SCF run NOT converged

Cindy Putri Arinta cputri... at gmail.com
Tue Mar 8 08:14:14 UTC 2016


thanks mr. Rizwan

first result still not converged but second result is run converged. is 
that problem?
and value of HOMO-LUMO gap is negative. my lecture say if the value is 
negative can not be accurate. how can i make this value be positive?
by the way, is there something wrong of my out???  


 DBCSR| Multiplication stack size                                           
1000
 DBCSR| Multiplication size 
stacks                                             0
 DBCSR| Use 
subcommunicators                                                   T
 DBCSR| Use MPI combined 
types                                                 F
 DBCSR| Use MPI memory 
allocation                                              T
 DBCSR| Use Communication 
thread                                               T
 DBCSR| Communication thread 
load                                            100


  **** **** ******  **  PROGRAM STARTED AT               2016-03-08 
15:03:20.514
 ***** ** ***  *** **   PROGRAM STARTED ON                       
kimiafmipaunesa
 **    ****   ******    PROGRAM STARTED BY                            
kimiaunesa
 ***** **    ** ** **   PROGRAM PROCESS ID                                  
5548
  **** **  *******  **  PROGRAM STARTED IN            
/home/kimiaunesa/Downloads

 CP2K| version string:                                        CP2K version 
2.4.0
 CP2K| source code revision number:                                        
12993
 CP2K| is freely available from                             
http://www.cp2k.org/
 CP2K| Program compiled at                          Sun Dec 22 03:52:45 UTC 
2013
 CP2K| Program compiled on                                               
komainu
 CP2K| Program compiled for                                
Linux-x86_64-gfortran
 CP2K| Input file name                                          
withOTmethod.inp

 GLOBAL| Force Environment 
number                                              1
 GLOBAL| Basis set file name                                      
./BASIS_MOLOPT
 GLOBAL| Geminal file name                                         
BASIS_GEMINAL
 GLOBAL| Potential file name                                         
./POTENTIAL
 GLOBAL| MM Potential file name                                     
MM_POTENTIAL
 GLOBAL| Coordinate file name                                      
__STD_INPUT__
 GLOBAL| Method name                                                        
CP2K
 GLOBAL| Project name                                                   
SiNT77Dd
 GLOBAL| Preferred FFT library                                             
FFTW3
 GLOBAL| Run type                                                   
ENERGY_FORCE
 GLOBAL| All-to-all communication in single 
precision                          F
 GLOBAL| FFTs using library dependent 
lengths                                  F
 GLOBAL| Global print 
level                                                  LOW
 GLOBAL| Total number of message passing 
processes                             1
 GLOBAL| Number of threads for this 
process                                    1
 GLOBAL| This output is from 
process                                           0

 MEMORY| system memory details [Kb]
 MEMORY|                        rank 0           min           max       
average
 MEMORY| MemTotal              2037340       2037340       2037340       
2037340
 MEMORY| MemFree                350984        350984        350984        
350984
 MEMORY| Buffers                 19056         19056         19056         
19056
 MEMORY| Cached                 328184        328184        328184        
328184
 MEMORY| Slab                    55256         55256         55256         
55256
 MEMORY| SReclaimable            30248         30248         30248         
30248
 MEMORY| MemLikelyFree          728472        728472        728472        
728472


 GENERATE|  Preliminary Number of Bonds 
generated:                             0
 GENERATE|  Achieved consistency in connectivity generation.

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######    **
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##        **
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##        **
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##        **
 **                                                                           
**
 **                                                ... make the atoms 
dance   **
 **                                                                           
**
 **            Copyright (C) by CP2K Developers Group (2000 - 
2013)           **
 **                                                                           
**
 *******************************************************************************


 SCF PARAMETERS         Density guess:                                    
ATOMIC
                        
--------------------------------------------------------
                        
max_scf:                                             100
                        
max_scf_history:                                       0
                        
max_diis:                                              4
                        
--------------------------------------------------------
                        eps_scf:                                        
1.00E-05
                        eps_scf_history:                                
0.00E+00
                        eps_diis:                                       
1.00E-01
                        eps_eigval:                                     
1.00E-05
                        
--------------------------------------------------------
                        level_shift [a.u.]:                                 
0.00
                        
--------------------------------------------------------
                        Outer loop SCF in use 
                        No variables optimised in outer loop
                        eps_scf                                         
1.00E-05
                        
max_scf                                              100
                        DIIS optimization
                        DIIS buffer 
length                                     3
                        step_size                                       
5.00E-01

 Number of 
electrons:                                                         56
 Number of occupied 
orbitals:                                                 28
 Number of molecular 
orbitals:                                                28

 Number of orbital 
functions:                                                308
 Number of independent orbital 
functions:                                    308

 Extrapolation method: initial_guess


 SCF WAVEFUNCTION OPTIMIZATION

  ----------------------------------- OT 
---------------------------------------

  Allowing for rotations:  F
  Optimizing orbital energies:  F
  Minimizer      : CG                  : conjugate gradient
  Preconditioner : FULL_KINETIC        : cholesky inversion of T + eS
  Precond_solver : DEFAULT
  Line search    : 2PNT                : 2 energies, one gradient
  stepsize       :    0.15000000
  energy_gap     :    0.00010000

  eps_taylor     :   0.10000E-15
  max_taylor     :             4

  mixed_precision    : F

  ----------------------------------- OT 
---------------------------------------

  Step     Update method      Time    Convergence         Total energy    
Change
  
------------------------------------------------------------------------------
     1 OT CG       0.15E+00    0.7     0.07404444       -41.5074835715 
-4.15E+01
     2 OT LS       0.14E+00    0.5                      -44.6931805716
     3 OT CG       0.14E+00    0.9     0.03749527       -44.6671323973 
-3.16E+00
     4 OT LS       0.23E+00    0.5                      -45.8865777659
     5 OT CG       0.23E+00    0.8     0.02684912       -46.1365749967 
-1.47E+00
     6 OT LS       0.19E+00    0.4                      -46.7260580759
     7 OT CG       0.19E+00    0.8     0.01861989       -46.7483298944 
-6.12E-01
     8 OT LS       0.22E+00    0.5                      -47.0735511437
     9 OT CG       0.22E+00    1.0     0.01337661       -47.0783241199 
-3.30E-01
    10 OT LS       0.23E+00    0.4                      -47.2551889345
    11 OT CG       0.23E+00    0.8     0.00990581       -47.2555084712 
-1.77E-01
    12 OT LS       0.28E+00    0.4                      -47.3703740137
    13 OT CG       0.28E+00    0.8     0.00817938       -47.3737541324 
-1.18E-01
    14 OT LS       0.29E+00    0.4                      -47.4568180594
    15 OT CG       0.29E+00    0.8     0.00708931       -47.4568676679 
-8.31E-02
    16 OT LS       0.26E+00    0.4                      -47.5120651520
    17 OT CG       0.26E+00    0.8     0.00588672       -47.5128662082 
-5.60E-02
    18 OT LS       0.25E+00    0.4                      -47.5507774131
    19 OT CG       0.25E+00    0.8     0.00498408       -47.5507900510 
-3.79E-02
    20 OT LS       0.27E+00    0.4                      -47.5795999401
    21 OT CG       0.27E+00    0.8     0.00428766       -47.5796845575 
-2.89E-02
    22 OT LS       0.30E+00    0.4                      -47.6028426309
    23 OT CG       0.30E+00    0.8     0.00363344       -47.6029981343 
-2.33E-02
    24 OT LS       0.29E+00    0.4                      -47.6197299773
    25 OT CG       0.29E+00    0.8     0.00325087       -47.6197301023 
-1.67E-02
    26 OT LS       0.27E+00    0.4                      -47.6319015927
    27 OT CG       0.27E+00    0.8     0.00286563       -47.6320066327 
-1.23E-02
    28 OT LS       0.31E+00    0.4                      -47.6426685982
    29 OT CG       0.31E+00    0.8     0.00267709       -47.6428136525 
-1.08E-02
    30 OT LS       0.28E+00    0.4                      -47.6512454727
    31 OT CG       0.28E+00    0.8     0.00237289       -47.6513441347 
-8.53E-03
    32 OT LS       0.28E+00    0.4                      -47.6580867389
    33 OT CG       0.28E+00    0.8     0.00213503       -47.6580869617 
-6.74E-03
    34 OT LS       0.35E+00    0.4                      -47.6646250642
    35 OT CG       0.35E+00    0.8     0.00208166       -47.6648870028 
-6.80E-03
    36 OT LS       0.34E+00    0.4                      -47.6712677863
    37 OT CG       0.34E+00    0.8     0.00208224       -47.6712694732 
-6.38E-03
    38 OT LS       0.28E+00    0.4                      -47.6762271893
    39 OT CG       0.28E+00    0.8     0.00199653       -47.6764944235 
-5.22E-03
    40 OT LS       0.29E+00    0.4                      -47.6814843963
    41 OT CG       0.29E+00    0.8     0.00186078       -47.6814913594 
-5.00E-03
    42 OT LS       0.32E+00    0.4                      -47.6861790108
    43 OT CG       0.32E+00    0.8     0.00168456       -47.6862068834 
-4.72E-03
    44 OT LS       0.33E+00    0.4                      -47.6902333082
    45 OT CG       0.33E+00    0.8     0.00158222       -47.6902403275 
-4.03E-03
    46 OT LS       0.27E+00    0.4                      -47.6929474325
    47 OT CG       0.27E+00    0.8     0.00141051       -47.6931145556 
-2.87E-03
    48 OT LS       0.29E+00    0.4                      -47.6955569339
    49 OT CG       0.29E+00    0.8     0.00123671       -47.6955686950 
-2.45E-03
    50 OT LS       0.30E+00    0.4                      -47.6975606676
    51 OT CG       0.30E+00    0.8     0.00115749       -47.6975667627 
-2.00E-03
    52 OT LS       0.30E+00    0.4                      -47.6992823339
    53 OT CG       0.30E+00    0.8     0.00104284       -47.6992829536 
-1.72E-03
    54 OT LS       0.31E+00    0.4                      -47.7007435754
    55 OT CG       0.31E+00    0.8     0.00095916       -47.7007469945 
-1.46E-03
    56 OT LS       0.30E+00    0.4                      -47.7019500761
    57 OT CG       0.30E+00    0.8     0.00090972       -47.7019510028 
-1.20E-03
    58 OT LS       0.29E+00    0.4                      -47.7029687432
    59 OT CG       0.29E+00    0.8     0.00084119       -47.7029725720 
-1.02E-03
    60 OT LS       0.31E+00    0.4                      -47.7039141256
    61 OT CG       0.31E+00    0.8     0.00079929       -47.7039199779 
-9.47E-04
    62 OT LS       0.31E+00    0.4                      -47.7047812248
    63 OT CG       0.31E+00    0.8     0.00074819       -47.7047812628 
-8.61E-04
    64 OT LS       0.31E+00    0.4                      -47.7055225190
    65 OT CG       0.31E+00    0.8     0.00068894       -47.7055227463 
-7.41E-04
    66 OT LS       0.29E+00    0.4                      -47.7061257060
    67 OT CG       0.29E+00    0.8     0.00063286       -47.7061267858 
-6.04E-04
    68 OT LS       0.28E+00    0.4                      -47.7066165506
    69 OT CG       0.28E+00    0.8     0.00057619       -47.7066172432 
-4.90E-04
    70 OT LS       0.29E+00    0.4                      -47.7070280441
    71 OT CG       0.29E+00    0.8     0.00050490       -47.7070280780 
-4.11E-04
    72 OT LS       0.32E+00    0.4                      -47.7073718124
    73 OT CG       0.32E+00    0.8     0.00045896       -47.7073746228 
-3.47E-04
    74 OT LS       0.29E+00    0.4                      -47.7076348050
    75 OT CG       0.29E+00    0.8     0.00042595       -47.7076370091 
-2.62E-04
    76 OT LS       0.29E+00    0.4                      -47.7078604494
    77 OT CG       0.29E+00    0.8     0.00038158       -47.7078604786 
-2.23E-04
    78 OT LS       0.31E+00    0.4                      -47.7080513075
    79 OT CG       0.31E+00    0.8     0.00035095       -47.7080520818 
-1.92E-04
    80 OT LS       0.29E+00    0.4                      -47.7082065189
    81 OT CG       0.29E+00    0.8     0.00031260       -47.7082068589 
-1.55E-04
    82 OT LS       0.29E+00    0.4                      -47.7083300205
    83 OT CG       0.29E+00    0.8     0.00028611       -47.7083300213 
-1.23E-04
    84 OT LS       0.28E+00    0.4                      -47.7084290860
    85 OT CG       0.28E+00    0.8     0.00024937       -47.7084292432 
-9.92E-05
    86 OT LS       0.30E+00    0.4                      -47.7085099626
    87 OT CG       0.30E+00    0.8     0.00022497       -47.7085103691 
-8.11E-05
    88 OT LS       0.29E+00    0.4                      -47.7085743360
    89 OT CG       0.29E+00    0.8     0.00020233       -47.7085743984 
-6.40E-05
    90 OT LS       0.28E+00    0.4                      -47.7086245267
    91 OT CG       0.28E+00    0.8     0.00018547       -47.7086245785 
-5.02E-05
    92 OT LS       0.30E+00    0.4                      -47.7086684309
    93 OT CG       0.30E+00    0.8     0.00016763       -47.7086685012 
-4.39E-05
    94 OT LS       0.30E+00    0.4                      -47.7087052414
    95 OT CG       0.30E+00    0.8     0.00015375       -47.7087052626 
-3.68E-05
    96 OT LS       0.29E+00    0.4                      -47.7087351131
    97 OT CG       0.29E+00    0.8     0.00013654       -47.7087351495 
-2.99E-05
    98 OT LS       0.30E+00    0.4                      -47.7087589601
    99 OT CG       0.30E+00    0.8     0.00012513       -47.7087589626 
-2.38E-05
   100 OT LS       0.29E+00    0.4                      -47.7087782371

  *** SCF run NOT converged ***


  Electronic density on regular grids:        -55.9999959549        
0.0000040451
  Core density on regular grids:               55.9992335002       
-0.0007664998
  Total charge density on r-space grids:       -0.0007624547
  Total charge density g-space grids:          -0.0007624547

  Overlap energy of the core charge distribution:               
0.10191923351839
  Self energy of the core charge distribution:               
-143.61189399397432
  Core Hamiltonian energy:                                     
40.86423685761076
  Hartree energy:                                              
72.95311806125856
  Exchange-correlation energy:                                
-18.01615839547864

  Total energy:                                               
-47.70877823706523

  outer SCF iter =    1 RMS gradient =   0.13E-03 energy =        
-47.7087782371

  ----------------------------------- OT 
---------------------------------------

  Allowing for rotations:  F
  Optimizing orbital energies:  F
  Minimizer      : CG                  : conjugate gradient
  Preconditioner : FULL_KINETIC        : cholesky inversion of T + eS
  Precond_solver : DEFAULT
  Line search    : 2PNT                : 2 energies, one gradient
  stepsize       :    0.15000000
  energy_gap     :    0.00010000

  eps_taylor     :   0.10000E-15
  max_taylor     :             4

  mixed_precision    : F

  ----------------------------------- OT 
---------------------------------------

  Step     Update method      Time    Convergence         Total energy    
Change
  
------------------------------------------------------------------------------
     1 OT CG       0.15E+00    1.2     0.00021854       -47.7087782626 
-1.93E-05
     2 OT LS       0.29E+00    0.4                      -47.7088239378
     3 OT CG       0.29E+00    0.8     0.00022628       -47.7088375138 
-5.93E-05
     4 OT LS       0.20E+00    0.4                      -47.7088730333
     5 OT CG       0.20E+00    0.8     0.00016434       -47.7088816073 
-4.41E-05
     6 OT LS       0.29E+00    0.4                      -47.7089118992
     7 OT CG       0.29E+00    0.8     0.00012750       -47.7089149543 
-3.33E-05
     8 OT LS       0.24E+00    0.4                      -47.7089314427
     9 OT CG       0.24E+00    0.8     0.00009299       -47.7089319859 
-1.70E-05
    10 OT LS       0.30E+00    0.4                      -47.7089427423
    11 OT CG       0.30E+00    0.8     0.00008330       -47.7089431341 
-1.11E-05
    12 OT LS       0.29E+00    0.4                      -47.7089517887
    13 OT CG       0.29E+00    0.8     0.00007053       -47.7089517979 
-8.66E-06
    14 OT LS       0.29E+00    0.4                      -47.7089579402
    15 OT CG       0.29E+00    0.8     0.00006081       -47.7089579410 
-6.14E-06
    16 OT LS       0.29E+00    0.4                      -47.7089624926
    17 OT CG       0.29E+00    0.8     0.00005061       -47.7089624926 
-4.55E-06
    18 OT LS       0.31E+00    0.4                      -47.7089659226
    19 OT CG       0.31E+00    0.8     0.00004707       -47.7089659494 
-3.46E-06
    20 OT LS       0.30E+00    0.4                      -47.7089687868
    21 OT CG       0.30E+00    0.8     0.00004107       -47.7089687942 
-2.84E-06
    22 OT LS       0.29E+00    0.4                      -47.7089708861
    23 OT CG       0.29E+00    0.8     0.00003484       -47.7089708885 
-2.09E-06
    24 OT LS       0.28E+00    0.4                      -47.7089723509
    25 OT CG       0.28E+00    0.8     0.00003111       -47.7089723521 
-1.46E-06
    26 OT LS       0.27E+00    0.4                      -47.7089734727
    27 OT CG       0.27E+00    0.8     0.00002511       -47.7089734745 
-1.12E-06
    28 OT LS       0.29E+00    0.4                      -47.7089742656
    29 OT CG       0.29E+00    0.8     0.00002095       -47.7089742709 
-7.96E-07
    30 OT LS       0.31E+00    0.4                      -47.7089748549
    31 OT CG       0.31E+00    0.8     0.00001852       -47.7089748566 
-5.86E-07
    32 OT LS       0.27E+00    0.4                      -47.7089752558
    33 OT CG       0.27E+00    0.8     0.00001563       -47.7089752624 
-4.06E-07
    34 OT LS       0.24E+00    0.4                      -47.7089755106
    35 OT CG       0.24E+00    0.8     0.00001270       -47.7089755157 
-2.53E-07
    36 OT LS       0.24E+00    0.4                      -47.7089756805
    37 OT CG       0.24E+00    0.9     0.00001035       -47.7089756806 
-1.65E-07
    38 OT LS       0.25E+00    0.5                      -47.7089757949
    39 OT CG       0.25E+00    0.8     0.00000800       -47.7089757952 
-1.15E-07

  *** SCF run converged in    39 steps ***


  Electronic density on regular grids:        -55.9999959620        
0.0000040380
  Core density on regular grids:               55.9992335002       
-0.0007664998
  Total charge density on r-space grids:       -0.0007624618
  Total charge density g-space grids:          -0.0007624618

  Overlap energy of the core charge distribution:               
0.10191923351839
  Self energy of the core charge distribution:               
-143.61189399397432
  Core Hamiltonian energy:                                     
40.86857517501443
  Hartree energy:                                              
72.94910611157788
  Exchange-correlation energy:                                
-18.01668232129036

  Total energy:                                               
-47.70897579515398

  outer SCF iter =    2 RMS gradient =   0.80E-05 energy =        
-47.7089757952
  outer SCF loop converged in   2 iterations or  139 steps

  
  Eigenvalues of the occupied subspace spin            1
 ---------------------------------------------
      -0.65614265     -0.56850376     -0.51849735     -0.43706784
      -0.43053420     -0.42591345     -0.41393475     -0.40665561
      -0.37420023     -0.33572589     -0.28498438     -0.25588240
      -0.24313310     -0.23375186     -0.21876717     -0.18604278
      -0.17980789     -0.17561798     -0.16223906     -0.15601129
      -0.15152653     -0.14240155     -0.12902764     -0.12822427
      -0.12226921     -0.11458259     -0.10270273     -0.07859282
 Fermi Energy [eV] :   -2.138619
  
  Lowest Eigenvalues of the unoccupied subspace spin            1
 -----------------------------------------------------
  Reached convergence in           73  iterations 
      -0.08473799
  
 HOMO - LUMO gap [eV] :   -0.167219

 ENERGY| Total FORCE_EVAL ( QS ) energy (a.u.):              
-47.708975869398131


 -------------------------------------------------------------------------------
 -                                                                             
-
 -                         MESSAGE PASSING 
PERFORMANCE                         -
 -                                                                             
-
 -------------------------------------------------------------------------------

 ROUTINE             CALLS  TOT TIME [s]  AVE VOLUME [Bytes]  PERFORMANCE 
[MB/s]
 MP_Group                4         0.000
 MP_Bcast              141         0.001                  5.                
0.65
 MP_Allreduce          457         0.001                 17.                
7.60
 MP_Sync             23332         0.004
 -------------------------------------------------------------------------------


 -------------------------------------------------------------------------------
 -                                                                             
-
 -                           R E F E R E N C E 
S                               -
 -                                                                             
-
 -------------------------------------------------------------------------------
 
 CP2K version 2.4.0, the CP2K developers group (2013).
 CP2K is freely available from http://www.cp2k.org/ .

 VandeVondele, J; Hutter, J. 
 JOURNAL OF CHEMICAL PHYSICS, 127 (11), 114105 (2007). 
 Gaussian basis sets for accurate calculations on molecular systems in
 gas and condensed phases.
 http://dx.doi.org/10.1063/1.2770708


 Krack, M. 
 THEORETICAL CHEMISTRY ACCOUNTS, 114 (1-3), 145-152 (2005). 
 Pseudopotentials for H to Kr optimized for gradient-corrected
 exchange-correlation functionals.
 http://dx.doi.org/10.1007/s00214-005-0655-y


 VandeVondele, J; Krack, M; Mohamed, F; Parrinello, M; Chassaing, T;
 Hutter, J. COMPUTER PHYSICS COMMUNICATIONS, 167 (2), 103-128 (2005). 
 QUICKSTEP: Fast and accurate density functional calculations using a
 mixed Gaussian and plane waves approach.
 http://dx.doi.org/10.1016/j.cpc.2004.12.014


 Frigo, M; Johnson, SG. 
 PROCEEDINGS OF THE IEEE, 93 (2), 216-231 (2005). 
 The design and implementation of FFTW3.
 http://dx.doi.org/10.1109/JPROC.2004.840301


 VandeVondele, J; Hutter, J. 
 JOURNAL OF CHEMICAL PHYSICS, 118 (10), 4365-4369 (2003). 
 An efficient orbital transformation method for electronic structure
 calculations.
 http://dx.doi.org/10.1063/1.1543154


 Hartwigsen, C; Goedecker, S; Hutter, J. 
 PHYSICAL REVIEW B, 58 (7), 3641-3662 (1998). 
 Relativistic separable dual-space Gaussian pseudopotentials from H to Rn.
 http://dx.doi.org/10.1103/PhysRevB.58.3641


 Lippert, G; Hutter, J; Parrinello, M. 
 MOLECULAR PHYSICS, 92 (3), 477-487 (1997). 
 A hybrid Gaussian and plane wave density functional scheme.
 http://dx.doi.org/10.1080/002689797170220


 Goedecker, S; Teter, M; Hutter, J. 
 PHYSICAL REVIEW B, 54 (3), 1703-1710 (1996). 
 Separable dual-space Gaussian pseudopotentials.
 http://dx.doi.org/10.1103/PhysRevB.54.1703


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 SUBROUTINE                       CALLS  ASD         SELF TIME        TOTAL 
TIME
                                              AVERAGE  MAXIMUM  AVERAGE  
MAXIMUM
 CP2K                                 1  1.0    0.006    0.006   89.614   
89.614
 qs_forces                            1  2.0    0.020    0.020   89.185   
89.185
 qs_energies_scf                      1  3.0    0.000    0.000   88.484   
88.484
 scf_env_do_scf                       1  4.0    0.001    0.001   85.086   
85.086
 scf_env_do_scf_inner_loop          139  5.0    0.020    0.020   83.911   
83.911
 qs_ks_build_kohn_sham_matrix       140  7.0    0.076    0.076   42.705   
42.705
 qs_ks_update_qs_env                141  6.0    0.000    0.000   42.229   
42.229
 qs_rho_update_rho                  140  6.0    0.001    0.001   40.651   
40.651
 calculate_rho_elec                 140  7.0   16.199   16.199   40.650   
40.650
 fft_wrap_pw1pw2                   1066  9.4    0.019    0.019   32.603   
32.603
 fft_wrap_pw1pw2_160                427 10.1    2.264    2.264   29.932   
29.932
 density_rs2pw                      140  8.0    0.005    0.005   24.050   
24.050
 sum_up_and_integrate                71  8.0    0.556    0.556   20.439   
20.439
 fft3d_s                           1067 11.4   20.116   20.116   20.137   
20.137
 integrate_v_rspace                  71  9.0   13.208   13.208   19.883   
19.883
 qs_vxc_create                      140  8.0    0.003    0.003    9.964    
9.964
 xc_rho_set_and_dset_create         140 10.0    0.010    0.010    9.116    
9.116
 xc_functional_eval                 140 11.0    8.616    8.616    8.616    
8.616
 potential_pw2rs                     71 10.0    0.025    0.025    6.658    
6.658
 xc_vxc_pw_create                    71  9.0    0.431    0.431    5.454    
5.454
 pw_poisson_solve                   140  8.0    3.195    3.195    5.133    
5.133
 pw_gather_s                        640 11.2    5.110    5.110    5.110    
5.110
 pw_scatter_s                       426 11.8    4.799    4.799    4.799    
4.799
 xc_exc_calc                         69  9.0    0.414    0.414    4.507    
4.507
 pw_copy                            844  9.8    3.734    3.734    3.734    
3.734
 cp_dbcsr_multiply_d               3181  9.5    0.008    0.008    3.083    
3.083
 dbcsr_multiply_anytype            3181 11.5    0.088    0.088    2.936    
2.936
 scf_post_calculation_gpw             1  4.0    0.000    0.000    2.886    
2.886
 qs_scf_loop_do_ot                  139  6.0    0.000    0.000    2.354    
2.354
 pw_axpy                            708  8.8    2.268    2.268    2.268    
2.268
 fft_wrap_pw1pw2_60                 213 10.6    0.241    0.241    2.235    
2.235
 ot_scf_mini                        139  7.0    0.019    0.019    1.995    
1.995
 pw_to_cube                           2  6.0    1.866    1.866    1.866    
1.866
 dbcsr_mm_cannon_multiply          3181 12.5    0.052    0.052    1.540    
1.540
 dbcsr_mm_cannon_multiply_multre   3181 13.5    1.275    1.275    1.275    
1.275
 cp_dbcsr_mult_NS_NR                518  9.4    0.000    0.000    1.238    
1.238
 init_scf_loop                        2  5.0    0.016    0.016    1.174    
1.174
 qs_scf_post_unocc_cubes              1  5.0    0.000    0.000    1.148    
1.148
 ot_mini                            212  7.7    0.011    0.011    1.119    
1.119
 qs_scf_post_occ_cubes                1  5.0    0.000    0.000    1.094    
1.094
 rs_pw_transfer                     854  9.6    0.016    0.016    0.924    
0.924
 qs_ot_get_derivative               107  8.7    0.000    0.000    0.881    
0.881
 pw_zero                            142  9.0    0.657    0.657    0.657    
0.657
 make_lumo                            1  5.0    0.000    0.000    0.636    
0.636
 ot_eigensolver                       1  6.0    0.000    0.000    0.635    
0.635
 dbcsr_make_images                 6253 12.5    0.011    0.011    0.583    
0.583
 make_images                       6253 13.5    0.075    0.075    0.572    
0.572
 qs_ks_update_qs_env_forces           1  3.0    0.000    0.000    0.507    
0.507
 qs_ot_get_p                        216  7.6    0.001    0.001    0.480    
0.480
 rs_pw_transfer_RS2PW_160           143 10.0    0.476    0.476    0.476    
0.476
 cp_dbcsr_mult_NR_NS                708 10.4    0.003    0.003    0.469    
0.469
 qs_ot_get_derivative_diag           82  9.6    0.001    0.001    0.468    
0.468
 quickstep_create_force_env           1  2.0    0.000    0.000    0.418    
0.418
 rs_grid_zero                       569  8.0    0.409    0.409    0.409    
0.409
 qs_init_subsys                       1  3.0    0.002    0.002    0.409    
0.409
 pw_env_rebuild                       1  7.0    0.000    0.000    0.403    
0.403
 pw_env_create                        1  6.0    0.000    0.000    0.403    
0.403
 qs_env_rebuild_pw_env                1  5.0    0.000    0.000    0.403    
0.403
 qs_env_setup                         1  4.0    0.000    0.000    0.403    
0.403
 cp_dbcsr_mult_TR_NR                537 10.6    0.001    0.001    0.391    
0.391
 pw_grid_setup                        4  8.0    0.008    0.008    0.389    
0.389
 calculate_wavefunction               2  6.0    0.007    0.007    0.376    
0.376
 calculate_dm_sparse                140  7.0    0.001    0.001    0.362    
0.362
 fft_wrap_pw1pw2_20                 213 10.6    0.026    0.026    0.343    
0.343
 cp_dbcsr_mult_NR_TR                141  9.0    0.000    0.000    0.342    
0.342
 pw_grid_sort                         4  9.0    0.249    0.249    0.337    
0.337
 scf_env_initial_rho_setup            1  5.0    0.000    0.000    0.325    
0.325
 init_scf_run                         1  4.0    0.000    0.000    0.325    
0.325
 qs_ot_get_orbitals                 214  7.6    0.000    0.000    0.288    
0.288
 dbcsr_create_new                 52847 13.8    0.139    0.139    0.286    
0.286
 cp_dbcsr_mult_NS_NS                656 11.5    0.000    0.000    0.260    
0.260
 qs_ot_p2m_diag                     168  8.6    0.010    0.010    0.253    
0.253
 rs_pw_transfer_PW2RS_160            72 11.9    0.250    0.250    0.250    
0.250
 dbcsr_make_images_dense           5501 12.8    0.023    0.023    0.230    
0.230
 apply_single                       111  9.7    0.001    0.001    0.224    
0.224
 apply_preconditioner_dbcsr         111  8.7    0.000    0.000    0.224    
0.224
 make_dense                        8165 13.8    0.064    0.064    0.212    
0.212
 make_images_data                  6253 14.5    0.193    0.193    0.193    
0.193
 qs_ot_get_derivative_taylor         25  9.8    0.000    0.000    0.187    
0.187
 qs_energies_init_hamiltonians        1  4.0    0.000    0.000    0.183    
0.183
 build_core_hamiltonian_matrix_f      1  3.0    0.000    0.000    0.174    
0.174
 cp_dbcsr_mult_NS_TS                418 10.8    0.000    0.000    0.169    
0.169
 make_images_pack                  6253 14.5    0.146    0.146    0.167    
0.167
 pw_scale                            71  8.0    0.162    0.162    0.162    
0.162
 dbcsr_addto_index_array         270512 15.3    0.133    0.133    0.133    
0.133
 cp_dbcsr_copy                     7849 11.1    0.007    0.007    0.127    
0.127
 make_dense_data                   8165 14.8    0.100    0.100    0.121    
0.121
 matrix_match_sizes                3181 10.5    0.009    0.009    0.118    
0.118
 dbcsr_make_index_exist           52847 14.8    0.036    0.036    0.114    
0.114
 qs_env_update_s_mstruct              1  5.0    0.000    0.000    0.112    
0.112
 dbcsr_finalize                    5604 12.7    0.019    0.019    0.106    
0.106
 calculate_rho_core                   1  6.0    0.007    0.007    0.102    
0.102
 setup_buffer_matrices            12724 13.5    0.015    0.015    0.099    
0.099
 rs_pw_transfer_RS2PW_60            142 10.0    0.095    0.095    0.095    
0.095
 dbcsr_make_dense                  2664 12.9    0.007    0.007    0.092    
0.092
 dbcsr_copy                        8883 12.0    0.029    0.029    0.091    
0.091
 sort_shells                          4 10.0    0.088    0.088    0.088    
0.088
 quick_finalize                    9281 15.0    0.030    0.030    0.083    
0.083
 dbcsr_destroy                    44874 13.0    0.064    0.064    0.082    
0.082
 dbcsr_make_undense                2664 12.9    0.047    0.047    0.079    
0.079
 build_kinetic_matrix                 2  5.0    0.075    0.075    0.075    
0.075
 fft_wrap_pw1pw2_10                 213 10.6    0.008    0.008    0.074    
0.074
 cp_dbcsr_syevd                     168  9.6    0.006    0.006    0.073    
0.073
 make_preconditioner                  2  7.0    0.007    0.007    0.071    
0.071
 prepare_preconditioner               2  6.0    0.000    0.000    0.071    
0.071
 build_core_hamiltonian_matrix        1  5.0    0.000    0.000    0.070    
0.070
 dbcsr_special_finalize            6253 14.5    0.010    0.010    0.066    
0.066
 cp_dbcsr_mult_TS_NS                164 11.6    0.000    0.000    0.065    
0.065
 build_overlap_matrix                 2  5.0    0.061    0.061    0.061    
0.061
 internal_data_allocate           74277 14.7    0.060    0.060    0.060    
0.060
 qs_ot_p2m_taylor                    48  8.8    0.002    0.002    0.060    
0.060
 make_full_inverse_cholesky           2  8.0    0.000    0.000    0.057    
0.057
 dbcsr_iterator_start             31794 14.6    0.046    0.046    0.056    
0.056
 build_core_ppl_forces                1  4.0    0.051    0.051    0.051    
0.051
 dbcsr_merge_all                   2398 13.4    0.019    0.019    0.050    
0.050
 dbcsr_mm_multrec_init             3181 13.5    0.034    0.034    0.050    
0.050
 rs_pw_transfer_PW2RS_60             71 12.0    0.046    0.046    0.046    
0.046
 dbcsr_switch_data_area           28766 14.7    0.028    0.028    0.045    
0.045
 pw_grid_assign                       4  9.0    0.043    0.043    0.043    
0.043
 internal_data_deallocate         74277 14.7    0.042    0.042    0.042    
0.042
 dbcsr_make_untransposed_blocks    3748 12.5    0.032    0.032    0.041    
0.041
 dbcsr_complete_redistribute        413 13.1    0.026    0.026    0.041    
0.041
 cp_dbcsr_complete_redistribute     413 12.1    0.000    0.000    0.041    
0.041
 cp_dbcsr_create_template          6513 12.5    0.001    0.001    0.036    
0.036
 dbcsr_new_transposed              1384 12.5    0.006    0.006    0.035    
0.035
 cp_dbcsr_add_d                    1115  9.9    0.002    0.002    0.034    
0.034
 cp_fm_cholesky_invert                2  9.0    0.033    0.033    0.033    
0.033
 cp_fm_syevd_base                   170 11.6    0.033    0.033    0.033    
0.033
 cp_fm_syevd                        170 10.6    0.000    0.000    0.033    
0.033
 dbcsr_add_anytype                 1115 11.9    0.013    0.013    0.032    
0.032
 dbcsr_add_d                       1115 10.9    0.000    0.000    0.032    
0.032
 calculate_ecore                    280  7.0    0.001    0.001    0.031    
0.031
 dbcsr_trace_a_b_d                  782  9.3    0.031    0.031    0.031    
0.031
 cp_dbcsr_trace_ab_d                782  8.3    0.000    0.000    0.031    
0.031
 build_core_ppnl_forces               1  4.0    0.030    0.030    0.030    
0.030
 copy_dbcsr_to_fm                   412 10.6    0.002    0.002    0.030    
0.030
 dbcsr_make_index_list             6253 12.5    0.021    0.021    0.027    
0.027
 dbcsr_iterator_stop              31794 14.6    0.026    0.026    0.026    
0.026
 dbcsr_add_wm_from_matrix           567 12.0    0.001    0.001    0.025    
0.025
 copy_fm_to_dbcsr                   414 10.6    0.003    0.003    0.024    
0.024
 dbcsr_work_create                11679 13.7    0.016    0.016    0.024    
0.024
 dbcsr_fill_wm_from_matrix          567 13.0    0.013    0.013    0.023    
0.023
 dbcsr_sort_indices               11665 15.6    0.022    0.022    0.022    
0.022
 cp_dbcsr_sm_fm_multiply              6  7.2    0.000    0.000    0.022    
0.022
 build_core_ppl                       1  6.0    0.022    0.022    0.022    
0.022
 cp_dbcsr_mult_NR_NR                 39  9.9    0.000    0.000    0.021    
0.021
 get_fft_scratch                   1067 12.4    0.021    0.021    0.021    
0.021
 setup_rec_index                   6362 13.5    0.005    0.005    0.021    
0.021
 rs_pw_transfer_RS2PW_20            142 10.0    0.020    0.020    0.020    
0.020
 cp_dbcsr_sm_fm_multiply_core         6  8.2    0.000    0.000    0.020    
0.020
 dbcsr_make_dists_dense            2805 12.8    0.019    0.019    0.019    
0.019
 cp_dbcsr_release                  7040 11.4    0.008    0.008    0.019    
0.019
 cp_fm_cholesky_decompose             6  8.2    0.019    0.019    0.019    
0.019
 qs_scf_loop_print                  139  6.0    0.019    0.019    0.019    
0.019
 calculate_first_density_matrix       1  6.0    0.000    0.000    0.018    
0.018
 dbcsr_data_copyall                2054 12.2    0.018    0.018    0.018    
0.018
 dbcsr_index_prune_deleted         5501 13.8    0.011    0.011    0.017    
0.017
 dbcsr_make_index_local_row        6253 12.5    0.016    0.016    0.017    
0.017
 dbcsr_set_anytype                  446 10.8    0.017    0.017    0.017    
0.017
 cp_dbcsr_finalize                  511 10.7    0.000    0.000    0.017    
0.017
 cp_dbcsr_set_d                     282  8.7    0.000    0.000    0.016    
0.016
 call_rec_sort_index               6352 14.5    0.016    0.016    0.016    
0.016
 write_mo_set_to_restart            139  6.0    0.015    0.015    0.015    
0.015
 dbcsr_get_local_vrows            29118 13.3    0.013    0.013    0.013    
0.013
 merge_index                       2398 14.4    0.013    0.013    0.013    
0.013
 compute_max_radius                   1  8.0    0.013    0.013    0.013    
0.013
 cp_dbcsr_transposed                124 10.7    0.000    0.000    0.012    
0.012
 dbcsr_mm_driver_outer_init        3181 14.5    0.011    0.011    0.011    
0.011
 rs_pw_transfer_PW2RS_20             71 12.0    0.010    0.010    0.010    
0.010
 dbcsr_get_global_vrow_map        18116 13.0    0.010    0.010    0.010    
0.010
 dbcsr_iterator_seek              31794 15.6    0.010    0.010    0.010    
0.010
 generate_qs_task_list                1  7.0    0.009    0.009    0.010    
0.010
 qs_create_task_list                  1  6.0    0.000    0.000    0.010    
0.010
 ot_scf_init                          2  6.0    0.000    0.000    0.010    
0.010
 make_basis_sm                        2  6.5    0.000    0.000    0.009    
0.009
 dbcsr_data_copy_aa2                730 13.7    0.009    0.009    0.009    
0.009
 rs_pw_transfer_RS2PW_10            142 10.0    0.009    0.009    0.009    
0.009
 dbcsr_get_local_vcols            29118 13.3    0.009    0.009    0.009    
0.009
 transpose_index_local             1384 13.5    0.005    0.005    0.009    
0.009
 dbcsr_init_wm                    11679 14.7    0.006    0.006    0.008    
0.008
 dbcsr_scale_by_vector_anytype      475 10.1    0.006    0.006    0.007    
0.007
 cp_dbcsr_scale_by_vector_d         475  9.1    0.000    0.000    0.007    
0.007
 dbcsr_mm_multrec_finalize         3181 13.5    0.007    0.007    0.007    
0.007
 dbcsr_get_global_vcol_map        18116 13.0    0.007    0.007    0.007    
0.007
 read_atomic_kind                     1  4.0    0.004    0.004    0.007    
0.007
 read_atomic_kind_set                 1  3.0    0.000    0.000    0.007    
0.007
 subspace_eigenvalues_ks_fm           2  6.0    0.000    0.000    0.007    
0.007
 cp_dbcsr_plus_fm_fm_t_native         2  7.0    0.000    0.000    0.006    
0.006
 make_mo_eig                          1  5.0    0.000    0.000    0.006    
0.006
 dbcsr_redistribute                 124 12.7    0.001    0.001    0.006    
0.006
 dbcsr_get_local_rows              5845 13.2    0.006    0.006    0.006    
0.006
 cp_dbcsr_iterator_start            543 10.6    0.002    0.002    0.005    
0.005
 build_core_ppnl                      1  6.0    0.005    0.005    0.005    
0.005
 integrate_v_core_rspace              1  5.0    0.001    0.001    0.005    
0.005
 calculate_w_matrix_ot                1  5.0    0.000    0.000    0.004    
0.004
 qs_energies_compute_matrix_w         1  4.0    0.000    0.000    0.004    
0.004
 dbcsr_hadamard_product             164 11.6    0.002    0.002    0.004    
0.004
 cp_dbcsr_hadamard_product          164 10.6    0.000    0.000    0.004    
0.004
 cp_fm_upper_to_full                  8  9.5    0.004    0.004    0.004    
0.004
 fill_hash_tables                  3181 14.5    0.004    0.004    0.004    
0.004
 make_images_sizes                 6253 14.5    0.004    0.004    0.004    
0.004
 dbcsr_get_local_cols              5845 13.2    0.004    0.004    0.004    
0.004
 cp_dbcsr_distribution            10293 11.5    0.004    0.004    0.004    
0.004
 pw_pool_give_back_pw              2759  9.7    0.004    0.004    0.004    
0.004
 cp_dbcsr_create_new                527 11.0    0.000    0.000    0.004    
0.004
 tree_to_linear_d                   793 14.7    0.002    0.002    0.004    
0.004
 cp_dbcsr_deallocate_matrix          10  3.8    0.000    0.000    0.003    
0.003
 dbcsr_cholesky_invert                6  8.7    0.000    0.000    0.003    
0.003
 cp_fm_gemm                          11  7.1    0.003    0.003    0.003    
0.003
 dbcsr_get_global_row_map          3181 12.5    0.003    0.003    0.003    
0.003
 cp_dbcsr_nfullrows_total         15905 11.1    0.003    0.003    0.003    
0.003
 dbcsr_get_data_size_used          5426 13.7    0.003    0.003    0.003    
0.003
 cp_fm_create                       389 10.3    0.003    0.003    0.003    
0.003
 cp_dbcsr_init                     7040 11.4    0.003    0.003    0.003    
0.003
 parser_read_line_low                 2  5.0    0.003    0.003    0.003    
0.003
 cp_dbcsr_work_create               491 10.9    0.001    0.001    0.003    
0.003
 dbcsr_add_on_diag_anytype           96 10.8    0.000    0.000    0.002    
0.002
 cp_dbcsr_add_on_diag                96  9.8    0.000    0.000    0.002    
0.002
 cp_dbcsr_gershgorin_norm           216  8.6    0.002    0.002    0.002    
0.002
 make_full_kinetic                    2  8.0    0.000    0.000    0.002    
0.002
 rs_pw_transfer_PW2RS_10             71 12.0    0.002    0.002    0.002    
0.002
 dbcsr_get_global_col_map          3181 12.5    0.002    0.002    0.002    
0.002
 cp_dbcsr_nfullcols_total         15905 11.1    0.002    0.002    0.002    
0.002
 dbcsr_scale_anytype               1153 12.8    0.002    0.002    0.002    
0.002
 topology_control                     1  3.0    0.000    0.000    0.002    
0.002
 qs_scf_post_xray                     1  5.0    0.001    0.001    0.001    
0.001
 make_basis_sv_dbcsr                  2  7.0    0.000    0.000    0.001    
0.001
 write_mo_dependent_results           1  6.0    0.001    0.001    0.001    
0.001
 write_available_results              1  5.0    0.000    0.000    0.001    
0.001
 dbcsr_block_transpose_aa           385 12.9    0.001    0.001    0.001    
0.001
 dbcsr_set_block_pointer_any       1504 13.0    0.001    0.001    0.001    
0.001
 cp_fm_release                      394 10.1    0.001    0.001    0.001    
0.001
 dbcsr_mm_cannon_multiply_metroc   6362 13.5    0.001    0.001    0.001    
0.001
 cp_dbcsr_get_info                 2130 10.1    0.001    0.001    0.001    
0.001
 cp_fm_init_random                    2  6.5    0.001    0.001    0.001    
0.001
 cp_dbcsr_iterator_stop             543 10.6    0.001    0.001    0.001    
0.001
 calculate_atom_restricted            1  9.0    0.001    0.001    0.001    
0.001
 calculate_atom                       1  8.0    0.000    0.000    0.001    
0.001
 calculate_atomic_block_dm            1  7.0    0.000    0.000    0.001    
0.001
 wfi_extrapolate                      1  6.0    0.001    0.001    0.001    
0.001
 calculate_ecore_efield               2  4.0    0.001    0.001    0.001    
0.001
 distribute_tasks                     1  8.0    0.001    0.001    0.001    
0.001
 pw_pool_create_pw                 2272  9.5    0.001    0.001    0.001    
0.001
 init_cube_info                       4  8.0    0.001    0.001    0.001    
0.001
 pw_grid_distribute                   4  9.0    0.001    0.001    0.001    
0.001
 scf_c_write_parameters               1  4.0    0.001    0.001    0.001    
0.001
 write_qs_control                     1  4.0    0.001    0.001    0.001    
0.001
 scf_c_read_parameters                1  4.0    0.001    0.001    0.001    
0.001
 read_qs_section                      1  4.0    0.001    0.001    0.001    
0.001
 check_generate_mol                   1  7.0    0.001    0.001    0.001    
0.001
 topology_generate_bond_4             1  6.0    0.000    0.000    0.001    
0.001
 topology_generate_bond               1  5.0    0.000    0.000    0.001    
0.001
 connectivity_control                 1  4.0    0.000    0.000    0.001    
0.001
 read_topology_section                1  4.0    0.001    0.001    0.001    
0.001
 dbcsr_get_conf_nstacks            3182 14.5    0.001    0.001    0.001    
0.001
 -------------------------------------------------------------------------------

  **** **** ******  **  PROGRAM ENDED AT                 2016-03-08 
15:04:50.212
 ***** ** ***  *** **   PROGRAM RAN ON                           
kimiafmipaunesa
 **    ****   ******    PROGRAM RAN BY                                
kimiaunesa
 ***** **    ** ** **   PROGRAM PROCESS ID                                  
5548
  **** **  *******  **  PROGRAM STOPPED IN            
/home/kimiaunesa/Downloads

On Tuesday, March 8, 2016 at 2:45:18 PM UTC+7, Rizwan Nabi wrote:
>
>
> Hi Cindy Putri Arinta 
>
> I have modified your input file please try with this one. Hope it will 
> work fine now. 
>
> Regards 
>
> Rizwan 
> Mumbai(India)
>
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