[CP2K-user] [CP2K:14996] QM geometry optimisation on a Transition Metal (Fe2+)

salo...@gmail.com salome.l... at gmail.com
Wed Mar 24 13:43:52 UTC 2021


Dear Juerg, 

It shouldn't crash unless I used >3900MB. I'll try to increase the memory 
when submitting the job.
Sorry, about the files. I cannot attach the files I have copied them to 
this email. 

Thanks a lot!

This is the input file: 

&GLOBAL

  PROJECT AMT

  RUN_TYPE GEO_OPT

  PRINT_LEVEL LOW

&END GLOBAL


&FORCE_EVAL

  METHOD QS

  &SUBSYS

    &CELL

      ABC 40 40 40

    &END CELL

    &COORD

C         -6.42000        2.27900       47.86600

...

   &END COORD

    &KIND H

      BASIS_SET DZVP-GTH-PADE

      POTENTIAL GTH-PADE-q1

    &END KIND

    &KIND C

      BASIS_SET DZVP-GTH-PADE

      POTENTIAL GTH-PADE-q4

    &END KIND

    &KIND N

      BASIS_SET DZVP-GTH-PADE

      POTENTIAL GTH-PADE-q5

    &END KIND

    &KIND O

      BASIS_SET DZVP-GTH-PADE

      POTENTIAL GTH-PADE-q6

    &END KIND

    &KIND Fe

      BASIS_SET DZV-GTH-PADE

      POTENTIAL GTH-PADE-q16

    &END KIND



  &END SUBSYS

  &DFT

    CHARGE -2

    BASIS_SET_FILE_NAME ./BASIS_SET

    POTENTIAL_FILE_NAME ./POTENTIAL

    &QS

      EPS_DEFAULT 1.0E-7

    &END QS

    &MGRID

      CUTOFF 200

      NGRIDS 4

      REL_CUTOFF 30

    &END MGRID

    &SCF

      SCF_GUESS ATOMIC

      EPS_SCF 1.0E-05

      MAX_SCF 200

      &DIAGONALIZATION T

        ALGORITHM STANDARD

      &END DIAGONALIZATION

      &MIXING T

        ALPHA 0.5

        METHOD PULAY_MIXING

        NPULAY 5

      &END MIXING

      &PRINT

        &RESTART OFF

        &END RESTART

      &END PRINT

    &END SCF

    &XC

      &XC_FUNCTIONAL PADE

      &END XC_FUNCTIONAL

    &END XC

  &END DFT

&END FORCE_EVAL

&MOTION

  &GEO_OPT

    TYPE MINIMIZATION

    MAX_DR    1.0E-03

    MAX_FORCE 1.0E-03

    RMS_DR    1.0E-03

    RMS_FORCE 1.0E-03

    MAX_ITER 200

    OPTIMIZER CG

    &CG

      MAX_STEEP_STEPS  0

      RESTART_LIMIT 9.0E-01

    &END CG

  &END GEO_OPT

  &CONSTRAINT

    &FIXED_ATOMS

      COMPONENTS_TO_FIX XYZ

      LIST 1

    &END FIXED_ATOMS

  &END CONSTRAINT

&END MOTION

And this is the output I get: 

DBCSR| Multiplication driver                                               
BLAS

 DBCSR| Multrec recursion limit                                            
  512

 DBCSR| Multiplication stack size                                           
1000

 DBCSR| Maximum elements for images                                    
UNLIMITED

 DBCSR| Multiplicative factor virtual images                               
    1

 DBCSR| Multiplication size stacks                                         
    3

 DBCSR| Number of 3D layers                                               
SINGLE

 DBCSR| Use MPI memory allocation                                          
    T

 DBCSR| Use RMA algorithm                                                  
    F

 DBCSR| Use Communication thread                                           
    T

 DBCSR| Communication thread load                                           
  87



  **** **** ******  **  PROGRAM STARTED AT               2021-03-24 
14:18:50.840

 ***** ** ***  *** **   PROGRAM STARTED ON                            
pirineus29

 **    ****   ******    PROGRAM STARTED BY                              
ubafar01

 ***** **    ** ** **   PROGRAM PROCESS ID                                 
35914

  **** **  *******  **  PROGRAM STARTED IN                 
/tmp/ubafar01/1736286


 CP2K| version string:                    CP2K version 7.0 (Development 
Version)

 CP2K| source code revision number:

 CP2K| cp2kflags: libint fftw3 parallel mpi3 scalapack libderiv_max_am1=5 
libint

 CP2K|            _max_am=5 max_contr=4 mkl

 CP2K| is freely available from                            
https://www.cp2k.org/

 CP2K| Program compiled at                         Thu Jun 14 14:14:04 CEST 
2018

 CP2K| Program compiled on                                             
pirineus1

 CP2K| Program compiled for                                   
Linux-x86-64-intel

 CP2K| Data directory path                
/prod/apps/cp2k/src/cp2k-6.1/cp2k/data

 CP2K| Input file name                                                   
AMT.inp


 GLOBAL| Force Environment number                                          
    1

 GLOBAL| Basis set file name                                         
./BASIS_SET

 GLOBAL| Potential file name                                         
./POTENTIAL

 GLOBAL| MM Potential file name                                     
MM_POTENTIAL

 GLOBAL| Coordinate file name                                      
__STD_INPUT__

 GLOBAL| Method name                                                        
CP2K

 GLOBAL| Project name                                                      
  AMT

 GLOBAL| Preferred FFT library                                             
FFTW3

 GLOBAL| Preferred diagonalization lib.                                     
  SL

 GLOBAL| Run type                                                        
GEO_OPT

 GLOBAL| All-to-all communication in single precision                      
    F

 GLOBAL| FFTs using library dependent lengths                              
    F

 GLOBAL| Global print level                                                
  LOW

 GLOBAL| Total number of message passing processes                         
    1

 GLOBAL| Number of threads for this process                                
    1

 GLOBAL| This output is from process                                       
    0

 GLOBAL| CPU model name :  Intel(R) Xeon(R) Platinum 8168 CPU @ 2.70GHz


 MEMORY| system memory details [Kb]

 MEMORY|                        rank 0           min           max       
average

 MEMORY| MemTotal            196510368     196510368     196510368     
196510368

 MEMORY| MemFree             127368532     127368532     127368532     
127368532

 MEMORY| Buffers                347976        347976        347976        
347976

 MEMORY| Cached               46386224      46386224      46386224      
46386224

 MEMORY| Slab                  1120960       1120960       1120960       
1120960

 MEMORY| SReclaimable           827652        827652        827652        
827652

 MEMORY| MemLikelyFree       174930384     174930384     174930384     
174930384



 GENERATE|  Preliminary Number of Bonds generated:                         
    0

 GENERATE|  Achieved consistency in connectivity generation.


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 **                                                ... make the atoms dance 
  **

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 **            Copyright (C) by CP2K developers group (2000 - 2018)         
  **

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  **

 *******************************************************************************

 TOTAL NUMBERS AND MAXIMUM NUMBERS


  Total number of            - Atomic kinds:                               
    5

                             - Atoms:                                       
  91

                             - Shell sets:                                 
  181

                             - Shells:                                     
  381

                             - Primitive Cartesian functions:              
  456

                             - Cartesian basis functions:                  
  939

                             - Spherical basis functions:                  
  885


  Maximum angular momentum of- Orbital basis functions:                    
    2

                             - Local part of the GTH pseudopotential:      
    2

                             - Non-local part of the GTH pseudopotential:  
    3



 SCF PARAMETERS         Density guess:                                    
ATOMIC

                        
--------------------------------------------------------

                        max_scf:                                           
  200

                        max_scf_history:                                   
    0

                        max_diis:                                          
    4

                        
--------------------------------------------------------

                        eps_scf:                                        
1.00E-05

                        eps_scf_history:                                
0.00E+00

                        eps_diis:                                       
1.00E-01

                        eps_eigval:                                     
1.00E-05

                        
--------------------------------------------------------

                        level_shift [a.u.]:                                 
0.00

                        
--------------------------------------------------------

                        Mixing method:                              
PULAY_MIXING

                                                charge density mixing in 
g-space

                        
--------------------------------------------------------

                        No outer SCF


Salome

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