[CP2K-user] convergence problem with diagonalization for magnetism and conductive metal oxide

y...@163.com yis... at 163.com
Sun Apr 11 12:10:46 UTC 2021



Dear developers

I’m writing to ask for your help with SCF convergence issues. I have been 
trying to run an SCF calculation with a Co2(II)Mo3(IV)O8 (110) 2-layer slab 
model Owning to the low zero bandgaps (Co2(II)Mo3(IV)O8 one of the most 
important conductive metal oxide), I selected diagonalization as 
convergence algorithm. However, this calculation is not converged. Could 
you please explain the reasons? I try to use diagonalization before with 
smearing at 300 K and 1000 K electronic temperature but it doesn’t work. I 
tried all mixing methods, I found the KERKER_MIXING is a relatively better 
choice. But, the convergence of this calculation also cannot reach the 
desired value (1.0E-6), and only 0.0007 can be reached. I tried to change 
the value of ALPHA, but it also doesn’t work. The SCF cycle never 
converges. I believe there are problems with my input. Could someone give 
me some suggestions? 

I would very much appreciate it if you could give some advice or feedback 
on my input files (enclosed).

 

Thank you in advance for your help.

 

Sichi Yi

Chongqing University
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 DBCSR| CPU Multiplication driver                                           BLAS
 DBCSR| Multrec recursion limit                                              512
 DBCSR| Multiplication stack size                                           1000
 DBCSR| Maximum elements for images                                    UNLIMITED
 DBCSR| Multiplicative factor virtual images                                   1
 DBCSR| Use multiplication densification                                       T
 DBCSR| Multiplication size stacks                                             3
 DBCSR| Number of 3D layers                                               SINGLE
 DBCSR| Use MPI memory allocation                                              T
 DBCSR| Use RMA algorithm                                                      F
 DBCSR| Use Communication thread                                               T
 DBCSR| Communication thread load                                             87


  **** **** ******  **  PROGRAM STARTED AT               2021-04-11 18:21:56.344
 ***** ** ***  *** **   PROGRAM STARTED ON                       h2112.para.cstc
 **    ****   ******    PROGRAM STARTED BY                               sc32189
 ***** **    ** ** **   PROGRAM PROCESS ID                                 13683
  **** **  *******  **  PROGRAM STARTED IN            /public3/home/sc32189/11-3

 CP2K| version string:                                          CP2K version 7.1
 CP2K| source code revision number:                                  git:e635599
 CP2K| cp2kflags: libint fftw3 libxc parallel mpi3 scalapack max_contr=4 mkl    
 CP2K| is freely available from                            https://www.cp2k.org/
 CP2K| Program compiled at                           Mon Jan 6 14:34:24 CST 2020
 CP2K| Program compiled on                                         ln1.para.cstc
 CP2K| Program compiled for                                   Linux-x86-64-intel
 CP2K| Data directory path       /public1/home/deploy/cstc9-cp2k/cp2k-7.1.0/data
 CP2K| Input file name                                                  cp2k.inp
 
 GLOBAL| Force Environment number                                              1
 GLOBAL| Basis set file name             /public3/home/sc32189/data/BASIS_MOLOPT
 GLOBAL| Potential file name            /public3/home/sc32189/data/GTH_POTENTIAL
 GLOBAL| MM Potential file name                                     MM_POTENTIAL
 GLOBAL| Coordinate file name                                      __STD_INPUT__
 GLOBAL| Method name                                                        CP2K
 GLOBAL| Project name                                                       cp2k
 GLOBAL| Preferred FFT library                                             FFTW3
 GLOBAL| Preferred diagonalization lib.                                       SL
 GLOBAL| Run type                                                   ENERGY_FORCE
 GLOBAL| All-to-all communication in single precision                          F
 GLOBAL| FFTs using library dependent lengths                                  F
 GLOBAL| Global print level                                                  LOW
 GLOBAL| MPI I/O enabled                                                       T
 GLOBAL| Total number of message passing processes                            24
 GLOBAL| Number of threads for this process                                    1
 GLOBAL| This output is from process                                           0
 GLOBAL| CPU model name                Intel(R) Xeon(R) CPU E5-2678 v3 @ 2.50GHz

 MEMORY| system memory details [Kb]
 MEMORY|                        rank 0           min           max       average
 MEMORY| MemTotal             65877884      65877884      65877884      65877884
 MEMORY| MemFree              45583028      45583028      45583028      45583028
 MEMORY| Buffers                     0             0             0             0
 MEMORY| Cached               15562148      15562148      15562148      15562148
 MEMORY| Slab                   851916        851916        851916        851916
 MEMORY| SReclaimable           294536        294536        294536        294536
 MEMORY| MemLikelyFree        61439712      61439712      61439712      61439712

 
 GENERATE|  Preliminary Number of Bonds generated:                             0
 GENERATE|  Achieved consistency in connectivity generation.

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 **                                                ... make the atoms dance   **
 **                                                                           **
 **            Copyright (C) by CP2K developers group (2000 - 2019)           **
 **                                                                           **
 *******************************************************************************


 TOTAL NUMBERS AND MAXIMUM NUMBERS

  Total number of            - Atomic kinds:                                   6
                             - Atoms:                                         64
                             - Shell sets:                                    64
                             - Shells:                                       398
                             - Primitive Cartesian functions:                360
                             - Cartesian basis functions:                   1338
                             - Spherical basis functions:                   1170

  Maximum angular momentum of- Orbital basis functions:                        3
                             - Local part of the GTH pseudopotential:          2
                             - Non-local part of the GTH pseudopotential:      4


 SCF PARAMETERS         Density guess:                                   RESTART
                        --------------------------------------------------------
                        max_scf:                                             300
                        max_scf_history:                                       0
                        max_diis:                                              4
                        --------------------------------------------------------
                        eps_scf:                                        1.00E-06
                        eps_scf_history:                                0.00E+00
                        eps_diis:                                       1.00E-01
                        eps_eigval:                                     1.00E-05
                        --------------------------------------------------------
                        level_shift [a.u.]:                                 0.00
                        added MOs                                       500  500
                        --------------------------------------------------------
                        Mixing method:                             KERKER_MIXING
                                                charge density mixing in g-space
                        --------------------------------------------------------
                        Smear method:                                FERMI_DIRAC
                        Electronic temperature [K]:                       4000.0
                        Electronic temperature [a.u.]:                  1.27E-02
                        Accuracy threshold:                             1.00E-10
                        --------------------------------------------------------
                        Outer loop SCF in use 
                        No variables optimised in outer loop
                        eps_scf                                         1.00E-04
                        max_scf                                                2
                        No outer loop optimization
                        step_size                                       5.00E-01

 Spin 1

 Number of electrons:                                                        320
 Number of occupied orbitals:                                                320
 Number of molecular orbitals:                                               820

 Spin 2

 Number of electrons:                                                        308
 Number of occupied orbitals:                                                308
 Number of molecular orbitals:                                               808

 Number of orbital functions:                                               1170
 Number of independent orbital functions:                                   1170

 Extrapolation method: initial_guess

 *** WARNING in qs_initial_guess.F:280 :: User requested to restart the    ***
 *** wavefunction from the file named: ./cp2k-RESTART.wfn. This file does  ***
 *** not exist. Please check the existence of the file or change properly  ***
 *** the value of the keyword WFN_RESTART_FILE_NAME. Calculation continues ***
 *** using ATOMIC GUESS.                                                   ***



 SCF WAVEFUNCTION OPTIMIZATION

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 NoMix/Diag. 0.10E+00    3.6     0.91828589     -3310.4323754513 -3.31E+03
     2 Kerker/Diag.0.10E+00    4.9     0.10859948     -3212.2630895323  9.82E+01
     3 Kerker/Diag.0.10E+00    4.8     0.26297516     -3223.4626859677 -1.12E+01
     4 Kerker/Diag.0.10E+00    4.6     0.28019196     -3241.9790471492 -1.85E+01
     5 Kerker/Diag.0.10E+00    4.6     0.15779508     -3261.0685822893 -1.91E+01
     6 Kerker/Diag.0.10E+00    4.6     0.07174161     -3275.9526626615 -1.49E+01
     7 Kerker/Diag.0.10E+00    4.6     0.04845492     -3286.3811307754 -1.04E+01
     8 Kerker/Diag.0.10E+00    4.7     0.03393420     -3293.3463702785 -6.97E+00
     9 Kerker/Diag.0.10E+00    4.6     0.02463003     -3298.0394708764 -4.69E+00
    10 Kerker/Diag.0.10E+00    4.7     0.01848159     -3301.3153577780 -3.28E+00
    11 Kerker/Diag.0.10E+00    4.6     0.01437143     -3303.7117447402 -2.40E+00
    12 Kerker/Diag.0.10E+00    4.5     0.01166017     -3305.5558132119 -1.84E+00
    13 Kerker/Diag.0.10E+00    4.4     0.00991263     -3307.0396961336 -1.48E+00
    14 Kerker/Diag.0.10E+00    4.3     0.00874073     -3308.2704199528 -1.23E+00
    15 Kerker/Diag.0.10E+00    4.3     0.00790131     -3309.3087510947 -1.04E+00
    16 Kerker/Diag.0.10E+00    4.5     0.00725282     -3310.1889720125 -8.80E-01
    17 Kerker/Diag.0.10E+00    4.2     0.00671775     -3310.9343440592 -7.45E-01
    18 Kerker/Diag.0.10E+00    4.2     0.00625382     -3311.5617432860 -6.27E-01
    19 Kerker/Diag.0.10E+00    4.4     0.00583645     -3312.0852679025 -5.24E-01
    20 Kerker/Diag.0.10E+00    4.2     0.00545615     -3312.5177157438 -4.32E-01
    21 Kerker/Diag.0.10E+00    4.3     0.00514216     -3312.8704274542 -3.53E-01
    22 Kerker/Diag.0.10E+00    4.3     0.00501903     -3313.1536159889 -2.83E-01
    23 Kerker/Diag.0.10E+00    4.5     0.00489448     -3313.3757236951 -2.22E-01
    24 Kerker/Diag.0.10E+00    4.2     0.00476343     -3313.5441073867 -1.68E-01
    25 Kerker/Diag.0.10E+00    4.3     0.00463470     -3313.6665233451 -1.22E-01
    26 Kerker/Diag.0.10E+00    4.4     0.00450647     -3313.7494104005 -8.29E-02
    27 Kerker/Diag.0.10E+00    4.4     0.00438340     -3313.7981928982 -4.88E-02
    28 Kerker/Diag.0.10E+00    4.6     0.00425828     -3313.8173898142 -1.92E-02
    29 Kerker/Diag.0.10E+00    4.4     0.00413822     -3313.8112141904  6.18E-03
    30 Kerker/Diag.0.10E+00    4.4     0.00401710     -3313.7830883114  2.81E-02
    31 Kerker/Diag.0.10E+00    4.3     0.00390109     -3313.7373298779  4.58E-02
    32 Kerker/Diag.0.10E+00    4.4     0.00378651     -3313.6765504791  6.08E-02
    33 Kerker/Diag.0.10E+00    4.4     0.00367688     -3313.6033894212  7.32E-02
    34 Kerker/Diag.0.10E+00    4.2     0.00357017     -3313.5197599084  8.36E-02
    35 Kerker/Diag.0.10E+00    4.4     0.00346388     -3313.4275284011  9.22E-02
    36 Kerker/Diag.0.10E+00    4.6     0.00336304     -3313.3292696789  9.83E-02
    37 Kerker/Diag.0.10E+00    4.4     0.00326486     -3313.2258372994  1.03E-01
    38 Kerker/Diag.0.10E+00    4.2     0.00316798     -3313.1191060656  1.07E-01
    39 Kerker/Diag.0.10E+00    4.6     0.00307505     -3313.0095990843  1.10E-01
    40 Kerker/Diag.0.10E+00    4.4     0.00298437     -3312.8984809092  1.11E-01
    41 Kerker/Diag.0.10E+00    4.4     0.00289599     -3312.7866349577  1.12E-01
    42 Kerker/Diag.0.10E+00    4.4     0.00281300     -3312.6751977335  1.11E-01
    43 Kerker/Diag.0.10E+00    4.7     0.00273073     -3312.5634717348  1.12E-01
    44 Kerker/Diag.0.10E+00    4.6     0.00265035     -3312.4530391288  1.10E-01
    45 Kerker/Diag.0.10E+00    4.5     0.00257266     -3312.3442379350  1.09E-01
    46 Kerker/Diag.0.10E+00    4.6     0.00249865     -3312.2373559160  1.07E-01
    47 Kerker/Diag.0.10E+00    4.5     0.00242651     -3312.1323832872  1.05E-01
    48 Kerker/Diag.0.10E+00    4.3     0.00235638     -3312.0297743014  1.03E-01
    49 Kerker/Diag.0.10E+00    4.3     0.00228902     -3311.9294009809  1.00E-01
    50 Kerker/Diag.0.10E+00    4.7     0.00222245     -3311.8315402902  9.79E-02
    51 Kerker/Diag.0.10E+00    4.4     0.00215902     -3311.7368912152  9.46E-02
    52 Kerker/Diag.0.10E+00    4.6     0.00209777     -3311.6450647817  9.18E-02
    53 Kerker/Diag.0.10E+00    4.6     0.00203601     -3311.5559762319  8.91E-02
    54 Kerker/Diag.0.10E+00    4.5     0.00197864     -3311.4701741378  8.58E-02
    55 Kerker/Diag.0.10E+00    4.4     0.00192274     -3311.3872565531  8.29E-02
    56 Kerker/Diag.0.10E+00    4.4     0.00186913     -3311.3072608516  8.00E-02
    57 Kerker/Diag.0.10E+00    4.6     0.00181533     -3311.2298472536  7.74E-02
    58 Kerker/Diag.0.10E+00    4.2     0.00176485     -3311.1556381727  7.42E-02
    59 Kerker/Diag.0.10E+00    4.4     0.00171426     -3311.0844134557  7.12E-02
    60 Kerker/Diag.0.10E+00    4.2     0.00166628     -3311.0159211140  6.85E-02
    61 Kerker/Diag.0.10E+00    4.5     0.00162008     -3310.9503267832  6.56E-02
    62 Kerker/Diag.0.10E+00    4.3     0.00157453     -3310.8872986992  6.30E-02
    63 Kerker/Diag.0.10E+00    4.5     0.00153205     -3310.8267905962  6.05E-02
    64 Kerker/Diag.0.10E+00    4.6     0.00148881     -3310.7686299453  5.82E-02
    65 Kerker/Diag.0.10E+00    4.2     0.00144825     -3310.7130026146  5.56E-02
    66 Kerker/Diag.0.10E+00    4.5     0.00140775     -3310.6596600539  5.33E-02
    67 Kerker/Diag.0.10E+00    4.3     0.00136877     -3310.6085159021  5.11E-02
    68 Kerker/Diag.0.10E+00    4.5     0.00133188     -3310.5599540038  4.86E-02
    69 Kerker/Diag.0.10E+00    4.6     0.00129521     -3310.5132070323  4.67E-02
    70 Kerker/Diag.0.10E+00    4.7     0.00125991     -3310.4684332812  4.48E-02
    71 Kerker/Diag.0.10E+00    4.8     0.00122560     -3310.4255999950  4.28E-02
    72 Kerker/Diag.0.10E+00    4.6     0.00119234     -3310.3845965330  4.10E-02
    73 Kerker/Diag.0.10E+00    4.4     0.00115985     -3310.3454411905  3.92E-02
    74 Kerker/Diag.0.10E+00    4.4     0.00112975     -3310.3081212517  3.73E-02
    75 Kerker/Diag.0.10E+00    4.5     0.00109839     -3310.2720768637  3.60E-02
    76 Kerker/Diag.0.10E+00    4.7     0.00106894     -3310.2377894105  3.43E-02
    77 Kerker/Diag.0.10E+00    4.4     0.00103978     -3310.2047697666  3.30E-02
    78 Kerker/Diag.0.10E+00    4.5     0.00101199     -3310.1735217228  3.12E-02
    79 Kerker/Diag.0.10E+00    4.3     0.00098487     -3310.1436804005  2.98E-02
    80 Kerker/Diag.0.10E+00    4.3     0.00095861     -3310.1153496109  2.83E-02
    81 Kerker/Diag.0.10E+00    4.4     0.00093380     -3310.0882154196  2.71E-02
    82 Kerker/Diag.0.10E+00    4.5     0.00090836     -3310.0620967557  2.61E-02
    83 Kerker/Diag.0.10E+00    4.3     0.00088529     -3310.0374584553  2.46E-02
    84 Kerker/Diag.0.10E+00    4.4     0.00086409     -3310.0137929676  2.37E-02
    85 Kerker/Diag.0.10E+00    4.4     0.00084647     -3309.9913995472  2.24E-02
    86 Kerker/Diag.0.10E+00    4.4     0.00082677     -3309.9697236625  2.17E-02
    87 Kerker/Diag.0.10E+00    4.3     0.00080901     -3309.9490906403  2.06E-02
    88 Kerker/Diag.0.10E+00    4.3     0.00079019     -3309.9290993942  2.00E-02
    89 Kerker/Diag.0.10E+00    4.5     0.00077134     -3309.9099589908  1.91E-02
    90 Kerker/Diag.0.10E+00    4.4     0.00075474     -3309.8916904399  1.83E-02
    91 Kerker/Diag.0.10E+00    4.4     0.00073938     -3309.8740653388  1.76E-02
    92 Kerker/Diag.0.10E+00    4.3     0.00072260     -3309.8575370584  1.65E-02
    93 Kerker/Diag.0.10E+00    4.1     0.00070628     -3309.8417943485  1.57E-02
    94 Kerker/Diag.0.10E+00    4.0     0.00069022     -3309.8266964355  1.51E-02
    95 Kerker/Diag.0.10E+00    4.5     0.00067693     -3309.8124977928  1.42E-02
    96 Kerker/Diag.0.10E+00    4.2     0.00066218     -3309.7988181768  1.37E-02
    97 Kerker/Diag.0.10E+00    4.3     0.00065284     -3309.7854657503  1.34E-02
    98 Kerker/Diag.0.10E+00    4.4     0.00065307     -3309.7730440449  1.24E-02
    99 Kerker/Diag.0.10E+00    4.3     0.00065647     -3309.7612451318  1.18E-02
   100 Kerker/Diag.0.10E+00    4.3     0.00065566     -3309.7493087295  1.19E-02
   101 Kerker/Diag.0.10E+00    4.3     0.00065709     -3309.7381677599  1.11E-02
   102 Kerker/Diag.0.10E+00    4.1     0.00065761     -3309.7275386683  1.06E-02
   103 Kerker/Diag.0.10E+00    4.3     0.00065825     -3309.7173199782  1.02E-02
   104 Kerker/Diag.0.10E+00    4.3     0.00066064     -3309.7077297273  9.59E-03
   105 Kerker/Diag.0.10E+00    4.3     0.00065915     -3309.6987227136  9.01E-03
   106 Kerker/Diag.0.10E+00    4.3     0.00066227     -3309.6900928564  8.63E-03
   107 Kerker/Diag.0.10E+00    4.2     0.00066364     -3309.6815122135  8.58E-03
   108 Kerker/Diag.0.10E+00    4.0     0.00066232     -3309.6733013768  8.21E-03
   109 Kerker/Diag.0.10E+00    4.4     0.00066399     -3309.6658492654  7.45E-03
   110 Kerker/Diag.0.10E+00    4.0     0.00066415     -3309.6582710833  7.58E-03
   111 Kerker/Diag.0.10E+00    4.2     0.00066412     -3309.6512148727  7.06E-03
   112 Kerker/Diag.0.10E+00    4.1     0.00066600     -3309.6444485390  6.77E-03
   113 Kerker/Diag.0.10E+00    4.2     0.00066531     -3309.6376449125  6.80E-03
   114 Kerker/Diag.0.10E+00    3.9     0.00066804     -3309.6317747240  5.87E-03
   115 Kerker/Diag.0.10E+00    4.0     0.00066622     -3309.6254163836  6.36E-03
   116 Kerker/Diag.0.10E+00    4.2     0.00066661     -3309.6198532096  5.56E-03
   117 Kerker/Diag.0.10E+00    4.1     0.00066952     -3309.6145143272  5.34E-03
   118 Kerker/Diag.0.10E+00    4.3     0.00066903     -3309.6092866266  5.23E-03
   119 Kerker/Diag.0.10E+00    4.5     0.00067113     -3309.6042178146  5.07E-03
   120 Kerker/Diag.0.10E+00    4.2     0.00067128     -3309.5993086324  4.91E-03
   121 Kerker/Diag.0.10E+00    4.3     0.00067075     -3309.5945774221  4.73E-03
   122 Kerker/Diag.0.10E+00    4.4     0.00067210     -3309.5900618025  4.52E-03
   123 Kerker/Diag.0.10E+00    4.3     0.00066896     -3309.5859204542  4.14E-03
   124 Kerker/Diag.0.10E+00    4.1     0.00067037     -3309.5821822268  3.74E-03
   125 Kerker/Diag.0.10E+00    4.3     0.00067026     -3309.5781648142  4.02E-03
   126 Kerker/Diag.0.10E+00    4.2     0.00067222     -3309.5747578176  3.41E-03
   127 Kerker/Diag.0.10E+00    4.2     0.00067059     -3309.5710639469  3.69E-03
   128 Kerker/Diag.0.10E+00    4.2     0.00067266     -3309.5677438762  3.32E-03
   129 Kerker/Diag.0.10E+00    4.1     0.00067405     -3309.5646802420  3.06E-03
   130 Kerker/Diag.0.10E+00    4.0     0.00067501     -3309.5616535518  3.03E-03
   131 Kerker/Diag.0.10E+00    4.2     0.00067380     -3309.5584821964  3.17E-03
   132 Kerker/Diag.0.10E+00    4.1     0.00067414     -3309.5558090722  2.67E-03
   133 Kerker/Diag.0.10E+00    4.2     0.00067550     -3309.5530791587  2.73E-03
   134 Kerker/Diag.0.10E+00    4.0     0.00067499     -3309.5504975962  2.58E-03
   135 Kerker/Diag.0.10E+00    4.2     0.00067335     -3309.5479246258  2.57E-03
   136 Kerker/Diag.0.10E+00    4.2     0.00067524     -3309.5455133110  2.41E-03
   137 Kerker/Diag.0.10E+00    4.0     0.00067404     -3309.5430951288  2.42E-03
   138 Kerker/Diag.0.10E+00    4.1     0.00067477     -3309.5410840099  2.01E-03
   139 Kerker/Diag.0.10E+00    4.2     0.00067545     -3309.5389486710  2.14E-03
   140 Kerker/Diag.0.10E+00    4.1     0.00067459     -3309.5370932819  1.86E-03
   141 Kerker/Diag.0.10E+00    4.4     0.00067551     -3309.5355196091  1.57E-03
   142 Kerker/Diag.0.10E+00    4.3     0.00067531     -3309.5335170103  2.00E-03
   143 Kerker/Diag.0.10E+00    4.0     0.00067498     -3309.5318658551  1.65E-03
   144 Kerker/Diag.0.10E+00    4.1     0.00067428     -3309.5300595731  1.81E-03
   145 Kerker/Diag.0.10E+00    4.0     0.00067450     -3309.5284839269  1.58E-03
   146 Kerker/Diag.0.10E+00    4.2     0.00067353     -3309.5270624557  1.42E-03
   147 Kerker/Diag.0.10E+00    4.1     0.00067322     -3309.5258986177  1.16E-03
   148 Kerker/Diag.0.10E+00    4.4     0.00067575     -3309.5248187294  1.08E-03
   149 Kerker/Diag.0.10E+00    4.2     0.00067596     -3309.5232208212  1.60E-03
   150 Kerker/Diag.0.10E+00    4.1     0.00067426     -3309.5215805815  1.64E-03
   151 Kerker/Diag.0.10E+00    4.2     0.00067318     -3309.5203782407  1.20E-03
   152 Kerker/Diag.0.10E+00    4.1     0.00067380     -3309.5194029865  9.75E-04
   153 Kerker/Diag.0.10E+00    4.1     0.00067498     -3309.5181363963  1.27E-03
   154 Kerker/Diag.0.10E+00    4.2     0.00067303     -3309.5170168063  1.12E-03
   155 Kerker/Diag.0.10E+00    4.3     0.00067303     -3309.5158342166  1.18E-03
   156 Kerker/Diag.0.10E+00    4.3     0.00067259     -3309.5148037139  1.03E-03
   157 Kerker/Diag.0.10E+00    4.5     0.00067121     -3309.5138211810  9.83E-04
   158 Kerker/Diag.0.10E+00    4.4     0.00067167     -3309.5131747159  6.46E-04
   159 Kerker/Diag.0.10E+00    4.5     0.00067127     -3309.5122976084  8.77E-04
   160 Kerker/Diag.0.10E+00    4.4     0.00067097     -3309.5112709179  1.03E-03
   161 Kerker/Diag.0.10E+00    4.4     0.00066966     -3309.5102414117  1.03E-03
   162 Kerker/Diag.0.10E+00    4.3     0.00067076     -3309.5096801126  5.61E-04
   163 Kerker/Diag.0.10E+00    4.4     0.00066906     -3309.5087457166  9.34E-04
   164 Kerker/Diag.0.10E+00    4.4     0.00066868     -3309.5082744194  4.71E-04
   165 Kerker/Diag.0.10E+00    4.3     0.00066896     -3309.5073418527  9.33E-04
   166 Kerker/Diag.0.10E+00    4.4     0.00066729     -3309.5062565238  1.09E-03
   167 Kerker/Diag.0.10E+00    4.4     0.00066712     -3309.5056048981  6.52E-04
   168 Kerker/Diag.0.10E+00    4.5     0.00066554     -3309.5047935115  8.11E-04
   169 Kerker/Diag.0.10E+00    4.5     0.00066705     -3309.5042227558  5.71E-04
   170 Kerker/Diag.0.10E+00    4.4     0.00066523     -3309.5033311558  8.92E-04
   171 Kerker/Diag.0.10E+00    4.2     0.00066490     -3309.5027308657  6.00E-04
   172 Kerker/Diag.0.10E+00    4.4     0.00066234     -3309.5020899918  6.41E-04
   173 Kerker/Diag.0.10E+00    4.4     0.00066376     -3309.5016889334  4.01E-04
   174 Kerker/Diag.0.10E+00    4.2     0.00066264     -3309.5008871113  8.02E-04
   175 Kerker/Diag.0.10E+00    4.2     0.00065964     -3309.5001848404  7.02E-04
   176 Kerker/Diag.0.10E+00    4.4     0.00065912     -3309.4997783456  4.06E-04
   177 Kerker/Diag.0.10E+00    4.4     0.00065933     -3309.4993687292  4.10E-04
   178 Kerker/Diag.0.10E+00    4.4     0.00065874     -3309.4987650505  6.04E-04
   179 Kerker/Diag.0.10E+00    4.5     0.00065770     -3309.4982449975  5.20E-04
   180 Kerker/Diag.0.10E+00    4.3     0.00065557     -3309.4975319283  7.13E-04
   181 Kerker/Diag.0.10E+00    4.5     0.00065435     -3309.4972794309  2.52E-04
   182 Kerker/Diag.0.10E+00    4.4     0.00065343     -3309.4968940841  3.85E-04
   183 Kerker/Diag.0.10E+00    4.3     0.00065294     -3309.4963714569  5.23E-04
   184 Kerker/Diag.0.10E+00    4.3     0.00065123     -3309.4956334208  7.38E-04
   185 Kerker/Diag.0.10E+00    4.4     0.00064961     -3309.4952017577  4.32E-04
   186 Kerker/Diag.0.10E+00    4.3     0.00064929     -3309.4949408333  2.61E-04
   187 Kerker/Diag.0.10E+00    4.4     0.00064861     -3309.4943793704  5.61E-04
   188 Kerker/Diag.0.10E+00    4.5     0.00064688     -3309.4938830431  4.96E-04
   189 Kerker/Diag.0.10E+00    4.5     0.00064535     -3309.4934121988  4.71E-04
   190 Kerker/Diag.0.10E+00    4.3     0.00064348     -3309.4929759654  4.36E-04
   191 Kerker/Diag.0.10E+00    4.3     0.00064262     -3309.4926905241  2.85E-04
   192 Kerker/Diag.0.10E+00    4.5     0.00064238     -3309.4922561830  4.34E-04
   193 Kerker/Diag.0.10E+00    4.3     0.00064073     -3309.4917756671  4.81E-04
   194 Kerker/Diag.0.10E+00    4.4     0.00063903     -3309.4915364648  2.39E-04
   195 Kerker/Diag.0.10E+00    4.4     0.00063785     -3309.4910347308  5.02E-04
   196 Kerker/Diag.0.10E+00    4.3     0.00063610     -3309.4906731280  3.62E-04
   197 Kerker/Diag.0.10E+00    4.6     0.00063460     -3309.4901526628  5.20E-04
   198 Kerker/Diag.0.10E+00    4.3     0.00063327     -3309.4897653328  3.87E-04
   199 Kerker/Diag.0.10E+00    4.6     0.00062990     -3309.4894185504  3.47E-04
   200 Kerker/Diag.0.10E+00    4.5     0.00063102     -3309.4893829094  3.56E-05
   201 Kerker/Diag.0.10E+00    4.3     0.00063005     -3309.4887448422  6.38E-04
   202 Kerker/Diag.0.10E+00    4.3     0.00062660     -3309.4881267265  6.18E-04
   203 Kerker/Diag.0.10E+00    4.4     0.00062567     -3309.4878327010  2.94E-04
   204 Kerker/Diag.0.10E+00    4.6     0.00062435     -3309.4873057605  5.27E-04
   205 Kerker/Diag.0.10E+00    4.2     0.00062332     -3309.4867945984  5.11E-04
   206 Kerker/Diag.0.10E+00    4.3     0.00062051     -3309.4861986694  5.96E-04
   207 Kerker/Diag.0.10E+00    4.5     0.00061909     -3309.4857815835  4.17E-04
   208 Kerker/Diag.0.10E+00    4.4     0.00061567     -3309.4850766998  7.05E-04
   209 Kerker/Diag.0.10E+00    4.3     0.00061490     -3309.4848099031  2.67E-04
   210 Kerker/Diag.0.10E+00    4.4     0.00061366     -3309.4843066263  5.03E-04
   211 Kerker/Diag.0.10E+00    4.5     0.00061111     -3309.4835659245  7.41E-04
   212 Kerker/Diag.0.10E+00    4.4     0.00060868     -3309.4830941162  4.72E-04
   213 Kerker/Diag.0.10E+00    4.5     0.00060699     -3309.4826481255  4.46E-04
   214 Kerker/Diag.0.10E+00    4.6     0.00060531     -3309.4822113457  4.37E-04
   215 Kerker/Diag.0.10E+00    4.6     0.00060430     -3309.4817949917  4.16E-04
   216 Kerker/Diag.0.10E+00    4.3     0.00060205     -3309.4809924968  8.02E-04
   217 Kerker/Diag.0.10E+00    4.3     0.00059947     -3309.4802538987  7.39E-04
   218 Kerker/Diag.0.10E+00    4.4     0.00059740     -3309.4797537769  5.00E-04
   219 Kerker/Diag.0.10E+00    4.4     0.00059542     -3309.4792292454  5.25E-04
   220 Kerker/Diag.0.10E+00    4.4     0.00059338     -3309.4787674571  4.62E-04
   221 Kerker/Diag.0.10E+00    4.4     0.00059030     -3309.4782965338  4.71E-04
   222 Kerker/Diag.0.10E+00    4.2     0.00058882     -3309.4779542865  3.42E-04
   223 Kerker/Diag.0.10E+00    4.3     0.00058744     -3309.4775039575  4.50E-04
   224 Kerker/Diag.0.10E+00    4.5     0.00058512     -3309.4767966812  7.07E-04
   225 Kerker/Diag.0.10E+00    4.4     0.00058280     -3309.4762379145  5.59E-04
   226 Kerker/Diag.0.10E+00    4.4     0.00058029     -3309.4757152073  5.23E-04
   227 Kerker/Diag.0.10E+00    4.3     0.00057896     -3309.4753254910  3.90E-04
   228 Kerker/Diag.0.10E+00    4.3     0.00057632     -3309.4746536895  6.72E-04
   229 Kerker/Diag.0.10E+00    4.4     0.00057353     -3309.4741084946  5.45E-04
   230 Kerker/Diag.0.10E+00    4.5     0.00057185     -3309.4735989845  5.10E-04
   231 Kerker/Diag.0.10E+00    4.2     0.00056951     -3309.4729007444  6.98E-04
   232 Kerker/Diag.0.10E+00    4.4     0.00056684     -3309.4723309369  5.70E-04
   233 Kerker/Diag.0.10E+00    4.3     0.00056461     -3309.4717585031  5.72E-04
   234 Kerker/Diag.0.10E+00    4.4     0.00056255     -3309.4711650177  5.93E-04
   235 Kerker/Diag.0.10E+00    4.4     0.00055993     -3309.4705144654  6.51E-04
   236 Kerker/Diag.0.10E+00    4.5     0.00055765     -3309.4699797055  5.35E-04
   237 Kerker/Diag.0.10E+00    4.5     0.00055531     -3309.4693380978  6.42E-04
   238 Kerker/Diag.0.10E+00    4.4     0.00055302     -3309.4685671152  7.71E-04
   239 Kerker/Diag.0.10E+00    4.6     0.00054987     -3309.4679198639  6.47E-04
   240 Kerker/Diag.0.10E+00    4.7     0.00054740     -3309.4674443842  4.75E-04
   241 Kerker/Diag.0.10E+00    4.6     0.00054537     -3309.4668649902  5.79E-04
   242 Kerker/Diag.0.10E+00    4.5     0.00054284     -3309.4662100779  6.55E-04
   243 Kerker/Diag.0.10E+00    4.4     0.00054044     -3309.4656863523  5.24E-04
   244 Kerker/Diag.0.10E+00    4.5     0.00053831     -3309.4650529303  6.33E-04
   245 Kerker/Diag.0.10E+00    4.6     0.00053585     -3309.4643347396  7.18E-04
   246 Kerker/Diag.0.10E+00    4.3     0.00053213     -3309.4637217930  6.13E-04
   247 Kerker/Diag.0.10E+00    4.5     0.00053056     -3309.4633614065  3.60E-04
   248 Kerker/Diag.0.10E+00    4.6     0.00052812     -3309.4626962440  6.65E-04
   249 Kerker/Diag.0.10E+00    4.4     0.00052603     -3309.4620517250  6.45E-04
   250 Kerker/Diag.0.10E+00    4.4     0.00052270     -3309.4613619127  6.90E-04
   251 Kerker/Diag.0.10E+00    4.3     0.00051995     -3309.4608039110  5.58E-04
   252 Kerker/Diag.0.10E+00    4.2     0.00051784     -3309.4602785387  5.25E-04
   253 Kerker/Diag.0.10E+00    4.2     0.00051484     -3309.4595908003  6.88E-04
   254 Kerker/Diag.0.10E+00    4.3     0.00051282     -3309.4590283862  5.62E-04
   255 Kerker/Diag.0.10E+00    4.5     0.00050991     -3309.4583276983  7.01E-04
   256 Kerker/Diag.0.10E+00    4.2     0.00050720     -3309.4577524595  5.75E-04
   257 Kerker/Diag.0.10E+00    4.4     0.00050465     -3309.4570572059  6.95E-04
   258 Kerker/Diag.0.10E+00    4.2     0.00050166     -3309.4564331751  6.24E-04
   259 Kerker/Diag.0.10E+00    4.4     0.00049900     -3309.4558451879  5.88E-04
   260 Kerker/Diag.0.10E+00    4.5     0.00049662     -3309.4552775810  5.68E-04
   261 Kerker/Diag.0.10E+00    4.4     0.00049438     -3309.4547026985  5.75E-04
   262 Kerker/Diag.0.10E+00    4.7     0.00049162     -3309.4541044061  5.98E-04
   263 Kerker/Diag.0.10E+00    4.5     0.00048905     -3309.4534789520  6.25E-04
   264 Kerker/Diag.0.10E+00    4.5     0.00048644     -3309.4528491651  6.30E-04
   265 Kerker/Diag.0.10E+00    4.5     0.00048337     -3309.4521545718  6.95E-04
   266 Kerker/Diag.0.10E+00    4.4     0.00048061     -3309.4515918750  5.63E-04
   267 Kerker/Diag.0.10E+00    4.3     0.00047818     -3309.4510003403  5.92E-04
   268 Kerker/Diag.0.10E+00    4.5     0.00047526     -3309.4503520594  6.48E-04
   269 Kerker/Diag.0.10E+00    4.4     0.00047289     -3309.4498001296  5.52E-04
   270 Kerker/Diag.0.10E+00    4.5     0.00047025     -3309.4491514467  6.49E-04
   271 Kerker/Diag.0.10E+00    4.4     0.00046771     -3309.4485285293  6.23E-04
   272 Kerker/Diag.0.10E+00    4.3     0.00046481     -3309.4478582673  6.70E-04
   273 Kerker/Diag.0.10E+00    4.2     0.00046225     -3309.4472367210  6.22E-04
   274 Kerker/Diag.0.10E+00    4.4     0.00045956     -3309.4465707634  6.66E-04
   275 Kerker/Diag.0.10E+00    4.5     0.00045644     -3309.4458752560  6.96E-04
   276 Kerker/Diag.0.10E+00    4.7     0.00045369     -3309.4452544491  6.21E-04
   277 Kerker/Diag.0.10E+00    4.6     0.00045100     -3309.4446713463  5.83E-04
   278 Kerker/Diag.0.10E+00    4.4     0.00044846     -3309.4441330025  5.38E-04
   279 Kerker/Diag.0.10E+00    4.4     0.00044571     -3309.4435117817  6.21E-04
   280 Kerker/Diag.0.10E+00    4.4     0.00044291     -3309.4429534164  5.58E-04
   281 Kerker/Diag.0.10E+00    4.5     0.00044043     -3309.4423525255  6.01E-04
   282 Kerker/Diag.0.10E+00    4.6     0.00043759     -3309.4417398356  6.13E-04
   283 Kerker/Diag.0.10E+00    4.7     0.00043488     -3309.4411588483  5.81E-04
   284 Kerker/Diag.0.10E+00    4.6     0.00043204     -3309.4405798649  5.79E-04
   285 Kerker/Diag.0.10E+00    4.4     0.00042975     -3309.4400838519  4.96E-04
   286 Kerker/Diag.0.10E+00    4.5     0.00042693     -3309.4394372617  6.47E-04
   287 Kerker/Diag.0.10E+00    4.4     0.00042430     -3309.4388767547  5.61E-04
   288 Kerker/Diag.0.10E+00    4.7     0.00042144     -3309.4382580528  6.19E-04
   289 Kerker/Diag.0.10E+00    4.7     0.00041878     -3309.4377136960  5.44E-04
   290 Kerker/Diag.0.10E+00    4.4     0.00041609     -3309.4371639695  5.50E-04
   291 Kerker/Diag.0.10E+00    4.6     0.00041351     -3309.4366294157  5.35E-04
   292 Kerker/Diag.0.10E+00    4.6     0.00041100     -3309.4360782774  5.51E-04
   293 Kerker/Diag.0.10E+00    4.5     0.00040843     -3309.4354874031  5.91E-04
   294 Kerker/Diag.0.10E+00    4.3     0.00040563     -3309.4348802656  6.07E-04
   295 Kerker/Diag.0.10E+00    4.4     0.00040302     -3309.4343259996  5.54E-04
   296 Kerker/Diag.0.10E+00    4.2     0.00040010     -3309.4337335428  5.92E-04
   297 Kerker/Diag.0.10E+00    4.5     0.00039742     -3309.4332001126  5.33E-04
   298 Kerker/Diag.0.10E+00    4.3     0.00039457     -3309.4326772498  5.23E-04
   299 Kerker/Diag.0.10E+00    4.5     0.00039201     -3309.4321833865  4.94E-04
   300 Kerker/Diag.0.10E+00    4.4     0.00038953     -3309.4316897323  4.94E-04

  Leaving inner SCF loop after reaching   300 steps.


  Electronic density on regular grids:       -627.9999999994        0.0000000006
  Core density on regular grids:              627.9999999998       -0.0000000002
  Total charge density on r-space grids:        0.0000000004
  Total charge density g-space grids:           0.0000000004

  Overlap energy of the core charge distribution:               0.00000000002339
  Self energy of the core charge distribution:              -6133.94225516408187
  Core Hamiltonian energy:                                   1626.87342123596818
  Hartree energy:                                            1619.80107261786566
  Exchange-correlation energy:                               -422.11487947465548
  Electronic entropic energy:                                  -0.61095953632477
  Fermi energy:                                                 0.02975260355339

  DFT+U energy:                                                 0.56191866849958

  Total energy:                                             -3309.43168973229831

  outer SCF iter =    1 RMS gradient =   0.39E-03 energy =      -3309.4316897323
     1 Kerker/Diag.0.10E+00    8.9     0.01330530     -3309.3921346418  3.96E-02
     2 Kerker/Diag.0.10E+00    4.4     0.00932285     -3309.3687365451  2.34E-02
     3 Kerker/Diag.0.10E+00    4.5     0.00241733     -3309.4488575938 -8.01E-02
     4 Kerker/Diag.0.10E+00    4.6     0.00119705     -3309.4516485073 -2.79E-03
     5 Kerker/Diag.0.10E+00    4.6     0.00085164     -3309.4412082320  1.04E-02
     6 Kerker/Diag.0.10E+00    4.4     0.00046373     -3309.4334849267  7.72E-03
     7 Kerker/Diag.0.10E+00    4.5     0.00037205     -3309.4293062492  4.18E-03
     8 Kerker/Diag.0.10E+00    4.5     0.00036677     -3309.4273420416  1.96E-03
     9 Kerker/Diag.0.10E+00    4.6     0.00035829     -3309.4263663412  9.76E-04
    10 Kerker/Diag.0.10E+00    4.7     0.00036577     -3309.4258829451  4.83E-04
    11 Kerker/Diag.0.10E+00    4.4     0.00036390     -3309.4255348726  3.48E-04
    12 Kerker/Diag.0.10E+00    4.6     0.00035986     -3309.4252526204  2.82E-04
    13 Kerker/Diag.0.10E+00    4.5     0.00035616     -3309.4249577757  2.95E-04
    14 Kerker/Diag.0.10E+00    4.4     0.00035350     -3309.4247278897  2.30E-04
    15 Kerker/Diag.0.10E+00    4.4     0.00035095     -3309.4244256005  3.02E-04
    16 Kerker/Diag.0.10E+00    4.4     0.00034857     -3309.4241284140  2.97E-04
    17 Kerker/Diag.0.10E+00    4.4     0.00034593     -3309.4237910446  3.37E-04
    18 Kerker/Diag.0.10E+00    4.4     0.00034333     -3309.4234853166  3.06E-04
    19 Kerker/Diag.0.10E+00    4.6     0.00034089     -3309.4231755583  3.10E-04
    20 Kerker/Diag.0.10E+00    4.3     0.00033839     -3309.4228453799  3.30E-04
    21 Kerker/Diag.0.10E+00    4.3     0.00033609     -3309.4225187833  3.27E-04
    22 Kerker/Diag.0.10E+00    4.4     0.00033359     -3309.4221577137  3.61E-04
    23 Kerker/Diag.0.10E+00    4.0     0.00033131     -3309.4218206386  3.37E-04
    24 Kerker/Diag.0.10E+00    4.2     0.00032888     -3309.4214414203  3.79E-04
    25 Kerker/Diag.0.10E+00    4.5     0.00032655     -3309.4210735783  3.68E-04
    26 Kerker/Diag.0.10E+00    4.4     0.00032403     -3309.4206856871  3.88E-04
    27 Kerker/Diag.0.10E+00    4.4     0.00032165     -3309.4203286855  3.57E-04
    28 Kerker/Diag.0.10E+00    4.7     0.00031941     -3309.4199643163  3.64E-04
    29 Kerker/Diag.0.10E+00    4.3     0.00031700     -3309.4195804600  3.84E-04
    30 Kerker/Diag.0.10E+00    4.3     0.00031465     -3309.4192204217  3.60E-04
    31 Kerker/Diag.0.10E+00    4.4     0.00031240     -3309.4188399852  3.80E-04
    32 Kerker/Diag.0.10E+00    4.3     0.00030992     -3309.4184412282  3.99E-04
    33 Kerker/Diag.0.10E+00    4.3     0.00030771     -3309.4180903297  3.51E-04
    34 Kerker/Diag.0.10E+00    4.2     0.00030514     -3309.4176804276  4.10E-04
    35 Kerker/Diag.0.10E+00    4.4     0.00030283     -3309.4173587118  3.22E-04
    36 Kerker/Diag.0.10E+00    4.2     0.00030059     -3309.4170054470  3.53E-04
    37 Kerker/Diag.0.10E+00    4.4     0.00029825     -3309.4166528350  3.53E-04
    38 Kerker/Diag.0.10E+00    4.5     0.00029597     -3309.4163154375  3.37E-04
    39 Kerker/Diag.0.10E+00    4.4     0.00029372     -3309.4159900218  3.25E-04
    40 Kerker/Diag.0.10E+00    4.4     0.00029157     -3309.4156523471  3.38E-04
    41 Kerker/Diag.0.10E+00    4.6     0.00028936     -3309.4153146595  3.38E-04
    42 Kerker/Diag.0.10E+00    4.3     0.00028718     -3309.4149794938  3.35E-04
    43 Kerker/Diag.0.10E+00    4.3     0.00028716     -3309.4146382325  3.41E-04
    44 Kerker/Diag.0.10E+00    4.6     0.00028744     -3309.4142818648  3.56E-04
    45 Kerker/Diag.0.10E+00    4.5     0.00028769     -3309.4139526251  3.29E-04
    46 Kerker/Diag.0.10E+00    4.4     0.00028792     -3309.4136125581  3.40E-04
    47 Kerker/Diag.0.10E+00    4.4     0.00028808     -3309.4132925228  3.20E-04
    48 Kerker/Diag.0.10E+00    4.5     0.00028822     -3309.4129825565  3.10E-04
    49 Kerker/Diag.0.10E+00    4.3     0.00028870     -3309.4126744631  3.08E-04
    50 Kerker/Diag.0.10E+00    4.4     0.00028865     -3309.4123554793  3.19E-04
    51 Kerker/Diag.0.10E+00    4.2     0.00028970     -3309.4120738538  2.82E-04
    52 Kerker/Diag.0.10E+00    4.5     0.00029128     -3309.4118020365  2.72E-04
    53 Kerker/Diag.0.10E+00    4.5     0.00029302     -3309.4115309500  2.71E-04
    54 Kerker/Diag.0.10E+00    4.3     0.00029270     -3309.4112327292  2.98E-04
    55 Kerker/Diag.0.10E+00    4.7     0.00029223     -3309.4109898117  2.43E-04
    56 Kerker/Diag.0.10E+00    4.4     0.00029384     -3309.4107279347  2.62E-04
    57 Kerker/Diag.0.10E+00    4.4     0.00029578     -3309.4104545802  2.73E-04
    58 Kerker/Diag.0.10E+00    4.1     0.00029387     -3309.4102012633  2.53E-04
    59 Kerker/Diag.0.10E+00    4.3     0.00029549     -3309.4099234120  2.78E-04
    60 Kerker/Diag.0.10E+00    4.2     0.00029674     -3309.4096536019  2.70E-04
    61 Kerker/Diag.0.10E+00    4.4     0.00029702     -3309.4093731302  2.80E-04
    62 Kerker/Diag.0.10E+00    4.6     0.00029831     -3309.4091036213  2.70E-04
    63 Kerker/Diag.0.10E+00    4.3     0.00029897     -3309.4088334453  2.70E-04
    64 Kerker/Diag.0.10E+00    4.2     0.00029854     -3309.4085783137  2.55E-04
    65 Kerker/Diag.0.10E+00    4.2     0.00030099     -3309.4083334334  2.45E-04
    66 Kerker/Diag.0.10E+00    4.2     0.00030105     -3309.4080837530  2.50E-04
    67 Kerker/Diag.0.10E+00    4.1     0.00029936     -3309.4078560036  2.28E-04
    68 Kerker/Diag.0.10E+00    4.1     0.00030097     -3309.4076285734  2.27E-04
    69 Kerker/Diag.0.10E+00    4.2     0.00030258     -3309.4074014034  2.27E-04
    70 Kerker/Diag.0.10E+00    4.2     0.00030337     -3309.4071754227  2.26E-04
    71 Kerker/Diag.0.10E+00    4.1     0.00030371     -3309.4069440454  2.31E-04
    72 Kerker/Diag.0.10E+00    4.2     0.00030414     -3309.4067120330  2.32E-04
    73 Kerker/Diag.0.10E+00    4.2     0.00030476     -3309.4064969201  2.15E-04
    74 Kerker/Diag.0.10E+00    4.1     0.00030571     -3309.4062855867  2.11E-04
    75 Kerker/Diag.0.10E+00    4.1     0.00030580     -3309.4060681053  2.17E-04
    76 Kerker/Diag.0.10E+00    4.1     0.00030610     -3309.4058491330  2.19E-04
    77 Kerker/Diag.0.10E+00    4.2     0.00030675     -3309.4056505075  1.99E-04
    78 Kerker/Diag.0.10E+00    4.1     0.00030706     -3309.4054482511  2.02E-04
    79 Kerker/Diag.0.10E+00    4.0     0.00030770     -3309.4052564224  1.92E-04
    80 Kerker/Diag.0.10E+00    4.2     0.00030884     -3309.4050496702  2.07E-04
    81 Kerker/Diag.0.10E+00    4.3     0.00030851     -3309.4048513031  1.98E-04
    82 Kerker/Diag.0.10E+00    4.4     0.00031001     -3309.4046666272  1.85E-04
    83 Kerker/Diag.0.10E+00    4.6     0.00031015     -3309.4044910683  1.76E-04
    84 Kerker/Diag.0.10E+00    4.5     0.00031187     -3309.4043077550  1.83E-04
    85 Kerker/Diag.0.10E+00    4.3     0.00031202     -3309.4041176483  1.90E-04
    86 Kerker/Diag.0.10E+00    4.2     0.00031131     -3309.4039316598  1.86E-04
    87 Kerker/Diag.0.10E+00    4.2     0.00031297     -3309.4037528183  1.79E-04
    88 Kerker/Diag.0.10E+00    4.4     0.00031228     -3309.4035636616  1.89E-04
    89 Kerker/Diag.0.10E+00    4.2     0.00031296     -3309.4033945858  1.69E-04
    90 Kerker/Diag.0.10E+00    4.4     0.00031375     -3309.4032217178  1.73E-04
    91 Kerker/Diag.0.10E+00    4.4     0.00031496     -3309.4030505611  1.71E-04
    92 Kerker/Diag.0.10E+00    4.5     0.00031591     -3309.4028805355  1.70E-04
    93 Kerker/Diag.0.10E+00    4.2     0.00031531     -3309.4027022934  1.78E-04
    94 Kerker/Diag.0.10E+00    4.2     0.00031552     -3309.4025422720  1.60E-04
    95 Kerker/Diag.0.10E+00    4.5     0.00031631     -3309.4023831528  1.59E-04
    96 Kerker/Diag.0.10E+00    4.2     0.00031612     -3309.4022204686  1.63E-04
    97 Kerker/Diag.0.10E+00    4.4     0.00031685     -3309.4020682112  1.52E-04
    98 Kerker/Diag.0.10E+00    4.3     0.00031765     -3309.4019311551  1.37E-04
    99 Kerker/Diag.0.10E+00    4.4     0.00031819     -3309.4017911959  1.40E-04
   100 Kerker/Diag.0.10E+00    4.7     0.00031808     -3309.4016521695  1.39E-04
   101 Kerker/Diag.0.10E+00    4.5     0.00031935     -3309.4015130388  1.39E-04
   102 Kerker/Diag.0.10E+00    4.5     0.00031958     -3309.4013674622  1.46E-04
   103 Kerker/Diag.0.10E+00    4.6     0.00031974     -3309.4012256954  1.42E-04
   104 Kerker/Diag.0.10E+00    4.3     0.00031969     -3309.4010830480  1.43E-04
   105 Kerker/Diag.0.10E+00    4.3     0.00032045     -3309.4009413097  1.42E-04
   106 Kerker/Diag.0.10E+00    4.2     0.00032028     -3309.4007986027  1.43E-04
   107 Kerker/Diag.0.10E+00    4.3     0.00032134     -3309.4006605133  1.38E-04
   108 Kerker/Diag.0.10E+00    4.3     0.00032154     -3309.4005232905  1.37E-04
   109 Kerker/Diag.0.10E+00    4.3     0.00032225     -3309.4003930471  1.30E-04
   110 Kerker/Diag.0.10E+00    4.3     0.00032284     -3309.4002631418  1.30E-04
   111 Kerker/Diag.0.10E+00    4.3     0.00032305     -3309.4001293510  1.34E-04
   112 Kerker/Diag.0.10E+00    4.4     0.00032316     -3309.4000033359  1.26E-04
   113 Kerker/Diag.0.10E+00    4.3     0.00032313     -3309.3998761706  1.27E-04
   114 Kerker/Diag.0.10E+00    4.2     0.00032376     -3309.3997554173  1.21E-04
   115 Kerker/Diag.0.10E+00    4.2     0.00032397     -3309.3996350540  1.20E-04
   116 Kerker/Diag.0.10E+00    4.6     0.00032472     -3309.3995151735  1.20E-04
   117 Kerker/Diag.0.10E+00    4.4     0.00032458     -3309.3993998450  1.15E-04
   118 Kerker/Diag.0.10E+00    4.4     0.00032560     -3309.3992839959  1.16E-04
   119 Kerker/Diag.0.10E+00    4.3     0.00032587     -3309.3991708006  1.13E-04
   120 Kerker/Diag.0.10E+00    4.5     0.00032592     -3309.3990607814  1.10E-04
   121 Kerker/Diag.0.10E+00    4.2     0.00032614     -3309.3989484032  1.12E-04
   122 Kerker/Diag.0.10E+00    4.5     0.00032626     -3309.3988382072  1.10E-04
   123 Kerker/Diag.0.10E+00    4.1     0.00032693     -3309.3987315944  1.07E-04
   124 Kerker/Diag.0.10E+00    4.3     0.00032673     -3309.3986260730  1.06E-04
   125 Kerker/Diag.0.10E+00    4.5     0.00032710     -3309.3985225236  1.04E-04
   126 Kerker/Diag.0.10E+00    4.4     0.00032748     -3309.3984202212  1.02E-04
   127 Kerker/Diag.0.10E+00    4.3     0.00032747     -3309.3983190093  1.01E-04
   128 Kerker/Diag.0.10E+00    4.2     0.00032786     -3309.3982212859  9.77E-05
   129 Kerker/Diag.0.10E+00    4.4     0.00032814     -3309.3981204007  1.01E-04
   130 Kerker/Diag.0.10E+00    4.5     0.00032854     -3309.3980200600  1.00E-04
   131 Kerker/Diag.0.10E+00    4.5     0.00032848     -3309.3979245629  9.55E-05
   132 Kerker/Diag.0.10E+00    4.6     0.00032892     -3309.3978337032  9.09E-05
   133 Kerker/Diag.0.10E+00    4.2     0.00032941     -3309.3977423106  9.14E-05
   134 Kerker/Diag.0.10E+00    4.3     0.00032933     -3309.3976454541  9.69E-05
   135 Kerker/Diag.0.10E+00    4.4     0.00032917     -3309.3975556613  8.98E-05
   136 Kerker/Diag.0.10E+00    4.3     0.00033012     -3309.3974658897  8.98E-05
   137 Kerker/Diag.0.10E+00    4.6     0.00033026     -3309.3973735582  9.23E-05
   138 Kerker/Diag.0.10E+00    4.1     0.00033036     -3309.3972875302  8.60E-05
   139 Kerker/Diag.0.10E+00    4.3     0.00033061     -3309.3972037516  8.38E-05
   140 Kerker/Diag.0.10E+00    4.4     0.00033087     -3309.3971213990  8.24E-05
   141 Kerker/Diag.0.10E+00    4.4     0.00033069     -3309.3970376484  8.38E-05
   142 Kerker/Diag.0.10E+00    4.2     0.00033048     -3309.3969558839  8.18E-05
   143 Kerker/Diag.0.10E+00    4.2     0.00033121     -3309.3968773733  7.85E-05
   144 Kerker/Diag.0.10E+00    4.4     0.00033117     -3309.3967951087  8.23E-05
   145 Kerker/Diag.0.10E+00    4.1     0.00033132     -3309.3967193383  7.58E-05
   146 Kerker/Diag.0.10E+00    4.3     0.00033165     -3309.3966419186  7.74E-05
   147 Kerker/Diag.0.10E+00    4.3     0.00033183     -3309.3965649412  7.70E-05
   148 Kerker/Diag.0.10E+00    4.3     0.00033163     -3309.3964862890  7.87E-05
   149 Kerker/Diag.0.10E+00    4.6     0.00033189     -3309.3964147667  7.15E-05
   150 Kerker/Diag.0.10E+00    4.3     0.00033208     -3309.3963432491  7.15E-05
   151 Kerker/Diag.0.10E+00    4.1     0.00033169     -3309.3962706403  7.26E-05
   152 Kerker/Diag.0.10E+00    4.2     0.00033218     -3309.3962015939  6.90E-05
   153 Kerker/Diag.0.10E+00    4.4     0.00033231     -3309.3961321768  6.94E-05
   154 Kerker/Diag.0.10E+00    4.3     0.00033244     -3309.3960667568  6.54E-05
   155 Kerker/Diag.0.10E+00    4.2     0.00033264     -3309.3959978691  6.89E-05
   156 Kerker/Diag.0.10E+00    4.2     0.00033292     -3309.3959292910  6.86E-05
   157 Kerker/Diag.0.10E+00    4.3     0.00033282     -3309.3958629706  6.63E-05
   158 Kerker/Diag.0.10E+00    4.2     0.00033255     -3309.3957977610  6.52E-05
   159 Kerker/Diag.0.10E+00    4.1     0.00033280     -3309.3957360281  6.17E-05
   160 Kerker/Diag.0.10E+00    4.2     0.00033316     -3309.3956738362  6.22E-05
   161 Kerker/Diag.0.10E+00    4.1     0.00033325     -3309.3956101665  6.37E-05
   162 Kerker/Diag.0.10E+00    4.3     0.00033327     -3309.3955461676  6.40E-05
   163 Kerker/Diag.0.10E+00    4.1     0.00033331     -3309.3954845291  6.16E-05
   164 Kerker/Diag.0.10E+00    4.2     0.00033353     -3309.3954258962  5.86E-05
   165 Kerker/Diag.0.10E+00    4.5     0.00033341     -3309.3953646600  6.12E-05
   166 Kerker/Diag.0.10E+00    4.7     0.00033319     -3309.3953048204  5.98E-05
   167 Kerker/Diag.0.10E+00    4.3     0.00033323     -3309.3952491849  5.56E-05
   168 Kerker/Diag.0.10E+00    4.6     0.00033325     -3309.3951933121  5.59E-05
   169 Kerker/Diag.0.10E+00    4.4     0.00033338     -3309.3951377448  5.56E-05
   170 Kerker/Diag.0.10E+00    4.3     0.00033312     -3309.3950834249  5.43E-05
   171 Kerker/Diag.0.10E+00    4.4     0.00033332     -3309.3950313673  5.21E-05
   172 Kerker/Diag.0.10E+00    4.3     0.00033330     -3309.3949807834  5.06E-05
   173 Kerker/Diag.0.10E+00    4.2     0.00033342     -3309.3949300586  5.07E-05
   174 Kerker/Diag.0.10E+00    4.2     0.00033331     -3309.3948780510  5.20E-05
   175 Kerker/Diag.0.10E+00    4.3     0.00033317     -3309.3948300643  4.80E-05
   176 Kerker/Diag.0.10E+00    4.3     0.00033338     -3309.3947803542  4.97E-05
   177 Kerker/Diag.0.10E+00    4.4     0.00033342     -3309.3947296243  5.07E-05
   178 Kerker/Diag.0.10E+00    4.4     0.00033351     -3309.3946783514  5.13E-05
   179 Kerker/Diag.0.10E+00    4.6     0.00033328     -3309.3946286434  4.97E-05
   180 Kerker/Diag.0.10E+00    4.4     0.00033348     -3309.3945806477  4.80E-05
   181 Kerker/Diag.0.10E+00    4.4     0.00033318     -3309.3945314465  4.92E-05
   182 Kerker/Diag.0.10E+00    4.2     0.00033299     -3309.3944852999  4.61E-05
   183 Kerker/Diag.0.10E+00    4.5     0.00033298     -3309.3944395425  4.58E-05
   184 Kerker/Diag.0.10E+00    4.5     0.00033309     -3309.3943954458  4.41E-05
   185 Kerker/Diag.0.10E+00    4.4     0.00033299     -3309.3943510138  4.44E-05
   186 Kerker/Diag.0.10E+00    4.4     0.00033302     -3309.3943071666  4.38E-05
   187 Kerker/Diag.0.10E+00    4.6     0.00033314     -3309.3942640702  4.31E-05
   188 Kerker/Diag.0.10E+00    4.4     0.00033303     -3309.3942207487  4.33E-05
   189 Kerker/Diag.0.10E+00    4.4     0.00033290     -3309.3941781018  4.26E-05
   190 Kerker/Diag.0.10E+00    4.2     0.00033274     -3309.3941361593  4.19E-05
   191 Kerker/Diag.0.10E+00    4.2     0.00033256     -3309.3940966325  3.95E-05
   192 Kerker/Diag.0.10E+00    4.1     0.00033237     -3309.3940566816  4.00E-05
   193 Kerker/Diag.0.10E+00    4.2     0.00033242     -3309.3940171083  3.96E-05
   194 Kerker/Diag.0.10E+00    4.5     0.00033234     -3309.3939762651  4.08E-05
   195 Kerker/Diag.0.10E+00    4.2     0.00033232     -3309.3939369696  3.93E-05
   196 Kerker/Diag.0.10E+00    4.3     0.00033222     -3309.3938981500  3.88E-05
   197 Kerker/Diag.0.10E+00    4.2     0.00033209     -3309.3938595544  3.86E-05
   198 Kerker/Diag.0.10E+00    4.3     0.00033198     -3309.3938231758  3.64E-05
   199 Kerker/Diag.0.10E+00    4.1     0.00033186     -3309.3937871484  3.60E-05
   200 Kerker/Diag.0.10E+00    4.2     0.00033157     -3309.3937508713  3.63E-05
   201 Kerker/Diag.0.10E+00    4.1     0.00033175     -3309.3937155178  3.54E-05
   202 Kerker/Diag.0.10E+00    4.5     0.00033169     -3309.3936789881  3.65E-05
   203 Kerker/Diag.0.10E+00    4.4     0.00033138     -3309.3936428662  3.61E-05
   204 Kerker/Diag.0.10E+00    4.1     0.00033123     -3309.3936090580  3.38E-05
   205 Kerker/Diag.0.10E+00    4.3     0.00033123     -3309.3935752646  3.38E-05
   206 Kerker/Diag.0.10E+00    4.2     0.00033094     -3309.3935425796  3.27E-05
   207 Kerker/Diag.0.10E+00    4.2     0.00033076     -3309.3935100318  3.25E-05
   208 Kerker/Diag.0.10E+00    4.1     0.00033077     -3309.3934779889  3.20E-05
   209 Kerker/Diag.0.10E+00    4.4     0.00033062     -3309.3934451105  3.29E-05
   210 Kerker/Diag.0.10E+00    4.3     0.00033022     -3309.3934132941  3.18E-05
   211 Kerker/Diag.0.10E+00    4.3     0.00033018     -3309.3933823481  3.09E-05
   212 Kerker/Diag.0.10E+00    4.3     0.00033005     -3309.3933511164  3.12E-05
   213 Kerker/Diag.0.10E+00    4.4     0.00032978     -3309.3933197833  3.13E-05
   214 Kerker/Diag.0.10E+00    4.3     0.00032945     -3309.3932905254  2.93E-05
   215 Kerker/Diag.0.10E+00    4.1     0.00032927     -3309.3932622707  2.83E-05
   216 Kerker/Diag.0.10E+00    4.1     0.00032916     -3309.3932337162  2.86E-05
   217 Kerker/Diag.0.10E+00    4.1     0.00032901     -3309.3932038549  2.99E-05
   218 Kerker/Diag.0.10E+00    4.3     0.00032873     -3309.3931757681  2.81E-05
   219 Kerker/Diag.0.10E+00    4.5     0.00032849     -3309.3931485504  2.72E-05
   220 Kerker/Diag.0.10E+00    4.3     0.00032836     -3309.3931208760  2.77E-05
   221 Kerker/Diag.0.10E+00    4.1     0.00032818     -3309.3930932654  2.76E-05
   222 Kerker/Diag.0.10E+00    4.5     0.00032796     -3309.3930661893  2.71E-05
   223 Kerker/Diag.0.10E+00    4.5     0.00032764     -3309.3930391399  2.70E-05
   224 Kerker/Diag.0.10E+00    4.3     0.00032759     -3309.3930132195  2.59E-05
   225 Kerker/Diag.0.10E+00    4.6     0.00032734     -3309.3929861651  2.71E-05
   226 Kerker/Diag.0.10E+00    4.3     0.00032710     -3309.3929602307  2.59E-05
   227 Kerker/Diag.0.10E+00    4.5     0.00032677     -3309.3929349657  2.53E-05
   228 Kerker/Diag.0.10E+00    4.4     0.00032656     -3309.3929106348  2.43E-05
   229 Kerker/Diag.0.10E+00    4.4     0.00032628     -3309.3928856347  2.50E-05
   230 Kerker/Diag.0.10E+00    4.6     0.00032603     -3309.3928611451  2.45E-05
   231 Kerker/Diag.0.10E+00    4.4     0.00032585     -3309.3928380937  2.31E-05
   232 Kerker/Diag.0.10E+00    4.3     0.00032570     -3309.3928136930  2.44E-05
   233 Kerker/Diag.0.10E+00    4.3     0.00032529     -3309.3927897567  2.39E-05
   234 Kerker/Diag.0.10E+00    4.4     0.00032500     -3309.3927669250  2.28E-05
   235 Kerker/Diag.0.10E+00    4.4     0.00032468     -3309.3927438598  2.31E-05
   236 Kerker/Diag.0.10E+00    4.5     0.00032445     -3309.3927216584  2.22E-05
   237 Kerker/Diag.0.10E+00    4.3     0.00032416     -3309.3926995650  2.21E-05
   238 Kerker/Diag.0.10E+00    4.5     0.00032393     -3309.3926775157  2.20E-05
   239 Kerker/Diag.0.10E+00    4.4     0.00032371     -3309.3926553481  2.22E-05
   240 Kerker/Diag.0.10E+00    4.5     0.00032350     -3309.3926335295  2.18E-05
   241 Kerker/Diag.0.10E+00    4.5     0.00032315     -3309.3926121845  2.13E-05
   242 Kerker/Diag.0.10E+00    4.4     0.00032286     -3309.3925913183  2.09E-05
   243 Kerker/Diag.0.10E+00    4.2     0.00032250     -3309.3925711720  2.01E-05
   244 Kerker/Diag.0.10E+00    4.2     0.00032221     -3309.3925506869  2.05E-05
   245 Kerker/Diag.0.10E+00    4.5     0.00032184     -3309.3925296064  2.11E-05
   246 Kerker/Diag.0.10E+00    4.5     0.00032173     -3309.3925098990  1.97E-05
   247 Kerker/Diag.0.10E+00    4.5     0.00032177     -3309.3924897637  2.01E-05
   248 Kerker/Diag.0.10E+00    4.6     0.00032190     -3309.3924693745  2.04E-05
   249 Kerker/Diag.0.10E+00    4.5     0.00032206     -3309.3924497551  1.96E-05
   250 Kerker/Diag.0.10E+00    4.3     0.00032217     -3309.3924304625  1.93E-05
   251 Kerker/Diag.0.10E+00    4.6     0.00032219     -3309.3924107402  1.97E-05
   252 Kerker/Diag.0.10E+00    4.6     0.00032221     -3309.3923914124  1.93E-05
   253 Kerker/Diag.0.10E+00    4.3     0.00032234     -3309.3923735563  1.79E-05
   254 Kerker/Diag.0.10E+00    4.6     0.00032244     -3309.3923549831  1.86E-05
   255 Kerker/Diag.0.10E+00    4.5     0.00032253     -3309.3923365302  1.85E-05
   256 Kerker/Diag.0.10E+00    4.5     0.00032256     -3309.3923182884  1.82E-05
   257 Kerker/Diag.0.10E+00    4.4     0.00032260     -3309.3923010559  1.72E-05
   258 Kerker/Diag.0.10E+00    4.3     0.00032260     -3309.3922830611  1.80E-05
   259 Kerker/Diag.0.10E+00    4.4     0.00032255     -3309.3922652405  1.78E-05
   260 Kerker/Diag.0.10E+00    4.3     0.00032265     -3309.3922486141  1.66E-05
   261 Kerker/Diag.0.10E+00    4.4     0.00032277     -3309.3922311454  1.75E-05
   262 Kerker/Diag.0.10E+00    4.4     0.00032272     -3309.3922140384  1.71E-05
   263 Kerker/Diag.0.10E+00    4.3     0.00032272     -3309.3921974361  1.66E-05
   264 Kerker/Diag.0.10E+00    4.4     0.00032280     -3309.3921812651  1.62E-05
   265 Kerker/Diag.0.10E+00    4.6     0.00032289     -3309.3921647681  1.65E-05
   266 Kerker/Diag.0.10E+00    4.6     0.00032279     -3309.3921486974  1.61E-05
   267 Kerker/Diag.0.10E+00    4.3     0.00032285     -3309.3921322393  1.65E-05
   268 Kerker/Diag.0.10E+00    4.5     0.00032288     -3309.3921157510  1.65E-05
   269 Kerker/Diag.0.10E+00    4.4     0.00032283     -3309.3920999489  1.58E-05
   270 Kerker/Diag.0.10E+00    4.2     0.00032283     -3309.3920843880  1.56E-05
   271 Kerker/Diag.0.10E+00    4.5     0.00032282     -3309.3920689445  1.54E-05
   272 Kerker/Diag.0.10E+00    4.5     0.00032279     -3309.3920538711  1.51E-05
   273 Kerker/Diag.0.10E+00    4.4     0.00032276     -3309.3920392082  1.47E-05
   274 Kerker/Diag.0.10E+00    4.4     0.00032274     -3309.3920245976  1.46E-05
   275 Kerker/Diag.0.10E+00    4.7     0.00032268     -3309.3920100263  1.46E-05
   276 Kerker/Diag.0.10E+00    4.5     0.00032274     -3309.3919954533  1.46E-05
   277 Kerker/Diag.0.10E+00    4.4     0.00032261     -3309.3919808965  1.46E-05
   278 Kerker/Diag.0.10E+00    4.3     0.00032261     -3309.3919674736  1.34E-05
   279 Kerker/Diag.0.10E+00    4.3     0.00032258     -3309.3919532352  1.42E-05
   280 Kerker/Diag.0.10E+00    4.6     0.00032258     -3309.3919390307  1.42E-05
   281 Kerker/Diag.0.10E+00    4.5     0.00032251     -3309.3919250506  1.40E-05
   282 Kerker/Diag.0.10E+00    4.7     0.00032248     -3309.3919107424  1.43E-05
   283 Kerker/Diag.0.10E+00    4.5     0.00032238     -3309.3918963599  1.44E-05
   284 Kerker/Diag.0.10E+00    4.6     0.00032236     -3309.3918826167  1.37E-05
   285 Kerker/Diag.0.10E+00    4.7     0.00032231     -3309.3918691831  1.34E-05
   286 Kerker/Diag.0.10E+00    4.5     0.00032213     -3309.3918555646  1.36E-05
   287 Kerker/Diag.0.10E+00    4.7     0.00032213     -3309.3918423134  1.33E-05
   288 Kerker/Diag.0.10E+00    4.5     0.00032208     -3309.3918287166  1.36E-05
   289 Kerker/Diag.0.10E+00    4.6     0.00032201     -3309.3918151507  1.36E-05
   290 Kerker/Diag.0.10E+00    4.6     0.00032193     -3309.3918015206  1.36E-05
   291 Kerker/Diag.0.10E+00    4.6     0.00032183     -3309.3917882355  1.33E-05
   292 Kerker/Diag.0.10E+00    4.6     0.00032173     -3309.3917750934  1.31E-05
   293 Kerker/Diag.0.10E+00    4.7     0.00032163     -3309.3917620222  1.31E-05
   294 Kerker/Diag.0.10E+00    4.4     0.00032156     -3309.3917487892  1.32E-05
   295 Kerker/Diag.0.10E+00    4.4     0.00032149     -3309.3917355815  1.32E-05
   296 Kerker/Diag.0.10E+00    4.5     0.00032135     -3309.3917222758  1.33E-05
   297 Kerker/Diag.0.10E+00    4.4     0.00032126     -3309.3917094041  1.29E-05
   298 Kerker/Diag.0.10E+00    4.7     0.00032115     -3309.3916967280  1.27E-05
   299 Kerker/Diag.0.10E+00    4.4     0.00032100     -3309.3916840175  1.27E-05
   300 Kerker/Diag.0.10E+00    4.5     0.00032091     -3309.3916713665  1.27E-05

  Leaving inner SCF loop after reaching   300 steps.


  Electronic density on regular grids:       -627.9999999995        0.0000000005
  Core density on regular grids:              627.9999999998       -0.0000000002
  Total charge density on r-space grids:        0.0000000003
  Total charge density g-space grids:           0.0000000003

  Overlap energy of the core charge distribution:               0.00000000002339
  Self energy of the core charge distribution:              -6133.94225516408187
  Core Hamiltonian energy:                                   1626.88462183508818
  Hartree energy:                                            1619.81026911963136
  Exchange-correlation energy:                               -422.09834909825730
  Electronic entropic energy:                                  -0.60621248081268
  Fermi energy:                                                 0.02885709999468

  DFT+U energy:                                                 0.56027655300902

  Total energy:                                             -3309.39167136653623

  outer SCF iter =    2 RMS gradient =   0.32E-03 energy =      -3309.3916713665
     1 Kerker/Diag.0.10E+00    8.7     0.01779568     -3309.3941826073 -2.51E-03
     2 Kerker/Diag.0.10E+00    4.4     0.01333738     -3309.3911250028  3.06E-03
     3 Kerker/Diag.0.10E+00    4.6     0.00271897     -3309.3922370549 -1.11E-03
     4 Kerker/Diag.0.10E+00    4.5     0.00043207     -3309.3902042103  2.03E-03
     5 Kerker/Diag.0.10E+00    4.3     0.00016390     -3309.3899688706  2.35E-04
     6 Kerker/Diag.0.10E+00    4.9     0.00027598     -3309.3904034890 -4.35E-04
     7 Kerker/Diag.0.10E+00    4.8     0.00030241     -3309.3908338993 -4.30E-04
     8 Kerker/Diag.0.10E+00    4.4     0.00030991     -3309.3911184632 -2.85E-04
     9 Kerker/Diag.0.10E+00    4.4     0.00031262     -3309.3912800543 -1.62E-04
    10 Kerker/Diag.0.10E+00    4.4     0.00031382     -3309.3913670352 -8.70E-05
    11 Kerker/Diag.0.10E+00    4.5     0.00031448     -3309.3914139463 -4.69E-05
    12 Kerker/Diag.0.10E+00    4.7     0.00031488     -3309.3914392316 -2.53E-05
    13 Kerker/Diag.0.10E+00    4.4     0.00031518     -3309.3914532751 -1.40E-05
    14 Kerker/Diag.0.10E+00    4.5     0.00031536     -3309.3914602575 -6.98E-06
    15 Kerker/Diag.0.10E+00    4.4     0.00031540     -3309.3914630783 -2.82E-06
    16 Kerker/Diag.0.10E+00    4.8     0.00031545     -3309.3914626177  4.61E-07
    17 Kerker/Diag.0.10E+00    4.7     0.00031544     -3309.3914601549  2.46E-06
    18 Kerker/Diag.0.10E+00    4.5     0.00031540     -3309.3914556735  4.48E-06
    19 Kerker/Diag.0.10E+00    4.4     0.00031539     -3309.3914501068  5.57E-06
    20 Kerker/Diag.0.10E+00    4.5     0.00031532     -3309.3914435332  6.57E-06
    21 Kerker/Diag.0.10E+00    4.5     0.00031524     -3309.3914361754  7.36E-06
    22 Kerker/Diag.0.10E+00    4.4     0.00031515     -3309.3914280904  8.08E-06
    23 Kerker/Diag.0.10E+00    4.4     0.00031509     -3309.3914191589  8.93E-06
    24 Kerker/Diag.0.10E+00    4.3     0.00031498     -3309.3914091864  9.97E-06
    25 Kerker/Diag.0.10E+00    4.5     0.00031488     -3309.3913991238  1.01E-05
    26 Kerker/Diag.0.10E+00    4.3     0.00031474     -3309.3913886184  1.05E-05
    27 Kerker/Diag.0.10E+00    4.3     0.00031464     -3309.3913775169  1.11E-05
    28 Kerker/Diag.0.10E+00    4.0     0.00031451     -3309.3913662525  1.13E-05
    29 Kerker/Diag.0.10E+00    4.1     0.00031437     -3309.3913544225  1.18E-05
    30 Kerker/Diag.0.10E+00    4.3     0.00031419     -3309.3913422613  1.22E-05
    31 Kerker/Diag.0.10E+00    4.3     0.00031404     -3309.3913304310  1.18E-05
    32 Kerker/Diag.0.10E+00    4.2     0.00031385     -3309.3913183859  1.20E-05
    33 Kerker/Diag.0.10E+00    4.3     0.00031368     -3309.3913059939  1.24E-05
    34 Kerker/Diag.0.10E+00    4.2     0.00031345     -3309.3912932774  1.27E-05
    35 Kerker/Diag.0.10E+00    4.5     0.00031328     -3309.3912808447  1.24E-05
    36 Kerker/Diag.0.10E+00    4.2     0.00031310     -3309.3912682050  1.26E-05
    37 Kerker/Diag.0.10E+00    4.3     0.00031287     -3309.3912551458  1.31E-05
    38 Kerker/Diag.0.10E+00    4.2     0.00031272     -3309.3912420463  1.31E-05
    39 Kerker/Diag.0.10E+00    4.4     0.00031248     -3309.3912287402  1.33E-05
    40 Kerker/Diag.0.10E+00    4.2     0.00031222     -3309.3912157067  1.30E-05
    41 Kerker/Diag.0.10E+00    4.3     0.00031201     -3309.3912027086  1.30E-05
    42 Kerker/Diag.0.10E+00    4.3     0.00031177     -3309.3911898903  1.28E-05
    43 Kerker/Diag.0.10E+00    4.5     0.00031153     -3309.3911767726  1.31E-05
    44 Kerker/Diag.0.10E+00    4.5     0.00031131     -3309.3911638122  1.30E-05
    45 Kerker/Diag.0.10E+00    4.4     0.00031109     -3309.3911508514  1.30E-05
    46 Kerker/Diag.0.10E+00    4.4     0.00031083     -3309.3911375484  1.33E-05
    47 Kerker/Diag.0.10E+00    4.4     0.00031058     -3309.3911241951  1.34E-05
    48 Kerker/Diag.0.10E+00    4.5     0.00031034     -3309.3911111389  1.31E-05
    49 Kerker/Diag.0.10E+00    4.6     0.00031006     -3309.3910978526  1.33E-05
    50 Kerker/Diag.0.10E+00    4.5     0.00030980     -3309.3910845670  1.33E-05
    51 Kerker/Diag.0.10E+00    4.4     0.00031122     -3309.3910714275  1.31E-05
    52 Kerker/Diag.0.10E+00    4.3     0.00031283     -3309.3910584199  1.30E-05
    53 Kerker/Diag.0.10E+00    4.4     0.00031445     -3309.3910457391  1.27E-05
    54 Kerker/Diag.0.10E+00    4.6     0.00031611     -3309.3910329996  1.27E-05
    55 Kerker/Diag.0.10E+00    4.4     0.00031782     -3309.3910201828  1.28E-05
    56 Kerker/Diag.0.10E+00    4.2     0.00031952     -3309.3910072096  1.30E-05
    57 Kerker/Diag.0.10E+00    4.3     0.00032124     -3309.3909943098  1.29E-05
    58 Kerker/Diag.0.10E+00    4.2     0.00032299     -3309.3909820106  1.23E-05
    59 Kerker/Diag.0.10E+00    4.4     0.00032475     -3309.3909695900  1.24E-05
    60 Kerker/Diag.0.10E+00    4.4     0.00032647     -3309.3909569856  1.26E-05
    61 Kerker/Diag.0.10E+00    4.3     0.00032822     -3309.3909447089  1.23E-05
    62 Kerker/Diag.0.10E+00    4.2     0.00032998     -3309.3909322048  1.25E-05
    63 Kerker/Diag.0.10E+00    4.3     0.00033178     -3309.3909195043  1.27E-05
    64 Kerker/Diag.0.10E+00    4.1     0.00033355     -3309.3909071120  1.24E-05
    65 Kerker/Diag.0.10E+00    4.3     0.00033532     -3309.3908947744  1.23E-05
    66 Kerker/Diag.0.10E+00    4.3     0.00033716     -3309.3908824662  1.23E-05
    67 Kerker/Diag.0.10E+00    4.4     0.00033896     -3309.3908702849  1.22E-05
    68 Kerker/Diag.0.10E+00    4.4     0.00034080     -3309.3908580600  1.22E-05
    69 Kerker/Diag.0.10E+00    4.2     0.00034262     -3309.3908463362  1.17E-05
    70 Kerker/Diag.0.10E+00    4.4     0.00034448     -3309.3908348525  1.15E-05
    71 Kerker/Diag.0.10E+00    4.4     0.00034635     -3309.3908231900  1.17E-05
    72 Kerker/Diag.0.10E+00    4.3     0.00034824     -3309.3908117483  1.14E-05
    73 Kerker/Diag.0.10E+00    4.5     0.00035006     -3309.3908002046  1.15E-05
    74 Kerker/Diag.0.10E+00    4.3     0.00035195     -3309.3907885789  1.16E-05
    75 Kerker/Diag.0.10E+00    4.1     0.00035380     -3309.3907770914  1.15E-05
    76 Kerker/Diag.0.10E+00    4.1     0.00035568     -3309.3907656522  1.14E-05
    77 Kerker/Diag.0.10E+00    4.3     0.00035759     -3309.3907542060  1.14E-05
    78 Kerker/Diag.0.10E+00    4.2     0.00035950     -3309.3907427758  1.14E-05
    79 Kerker/Diag.0.10E+00    4.1     0.00036142     -3309.3907316190  1.12E-05
    80 Kerker/Diag.0.10E+00    4.1     0.00036335     -3309.3907204652  1.12E-05
    81 Kerker/Diag.0.10E+00    4.1     0.00036528     -3309.3907092010  1.13E-05
    82 Kerker/Diag.0.10E+00    4.2     0.00036724     -3309.3906982089  1.10E-05
    83 Kerker/Diag.0.10E+00    4.2     0.00036919     -3309.3906870899  1.11E-05
    84 Kerker/Diag.0.10E+00    4.0     0.00037115     -3309.3906760793  1.10E-05
    85 Kerker/Diag.0.10E+00    4.4     0.00037314     -3309.3906649774  1.11E-05
    86 Kerker/Diag.0.10E+00    4.2     0.00037509     -3309.3906543319  1.06E-05
    87 Kerker/Diag.0.10E+00    4.3     0.00037708     -3309.3906436380  1.07E-05
    88 Kerker/Diag.0.10E+00    4.4     0.00037909     -3309.3906330057  1.06E-05
    89 Kerker/Diag.0.10E+00    4.2     0.00038109     -3309.3906223335  1.07E-05
    90 Kerker/Diag.0.10E+00    4.3     0.00038309     -3309.3906117367  1.06E-05
    91 Kerker/Diag.0.10E+00    4.2     0.00038511     -3309.3906010561  1.07E-05
    92 Kerker/Diag.0.10E+00    4.3     0.00038713     -3309.3905904372  1.06E-05
    93 Kerker/Diag.0.10E+00    4.2     0.00038917     -3309.3905797554  1.07E-05
    94 Kerker/Diag.0.10E+00    4.2     0.00039119     -3309.3905692604  1.05E-05
    95 Kerker/Diag.0.10E+00    4.4     0.00039327     -3309.3905586573  1.06E-05
    96 Kerker/Diag.0.10E+00    4.4     0.00039534     -3309.3905481273  1.05E-05
    97 Kerker/Diag.0.10E+00    4.4     0.00039742     -3309.3905376880  1.04E-05
    98 Kerker/Diag.0.10E+00    4.5     0.00039952     -3309.3905275947  1.01E-05
    99 Kerker/Diag.0.10E+00    4.3     0.00040159     -3309.3905175572  1.00E-05
   100 Kerker/Diag.0.10E+00    4.5     0.00040368     -3309.3905074715  1.01E-05
   101 Kerker/Diag.0.10E+00    4.3     0.00040577     -3309.3904972114  1.03E-05
   102 Kerker/Diag.0.10E+00    4.5     0.00040788     -3309.3904870337  1.02E-05
   103 Kerker/Diag.0.10E+00    4.5     0.00041003     -3309.3904768393  1.02E-05
   104 Kerker/Diag.0.10E+00    4.5     0.00041216     -3309.3904668978  9.94E-06
   105 Kerker/Diag.0.10E+00    4.5     0.00041428     -3309.3904570924  9.81E-06
   106 Kerker/Diag.0.10E+00    4.6     0.00041641     -3309.3904470818  1.00E-05
   107 Kerker/Diag.0.10E+00    4.5     0.00041857     -3309.3904371824  9.90E-06
   108 Kerker/Diag.0.10E+00    4.5     0.00042073     -3309.3904272492  9.93E-06
   109 Kerker/Diag.0.10E+00    4.5     0.00042291     -3309.3904174388  9.81E-06
   110 Kerker/Diag.0.10E+00    4.6     0.00042511     -3309.3904075313  9.91E-06
   111 Kerker/Diag.0.10E+00    4.6     0.00042728     -3309.3903977140  9.82E-06
   112 Kerker/Diag.0.10E+00    4.6     0.00042947     -3309.3903879438  9.77E-06
   113 Kerker/Diag.0.10E+00    4.6     0.00043168     -3309.3903783230  9.62E-06
   114 Kerker/Diag.0.10E+00    4.6     0.00043389     -3309.3903689134  9.41E-06
   115 Kerker/Diag.0.10E+00    4.6     0.00043611     -3309.3903589677  9.95E-06
   116 Kerker/Diag.0.10E+00    4.4     0.00043830     -3309.3903491923  9.78E-06
   117 Kerker/Diag.0.10E+00    4.6     0.00044052     -3309.3903394393  9.75E-06
   118 Kerker/Diag.0.10E+00    4.3     0.00044276     -3309.3903298172  9.62E-06
   119 Kerker/Diag.0.10E+00    4.6     0.00044501     -3309.3903201337  9.68E-06
   120 Kerker/Diag.0.10E+00    4.5     0.00044728     -3309.3903104165  9.72E-06
   121 Kerker/Diag.0.10E+00    4.5     0.00044955     -3309.3903007200  9.70E-06
   122 Kerker/Diag.0.10E+00    4.6     0.00045180     -3309.3902911503  9.57E-06
   123 Kerker/Diag.0.10E+00    4.5     0.00045408     -3309.3902816724  9.48E-06
   124 Kerker/Diag.0.10E+00    4.4     0.00045636     -3309.3902719958  9.68E-06
   125 Kerker/Diag.0.10E+00    4.5     0.00045865     -3309.3902624129  9.58E-06
   126 Kerker/Diag.0.10E+00    4.6     0.00046095     -3309.3902525749  9.84E-06
   127 Kerker/Diag.0.10E+00    4.6     0.00046323     -3309.3902428216  9.75E-06
   128 Kerker/Diag.0.10E+00    4.6     0.00046556     -3309.3902330942  9.73E-06
   129 Kerker/Diag.0.10E+00    4.4     0.00046784     -3309.3902232251  9.87E-06
   130 Kerker/Diag.0.10E+00    4.5     0.00047016     -3309.3902137110  9.51E-06
   131 Kerker/Diag.0.10E+00    4.5     0.00047246     -3309.3902038199  9.89E-06
   132 Kerker/Diag.0.10E+00    4.6     0.00047481     -3309.3901937823  1.00E-05
   133 Kerker/Diag.0.10E+00    4.6     0.00047713     -3309.3901833563  1.04E-05
   134 Kerker/Diag.0.10E+00    4.4     0.00047945     -3309.3901731015  1.03E-05
   135 Kerker/Diag.0.10E+00    4.5     0.00048181     -3309.3901627560  1.03E-05
   136 Kerker/Diag.0.10E+00    4.6     0.00048416     -3309.3901526139  1.01E-05
   137 Kerker/Diag.0.10E+00    4.5     0.00048652     -3309.3901424947  1.01E-05
   138 Kerker/Diag.0.10E+00    4.6     0.00048888     -3309.3901323846  1.01E-05
   139 Kerker/Diag.0.10E+00    4.4     0.00049125     -3309.3901219791  1.04E-05
   140 Kerker/Diag.0.10E+00    4.6     0.00049359     -3309.3901116405  1.03E-05
   141 Kerker/Diag.0.10E+00    4.4     0.00049597     -3309.3901011407  1.05E-05
   142 Kerker/Diag.0.10E+00    4.6     0.00049837     -3309.3900908778  1.03E-05
   143 Kerker/Diag.0.10E+00    4.6     0.00050075     -3309.3900807462  1.01E-05
   144 Kerker/Diag.0.10E+00    4.5     0.00050313     -3309.3900705118  1.02E-05
   145 Kerker/Diag.0.10E+00    4.6     0.00050552     -3309.3900602517  1.03E-05
   146 Kerker/Diag.0.10E+00    4.5     0.00050791     -3309.3900496351  1.06E-05
   147 Kerker/Diag.0.10E+00    5.1     0.00051032     -3309.3900391432  1.05E-05
   148 Kerker/Diag.0.10E+00    4.5     0.00051275     -3309.3900289562  1.02E-05
   149 Kerker/Diag.0.10E+00    4.5     0.00051516     -3309.3900184972  1.05E-05
   150 Kerker/Diag.0.10E+00    4.3     0.00051756     -3309.3900077049  1.08E-05
   151 Kerker/Diag.0.10E+00    4.6     0.00052000     -3309.3899969419  1.08E-05
   152 Kerker/Diag.0.10E+00    4.3     0.00052243     -3309.3899862254  1.07E-05
   153 Kerker/Diag.0.10E+00    4.4     0.00052484     -3309.3899760022  1.02E-05
   154 Kerker/Diag.0.10E+00    4.2     0.00052728     -3309.3899656188  1.04E-05
   155 Kerker/Diag.0.10E+00    4.5     0.00052970     -3309.3899553212  1.03E-05
   156 Kerker/Diag.0.10E+00    4.4     0.00053215     -3309.3899449977  1.03E-05
   157 Kerker/Diag.0.10E+00    4.3     0.00053459     -3309.3899346715  1.03E-05
   158 Kerker/Diag.0.10E+00    4.2     0.00053702     -3309.3899243529  1.03E-05
   159 Kerker/Diag.0.10E+00    4.4     0.00053946     -3309.3899137014  1.07E-05
   160 Kerker/Diag.0.10E+00    4.3     0.00054191     -3309.3899029138  1.08E-05
   161 Kerker/Diag.0.10E+00    4.5     0.00054434     -3309.3898919884  1.09E-05
   162 Kerker/Diag.0.10E+00    4.5     0.00054680     -3309.3898808142  1.12E-05
   163 Kerker/Diag.0.10E+00    4.1     0.00054927     -3309.3898693461  1.15E-05
   164 Kerker/Diag.0.10E+00    4.1     0.00055169     -3309.3898581728  1.12E-05
   165 Kerker/Diag.0.10E+00    4.3     0.00055417     -3309.3898470874  1.11E-05
   166 Kerker/Diag.0.10E+00    4.2     0.00055663     -3309.3898356708  1.14E-05
   167 Kerker/Diag.0.10E+00    4.1     0.00055908     -3309.3898242102  1.15E-05
   168 Kerker/Diag.0.10E+00    4.5     0.00056155     -3309.3898126531  1.16E-05
   169 Kerker/Diag.0.10E+00    4.1     0.00056399     -3309.3898011356  1.15E-05
   170 Kerker/Diag.0.10E+00    4.3     0.00056644     -3309.3897893672  1.18E-05
   171 Kerker/Diag.0.10E+00    4.3     0.00056889     -3309.3897774766  1.19E-05
   172 Kerker/Diag.0.10E+00    4.6     0.00057132     -3309.3897654812  1.20E-05
   173 Kerker/Diag.0.10E+00    4.5     0.00057377     -3309.3897533487  1.21E-05
   174 Kerker/Diag.0.10E+00    4.5     0.00057624     -3309.3897411379  1.22E-05
   175 Kerker/Diag.0.10E+00    4.3     0.00057870     -3309.3897292430  1.19E-05
   176 Kerker/Diag.0.10E+00    4.8     0.00058115     -3309.3897172058  1.20E-05
   177 Kerker/Diag.0.10E+00    4.6     0.00058362     -3309.3897045155  1.27E-05
   178 Kerker/Diag.0.10E+00    4.3     0.00058606     -3309.3896921292  1.24E-05
   179 Kerker/Diag.0.10E+00    4.7     0.00058852     -3309.3896795824  1.25E-05
   180 Kerker/Diag.0.10E+00    4.3     0.00059097     -3309.3896668891  1.27E-05
   181 Kerker/Diag.0.10E+00    4.4     0.00059338     -3309.3896540863  1.28E-05
   182 Kerker/Diag.0.10E+00    4.6     0.00059581     -3309.3896409260  1.32E-05
   183 Kerker/Diag.0.10E+00    4.4     0.00059824     -3309.3896273777  1.35E-05
   184 Kerker/Diag.0.10E+00    4.6     0.00060066     -3309.3896136793  1.37E-05
   185 Kerker/Diag.0.10E+00    4.5     0.00060309     -3309.3896000415  1.36E-05
   186 Kerker/Diag.0.10E+00    4.6     0.00060555     -3309.3895864023  1.36E-05
   187 Kerker/Diag.0.10E+00    4.2     0.00060798     -3309.3895726977  1.37E-05
   188 Kerker/Diag.0.10E+00    4.3     0.00061039     -3309.3895592219  1.35E-05
   189 Kerker/Diag.0.10E+00    4.4     0.00061280     -3309.3895456767  1.35E-05
   190 Kerker/Diag.0.10E+00    4.3     0.00061519     -3309.3895319107  1.38E-05
   191 Kerker/Diag.0.10E+00    4.2     0.00061758     -3309.3895182602  1.37E-05
   192 Kerker/Diag.0.10E+00    4.2     0.00061998     -3309.3895048512  1.34E-05
   193 Kerker/Diag.0.10E+00    4.4     0.00062237     -3309.3894914060  1.34E-05
   194 Kerker/Diag.0.10E+00    4.6     0.00062479     -3309.3894778989  1.35E-05
   195 Kerker/Diag.0.10E+00    4.4     0.00062717     -3309.3894643350  1.36E-05
   196 Kerker/Diag.0.10E+00    4.1     0.00062952     -3309.3894507169  1.36E-05
   197 Kerker/Diag.0.10E+00    4.2     0.00063188     -3309.3894366733  1.40E-05
   198 Kerker/Diag.0.10E+00    4.3     0.00063426     -3309.3894225009  1.42E-05
   199 Kerker/Diag.0.10E+00    4.6     0.00063664     -3309.3894083703  1.41E-05
   200 Kerker/Diag.0.10E+00    4.3     0.00063898     -3309.3893947263  1.36E-05
   201 Kerker/Diag.0.10E+00    4.3     0.00064130     -3309.3893806935  1.40E-05
   202 Kerker/Diag.0.10E+00    4.3     0.00064363     -3309.3893670892  1.36E-05
   203 Kerker/Diag.0.10E+00    4.6     0.00064594     -3309.3893535288  1.36E-05
   204 Kerker/Diag.0.10E+00    4.5     0.00064826     -3309.3893398787  1.37E-05
   205 Kerker/Diag.0.10E+00    4.3     0.00065056     -3309.3893262557  1.36E-05
   206 Kerker/Diag.0.10E+00    4.3     0.00065287     -3309.3893128063  1.34E-05
   207 Kerker/Diag.0.10E+00    4.3     0.00065514     -3309.3892992365  1.36E-05
   208 Kerker/Diag.0.10E+00    4.3     0.00065742     -3309.3892858054  1.34E-05
   209 Kerker/Diag.0.10E+00    4.3     0.00065967     -3309.3892727981  1.30E-05
   210 Kerker/Diag.0.10E+00    4.5     0.00066194     -3309.3892597238  1.31E-05
   211 Kerker/Diag.0.10E+00    4.3     0.00066420     -3309.3892470696  1.27E-05
   212 Kerker/Diag.0.10E+00    4.5     0.00066641     -3309.3892344875  1.26E-05
   213 Kerker/Diag.0.10E+00    4.2     0.00066864     -3309.3892217988  1.27E-05
   214 Kerker/Diag.0.10E+00    4.4     0.00067085     -3309.3892092499  1.25E-05
   215 Kerker/Diag.0.10E+00    4.2     0.00067305     -3309.3891967734  1.25E-05
   216 Kerker/Diag.0.10E+00    4.4     0.00067522     -3309.3891845489  1.22E-05
   217 Kerker/Diag.0.10E+00    4.4     0.00067737     -3309.3891724229  1.21E-05
   218 Kerker/Diag.0.10E+00    4.3     0.00067951     -3309.3891607184  1.17E-05
   219 Kerker/Diag.0.10E+00    4.4     0.00068164     -3309.3891493479  1.14E-05
   220 Kerker/Diag.0.10E+00    4.5     0.00068377     -3309.3891383330  1.10E-05
   221 Kerker/Diag.0.10E+00    4.2     0.00068586     -3309.3891275342  1.08E-05
   222 Kerker/Diag.0.10E+00    4.3     0.00068797     -3309.3891163190  1.12E-05
   223 Kerker/Diag.0.10E+00    4.2     0.00069007     -3309.3891058390  1.05E-05
   224 Kerker/Diag.0.10E+00    4.5     0.00069213     -3309.3890956200  1.02E-05
   225 Kerker/Diag.0.10E+00    4.5     0.00069415     -3309.3890857043  9.92E-06
   226 Kerker/Diag.0.10E+00    4.4     0.00069619     -3309.3890759390  9.77E-06
   227 Kerker/Diag.0.10E+00    4.3     0.00069820     -3309.3890660628  9.88E-06
   228 Kerker/Diag.0.10E+00    4.4     0.00070017     -3309.3890564764  9.59E-06
   229 Kerker/Diag.0.10E+00    4.4     0.00070214     -3309.3890470762  9.40E-06
   230 Kerker/Diag.0.10E+00    4.4     0.00070410     -3309.3890375903  9.49E-06
   231 Kerker/Diag.0.10E+00    4.3     0.00070604     -3309.3890285717  9.02E-06
   232 Kerker/Diag.0.10E+00    4.4     0.00070797     -3309.3890187362  9.84E-06
   233 Kerker/Diag.0.10E+00    4.2     0.00070989     -3309.3890101759  8.56E-06
   234 Kerker/Diag.0.10E+00    4.6     0.00071177     -3309.3890016969  8.48E-06
   235 Kerker/Diag.0.10E+00    4.3     0.00071362     -3309.3889934289  8.27E-06
   236 Kerker/Diag.0.10E+00    4.4     0.00071546     -3309.3889851333  8.30E-06
   237 Kerker/Diag.0.10E+00    4.3     0.00071729     -3309.3889771655  7.97E-06
   238 Kerker/Diag.0.10E+00    4.2     0.00071907     -3309.3889692704  7.90E-06
   239 Kerker/Diag.0.10E+00    4.4     0.00072085     -3309.3889612505  8.02E-06
   240 Kerker/Diag.0.10E+00    4.1     0.00072262     -3309.3889537080  7.54E-06
   241 Kerker/Diag.0.10E+00    4.4     0.00072434     -3309.3889458914  7.82E-06
   242 Kerker/Diag.0.10E+00    4.3     0.00072606     -3309.3889385868  7.30E-06
   243 Kerker/Diag.0.10E+00    4.2     0.00072774     -3309.3889317353  6.85E-06
   244 Kerker/Diag.0.10E+00    4.3     0.00072941     -3309.3889249614  6.77E-06
   245 Kerker/Diag.0.10E+00    4.1     0.00073105     -3309.3889181195  6.84E-06
   246 Kerker/Diag.0.10E+00    4.2     0.00073266     -3309.3889109797  7.14E-06
   247 Kerker/Diag.0.10E+00    4.2     0.00073425     -3309.3889039532  7.03E-06
   248 Kerker/Diag.0.10E+00    4.4     0.00073583     -3309.3888973871  6.57E-06
   249 Kerker/Diag.0.10E+00    4.5     0.00073736     -3309.3888904332  6.95E-06
   250 Kerker/Diag.0.10E+00    4.2     0.00073888     -3309.3888838771  6.56E-06
   251 Kerker/Diag.0.10E+00    4.7     0.00074037     -3309.3888776785  6.20E-06
   252 Kerker/Diag.0.10E+00    4.5     0.00074183     -3309.3888718322  5.85E-06
   253 Kerker/Diag.0.10E+00    4.6     0.00074329     -3309.3888653367  6.50E-06
   254 Kerker/Diag.0.10E+00    4.7     0.00074471     -3309.3888594270  5.91E-06
   255 Kerker/Diag.0.10E+00    4.7     0.00074610     -3309.3888534653  5.96E-06
   256 Kerker/Diag.0.10E+00    4.7     0.00074746     -3309.3888473100  6.16E-06
   257 Kerker/Diag.0.10E+00    4.6     0.00074880     -3309.3888413682  5.94E-06
   258 Kerker/Diag.0.10E+00    4.4     0.00075008     -3309.3888356443  5.72E-06
   259 Kerker/Diag.0.10E+00    4.5     0.00075137     -3309.3888297086  5.94E-06
   260 Kerker/Diag.0.10E+00    4.7     0.00075263     -3309.3888234599  6.25E-06
   261 Kerker/Diag.0.10E+00    4.5     0.00075385     -3309.3888172308  6.23E-06
   262 Kerker/Diag.0.10E+00    4.5     0.00075503     -3309.3888109623  6.27E-06
   263 Kerker/Diag.0.10E+00    4.5     0.00075621     -3309.3888052272  5.74E-06
   264 Kerker/Diag.0.10E+00    4.4     0.00075733     -3309.3887997991  5.43E-06
   265 Kerker/Diag.0.10E+00    4.5     0.00075843     -3309.3887940217  5.78E-06
   266 Kerker/Diag.0.10E+00    4.5     0.00075950     -3309.3887882734  5.75E-06
   267 Kerker/Diag.0.10E+00    4.8     0.00076056     -3309.3887821646  6.11E-06
   268 Kerker/Diag.0.10E+00    4.3     0.00076157     -3309.3887769023  5.26E-06
   269 Kerker/Diag.0.10E+00    4.5     0.00076255     -3309.3887717004  5.20E-06
   270 Kerker/Diag.0.10E+00    4.3     0.00076349     -3309.3887662124  5.49E-06
   271 Kerker/Diag.0.10E+00    4.6     0.00076441     -3309.3887600702  6.14E-06
   272 Kerker/Diag.0.10E+00    4.2     0.00076531     -3309.3887536753  6.39E-06
   273 Kerker/Diag.0.10E+00    4.3     0.00076616     -3309.3887480211  5.65E-06
   274 Kerker/Diag.0.10E+00    4.4     0.00076700     -3309.3887428958  5.13E-06
   275 Kerker/Diag.0.10E+00    4.4     0.00076779     -3309.3887373957  5.50E-06
   276 Kerker/Diag.0.10E+00    4.4     0.00076856     -3309.3887323352  5.06E-06
   277 Kerker/Diag.0.10E+00    4.4     0.00076929     -3309.3887277995  4.54E-06
   278 Kerker/Diag.0.10E+00    4.5     0.00076998     -3309.3887233431  4.46E-06
   279 Kerker/Diag.0.10E+00    4.3     0.00077064     -3309.3887188196  4.52E-06
   280 Kerker/Diag.0.10E+00    4.5     0.00077128     -3309.3887139488  4.87E-06
   281 Kerker/Diag.0.10E+00    4.4     0.00077189     -3309.3887096453  4.30E-06
   282 Kerker/Diag.0.10E+00    4.2     0.00077245     -3309.3887057943  3.85E-06
   283 Kerker/Diag.0.10E+00    4.3     0.00077299     -3309.3887019229  3.87E-06
   284 Kerker/Diag.0.10E+00    4.4     0.00077349     -3309.3886979919  3.93E-06
   285 Kerker/Diag.0.10E+00    4.1     0.00077397     -3309.3886941597  3.83E-06
   286 Kerker/Diag.0.10E+00    4.2     0.00077438     -3309.3886904260  3.73E-06
   287 Kerker/Diag.0.10E+00    4.3     0.00077476     -3309.3886866397  3.79E-06
   288 Kerker/Diag.0.10E+00    4.2     0.00077519     -3309.3886824155  4.22E-06
   289 Kerker/Diag.0.10E+00    4.1     0.00077555     -3309.3886779226  4.49E-06
   290 Kerker/Diag.0.10E+00    4.2     0.00077585     -3309.3886743910  3.53E-06
   291 Kerker/Diag.0.10E+00    4.2     0.00077612     -3309.3886709885  3.40E-06
   292 Kerker/Diag.0.10E+00    4.5     0.00077636     -3309.3886679462  3.04E-06
   293 Kerker/Diag.0.10E+00    4.1     0.00077656     -3309.3886649813  2.96E-06
   294 Kerker/Diag.0.10E+00    4.1     0.00077672     -3309.3886616294  3.35E-06
   295 Kerker/Diag.0.10E+00    4.0     0.00077687     -3309.3886586154  3.01E-06
   296 Kerker/Diag.0.10E+00    4.2     0.00077698     -3309.3886548024  3.81E-06
   297 Kerker/Diag.0.10E+00    4.0     0.00077706     -3309.3886516926  3.11E-06
   298 Kerker/Diag.0.10E+00    4.0     0.00077709     -3309.3886492840  2.41E-06
   299 Kerker/Diag.0.10E+00    4.0     0.00077709     -3309.3886468254  2.46E-06
   300 Kerker/Diag.0.10E+00    4.1     0.00077705     -3309.3886440293  2.80E-06

  Leaving inner SCF loop after reaching   300 steps.


  Electronic density on regular grids:       -627.9999999995        0.0000000005
  Core density on regular grids:              627.9999999998       -0.0000000002
  Total charge density on r-space grids:        0.0000000003
  Total charge density g-space grids:           0.0000000003

  Overlap energy of the core charge distribution:               0.00000000002339
  Self energy of the core charge distribution:              -6133.94225516408187
  Core Hamiltonian energy:                                   1626.91963268222116
  Hartree energy:                                            1619.79086511562423
  Exchange-correlation energy:                               -422.11653295500241
  Electronic entropic energy:                                  -0.59686175608330
  Fermi energy:                                                 0.02872987116031

  DFT+U energy:                                                 0.55655262253310

  Total energy:                                             -3309.38864402934541

  outer SCF iter =    3 RMS gradient =   0.78E-03 energy =      -3309.3886440293
  outer SCF loop FAILED to converge after    3 iterations or  900 steps


 *** WARNING in qs_scf.F:542 :: SCF run NOT converged ***


  Integrated absolute spin density  :                              36.0888187490
  WARNING: S**2 computation does not yet treat fractional occupied orbitals

 ENERGY| Total FORCE_EVAL ( QS ) energy (a.u.):            -3309.397410546341689


 -------------------------------------------------------------------------------
 -                                                                             -
 -                                DBCSR STATISTICS                             -
 -                                                                             -
 -------------------------------------------------------------------------------
 COUNTER                                    TOTAL       BLAS       SMM       ACC
 flops    13 x    18 x    13             17570592     100.0%      0.0%      0.0%
 flops    26 x    18 x    13             24043968     100.0%      0.0%      0.0%
 flops    13 x    18 x    26             24043968     100.0%      0.0%      0.0%
 flops    26 x    18 x    26             32902272     100.0%      0.0%      0.0%
 flops    13 x    32 x    13           1124517888     100.0%      0.0%      0.0%
 flops    26 x    32 x    13           1538813952     100.0%      0.0%      0.0%
 flops    13 x    32 x    26           1538813952     100.0%      0.0%      0.0%
 flops    26 x    32 x    26           2105745408     100.0%      0.0%      0.0%
 flops    13 x    13 x    72          16247711376     100.0%      0.0%      0.0%
 flops    13 x    13 x    84          18955663272     100.0%      0.0%      0.0%
 flops    26 x    13 x    72          21663615168     100.0%      0.0%      0.0%
 flops    13 x    26 x    72          21663615168     100.0%      0.0%      0.0%
 flops    26 x    13 x    84          25274217696     100.0%      0.0%      0.0%
 flops    13 x    26 x    84          25274217696     100.0%      0.0%      0.0%
 flops    26 x    26 x    72          30785137344     100.0%      0.0%      0.0%
 flops    26 x    26 x    84          35915993568     100.0%      0.0%      0.0%
 flops    13 x    13 x    96          43327230336     100.0%      0.0%      0.0%
 flops    26 x    13 x    96          57769640448     100.0%      0.0%      0.0%
 flops    13 x    26 x    96          57769640448     100.0%      0.0%      0.0%
 flops    26 x    26 x    96          82093699584     100.0%      0.0%      0.0%
 flops    13 x    13 x    64         288848202240     100.0%      0.0%      0.0%
 flops    26 x    13 x    64         385130936320     100.0%      0.0%      0.0%
 flops    13 x    26 x    64         385130936320     100.0%      0.0%      0.0%
 flops    26 x    26 x    64         547291330560     100.0%      0.0%      0.0%
 flops inhomo. stacks                           0       0.0%      0.0%      0.0%
 flops total                         2.049548E+12     100.0%      0.0%      0.0%
 flops max/rank                     98.434667E+09     100.0%      0.0%      0.0%
 matmuls inhomo. stacks                         0       0.0%      0.0%      0.0%
 matmuls total                           45281024     100.0%      0.0%      0.0%
 number of processed stacks               2078592     100.0%      0.0%      0.0%
 average stack size                                    21.8       0.0       0.0
 marketing flops                     2.037199E+12
 -------------------------------------------------------------------------------
 # multiplications                           1804
 max memory usage/rank               2.409701E+09
 # max total images/rank                        3
 # max 3D layers                                1
 # MPI messages exchanged                  822624
 MPI messages size (bytes):
  total size                       110.011654E+09
  min size                          93.184000E+03
  max size                         248.768000E+03
  average size                     133.732609E+03
 MPI breakdown and total messages size (bytes):
             size <=      128                   0                        0
       128 < size <=     8192                   0                        0
      8192 < size <=    32768                   0                        0
     32768 < size <=   131072              354093              35953100352
    131072 < size <=  4194304              468531              74058199488
   4194304 < size <= 16777216                   0                        0
  16777216 < size                               0                        0
 -------------------------------------------------------------------------------

 *** WARNING in dbcsr_mm.F:297 :: Using a non-square number of MPI ranks ***
 *** might lead to poor performance. Used ranks: 24 Suggested: 25 49     ***

 -------------------------------------------------------------------------------
 -                                                                             -
 -                      DBCSR MESSAGE PASSING PERFORMANCE                      -
 -                                                                             -
 -------------------------------------------------------------------------------
 ROUTINE             CALLS      AVE VOLUME [Bytes]
 MP_Group             1805
 MP_Bcast               25                     12.
 MP_Allreduce        12689                      8.
 MP_Alltoall         50498                 164136.
 MP_Wait            101024
 MP_ISend            86588                  60621.
 MP_IRecv            82988                  59791.
 MP_Memory          320992
 -------------------------------------------------------------------------------
 
 MEMORY| Estimated peak process memory [MiB]                                2312

 -------------------------------------------------------------------------------
 -                                                                             -
 -                         MESSAGE PASSING PERFORMANCE                         -
 -                                                                             -
 -------------------------------------------------------------------------------

 ROUTINE             CALLS      AVE VOLUME [Bytes]
 MP_Group                4
 MP_Bcast             2881                 405616.
 MP_Allreduce        19129                   1827.
 MP_Sync              1805
 MP_Alltoall         40556               10332128.
 MP_ISendRecv       165784                  51360.
 MP_Wait            432650
 MP_comm_split        1801
 MP_ISend           230806                 247707.
 MP_IRecv           230806                 247706.
 MP_Recv              2160                 299520.
 -------------------------------------------------------------------------------


 -------------------------------------------------------------------------------
 -                                                                             -
 -                           R E F E R E N C E S                               -
 -                                                                             -
 -------------------------------------------------------------------------------
 
 CP2K version 7.1, the CP2K developers group (2019).
 CP2K is freely available from https://www.cp2k.org/ .

 Schuett, Ole; Messmer, Peter; Hutter, Juerg; VandeVondele, Joost. 
 Electronic Structure Calculations on Graphics Processing Units, John
 Wiley & Sons, Ltd, 173-190 (2016). 
 GPU-Accelerated Sparse Matrix-Matrix Multiplication for
 Linear Scaling Density Functional Theory.
 https://dx.doi.org/10.1002/9781118670712.ch8

 Borstnik, U; VandeVondele, J; Weber, V; Hutter, J. 
 PARALLEL COMPUTING, 40 (5-6), 47-58 (2014). 
 Sparse matrix multiplication: The distributed block-compressed sparse
 row library.
 https://dx.doi.org/10.1016/j.parco.2014.03.012

 Hutter, J; Iannuzzi, M; Schiffmann, F; VandeVondele, J. 
 WIREs Comput Mol Sci., 4 (1), 15-25 (2014). 
 CP2K: atomistic simulations of condensed matter systems.
 https://dx.doi.org/10.1002/wcms.1159

 VandeVondele, J; Hutter, J. 
 JOURNAL OF CHEMICAL PHYSICS, 127 (11), 114105 (2007). 
 Gaussian basis sets for accurate calculations on molecular systems in
 gas and condensed phases.
 https://dx.doi.org/10.1063/1.2770708

 Genovese, L; Deutsch, T; Goedecker, S. 
 JOURNAL OF CHEMICAL PHYSICS, 127 (5), 054704 (2007). 
 Efficient and accurate three-dimensional Poisson solver for surface
 problems.
 https://dx.doi.org/10.1063/1.2754685

 Genovese, L; Deutsch, T; Neelov, A; Goedecker, S; Beylkin, G. 
 JOURNAL OF CHEMICAL PHYSICS, 125 (7), 074105 (2006). 
 Efficient solution of Poisson's equation with free boundary conditions.
 https://dx.doi.org/10.1063/1.2335442

 Krack, M. 
 THEORETICAL CHEMISTRY ACCOUNTS, 114 (1-3), 145-152 (2005). 
 Pseudopotentials for H to Kr optimized for gradient-corrected
 exchange-correlation functionals.
 https://dx.doi.org/10.1007/s00214-005-0655-y

 VandeVondele, J; Krack, M; Mohamed, F; Parrinello, M; Chassaing, T;
 Hutter, J. COMPUTER PHYSICS COMMUNICATIONS, 167 (2), 103-128 (2005). 
 QUICKSTEP: Fast and accurate density functional calculations using a
 mixed Gaussian and plane waves approach.
 https://dx.doi.org/10.1016/j.cpc.2004.12.014

 Frigo, M; Johnson, SG. 
 PROCEEDINGS OF THE IEEE, 93 (2), 216-231 (2005). 
 The design and implementation of FFTW3.
 https://dx.doi.org/10.1109/JPROC.2004.840301

 Hartwigsen, C; Goedecker, S; Hutter, J. 
 PHYSICAL REVIEW B, 58 (7), 3641-3662 (1998). 
 Relativistic separable dual-space Gaussian pseudopotentials from H to Rn.
 https://dx.doi.org/10.1103/PhysRevB.58.3641

 Dudarev, SL; Botton, GA; Savrasov, SY; Humphreys, CJ; Sutton, AP. 
 PHYSICAL REVIEW B, 57 (3), 1505-1509 (1998). 
 Electron-energy-loss spectra and the structural stability of
 nickel oxide: An LSDA+U study.
 https://dx.doi.org/10.1103/PhysRevB.57.1505

 Lippert, G; Hutter, J; Parrinello, M. 
 MOLECULAR PHYSICS, 92 (3), 477-487 (1997). 
 A hybrid Gaussian and plane wave density functional scheme.
 https://dx.doi.org/10.1080/002689797170220

 Dudarev, SL; Manh, DN; Sutton, AP. 
 PHILOSOPHICAL MAGAZINE B, 75 (5), 613-628 (1997). 
 Effect of Mott-Hubbard correlations on the electronic
 structure and structural stability of uranium dioxide.
 https://dx.doi.org/10.1080/13642819708202343

 Perdew, JP; Burke, K; Ernzerhof, M. 
 PHYSICAL REVIEW LETTERS, 77 (18), 3865-3868 (1996). 
 Generalized gradient approximation made simple.
 https://dx.doi.org/10.1103/PhysRevLett.77.3865

 Goedecker, S; Teter, M; Hutter, J. 
 PHYSICAL REVIEW B, 54 (3), 1703-1710 (1996). 
 Separable dual-space Gaussian pseudopotentials.
 https://dx.doi.org/10.1103/PhysRevB.54.1703


 -------------------------------------------------------------------------------
 -                                                                             -
 -                                T I M I N G                                  -
 -                                                                             -
 -------------------------------------------------------------------------------
 SUBROUTINE                       CALLS  ASD         SELF TIME        TOTAL TIME
                                MAXIMUM       AVERAGE  MAXIMUM  AVERAGE  MAXIMUM
 CP2K                                 1  1.0    0.036    0.049 3955.101 3955.107
 qs_forces                            1  2.0    0.000    0.001 3954.055 3954.055
 qs_energies                          1  3.0    0.001    0.010 3949.118 3949.119
 scf_env_do_scf                       1  4.0    0.002    0.011 3945.324 3945.355
 scf_env_do_scf_inner_loop          900  5.0    0.059    0.243 3945.315 3945.344
 rebuild_ks_matrix                  901  7.0    0.003    0.003 2375.251 2375.265
 qs_ks_build_kohn_sham_matrix       901  8.0    0.196    0.241 2375.249 2375.262
 qs_ks_update_qs_env                900  6.0    0.009    0.019 2371.963 2371.976
 pw_transfer                      33331 10.5    3.794    5.262 1336.487 1354.613
 fft_wrap_pw1pw2                  33331 11.5    0.453    0.614 1332.693 1350.853
 fft_wrap_pw1pw2_280              22519 12.5   97.920  102.577 1284.195 1313.910
 sum_up_and_integrate               901  9.0    7.959    8.115 1155.712 1156.255
 integrate_v_rspace                1802 10.0  683.094  842.061 1147.739 1148.251
 qs_rho_update_rho                  901  6.0    0.010    0.027 1108.938 1109.055
 calculate_rho_elec                1802  7.0  600.874  759.545 1108.927 1109.028
 fft3d_ps                         33331 13.5  655.349  778.540  987.330 1039.080
 qs_vxc_create                      901  9.0    0.038    0.067  997.615 1002.430
 xc_vxc_pw_create                   901 10.0   25.772   27.664  997.577 1002.406
 density_rs2pw                     1802  8.0    0.145    0.217  472.135  668.025
 rs_pw_transfer                   14421 10.5    0.218    0.290  387.369  578.563
 xc_rho_set_and_dset_create         901 11.0   10.310   10.626  489.404  495.617
 mp_waitany                      230806 12.5  206.125  393.486  206.125  393.486
 rs_pw_transfer_RS2PW_280          1804 10.0   28.359   36.542  197.884  387.366
 mp_alltoall_d11v                 27051 10.3  172.319  380.410  172.319  380.410
 rs_distribute_matrix              3606  9.5    5.108    9.367  170.717  374.887
 qs_scf_new_mos                     900  6.0    0.037    0.065  322.844  323.680
 mp_alltoall_z22v                 33331 15.5  207.655  301.811  207.655  301.811
 potential_pw2rs                   1802 11.0    0.873    1.051  301.052  301.476
 eigensolver                       1800  7.0    0.129    0.195  288.685  288.859
 cp_fm_syevd                       1801  8.0    0.018    0.023  244.078  244.306
 cp_fm_redistribute_end            1801  9.0   41.756  240.688   42.156  240.963
 cp_fm_syevd_base                  1801  9.0  198.157  238.079  198.157  238.079
 yz_to_x                          15319 14.1   35.706   50.876  149.209  227.637
 x_to_yz                          18012 14.8   87.581   93.023  181.734  225.619
 pw_poisson_solve                   901  9.0   10.352   11.766  160.800  160.813
 pw_scatter_p                     18012 13.8  142.785  156.350  142.785  156.350
 xc_functional_eval                 901 12.0    0.019    0.042  145.751  152.967
 pbe_lsd_eval                       901 13.0  145.733  152.958  145.733  152.958
 gspace_mixing                      897  6.0    3.326    3.979  139.056  139.066
 rs_pw_transfer_PW2RS_280          1805 13.0   67.127   70.331  116.693  118.617
 pw_gather_p                      15319 13.1  101.577  117.282  101.577  117.282
 -------------------------------------------------------------------------------

 The number of warnings for this run is : 3
 
 -------------------------------------------------------------------------------
  **** **** ******  **  PROGRAM ENDED AT                 2021-04-11 19:27:54.653
 ***** ** ***  *** **   PROGRAM RAN ON                           h2112.para.cstc
 **    ****   ******    PROGRAM RAN BY                                   sc32189
 ***** **    ** ** **   PROGRAM PROCESS ID                                 13683
  **** **  *******  **  PROGRAM STOPPED IN            /public3/home/sc32189/11-3
-------------- next part --------------
@set datapath /public3/home/sc32189/data 
&GLOBAL
        PROJECT cp2k
        RUN_TYPE ENERGY_FORCE 
        PRINT_LEVEL low
&END GLOBAL

&FORCE_EVAL
        METHOD QUICKSTEP
        STRESS_TENSOR ANALYTICAL
        &DFT
                BASIS_SET_FILE_NAME ${datapath}/BASIS_MOLOPT
                POTENTIAL_FILE_NAME ${datapath}/GTH_POTENTIALS
                UKS T
                WFN_RESTART_FILE_NAME ./cp2k-RESTART.wfn
                MULTIPLICITY 13 
                CHARGE 0
                PLUS_U_METHOD MULliKEN_CHARGES
                # RELAX_MULTIPLICITY 0.1
                # SURFACE_DIPOLE_CORRECTION T
                # SURF_DIP_DIR 
                # EXCITATIONS
                &QS
                        EPS_DEFAULT 1.0E-12
                        EXTRAPOLATION ASPC
                        EXTRAPOLATION_ORDER 3 
                &END QS
                &MGRID
                        NGRIDS 4
                        CUTOFF 550
                        REL_CUTOFF 60
                &END MGRID
                &XC
                        &XC_FUNCTIONAL PBE
                        &END XC_FUNCTIONAL
                &END XC
                &POISSON
                        POISSON_SOLVER WAVELET
                        &WAVELET
                        &END WAVELET
                &END POISSON
                #&KPOINTS
                #        SCHEME MONKHORST-PACK 5 5 3
                #        SYMMETRY T
                #        VERBOSE T
                #        FULL_GRID T
                #&END KPOINTS
                &SCF
                        SCF_GUESS RESTART
                        EPS_SCF 1.0E-6
                        MAX_SCF 300
                        ADDED_MOS 500
                        # CHOLESKY INVERSE
                        &SMEAR ON
                                METHOD FERMI_DIRAC
                                ELECTRONIC_TEMPERATURE [K] 4000
                        &END SMEAR
                        &DIAGONALIZATION
                                ALGORITHM STANDARD
                                EPS_ADAPT 0.01
                        &END DIAGONALIZATION
                        &MIXING
                                METHOD  KERKER_MIXING
                                ALPHA 0.1
                                BETA 3
                                NBROYDEN 8
                        &END MIXING
                        &OUTER_SCF T
                                EPS_SCF 1.0E-4
                                MAX_SCF 2
                        &END OUTER_SCF
                &END SCF
                &PRINT
                        &LOWDIN SILENT
                                FILENAME lowdin
                        &END LOWDIN
                        &HIRSHFELD SILENT
                                FILENAME hirshfeld 
                        &END HIRSHFELD
                        &MULLIKEN SILENT
                                FILENAME Mulliken 
                        &END MULLIKEN
                        # &PLUS_U
                        #        &EACH
                        #                QS_SCF 1
                        #        &END EACH
                        # &END PLUS_U
                &END PRINT
        &END DFT
        &SUBSYS
                &CELL
                        ABC 9.99289 10.1300 20.8486
                        ALPHA_BETA_GAMMA 90 90 90
                        PERIODIC XY 
                &END CELL
                &COORD
                        @INCLUDE 'coord.inc'
                &END COORD
                &KIND O
                        ELEMENT O
                        BASIS_SET DZVP-MOLOPT-SR-GTH
                        POTENTIAL GTH-PBE
                &END KIND
                &KIND Co1
                        ELEMENT Co
                        BASIS_SET DZVP-MOLOPT-SR-GTH
                        POTENTIAL GTH-PBE
                        MAGNETIZATION 3.0
                        &DFT_PLUS_U
                                EPS_U_RAMPING 1.0E-3
                                U_RAMPING 0.1
                                L 2
                                U_MINUS_J [ev] 0.5
                        &END DFT_PLUS_U
                &END KIND
                &KIND Co2
                        ELEMENT Co
                        BASIS_SET DZVP-MOLOPT-SR-GTH
                        POTENTIAL GTH-PBE
                        MAGNETIZATION -3.0
                        &DFT_PLUS_U
                                EPS_U_RAMPING 1.0E-3
                                U_RAMPING 0.1
                                L 2
                                U_MINUS_J [ev] 0.5
                        &END DFT_PLUS_U
                &END KIND
		&KIND Co3
                        ELEMENT Co
                        BASIS_SET DZVP-MOLOPT-SR-GTH
                        POTENTIAL GTH-PBE
                        MAGNETIZATION 3.0
                        &DFT_PLUS_U
                                EPS_U_RAMPING 1.0E-3
                                U_RAMPING 0.1
                                L 2
                                U_MINUS_J [ev] 0.5
                        &END DFT_PLUS_U
                &END KIND
		&KIND Co4
                        ELEMENT Co
                        BASIS_SET DZVP-MOLOPT-SR-GTH
                        POTENTIAL GTH-PBE
                        MAGNETIZATION -3.0
                        &DFT_PLUS_U
                                EPS_U_RAMPING 1.0E-3
                                U_RAMPING 0.1
                                L 2
                                U_MINUS_J [ev] 0.5
                        &END DFT_PLUS_U
                &END KIND
                &KIND Mo
                        ELEMENT Mo
                        BASIS_SET DZVP-MOLOPT-SR-GTH
                        POTENTIAL GTH-PBE
                         &DFT_PLUS_U
                                EPS_U_RAMPING 1.0E-3
                                U_RAMPING 0.1
                                L 2
                                U_MINUS_J [ev] 0.8
                         &END DFT_PLUS_U
                &END KIND
        &END SUBSYS
&END FORCE_EVAL

#&MOTION
#        &CELL_OPT
#                EXTERNAL_PRESSURE 1.0 0.0 0.0 0.0 1.0 0.0 0.0 0.0 1.0
#                KEEP_ANGLES T
#                KEEP_SYMMETRY T
#                OPTIMIZER CG
#                # CONSTRAINT Z
#                # TYPE DIRECT_CELL_OPT 
#                &CG
#                        &LINE_SEARCH
#                                TYPE 2PNT
#                        &END LINE_SEARCH
#                &END CG
#        &END CELL_OPT
#        &GEO_OPT
#        &END GEO_OPT
#        &PRINT
#                &TRAJECTORY
#                        FORMAT PDB
#                &END TRAJECTORY
#        &END PRINT
#&END MOTION
-------------- next part --------------
O 6.320343  1.698461  1.000009 
O 1.441905  3.376654  1.000015 
O 8.641983  5.186123  1.000015 
O 6.438301  6.753341  1.000015 
O 1.323991  8.431494  1.000020 
O 3.918766  10.130008  1.000020 
O 3.645608  4.943878  1.000023 
O 8.915151  10.130013  1.000023 
O 8.641984  7.536953  2.357275 
O 3.645617  2.593043  2.357278 
O 1.323980  5.914242  2.453361 
O 6.320334  4.215754  2.453394 
O 6.320347  9.280789  2.470942 
O 1.323988  0.849227  2.470980 
O 8.641992  2.471954  2.567029 
O 3.645609  7.658063  2.567067 
O 6.320346  6.763487  3.924307 
O 8.641981  0.121108  3.924312 
O 6.438299  1.688327  3.924312 
O 1.441908  8.441680  3.924312 
O 1.323989  3.366479  3.924318 
O 3.918764  5.064993  3.924318 
O 8.915149  5.064998  3.924321 
O 3.645611  10.008904  3.924321 
O 8.641982  2.471939  5.281573 
O 3.645620  7.658068  5.281576 
O 1.323978  0.849228  5.377659 
O 6.320337  9.280780  5.377691 
O 6.320345  4.215775  5.395240 
O 1.323991  5.914253  5.395278 
O 8.641995  7.536979  5.491327 
O 3.645607  2.593049  5.491365 
O 6.320344  1.698473  6.848604 
O 1.441906  3.376666  6.848610 
O 8.641984  5.186134  6.848610 
O 6.438303  6.753353  6.848610 
O 1.323992  8.431505  6.848616 
O 3.918767  10.130019  6.848616 
Co1 9.463128  3.376649  1.000000 
Co1 9.463131  8.441675  3.924298 
Co1 9.463129  3.376661  6.848596 
Co2 4.466584  6.753321  1.000009 
Co2 4.466585  6.753332  6.848604 
Co2 4.466582  1.688306  3.924307 
Co3 5.154336  8.441690  3.924312 
Co3 5.154333  3.376664  1.000015 
Co3 5.154334  3.376676  6.848610 
Co4 0.157880  6.753336  1.000012 
Co4 0.157878  1.688322  3.924310 
Co4 0.157881  6.753348  6.848607 
Mo 2.491097  1.477530  1.000018 
Mo 7.487486  8.652460  1.000020 
Mo 7.487482  0.738769  2.279614 
Mo 2.491102  9.391236  2.279623 
Mo 7.487485  5.803780  2.644707 
Mo 2.491099  4.326212  2.644713 
Mo 2.491100  6.542556  3.924315 
Mo 7.487484  3.587446  3.924318 
Mo 7.487485  5.803795  5.203912 
Mo 2.491099  4.326222  5.203921 
Mo 7.487483  0.738765  5.569005 
Mo 2.491102  9.391238  5.569011 
Mo 2.491098  1.477542  6.848613 
Mo 7.487487  8.652472  6.848616 


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