[CP2K-user] Electronic state energies with mndod

mr...@gmail.com mrbsm... at gmail.com
Mon Sep 28 11:24:05 UTC 2020


Hi everyone,

I am wondering, can one print the electronic state energies for a MNDOD 
calculation using cp2k? 

Also, I have provided the input file for a single point MNDOD calculation. 
Can someone please tell me if it looks OK and/or if it can be improved? 

On a side note, this MNDOD calculation is for a Cd33Se33 quantum dot, but I 
notice that CP2K outputs information for Ca, not Cd, which can be seen in 
the attached output file.

Thank you very much for your time,
Kind regards,
Brendan Smith
SUNY Buffalo, Chemistry department
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 DBCSR| CPU Multiplication driver                                           BLAS
 DBCSR| Multrec recursion limit                                              512
 DBCSR| Multiplication stack size                                           1000
 DBCSR| Maximum elements for images                                    UNLIMITED
 DBCSR| Multiplicative factor virtual images                                   1
 DBCSR| Use multiplication densification                                       T
 DBCSR| Multiplication size stacks                                             3
 DBCSR| Number of 3D layers                                               SINGLE
 DBCSR| Use MPI memory allocation                                              T
 DBCSR| Use RMA algorithm                                                      F
 DBCSR| Use Communication thread                                               T
 DBCSR| Communication thread load                                             87


  **** **** ******  **  PROGRAM STARTED AT               2020-09-28 07:22:24.839
 ***** ** ***  *** **   PROGRAM STARTED ON        cpn-u28-38.cbls.ccr.buffalo.ed
 **    ****   ******    PROGRAM STARTED BY                              bsmith24
 ***** **    ** ** **   PROGRAM PROCESS ID                                 44895
  **** **  *******  **  PROGRAM STARTED IN /panfs/panfs.cbls.ccr.buffalo.edu/scr
                                           atch/grp-alexeyak/brendan/cp2k_md_rep
                                           ository/mndod_cd33se33

 CP2K| version string:                                          CP2K version 7.1
 CP2K| source code revision number:                                  git:e635599
 CP2K| cp2kflags: fftw3 parallel mpi3 scalapack spglib                          
 CP2K| is freely available from                            https://www.cp2k.org/
 CP2K| Program compiled at                          Thu Sep 17 16:12:40 EDT 2020
 CP2K| Program compiled on                       srv-p22-12.cbls.ccr.buffalo.edu
 CP2K| Program compiled for                                                local
 CP2K| Data directory path    /panfs/panfs.cbls.ccr.buffalo.edu/scratch/grp-alex
 CP2K| Input file name                                   cp2k_input_template.inp

 GLOBAL| Force Environment number                                              1
 GLOBAL| Basis set file name                                           BASIS_SET
 GLOBAL| Potential file name                                           POTENTIAL
 GLOBAL| MM Potential file name                                     MM_POTENTIAL
 GLOBAL| Coordinate file name                                          coord.xyz
 GLOBAL| Method name                                                        CP2K
 GLOBAL| Project name                                             cd33se33_mndod
 GLOBAL| Preferred FFT library                                             FFTW3
 GLOBAL| Preferred diagonalization lib.                                       SL
 GLOBAL| Run type                                                         ENERGY
 GLOBAL| All-to-all communication in single precision                          F
 GLOBAL| FFTs using library dependent lengths                                  F
 GLOBAL| Global print level                                               MEDIUM
 GLOBAL| MPI I/O enabled                                                       T
 GLOBAL| Total number of message passing processes                            32
 GLOBAL| Number of threads for this process                                    1
 GLOBAL| This output is from process                                           0
 GLOBAL| CPU model name                 Intel(R) Xeon(R) Gold 6130 CPU @ 2.10GHz
 GLOBAL| CPUID                                                              1003

 MEMORY| system memory details [Kb]
 MEMORY|                        rank 0           min           max       average
 MEMORY| MemTotal            196317880     196317880     196317880     196317880
 MEMORY| MemFree              81917332      81917332      81917332      81917332
 MEMORY| Buffers                472160        472160        472160        472160
 MEMORY| Cached              107554680     107554680     107554680     107554680
 MEMORY| Slab                  1893288       1893288       1893288       1893288
 MEMORY| SReclaimable          1586176       1586176       1586176       1586176
 MEMORY| MemLikelyFree       191530348     191530348     191530348     191530348


 *** Fundamental physical constants (SI units) ***

 *** Literature: B. J. Mohr and B. N. Taylor,
 ***             CODATA recommended values of the fundamental physical
 ***             constants: 2006, Web Version 5.1
 ***             http://physics.nist.gov/constants

 Speed of light in vacuum [m/s]                             2.99792458000000E+08
 Magnetic constant or permeability of vacuum [N/A**2]       1.25663706143592E-06
 Electric constant or permittivity of vacuum [F/m]          8.85418781762039E-12
 Planck constant (h) [J*s]                                  6.62606896000000E-34
 Planck constant (h-bar) [J*s]                              1.05457162825177E-34
 Elementary charge [C]                                      1.60217648700000E-19
 Electron mass [kg]                                         9.10938215000000E-31
 Electron g factor [ ]                                     -2.00231930436220E+00
 Proton mass [kg]                                           1.67262163700000E-27
 Fine-structure constant                                    7.29735253760000E-03
 Rydberg constant [1/m]                                     1.09737315685270E+07
 Avogadro constant [1/mol]                                  6.02214179000000E+23
 Boltzmann constant [J/K]                                   1.38065040000000E-23
 Atomic mass unit [kg]                                      1.66053878200000E-27
 Bohr radius [m]                                            5.29177208590000E-11

 *** Conversion factors ***

 [u] -> [a.u.]                                              1.82288848426455E+03
 [Angstrom] -> [Bohr] = [a.u.]                              1.88972613288564E+00
 [a.u.] = [Bohr] -> [Angstrom]                              5.29177208590000E-01
 [a.u.] -> [s]                                              2.41888432650478E-17
 [a.u.] -> [fs]                                             2.41888432650478E-02
 [a.u.] -> [J]                                              4.35974393937059E-18
 [a.u.] -> [N]                                              8.23872205491840E-08
 [a.u.] -> [K]                                              3.15774647902944E+05
 [a.u.] -> [kJ/mol]                                         2.62549961709828E+03
 [a.u.] -> [kcal/mol]                                       6.27509468713739E+02
 [a.u.] -> [Pa]                                             2.94210107994716E+13
 [a.u.] -> [bar]                                            2.94210107994716E+08
 [a.u.] -> [atm]                                            2.90362800883016E+08
 [a.u.] -> [eV]                                             2.72113838565563E+01
 [a.u.] -> [Hz]                                             6.57968392072181E+15
 [a.u.] -> [1/cm] (wave numbers)                            2.19474631370540E+05
 [a.u./Bohr**2] -> [1/cm]                                   5.14048714338585E+03
 

 CELL_TOP| Volume [angstrom^3]:                                        15625.000
 CELL_TOP| Vector a [angstrom    25.000     0.000     0.000    |a| =      25.000
 CELL_TOP| Vector b [angstrom     0.000    25.000     0.000    |b| =      25.000
 CELL_TOP| Vector c [angstrom     0.000     0.000    25.000    |c| =      25.000
 CELL_TOP| Angle (b,c), alpha [degree]:                                   90.000
 CELL_TOP| Angle (a,c), beta  [degree]:                                   90.000
 CELL_TOP| Angle (a,b), gamma [degree]:                                   90.000
 CELL_TOP| Numerically orthorhombic:                                         YES

 GENERATE|  Preliminary Number of Bonds generated:                             0
 GENERATE|  Achieved consistency in connectivity generation.

 CELL| Volume [angstrom^3]:                                            15625.000
 CELL| Vector a [angstrom]:      25.000     0.000     0.000    |a| =      25.000
 CELL| Vector b [angstrom]:       0.000    25.000     0.000    |b| =      25.000
 CELL| Vector c [angstrom]:       0.000     0.000    25.000    |c| =      25.000
 CELL| Angle (b,c), alpha [degree]:                                       90.000
 CELL| Angle (a,c), beta  [degree]:                                       90.000
 CELL| Angle (a,b), gamma [degree]:                                       90.000
 CELL| Numerically orthorhombic:                                             YES

 CELL_REF| Volume [angstrom^3]:                                        15625.000
 CELL_REF| Vector a [angstrom    25.000     0.000     0.000    |a| =      25.000
 CELL_REF| Vector b [angstrom     0.000    25.000     0.000    |b| =      25.000
 CELL_REF| Vector c [angstrom     0.000     0.000    25.000    |c| =      25.000
 CELL_REF| Angle (b,c), alpha [degree]:                                   90.000
 CELL_REF| Angle (a,c), beta  [degree]:                                   90.000
 CELL_REF| Angle (a,b), gamma [degree]:                                   90.000
 CELL_REF| Numerically orthorhombic:                                         YES


              #####   #####        # #     # ######  ######   #####  
             #     # #     #      #  ##    # #     # #     # #     # 
             #     # #           #   # #   # #     # #     # #     # 
             #     #  #####     #    #  #  # #     # #     # #     # 
             #   # #       #   #     #   # # #     # #     # #     # 
             #    #  #     #  #      #    ## #     # #     # #     # 
              #### #  #####  #       #     # ######  ######   #####  
                                                                     
                              T. Laino and J. Hutter                 
                                                                     
                                   2008 - 2015                       


 SEMIEMPIRICAL|                      Coulomb Integral cutoff/taper was redefined
 SEMIEMPIRICAL| Old value [a.u.]                                          22.677
 SEMIEMPIRICAL| New value [a.u.]                                          47.243


 SEMIEMPIRICAL|                             Coulomb Integral cutoff/taper values
 SEMIEMPIRICAL| Cutoff [a.u.]                                             47.243
 SEMIEMPIRICAL| Taper  [a.u.]                                             47.243
 SEMIEMPIRICAL| Range  [a.u.]                                              0.000


 SEMIEMPIRICAL|                     Exchange Integral cutoff/taper was redefined
 SEMIEMPIRICAL| Default value [a.u.]                                      22.677
 SEMIEMPIRICAL| New value [a.u.]                                          11.811


 SEMIEMPIRICAL|                            Exchange Integral cutoff/taper values
 SEMIEMPIRICAL| Cutoff [a.u.]                                             11.811
 SEMIEMPIRICAL| Taper  [a.u.]                                             11.811
 SEMIEMPIRICAL| Range  [a.u.]                                              0.000



 ATOMIC KIND INFORMATION

  1. Atomic kind: Cd                                    Number of atoms:      33

     Orbital Basis Set                                            Cadmium_STO-6G

       Number of orbital shell sets:                                           2
       Number of orbital shells:                                               2
       Number of primitive Cartesian functions:                               12
       Number of Cartesian basis functions:                                    4
       Number of spherical basis functions:                                    4
       Norm type:                                                              2

       Normalised Cartesian orbitals:

                        Set   Shell   Orbital            Exponent    Coefficient

                          1       1    1s                4.312625       0.005749
                                                         1.552978       0.018344
                                                         0.565155      -0.044544
                                                         0.324509      -0.159364
                                                         0.112228       0.150301
                                                         0.067698       0.029360

                          2       1    2px               9.233596       0.002669
                                                         0.855059      -0.034232
                                                         0.411308      -0.064842
                                                         0.132056       0.064749
                                                         0.081347       0.029531
                                                         0.050432       0.002051
                          2       1    2py               9.233596       0.002669
                                                         0.855059      -0.034232
                                                         0.411308      -0.064842
                                                         0.132056       0.064749
                                                         0.081347       0.029531
                                                         0.050432       0.002051
                          2       1    2pz               9.233596       0.002669
                                                         0.855059      -0.034232
                                                         0.411308      -0.064842
                                                         0.132056       0.064749
                                                         0.081347       0.029531
                                                         0.050432       0.002051

     AE Potential information for                                        Cadmium

       Description:                                       Bare Coulomb Potential
                                                             Valence charge only

       Gaussian exponent of the core charge distribution:               0.913075
       Electronic configuration (s p d ...):                       2   0   0   0

  2. Atomic kind: Se                                    Number of atoms:      33

     Orbital Basis Set                                           Selenium_STO-6G

       Number of orbital shell sets:                                           2
       Number of orbital shells:                                               2
       Number of primitive Cartesian functions:                               12
       Number of Cartesian basis functions:                                    4
       Number of spherical basis functions:                                    4
       Norm type:                                                              2

       Normalised Cartesian orbitals:

                        Set   Shell   Orbital            Exponent    Coefficient

                          1       1    1s                1.695960       0.001456
                                                         0.189161      -0.017716
                                                         0.090122      -0.036700
                                                         0.027687       0.037794
                                                         0.016595       0.014464
                                                         0.009832       0.000553

                          2       1    2px               8.871329      -0.036356
                                                         2.955330      -0.091547
                                                         1.267946      -0.114276
                                                         0.328442       0.143649
                                                         0.184064       0.093383
                                                         0.104572       0.010214
                          2       1    2py               8.871329      -0.036356
                                                         2.955330      -0.091547
                                                         1.267946      -0.114276
                                                         0.328442       0.143649
                                                         0.184064       0.093383
                                                         0.104572       0.010214
                          2       1    2pz               8.871329      -0.036356
                                                         2.955330      -0.091547
                                                         1.267946      -0.114276
                                                         0.328442       0.143649
                                                         0.184064       0.093383
                                                         0.104572       0.010214

     AE Potential information for                                       Selenium

       Description:                                       Bare Coulomb Potential
                                                             Valence charge only

       Gaussian exponent of the core charge distribution:               1.486326
       Electronic configuration (s p d ...):                       2   4   0   0


 MOLECULE KIND INFORMATION


 All atoms are their own molecule, skipping detailed information


 TOTAL NUMBERS AND MAXIMUM NUMBERS

  Total number of            - Atomic kinds:                                   2
                             - Atoms:                                         66
                             - Shell sets:                                   132
                             - Shells:                                       132
                             - Primitive Cartesian functions:                792
                             - Cartesian basis functions:                    264
                             - Spherical basis functions:                    264

  Maximum angular momentum of the orbital basis functions:                     1


 MODULE QUICKSTEP:  ATOMIC COORDINATES IN angstrom

  Atom  Kind  Element       X           Y           Z          Z(eff)       Mass

       1     1 Cd  48   16.384045   16.103922   14.218678      2.00     112.4110
       2     1 Cd  48   13.745581   17.025862   16.970785      2.00     112.4110
       3     1 Cd  48   14.277182   12.578492   19.019757      2.00     112.4110
       4     1 Cd  48   13.720146    9.814772   18.631997      2.00     112.4110
       5     1 Cd  48   10.715717   12.077681   19.099388      2.00     112.4110
       6     1 Cd  48   10.370603    8.672907   17.707665      2.00     112.4110
       7     1 Cd  48    8.438306   11.487859   16.445216      2.00     112.4110
       8     1 Cd  48    6.454121   13.914575   13.830797      2.00     112.4110
       9     1 Cd  48    8.441465   15.763304   10.068957      2.00     112.4110
      10     1 Cd  48   10.169752   12.991160    7.709701      2.00     112.4110
      11     1 Cd  48   13.338974   12.033099    7.690992      2.00     112.4110
      12     1 Cd  48   13.438902    9.208353    9.591899      2.00     112.4110
      13     1 Cd  48   11.642485   12.010234   10.774176      2.00     112.4110
      14     1 Cd  48   10.103017   15.019260   12.879547      2.00     112.4110
      15     1 Cd  48   12.076903   18.203018   10.268248      2.00     112.4110
      16     1 Cd  48   14.945747   18.198455   11.000803      2.00     112.4110
      17     1 Cd  48   12.947640   18.245183   14.139476      2.00     112.4110
      18     1 Cd  48    9.753721   16.285229   16.107731      2.00     112.4110
      19     1 Cd  48   12.208850   13.726281   15.918031      2.00     112.4110
      20     1 Cd  48   10.418713   10.684796   14.115401      2.00     112.4110
      21     1 Cd  48    6.454444   10.026554   12.699752      2.00     112.4110
      22     1 Cd  48    9.092629    9.778751   10.275210      2.00     112.4110
      23     1 Cd  48   13.892581    7.376240   12.884756      2.00     112.4110
      24     1 Cd  48   16.458932    9.350054   12.141008      2.00     112.4110
      25     1 Cd  48   15.862938   11.886552   10.034399      2.00     112.4110
      26     1 Cd  48   13.040883   15.334304    7.862875      2.00     112.4110
      27     1 Cd  48   18.298133   13.037869   12.788723      2.00     112.4110
      28     1 Cd  48   14.033946   14.791691   12.254837      2.00     112.4110
      29     1 Cd  48   15.936152   12.849004   15.743760      2.00     112.4110
      30     1 Cd  48   13.899762   10.499184   13.918456      2.00     112.4110
      31     1 Cd  48    6.426368   12.845426    9.944669      2.00     112.4110
      32     1 Cd  48   13.228614    7.356466   15.974468      2.00     112.4110
      33     1 Cd  48   10.336500    7.493323   13.329468      2.00     112.4110
      34     2 Se  34   15.386358   18.154305   15.376332      6.00      78.9600
      35     2 Se  34   14.353507   14.532589   17.263303      6.00      78.9600
      36     2 Se  34   16.013394   10.980201   17.991685      6.00      78.9600
      37     2 Se  34   12.685862   11.643776   20.761321      6.00      78.9600
      38     2 Se  34   12.562943    7.459099   18.433797      6.00      78.9600
      39     2 Se  34    8.758364   10.309544   18.833072      6.00      78.9600
      40     2 Se  34    6.335913   11.577917   14.923689      6.00      78.9600
      41     2 Se  34    6.200017   14.881531   11.327656      6.00      78.9600
      42     2 Se  34    7.965791   14.184806    7.901820      6.00      78.9600
      43     2 Se  34   12.143527   13.680903    5.989486      6.00      78.9600
      44     2 Se  34   15.290061   10.428102    7.926467      6.00      78.9600
      45     2 Se  34   12.115826    9.696625   11.965219      6.00      78.9600
      46     2 Se  34    9.489814   12.355691   12.432346      6.00      78.9600
      47     2 Se  34   10.989781   15.831153   10.319048      6.00      78.9600
      48     2 Se  34   13.705940   17.856191    8.235835      6.00      78.9600
      49     2 Se  34   13.401975   19.887548   12.174984      6.00      78.9600
      50     2 Se  34   11.392400   18.202385   16.494175      6.00      78.9600
      51     2 Se  34    9.720267   13.858764   17.289457      6.00      78.9600
      52     2 Se  34   12.345041   11.062987   16.056330      6.00      78.9600
      53     2 Se  34    9.264728    8.829281   15.410846      6.00      78.9600
      54     2 Se  34    8.490080    7.726251   11.718187      6.00      78.9600
      55     2 Se  34   10.779630   10.578752    8.268784      6.00      78.9600
      56     2 Se  34   15.603829    8.801145   14.793020      6.00      78.9600
      57     2 Se  34   15.276717    7.658457   10.691746      6.00      78.9600
      58     2 Se  34   18.275882   11.025549   10.905378      6.00      78.9600
      59     2 Se  34   13.716692   13.490244   10.026052      6.00      78.9600
      60     2 Se  34   16.223979   16.126978   11.633406      6.00      78.9600
      61     2 Se  34   12.366480   15.563598   13.945202      6.00      78.9600
      62     2 Se  34   18.279639   14.281579   15.019381      6.00      78.9600
      63     2 Se  34   15.154622   12.591620   13.253836      6.00      78.9600
      64     2 Se  34    8.118286   16.220000   14.171232      6.00      78.9600
      65     2 Se  34    6.395777   10.299234   10.191381      6.00      78.9600
      66     2 Se  34   12.204452    5.761499   13.979956      6.00      78.9600




 SCF PARAMETERS         Density guess:                                    ATOMIC
                        --------------------------------------------------------
                        max_scf:                                            1000
                        max_scf_history:                                       0
                        max_diis:                                              4
                        --------------------------------------------------------
                        eps_scf:                                        1.00E-05
                        eps_scf_history:                                0.00E+00
                        eps_diis:                                       1.00E-01
                        eps_eigval:                                     1.00E-05
                        --------------------------------------------------------
                        level_shift [a.u.]:                                 0.00
                        --------------------------------------------------------
                        No outer SCF

 PW_GRID| Information for grid number                                          1
 PW_GRID| Grid distributed over                                    32 processors
 PW_GRID| Real space group dimensions                                     4    8
 PW_GRID| the grid is blocked:                                               YES
 PW_GRID| Cutoff [a.u.]                                                      1.0
 PW_GRID| spherical cutoff:                                                   NO
 PW_GRID|   Bounds   1            -12      11                Points:          24
 PW_GRID|   Bounds   2            -12      11                Points:          24
 PW_GRID|   Bounds   3            -12      11                Points:          24
 PW_GRID| Volume element (a.u.^3)   7.628         Volume (a.u.^3)    105442.7279
 PW_GRID| Grid span                                                    FULLSPACE
 PW_GRID|   Distribution                         Average         Max         Min
 PW_GRID|   G-Vectors                              432.0         432         432
 PW_GRID|   G-Rays                                  18.0          18          18
 PW_GRID|   Real Space Points                      432.0         432         432

 POISSON| Solver                                                        PERIODIC
 POISSON| Periodicity                                                        XYZ

 RS_GRID| Information for grid number                                          1
 RS_GRID|   Bounds   1            -12      11                Points:          24
 RS_GRID|   Bounds   2            -12      11                Points:          24
 RS_GRID|   Bounds   3            -12      11                Points:          24
 RS_GRID| Real space fully replicated
 RS_GRID| Group size                                                           1

 Number of electrons:                                                        264
 Number of occupied orbitals:                                                132
 Number of molecular orbitals:                                               132

 Number of orbital functions:                                                264
 Number of independent orbital functions:                                    264

 Extrapolation method: initial_guess


 SCF WAVEFUNCTION OPTIMIZATION

  ----------------------------------- OT ---------------------------------------
  Minimizer      : DIIS                : direct inversion
                                         in the iterative subspace
                                         using   7 DIIS vectors
                                         safer DIIS on
  Preconditioner : NONE
  Precond_solver : DEFAULT
  stepsize       :    0.15000000                  energy_gap     :    0.20000000
  eps_taylor     :   0.10000E-15                  max_taylor     :             4
  ----------------------------------- OT ---------------------------------------

  Step     Update method      Time    Convergence         Total energy    Change
  ------------------------------------------------------------------------------
     1 OT DIIS     0.15E+00    0.0     0.05760794      -204.9028339933 -2.05E+02
     2 OT DIIS     0.15E+00    0.0     0.04327471      -213.4132377661 -8.51E+00
     3 OT DIIS     0.15E+00    0.0     0.02610569      -217.2106656859 -3.80E+00
     4 OT DIIS     0.15E+00    0.0     0.02095112      -220.6207162285 -3.41E+00
     5 OT DIIS     0.15E+00    0.0     0.01841990      -223.9797896192 -3.36E+00
     6 OT DIIS     0.15E+00    0.0     0.01642088      -226.3617545541 -2.38E+00
     7 OT DIIS     0.15E+00    0.0     0.01397880      -229.4688664063 -3.11E+00
     8 OT DIIS     0.15E+00    0.0     0.01147575      -231.5361083014 -2.07E+00
     9 OT DIIS     0.15E+00    0.0     0.00943726      -233.2902926120 -1.75E+00
    10 OT DIIS     0.15E+00    0.0     0.00809934      -234.2256428826 -9.35E-01
    11 OT DIIS     0.15E+00    0.0     0.00648646      -235.0476127075 -8.22E-01
    12 OT DIIS     0.15E+00    0.0     0.00576914      -235.5844908331 -5.37E-01
    13 OT DIIS     0.15E+00    0.0     0.00463159      -235.9484907083 -3.64E-01
    14 OT DIIS     0.15E+00    0.0     0.00392650      -236.2529271601 -3.04E-01
    15 OT DIIS     0.15E+00    0.0     0.00359712      -236.4125119549 -1.60E-01
    16 OT DIIS     0.15E+00    0.0     0.00296972      -236.5944227496 -1.82E-01
    17 OT DIIS     0.15E+00    0.0     0.00260121      -236.7081993079 -1.14E-01
    18 OT DIIS     0.15E+00    0.0     0.00237166      -236.8000962492 -9.19E-02
    19 OT DIIS     0.15E+00    0.0     0.00224239      -236.8591823096 -5.91E-02
    20 OT DIIS     0.15E+00    0.0     0.00209753      -236.9044587109 -4.53E-02
    21 OT DIIS     0.15E+00    0.4     0.00193837      -236.9805216233 -7.61E-02
    22 OT DIIS     0.15E+00    0.2     0.00167658      -237.0480930457 -6.76E-02
    23 OT DIIS     0.15E+00    0.0     0.00142306      -237.0980797510 -5.00E-02
    24 OT DIIS     0.15E+00    0.0     0.00125354      -237.1317560747 -3.37E-02
    25 OT DIIS     0.15E+00    0.0     0.00107481      -237.1566584184 -2.49E-02
    26 OT DIIS     0.15E+00    0.0     0.00095382      -237.1745698950 -1.79E-02
    27 OT DIIS     0.15E+00    0.0     0.00083216      -237.1918688982 -1.73E-02
    28 OT DIIS     0.15E+00    0.0     0.00080813      -237.1973277182 -5.46E-03
    29 OT DIIS     0.15E+00    0.0     0.00066716      -237.2098538354 -1.25E-02
    30 OT DIIS     0.15E+00    0.0     0.00062101      -237.2164725198 -6.62E-03
    31 OT DIIS     0.15E+00    0.0     0.00053420      -237.2242561252 -7.78E-03
    32 OT DIIS     0.15E+00    0.0     0.00047465      -237.2307597034 -6.50E-03
    33 OT DIIS     0.15E+00    0.0     0.00043709      -237.2344854015 -3.73E-03
    34 OT DIIS     0.15E+00    0.0     0.00040345      -237.2379345249 -3.45E-03
    35 OT DIIS     0.15E+00    0.0     0.00036756      -237.2407186370 -2.78E-03
    36 OT DIIS     0.15E+00    0.0     0.00033603      -237.2445010527 -3.78E-03
    37 OT DIIS     0.15E+00    0.0     0.00031509      -237.2458814617 -1.38E-03
    38 OT DIIS     0.15E+00    0.0     0.00028179      -237.2486799384 -2.80E-03
    39 OT DIIS     0.15E+00    0.0     0.00025261      -237.2509154955 -2.24E-03
    40 OT DIIS     0.15E+00    0.0     0.00023222      -237.2525027404 -1.59E-03
    41 OT DIIS     0.15E+00    0.0     0.00021613      -237.2538846334 -1.38E-03
    42 OT DIIS     0.15E+00    0.0     0.00019933      -237.2551938592 -1.31E-03
    43 OT DIIS     0.15E+00    0.0     0.00018447      -237.2561760994 -9.82E-04
    44 OT DIIS     0.15E+00    0.0     0.00017308      -237.2569075668 -7.31E-04
    45 OT DIIS     0.15E+00    0.0     0.00016317      -237.2576744941 -7.67E-04
    46 OT DIIS     0.15E+00    0.1     0.00015289      -237.2582097847 -5.35E-04
    47 OT DIIS     0.15E+00    0.0     0.00014309      -237.2587893261 -5.80E-04
    48 OT DIIS     0.15E+00    0.0     0.00013589      -237.2592615556 -4.72E-04
    49 OT DIIS     0.15E+00    0.0     0.00012947      -237.2596756737 -4.14E-04
    50 OT DIIS     0.15E+00    0.0     0.00012277      -237.2600934951 -4.18E-04
    51 OT DIIS     0.15E+00    0.0     0.00011694      -237.2604830922 -3.90E-04
    52 OT DIIS     0.15E+00    0.0     0.00011168      -237.2608406349 -3.58E-04
    53 OT DIIS     0.15E+00    0.0     0.00010580      -237.2612234998 -3.83E-04
    54 OT DIIS     0.15E+00    0.0     0.00010121      -237.2614935776 -2.70E-04
    55 OT DIIS     0.15E+00    0.1     0.00009640      -237.2617597965 -2.66E-04
    56 OT DIIS     0.15E+00    0.1     0.00009222      -237.2620537634 -2.94E-04
    57 OT DIIS     0.15E+00    0.2     0.00008848      -237.2623109700 -2.57E-04
    58 OT DIIS     0.15E+00    0.0     0.00008454      -237.2625604877 -2.50E-04
    59 OT DIIS     0.15E+00    0.0     0.00008131      -237.2627650384 -2.05E-04
    60 OT DIIS     0.15E+00    0.0     0.00007766      -237.2630159520 -2.51E-04
    61 OT DIIS     0.15E+00    0.0     0.00007436      -237.2632056245 -1.90E-04
    62 OT DIIS     0.15E+00    0.0     0.00007128      -237.2633980264 -1.92E-04
    63 OT DIIS     0.15E+00    0.0     0.00006824      -237.2635461597 -1.48E-04
    64 OT DIIS     0.15E+00    0.0     0.00006536      -237.2637101933 -1.64E-04
    65 OT DIIS     0.15E+00    0.0     0.00006324      -237.2638274652 -1.17E-04
    66 OT DIIS     0.15E+00    0.0     0.00006133      -237.2639402581 -1.13E-04
    67 OT DIIS     0.15E+00    0.0     0.00005979      -237.2640300044 -8.97E-05
    68 OT DIIS     0.15E+00    0.0     0.00005782      -237.2641572624 -1.27E-04
    69 OT DIIS     0.15E+00    0.0     0.00005650      -237.2642247103 -6.74E-05
    70 OT DIIS     0.15E+00    0.0     0.00005506      -237.2643106881 -8.60E-05
    71 OT DIIS     0.15E+00    0.0     0.00005383      -237.2643806232 -6.99E-05
    72 OT DIIS     0.15E+00    0.0     0.00005232      -237.2644762672 -9.56E-05
    73 OT DIIS     0.15E+00    0.0     0.00005111      -237.2645519742 -7.57E-05
    74 OT DIIS     0.15E+00    0.0     0.00004992      -237.2646331868 -8.12E-05
    75 OT DIIS     0.15E+00    0.0     0.00004887      -237.2647031363 -6.99E-05
    76 OT DIIS     0.15E+00    0.0     0.00004733      -237.2648103377 -1.07E-04
    77 OT DIIS     0.15E+00    0.0     0.00004636      -237.2648771627 -6.68E-05
    78 OT DIIS     0.15E+00    0.0     0.00004498      -237.2649646972 -8.75E-05
    79 OT DIIS     0.15E+00    0.0     0.00004378      -237.2650348072 -7.01E-05
    80 OT DIIS     0.15E+00    0.0     0.00004237      -237.2651201924 -8.54E-05
    81 OT DIIS     0.15E+00    0.0     0.00004130      -237.2651849927 -6.48E-05
    82 OT DIIS     0.15E+00    0.0     0.00004017      -237.2652585523 -7.36E-05
    83 OT DIIS     0.15E+00    0.0     0.00003913      -237.2653225616 -6.40E-05
    84 OT DIIS     0.15E+00    0.0     0.00003770      -237.2654031162 -8.06E-05
    85 OT DIIS     0.15E+00    0.0     0.00003684      -237.2654536132 -5.05E-05
    86 OT DIIS     0.15E+00    0.0     0.00003573      -237.2655130945 -5.95E-05
    87 OT DIIS     0.15E+00    0.0     0.00003475      -237.2655629575 -4.99E-05
    88 OT DIIS     0.15E+00    0.0     0.00003360      -237.2656193624 -5.64E-05
    89 OT DIIS     0.15E+00    0.0     0.00003281      -237.2656571547 -3.78E-05
    90 OT DIIS     0.15E+00    0.0     0.00003207      -237.2656948948 -3.77E-05
    91 OT DIIS     0.15E+00    0.0     0.00003143      -237.2657291912 -3.43E-05
    92 OT DIIS     0.15E+00    0.0     0.00003064      -237.2657663261 -3.71E-05
    93 OT DIIS     0.15E+00    0.0     0.00003014      -237.2657920217 -2.57E-05
    94 OT DIIS     0.15E+00    0.0     0.00002956      -237.2658182700 -2.62E-05
    95 OT DIIS     0.15E+00    0.0     0.00002906      -237.2658403833 -2.21E-05
    96 OT DIIS     0.15E+00    0.0     0.00002851      -237.2658657737 -2.54E-05
    97 OT DIIS     0.15E+00    0.0     0.00002811      -237.2658854547 -1.97E-05
    98 OT DIIS     0.15E+00    0.0     0.00002770      -237.2659059799 -2.05E-05
    99 OT DIIS     0.15E+00    0.0     0.00002732      -237.2659257101 -1.97E-05
   100 OT DIIS     0.15E+00    0.0     0.00002692      -237.2659455663 -1.99E-05
   101 OT DIIS     0.15E+00    0.0     0.00002660      -237.2659634083 -1.78E-05
   102 OT DIIS     0.15E+00    0.0     0.00002624      -237.2659840016 -2.06E-05
   103 OT DIIS     0.15E+00    0.0     0.00002584      -237.2660033508 -1.93E-05
   104 OT DIIS     0.15E+00    0.0     0.00002538      -237.2660265322 -2.32E-05
   105 OT DIIS     0.15E+00    0.0     0.00002503      -237.2660454049 -1.89E-05
   106 OT DIIS     0.15E+00    0.0     0.00002464      -237.2660664897 -2.11E-05
   107 OT DIIS     0.15E+00    0.0     0.00002423      -237.2660895234 -2.30E-05
   108 OT DIIS     0.15E+00    0.0     0.00002378      -237.2661130925 -2.36E-05
   109 OT DIIS     0.15E+00    0.0     0.00002338      -237.2661340664 -2.10E-05
   110 OT DIIS     0.15E+00    0.0     0.00002294      -237.2661578339 -2.38E-05
   111 OT DIIS     0.15E+00    0.0     0.00002247      -237.2661798943 -2.21E-05
   112 OT DIIS     0.15E+00    0.0     0.00002189      -237.2662052372 -2.53E-05
   113 OT DIIS     0.15E+00    0.0     0.00002145      -237.2662254756 -2.02E-05
   114 OT DIIS     0.15E+00    0.0     0.00002100      -237.2662451896 -1.97E-05
   115 OT DIIS     0.15E+00    0.0     0.00002056      -237.2662643245 -1.91E-05
   116 OT DIIS     0.15E+00    0.0     0.00002014      -237.2662823620 -1.80E-05
   117 OT DIIS     0.15E+00    0.0     0.00001976      -237.2662982582 -1.59E-05
   118 OT DIIS     0.15E+00    0.1     0.00001935      -237.2663150883 -1.68E-05
   119 OT DIIS     0.15E+00    0.0     0.00001896      -237.2663286720 -1.36E-05
   120 OT DIIS     0.15E+00    0.0     0.00001853      -237.2663426910 -1.40E-05
   121 OT DIIS     0.15E+00    0.0     0.00001824      -237.2663536588 -1.10E-05
   122 OT DIIS     0.15E+00    0.0     0.00001795      -237.2663642004 -1.05E-05
   123 OT DIIS     0.15E+00    0.0     0.00001766      -237.2663741929 -9.99E-06
   124 OT DIIS     0.15E+00    0.0     0.00001741      -237.2663832117 -9.02E-06
   125 OT DIIS     0.15E+00    0.0     0.00001720      -237.2663908359 -7.62E-06
   126 OT DIIS     0.15E+00    0.0     0.00001698      -237.2663994003 -8.56E-06
   127 OT DIIS     0.15E+00    0.0     0.00001676      -237.2664067341 -7.33E-06
   128 OT DIIS     0.15E+00    0.0     0.00001652      -237.2664145887 -7.85E-06
   129 OT DIIS     0.15E+00    0.0     0.00001634      -237.2664210175 -6.43E-06
   130 OT DIIS     0.15E+00    0.0     0.00001617      -237.2664277633 -6.75E-06
   131 OT DIIS     0.15E+00    0.0     0.00001599      -237.2664343293 -6.57E-06
   132 OT DIIS     0.15E+00    0.0     0.00001582      -237.2664416578 -7.33E-06
   133 OT DIIS     0.15E+00    0.0     0.00001566      -237.2664480935 -6.44E-06
   134 OT DIIS     0.15E+00    0.0     0.00001547      -237.2664557660 -7.67E-06
   135 OT DIIS     0.15E+00    0.0     0.00001529      -237.2664624361 -6.67E-06
   136 OT DIIS     0.15E+00    0.0     0.00001508      -237.2664700900 -7.65E-06
   137 OT DIIS     0.15E+00    0.0     0.00001491      -237.2664768864 -6.80E-06
   138 OT DIIS     0.15E+00    0.0     0.00001471      -237.2664848190 -7.93E-06
   139 OT DIIS     0.15E+00    0.0     0.00001452      -237.2664915712 -6.75E-06
   140 OT DIIS     0.15E+00    0.0     0.00001433      -237.2664992732 -7.70E-06
   141 OT DIIS     0.15E+00    0.0     0.00001416      -237.2665060643 -6.79E-06
   142 OT DIIS     0.15E+00    0.0     0.00001395      -237.2665141709 -8.11E-06
   143 OT DIIS     0.15E+00    0.0     0.00001374      -237.2665207973 -6.63E-06
   144 OT DIIS     0.15E+00    0.0     0.00001352      -237.2665279729 -7.18E-06
   145 OT DIIS     0.15E+00    0.0     0.00001335      -237.2665336173 -5.64E-06
   146 OT DIIS     0.15E+00    0.0     0.00001316      -237.2665403666 -6.75E-06
   147 OT DIIS     0.15E+00    0.0     0.00001299      -237.2665456062 -5.24E-06
   148 OT DIIS     0.15E+00    0.0     0.00001281      -237.2665514421 -5.84E-06
   149 OT DIIS     0.15E+00    0.0     0.00001268      -237.2665560319 -4.59E-06
   150 OT DIIS     0.15E+00    0.0     0.00001251      -237.2665611769 -5.14E-06
   151 OT DIIS     0.15E+00    0.0     0.00001237      -237.2665652614 -4.08E-06
   152 OT DIIS     0.15E+00    0.0     0.00001221      -237.2665698344 -4.57E-06
   153 OT DIIS     0.15E+00    0.0     0.00001209      -237.2665731793 -3.34E-06
   154 OT DIIS     0.15E+00    0.0     0.00001196      -237.2665772807 -4.10E-06
   155 OT DIIS     0.15E+00    0.0     0.00001186      -237.2665803574 -3.08E-06
   156 OT DIIS     0.15E+00    0.0     0.00001174      -237.2665840766 -3.72E-06
   157 OT DIIS     0.15E+00    0.0     0.00001165      -237.2665873602 -3.28E-06
   158 OT DIIS     0.15E+00    0.0     0.00001153      -237.2665911571 -3.80E-06
   159 OT DIIS     0.15E+00    0.0     0.00001142      -237.2665941654 -3.01E-06
   160 OT DIIS     0.15E+00    0.0     0.00001131      -237.2665979185 -3.75E-06
   161 OT DIIS     0.15E+00    0.0     0.00001121      -237.2666010526 -3.13E-06
   162 OT DIIS     0.15E+00    0.0     0.00001109      -237.2666051031 -4.05E-06
   163 OT DIIS     0.15E+00    0.0     0.00001099      -237.2666084210 -3.32E-06
   164 OT DIIS     0.15E+00    0.0     0.00001087      -237.2666123549 -3.93E-06
   165 OT DIIS     0.15E+00    0.0     0.00001078      -237.2666161174 -3.76E-06
   166 OT DIIS     0.15E+00    0.0     0.00001064      -237.2666207020 -4.58E-06
   167 OT DIIS     0.15E+00    0.0     0.00001052      -237.2666243348 -3.63E-06
   168 OT DIIS     0.15E+00    0.0     0.00001038      -237.2666288522 -4.52E-06
   169 OT DIIS     0.15E+00    0.0     0.00001026      -237.2666325343 -3.68E-06
   170 OT DIIS     0.15E+00    0.0     0.00001012      -237.2666368143 -4.28E-06
   171 OT DIIS     0.15E+00    0.0     0.00001001      -237.2666403565 -3.54E-06
   172 OT DIIS     0.15E+00    0.0     0.00000988      -237.2666442871 -3.93E-06

  *** SCF run converged in   172 steps ***


  Core-core repulsion energy [eV]:                          70309.91179873071087
  Core Hamiltonian energy [eV]:                            -10018.95331332087699
  Two-electron integral energy [eV]:                      -133494.62443892689771
  Electronic energy [eV]:                                  -76766.26553278433857

  Total energy [eV]:                                        -6456.35373405362498

  Atomic reference energy [eV]:                              6422.19856796472595
  Heat of formation [kcal/mol]:                              -787.63690370383927


 POPULATION ANALYSIS

  # Atom   Element   Kind        Atomic population                    Net charge
       1      Ca        1                 1.623325                     62.376675
       2      Ca        1                 1.556284                     62.443716
       3      Ca        1                 1.644415                     62.355585
       4      Ca        1                 1.618845                     62.381155
       5      Ca        1                 1.589459                     62.410541
       6      Ca        1                 1.653486                     62.346514
       7      Ca        1                 1.559053                     62.440947
       8      Ca        1                 1.526359                     62.473641
       9      Ca        1                 1.484558                     62.515442
      10      Ca        1                 1.628940                     62.371060
      11      Ca        1                 1.670985                     62.329015
      12      Ca        1                 1.508341                     62.491659
      13      Ca        1                 1.573154                     62.426846
      14      Ca        1                 1.633767                     62.366233
      15      Ca        1                 1.556817                     62.443183
      16      Ca        1                 1.597016                     62.402984
      17      Ca        1                 1.632593                     62.367407
      18      Ca        1                 1.557076                     62.442924
      19      Ca        1                 1.624957                     62.375043
      20      Ca        1                 1.623538                     62.376462
      21      Ca        1                 1.489921                     62.510079
      22      Ca        1                 1.532685                     62.467315
      23      Ca        1                 1.686010                     62.313990
      24      Ca        1                 1.598271                     62.401729
      25      Ca        1                 1.606604                     62.393396
      26      Ca        1                 1.523095                     62.476905
      27      Ca        1                 1.492737                     62.507263
      28      Ca        1                 1.620740                     62.379260
      29      Ca        1                 1.504733                     62.495267
      30      Ca        1                 1.673819                     62.326181
      31      Ca        1                 1.627735                     62.372265
      32      Ca        1                 1.598360                     62.401640
      33      Ca        1                 1.619303                     62.380697
      34      Se        2                 6.375047                    185.624953
      35      Se        2                 6.442396                    185.557604
      36      Se        2                 6.397947                    185.602053
      37      Se        2                 6.330724                    185.669276
      38      Se        2                 6.125855                    185.874145
      39      Se        2                 6.339196                    185.660804
      40      Se        2                 6.261927                    185.738073
      41      Se        2                 6.396513                    185.603487
      42      Se        2                 6.489947                    185.510053
      43      Se        2                 6.258842                    185.741158
      44      Se        2                 6.204841                    185.795159
      45      Se        2                 6.731424                    185.268576
      46      Se        2                 6.498025                    185.501975
      47      Se        2                 6.614939                    185.385061
      48      Se        2                 6.502677                    185.497323
      49      Se        2                 6.215895                    185.784105
      50      Se        2                 6.442225                    185.557775
      51      Se        2                 6.560821                    185.439179
      52      Se        2                 6.699963                    185.300037
      53      Se        2                 6.432610                    185.567390
      54      Se        2                 6.508847                    185.491153
      55      Se        2                 6.533640                    185.466360
      56      Se        2                 6.435996                    185.564004
      57      Se        2                 6.236865                    185.763135
      58      Se        2                 6.267806                    185.732194
      59      Se        2                 6.508484                    185.491516
      60      Se        2                 6.367967                    185.632033
      61      Se        2                 6.382817                    185.617183
      62      Se        2                 6.351061                    185.648939
      63      Se        2                 6.695086                    185.304914
      64      Se        2                 6.468338                    185.531662
      65      Se        2                 6.257522                    185.742478
      66      Se        2                 6.226776                    185.773224
 # Total charge                         264.000000                   8184.000000


 *** WARNING in qs_scf_post_se.F:584 :: Hirshfeld charges not available ***
 *** for semi-empirical calculations!                                   ***


 ENERGY| Total FORCE_EVAL ( QS ) energy (a.u.):             -237.266644287112740


 -------------------------------------------------------------------------------
 -                                                                             -
 -                                DBCSR STATISTICS                             -
 -                                                                             -
 -------------------------------------------------------------------------------
 COUNTER                                    TOTAL       BLAS       SMM       ACC
 flops    36 x     4 x     4              1776384     100.0%      0.0%      0.0%
 flops    72 x     4 x     4              1976832     100.0%      0.0%      0.0%
 flops     4 x    32 x    32              2162688     100.0%      0.0%      0.0%
 flops    32 x     4 x     4              4737024     100.0%      0.0%      0.0%
 flops    64 x     4 x     4              5271552     100.0%      0.0%      0.0%
 flops    36 x     4 x    36             14245632     100.0%      0.0%      0.0%
 flops    32 x     4 x    36             37988352     100.0%      0.0%      0.0%
 flops    36 x    32 x     4             56844288     100.0%      0.0%      0.0%
 flops    72 x    32 x     4             63258624     100.0%      0.0%      0.0%
 flops    72 x     4 x    32             63258624     100.0%      0.0%      0.0%
 flops    36 x     4 x    32             94832640     100.0%      0.0%      0.0%
 flops     4 x     4 x     4            145428096     100.0%      0.0%      0.0%
 flops    32 x    32 x     4            151584768     100.0%      0.0%      0.0%
 flops    64 x     4 x    32            168689664     100.0%      0.0%      0.0%
 flops    64 x    32 x     4            168689664     100.0%      0.0%      0.0%
 flops    32 x     4 x    32            252887040     100.0%      0.0%      0.0%
 flops    36 x    32 x    36            455860224     100.0%      0.0%      0.0%
 flops    32 x    32 x    36           1215627264     100.0%      0.0%      0.0%
 flops     4 x     4 x    32           1566732288     100.0%      0.0%      0.0%
 flops    72 x    32 x    32           2024275968     100.0%      0.0%      0.0%
 flops    36 x    32 x    32           3034644480     100.0%      0.0%      0.0%
 flops     4 x    32 x     4           3086696448     100.0%      0.0%      0.0%
 flops    64 x    32 x    32           5398069248     100.0%      0.0%      0.0%
 flops    32 x    32 x    32           8092385280     100.0%      0.0%      0.0%
 flops inhomo. stacks                           0       0.0%      0.0%      0.0%
 flops total                        26.107923E+09     100.0%      0.0%      0.0%
 flops max/rank                      1.684362E+09     100.0%      0.0%      0.0%
 matmuls inhomo. stacks                         0       0.0%      0.0%      0.0%
 matmuls total                            6030705     100.0%      0.0%      0.0%
 number of processed stacks                405300     100.0%      0.0%      0.0%
 average stack size                                    14.9       0.0       0.0
 marketing flops                    27.690979E+09
 -------------------------------------------------------------------------------
 # multiplications                           3435
 max memory usage/rank              62.857216E+06
 # max total images/rank                        2
 # max 3D layers                                1
 # MPI messages exchanged                 1428960
 MPI messages size (bytes):
  total size                         7.402093E+09
  min size                           0.000000E+00
  max size                          20.736000E+03
  average size                       5.180056E+03
 MPI breakdown and total messages size (bytes):
             size <=      128              579188                   921984
       128 < size <=     8192              560142               3515099136
      8192 < size <=    32768              289630               3886071552
     32768 < size <=   131072                   0                        0
    131072 < size <=  4194304                   0                        0
   4194304 < size <= 16777216                   0                        0
  16777216 < size                               0                        0
 -------------------------------------------------------------------------------

 *** WARNING in dbcsr_mm.F:295 :: Using a non-square number of MPI ranks ***
 *** might lead to poor performance. Used ranks: 32 Suggested: 36 64     ***

 -------------------------------------------------------------------------------
 -                                                                             -
 -                      DBCSR MESSAGE PASSING PERFORMANCE                      -
 -                                                                             -
 -------------------------------------------------------------------------------
 ROUTINE             CALLS      AVE VOLUME [Bytes]
 MP_Group              187
 MP_Bcast               25                     12.
 MP_Allreduce        19451                     92.
 MP_Alltoall         11552                   3252.
 MP_Wait            219840
 MP_ISend           106826                   3223.
 MP_IRecv           106826                   2740.
 MP_Memory          164884
 -------------------------------------------------------------------------------

 MEMORY| Estimated peak process memory [MiB]                                  61

 -------------------------------------------------------------------------------
 ----                             MULTIGRID INFO                            ----
 -------------------------------------------------------------------------------
 total grid count     :         19200              cutoff [a.u.]            1.00

 -------------------------------------------------------------------------------
 -                                                                             -
 -                         MESSAGE PASSING PERFORMANCE                         -
 -                                                                             -
 -------------------------------------------------------------------------------

 ROUTINE             CALLS      AVE VOLUME [Bytes]
 MP_Group                1
 MP_Bcast            11363                    659.
 MP_Allreduce        28611                    158.
 MP_Sync               173
 MP_comm_split         172
 MP_Recv                63                  35904.
 -------------------------------------------------------------------------------


 -------------------------------------------------------------------------------
 -                                                                             -
 -                           R E F E R E N C E S                               -
 -                                                                             -
 -------------------------------------------------------------------------------
 
 CP2K version 7.1, the CP2K developers group (2019).
 CP2K is freely available from https://www.cp2k.org/ .

 Schuett, Ole; Messmer, Peter; Hutter, Juerg; VandeVondele, Joost. 
 Electronic Structure Calculations on Graphics Processing Units, John
 Wiley & Sons, Ltd, 173-190 (2016). 
 GPU-Accelerated Sparse Matrix-Matrix Multiplication for
 Linear Scaling Density Functional Theory.
 https://dx.doi.org/10.1002/9781118670712.ch8

 Borstnik, U; VandeVondele, J; Weber, V; Hutter, J. 
 PARALLEL COMPUTING, 40 (5-6), 47-58 (2014). 
 Sparse matrix multiplication: The distributed block-compressed sparse
 row library.
 https://dx.doi.org/10.1016/j.parco.2014.03.012

 Hutter, J; Iannuzzi, M; Schiffmann, F; VandeVondele, J. 
 WIREs Comput Mol Sci., 4 (1), 15-25 (2014). 
 CP2K: atomistic simulations of condensed matter systems.
 https://dx.doi.org/10.1002/wcms.1159

 Frigo, M; Johnson, SG. 
 PROCEEDINGS OF THE IEEE, 93 (2), 216-231 (2005). 
 The design and implementation of FFTW3.
 https://dx.doi.org/10.1109/JPROC.2004.840301

 VandeVondele, J; Hutter, J. 
 JOURNAL OF CHEMICAL PHYSICS, 118 (10), 4365-4369 (2003). 
 An efficient orbital transformation method for electronic structure
 calculations.
 https://dx.doi.org/10.1063/1.1543154

 THIEL, W; VOITYUK, AA. 
 THEORETICA CHIMICA ACTA, 81 (6), 391-404 (1992). 
 EXTENSION OF THE MNDO FORMALISM TO D-ORBITALS - INTEGRAL APPROXIMATIONS
 AND PRELIMINARY NUMERICAL RESULTS.
 https://dx.doi.org/10.1007/BF01134863

 DEWAR, MJS; THIEL, W. 
 JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 99 (15), 4899-4907 (1977). 
 GROUND-STATES OF MOLECULES .38. MNDO METHOD - APPROXIMATIONS AND
 PARAMETERS.
 https://dx.doi.org/10.1021/ja00457a004


 -------------------------------------------------------------------------------
 -                                                                             -
 -                                T I M I N G                                  -
 -                                                                             -
 -------------------------------------------------------------------------------
 SUBROUTINE                       CALLS  ASD         SELF TIME        TOTAL TIME
                                MAXIMUM       AVERAGE  MAXIMUM  AVERAGE  MAXIMUM
 CP2K                                 1  1.0    0.011    0.018   13.243   13.245
 qs_energies                          1  2.0    0.001    0.001   13.157   13.168
 scf_env_do_scf                       1  3.0    0.000    0.000   13.114   13.115
 scf_env_do_scf_inner_loop          172  4.0    0.019    0.461   12.845   13.104
 write_mo_set_to_restart            172  5.0    0.133    4.172    4.185    6.203
 qs_scf_new_mos                     172  5.0    0.001    0.001    5.917    5.960
 qs_scf_loop_do_ot                  172  6.0    0.001    0.001    5.916    5.959
 ot_scf_mini                        172  7.0    0.002    0.003    5.678    5.713
 write_mo_set_low                     9  6.0    0.000    0.001    4.046    5.325
 cp_fm_write_unformatted              9  7.0    3.894    3.955    4.046    5.325
 dbcsr_multiply_generic            3435 10.1    0.113    0.128    4.106    4.125
 qs_ks_update_qs_env                173  5.0    0.001    0.001    2.715    2.935
 ot_mini                            172  8.0    0.001    0.001    2.759    2.804
 qs_ot_get_derivative               172  9.0    0.001    0.001    2.630    2.666
 mp_sum_d                          8659 11.1    2.306    2.552    2.306    2.552
 dbcsr_dot_sd                      2215  9.6    0.011    0.019    2.292    2.530
 qs_ot_get_p                        173  8.0    0.001    0.001    2.490    2.515
 evaluate_core_matrix_traces        172  6.0    0.000    0.000    2.215    2.401
 calculate_ptrace_kp                172  7.0    0.000    0.000    2.215    2.401
 qs_ot_get_derivative_diag          171 10.0    0.003    0.003    1.993    2.030
 multiply_cannon                   3435 11.1    0.333    0.404    1.737    1.829
 qs_ot_p2m_diag                     172  9.0    0.015    0.035    1.608    1.633
 make_m2s                          6870 11.1    0.094    0.106    1.474    1.514
 mp_send_dv                           9  8.0    0.152    1.370    0.152    1.370
 cp_dbcsr_syevd                     172 10.0    0.012    0.013    1.220    1.223
 make_images                       6870 12.1    0.126    0.146    1.077    1.174
 cp_fm_syevd                        172 11.0    0.001    0.001    1.096    1.099
 cp_fm_redistribute_end             172 12.0    0.874    0.993    0.882    0.996
 cp_fm_syevd_base                   172 12.0    0.112    0.896    0.112    0.896
 mp_waitall_1                    219840 13.7    0.580    0.819    0.580    0.819
 multiply_cannon_metrocomm3       27480 12.1    0.071    0.080    0.518    0.797
 arnoldi_extremal                   173  9.0    0.002    0.002    0.657    0.685
 arnoldi_normal_ev                  173 10.0    0.003    0.003    0.655    0.683
 make_images_sizes                 6870 13.1    0.006    0.007    0.437    0.650
 mp_alltoall_i44                   6870 14.1    0.431    0.644    0.431    0.644
 mp_sum_l                         16851 11.2    0.402    0.635    0.402    0.635
 build_subspace                     173 11.0    0.020    0.023    0.553    0.572
 rebuild_ks_matrix                  172  6.0    0.000    0.000    0.499    0.539
 build_se_fock_matrix               172  7.0    0.002    0.003    0.499    0.538
 dbcsr_matrix_vector_mult          5505 12.0    0.037    0.043    0.401    0.444
 qs_ot_get_orbitals                 172  8.0    0.000    0.001    0.426    0.443
 copy_dbcsr_to_fm                   186 10.7    0.002    0.002    0.350    0.403
 mp_alltoall_i22                    722 12.8    0.293    0.357    0.293    0.357
 multiply_cannon_multrec          27480 12.1    0.170    0.336    0.179    0.345
 dbcsr_make_images_dense           6520 12.3    0.059    0.067    0.260    0.334
 mp_sum_dv                        22016 13.2    0.293    0.328    0.293    0.328
 dbcsr_desymmetrize_deep            186 11.7    0.004    0.004    0.276    0.328
 make_images_data                  6870 13.1    0.069    0.091    0.232    0.291
 dbcsr_create_new                 50069 12.7    0.121    0.138    0.251    0.286
 mp_allgather_i34                  3435 12.1    0.159    0.282    0.159    0.282
 -------------------------------------------------------------------------------

 The number of warnings for this run is : 2
 
 -------------------------------------------------------------------------------
  **** **** ******  **  PROGRAM ENDED AT                 2020-09-28 07:22:39.022
 ***** ** ***  *** **   PROGRAM RAN ON            cpn-u28-38.cbls.ccr.buffalo.ed
 **    ****   ******    PROGRAM RAN BY                                  bsmith24
 ***** **    ** ** **   PROGRAM PROCESS ID                                 44895
  **** **  *******  **  PROGRAM STOPPED IN /panfs/panfs.cbls.ccr.buffalo.edu/scr
                                           atch/grp-alexeyak/brendan/cp2k_md_rep
                                           ository/mndod_cd33se33
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