[CP2K-user] Running GEO_OPT on big Cu nanoparticles

Hasan Al-Mahayni hasanal... at gmail.com
Fri Jun 18 01:51:28 UTC 2021


Hello Everyone,

I am trying to run DFT GEO_OPT using CP2K on Cu nanoparticles created by 
ASE's Wolff construction. I started at 13 atoms, and slowly made them 
bigger. My biggest successful run is 365 atoms. However, I am getting the 
same error when I try with 489 atoms... I asked the support team on my 
virtual machine what is the problem and they said it is not a memory 
problem but rather a CP2K problem... I will attach my input file, xyz file 
and error file I am getting. I will also attach my results file, where it 
was working fine in the SCF loop then it suddenly stopped... Any ideas on 
how to solve with would be much appreciated!

Thanks,

Hasan.


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 DBCSR| Multiplication driver                                               XSMM
 DBCSR| Multrec recursion limit                                              512
 DBCSR| Multiplication stack size                                           1000
 DBCSR| Maximum elements for images                                    UNLIMITED
 DBCSR| Multiplicative factor virtual images                                   1
 DBCSR| Randmat seed                                                    12341313
 DBCSR| Multiplication size stacks                                             3
 DBCSR| Number of 3D layers                                               SINGLE
 DBCSR| Use MPI memory allocation                                              T
 DBCSR| Use RMA algorithm                                                      F
 DBCSR| Use Communication thread                                               T
 DBCSR| Communication thread load                                             87


  **** **** ******  **  PROGRAM STARTED AT               2021-05-25 09:53:53.177
 ***** ** ***  *** **   PROGRAM STARTED ON        cdr1960.int.cedar.computecanad
 **    ****   ******    PROGRAM STARTED BY                               hasan99
 ***** **    ** ** **   PROGRAM PROCESS ID                                105644
  **** **  *******  **  PROGRAM STARTED IN /project/6029546/hasan99/surfaceenerg
                                           y/SE/Cu2.5/111/2.2

 CP2K| version string:                                          CP2K version 4.1
 CP2K| source code revision number:                                    svn:17462
 CP2K| cp2kflags: libint fftw3 libxc parallel mpi3 scalapack libxsmm plumed2    
 CP2K| is freely available from                            https://www.cp2k.org/
 CP2K| Program compiled at                          Wed_Apr_26_01:50:37_UTC_2017
 CP2K| Program compiled on                           build-node.computecanada.ca
 CP2K| Program compiled for                                   Linux-x86-64-gomkl
 CP2K| Data directory path    /cvmfs/soft.computecanada.ca/easybuild/software/20
 CP2K| Input file name                                                  cp2k.inp

 GLOBAL| Force Environment number                                              1
 GLOBAL| Basis set file name                                        BASIS_MOLOPT
 GLOBAL| Potential file name                                      GTH_POTENTIALS
 GLOBAL| MM Potential file name                                     MM_POTENTIAL
 GLOBAL| Coordinate file name                                Cu_111_21.983nm.xyz
 GLOBAL| Method name                                                        CP2K
 GLOBAL| Project name                                                       cp2k
 GLOBAL| Preferred FFT library                                             FFTW3
 GLOBAL| Preferred diagonalization lib.                                       SL
 GLOBAL| Run type                                                        GEO_OPT
 GLOBAL| All-to-all communication in single precision                          F
 GLOBAL| FFTs using library dependent lengths                                  T
 GLOBAL| Global print level                                                  LOW
 GLOBAL| Total number of message passing processes                           384
 GLOBAL| Number of threads for this process                                    1
 GLOBAL| This output is from process                                           0
 GLOBAL| CPU model name :  Intel(R) Xeon(R) Platinum 8260 CPU @ 2.40GHz

 MEMORY| system memory details [Kb]
 MEMORY|                        rank 0           min           max       average
 MEMORY| MemTotal            196629328     196629328     196629328     196629328
 MEMORY| MemFree             161537544     149422640     176042348     162007125
 MEMORY| Buffers                     0             0           144            12
 MEMORY| Cached               25697152      12237292      36050532      25003999
 MEMORY| Slab                  2248196       1371980       3767592       2437018
 MEMORY| SReclaimable          1343012        565188       2260120       1381154
 MEMORY| MemLikelyFree       188577708     187650764     189028748     188392291


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 **                                                                           **
 **                                                ... make the atoms dance   **
 **                                                                           **
 **            Copyright (C) by CP2K developers group (2000 - 2016)           **
 **                                                                           **
 *******************************************************************************


 SCF PARAMETERS         Density guess:                                   RESTART
                        --------------------------------------------------------
                        max_scf:                                             100
                        max_scf_history:                                       0
                        max_diis:                                              4
                        --------------------------------------------------------
                        eps_scf:                                        1.00E-06
                        eps_scf_history:                                0.00E+00
                        eps_diis:                                       1.00E-01
                        eps_eigval:                                     1.00E-05
                        --------------------------------------------------------
                        level_shift [a.u.]:                                 0.00
                        added MOs                                       200  200
                        --------------------------------------------------------
                        Mixing method:                            BROYDEN_MIXING
                                                charge density mixing in g-space
                        --------------------------------------------------------
                        Smear method:                                FERMI_DIRAC
                        Electronic temperature [K]:                        300.0
                        Electronic temperature [a.u.]:                  9.50E-04
                        Accuracy threshold:                             1.00E-10
                        --------------------------------------------------------
                        No outer SCF

 *******************************************************************************
 ***                     STARTING GEOMETRY OPTIMIZATION                      ***
 ***                                   BFGS                                  ***
 *******************************************************************************

 Spin 1

 Number of electrons:                                                       2690
 Number of occupied orbitals:                                               2690
 Number of molecular orbitals:                                              2890

 Spin 2

 Number of electrons:                                                       2689
 Number of occupied orbitals:                                               2689
 Number of molecular orbitals:                                              2889

 Number of orbital functions:                                              12225
 Number of independent orbital functions:                                  12225

 Extrapolation method: initial_guess

 *** WARNING in qs_initial_guess.F:262 :: User requested to restart the    ***
 *** wavefunction from the file named: cp2k-RESTART.wfn. This file does    ***
 *** not exist. Please check the existence of the file or change properly  ***
 *** the value of the keyword WFN_RESTART_FILE_NAME. Calculation continues ***
 *** using ATOMIC GUESS.                                                   ***



 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 NoMix/Diag. 0.40E+00   31.2     0.20709644    -23528.6555509050 -2.35E+04
     2 Broy./Diag. 0.40E+00   33.8     0.10453966    -24068.6070094628 -5.40E+02
     3 Broy./Diag. 0.40E+00   33.8     0.04203327    -23534.4962532859  5.34E+02
     4 Broy./Diag. 0.40E+00   33.8     0.00980937    -23542.2443397723 -7.75E+00
     5 Broy./Diag. 0.40E+00   33.5     0.01776464    -23531.1896903687  1.11E+01
     6 Broy./Diag. 0.40E+00   33.7     0.00609945    -23527.9887829846  3.20E+00
     7 Broy./Diag. 0.40E+00   33.8     0.00319991    -23526.7858742043  1.20E+00
     8 Broy./Diag. 0.40E+00   33.4     0.00223329    -23527.0540527969 -2.68E-01
     9 Broy./Diag. 0.40E+00   33.5     0.00149592    -23527.2263305393 -1.72E-01
    10 Broy./Diag. 0.40E+00   33.9     0.00116415    -23527.3298425352 -1.04E-01
    11 Broy./Diag. 0.40E+00   33.8     0.00161151    -23527.3091090950  2.07E-02
    12 Broy./Diag. 0.40E+00   33.8     0.00086074    -23527.5698856568 -2.61E-01
    13 Broy./Diag. 0.40E+00   33.7     0.00056786    -23527.7703460914 -2.00E-01
    14 Broy./Diag. 0.40E+00   34.0     0.00045549    -23527.8497066586 -7.94E-02
    15 Broy./Diag. 0.40E+00   33.7     0.00025166    -23527.8916823658 -4.20E-02
    16 Broy./Diag. 0.40E+00   33.7     0.00018601    -23527.8863173012  5.37E-03
    17 Broy./Diag. 0.40E+00   33.8     0.00008766    -23527.9116172821 -2.53E-02
    18 Broy./Diag. 0.40E+00   34.3     0.00006850    -23527.9291537094 -1.75E-02
    19 Broy./Diag. 0.40E+00   34.0     0.00005256    -23527.9267560618  2.40E-03
    20 Broy./Diag. 0.40E+00   33.9     0.00009059    -23527.9240853974  2.67E-03
    21 Broy./Diag. 0.40E+00   34.2     0.00003649    -23527.9259455132 -1.86E-03
    22 Broy./Diag. 0.40E+00   33.8     0.00003352    -23527.9215839376  4.36E-03
    23 Broy./Diag. 0.40E+00   33.7     0.00004231    -23527.9236552018 -2.07E-03
    24 Broy./Diag. 0.40E+00   34.1     0.00003645    -23527.9275730333 -3.92E-03
    25 Broy./Diag. 0.40E+00   34.1     0.00000807    -23527.9288883915 -1.32E-03
    26 Broy./Diag. 0.40E+00   34.4     0.00000588    -23527.9287590757  1.29E-04
    27 Broy./Diag. 0.40E+00   34.1     0.00000234    -23527.9288599589 -1.01E-04
    28 Broy./Diag. 0.40E+00   34.4     0.00000547    -23527.9277191592  1.14E-03
    29 Broy./Diag. 0.40E+00   33.9     0.00000339    -23527.9274626799  2.56E-04
    30 Broy./Diag. 0.40E+00   33.9     0.00000202    -23527.9274951748 -3.25E-05
    31 Broy./Diag. 0.40E+00   34.2     0.00000197    -23527.9275737573 -7.86E-05
    32 Broy./Diag. 0.40E+00   34.0     0.00000188    -23527.9277202063 -1.46E-04
    33 Broy./Diag. 0.40E+00   34.2     0.00000157    -23527.9279625944 -2.42E-04
    34 Broy./Diag. 0.40E+00   34.0     0.00000201    -23527.9280014439 -3.88E-05
    35 Broy./Diag. 0.40E+00   34.3     0.00000202    -23527.9280565926 -5.51E-05
    36 Broy./Diag. 0.40E+00   33.9     0.00000134    -23527.9281459558 -8.94E-05
    37 Broy./Diag. 0.40E+00   34.1     0.00000074    -23527.9281539904 -8.03E-06

  *** SCF run converged in    37 steps ***


  Electronic density on regular grids:      -5378.9999998438        0.0000001562
  Core density on regular grids:             5378.9999993736       -0.0000006264
  Total charge density on r-space grids:       -0.0000004702
  Total charge density g-space grids:          -0.0000004702

  Overlap energy of the core charge distribution:               0.00000448732134
  Self energy of the core charge distribution:             -31492.95610277094238
  Core Hamiltonian energy:                                  10655.58673706336413
  Hartree energy:                                            1099.80910949847294
  Exchange-correlation energy:                              -3790.35282186228778
  Electronic entropic energy:                                  -0.01508040674130
  Fermi energy:                                                -0.12673132803331

  Total energy:                                            -23527.92815399039318

  Integrated absolute spin density  :                               0.0000040883
  WARNING: S**2 computation does not yet treat fractional occupied orbitals

 ENERGY| Total FORCE_EVAL ( QS ) energy (a.u.):           -23527.928167719634075


 STRESS TENSOR [GPa]

            X               Y               Z
  X      -0.25199861      0.00002993      0.00002994
  Y       0.00002993     -0.25199851      0.00002993
  Z       0.00002994      0.00002993     -0.25199855

  1/3 Trace(stress tensor):  -2.51998556E-01

  Det(stress tensor)      :  -1.60027322E-02


 EIGENVECTORS AND EIGENVALUES OF THE STRESS TENSOR

         -0.25202852     -0.25202846     -0.25193868

          0.79981863      0.16530871      0.57702963
         -0.25654385     -0.77495614      0.57760560
         -0.54265589      0.61001312      0.57741543

 --------  Informations at step =     0 ------------
  Optimization Method        =                 BFGS
  Total Energy               =    -23527.9281677196
  Used time                  =             1287.843
 ---------------------------------------------------

 --------------------------
 OPTIMIZATION STEP:      1
 --------------------------

 Spin 1

 Number of electrons:                                                       2690
 Number of occupied orbitals:                                               2736
 Number of molecular orbitals:                                              2890

 Spin 2

 Number of electrons:                                                       2689
 Number of occupied orbitals:                                               2736
 Number of molecular orbitals:                                              2889

 Number of orbital functions:                                              12225
 Number of independent orbital functions:                                  12225

 Extrapolation method: initial_guess


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00   32.4     0.00838066    -23528.0796370635 -2.35E+04
     2 Broy./Diag. 0.40E+00   34.5     0.00344470    -23532.0429068236 -3.96E+00
     3 Broy./Diag. 0.40E+00   34.3     0.00156193    -23528.0299712207  4.01E+00
     4 Broy./Diag. 0.40E+00   34.6     0.00139214    -23528.1854596207 -1.55E-01
     5 Broy./Diag. 0.40E+00   34.5     0.00065889    -23528.0363347065  1.49E-01
     6 Broy./Diag. 0.40E+00   34.3     0.00070862    -23527.9684974798  6.78E-02
     7 Broy./Diag. 0.40E+00   34.8     0.00036970    -23528.0653724213 -9.69E-02
     8 Broy./Diag. 0.40E+00   34.6     0.00028811    -23528.0392182430  2.62E-02
     9 Broy./Diag. 0.40E+00   35.3     0.00012621    -23528.0533688048 -1.42E-02
    10 Broy./Diag. 0.40E+00   34.5     0.00007387    -23528.0736452304 -2.03E-02
    11 Broy./Diag. 0.40E+00   34.8     0.00003374    -23528.0836266189 -9.98E-03
    12 Broy./Diag. 0.40E+00   34.4     0.00005292    -23528.0863868003 -2.76E-03
    13 Broy./Diag. 0.40E+00   34.3     0.00003378    -23528.0916223054 -5.24E-03
    14 Broy./Diag. 0.40E+00   34.6     0.00001876    -23528.0973559032 -5.73E-03
    15 Broy./Diag. 0.40E+00   34.8     0.00001195    -23528.1007616092 -3.41E-03
    16 Broy./Diag. 0.40E+00   34.7     0.00001101    -23528.1012345819 -4.73E-04
    17 Broy./Diag. 0.40E+00   34.5     0.00000784    -23528.1016007148 -3.66E-04
    18 Broy./Diag. 0.40E+00   34.7     0.00000697    -23528.1011320086  4.69E-04
    19 Broy./Diag. 0.40E+00   34.5     0.00000358    -23528.1008910607  2.41E-04
    20 Broy./Diag. 0.40E+00   34.7     0.00000269    -23528.1011126615 -2.22E-04
    21 Broy./Diag. 0.40E+00   34.7     0.00000230    -23528.1010294258  8.32E-05
    22 Broy./Diag. 0.40E+00   34.9     0.00000274    -23528.1008056512  2.24E-04
    23 Broy./Diag. 0.40E+00   34.9     0.00000255    -23528.1008650372 -5.94E-05
    24 Broy./Diag. 0.40E+00   34.7     0.00000354    -23528.1008033545  6.17E-05
    25 Broy./Diag. 0.40E+00   35.1     0.00000208    -23528.1008000540  3.30E-06
    26 Broy./Diag. 0.40E+00   34.8     0.00000128    -23528.1010406447 -2.41E-04
    27 Broy./Diag. 0.40E+00   34.5     0.00000037    -23528.1011665627 -1.26E-04

  *** SCF run converged in    27 steps ***


  Electronic density on regular grids:      -5378.9999997608        0.0000002392
  Core density on regular grids:             5378.9999993742       -0.0000006258
  Total charge density on r-space grids:       -0.0000003865
  Total charge density g-space grids:          -0.0000003865

  Overlap energy of the core charge distribution:               0.00000519657552
  Self energy of the core charge distribution:             -31492.95610277094238
  Core Hamiltonian energy:                                  10656.38589701242745
  Hartree energy:                                            1099.55722379135159
  Exchange-correlation energy:                              -3791.07366112260752
  Electronic entropic energy:                                  -0.01452866500412
  Fermi energy:                                                -0.12689384605516

  Total energy:                                            -23528.10116656270839

  Integrated absolute spin density  :                               0.0000003274
  WARNING: S**2 computation does not yet treat fractional occupied orbitals

 ENERGY| Total FORCE_EVAL ( QS ) energy (a.u.):           -23528.101153481740766


 STRESS TENSOR [GPa]

            X               Y               Z
  X      -0.13218903     -0.00047890     -0.00047892
  Y      -0.00047890     -0.13218884     -0.00047891
  Z      -0.00047892     -0.00047891     -0.13218898

  1/3 Trace(stress tensor):  -1.32188951E-01

  Det(stress tensor)      :  -2.30976826E-03


 EIGENVECTORS AND EIGENVALUES OF THE STRESS TENSOR

         -0.13314677     -0.13171009     -0.13170999

          0.57738304     -0.77684855     -0.25126708
          0.57730466      0.17081683      0.79846161
          0.57736310      0.60607585     -0.54710503

 --------  Informations at step =     1 ------------
  Optimization Method        =                 BFGS
  Total Energy               =    -23528.1011534817
  Real energy change         =        -0.1729857621
  Predicted change in energy =        -0.1710950617
  Scaling factor             =         0.0000000000
  Step size                  =         0.1515898326
  Trust radius               =         0.4724315332
  Decrease in energy         =                  YES
  Used time                  =              974.215

  Convergence check :
  Max. step size             =         0.1515898326
  Conv. limit for step size  =         0.0005000000
  Convergence in step size   =                   NO
  RMS step size              =         0.0474065500
  Conv. limit for RMS step   =         0.0015000000
  Convergence in RMS step    =                   NO
  Max. gradient              =         0.0121064191
  Conv. limit for gradients  =         0.0004500000
  Conv. for gradients        =                   NO
  RMS gradient               =         0.0033573168
  Conv. limit for RMS grad.  =         0.0003000000
  Conv. for gradients        =                   NO
 ---------------------------------------------------

 --------------------------
 OPTIMIZATION STEP:      2
 --------------------------

 Spin 1

 Number of electrons:                                                       2690
 Number of occupied orbitals:                                               2741
 Number of molecular orbitals:                                              2890

 Spin 2

 Number of electrons:                                                       2689
 Number of occupied orbitals:                                               2741
 Number of molecular orbitals:                                              2889

 Number of orbital functions:                                              12225
 Number of independent orbital functions:                                  12225

 Extrapolation method: initial_guess


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00   32.1     0.00538254    -23528.1325490323 -2.35E+04
     2 Broy./Diag. 0.40E+00   34.7     0.00161984    -23530.4702055220 -2.34E+00
     3 Broy./Diag. 0.40E+00   34.6     0.00074939    -23528.1268955924  2.34E+00
     4 Broy./Diag. 0.40E+00   34.9     0.00079237    -23528.1599449529 -3.30E-02
     5 Broy./Diag. 0.40E+00   34.5     0.00061162    -23528.0510137415  1.09E-01
     6 Broy./Diag. 0.40E+00   34.5     0.00035135    -23528.0671850606 -1.62E-02
     7 Broy./Diag. 0.40E+00   34.6     0.00013715    -23528.1318624005 -6.47E-02
     8 Broy./Diag. 0.40E+00   34.8     0.00011761    -23528.1048632035  2.70E-02
     9 Broy./Diag. 0.40E+00   34.9     0.00004772    -23528.1166006005 -1.17E-02
    10 Broy./Diag. 0.40E+00   34.8     0.00005047    -23528.1300761426 -1.35E-02
    11 Broy./Diag. 0.40E+00   34.8     0.00002406    -23528.1376556623 -7.58E-03
    12 Broy./Diag. 0.40E+00   34.6     0.00002032    -23528.1381290683 -4.73E-04
    13 Broy./Diag. 0.40E+00   34.6     0.00002276    -23528.1389326066 -8.04E-04
    14 Broy./Diag. 0.40E+00   34.7     0.00001215    -23528.1430918890 -4.16E-03
    15 Broy./Diag. 0.40E+00   34.8     0.00001039    -23528.1458390052 -2.75E-03
    16 Broy./Diag. 0.40E+00   35.0     0.00000781    -23528.1466801276 -8.41E-04
    17 Broy./Diag. 0.40E+00   34.7     0.00000546    -23528.1462905789  3.90E-04
    18 Broy./Diag. 0.40E+00   35.0     0.00000427    -23528.1463645321 -7.40E-05
    19 Broy./Diag. 0.40E+00   34.8     0.00000446    -23528.1462205420  1.44E-04
    20 Broy./Diag. 0.40E+00   34.6     0.00000290    -23528.1462969260 -7.64E-05
    21 Broy./Diag. 0.40E+00   34.7     0.00000352    -23528.1463284147 -3.15E-05
    22 Broy./Diag. 0.40E+00   34.8     0.00000092    -23528.1463873467 -5.89E-05

  *** SCF run converged in    22 steps ***


  Electronic density on regular grids:      -5378.9999997348        0.0000002652
  Core density on regular grids:             5378.9999993738       -0.0000006262
  Total charge density on r-space grids:       -0.0000003610
  Total charge density g-space grids:          -0.0000003610

  Overlap energy of the core charge distribution:               0.00000577659540
  Self energy of the core charge distribution:             -31492.95610277094238
  Core Hamiltonian energy:                                  10656.92534594682729
  Hartree energy:                                            1099.38343891866270
  Exchange-correlation energy:                              -3791.48466133271359
  Electronic entropic energy:                                  -0.01441385797186
  Fermi energy:                                                -0.12692395973928

  Total energy:                                            -23528.14638734666005

  Integrated absolute spin density  :                               0.0000012821
  WARNING: S**2 computation does not yet treat fractional occupied orbitals

 ENERGY| Total FORCE_EVAL ( QS ) energy (a.u.):           -23528.146291826094966


 STRESS TENSOR [GPa]

            X               Y               Z
  X      -0.07181889     -0.00087055     -0.00087058
  Y      -0.00087055     -0.07181870     -0.00087058
  Z      -0.00087058     -0.00087058     -0.07181885

  1/3 Trace(stress tensor):  -7.18188151E-02

  Det(stress tensor)      :  -3.70275323E-04


 EIGENVECTORS AND EIGENVALUES OF THE STRESS TENSOR

         -0.07355996     -0.07094830     -0.07094819

          0.57736447     -0.78315704     -0.23090112
          0.57732395      0.19160458      0.79371578
          0.57736239      0.59156804     -0.56276099

 --------  Informations at step =     2 ------------
  Optimization Method        =                 BFGS
  Total Energy               =    -23528.1462918261
  Real energy change         =        -0.0451383444
  Predicted change in energy =        -0.0522682983
  Scaling factor             =         0.0000000000
  Step size                  =         0.1407170493
  Trust radius               =         0.4724315332
  Decrease in energy         =                  YES
  Used time                  =              802.313

  Convergence check :
  Max. step size             =         0.1407170493
  Conv. limit for step size  =         0.0005000000
  Convergence in step size   =                   NO
  RMS step size              =         0.0250308988
  Conv. limit for RMS step   =         0.0015000000
  Convergence in RMS step    =                   NO
  Max. gradient              =         0.0106763762
  Conv. limit for gradients  =         0.0004500000
  Conv. for gradients        =                   NO
  RMS gradient               =         0.0024130670
  Conv. limit for RMS grad.  =         0.0003000000
  Conv. for gradients        =                   NO
 ---------------------------------------------------

 --------------------------
 OPTIMIZATION STEP:      3
 --------------------------

 Spin 1

 Number of electrons:                                                       2690
 Number of occupied orbitals:                                               2741
 Number of molecular orbitals:                                              2890

 Spin 2

 Number of electrons:                                                       2689
 Number of occupied orbitals:                                               2741
 Number of molecular orbitals:                                              2889

 Number of orbital functions:                                              12225
 Number of independent orbital functions:                                  12225

 Extrapolation method: initial_guess


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 Broy./Diag. 0.40E+00   32.5     0.00504990    -23528.1708681549 -2.35E+04
     2 Broy./Diag. 0.40E+00   34.5     0.00140344    -23529.9206354800 -1.75E+00
     3 Broy./Diag. 0.40E+00   34.3     0.00070560    -23528.1917430819  1.73E+00
     4 Broy./Diag. 0.40E+00   34.4     0.00059575    -23528.2726215276 -8.09E-02
     5 Broy./Diag. 0.40E+00   34.7     0.00036631    -23528.1834295521  8.92E-02
     6 Broy./Diag. 0.40E+00   35.3     0.00026584    -23528.1434827926  3.99E-02
     7 Broy./Diag. 0.40E+00   34.6     0.00014946    -23528.1867702851 -4.33E-02
     8 Broy./Diag. 0.40E+00   34.9     0.00008576    -23528.1741127128  1.27E-02
     9 Broy./Diag. 0.40E+00   34.6     0.00002613    -23528.1720239977  2.09E-03
    10 Broy./Diag. 0.40E+00   34.5     0.00001736    -23528.1761384353 -4.11E-03
    11 Broy./Diag. 0.40E+00   34.6     0.00001804    -23528.1772398791 -1.10E-03
    12 Broy./Diag. 0.40E+00   34.6     0.00001692    -23528.1776938541 -4.54E-04
    13 Broy./Diag. 0.40E+00   34.9     0.00001439    -23528.1781338362 -4.40E-04
    14 Broy./Diag. 0.40E+00   34.7     0.00001045    -23528.1785925148 -4.59E-04
    15 Broy./Diag. 0.40E+00   35.1     0.00000887    -23528.1789600943 -3.68E-04
    16 Broy./Diag. 0.40E+00   34.7     0.00000398    -23528.1793273107 -3.67E-04
    17 Broy./Diag. 0.40E+00   34.6     0.00000420    -23528.1791876729  1.40E-04
    18 Broy./Diag. 0.40E+00   34.6     0.00000291    -23528.1791929070 -5.23E-06
    19 Broy./Diag. 0.40E+00   34.7     0.00000230    -23528.1792157890 -2.29E-05
    20 Broy./Diag. 0.40E+00   35.0     0.00000230    -23528.1793320181 -1.16E-04
    21 Broy./Diag. 0.40E+00   34.7     0.00000205    -23528.1793308974  1.12E-06
-------------- next part --------------
srun: error: cdr1969: task 70: Segmentation fault (core dumped)
srun: launch/slurm: _step_signal: Terminating StepId=3371335.0
slurmstepd: error: *** STEP 3371335.0 ON cdr1960 CANCELLED AT 2021-05-25T10:58:16 ***
srun: error: cdr1971: tasks 96-127: Terminated
srun: error: cdr1985: tasks 352-383: Terminated
srun: error: cdr1979: tasks 288-319: Terminated
srun: error: cdr1972: tasks 128-159: Terminated
srun: error: cdr1969: tasks 64-69,71-95: Terminated
srun: error: cdr1973: tasks 160-191: Terminated
srun: error: cdr1980: tasks 320-351: Terminated
srun: error: cdr1967: tasks 32-63: Terminated
srun: error: cdr1978: tasks 256-287: Terminated
srun: error: cdr1976: tasks 192-223: Terminated
srun: error: cdr1977: tasks 224-255: Terminated
srun: error: cdr1960: tasks 0-31: Terminated
srun: Force Terminated StepId=3371335.0
-------------- next part --------------
!&EXT_RESTART
  !RESTART_FILE_NAME cp2k-1.restart
!&END

&GLOBAL
   RUN_TYPE GEO_OPT
   EXTENDED_FFT_LENGTHS .TRUE.
   FFTW_PLAN_TYPE ESTIMATE
   PREFERRED_FFT_LIBRARY FFTW3
   PROJECT cp2k
   PRINT_LEVEL LOW
   &TIMINGS SILENT
      THRESHOLD 1e-08
   &END TIMINGS
&END GLOBAL
&MOTION
   &GEO_OPT
      MAX_ITER 400
      OPTIMIZER BFGS
      MAX_DR 5e-04
     !RESTART_FILE_NAME cp2k-BFGS.Hessian
   &END GEO_OPT
   &PRINT
      &TRAJECTORY
         FORMAT XYZ
      &END TRAJECTORY
   &END PRINT
&END MOTION
&FORCE_EVAL
   METHOD Quickstep
   STRESS_TENSOR ANALYTICAL
   &PRINT
      &STRESS_TENSOR ON
      &END STRESS_TENSOR
   &END PRINT
   &DFT
      UKS .TRUE.
      CHARGE 0
      WFN_RESTART_FILE_NAME   cp2k-RESTART.wfn
      BASIS_SET_FILE_NAME BASIS_MOLOPT
      POTENTIAL_FILE_NAME GTH_POTENTIALS
      &MGRID
         NGRIDS 5
 RELATIVE_CUTOFF 50
         CUTOFF 350
      &END MGRID
      &QS
         EPS_DEFAULT 1.0E-10
         METHOD GPW
         EXTRAPOLATION USE_GUESS
      &END QS
      &SCF
         EPS_SCF 1.0E-6
         SCF_GUESS RESTART
         ADDED_MOS  200
         CHOLESKY  OFF
         MAX_SCF 100
         &OUTER_SCF F
            EPS_SCF 1.0E-7
            MAX_SCF 50
         &END OUTER_SCF
         &SMEAR T
            METHOD  FERMI_DIRAC
            ELECTRONIC_TEMPERATURE     3.0000000000000000E+02
         &END SMEAR
         &MIXING T
            METHOD  BROYDEN_MIXING
            ALPHA     4.0000000000000002E-01
            BETA     1.5000000000000000E+00
            NMIXING  5
            NBUFFER  8
         &END MIXING
      &END SCF
      &XC
         FUNCTIONAL_ROUTINE NEW
         DENSITY_CUTOFF 1.0e-12
         GRADIENT_CUTOFF 1.0e-12
         TAU_CUTOFF 1.0e-12
         &XC_FUNCTIONAL
            &PBE
            &END PBE
         &END XC_FUNCTIONAL
         &XC_GRID
            USE_FINER_GRID  .TRUE.
&END XC_GRID
      &END XC
      &LS_SCF
         MAX_SCF 60
      &END LS_SCF
   &END DFT
   &SUBSYS
      &CELL
         ABC 40 40 40
         ALPHA_BETA_GAMMA   90.000000  90.000000  90.0000
         PERIODIC NONE
      &END CELL

  &KIND Cu
   BASIS_SET DZVP-MOLOPT-SR-GTH-q11
   POTENTIAL GTH-PBE-q11
  &END KIND
  &TOPOLOGY
   COORD_FILE_FORMAT XYZ
   COORD_FILE_NAME Cu_111_21.983nm.xyz
   CONN_FILE_FORMAT off
  &END TOPOLOGY


   &END SUBSYS
&END FORCE_EVAL


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