                         ##              ##                      **
 **    ##   ##            ##          ##              ##                      **
 **   ##     ##                       ##            ######                    **
 **   ##     ##  ##   ##  ##   #####  ##  ##   ####   ##    #####    #####    **
 **   ##     ##  ##   ##  ##  ##      ## ##   ##      ##   ##   ##  ##   ##   **
 **   ##  ## ##  ##   ##  ##  ##      ####     ###    ##   ######   ######    **
 **    ##  ###   ##   ##  ##  ##      ## ##      ##   ##   ##       ##        **
 **     #######   #####   ##   #####  ##  ##  ####    ##    #####   ##        **
 **           ##                                                    ##        **
 **                                                                           **
 **                                                ... make the atoms dance   **
 **                                                                           **
 **            Copyright (C) by CP2K developers group (2000 - 2020)           **
 **                      J. Chem. Phys. 152, 194103 (2020)                    **
 **                                                                           **
 *******************************************************************************


 TOTAL NUMBERS AND MAXIMUM NUMBERS

  Total number of            - Atomic kinds:                                   3
                             - Atoms:                                        254
                             - Shell sets:                                   590
                             - Shells:                                      2366
                             - Primitive Cartesian functions:               2028
                             - Cartesian basis functions:                   9468
                             - Spherical basis functions:                   7946

  Maximum angular momentum of- Orbital basis functions:                        3
                             - Local part of the GTH pseudopotential:          2
                             - Non-local part of the GTH pseudopotential:      4


 SCF PARAMETERS         Density guess:                                    ATOMIC
                        --------------------------------------------------------
                        max_scf:                                              30
                        max_scf_history:                                       0
                        max_diis:                                              4
                        --------------------------------------------------------
                        eps_scf:                                        1.00E-07
                        eps_scf_history:                                0.00E+00
                        eps_diis:                                       1.00E-01
                        eps_eigval:                                     1.00E-05
                        --------------------------------------------------------
                        level_shift [a.u.]:                                 0.00
                        --------------------------------------------------------
                        Outer loop SCF in use 
                        No variables optimised in outer loop
                        eps_scf                                         1.00E-07
                        max_scf                                               20
                        No outer loop optimization
                        step_size                                       5.00E-01

 BFGS| Use rational function optimization for step estimation:                NO
 BFGS| Use model Hessian for initial guess:                                  YES
 BFGS| Restart Hessian:                                                       NO
 BFGS| Trust radius:                                                       0.472

 *******************************************************************************
 ***                     STARTING GEOMETRY OPTIMIZATION                      ***
 ***                                   BFGS                                  ***
 *******************************************************************************

 Spin 1

 Number of electrons:                                                       1026
 Number of occupied orbitals:                                               1026
 Number of molecular orbitals:                                              1026

 Spin 2

 Number of electrons:                                                       1026
 Number of occupied orbitals:                                               1026
 Number of molecular orbitals:                                              1026

 Number of orbital functions:                                               7946
 Number of independent orbital functions:                                   7946

 Extrapolation method: initial_guess


 SCF WAVEFUNCTION OPTIMIZATION

  ----------------------------------- OT ---------------------------------------
  Minimizer      : DIIS                : direct inversion
                                         in the iterative subspace
                                         using   7 DIIS vectors
                                         safer DIIS on
  Preconditioner : FULL_SINGLE_INVERSE : inversion of 
                                         H + eS - 2*(Sc)(c^T*H*c+const)(Sc)^T
  Precond_solver : DEFAULT
  stepsize       :    0.08000000                  energy_gap     :    0.08000000
  eps_taylor     :   0.10000E-15                  max_taylor     :             4
  ----------------------------------- OT ---------------------------------------

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------

 *******************************************************************************
 *   ___                                                                       *
 *  /   \                                                                      *
 * [ABORT]                                                                     *
 *  \___/                         No suitable data field                       *
 *    |                                                                        *
 *  O/|                                                                        *
 * /| |                                                                        *
 * / \                                                     pw/pw_methods.F:875 *
 *******************************************************************************


 ===== Routine Calling Stack ===== 

           13 pw_axpy
           12 calc_dipsurf_potential
           11 qs_ks_build_kohn_sham_matrix
           10 rebuild_ks_matrix
            9 qs_ks_update_qs_env
            8 init_scf_loop
            7 scf_env_do_scf
            6 qs_energies
            5 qs_forces
            4 cp_eval_at
            3 geoopt_bfgs
            2 cp_geo_opt
            1 CP2K
-------------- next part --------------
A non-text attachment was scrubbed...
Name: ceo2cp2k.inp
Type: chemical/x-gamess-input
Size: 2216 bytes
Desc: not available
URL: <https://lists.cp2k.org/archives/cp2k-user/attachments/20211118/0e34b0dd/attachment.inp>


More information about the CP2K-user mailing list