[CP2K-user] [CP2K:15195] Re: Does CP2K allow a multi-GPU run?

Lenard Carroll lenardc... at gmail.com
Thu Apr 22 15:44:26 UTC 2021


Here's the log file. The job ended prematurely.

On Thu, Apr 22, 2021 at 3:23 PM Lenard Carroll <lenardc... at gmail.com>
wrote:

> Not sure yet. The job is still in the queue. As soon as it is finished
> I'll post the log file info here.
>
> On Thu, Apr 22, 2021 at 3:15 PM Alfio Lazzaro <alfio.... at gmail.com>
> wrote:
>
>> And it works? Check the output and the performance... It can be that your
>> particular test case doesn't use the GPU at all, so could you attach the
>> log (at least the final part of it)
>>
>> Il giorno giovedì 22 aprile 2021 alle 13:42:16 UTC+2 ASSIDUO Network ha
>> scritto:
>>
>>> I am using 30 threads now over 3 GPUs, so I used:
>>>
>>> export OMP_NUM_THREADS=10
>>> mpiexec -n 3 cp2k.psmp -i gold50.inp -o gold50.out
>>>
>>>
>>> On Thu, Apr 22, 2021 at 1:34 PM Alfio Lazzaro <al... at gmail.com>
>>> wrote:
>>>
>>>> Wait, I see you have 32 threads in total, so need to have 32/4 = 8
>>>> threads.
>>>> Please change
>>>>
>>>> export OMP_NUM_THREADS=8
>>>>
>>>> Il giorno giovedì 22 aprile 2021 alle 13:27:59 UTC+2 ASSIDUO Network ha
>>>> scritto:
>>>>
>>>>> Shall do. I already set it up, but it's in a long queue.
>>>>>
>>>>> On Thu, Apr 22, 2021 at 1:22 PM Alfio Lazzaro <al... at gmail.com>
>>>>> wrote:
>>>>>
>>>>>> Could you try what I suggested:
>>>>>>
>>>>>> export OMP_NUM_THREADS=10
>>>>>> mpirun -np 4 ./cp2k.psmp -i gold.inp -o gold_pbc.out
>>>>>>
>>>>>> Please check the corresponding log.
>>>>>>
>>>>>> As I said above, you need an MPI rank per GPU and you told us that
>>>>>> you have 4 GPUs, so you need 4 ranks (or multiple). With 10 you get
>>>>>> unbalance.
>>>>>>
>>>>>>
>>>>>> Il giorno giovedì 22 aprile 2021 alle 10:17:27 UTC+2 ASSIDUO Network
>>>>>> ha scritto:
>>>>>>
>>>>>>> Correction, he told me to use:
>>>>>>>
>>>>>>> mpirun -np 10 cp2k.psmp -i gold.inp -o gold_pbc.out
>>>>>>>
>>>>>>> but it didn't run correctly.
>>>>>>>
>>>>>>> On Thu, Apr 22, 2021 at 9:51 AM Lenard Carroll <len... at gmail.com>
>>>>>>> wrote:
>>>>>>>
>>>>>>>> He suggested I try out:
>>>>>>>> mpirun -n 10 cp2k.psmp -i gold.inp -o gold_pbc.out
>>>>>>>>
>>>>>>>> as he is hoping that will cause the 1 GPU to use 10 CPUs over the
>>>>>>>> selected 4 GPUs.
>>>>>>>>
>>>>>>>>
>>>>>>>> On Thu, Apr 22, 2021 at 9:48 AM Alfio Lazzaro <al... at gmail.com>
>>>>>>>> wrote:
>>>>>>>>
>>>>>>>>> Hi,
>>>>>>>>> Your command to run CP2K doesn't mention MPI (mpirun, mpiexc,
>>>>>>>>> ...). Are you running with multiple ranks?
>>>>>>>>>
>>>>>>>>> You can check those lines in the output:
>>>>>>>>>
>>>>>>>>>  GLOBAL| Total number of message passing processes
>>>>>>>>>             32
>>>>>>>>>  GLOBAL| Number of threads for this process
>>>>>>>>>             4
>>>>>>>>>
>>>>>>>>> And check your numbers.
>>>>>>>>> I can guess you have 1 rank and 40 threads.
>>>>>>>>> To use 4 GPUs you need 4 ranks (and less threads per rank), i.e.
>>>>>>>>> something like
>>>>>>>>>
>>>>>>>>> export OMP_NUM_THREADS=10
>>>>>>>>> mpiexec -n 4 ./cp2k.psmp -i gold.inp -o gold_pbc.out
>>>>>>>>>
>>>>>>>>> Please check with your sysadmin on how to run with multiple MPI
>>>>>>>>> ranks.
>>>>>>>>>
>>>>>>>>> Hope it helps.
>>>>>>>>>
>>>>>>>>> Alfio
>>>>>>>>>
>>>>>>>>>
>>>>>>>>>
>>>>>>>>> Il giorno mercoledì 21 aprile 2021 alle 09:26:53 UTC+2 ASSIDUO
>>>>>>>>> Network ha scritto:
>>>>>>>>>
>>>>>>>>>> This is what my PBS file looks like:
>>>>>>>>>>
>>>>>>>>>> #!/bin/bash
>>>>>>>>>> #PBS -P <PROJECT>
>>>>>>>>>> #PBS -N <JOBNAME>
>>>>>>>>>> #PBS -l select=1:ncpus=40:ngpus=4
>>>>>>>>>> #PBS -l walltime=08:00:00
>>>>>>>>>> #PBS -q gpu_4
>>>>>>>>>> #PBS -m be
>>>>>>>>>> #PBS -M none
>>>>>>>>>>
>>>>>>>>>> module purge
>>>>>>>>>> module load chpc/cp2k/8.1.0/cuda10.1/openmpi-4.0.0/gcc-7.3.0
>>>>>>>>>> source $SETUP
>>>>>>>>>> cd $PBS_O_WORKDIR
>>>>>>>>>>
>>>>>>>>>> cp2k.psmp -i gold.inp -o gold_pbc.out
>>>>>>>>>> ~
>>>>>>>>>>                                                        ~
>>>>>>>>>>
>>>>>>>>>>
>>>>>>>>>> On Wed, Apr 21, 2021 at 9:22 AM Alfio Lazzaro <
>>>>>>>>>> al... at gmail.com> wrote:
>>>>>>>>>>
>>>>>>>>>>> The way to use 4 GPUs per node is to use 4 MPI ranks. How many
>>>>>>>>>>> ranks are you using?
>>>>>>>>>>>
>>>>>>>>>>> Il giorno martedì 20 aprile 2021 alle 19:44:15 UTC+2 ASSIDUO
>>>>>>>>>>> Network ha scritto:
>>>>>>>>>>>
>>>>>>>>>>>> I'm asking, since the administrator running my country's HPC is
>>>>>>>>>>>> saying that although I'm requesting access to 4 GPUs, CP2K is only using 1.
>>>>>>>>>>>> I checked the following output:
>>>>>>>>>>>>  DBCSR| ACC: Number of devices/node
>>>>>>>>>>>>                 4
>>>>>>>>>>>>
>>>>>>>>>>>> And it shows that CP2K is picking up 4 GPUs.
>>>>>>>>>>>>
>>>>>>>>>>>> On Tuesday, April 20, 2021 at 3:00:17 PM UTC+2 ASSIDUO Network
>>>>>>>>>>>> wrote:
>>>>>>>>>>>>
>>>>>>>>>>>>> I currently have access to 4 GPUs to run an AIMD simulation,
>>>>>>>>>>>>> but only one of the GPUs are being used. Is there a way to use the other 3,
>>>>>>>>>>>>> and if so, can you tell me how to set it up with a PBS job?
>>>>>>>>>>>>
>>>>>>>>>>>> --
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>>>>>>>>>>> To view this discussion on the web visit
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>>>>>>>>>>> <https://groups.google.com/d/msgid/cp2k/70ba0fce-8636-4b75-940d-133ce4dbf0can%40googlegroups.com?utm_medium=email&utm_source=footer>
>>>>>>>>>>> .
>>>>>>>>>>>
>>>>>>>>>> --
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>>>>>>>>> <https://groups.google.com/d/msgid/cp2k/92e4f88d-fde8-4127-ab5f-0b98bbbba8ebn%40googlegroups.com?utm_medium=email&utm_source=footer>
>>>>>>>>> .
>>>>>>>>>
>>>>>>>> --
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>>>>>> send an email to cp... at googlegroups.com.
>>>>>>
>>>>> To view this discussion on the web visit
>>>>>> https://groups.google.com/d/msgid/cp2k/59a635d8-0f0c-4dc5-abaf-b8bbe3c18da5n%40googlegroups.com
>>>>>> <https://groups.google.com/d/msgid/cp2k/59a635d8-0f0c-4dc5-abaf-b8bbe3c18da5n%40googlegroups.com?utm_medium=email&utm_source=footer>
>>>>>> .
>>>>>>
>>>>> --
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>>>>
>>> To view this discussion on the web visit
>>>> https://groups.google.com/d/msgid/cp2k/ec4efd81-6314-4ce7-b22c-148b362d2ba6n%40googlegroups.com
>>>> <https://groups.google.com/d/msgid/cp2k/ec4efd81-6314-4ce7-b22c-148b362d2ba6n%40googlegroups.com?utm_medium=email&utm_source=footer>
>>>> .
>>>>
>>> --
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>> email to cp... at googlegroups.com.
>> To view this discussion on the web visit
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>> <https://groups.google.com/d/msgid/cp2k/d29306aa-e0b8-4797-9298-13dab23e9083n%40googlegroups.com?utm_medium=email&utm_source=footer>
>> .
>>
>
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 *******************************************************************************
 *                            RESTART INFORMATION                              *
 *******************************************************************************
 *                                                                             *
 *    RESTART FILE NAME: AIMD_ENERGY-MD.REST-1.restart                         *
 *                                                                             *
 * RESTARTED QUANTITIES:                                                       *
 *                       CELL                                                  *
 *                       COORDINATES                                           *
 *                       RANDOM NUMBER GENERATOR                               *
 *                       VELOCITIES                                            *
 *                       MD COUNTERS                                           *
 *                       GEO_OPT COUNTERS                                      *
 *                       CELL_OPT COUNTERS                                     *
 *                       MD AVERAGES                                           *
 *                       PARTICLE THERMOSTAT                                   *
 *                       CONSTRAINTS/RESTRAINTS                                *
 *                       REAL TIME PROPAGATION                                 *
 *                       PINT BEAD POSITIONS                                   *
 *                       PINT BEAD VELOCITIES                                  *
 *                       PINT NOSE THERMOSTAT                                  *
 *                       PINT GLE THERMOSTAT                                   *
 *                       HELIUM BEAD POSITIONS                                 *
 *                       HELIUM PERMUTATION STATE                              *
 *                       HELIUM FORCES ON SOLUTE                               *
 *                       HELIUM RNG STATE                                      *
 *******************************************************************************

 DBCSR| CPU Multiplication driver                                           XSMM
 DBCSR| Multrec recursion limit                                              512
 DBCSR| Multiplication stack size                                          30000
 DBCSR| Maximum elements for images                                    UNLIMITED
 DBCSR| Multiplicative factor virtual images                                   1
 DBCSR| Use multiplication densification                                       F
 DBCSR| Multiplication size stacks                                             3
 DBCSR| Use memory pool for CPU allocation                                     F
 DBCSR| Number of 3D layers                                               SINGLE
 DBCSR| Use MPI memory allocation                                              F
 DBCSR| Use RMA algorithm                                                      F
 DBCSR| Use Communication thread                                               T
 DBCSR| Communication thread load                                             53
 DBCSR| MPI: My node id                                                        0
 DBCSR| MPI: Number of nodes                                                   3
 DBCSR| OMP: Current number of threads                                        10
 DBCSR| OMP: Max number of threads                                            10
 DBCSR| ACC: Number of devices/node                                            3
 DBCSR| ACC: Number of priority stack-buffers                                 40
 DBCSR| ACC: Number of posterior stack-buffers                                80
 DBCSR| ACC: Number of priority streams                                        4
 DBCSR| ACC: Number of posterior streams                                       4
 DBCSR| ACC: Avoid driver after busy                                           F
 DBCSR| ACC: Process inhomogeneous stacks                                      T
 DBCSR| ACC: Min. flop for processing                                          0
 DBCSR| ACC: Min. flop for sorting                                          4000
 DBCSR| ACC: Number of binning bins                                         4096
 DBCSR| ACC: Size of binning bins                                             16
 DBCSR| Split modifier for TAS multiplication algorithm                  1.0E+00


  **** **** ******  **  PROGRAM STARTED AT               2021-04-22 15:50:51.368
 ***** ** ***  *** **   PROGRAM STARTED ON                               gpu4002
 **    ****   ******    PROGRAM STARTED BY                              lcarroll
 ***** **    ** ** **   PROGRAM PROCESS ID                                383098
  **** **  *******  **  PROGRAM STARTED IN /mnt/lustre/users/lcarroll/AIMD/Au111
                                           /Heat/SLOW

 CP2K| version string:                    CP2K version 9.0 (Development Version)
 CP2K| source code revision number:                                  git:122ed37
 CP2K| cp2kflags: omp libint fftw3 libxc parallel mpi3 scalapack acc pw_cuda xsm
 CP2K|            m dbcsr_acc spglib sirius libvori libbqb grid_cuda
 CP2K| is freely available from                            https://www.cp2k.org/
 CP2K| Program compiled at                         Fri Feb 26 17:22:46 SAST 2021
 CP2K| Program compiled on                                               gpu2003
 CP2K| Program compiled for                                           local_cuda
 CP2K| Data directory path                   /apps/chpc/chem/gpu/cp2k/8.1.0/data
 CP2K| Input file name                                                gold50.inp

 GLOBAL| Force Environment number                                              1
 GLOBAL| Basis set file name                                      ./BASIS_MOLOPT
 GLOBAL| Potential file name                                    ./GTH_POTENTIALS
 GLOBAL| MM Potential file name                                     MM_POTENTIAL
 GLOBAL| Coordinate file name                                         ./gold.xyz
 GLOBAL| Method name                                                        CP2K
 GLOBAL| Project name                                                AIMD_ENERGY
 GLOBAL| Preferred FFT library                                             FFTW3
 GLOBAL| Preferred diagonalization lib.                                       SL
 GLOBAL| Run type                                                             MD
 GLOBAL| All-to-all communication in single precision                          F
 GLOBAL| FFTs using library dependent lengths                                  F
 GLOBAL| Global print level                                                  LOW
 GLOBAL| MPI I/O enabled                                                       T
 GLOBAL| Total number of message passing processes                             3
 GLOBAL| Number of threads for this process                                   10
 GLOBAL| This output is from process                                           0
 GLOBAL| CPU model name                 Intel(R) Xeon(R) Gold 6148 CPU @ 2.40GHz
 GLOBAL| CPUID                                                              1003

 MEMORY| system memory details [Kb]
 MEMORY|                        rank 0           min           max       average
 MEMORY| MemTotal            196690260     196690260     196690260     196690260
 MEMORY| MemFree             191021892     191021892     191022132     191022052
 MEMORY| Buffers                  1552          1552          1552          1552
 MEMORY| Cached                 857236        857236        857264        857254
 MEMORY| Slab                   548640        548104        548640        548282
 MEMORY| SReclaimable            66032         66032         66032         66032
 MEMORY| MemLikelyFree       191946712     191946712     191946980     191946890


 *** WARNING in atoms_input.F:123 :: Overwriting coordinates. Active    ***
 *** coordinates read from &COORD section. Active coordinates READ from ***
 *** &COORD section                                                     ***


 GENERATE|  Preliminary Number of Bonds generated:                             0
 GENERATE|  Achieved consistency in connectivity generation.

 *******************************************************************************
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 **           ##                                                    ##        **
 **                                                                           **
 **                                                ... make the atoms dance   **
 **                                                                           **
 **            Copyright (C) by CP2K developers group (2000-2021)             **
 **                      J. Chem. Phys. 152, 194103 (2020)                    **
 **                                                                           **
 *******************************************************************************


 TOTAL NUMBERS AND MAXIMUM NUMBERS

  Total number of            - Atomic kinds:                                   3
                             - Atoms:                                        153
                             - Shell sets:                                   153
                             - Shells:                                      1065
                             - Primitive Cartesian functions:                765
                             - Cartesian basis functions:                   4542
                             - Spherical basis functions:                   3789

  Maximum angular momentum of- Orbital basis functions:                        3
                             - Local part of the GTH pseudopotential:          2
                             - Non-local part of the GTH pseudopotential:      4


 MODULE QUICKSTEP:  ATOMIC COORDINATES IN angstrom

  Atom  Kind  Element       X           Y           Z          Z(eff)       Mass

       1     1 Au  79    1.475090    0.851650    0.000000     11.0000     196.9666
       2     1 Au  79    2.950160    3.406530    0.000000     11.0000     196.9666
       3     1 Au  79    4.425220    0.851650    0.000000     11.0000     196.9666
       4     1 Au  79    5.900290    3.406530    0.000000     11.0000     196.9666
       5     1 Au  79    7.375350    0.851650    0.000000     11.0000     196.9666
       6     1 Au  79    8.850420    3.406530    0.000000     11.0000     196.9666
       7     1 Au  79   10.325480    0.851650    0.000000     11.0000     196.9666
       8     1 Au  79   11.800550    3.406530    0.000000     11.0000     196.9666
       9     1 Au  79   13.275610    0.851650    0.000000     11.0000     196.9666
      10     1 Au  79   14.750680    3.406530    0.000000     11.0000     196.9666
      11     1 Au  79    4.425220    5.961420    0.000000     11.0000     196.9666
      12     1 Au  79    5.900290    8.516310    0.000000     11.0000     196.9666
      13     1 Au  79    7.375350    5.961420    0.000000     11.0000     196.9666
      14     1 Au  79    8.850420    8.516310    0.000000     11.0000     196.9666
      15     1 Au  79   10.325480    5.961420    0.000000     11.0000     196.9666
      16     1 Au  79   11.800550    8.516310    0.000000     11.0000     196.9666
      17     1 Au  79   13.275610    5.961420    0.000000     11.0000     196.9666
      18     1 Au  79   14.750680    8.516310    0.000000     11.0000     196.9666
      19     1 Au  79   16.225740    5.961420    0.000000     11.0000     196.9666
      20     1 Au  79   17.700810    8.516310    0.000000     11.0000     196.9666
      21     1 Au  79    7.375350   11.071200    0.000000     11.0000     196.9666
      22     1 Au  79   10.325480   11.071200    0.000000     11.0000     196.9666
      23     1 Au  79   13.275610   11.071200    0.000000     11.0000     196.9666
      24     1 Au  79   16.225740   11.071200    0.000000     11.0000     196.9666
      25     1 Au  79   19.175870   11.071200    0.000000     11.0000     196.9666
      26     1 Au  79    2.950100    1.703240    2.408700     11.0000     196.9666
      27     1 Au  79    4.425170    4.258130    2.408700     11.0000     196.9666
      28     1 Au  79    5.900230    1.703240    2.408700     11.0000     196.9666
      29     1 Au  79    7.375300    4.258130    2.408700     11.0000     196.9666
      30     1 Au  79    8.850360    1.703240    2.408700     11.0000     196.9666
      31     1 Au  79   10.325430    4.258130    2.408700     11.0000     196.9666
      32     1 Au  79   11.800490    1.703240    2.408700     11.0000     196.9666
      33     1 Au  79   13.275560    4.258130    2.408700     11.0000     196.9666
      34     1 Au  79   14.750620    1.703240    2.408700     11.0000     196.9666
      35     1 Au  79   16.225690    4.258130    2.408700     11.0000     196.9666
      36     1 Au  79    5.900230    6.813020    2.408700     11.0000     196.9666
      37     1 Au  79    7.375300    9.367900    2.408700     11.0000     196.9666
      38     1 Au  79    8.850360    6.813020    2.408700     11.0000     196.9666
      39     1 Au  79   10.325430    9.367900    2.408700     11.0000     196.9666
      40     1 Au  79   11.800490    6.813020    2.408700     11.0000     196.9666
      41     1 Au  79   13.275560    9.367900    2.408700     11.0000     196.9666
      42     1 Au  79   14.750620    6.813020    2.408700     11.0000     196.9666
      43     1 Au  79   16.225690    9.367900    2.408700     11.0000     196.9666
      44     1 Au  79   17.700750    6.813020    2.408700     11.0000     196.9666
      45     1 Au  79   19.175820    9.367900    2.408700     11.0000     196.9666
      46     1 Au  79    8.850360   11.922790    2.408700     11.0000     196.9666
      47     1 Au  79   11.800490   11.922790    2.408700     11.0000     196.9666
      48     1 Au  79   14.750620   11.922790    2.408700     11.0000     196.9666
      49     1 Au  79   17.700750   11.922790    2.408700     11.0000     196.9666
      50     1 Au  79   20.650880   11.922790    2.408700     11.0000     196.9666
      51     1 Au  79    0.000000    0.000000    4.817400     11.0000     196.9666
      52     1 Au  79    1.475070    2.554890    4.817400     11.0000     196.9666
      53     1 Au  79    2.950130    0.000000    4.817400     11.0000     196.9666
      54     1 Au  79    4.425200    2.554890    4.817400     11.0000     196.9666
      55     1 Au  79    5.900260    0.000000    4.817400     11.0000     196.9666
      56     1 Au  79    7.375330    2.554890    4.817400     11.0000     196.9666
      57     1 Au  79    8.850390    0.000000    4.817400     11.0000     196.9666
      58     1 Au  79   10.325460    2.554890    4.817400     11.0000     196.9666
      59     1 Au  79   11.800520    0.000000    4.817400     11.0000     196.9666
      60     1 Au  79   13.275590    2.554890    4.817400     11.0000     196.9666
      61     1 Au  79    2.950130    5.109780    4.817400     11.0000     196.9666
      62     1 Au  79    4.425200    7.664660    4.817400     11.0000     196.9666
      63     1 Au  79    5.900260    5.109780    4.817400     11.0000     196.9666
      64     1 Au  79    7.375330    7.664660    4.817400     11.0000     196.9666
      65     1 Au  79    8.850390    5.109780    4.817400     11.0000     196.9666
      66     1 Au  79   10.325460    7.664660    4.817400     11.0000     196.9666
      67     1 Au  79   11.800520    5.109780    4.817400     11.0000     196.9666
      68     1 Au  79   13.275590    7.664660    4.817400     11.0000     196.9666
      69     1 Au  79   14.750650    5.109780    4.817400     11.0000     196.9666
      70     1 Au  79   16.225720    7.664660    4.817400     11.0000     196.9666
      71     1 Au  79    5.900260   10.219550    4.817400     11.0000     196.9666
      72     1 Au  79    8.850390   10.219550    4.817400     11.0000     196.9666
      73     1 Au  79   11.800520   10.219550    4.817400     11.0000     196.9666
      74     1 Au  79   14.750650   10.219550    4.817400     11.0000     196.9666
      75     1 Au  79   17.700780   10.219550    4.817400     11.0000     196.9666
      76     1 Au  79    1.475039    0.832004    7.208300     11.0000     196.9666
      77     1 Au  79    2.941634    3.372982    7.239731     11.0000     196.9666
      78     1 Au  79    4.465691    0.821652    7.251656     11.0000     196.9666
      79     1 Au  79    5.929247    3.362749    7.262121     11.0000     196.9666
      80     1 Au  79    7.366181    0.809330    7.303406     11.0000     196.9666
      81     1 Au  79    8.834563    3.387629    7.286934     11.0000     196.9666
      82     1 Au  79   10.269593    0.790832    7.268050     11.0000     196.9666
      83     1 Au  79   11.705444    3.419587    7.234168     11.0000     196.9666
      84     1 Au  79   13.238707    0.928470    7.222341     11.0000     196.9666
      85     1 Au  79   14.714348    3.451881    7.204065     11.0000     196.9666
      86     1 Au  79    4.419533    5.918290    7.291549     11.0000     196.9666
      87     1 Au  79    5.867471    8.509041    7.228627     11.0000     196.9666
      88     1 Au  79    7.354514    5.955842    7.297965     11.0000     196.9666
      89     1 Au  79    8.804456    8.542285    7.260277     11.0000     196.9666
      90     1 Au  79   10.301915    5.963555    7.261094     11.0000     196.9666
      91     1 Au  79   11.765016    8.464093    7.264488     11.0000     196.9666
      92     1 Au  79   13.252200    5.963915    7.238607     11.0000     196.9666
      93     1 Au  79   14.763380    8.532816    7.253956     11.0000     196.9666
      94     1 Au  79   16.197782    5.975585    7.247116     11.0000     196.9666
      95     1 Au  79   17.700869    8.516169    7.319095     11.0000     196.9666
      96     1 Au  79    7.321002   11.066235    7.229642     11.0000     196.9666
      97     1 Au  79   10.321375   11.045187    7.223293     11.0000     196.9666
      98     1 Au  79   13.187288   11.013947    7.247296     11.0000     196.9666
      99     1 Au  79   16.167512   11.055369    7.248602     11.0000     196.9666
     100     1 Au  79   19.171484   11.097161    7.293805     11.0000     196.9666
     101     1 Au  79    2.892916    1.636961    9.665053     11.0000     196.9666
     102     1 Au  79    4.377392    4.231469    9.709798     11.0000     196.9666
     103     1 Au  79    5.809359    1.680412    9.711313     11.0000     196.9666
     104     1 Au  79    7.280531    4.259939    9.735698     11.0000     196.9666
     105     1 Au  79    8.825383    1.700318    9.706738     11.0000     196.9666
     106     1 Au  79   10.247078    4.260505    9.768579     11.0000     196.9666
     107     1 Au  79   11.820861    1.711331    9.682680     11.0000     196.9666
     108     1 Au  79   13.213518    4.198641    9.640968     11.0000     196.9666
     109     1 Au  79   14.772283    1.678593    9.656870     11.0000     196.9666
     110     1 Au  79   16.154765    4.172386    9.654423     11.0000     196.9666
     111     1 Au  79    5.813687    6.819906    9.709737     11.0000     196.9666
     112     1 Au  79    7.307105    9.377354    9.704694     11.0000     196.9666
     113     1 Au  79    8.770929    6.774026    9.742609     11.0000     196.9666
     114     1 Au  79   10.218866    9.342286    9.681392     11.0000     196.9666
     115     1 Au  79   11.739229    6.768600    9.672960     11.0000     196.9666
     116     1 Au  79   13.195728    9.299521    9.654356     11.0000     196.9666
     117     1 Au  79   14.670922    6.774859    9.665525     11.0000     196.9666
     118     1 Au  79   16.191423    9.328580    9.749751     11.0000     196.9666
     119     1 Au  79   17.566225    6.697143    9.690707     11.0000     196.9666
     120     1 Au  79   19.103405    9.335251    9.705983     11.0000     196.9666
     121     1 Au  79    8.820092   11.902292    9.598472     11.0000     196.9666
     122     1 Au  79   11.747812   11.903909    9.688080     11.0000     196.9666
     123     1 Au  79   14.666876   11.878720    9.676106     11.0000     196.9666
     124     1 Au  79   17.659023   11.867017    9.751154     11.0000     196.9666
     125     1 Au  79   20.642696   11.945592    9.664048     11.0000     196.9666
     126     1 Au  79    0.012445   -0.027859   12.212749     11.0000     196.9666
     127     1 Au  79    1.385405    2.555785   12.232521     11.0000     196.9666
     128     1 Au  79    2.863660   -0.036240   12.192619     11.0000     196.9666
     129     1 Au  79    4.278252    2.456689   12.104417     11.0000     196.9666
     130     1 Au  79    5.818993   -0.064186   12.166963     11.0000     196.9666
     131     1 Au  79    7.344012    2.438815   12.088490     11.0000     196.9666
     132     1 Au  79    8.825857   -0.051663   12.173455     11.0000     196.9666
     133     1 Au  79   10.341181    2.460689   12.202321     11.0000     196.9666
     134     1 Au  79   11.805272   -0.024807   12.119955     11.0000     196.9666
     135     1 Au  79   13.240156    2.536987   12.219348     11.0000     196.9666
     136     1 Au  79    2.855688    5.029173   12.174158     11.0000     196.9666
     137     1 Au  79    4.304582    7.579120   12.065541     11.0000     196.9666
     138     1 Au  79    5.700822    4.908633   12.263734     11.0000     196.9666
     139     1 Au  79    7.256662    7.830764   12.163691     11.0000     196.9666
     140     1 Au  79    8.986279    4.941558   12.290449     11.0000     196.9666
     141     1 Au  79   10.292752    7.665270   12.156004     11.0000     196.9666
     142     1 Au  79   11.845391    5.109967   12.214701     11.0000     196.9666
     143     1 Au  79   13.223781    7.639050   12.167527     11.0000     196.9666
     144     1 Au  79   14.714965    5.092423   12.077011     11.0000     196.9666
     145     1 Au  79   16.140016    7.596374   12.233331     11.0000     196.9666
     146     1 Au  79    5.843083   10.272034   12.098669     11.0000     196.9666
     147     1 Au  79    8.849694   10.207289   12.190899     11.0000     196.9666
     148     1 Au  79   11.709038   10.226993   12.129150     11.0000     196.9666
     149     1 Au  79   14.603205   10.169913   12.107143     11.0000     196.9666
     150     1 Au  79   17.589852   10.126627   12.264515     11.0000     196.9666
     151     2 C    6   17.653787   10.204184   14.333812      4.0000      12.0107
     152     3 O    8   17.474648   10.115576   15.472094      6.0000      15.9994
     153     3 O    8    7.329475    5.929701   13.229058      6.0000      15.9994




 SCF PARAMETERS         Density guess:                                    ATOMIC
                        --------------------------------------------------------
                        max_scf:                                             200
                        max_scf_history:                                       0
                        max_diis:                                              4
                        --------------------------------------------------------
                        eps_scf:                                        1.00E-06
                        eps_scf_history:                                0.00E+00
                        eps_diis:                                       1.00E-01
                        eps_eigval:                                     1.00E-05
                        --------------------------------------------------------
                        level_shift [a.u.]:                                 0.00
                        added MOs                                       200    0
                        --------------------------------------------------------
                        Mixing method:                            BROYDEN_MIXING
                                                charge density mixing in g-space
                        --------------------------------------------------------
                        Smear method:                                FERMI_DIRAC
                        Electronic temperature [K]:                       2300.0
                        Electronic temperature [a.u.]:                  7.28E-03
                        Accuracy threshold:                             1.00E-10
                        --------------------------------------------------------
                        No outer SCF

 KPOINTS| Number of kpoint groups                                              1
 KPOINTS| Size of each kpoint group                                            3
 KPOINTS| Number of kpoints per group                                          2

 MD_PAR| Molecular dynamics protocol (MD input parameters)
 MD_PAR| Ensemble type                                                       NVT
 MD_PAR| Number of time steps                                                 10
 MD_PAR| Time step [fs]                                                 2.000000
 MD_PAR| Temperature [K]                                               50.000000
 MD_PAR| Temperature tolerance [K]                                      0.000000
 MD_PAR| Constraints activated
 MD_PAR| Tolerance for shake                                            0.000001
 MD_PAR| Print MD information every                                    1 step(s)
 MD_PAR| File type   Print frequency [steps]                          File names
 MD_PAR| Coordinates         10                    AIMD_ENERGY-MD.TRAJ-pos-1.xyz
 MD_PAR| Velocities           1                            AIMD_ENERGY-vel-1.xyz
 MD_PAR| Energies             1                               AIMD_ENERGY-1.ener
 MD_PAR| Dump                 1                    AIMD_ENERGY-MD.REST-1.restart

 ROT| Rotational analysis information
 ROT| Principal axes and moments of inertia [a.u.]
 ROT|                           1                   2                   3
 ROT| Eigenvalues      4.98263649310E+09   7.12333681755E+09   8.74763993819E+09
 ROT|      x              0.858476230024      0.113870525886     -0.500052063108
 ROT|      y              0.495819884248      0.064924808344      0.865995041352
 ROT|      z             -0.131077095133      0.991371914367      0.000722866262
 ROT| Number of rotovibrational vectors                                        6

 DOF| Calculation of degrees of freedom
 DOF| Number of atoms                                                        153
 DOF| Number of intramolecular constraints                                   225
 DOF| Number of intermolecular constraints                                     0
 DOF| Invariants (translations + rotations)                                    3
 DOF| Degrees of freedom                                                     231

 DOF| Restraints information
 DOF| Number of intramolecular restraints                                      0
 DOF| Number of intermolecular restraints                                      0

 THERMOSTAT| Thermostat information for PARTICLES
 THERMOSTAT| Type of thermostat                               Nose-Hoover-Chains
 THERMOSTAT| Nose-Hoover-Chain length                                          3
 THERMOSTAT| Nose-Hoover-Chain time constant [fs]                    1000.000000
 THERMOSTAT| Order of Yoshida integrator                                       3
 THERMOSTAT| Number of multiple time steps                                     2
 THERMOSTAT| Initial potential energy                         0.000000000000E+00
 THERMOSTAT| Initial kinetic energy                           0.791703835822E-04
 THERMOSTAT| End of thermostat information for PARTICLES

 MD_VEL| Velocities initialization
 MD_VEL| Initial temperature [K]                                       18.936624
 MD_VEL| COM velocity             0.0000002610     0.0000000219     0.0000021821

 Number of electrons:                                                       1666
 Number of occupied orbitals:                                                833
 Number of molecular orbitals:                                              1033

 Number of orbital functions:                                               3789
 Number of independent orbital functions:                                   3789

 Extrapolation method: initial_guess


 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------


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