[CP2K-user] SCF run NOT converged with geometry optimization

Travis polla... at gmail.com
Sat Sep 21 14:36:06 UTC 2019


Hi,

The first thing that comes to mind that would cause issues here is applying 
DFT+U to metallic Pt. I'd recommend trying your calculation without DFT+U 
first (TiO2 still has a sizable enough band gap with GGAs, no +U). Then 
reintroduce DFT+U to Ti and O, if you need to. Since literature values are 
almost entirely related to VASP potentials, you should first run 
calculations on bulk TiO2 to match the band gap, sampling several U-J 
values.

-T


On Wednesday, September 18, 2019 at 12:56:57 PM UTC-4, Wei Zhang wrote:
>
> [image: capture(11).png]
> Hi All,
>
> I have been performing Geometry Optimizations for my model with the input 
> file wrote by me. The model is Pt12 cluster supported by TiO2(0 0 1)-4x4x1 
> and I merged the two parts as a intergated model by crystalmaker software 
> into a *.xyz file. To ensure the calculation accuration I employed the 
> DFT+U method in the program. The cp2k script works well but it finishes 
> without convergence and I don't know what reason casued. I will appreciate 
> if someone could suggest whether everything is OK with optimization. The 
> key information is as follows.
>
>   Leaving inner SCF loop after reaching  1000 steps.
>
>
>   Electronic density on regular grids:      -1745.9999999998        
> 0.0000000002
>   Core density on regular grids:             1745.9999999994       
> -0.0000000006
>   Total charge density on r-space grids:       -0.0000000004
>   Total charge density g-space grids:          -0.0000000004
>
>   Overlap energy of the core charge distribution:               
> 0.00000001735215
>   Self energy of the core charge distribution:             
> -14308.93845509827406
>   Core Hamiltonian energy:                                   
> 3711.19302865196914
>   Hartree energy:                                            
> 4442.24204301130521
>   Exchange-correlation energy:                              
> -1051.94297009336083
>   Dispersion energy:                                           
> -0.97264014080053
>   Electronic entropic energy:                                  
> -0.01038727948234
>   Fermi energy:                                                
> -0.01126208822328
>
>   DFT+U energy:                                                 
> 3.80737051668434
>
>   Total energy:                                             
> -7204.62436606955271
>
>  *** WARNING in qs_scf.F:542 :: SCF run NOT converged ***
>
>
> !-----------------------------------------------------------------------------!
>                      Mulliken Population Analysis
>
>  #  Atom  Element  Kind  Atomic population                           Net 
> charge
>        1     O        1          6.647536                             
> -0.647536
>        2     O        1          6.699390                             
> -0.699390
>        3     O        1          6.686023                             
> -0.686023
>        4     O        1          6.048950                             
> -0.048950
>        5     O        1          6.708597                             
> -0.708597
>        6     O        1          6.755855                             
> -0.755855
>        7     O        1          6.717386                             
> -0.717386
>        8     O        1          6.372221                             
> -0.372221
>        9     O        1          6.648122                             
> -0.648122
>       10     O        1          6.693735                             
> -0.693735
>       11     O        1          6.694745                             
> -0.694745
>       12     O        1          6.014144                             
> -0.014144
>       13     O        1          6.715172                             
> -0.715172
>       14     O        1          6.758861                             
> -0.758861
>       15     O        1          6.717428                             
> -0.717428
>       16     O        1          6.371743                             
> -0.371743
>       17     O        1          6.355334                             
> -0.355334
>       18     O        1          6.717507                             
> -0.717507
>       19     O        1          6.052674                             
> -0.052674
>       20     O        1          6.691813                             
> -0.691813
>       21     O        1          6.699650                             
> -0.699650
>       22     O        1          6.642763                             
> -0.642763
>       23     O        1          6.759133                             
> -0.759133
>       24     O        1          6.713516                             
> -0.713516
>       25     O        1          6.640317                             
> -0.640317
>       26     O        1          6.692880                             
> -0.692880
>       27     O        1          6.689746                             
> -0.689746
>       28     O        1          6.012526                             
> -0.012526
>       29     O        1          6.716405                             
> -0.716405
>       30     O        1          6.762208                             
> -0.762208
>       31     O        1          6.717409                             
> -0.717409
>       32     O        1          6.353842                             
> -0.353842
>       33     O        1          6.722215                             
> -0.722215
>       34     O        1          6.700366                             
> -0.700366
>       35     O        1          6.681604                             
> -0.681604
>       36     O        1          6.110374                             
> -0.110374
>       37     O        1          6.708581                             
> -0.708581
>       38     O        1          6.777432                             
> -0.777432
>       39     O        1          6.716137                             
> -0.716137
>       40     O        1          6.400911                             
> -0.400911
>       41     O        1          6.777656                             
> -0.777656
>       42     O        1          6.708100                             
> -0.708100
>       43     O        1          6.698338                             
> -0.698338
>       44     O        1          6.724455                             
> -0.724455
>       45     O        1          6.279041                             
> -0.279041
>       46     O        1          6.683128                             
> -0.683128
>       47     O        1          6.523876                             
> -0.523876
>       48     O        1          6.715990                             
> -0.715990
>       49     O        1          6.641322                             
> -0.641322
>       50     O        1          6.695875                             
> -0.695875
>       51     O        1          6.685503                             
> -0.685503
>       52     O        1          6.089288                             
> -0.089288
>       53     O        1          6.715802                             
> -0.715802
>       54     O        1          6.775039                             
> -0.775039
>       55     O        1          6.716099                             
> -0.716099
>       56     O        1          6.400813                             
> -0.400813
>       57     O        1          6.775035                             
> -0.775035
>       58     O        1          6.714443                             
> -0.714443
>       59     O        1          6.392979                             
> -0.392979
>       60     O        1          6.716244                             
> -0.716244
>       61     O        1          6.693999                             
> -0.693999
>       62     O        1          6.647102                             
> -0.647102
>       63     O        1          6.138017                             
> -0.138017
>       64     O        1          6.684038                             
> -0.684038
>       65     O        1          6.702326                             
> -0.702326
>       66     O        1          6.631320                             
> -0.631320
>       67     O        1          6.453846                             
> -0.453846
>       68     O        1          6.688062                             
> -0.688062
>       69     O        1          6.760528                             
> -0.760528
>       70     O        1          6.712922                             
> -0.712922
>       71     O        1          6.507566                             
> -0.507566
>       72     O        1          6.716406                             
> -0.716406
>       73     O        1          6.712399                             
> -0.712399
>       74     O        1          6.773307                             
> -0.773307
>       75     O        1          6.716229                             
> -0.716229
>       76     O        1          6.551406                             
> -0.551406
>       77     O        1          6.627942                             
> -0.627942
>       78     O        1          6.700980                             
> -0.700980
>       79     O        1          6.691165                             
> -0.691165
>       80     O        1          6.277681                             
> -0.277681
>       81     O        1          6.663558                             
> -0.663558
>       82     O        1          6.695582                             
> -0.695582
>       83     O        1          6.691744                             
> -0.691744
>       84     O        1          6.129888                             
> -0.129888
>       85     O        1          6.717583                             
> -0.717583
>       86     O        1          6.772714                             
> -0.772714
>       87     O        1          6.717397                             
> -0.717397
>       88     O        1          6.385670                             
> -0.385670
>       89     O        1          6.760881                             
> -0.760881
>       90     O        1          6.715249                             
> -0.715249
>       91     O        1          6.696550                             
> -0.696550
>       92     O        1          6.642593                             
> -0.642593
>       93     O        1          6.417455                             
> -0.417455
>       94     O        1          6.683856                             
> -0.683856
>       95     O        1          6.511376                             
> -0.511376
>       96     O        1          6.717164                             
> -0.717164
>       97     O        1          6.651671                             
> -0.651671
>       98     O        1          6.699698                             
> -0.699698
>       99     O        1          6.678670                             
> -0.678670
>      100     O        1          6.108045                             
> -0.108045
>      101     O        1          6.706662                             
> -0.706662
>      102     O        1          6.772712                             
> -0.772712
>      103     O        1          6.715089                             
> -0.715089
>      104     O        1          6.464953                             
> -0.464953
>      105     O        1          6.661824                             
> -0.661824
>      106     O        1          6.697325                             
> -0.697325
>      107     O        1          6.682167                             
> -0.682167
>      108     O        1          6.425999                             
> -0.425999
>      109     O        1          6.711753                             
> -0.711753
>      110     O        1          6.758328                             
> -0.758328
>      111     O        1          6.715837                             
> -0.715837
>      112     O        1          6.573485                             
> -0.573485
>      113     O        1          6.474035                             
> -0.474035
>      114     O        1          6.715061                             
> -0.715061
>      115     O        1          6.277308                             
> -0.277308
>      116     O        1          6.680426                             
> -0.680426
>      117     O        1          6.702047                             
> -0.702047
>      118     O        1          6.642170                             
> -0.642170
>      119     O        1          6.788633                             
> -0.788633
>      120     O        1          6.711059                             
> -0.711059
>      121     O        1          6.665956                             
> -0.665956
>      122     O        1          6.696881                             
> -0.696881
>      123     O        1          6.685969                             
> -0.685969
>      124     O        1          6.697529                             
> -0.697529
>      125     O        1          6.774744                             
> -0.774744
>      126     O        1          6.717788                             
> -0.717788
>      127     O        1          6.603342                             
> -0.603342
>      128     Pt       2         17.932464                              
> 0.067536
>      129     Pt       2         18.384344                             
> -0.384344
>      130     Pt       2         18.420895                             
> -0.420895
>      131     Pt       2         18.483125                             
> -0.483125
>      132     Pt       2         18.216916                             
> -0.216916
>      133     Pt       2         17.922049                              
> 0.077951
>      134     Pt       2         18.364803                             
> -0.364803
>      135     Pt       2         18.153541                             
> -0.153541
>      136     Pt       2         18.323463                             
> -0.323463
>      137     Pt       2         18.348845                             
> -0.348845
>      138     Pt       2         17.982313                              
> 0.017687
>      139     Pt       2         18.064956                             
> -0.064956
>      140     Ti       3         11.333292                              
> 0.666708
>      141     Ti       3         10.588678                              
> 1.411322
>      142     Ti       3         10.573930                              
> 1.426070
>      143     Ti       3         10.657548                              
> 1.342452
>      144     Ti       3         11.312884                              
> 0.687116
>      145     Ti       3         10.588781                              
> 1.411219
>      146     Ti       3         10.563197                              
> 1.436803
>      147     Ti       3         10.662379                              
> 1.337621
>      148     Ti       3         10.669837                              
> 1.330163
>      149     Ti       3         10.576066                              
> 1.423934
>      150     Ti       3         10.585444                              
> 1.414556
>      151     Ti       3         11.358567                              
> 0.641433
>      152     Ti       3         11.314881                              
> 0.685119
>      153     Ti       3         10.587551                              
> 1.412449
>      154     Ti       3         10.648970                              
> 1.351030
>      155     Ti       3         10.564381                              
> 1.435619
>      156     Ti       3         10.593438                              
> 1.406562
>      157     Ti       3         11.165921                              
> 0.834079
>      158     Ti       3         10.576064                              
> 1.423936
>      159     Ti       3         10.657047                              
> 1.342953
>      160     Ti       3         11.376394                              
> 0.623606
>      161     Ti       3         10.593639                              
> 1.406361
>      162     Ti       3         10.563146                              
> 1.436854
>      163     Ti       3         10.655596                              
> 1.344404
>      164     Ti       3         10.672501                              
> 1.327499
>      165     Ti       3         10.577818                              
> 1.422182
>      166     Ti       3         10.582850                              
> 1.417150
>      167     Ti       3         11.383427                              
> 0.616573
>      168     Ti       3         11.331238                              
> 0.668762
>      169     Ti       3         10.588131                              
> 1.411869
>      170     Ti       3         10.575604                              
> 1.424396
>      171     Ti       3         10.657397                              
> 1.342603
>      172     Ti       3         10.661210                              
> 1.338790
>      173     Ti       3         10.569331                              
> 1.430669
>      174     Ti       3         10.585850                              
> 1.414150
>      175     Ti       3         11.224987                              
> 0.775013
>      176     Ti       3         10.568649                              
> 1.431351
>      177     Ti       3         10.658622                              
> 1.341378
>      178     Ti       3         11.262913                              
> 0.737087
>      179     Ti       3         10.593590                              
> 1.406410
>      180     Ti       3         10.587723                              
> 1.412277
>      181     Ti       3         11.278077                              
> 0.721923
>      182     Ti       3         10.651909                              
> 1.348091
>      183     Ti       3         10.565361                              
> 1.434639
>      184     Ti       3         10.599790                              
> 1.400210
>      185     Ti       3         10.594140                              
> 1.405860
>      186     Ti       3         10.553813                              
> 1.446187
>      187     Ti       3         10.636844                              
> 1.363156
>      188     Ti       3         10.659152                              
> 1.340848
>      189     Ti       3         10.569862                              
> 1.430138
>      190     Ti       3         10.575894                              
> 1.424106
>      191     Ti       3         11.228467                              
> 0.771533
>      192     Ti       3         10.579788                              
> 1.420212
>      193     Ti       3         10.625913                              
> 1.374087
>      194     Ti       3         10.588002                              
> 1.411998
>      195     Ti       3         11.388023                              
> 0.611977
>      196     Ti       3         10.671178                              
> 1.328822
>      197     Ti       3         10.577849                              
> 1.422151
>      198     Ti       3         10.361223                              
> 1.638777
>      199     Ti       3         10.582967                              
> 1.417033
>      200     Ti       3         10.600490                              
> 1.399510
>      201     Ti       3         10.574448                              
> 1.425552
>      202     Ti       3         10.566985                              
> 1.433015
>      203     Ti       3         10.644698                              
> 1.355302
>  # Total charge                           1746.000000                  
> 0.000000
>
>
>  !-----------------------------------------------------------------------------!
>
>
>  !-----------------------------------------------------------------------------!
>                            Hirshfeld Charges
>
>   #Atom  Element  Kind  Ref Charge     Population                    Net 
> charge
>       1       O      1       6.000          5.511                         
> 0.489
>       2       O      1       6.000          5.539                         
> 0.461
>       3       O      1       6.000          5.540                         
> 0.460
>       4       O      1       6.000          5.583                         
> 0.417
>       5       O      1       6.000          5.589                         
> 0.411
>       6       O      1       6.000          5.540                         
> 0.460
>       7       O      1       6.000          5.574                         
> 0.426
>       8       O      1       6.000          5.492                         
> 0.508
>       9       O      1       6.000          5.512                         
> 0.488
>      10       O      1       6.000          5.529                         
> 0.471
>      11       O      1       6.000          5.546                         
> 0.454
>      12       O      1       6.000          5.550                         
> 0.450
>      13       O      1       6.000          5.598                         
> 0.402
>      14       O      1       6.000          5.546                         
> 0.454
>      15       O      1       6.000          5.573                         
> 0.427
>      16       O      1       6.000          5.487                         
> 0.513
>      17       O      1       6.000          5.485                         
> 0.515
>      18       O      1       6.000          5.575                         
> 0.425
>      19       O      1       6.000          5.591                         
> 0.409
>      20       O      1       6.000          5.547                         
> 0.453
>      21       O      1       6.000          5.544                         
> 0.456
>      22       O      1       6.000          5.509                         
> 0.491
>      23       O      1       6.000          5.547                         
> 0.453
>      24       O      1       6.000          5.592                         
> 0.408
>      25       O      1       6.000          5.506                         
> 0.494
>      26       O      1       6.000          5.532                         
> 0.468
>      27       O      1       6.000          5.545                         
> 0.455
>      28       O      1       6.000          5.552                         
> 0.448
>      29       O      1       6.000          5.599                         
> 0.401
>      30       O      1       6.000          5.553                         
> 0.447
>      31       O      1       6.000          5.574                         
> 0.426
>      32       O      1       6.000          5.479                         
> 0.521
>      33       O      1       6.000          5.576                         
> 0.424
>      34       O      1       6.000          5.537                         
> 0.463
>      35       O      1       6.000          5.536                         
> 0.464
>      36       O      1       6.000          5.641                         
> 0.359
>      37       O      1       6.000          5.589                         
> 0.411
>      38       O      1       6.000          5.554                         
> 0.446
>      39       O      1       6.000          5.572                         
> 0.428
>      40       O      1       6.000          5.517                         
> 0.483
>      41       O      1       6.000          5.554                         
> 0.446
>      42       O      1       6.000          5.589                         
> 0.411
>      43       O      1       6.000          5.539                         
> 0.461
>      44       O      1       6.000          5.579                         
> 0.421
>      45       O      1       6.000          5.787                         
> 0.213
>      46       O      1       6.000          5.538                         
> 0.462
>      47       O      1       6.000          5.625                         
> 0.375
>      48       O      1       6.000          5.574                         
> 0.426
>      49       O      1       6.000          5.508                         
> 0.492
>      50       O      1       6.000          5.527                         
> 0.473
>      51       O      1       6.000          5.539                         
> 0.461
>      52       O      1       6.000          5.594                         
> 0.406
>      53       O      1       6.000          5.599                         
> 0.401
>      54       O      1       6.000          5.554                         
> 0.446
>      55       O      1       6.000          5.571                         
> 0.429
>      56       O      1       6.000          5.516                         
> 0.484
>      57       O      1       6.000          5.554                         
> 0.446
>      58       O      1       6.000          5.595                         
> 0.405
>      59       O      1       6.000          5.516                         
> 0.484
>      60       O      1       6.000          5.573                         
> 0.427
>      61       O      1       6.000          5.528                         
> 0.472
>      62       O      1       6.000          5.512                         
> 0.488
>      63       O      1       6.000          5.667                         
> 0.333
>      64       O      1       6.000          5.541                         
> 0.459
>      65       O      1       6.000          5.548                         
> 0.452
>      66       O      1       6.000          5.500                         
> 0.500
>      67       O      1       6.000          5.952                         
> 0.048
>      68       O      1       6.000          5.544                         
> 0.456
>      69       O      1       6.000          5.548                         
> 0.452
>      70       O      1       6.000          5.591                         
> 0.409
>      71       O      1       6.000          5.620                         
> 0.380
>      72       O      1       6.000          5.575                         
> 0.425
>      73       O      1       6.000          5.591                         
> 0.409
>      74       O      1       6.000          5.560                         
> 0.440
>      75       O      1       6.000          5.574                         
> 0.426
>      76       O      1       6.000          5.650                         
> 0.350
>      77       O      1       6.000          5.497                         
> 0.503
>      78       O      1       6.000          5.543                         
> 0.457
>      79       O      1       6.000          5.542                         
> 0.458
>      80       O      1       6.000          5.726                         
> 0.274
>      81       O      1       6.000          5.519                         
> 0.481
>      82       O      1       6.000          5.533                         
> 0.467
>      83       O      1       6.000          5.546                         
> 0.454
>      84       O      1       6.000          5.551                         
> 0.449
>      85       O      1       6.000          5.599                         
> 0.401
>      86       O      1       6.000          5.563                         
> 0.437
>      87       O      1       6.000          5.569                         
> 0.431
>      88       O      1       6.000          5.511                         
> 0.489
>      89       O      1       6.000          5.551                         
> 0.449
>      90       O      1       6.000          5.591                         
> 0.409
>      91       O      1       6.000          5.537                         
> 0.463
>      92       O      1       6.000          5.508                         
> 0.492
>      93       O      1       6.000          5.880                         
> 0.120
>      94       O      1       6.000          5.540                         
> 0.460
>      95       O      1       6.000          5.623                         
> 0.377
>      96       O      1       6.000          5.575                         
> 0.425
>      97       O      1       6.000          5.514                         
> 0.486
>      98       O      1       6.000          5.534                         
> 0.466
>      99       O      1       6.000          5.534                         
> 0.466
>     100       O      1       6.000          5.627                         
> 0.373
>     101       O      1       6.000          5.586                         
> 0.414
>     102       O      1       6.000          5.553                         
> 0.447
>     103       O      1       6.000          5.573                         
> 0.427
>     104       O      1       6.000          5.575                         
> 0.425
>     105       O      1       6.000          5.515                         
> 0.485
>     106       O      1       6.000          5.526                         
> 0.474
>     107       O      1       6.000          5.536                         
> 0.464
>     108       O      1       6.000          5.772                         
> 0.228
>     109       O      1       6.000          5.593                         
> 0.407
>     110       O      1       6.000          5.546                         
> 0.454
>     111       O      1       6.000          5.572                         
> 0.428
>     112       O      1       6.000          5.667                         
> 0.333
>     113       O      1       6.000          5.590                         
> 0.410
>     114       O      1       6.000          5.574                         
> 0.426
>     115       O      1       6.000          5.782                         
> 0.218
>     116       O      1       6.000          5.537                         
> 0.463
>     117       O      1       6.000          5.550                         
> 0.450
>     118       O      1       6.000          5.508                         
> 0.492
>     119       O      1       6.000          5.569                         
> 0.431
>     120       O      1       6.000          5.584                         
> 0.416
>     121       O      1       6.000          5.521                         
> 0.479
>     122       O      1       6.000          5.540                         
> 0.460
>     123       O      1       6.000          5.541                         
> 0.459
>     124       O      1       6.000          5.544                         
> 0.456
>     125       O      1       6.000          5.565                         
> 0.435
>     126       O      1       6.000          5.570                         
> 0.430
>     127       O      1       6.000          5.697                         
> 0.303
>     128       Pt     2      18.000         17.978                         
> 0.022
>     129       Pt     2      18.000         18.312                        
> -0.312
>     130       Pt     2      18.000         18.443                        
> -0.443
>     131       Pt     2      18.000         18.479                        
> -0.479
>     132       Pt     2      18.000         18.211                        
> -0.211
>     133       Pt     2      18.000         18.065                        
> -0.065
>     134       Pt     2      18.000         18.389                        
> -0.389
>     135       Pt     2      18.000         18.155                        
> -0.155
>     136       Pt     2      18.000         18.355                        
> -0.355
>     137       Pt     2      18.000         18.421                        
> -0.421
>     138       Pt     2      18.000         18.156                        
> -0.156
>     139       Pt     2      18.000         18.220                        
> -0.220
>     140       Ti     3      12.000         12.504                        
> -0.504
>     141       Ti     3      12.000         12.932                        
> -0.932
>     142       Ti     3      12.000         12.902                        
> -0.902
>     143       Ti     3      12.000         13.080                        
> -1.080
>     144       Ti     3      12.000         12.473                        
> -0.473
>     145       Ti     3      12.000         12.928                        
> -0.928
>     146       Ti     3      12.000         12.904                        
> -0.904
>     147       Ti     3      12.000         13.083                        
> -1.083
>     148       Ti     3      12.000         13.130                        
> -1.130
>     149       Ti     3      12.000         12.908                        
> -0.908
>     150       Ti     3      12.000         12.929                        
> -0.929
>     151       Ti     3      12.000         12.565                        
> -0.565
>     152       Ti     3      12.000         12.523                        
> -0.523
>     153       Ti     3      12.000         12.930                        
> -0.930
>     154       Ti     3      12.000         13.050                        
> -1.050
>     155       Ti     3      12.000         12.904                        
> -0.904
>     156       Ti     3      12.000         12.937                        
> -0.937
>     157       Ti     3      12.000         12.309                        
> -0.309
>     158       Ti     3      12.000         12.905                        
> -0.905
>     159       Ti     3      12.000         13.081                        
> -1.081
>     160       Ti     3      12.000         12.534                        
> -0.534
>     161       Ti     3      12.000         12.933                        
> -0.933
>     162       Ti     3      12.000         12.896                        
> -0.896
>     163       Ti     3      12.000         13.054                        
> -1.054
>     164       Ti     3      12.000         13.117                        
> -1.117
>     165       Ti     3      12.000         12.911                        
> -0.911
>     166       Ti     3      12.000         12.922                        
> -0.922
>     167       Ti     3      12.000         12.560                        
> -0.560
>     168       Ti     3      12.000         12.493                        
> -0.493
>     169       Ti     3      12.000         12.927                        
> -0.927
>     170       Ti     3      12.000         12.904                        
> -0.904
>     171       Ti     3      12.000         13.064                        
> -1.064
>     172       Ti     3      12.000         13.120                        
> -1.120
>     173       Ti     3      12.000         12.911                        
> -0.911
>     174       Ti     3      12.000         12.929                        
> -0.929
>     175       Ti     3      12.000         12.376                        
> -0.376
>     176       Ti     3      12.000         12.911                        
> -0.911
>     177       Ti     3      12.000         13.106                        
> -1.106
>     178       Ti     3      12.000         12.421                        
> -0.421
>     179       Ti     3      12.000         12.936                        
> -0.936
>     180       Ti     3      12.000         12.927                        
> -0.927
>     181       Ti     3      12.000         12.434                        
> -0.434
>     182       Ti     3      12.000         13.059                        
> -1.059
>     183       Ti     3      12.000         12.901                        
> -0.901
>     184       Ti     3      12.000         11.777                         
> 0.223
>     185       Ti     3      12.000         12.933                        
> -0.933
>     186       Ti     3      12.000         12.891                        
> -0.891
>     187       Ti     3      12.000         13.010                        
> -1.010
>     188       Ti     3      12.000         13.086                        
> -1.086
>     189       Ti     3      12.000         12.907                        
> -0.907
>     190       Ti     3      12.000         12.910                        
> -0.910
>     191       Ti     3      12.000         12.380                        
> -0.380
>     192       Ti     3      12.000         12.910                        
> -0.910
>     193       Ti     3      12.000         13.029                        
> -1.029
>     194       Ti     3      12.000         12.927                        
> -0.927
>     195       Ti     3      12.000         12.546                        
> -0.546
>     196       Ti     3      12.000         13.116                        
> -1.116
>     197       Ti     3      12.000         12.909                        
> -0.909
>     198       Ti     3      12.000         11.567                         
> 0.433
>     199       Ti     3      12.000         12.918                        
> -0.918
>     200       Ti     3      12.000         11.786                         
> 0.214
>     201       Ti     3      12.000         12.904                        
> -0.904
>     202       Ti     3      12.000         12.904                        
> -0.904
>     203       Ti     3      12.000         12.785                        
> -0.785
>
>   Total Charge                                                            
> 0.000
>
>  !-----------------------------------------------------------------------------!
>
>  ENERGY| Total FORCE_EVAL ( QS ) energy (a.u.):            
> -7204.624366069552707
>
>
>
>  -------------------------------------------------------------------------------
>  -                                                                             
> -
>  -                                DBCSR 
> STATISTICS                             -
>  -                                                                             
> -
>
>  -------------------------------------------------------------------------------
>  COUNTER                                    TOTAL       BLAS       
> SMM       ACC
>  flops    13 x    25 x    13           3743096500       0.0%    
> 100.0%      0.0%
>  flops    26 x    25 x    13           4641145600       0.0%    
> 100.0%      0.0%
>  flops    13 x    25 x    26           4641145600       0.0%    
> 100.0%      0.0%
>  flops    26 x    25 x    26           5729100000       0.0%    
> 100.0%      0.0%
>  flops    13 x    32 x    13         186855377280       0.0%    
> 100.0%      0.0%
>  flops    26 x    32 x    13         231685988352       0.0%    
> 100.0%      0.0%
>  flops    13 x    32 x    26         231685988352       0.0%    
> 100.0%      0.0%
>  flops    26 x    32 x    26         285996672000       0.0%    
> 100.0%      0.0%
>  flops    13 x    13 x    57        1293425607240       0.0%    
> 100.0%      0.0%
>  flops    26 x    13 x    57        1589221360272       0.0%    
> 100.0%      0.0%
>  flops    13 x    26 x    57        1590495112596       0.0%    
> 100.0%      0.0%
>  flops    26 x    26 x    57        1989238235712       0.0%    
> 100.0%      0.0%
>  flops    13 x    13 x    64       27593079621120       0.0%    
> 100.0%      0.0%
>  flops    26 x    13 x    64       33903389019136       0.0%    
> 100.0%      0.0%
>  flops    13 x    26 x    64       33930562402048       0.0%    
> 100.0%      0.0%
>  flops    26 x    26 x    64       42437082361856       0.0%    
> 100.0%      0.0%
>  flops inhomo. stacks                           0       0.0%      
> 0.0%      0.0%
>  flops total                       145.281472E+12       0.0%    
> 100.0%      0.0%
>  flops max/rank                      3.901350E+12       0.0%    
> 100.0%      0.0%
>  matmuls inhomo. stacks                         0       0.0%      
> 0.0%      0.0%
>  matmuls total                         3555856660       0.0%    
> 100.0%      0.0%
>  number of processed stacks              28956800       0.0%    
> 100.0%      0.0%
>  average stack size                                     0.0     
> 122.8       0.0
>  marketing flops                   215.450693E+12
>
>  -------------------------------------------------------------------------------
>  # multiplications                           9046
>  max memory usage/rank               3.095101E+09
>  # max total images/rank                        5
>  # max 3D layers                                1
>  # MPI messages exchanged                22795920
>  MPI messages size (bytes):
>   total size                         6.049683E+12
>   min size                         160.056000E+03
>   max size                           1.391208E+06
>   average size                     265.384469E+03
>  MPI breakdown and total messages size (bytes):
>              size <=      128                   0                        0
>        128 < size <=     8192                   0                        0
>       8192 < size <=    32768                   0                        0
>      32768 < size <=   131072                   0                        0
>     131072 < size <=  4194304            22795920            6031471129632
>    4194304 < size <= 16777216                   0                        0
>   16777216 < size                               0                        0
>
>  -------------------------------------------------------------------------------
>
>  *** WARNING in dbcsr/mm/dbcsr_mm.F:268 :: Using a non-square number of ***
>  *** MPI ranks might lead to poor performance.                          ***
>  *** Used ranks: 40                                                     ***
>  *** Suggested: 36 81                                                   ***
>
>
>  -------------------------------------------------------------------------------
>
>  MEMORY| Estimated peak process memory 
> [MiB]                                2986
>
>
>  -------------------------------------------------------------------------------
>  ----                             MULTIGRID 
> INFO                            ----
>
>  -------------------------------------------------------------------------------
>  count for grid        1:        1075567          cutoff [a.u.]          
> 500.00
>  count for grid        2:        1613639          cutoff [a.u.]          
> 166.67
>  
> ...

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